08-06-2025

5301CJA101001250004 JM

PHYSICS

SECTION-I

1)

Consider 2 vectors and . If we define vector component of along as and

vector component of perpendicular to as where ‘^’ represent unit vector &

‘.’ represent dot product then answer the following questions.

A. Vector component of perpendicular to is given by :

(A)
(B)
(C)
(D)

2)

Consider 2 vectors and . If we define vector component of along as and

vector component of perpendicular to as where ‘^’ represent unit vector &

‘.’ represent dot product then answer the following questions.

If and vector component of along is then which of the following cannot

be ?

(A)

(B)

(C)

(D)

3)

Consider East as +ve x-axis, North as +ve y-axis. A girl walks 10 m East first time then 10 m in a
direction 30° West of North for the 2nd time & then third time in unknown direction and magnitude,
so as to return to her initial position. What is her third displacement vector :-
(A)

(B)

(C)
(D) she cannot return

4) A particle moves on x-axis with a velocity which depends on time as per equation v = t2 – 8t + 15
(m/s) where time t is in seconds. Match the List.

List–I List–II

(P) At t = 4s (1) acceleration is in positive direction.

(Q) At t = 2s (2) acceleration is in negative direction.

(R) At t = 6 s (3) acceleration is zero.

(S) At t = 5s (4) particle moves in positive direction.

(5) Particle moves in negative direction.

(A) P 3,5, Q 2,4, R 1, 4, S 1
(B) P 3,5, Q 2,5, R 1, 2, S 1
(C) P 1,4, Q 2, 4, R 1, 2, S 3
(D) P 2,4, Q 1, 5, R 2,4, S 2

5) After firing, a bullet is found to move at an angle of 37º to horizontal. Its acceleration is 10 m/s2
downwards. Find the component of acceleration in the direction of the velocity.

(A) – 6 m/s2
(B) – 4 m/s2
(C) – 8 m/s2
(D) – 5 m/s2

6)

In case of ground to ground projectile, maximum height achieved by particle is 10m. Then

(A) Range of the projectile must be greater than 10m.

(B) Range of the projectile must be greater than 20m.
(C) Time of flight must be greater than 2 sec.
(D) Time of flight must be equal to 2 sec.

7) An object is thrown horizontally from a tower H meter high with a velocity of m/s. Its speed
on striking the ground will be :

(A)
(B)
(C)
(D)

8) A ball is thrown at angle α(90° > α > θ) on inclined plane as shown in figure then the minimum

speed of the ball during the motion is :

(A) u cos α
(B) u cos θ
(C) u cos (α – θ)
(D) Zero

9) A gun is mounted in a stationary battleship which is used to hit two different boats A and B. The
initial speed of both the shots is the same. Choose the correct statement.

(A) Both shots have same time of flight and same final speed
(B) Both shots have same time of flight but different final speeds
(C) Both shots have different time of flight but same final speed
(D) Both shots have different time of flight and different final speed

10) A ball is thrown vertically down with velocity of 5m/s. With what velocity should another ball be
thrown down after 2 seconds so that it can hit the 1st ball in 2 seconds

(A) 40 m/s
(B) 55 m/s
(C) 15 m/s
(D) 25 m/s

11) A man can swim with a certain speed, in still water to cross a river to a point directly opposite to
the starting point in time t0. When the river flows, he crosses the river directly along the same path
in a time t1. If ‘d’ be the river width, Then the velocity of water current is :
(A)

(B)

(C)

(D)

12) An object initially at origin starts from rest and moves along the x axis with a constant
acceleration of 4m/s2. Its average velocity as it goes from
x = 2m to x = 8m is :

(A) 1m/s
(B) 2m/s
(C) 3m/s
(D) 6m/s

13) Two trains, which are moving along different tracks in opposite directions towards each other,
are put on the same track by mistake. Their drivers, on noticing the mistake, start slowing down the
trains when the trains are 300 m apart. Graphs given below show their velocities as function of time
as the trains slow down. The separation between the trains after both have stopped, is :

(A) 120 m
(B) 280 m
(C) 60 m
(D) 20 m

14) A jet plane flies horizontally at a height 10 m from the gun at a speed 5 m/s. An anti air craft gun
fire a shell at the plane when it is vertically above the gun. Then minimum muzzle speed required to
hit the plane is :-

(A) 15 m/s
(B) m/s
(C) 20 m/s
(D) m/s

15) A cyclist moves across a bridge and a boat is rowed in a river as shown in figure. Both the cyclist
and boat start at same instant from same point. Both reach point A across the river simultaneously.
A person on a floating raft in river sees both of them moving 127° with flow and crossing 40 m wide
river in 10 second. Mark the incorrect statement(s) :

