22-06-2026

4602CJA101031260003 JM

PART-1 : PHYSICS

SECTION-I

1) Bullets of mass 50g are fired from a gun of mass 10 kg with velocity of 300 m/s. If 5 bullets are
fired per second then what force a person will have to apply on the gun so that it does not recoil:-

(A) 75 N
(B) 150 N
(C) 225 N
(D) 300 N

2) A unidirectional force F varying with time t as shown in the fig, acts on a body initially at rest, for

a short duration 2T. Then the velocity acquired by the body is :-

(A)

(B)

(C)

(D) zero

3) A block of mass m is resting on a wedge of angle θ as shown in the figure. With what minimum

acceleration a should the wedge move so that the mass m falls freely :-

(A) g
(B) g cos θ
(C) g cot θ
(D) g tan θ

4) Coefficient of friction of given parabolic surface is µ. Maximum height upto which a block can be
placed without slipping is :-

(A)

(B)

(C)

(D)

5) A horizontal force of 10 N is necessary to just hold a block stationary against a wall. The
coefficient of friction between the block and the wall is 0.2. The weight of the block is-

(A) 2 N
(B) 20 N
(C) 50 N
(D) 100 N

6) For the arrangement in figure, the tension in the string to prevent it from sliding down, is:-

(A) 6
(B) 6.4 N
(C) 0.4 N
(D) Zero

7) A body of mass m is moved from rest, along a straight line, by an engine delivering constant
power P. The velocity of the body after time t will be

(A)
(B)

(C)

(D)

8) A body initially at rest and sliding along a frictionless track from a height h (as shown in the
figure) just completes a vertical circle of diameter AB = D. The height h is equal to

(A)

(B) D

(C)

(D)

9) A bob is attached to a string. The string is held horizontal and the bob is released from this
position. When magnitude of centripetal acceleration of bob becomes equal in magnitude of the
tangential acceleration, string makes an angle θ with vertical. Then θ is equal to

(A) tan–1 (2)

(B)
tan–1

(C)
sin–1

(D)
cos–1

10) Track OABCD (as shown is figure) is smooth and fixed in vertical plane. What minimum speed
has to be given to a particle lying at point A, so that it can reach point C?
(A) 60 m/s
(B) 100 m/s
(C) 70 m/s
(D) 80 m/s

11) A particle moves in a circle and it covered the angle as θ = t2 + 2t, then instantaneous angular
acceleration at t = 2 s in rad/s2 will be :-

(A) 4
(B) 2
(C) 3
(D) 1

12) A car is moving on a curved path with banking angle θ, the coefficient of friction between tyres
of car and road is μs. The maximum safe velocity of car is:-

(A)

(B)

(C)

(D)

13) A mass M of 100 kg is suspended with the use of strings A, B and C as shown in the figure where
W is the vertical wall and R is a rigid horizontal rod. The tension in the string B is :-
(A) 103 N
(B) Zero
(C)

(D)

14) A trolley T (mass 5 kg) on a horizontal smooth surface is pulled by a load L (2 kg) through a
uniform rope ABC of length 2m and mass 1 kg. As the load falls from BC = 0m to BC = 2m, its

acceleration (in ms–2) changes from (Take g = 10 ms–2) :

(A)

(B)

(C)

(D) None of these

15) Two block (A) 2 kg and (B) 5 kg rest one over the other on a smooth horizontal plane. The
coefficient of static and dynamic friction between (A) and (B) is the same and equal to 0.60. The
maximum horizontal force that can be applied to (B) in order that both (A) and (B) do not have any

relative motion : (g = 10 m/s2)

(A) 42 N
(B) 42 kgf
(C) 5.4 kgf
(D) 1.2 N
16) If the spring constant of the spring in figure is 100 N/m, extension produced in it is nearly.

(Given system move with uniform steady state acceleration).

