12-07-2026

1001CJA101017260006 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) If α & β are roots of equation x2 – 2x – 7 = 0 and Sr = , then is equal to

(A) 1

(B)

(C)

(D)

2) If , and
then at (a > 0), a ≠ 1
is equal to ____

(A) 4
(B) 16
(C) 17
(D) 10

3) The least value of ∀x∈ is equal to

(A)

(B)

(C)

(D) 1

4) If 2cos2(π + x) + 3sin(3π + x) = 0, then the value of x lying in the interval [0, 2π] can be

(A)

(B)

(C)
(D)

SECTION-I (ii)

1) Which of following number(s) is/are rationals -

(A)

(B) sin75° cos15°

(C) (sin15° + sin75°)(cos15° + cos75°)
(D) sin15°cos15°

2) If 0 ≤ x ≤ π and , then x can be

(A)

(B)

(C)

(D)

3) Let set , then cardinality of given set is

(A) 2022
(B) 2020
(C) 2018
(D) 2016

4) The odd positive numbers are written in the form of a triangle Identify the
correct statements -

Total number of elements from first row upto nth row are
(A)

(B) The middle term in 7th row is 49

(C) Sum of the terms in 10th row is 1000
(D) First term of 6th row is 31

SECTION-I (iii)
1)

List-I List-II

(P) Let x = , then x4 – 4x3 + 4x2 is equal to (1) 1

If tan1°tan2°tan3° ...... tan89° = x2 – 15, then 3|x| is equal

(Q) (2) 4
to

(R) (3) 11
is equal to

If the roots of quadratic equation are

(S) imaginary, then largest possible integral value of m (4) 12
is equal to

(5) 14
(A) P → 4;Q → 1;R → 2;S → 3
(B) P → 1;Q → 2;R → 4;S → 3
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 2;Q → 1;R → 4;S → 3

2)

List-I List-II

If a, b, c, d ∈ R+ and
(a + b + c + d)4 ≤ 256abcd,
(P) (1)
then the value of is

If x + 2y + 3z = 6 (x, y, z ∈ R+),
(Q) (2) 4
then maximum value of x2yz3 is

The first two terms of an infinite G.P. are

together equal to 5 and every term is 3 times the
(R) (3) 5
sum of all the terms that follow it, then product
of first 2 terms is

(S) (4) 2
The value of is

(5)

(A) P → 4;Q → 3;R → 1;S → 2

(B) P → 2;Q → 1;R → 3;S → 5
(C) P → 3;Q → 4;R → 1;S → 5
(D) P → 3;Q → 4;R → 2;S → 1

3)
 List-I List-II

(P) (1) 4
If , then equals

The number of integral solutions of

(Q) (2)
is

(R) If (3) 5
, then the value of x is

The value of

(S) is (4) 1

, then λ is

(5) Prime Number

(A) P → 1,5;Q → 1,2;R → 3;S → 4
(B) P → 1,4;Q → 3;R → 2;S → 1,2
(C) P → 2;Q → 1,4;R → 4,5;S → 3
(D) P → 4;Q → 1;R → 2;S → 3,5

4) Let is a root of equation px2 + qx + r = 0 (p, q, r ∈ I where r is least positive integer) and

'm' be the maximum value of, then

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) The value of p is (1) –1

(Q) The value of (p + q) is (2) 0

(R) The value of (q + 49m) is (3) 1

(S) The value 7m is (4) 8

(5) 6
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 2;Q → 4;R → 1;S → 3
(C) P → 4;Q → 2;R → 1;S → 3
(D) P → 4;Q → 2;R → 3;S → 1

SECTION-II

1) The complete range of k for which the equation x4 – 2kx2 + x + k2 – k = 0 has all real solutions is

where m and n are relatively prime numbers. Then m + n is equal to

2) The least positive integral value of k for which the equation e2x + (1 – 2k)ex + k2 – 1 = 0 does not
have any real solution, is (where e is Napier's constant)