(A) River flow is 4 m/s

(B) Speed of cyclist is 4 m/s
(C) Speed of boat relative to water is 5 m/s
(D) Speed of raft is 3 m/s

16) A little masked girl is holding a helium-filled balloon with a string while riding in a closed
elevator going down a very tall building at constant speed. There is vacuum in elevator. Suddenly
the elevator cable snaps, sending the elevator into free fall. Being shocked, the girl lets go of the
string. She is even more surprised to see :-

(A) the balloon rising

(B) the balloon floating downward
(C) the balloon remaining stationary
(D) the balloon bouncing slowly between the floor and the ceiling

17) Three airplanes A, B and C each release an object from the same altitude and with the same
initial speed v0 with respect to the ground. At the moment when object is released, A is flying
horizontally, B is flying upward at an angle θ1 = 30° with respect to the horizontal, and C is flying at
the angle θ2 = 60° downward with respect to the horizontal. Assuming the ground to be horizontal
and neglecting any aerodynamical effect, the speeds v at which the three objects will hit the ground
satisfy

(A) vA = vB < vC
(B) vA > vB = vC
(C) vA = vB = vC
(D) vA < vB < vC

18) The velocity of projection of a projectile is . The horizontal range of the projectile
is :

(A) 4.9 m
(B) 9.6 m
(C) 19.6 m
(D) 14 m

19) The point from where a ball is projected is taken as the origin of the coordinate axis. The x and y
components of its displacement are given by x = 6t and y = 8t – 5t2. What is the velocity of
projection ?
(A) 6 m/s
(B) 8 m/s
(C) 10 m/s
(D) 14 m/s

20) If and then is equal to

(A)

(B)
(C) 1
(D) 2

SECTION-II

1) If the resultant of two forces of magnitudes P and Q acting at a point at an angle of 60° is Q,
then P / Q is

2) The resultant of two forces 3F and 2F is R. If the first force is doubled then the resultant is also
doubled. What is the angle between two forces (in degree) ?

3)

A bird starts from (1, 2, 0) and flies along with 9 m/s for 3 sec. Then it reverses its
direction and flies with 6 m/s for 4 sec. If final position of the bird is (x, y, z) then find value of x + y
+ z.

4)

If and are two non-collinear unit vectors and if , then the value of .

is . Find the value of x.

5) A projectile at any instant during its flight has velocity 5 m/s at 30° above the horizontal. How
long after this instant, will it be moving at right angle to the given direction?

CHEMISTRY

SECTION-I

1) Bond formation is :
(A) always exothermic
(B) always endothermic
(C) neither exothermic nor endothermic
(D) sometimes exothermic and sometimes endothermic

2) Which of the following compound does not show expanded octet

(A) PCl5
(B) SiF4
(C) ClF3
(D) IF7

3) Find the number of sigma bond in melamine (given as)

(A) 9
(B) 12
(C) 15
(D) 18

4) What is the nature of chemical bonding between Cs and F ?

(A) Ionic
(B) Covalent
(C) Coordinate
(D) Metallic

5) An element 'A' belongs to III period and having 6 electrons in its valence shell. Consider the
following statements for the given element and choose the correct option :
(I) It does not show variable valencies
(II) It can make AF2 type compounds
(Here : F → Fluorine)
(III) It can make hypervalent compounds.

(A) I, II, III

(B) I, II
(C) I, III
(D) II, III

6) The maximum covalency is equal to :-

(A) Number of unpaired p-electrons
(B) Number of paired d-electrons
(C) Number of unpaired s and p-electrons
(D) Total number of unpaired electron in ground/excited state

7) Values of Formal charge (F.C) on three oxygen atoms O(1), O(2) and O(3) respectively in O3

molecule will be

(A) 0, 0, 0
(B) +1, –1, 0
(C) –1, +1, 0
(D) –1, 0, +1

8) Which of the following overlapping is INCORRECT (assuming Y-axis is internuclear axis)?

(A) py + py → σ-bond
(B) dxy + dxy → π-bond
(C) dzx + dzx → σ-bond
(D) pz + pz → π-bond

9) Which of the following are isoelectronic and isostructural?

(A)
(B)
(C)
(D)

10) Which of the following has different hybridization than other :-

–
(A) I3
(B) XeO3
(C) SeCl4
–
(D) AsF4

11) The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be?

(A) – 2.55 eV
(B) – 5.1 eV
(C) – 10.2 eV
(D) + 2.55 eV
12) Which of the following is not correct :

(A) A σ-bond is weaker than π-bond

(B) A σ-bond is stronger than π-bond
(C) A double bond is stronger than a single bond
(D) a double bond is shorter than a single bond.