(A) 18 cm
(B) 13 cm
(C) 9 cm
(D) 21 cm

17) The graph between and p is -

(Ek = kinetic energy and P = momentum)

(A)

(B)

(C)

(D)

18) If the maximum compression in the spring is 50 cm then find the value of K(g = 10 m/s2) :-
(A)

(B)

(C)

(D) None of these

19) A particle is moving along a circular path. The angular velocity, velocity, angular acceleration
and centripetal acceleration of the partical at any instant respectively are , which of
the following relations is/are correct?
(a) (b)
(c) (d)

(A) a, b, c
(B) b, c, d
(C) a, c, d
(D) b, d, a

20)

A particle crosses the topmost point C of a vertical circle with critical speed; then the ratio of
velocities at points A, B and C is :-

(A) 3 : 2 : 1
(B) 5 : 3 : 1
(C) 52 : 32 : 12
(D)

SECTION-II

1) 10 kg block is placed 5m from rear end of a trolley coefficient of friction between block & trolley
is 0.2 starting from rest trolley is provided 3 m/s2 constant acceleration. After what distance (in m)
moved by trolley, block will start falling ? (g = 10m/s2)

2) Figure shows a boy on a horizontal platform A on a smooth horizontal surface, holding a rope
attached to a box B. Boy pulls the rope with a constant force of 50 N. (boy does not slip over the
platform). The combined mass of platform A and boy is 250 kg and that of box B is 500 kg. The
velocity of A relative to the box B (in m/s), 5 sec after the boy on A begins to pull the rope, will be

3) The potential energy of a 1 kg particle free to move along the x-axis is given by :-

The total mechanical energy of the particle is 2 J. Then the maximum speed (in m/s) is . Then N is
:-

4) A ball is thrown from 10m height at speed v0 vertically downward. In colliding surface of earth it
looses 50% of its energy and again reach upto same height. Value of v0 is :-

5) A block of mass m = 20 kg is kept at a distance R = 1m from central axis of rotation of a round

turn table (A table whose surface can rotate about central axis). Table starts from rest and rotates
with constant angular acceleration, α = 3 rad/sec2. The friction coefficient between block and table

is μ = 0.5. At time t = sec from starting of motion (i.e. t = 0 sec) the block is just about to slip.
Find the value of x.

PART-2 : CHEMISTRY

SECTION-I

1) An orbital with ℓ = 0 is symmetrical about the :-

(A) x-axis only

(B) y-axis only
(C) z-axis only
(D) The nucleus
2) Which of the following statement is true :-
(a) 6 electrons are present in Mg for which m = 0
(b) Maximum 6 electrons can accomdate in -orbital
(c) Maximum 18 electrons present in M-shell
(d) 3–electron present in phosphorous for which,

l = 0, S =

(A) a, b, c, d
(B) a, b c
(C) a, c, d
(D) c, d

3) Select incorrect probability distribution curve :

(A)

(B)

(C)

(D)

4) Radial part of wave function of a particular orbital is given below

where a = 0.529 Å and . Select the correct statement.

(A) The orbital has no radial node

(B) The orbital has one radial nodes
(C) The orbital has two radial nodes
(D) The orbital has three radial nodes
5) In which of the following processes, the value of magnetic moment does not change ?

–2
(A) N2 → N2
–2
(B) B2 → B2
+ –
(C) O2 → O2
– –2
(D) O2 → O2

6) Back bonding in BF3 does not affect :

(A) Planarity, Lewis acidic strength and bond angle

(B) Bond length, hybridization and bond strength
(C) Bond angle, planarity and geometry
(D) Lewis acidic strength, bond length and bond order (B–F)

7) Which of the following would result in the formation of strongest π-bond if the molecular axis is x-
axis ?

(A) 2px + 2px

(B) 2py + 2py
(C) 2py + 3dxy
(D) 2pz + 4pz

8) Which of the following statements is incorrect ?

(A) In O2 molecules, the energy of σ2pz is more than π2py

(B) C2, and N2 are diamagnetic

(C) He2 molecule does not exist as the effect of bonding and anti-bonding orbitals cancel each other
(D) Among , O2 and the order of bond strength is > O2 >

9) Which of the following species used both axial set of d-orbitals in hybridization of central atom?

+
(A) PCl4
(B) SF4
(C) XeF4
(D) ClF3

10) The shapes of XeF4, and SnCl2 are :-

(A) Octahedral, trigonal bipyramidal and bent

(B) Square pyramidal, pentagonal planar and linear
(C) Square planar, pentagonal planar and angular
(D) See-saw, T-shaped and linear

11) A sigma bond may be formed by the overlap of two atomic orbitals of atoms A and B. If the bond
is formed along the x-axis, which of the following overlaps is acceptable ?