3) If log2(log3(log4a)) = log3(log4(log2b)) = log4(log2(log3c)) = 0 and x2 + x – 1 = a + b + c, then largest

possible value of x is

4) The value of (1 + tan1°) (1 + tan7°) (1 + tan38°) (1 + tan44°) is equal to

PART-2 : PHYSICS

SECTION-I (i)

1) A block of mass m is placed at rest on a rough inclined plane of angle θ. If coefficient of friction
between the block and the inclined plane is μ, then the total force exerted by the inclined plane on
the block is :-

(A) mg
(B) μmg cosθ
(C) mg sinθ
(D) μmg tanθ

2) The magnitude of vectors , and in the given figure are equal. The direction of

with x-axis will be :-

(A)

(B)

(C)

(D)
3) Time taken by the projectile to reach from A to B is t. Then the distance AB is equal to :-

(A)

(B)

(C) ut
(D) 2 ut

4) Three fundamental physical constants are Planck’s constant Kg-m2/s, the

gravitational constant G = 6.67 × 10–11 m3/Kg-s2 and the speed of light C = 3 × 108 m/s. These
constants can be combined to yield quantity with dimensions of length. This length is called Planck’s
length. Value of Planck’s length is :-

(A) 1.6 × 10–30 m

(B) 1.6 × 10–35 m
(C) 1.6 × 10–40 m
(D) 1.6 × 10–46 m

SECTION-I (ii)

1) In a situation, a board is moving with a constant velocity v with respect to earth, while a man A
and man B are running with a velocity 2v with respect to earth and both men are running from the
opposite ends of the board at the same time, as shown. Length of the board is L. If they meet after

time T, then

Value of T is
(A)

Value of T is
(B)

(C) Displacement of man B with respect to board in time T is 3L/4

(D) Displacement of man A with respect to board in time T is L/4

2) A and B are two point on a same vertical line. A is 20 m above ground while B is 40 m above
ground. Two small balls are released from rest, one from A and B each at t = 0. Neglect air
resistance. Balls come to rest after collisions. Choose the correct option(s)

(A) acceleration of A relative to B is zero

(B) acceleration of A relative to B is 9.8 ms–2
(C) acceleration of A relative to B is zero is 0 sec sec
(D) acceleration of A relative to B is 9.8 ms–2 in 2 sec sec

3) Block A and B are connected by light string as shown in figure. All surface are frictionless then

which is the correct F.B.D. of block B and block A ?

(A)

(B)

(C)

(D)

4) Consider the system shown in figure. Surfaces between A & B and between wall and A are rough,
choose the incorrect statement for non zero value of F.

(A) Friction force on block A due to B will be in upward direction.

(B) Friction force on block A due to B will be in downward direction.
(C) On block A friction force due to both surfaces will act in upward direction.
(D) The system can not remain in equilibrium for any value of F.

SECTION-I (iii)

1) Consider the situations given in List-I for these situations, the directions of some vector physical
quantities is given in List-II. Match the proper directions of physical quantities from List-I to List-II

List-I List-II

A relaxed spring is attached to two blocks of mass m1 = 10 kg and m2 = 1kg

(P) forces F = 20 N and F = 10N are applied as shown. A few moments after the start of system. The (1) +x
1 2
direction of spring force on m1

(Q) (2) –x
The rough planck is accelerated horizontally as shown. The direction of friction
on block just after maximum compression state of spring

(R) (3) +y

Assume ideal pulley and ideal string, we are applying an external force F =
mg/2 on block A as shown. The direction of acceleration of A.

(S) (4) –y

All spring and string are ideal and initially system is at rest in equilibrium. Now, if we
cut spring S2, block B will have instantaneous acceleration in which direction (assume block B is very
small and neglect its rotation)
(5) None
(A) P → 1;Q → 4;R → 3;S → 3
(B) P → 2;Q → 2;R → 4;S → 1
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 1;Q → 2;R → 3;S → 4

2) List-I contains different situations of trolley moving on a straight horizontal road and List-II
contains the direction of total contact force on the block (Assume that there is no slipping between
block and trolley)

List-I List-II

(P) (1)

Trolley at rest

(Q) (2)

Trolley moving with constant velocity

(R) (3)

(S) (4)