13) The correct order of ionic size of N3–, Na+, F–, Mg2+ and O2– is :

(A) Mg2+ > Na+ > F– > O2– < N3–

(B) N3– < F– > O2– > Na+ > Mg2+
(C) Mg2+ > Na+ > F– > O2– > N3–
(D) N3– > O2– > F– > Na+ > Mg2+

14)

Match the LIST-I with LIST-II

LIST-I LIST-II
(Classification of molecules based on octet rule) (Example)

A. Molecules obeying octet rule I. NO, NO2

B. Molecules with incomplete octet II. BCl3, AlCl3

Molecules with incomplete octet with

C. III. H2SO4, PCl5
odd electron

D. Molecules with expanded octet IV. CCl4, CO2

Choose the correct answer from the options given below:
(A) A-IV, B-I, C-III, D-II
(B) A-IV, B-II, C-I, D-III
(C) A-II, B-IV, C-III, D-I
(D) A-III, B-II, C-I, D-IV

15) IUPAC name of the element placed just after actinide series :-

(A) Unniltrium
(B) Unnilpentium
(C) Unnilquadium
(D) Ununbium

16) The process that is NOT endothermic in nature is

(A)
(B)
(C)

(D)
17) The shapes of PCl4+, PCl4– and AsCl5 are respectively.

(A) square planar, tetrahedral and see-saw

(B) tetrahedral, see-saw and trigonal bipyramidal
(C) tetrahedral, square planar and pentagonal bipyramidal
(D) trigonal bipyramidal, tetrahedral and square pyramidal

18) In the following compound ,

, the C3 – C4 bond is of the type :

(A) sp – sp2
(B) sp3 – sp3
(C) sp3 – sp
(D) sp2 – sp3

19) Which of the following lewis acid - lewis base interaction is NOT possible.

- 3-
(A) AlF3 + 3F → AlF6

(B) BeF2 + 4F– →

(C) PCl5 + Cl– →

(D) SiF4 + 2F– →

20) Identify the hyper valent compound.

(A) BCl3
(B) NOF3
(C) XeF6
(D)

SECTION-II

1) What is atomic number of element which has maximum electron affinity?

2) The number of chemical species among the following which can produce spin magnetic moment
greater than zero is _____.
Sc3+, V3+, Cr6+, Mn2+, Zn, Pd, Ag+, Cu2+, Hg, Cu+, Cu

3)

If inter nuclear axis is x-axis then total number of overlap which will form π-bond
2px + s, 2px + 2py, 2py + 2py, 3s + 2py, 3px + 3px

4) Maximum number of atoms in one plane in the given molecule C3H4 (allene).
5) What is the number of lone pairs on central atom of

MATHS

SECTION-I

1) If roots of the equation are equal, then

(A) 2b = a + c

(B)

(C)
(D) none of these

2) =

(A) 3
(B) 2
(C) 1
(D)

3) The maximum value of expression is

(A) 1
(B) 2
(C) 3
(D) 4

4) If the roots and of the equation such that = 1 then p =

(A) 4
(B) 5
(C) 7
(D) 8

5) If & have a common root then c =

(A) 1, 5
(B) 0, 6
(C) 3, 2
(D) 5, 10
6) If the graph of f(x) = ax2 + bx + c is following then which is correct?

(A) a < 0
(B) b2 – 4ac < 0
(C) c > 0
(D) b > 0

7) Find the set of value of a for which the roots of the equation are less than 3.

(A) a > 2
(B) a < 2
(C) 1 < a < 2
(D) 2 < a < 3

8) If are the roots of and , then find the values of a.

(A) a > 1
(B) a < 1
(C) a > 2
(D) a < 2

9) The value of a for which one roots of the quadratic

equation is twice as large as the other is

(A) -2/3
(B) 1/3
(C) -1/3
(D) 2/3

10) Let and be the roots of equation . If , for , then the value of

is equal to

(A) 3
(B) -3
(C) 6
(D) -6

11) The minimum value of the sum of the squares of the roots of is:
(A) 4
(B) 5
(C) 6
(D) 8

12) Let r1, r2, r3 be roots of equation , then the value of

is

(A) 5050
(B) -5050
(C) 5066
(D) -5068

13) If are the roots of the equation then find the value of

(A)

(B)

(C)

(D)

14)

For what values of a is the difference between the roots of the equation =0
equal to their product?

(A) 1
(B) 2
(C) 3
(D) 4

15) If is a root of the equation , where , find c.

(A) 4
(B) 5
(C) 1
(D) 2

16) Find the value of a for which one root of the equation is twice as
large as the other.