(A) s-orbital of A and pz-orbital of B.

(B) px-orbital of A and py-orbital of B.
(C) pz - orbital of A and px - orbital of B
(D) px - orbital of A and s - orbital of B

12) Which of the following statements is true on the basis of back bonding ?

(A) Si–O bond is stronger than C–O bond

(B) Dimethyl ether acts a better lewis base than disilyl ether (SiH3–O–SiH3)
(C) (CH3)3C–O–H is less acidic than (CH3)3Si–O–H
(D) All of these

13) Which of the following compound does not have hydrogen bonding :

(A) K2HPO4
(B) K2HPO3
(C) NaHCO3(s)

(D)

14) Which force is least sensitive for distance :-

(A) Ion-dipole attraction

(B) Dipole-induced dipole
(C) Ion-induced dipole
(D) Dispersion force

15) Which of the following is an incorrect match ?

(A) Maximum IE in a period - Inert gases

(B) Maximum IE2 in second period - Li
(C) Maximum IE3 in third period - Mg
(D) Minimum IE in carbon family - Pb

16) Arrange the following statements in order of True(T)/False (F) :-

(a) Among Li+, Be+ and B+ ions Li+ has the highest ionization enthalpy
(b) The negative value of electron gain enthalpy of Cl > F because there is weak electron-electron
repulsion in the bigger 3p-subshell of Cl as compared to compact 2p-subshell of F
(c) Formation of S–2 and Ar–, both require the absorption of energy
(d) Incorrect order of electron affinity is S > Se > Te > O

(A) TTTF
(B) FFFT
(C) FFTT
(D) TTTT

17) There are four elements 'p', 'q', 'r' and 's' having atomic numbers Z–1, Z, Z+1 and Z+2
respectively. If the element 'q' is an inert gas, select the correct answers from the following
statements.
(i) 'p' has most negative electron gain enthalpy in the respective period.
(ii) 'r' is an alkali metal.
(iii) 's' exists in +2 oxidation state.

(A) (i) and (ii) only

(B) (ii) and (iii) only
(C) (i) and (iii) only
(D) (i), (ii) and (iii)

18) X ml of H2 gas effuses through a hole in a container in 5 seconds. The time taken for the effusion
of the same volume of gas specified below under identical condition is :-

(A) 10 seconds, helium

(B) 20 seconds, oxygen
(C) 25 seconds, carbon monoxide
(D) 55 seconds, carbon dioxide

19) Which one of the following statements is NOT true about the effect of an increase in temperature
on the distribution of molecular speeds in a gas?

(A) The fraction of the molecules with the most probable speed increases
(B) The most probable speed increases
(C) The area under the distribution curve remains the same as under the lower temperature
(D) The distribution becomes broader

20)

If Z is a compressibility factor, van der Waal's equation at low pressure can be written as :

Z=1–
(A)

Z=1+
(B)

Z=1+
(C)

Z=1–
(D)
 SECTION-II

1) The graph between compressibility factor (z) and pressure (P) is plotted for one mole of a real gas
at constant temperature of 273K as shown in fig. If the slope of graph at very high pressure is

, then excluded volume of one mole of real gas molecules ( "b" in litres/mole) is.

Given = R=

2) Critical temperature and critical pressure of a real gas is 27°C & 75 atm respectively. Then what
is critical volume of 1 mole of real gas (in mL).
(R = 0.08 atm-L/mol-K)

3) At identical temperature and pressure the rate of diffusion of hydrogen gas is that of a
hydrocarbon having molecular formula CnH2n–2. The value of n is:

4) The number of waves made by a Bohr electron in an orbit of maximum magnetic quantum number
+2:

5) In an atom, the total number of electrons having quantum numbers n = 4, |mℓ| = 1 and ms = – is

PART-3 : MATHEMATICS

SECTION-I

1) If sec θ + tan θ = 1/3.