(5)
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 2;Q → 2;R → 1;S → 3
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 1;Q → 2;R → 3;S → 4

3) An object is moving in a straight line. The velocity-time graph of the object is shown below. List-I
gives information about the state of motion of object. List-II gives the name of the segment.
 List–I List–II

(P) The object is motionless in (1) Segment e

(Q) The object is moving with constant velocity in (2) Segment b

(R) The object’s speed is increasing at a decreasing rate in (3) Segment c

(S) The object is travelling in north with constant acceleration in north in (4) Segment f

(5) None
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 1;Q → 2;R → 4;S → 3
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 4;Q → 3;R → 1;S → 2

4) A particle is projected from the point B on an incline plane at an angle of 37° from horizontal as
shown in figure. If initial speed of particle is 20 m/s in horizontal direction then match the list-I with

list-II.

List-I List-II

Time when particle hits the incline plane is

(P) (1) 30
t then the value of "5t"

(Q) Range of the projectile (in m) is (2) 4

(R) Horizontal distance AC (in m) is (3) 15

Magnitude of vertical component of velocity of

(S) the particle (in m/s) when it hit the incline (4) 75
plane is nearly

(5) None
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 4;Q → 3;R → 1;S → 2
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 2;Q → 1;R → 4;S → 3
 SECTION-II

1) A swimmer can swim in still water with a speed of m/s. While crossing a river his speed is 3
m/s with respect to ground. If he crosses the river in the shortest possible time, what is the speed of
flow of water (in m/s) ?

2) Three blocks A, B, and C, whose masses are 9 kg, 9 kg and 18 kg respectively as shown in the
figure, are released from rest. The co-efficient of friction between block A and surface-2 is 0.5 and
the co-efficient of friction between block B and surface-1 is also 0.5. The acceleration of block C just

after release is (m/s2). All strings and pulleys are ideal. Value of n is :-

3) When you walk in rain at 75 cm/s, you have to hold your umbrella vertically and when you double
your speed in the same direction, you have to hold your umbrella at 53° above the horizontal. What
is the speed of rain (in cm/s)?

4) A block of mass 2 kg is placed on a cart moving with acceleration 4 m/s2. A balloon is rising up
with acceleration 3 m/s2 as shown. If magnitude of pseudo force exerted on block for the study of the
motion of block from the frame of balloon is 2x (in N) then find the value of x.

PART-3 : CHEMISTRY

SECTION-I (i)

1)

The number of moles of C and D produced on mixing 5 moles of A and 7 moles of B are respectively :

(3A + 5B 7C + 9D)
(A) 9 moles and 11 moles
(B) 11.66 moles and 15 moles
(C) 9.8 moles and 12.6 moles
(D) 1 moles and 13 moles

2) Which of the following statement is incorrect -

(A) Para-nitrophenol has higher enthalpy of vaporization than ortho-nitrophenol

(B) Orthohydroxy benzaldehyde has higher B.P. than para hydroxy benzaldehyde
(C) In chloral hydrate intra molecular hydrogen bonding is present.
(D) H2O has more boiling point than HF

3) Which of the following represent correct order for atomic or ionic radius
(i) Co = Ni < Cu < Zn (ii) Sc < Y = La
(iii) Ti < Zr = Hf (iv) V < Nb > Ta
(v) Mg < Na < K < Rb

(A) (i), (ii), (iii)

(B) (i), (iii), (iv)
(C) (i), (ii), (iv)
(D) (i), (iii), (v)

4) Find out number of different functional groups present in given compound.

(A) 3
(B) 4
(C) 5
(D) 6

SECTION-I (ii)

1) If 24 g of Carbon is mixed with 96 g of O2(g) and is allowed to burn to produce CO2 gas as only
product , then choose the correct option(s) :

(A) Oxygen is the limiting reagent.

(B) Volume of CO2 gas produced at 0°C and 1 atm is 44.8 L.
(C) Unreacted O2 is 1 mol.
(D) Volume of unreacted O2 at 0°C and 4 atm is 11.2 L.