Then value of 8 cot2θ – 5 sinθ is :-

(A)

(B)

(C)

(D)

2) No. of solution of equation sin x =

in the interval [–π, 2π] is :-
(A) 2
(B) 3
(C) 4
(D) 6

3) If 1 + sinθ + sin2θ + .... to ∞ = 4 + 2 ,

0 < θ < π, , then θ =

(A)

(B)

(C)

(D)

4) If 0 < θ < π, then minimum value of

3 sin θ + cosec3 θ is :-

(A) 4
(B) 3
(C) 5
(D) 6

5) If tan A = and tan B =

then tan(A+B) is equal :-

(A)

(B)

(C) 1
(D) None

6) If sin θ, 1, cos 2θ are in G.P., then θ =

(A) nπ + (–1)n (-π/6)

(B) nπ + (–1)n (-π/2)
(C) no real θ exists
(D) None of these

7) Number of solutions of
in the interval [0, 4π] is :-
(A) 0
(B) 2
(C) 3
(D) 7

8)

In a triangle ABC, if
and a = 2, then its area is :-

(A)
(B)

(C)

(D)

9) In ΔABC, if .
then a2, b2 , c2 are in :-

(A) A.P.
(B) G.P.
(C) H.P.
(D) None of these

10) If x = 2 + 21/3 + 22/3

then value of x3 – 6x2 + 6x is :-

(A) –2
(B) 2
(C) 0
(D) None

11) If graph of y = ax2 – bx + c is following,

then sign of a, b, c are :-

(A) a < 0, b < 0, c < 0

(B) a < 0, b > 0, c < 0
(C) a < 0, b < 0, c > 0
(D) a > 0, b > 0, c < 0
12) If one root of equation (x–1)(7–x) = m
is three times the other then m is :-

(A) –5
(B) 0
(C) 2
(D) 5

13) The interval of k for which equation

x2+kx – 4 = 0 has its smaller root lies in the interval (–1,2) is :-

(A) (– ∞,–3)
(B) (0, 3)
(C) (0, ∞)
(D) (– ∞,–3) ∪ (0,∞)

14) If both roots of equation

x2 – (k – 1)x + k – 2 = 0
lies in (–2, 3) then k ∈

(A) R
(B) (–3, 5)
(C) (0, 5)
(D) (–3, 0)

15) If α2 = 5α – 3, β2 = 5β – 3

then the value of is :-

(A)

(B)

(C)

(D) none of these

16) Let α and β be the roots of the

equation 5x2 + 6x – 2 = 0.
If Sn = αn + βn, n = 1, 2, 3 ..., then

(A) 5S6 + 6S5 = 2S4

(B) 5S6 + 6S5 + 2S4 = 0
(C) 6S6 + 5S5 + 2S4 = 0
(D) 6S6 + 5S5 = 2S4

17) The roots of 5x2 – 7x + k = 0 are

sin A and cos A the value of k is :-

(A)

(B)

(C) 7
(D) 1

18) If α and β are the roots of equation

x2 – 3x + 12 = 0 and the roots of the equation

x2 + px + q = 0 are α2 + β2 and , then-

(A) p = –9, q = –90

(B) p = –9, q = 90
(C) p = 9, q = 90
(D) p = 9, q = –90

19) If α, β, γ, δ are the roots of

x4 – 100x3 + 2x2 + 4x + 10 = 0

then is equal to :-

(A)

(B)

(C) 4

(D)

20) The equation 5x2 + 12x + 13 = 0 and

ax2 + bx + c = 0 have a common root, where a, b, c are the sides of ΔABC, then find ∠C?

(A) 45°
(B) 60°
(C) 90°
(D) 30°

SECTION-II

1) Let p, q ∈ {1, 2, 3, 4}. Then number of equations of the form px2 + qx + 1 = 0, having real roots,
is :-

2) If α, β are the roots of the equation

x2 – 3x – 15 = 0, and f(n) = αn + βn,
then is equal to :-

3) The maximum value of the expression

is :-

4)

The value of is:-

5)

If tan θ = , then θ = (in degree)

where
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D C D A D A D A D B B A B A B C A C D

SECTION-II

Q. 21 22 23 24 25
A. 15.00 1.50 3.00 14.00 2.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D B C C C B A C C D D B A D A D B A D