2) Caro's acid (H2SO5) has –

(A) sp3 hybridised sulphur atom is present in its structure

(B) sp hybridised oxygen atom is present in its structure
(C) pπ-dπ bonds are present in its structure
(D) Peroxy linkage is present in its structure

3) Select correct orders for corresponding property as indicated in bracket for the following :

(A) NH3 > BiH3 > SbH3 > AsH3 > PH3 (Boiling point)
(B) H2O > H2Te > H2Se > H2S (Boiling point)
(C) B > Tℓ > Ga > Aℓ > In (I.E.1)
(D) S > O > Se > Te (E.A.)

4) Which of the following is/are correct about given compound ?

(A) It contains eight sp2 hybridized carbon atoms

(B) It contains one 4º carbon
(C) Its degree of unsaturation is same as that of benzene
(D) It contains four hydrogen atoms

SECTION-I (iii)

1) Match the List

List-I
List-II
(No. of moles of )

(P) Oxygen atom in 0.5 mol Ca3(PO4)2 (1) 8

(Q) Carbon atom in 113.5 lit. CH4 at STP. (2) 4

(R) Sulphur in 192 gm of SO2 (3) 5

(S) ‘Cl’ in 4 mole of Cl2O (4) 3

(5) 2
(A) P → 2;Q → 3;R → 4;S → 1
(B) P → 5;Q → 2;R → 3;S → 4
(C) P → 2;Q → 3;R → 4;S → 5
(D) P → 4;Q → 1;R → 3;S → 5

2) Match the following column :

List-I List-II

(P) 19.0 g N2O3 (1)

Number of N atoms in the sample =

(Q) 15.0 g NO (2) Number of O atoms in the sample = NA

 (R) 22.0 g N2O (3)
Number of O atoms in the sample =

(S) 23.0 g NO2 (4)

Number of O atoms in the sample =

(5)
Number of total atoms in the sample =
(A) P → 1, 4;Q → 1, 3;R → 3, 5;S → 1, 2, 5
(B) P → 1, 4;Q → 1, 3;R → 2, 5;S → 1, 2, 5
(C) P → 1, 5;Q → 1, 3;R → 3, 5;S → 1, 2, 5
(D) P → 1, 4;Q → 1, 2;R → 3, 5;S → 1, 2, 5

3)

Match the list:

List- I List- II
Oxy acid Name of oxyacid

(P) H4P2O7 (1) Pyrosulphuric acid

(Q) H2S2O8 (2) Peroxydiphosphoric acid

(R) H2SO5 (3) Caro's acid

(S) H2S2O7 (4) Pyrophosphoric acid

(5) Marshall's acid

(A) P → 5;Q → 4;R → 3;S → 2
(B) P → 4;Q → 5;R → 3;S → 1
(C) P → 4;Q → 1;R → 3;S → 2
(D) P → 4;Q → 2;R → 3;S → 1

4) Match the following:

List–I List–II

Same number of unpaired

(P) (1) Na+, Mg2+, F¯
electrons are present in (excluding zero)

Same number of electrons

(Q) (2) F¯, Mg, O2–
in s & p subshells.

Same number of electrons

(R) (3) Mg, Ne, O2–
with the ℓ = 1

Same number of total

(S) (4) Li, Na, K
electrons

(5) F, Cl , Br
(A) P → 1,2,5;Q → 3,4;R → 1;S → 4
(B) P → 4,2;Q → 1,3;R → 2,3;S → 1,4,5
(C) P → 4,5;Q → 1;R → 1,2,3;S → 1
(D) P → 3,5;Q → 1,2;R → 3,4;S → 1,3,4

SECTION-II

1) Find total number of oxy acid(s) in which '-ic' suffix is used in their name.
H2SO3 , H2SO4 , H2SO5 , H2S2O3 , H2S2O4 , H2S2O5 , H2S2O6 , H2S2O7 , H2S2O8

2) An element 'M' consists of three isotopes M20, M22 & M24. If percentage abundance of M20 is 20% &
average atomic mass of M is 22.73 amu then percentage abundance of M22 will be :

3) Ammonia is prepared with 90% yield through the reaction N2(g) + 3H2(g) → 2NH3(g). If 28 g
N2 and 8 g H2 is allowed to react to react, then mass of NH3 obtained in gm is :

4)

Double bond equivalent (DBE) of the following compound is ?

 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. B C C A

SECTION-I (ii)

Q. 5 6 7 8
A. A,C,D A,B,C,D B A,B,C,D

SECTION-I (iii)

Q. 9 10 11 12
A. C D D C

SECTION-II

Q. 13 14 15 16
A. 7.00 2.00 9.00 4.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 17 18 19 20
A. A A A B

SECTION-I (ii)

Q. 21 22 23 24
A. A,C,D C,D A,C A,C,D

SECTION-I (iii)

Q. 25 26 27 28
A. D B B C

SECTION-II

Q. 29 30 31 32
A. 2.00 6.50 125.00 3.00

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 33 34 35 36
A. C B D B

SECTION-I (ii)

Q. 37 38 39 40
A. B,C A,C,D B,C A,B,C

SECTION-I (iii)

Q. 41 42 43 44
A. A A B C

SECTION-II

Q. 45 46 47 48
A. 6.00 23.50 30.60 7.00
 SOLUTIONS

PART-1 : MATHEMATICS

1)
also α2 – 2α – 7 = 0 ⇒ (α – 1)2 = 8 & (β – 1)2 = 8

2)

3)

Least value is

4) 2cos2x – 3sinx = 0
2(1 – sin2x) – 3sinx = 0

5) Put the value and check option

6) Let . Then

Now,
⇒ y = 3, or y = 27 ⇒
⇒ ⇒ 4sin2x = 1 or 4sin2x = 3.

⇒ or ⇒

7) complementary counting
Let a,b ∈ {1,2,......2022} such that
 ⇒ a2 b2 – a2b + 2a2 – 2b2 + 2b – 4 = a2b2 – ab2 + 2b2 – 2a2 + 2a – 4
⇒ ab2 – a2b + 4a2 – 4b2 + 2b – 2a = 0
⇒ (b – a) (ab – 4a – 4b – 2) = 0
⇒ (a – 4) (b – 4) = 14

a–4 b–4

1 14
2 7
–1 –14
–2 –7

(6,11)
(3,0)×
+ (2,–3)×
Answer = 2022 – 4 + 2
= 2020

8) (A) Total number of elements = 1 + 2 + 3 +... + n =

(B) Middle term in each row is square of the row number
(C) Sum of terms in nth row = n3

9) (P)
square
x4 – 4x2 + 4x2 = 4
(Q) x2 – 15 = 1 ⇒ |x| = 4
(R) (1 + tanθ) (1 + tan(45° – θ)) = 2
(S) m – 12 < 0 ⇒ m < 12 ⇒ value is 11.

10) (P) AM ≥ GM

⇒ (a + b + c + d)4 ≥ 256 abcd

But (a + b + c + d)4 ≤ 256 abcd (given)
⇒a=b=c=d
(Q) AM ≥ GM

⇒ 2 ≥ x2yz3
(R) a + ar = 5 = a(1 + r)

also a = 3 (ar + ar2 ... ∞) =

⇒r= &a=4
(S) Let
11) (P) 32sin5A sinA = 16(cos4A – cos6A)
= 16(2 cos22A – 1) – (4 cos32A – 3cos2A)
= 11
(Q) 3x + 6 > x2 + 2
⇒ x2 – 3x – 4 < 0
x ∈ (–1, 4)
x = 0,1,2,3

(R)

(S) Clearly

12)

∴ second root =
quadratic equation is

x2 – x + = 0 ⇒ 8x2 – 8x + 1 = 0
∴ p = 8, q = – 8, r = 1

and

∴ ymax =

13) k2 – (2x2 + 1)k + x4 + x = 0

⇒ 2k = (2x2 + 1) ± (2x – 1)

+sign

–sign

⇒ and
 14) e2x + (1 – 2k)ex + k2 – 1 = 0
ex = t > 0
t2 + (1 – 2k)t + k2 – 1 = 0
Either D < 0
(1 – 2k)2 – 4(k2 – 1) < 0

or both the roots are ≤ 0

⇒ Least integral value of k = 2

15) log2(log3(log4a)) = 0 ⇒ a = 64
& b = 16, c = 9
x2 + x – 1 = 89
⇒ x = –10,9

16) (1 + tanθ) (1 + tan(45° – θ))

(∵ tan45° = 1)
=2

PART-2 : PHYSICS

17) f = mg sinθ, N = mg cosθ

R=
18)
Let magnitude be equal to λ.