SECTION-II

Q. 46 47 48 49 50
A. 8.00 120.00 4.00 3.00 6.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C D A C B C B A B A D A C A A A D D C

SECTION-II

Q. 71 72 73 74 75
A. 7.00 8.00 2.00 4.00 54.00
 SOLUTIONS

PART-1 : PHYSICS

1)

Correct option is (1)

2) Δp = Area of force time-graph = 0

3)
N + ma sinθ = mg cosθ
If the block falls freely, N = 0
ma sinθ = mg cosθ
a = g cotθ

4) Question Explanation : The question asks to find maximum height on a curve.

Concept : Limiting Frication and Slope of a curve.
Solution :

tan θ = µ ⇒ = µ ⇒ 4x = µ ⇒ x = y = 2x2 =
Final Answer : Option (4)

5) Given: Horizontal force, F = 10 N and coefficient of friction between block and wall (μ) =
0.2
We know that at equilibrium horizontal force provides the normal reaction to the block against
the wall. Therefore, normal reaction to the block (R) = F = 10 N
We also know that weight of the block (W) = Frictional force = 2 N.

6)
Fe = μ Mg cos37°

= 0.8 × 1 × 10 ×
Fe = 6.4 N
Mg sin37° < Fe
Thus T = 0

7)

8) As body is at rest initially, i.e., speed = 0.

At point A, speed = v
As track is frictionless, so total mechanical energy will remain constant
(T.M.E.)i = (T.M.E.)f

or
For completing the vertical circle,

9)

at = gsinθ = aC =

mg L cosθ = × mv2
V2 = 2gLcos(θ)

2g cos(θ) = g sin(θ)
tan(θ) = 2
10) Apply work energy theorem between point A & B.
v = 80 m/s

11) Explanation :-
A particle moves in a circle. Its angular position is given by θ = t2 + 2t. We need to find the
instantaneous angular acceleration at t = 2s.
Concept :-
Angular acceleration is the rate of change of angular velocity with respect to time.

Formula:
• Angular velocity (ω) = dθ/dt.
• Angular acceleration (α) = d2θ/dt2

Calculation :-
• θ = t2 + 2t
• First find angular velocity:
ω = dθ/dt = 2t + 2
• Now differentiate ω to find α:
Thus, the instantaneous angular acceleration is α = 2 rad/s2 .

Correct option: (2)

Correct answer with option : (2)

Estimated time ; 1-2 minute

level : Easy

12)

Fcp = N sinθ + f cosθ .... (1)

Mg + f sinθ = N cosθ ....(2)

13)

TC cos 45° = TB,

TC sin 45° = 103,
∵ TB = 103 N

14)

When BC = 0

When BC = 2m

15) Question Explanation : In this question, we are asked to find the maximum horizontal
force applied on block B such that blocks A and B move together without any relative motion
between them.

Concept : Two block system. (on a smooth surface)

Solution :
Mass of block A = 2 kg
Mass of block B = 5 kg
Coefficient of friction between A and B :
μ = 0.6
Acceleration due to gravity:
g = 10 m/s2
Step 1: Maximum friction between A and B
Normal reaction on A :
N = mA g = 2 × 10 = 20 N
Maximum static friction:

Step 2: Acceleration of system

Since both blocks are moving together with common acceleration (No relative motion between
them)
For block A, friction provides acceleration:

Step 3: Maximum force on system

Total mass of system:

Final Answer : Option (1)

16)
2g – T = 2a

kx = T =

⇒ x ⇌ 13 cm

18) Explanation the Question : Find spring constant from max compression on a rough
surface.
Concept: This question is based on work-energy theorem.
Solution:
wfriction = ΔKE + ΔU

– μmg(ℓ + x) =

Final answer : 1

19)

a, c, d

20)

Question Asking About:

The velocity ratio at points A, B and C in a vertical circle, given critical speed at C.

Key Concept:

• Energy Conservation =
• Critical Speed at C:

Formula & Calculation:

 VA = ?, VB = ?, VC = ?
• At C:
• At B:

• At A:

• Velocity Ratio:

Final Answer:

Conclusion:
Hence, option (4) is correct.