∴
∴ Angle with x-axis

19) Question Explanation : It is asking about the range AB on inclined plane if the time of
flight is 't'.
Concept : Projective motion
Solution :

(a) Horizontal component of velocity, uH = ucos60° =

AC = uH × t =

and AB = AC sec 30° =

Final Answer:

20)

Correct Answer is (B)

 21)

Explanation Question: In a situation, a board is moving with a constant velocity v with

respect to earth, while a man A and man B are running with a velocity 2v with respect to earth
and both men are running from the opposite ends of the board at the same time. We have to
find the time when both the person meet
Concept: This question is based on relative motion
Solution:

In the frame of board : vAB = 4v

Final Answer : The correct option is (1), (3) & (4)

22)

Correct Answer is (C,D)

23)

Correct Answer is (A,C)

24)

Correct Answer is (A,C,D)

25)

(P)

Spring will be compressed

(Q) At maximum compression, spring force is more than ma
(R)
For block A:
2T – (F + mg) = m(a)
For block B :
mg – T = m(2a)
Solving the two equation, we get

, positive sign represents that direction is upwards.

(S) Block B of mass 3m is heavier, hence, spring S2, S3 will be compressed.

26) Question Explanation:

The problem asks to determine the direction of the total contact force acting on a block placed
on a trolley in different scenarios, assuming no slipping occurs between the block and the
trolley.
Concept:
This question is based on friction, contact force.
Solution:
Fnet =

(P) ⇒
Trolley at rest

(Q) ⇒
Trolley moving with constant velocity

(R) ⇒
(S) ⇒

27)

P → motionless means velocity zero & segment 'e' has zero velocity
Q → constant velocity means slop of (velocity-time)graph is zero (acceleration=0)
which is in segment 'b'
R → slop of (V–t) graph gives acceleration & slop of segment 'f' decreasing with time. So, Rate
of increasing of speed is decreasing.

S→
V & a are in same direction & a = const.
so velocity will increase with const.
Rate i.e. slop of v-t curve +ve
segment 'e' has +ve slop

28)
(P) Vy = uy – g cos 37° × t'

⇒ 0= – 10 × ×t

⇒ t' = = 5t = 15s
t = 2t' = 3 sec.

29)
vr = 2 m/s

30)
Case I : Net driving force on the
system = 180 N
Net limiting friction on the system = 180 N
Hence all blocks will not move
Case II : Let block A is at rest and
block B moves
2mg – T = 2ma1 ........(i)

2T – = ma2 =
⇒ 4T – mg = ma1 ........(ii)
Equation (i) × 4 + Equation (ii), we have

7mg = 9ma1 ⇒ a1 =

T = 2mg – 2ma1 = 2 × 9 ×

31)
Appear falling vertically
v sinθ –75 = 0
v sinθ = 75

32)

Question Explanation : Calculate the value of x, given that the magnitude of the pseudo
force on a 2 kg block, observed from a balloon accelerating upwards at 3 m/s², is 2x.
Concept: Pseudo Force Principle: Magnitude is equal to mass times the acceleration of the
reference frame (F = ma).
Solution:
We are analyzing the block from the frame of reference of the balloon.
Given:
Mass of block (m) = 2 kg
Acceleration of the balloon (frame) = 3 m/s² (upwards)
The pseudo force acts on the block because the observer (balloon) is accelerating. The
magnitude of the pseudo force depends only on the mass of the object and the acceleration of
the observer's frame.
F_pseudo = m × a_frame
Substituting the values:
F_pseudo = 2 kg × 3 m/s²
F_pseudo = 6 N
 According to the problem, the magnitude of this force is given as 2x.
2x = 6
x=6/2
x=3
Final Answer: 3

PART-3 : CHEMISTRY

33)

Question Explanation: Moles of products formed considering a limiting reagent.