21)

[NCERT pg # 113]

Srelative = arelative t2

t=

strolley =

22)

a1 = m/s2 a2 = m/s2

v1 = 5 × = 1 m/s v2 = 5 × = m/s
 v12 = 1.5 m/s

23) Potential energy U =

For maximum kinetic energy, potential energy of a particle should be minimum.

For minimum value of U, and

After calculation at x = ±1

Umin = –
TE = KEmax + PEmin
⇒ KEmax = TE – PEmin

vmax =

24) Energy balance method

0
mgh + mv 2 = + mgh

0
mv 2 = mgh – mgh
v0 = = 14 m/s

25)

(0.5 × 10)2 = x4 + 9
x2 = 16
x=2

PART-2 : CHEMISTRY

26)

ℓ=0
s-orbital → non directional

symmetrical about the nucleus

27)

(b) One orbital occupied maximum 2e–

(c) M shell n = 3, no. of e– = 2n2 = 2 × 32 = 18
(d) P = 1s22s22p63s23p3

l = 0 for s orbital, so 6e–, in s, so for 3e, s =

and for 3e, s =

28)

Explain the question: Identify incorrect atomic orbital probability or wave plots.

Concept: Boundary conditions: Ψs(0) ≠ 0 and 4πr2Ψ2(0) = 0 always.

Solution:
According to quantum mechanics, s-orbitals possess non-zero electron density at the nucleus,
so their wave functions (Ψ) and probability densities (Ψ2) correctly start at a maximum at r = 0,
as seen in plots 1 and 3. For any orbital with ℓ > 0 (like 2p), the wave function is zero at the
origin, matching plot 4.
However, the Radial Probability Distribution Function is defined as 4πr2Ψ2. Because of the
leading r2 term, this function must always be zero at the origin (r = 0) for all orbitals,
including 1s. Plot 2 shows a non-zero maximum value for 4πr2Ψ2 at the nucleus, making it
fundamentally incorrect.

Final Answer: Option (2)

29) 6 – 6σ + σ2 is a quadratic expression and it has two real roots.

30)

31) Due to back bonding in BF3, it's bond length, bond energy, bond strength and lewis acidic
strength changes but there is no change in bond angle, hybridization, geometry and planarity.
32) 2px + 2px will form s-bond
2py + 2py and 2px + 3dxy will form π-bond but
2pπ-2pπ bond is stronger than 2pπ-3dπ

33) In O2 molecule, the energy of σ2pz is less than π2px and π2py.

34) Species lp bp shape

PCl4+ 0 4 sp3
SF4 1 4 sp3d
XeF4 2 4 sp3d2
ClF3 2 3 sp3d
In sp3d2 hybridization, axial d-orbitals and are used.

35)

36)

37) Question Explanation:

The question asks which statement is true on the basis of back bonding.

Concept:
pπ-dπ back bonding

Solution:
All three statements are correct due to back bonding:
1. bond is stronger than because of back donation from O to empty d-
orbital of Si .
2. Dimethyl ether is a better Lewis base than disilyl ether because back bonding in
reduces electron density on oxygen in disilyl ether.
3. is less acidic than because back bonding in makes the
bond weaker.

Final Answer: Option (4).

38)
 39) Ion-dipole attraction is least sensitive towards distance.

40)

Question Explanation:
Find the incorrect ionization energy match.

Concept:
In group 14, due to lanthanoid contraction, Pb has higher effective nuclear charge than Sn .
Solution:
Therefore, IE(Pb)>IE(Sn)
So minimum IE is Sn , not Pb .
Final Answer:
Option 4 (Incorrect match)

41)

Correct order of electron affinity is

S > Se > Te > O

42) As 'q' is noble gas, p, r and s having atomic number Z–1, Z+1 and Z+2 should belong to
halogen, alkali metal and alkaline earth metal respectively. As halogen has one electron less
than stable noble gas configuration it has greater tendency to accept an additional electron
forming anion. Alkaline earth metal having valence shell configuration ns2 exists in +2
oxidation state.