Concept: Limiting Reagent.
Solution: Identify the limiting reagent by comparing the available moles of reactants to their
stoichiometric requirements. Use the limiting reagent to determine product amounts.

(C) 3A + 5B 7C + 9D

= 1.66 1.4
So B is LR
3A + 5B 7C + 9D
5 moles 7 9

7 moles
= 9.8 = 12.6
Final Answer: 9.8 and 12.6

34) Question Explanation: Identify the incorrect statement regarding physical properties
and hydrogen bonding.
Concept: Intermolecular and Intramolecular Hydrogen Bonding.
Solution: Physical properties like boiling point (B.P.) depend on the strength of
intermolecular forces.
1. Para-nitrophenol has intermolecular H-bonding, leading to a higher B.P. and enthalpy of
vaporization than ortho-nitrophenol (intramolecular H-bonding). (Correct).
2. Para-hydroxybenzaldehyde has intermolecular H-bonding, so it has a higher B.P. than
ortho-hydroxybenzaldehyde (intramolecular H-bonding). Statement 2 claims the opposite.
(Incorrect).
3. Chloral hydrate is stabilized by intramolecular H-bonding between OH groups and Cl atoms.
(Correct).
4. H2​O can form 4 H-bonds per molecule, while HF forms only 2, giving H2​O a higher B.P.
(Correct).
Final Answer: Option (B)

35) Question Explanation :

Select correct orders of atomic/ionic radii
Concept:
Atomic radius trends: decreases across a period, increases down a group; lanthanide
contraction affects some 5d elements
Solution:
• (i) Co = Ni < Cu < Zn → Correct, radius decreases across period 4, then slight increase for
Zn → valid
• (ii) Sc < Y = La → Incorrect, Y and La are not similar because lanthanide contraction is not
effective
• (iii) Ti < Zr = Hf → Correct, Hf radius ≈ Zr (lanthanide contraction)
• (iv) V < Nb > Ta → Incorrect, radius increases down the group → V < Nb < Ta
• (v) Mg < Na < K < Rb
Final Answer: Option (D)

36)

Question Explanation:
The question asks for the number of different (unique) functional groups present in the given
organic structure.

Concept:
This question is based on Functional Group Identification, Ester, Nitrile, Ether, Aldehyde

Solution:
On examining the structure:

A. Ester (–COOR): Present twice, but counted as one type

B. Nitrile (–C≡N): One cyano group present

C. Ether (–O–): One ether linkage present

D. Aldehyde (–CHO): One terminal aldehyde group present

Only different types are counted, not their number of occurrences.

Final Answer: Option (B)

37)

Question Explanation:
Analyzing a combustion reaction to identify the limiting reagent and products.
Concept:
Stoichiometry and Limiting Reagent
Solution:
C + O2 CO2
moles 2 3
C is limiting reagent
Moles of CO2 produced = moles of C = 2
∴ Volume of CO2 = 2 × 22.4 = 44.8 L

Final answer: option (B, C)

38) Explain Question:

About the structure of H2SO5.
Concept:
This question is based on oxystructure.

S. No. = 4
sp3 sulphur atom
π bond involved is
pπ – dπ
O – O bond is peroxy linkage.

Final Answer:
option (A), (C), (D).

39) Explain Question:

Identify the correct trends in chemical properties for p-block hydrides.
Concept:
Periodic trends in Boiling Point, Acidity, and Basicity.
Solution:
• Boiling Point (Option 1): Incorrect. The correct order is BiH3 > SbH3 > NH3 > AsH3 > PH3.
While NH3 has H-bonding, the high molecular mass of BiH3 and SbH3 creates stronger Van der
Waals forces.
Boiling Point (Option 2): Correct. H2O has the highest boiling point due to strong H-bonding.
For others, boiling point increases with molecular mass (H2Te > H2Se > H2S).
IE1 : B > Tl > Ga > Al > In
EA : S > Se > Te > O

40)

The correct answer is option (A), (B), (C)

41) Question Explanation: Matching substances with their respective molar counts.
Concept: Conversion between Mass, Volume, and Moles
Solution:
Calculate the number of moles for each atom specified by identifying the total moles of the
compound and multiplying by the atom's subscript.
(P) Ca3(PO4)2 : 1 mole of Ca3 (PO4)2 constitutes 8 moles of oxygen atoms.
So in 0.5 mole of Ca3(PO4)2 → 4 mole of oxygen atoms → (2)
(Q) Carbon atom in 113.5 lit CH4 at STP.

Mole of CH4 = = 5 mole.

1 mole CH4 → 1 mole of Carbon atom → (3)
5 mole CH4 → 5 mole of Carbon atoms

(R) = = 3 ; number of moles of Sulphur = 3 → (4)

(S) 4 mole of Cl2O → 8 mole of 'Cl' → (1)
Final Answer: Option (A)

42) (P) moles of N2O3 =

so, number of N atoms = 2 × 0.25 × 6.023 × 1023 = 3.01 × 1023
atoms of oxygen = 4.52 × 1023
total atoms = 0.25 × 5 × 6.023 × 1023

(Q) moles of NO =
number of N atoms = 3.01 × 1023
atoms of oxygen = 3.01 × 1023

(R) moles of N2O =

number of N atoms = 6.02 × 1023
number of O atoms = 3.01 × 1023

(S) moles of NO2 =

23
number of N atoms = 3.01×10
number of O atoms = 6.02 × 1023

43) Explain question : Questio cesthing to watch moleculur formula of List-I with their name
in List -II
Concept: This question is based on oxy acid
Solution :-
(p) 2H3PO4 H4P2O7 pyrophosphoric acid.

(q)
Marshall's acid
(R) H2SO5
 caro's acid
(S) 2H2SO4 H2S2O7

pyrosulphuric acid

Final answer :- Option (B)

44) Question Explanation: Identify correct matches with given properties.

Concept: Apply concept of quantum no. and filling of electrons.
Solution:
• (P) Unpaired Electrons : Set (4) (Li, Na, K - ns1) and (5) (F, Cl, Br - np5) both have exactly 1
unpaired electron.
• (Q) Same electron in s and p subshells : Set (1) contains isoelectronic ions (Na+, Mg2+, F–).
They share the identical configuration 1s2 2s2 2p6, meaning they all have equal s (4) and p (6)
counts relative to one another.
• (R) Same l = 1 (p) electrons : Sets (1), (2) and (3) all revolve around the stable sp6 core.
Every species listed in these options has exactly options has exactly 6 p-electrons.
• (S) Same Total Electrons : Set (1) is the only isoelectronic set (all have 10 electrons.
Final Answer: Option (C)

45)

Question Explanation: Counting oxoacids named with the '-ic' suffix.

Concept: Nomenclature of Oxoacids.

Solution: Acids with sulfur in higher oxidation states or specific structures use 'ic', while
lower states use '-ous'.

Calculation: * '-ic' acids: H2SO4 (Sulphuric), H2SO5 (Peroxomonosulphuric),

H2S2O6 (Dithionic), H2S2O7 (Pyrosulphuric), H2S2O8 (Peroxodisulphuric).

A. Thio acid: H2S2O3 (Thiosulphuric).

B. '-ous' acids: H2SO3 (Sulphurous), H2S2O4 (Dithionous), H2S2O5 (Pyrosulphurous).

Final Answer: 6

46)
x = 23.50
47) + 3H2 2NH3
1 mol 4 mol

– 1 mol mol
mass = 1.8 × 17 = 30.60 gm

48)

Question Explanation: Calculating the Double Bond Equivalent (DBE).

Concept: This question is based on Degree of Unsaturation.

Solution: DBE is the sum of rings and π-bonds.

Calculation:

The structure contains 5 fused rings (5 DBE) and two π-bonds, one C=O and one C=C bond
(2 DBE). Total DBE = 5 + 2 = 7.
Final Answer: 7.00