43)

Check every option to satisfy the relation option (B) satisfied

44)

With increase in temperature curve moves to wards right side with flattening of curve

45)

At low pressure
 46) At high pressure z = 1 +

= slope

= 8 litres

47)

48)

14n – 2 = 54
14 n = 56 ⇒ n = 4

49) maximum magnetic [Link]. = +2

ℓ=2
ℓ=n–1
2=n–1
n=3

50)

n = 4, |mℓ| = 1, ms =

Total no. of electron having n = 4, |mℓ| = 1 &

ms = – =6

PART-3 : MATHEMATICS

51) sec θ + tan θ =

add.

52)

53)

54) Using A.M. ≥ G.M.

Hence, minimum value of 3 sinθ + cosec3θ is 4.

55) Using tan(A + B) =

56) sin θ, 1, cos 2θ are in G.P. ⇒ cos 2θ sin θ = 1

∴ sin θ – 2sin3θ = 1 ⇒ 2sin3θ – sin θ + 1 = 0
⇒ (sin θ + 1)(2sin2θ – 2sinθ + 1) = 0
⇒ sin θ = –1, since other roots are imaginary.

∴ θ = nπ + (–1)n
57) cosx + cos2x + cos3x + cos4x + cos5x = 5

58) We know

Given
Dividing (i) by (ii), we get
tan A = tan B = tan C
⇒ ΔABC is equilateral triangle.

∴ Area =

59) sinA sin (B-C) = sinC sin (A-B)

sin(B + C) sin (B – C)
= sin (A+B) sin (A–B)
sin2B–sin2C = sin2A–sin2B
2sin2B = sin2A + sin2C

2b2 = a2 + c2

60) x – 2 = 21/3 + 22/3

cutting both side

x3 – 8 – 3x · 2 (x–2) = (21/3 + 22/3)3
x3 – 8 – 6x2 + 12x = 2 + 22 + 3.2 (x–2)
x3 – 8 – 6x2 + 12x = 6 + 6x – 12
x3 – 6x2 + 6x = 2

61) Give graph indicates that both roots are positive so sum of roots > 0 and product of roots
>0

&
a < 0 because mouth of parabola opens downward
∴ b<0&c<0
So, a < 0, b < 0, c < 0

62)

x2– 8x + 7 + m = 0
Let α and 3α are roots then α + 3β = 8 ⇒ α = 2
Putting in equation gives m = 5
63)
Let f(x) = x2 + kx – 4
f(–1) > 0 and f(2) < 0
k < – 3 and k < 0
So k∈(– ∞, – 3)

64) A = 1, B = – (k – 1), C = (k – 2)
A+B+C=0
so one root of equation α = 1

other β = =
–2 < k – 2 < 3

65) α, β are the roots of the equation x2 – 5x + 3 = 0

α + β = 5 and αβ = 3
⇒ α2 + β2 + 2αβ = 25
⇒ α2 + β2 = 19

66) α and β are roots of 5x2 + 6x – 2 = 0

⇒ 5α2 + 6α – 2 = 0
⇒ 5αn + 2 + 6αn + 1 – 2αn = 0 ....(1)
(By multiplying αn)
Similarly 5βn + 2 + 6βn + 1 – 2βn = 0 ....(2)
By adding (1) & (2)
5Sn + 2 + 6Sn + 1 – 2Sn = 0
For n = 4

67) sinA + cosA =

68) α + β = 3, αβ = 12
Let x1 = α2 + β2
= (α + β)2 – 2αβ = 9 – 24 = –15

x2 =
x1 + x2 = –p ⇒ p = 9
x1x2 = q ⇒ q = –90

69) x4 – 100x3 + 2x2 + 4x + 10 = 0 → α,β,γ,δ

eqn whose roots are is

10x4 + 4x3 + 2x2 – 100x + 1 = 0 →

70) Roots of 5x2 + 12x + 13 = 0 are imaginary so

= k (let)

So cos C =

cos C = 0 ⇒ ∠C =

71)

for real roots

7 different equations

72) α8–3α7–15α6 = 0
β8–3β7–15β6 = 0
+_____________________
f(8) – 3f(7) – 15f(6) = 0
f(8) – 3f(7) = 15f(6)
f(8) – 3f(7) + f(16)

73) f(θ) =
∴ f(θ)max =

74)

=4

75)