(A) 2
(B) -5
(C) 4
(D) -4

17) Find x such that

(A)
(B)
(C)
(D)

18) The roots of the quadratic equation are

(A) imaginary
(B) real, rational and unequal
(C) irrational roots
(D) none of these

19) The equation whose roots are the squares of the roots of the equation is -

(A)

(B)

(C)

(D)

20) The sum of all real values of x satisfying the

equation = 1 is

(A) 3
(B) –4
(C) 6
(D) 5

SECTION-II

1) If x be real then the minimum value of 40 – 12 x + x2 is

2) For all real values of x, the maximum value of the expression is-

3) If the roots of the equations x2 – bx + c = 0 be two consecutive integers, then b2 – 4c equals-

4) If the sum of two of the roots of x3 + px2 + qx + 5 = 0 is zero, then product (pq) equals

5) The sum of all real roots of the equation |x - 2|2 + |x - 2| - 2 = 0 is...

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D A A A C C C C A B D D A A C C B C A

SECTION-II

Q. 21 22 23 24 25
A. 2.00 120 8.00 2.00 1.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B C A D D C C A B B A D B C B B C B C

SECTION-II

Q. 46 47 48 49 50
A. 17 4.00 1.00 5.00 2.00

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A C C B D B D D A C B B B C D B C C A

SECTION-II

Q. 71 72 73 74 75
A. 4.00 1.00 1.00 5.00 4.00
 SOLUTIONS

PHYSICS

1)

Put the values of vectors in the formula given in passage, and check.

2)

Put the values of vectors in the formula given in passage, and check.

3)

4)

Ans: P 3,5, Q 2,4, R 1, 4, S 1

5)

Ans. – 6 m/s2

6)

Ans. Time of flight must be greater than 2 sec.

7)

8) Horizontal component of velocity at point of projection will be minimum velocity during

motion.

9)

Ans. Both shots have different time of flight but same final speed

10)

Let both hit below H height from point of projection

H=5×4+ ...(i)

H=v×2+ ...(ii)
⇒ v = 40m/s

11)

0
t =

t1 =
vr = vbr sin θ

vr =
12)

v12 = 0 + 2 × (4) × (2)

v1 = 4 m/s
v22 = 0 + 2 × (4) × (8)
v2 = 8 m/s

vavg =

13)

Final separation
= Initial separation – |Relative displacement|
= 300 – [(1/2) × 40 × 10 + (1/2) × 20 × 8]
= 20 m

14)
u2sin2θ = 200 .....(i)
u cos θ = 5
⇒ u2cos2θ = 25 .....(ii)
⇒ u = 15 m/s

15)

w.r.t. person on raft velocity of cyclist

tan 37 =

vR = 3 m/s

speed of cyclist =
speed of raft = vR = 3 m/s
vbR = 5 m/s

16) Free falling elevator, there is vacuum in elevator therefore net force on the balloon is
mballoong.

17)
Ans. vA = vB = vC

18)

19)

Ans. 10 m/s

20)

Ans.

21)

Ans. 2

22)

and

Divide eq. (2) by (1)

On squaring and cross multiplication

52 + 48 cos θ = 40 + 24 cos θ
24 cos θ = – 12

θ =120°

23) ,

24)

a1 = a2 = 1
and
 Now

25) Taking direction of projection as x-axis and writing 1st equation of motion.
vx = ux + axt with vx = 0, ux = 5 & ax = –5.

CHEMISTRY

26)

always exothermic

27)

Explanation:
To determine which compound does not show an expanded octet.

Concept:
SiF4 (Silicon Tetrafluoride): Silicon is in the third period, so it can theoretically have an
expanded octet. However, in SiF4, silicon forms four single bonds with fluorine atoms. This
uses all four of silicon's valence electrons (four from the 3s and 3p orbitals). Silicon has eight
electrons around it, fulfilling the octet rule without expanding it.

PCl5, ClF3, and IF7: Phosphorus in PCl5, chlorine in ClF3, and iodine in IF7 all have more than
eight electrons around them. They utilize their d orbitals to accommodate the extra electrons,
thus demonstrating expanded octets. PCl5 has 10 electrons around P, ClF3 has 10 electrons
around Cl, and IF7 has 14 electrons around I.

Hence, option (2) is correct.

28)
No of bonds = 15
No. of bonds = 3

29)

Ans. Ionic
30)

Ans. (II) It can make AF2 type compounds

(Here : F → Fluorine)
(III) It can make hypervalent compounds.

31)

Ans. Total number of unpaired electron in ground/excited state

32)
Ans : –1, +1, 0

33)

Conceptual

34)

Ans.

35)

XeO3

36)

Ans. – 5.1 eV

37) Refers to notes

38)

Ans. N3– > O2– > F– > Na+ > Mg2+

39)

Ans. A-IV, B-II, C-I, D-III

40) In f-block Actinide series is from atomic no. 90 to 103

IUPAC name of atomic no. (z) 104 is Unnilquadium that is element Rutherfordium (Rf)
41)

Ans.

42)

Ans. tetrahedral, see-saw and trigonal bipyramidal

43)

44)

BeF2 + 4F– →

45)

Hypervalent means (contain more than 8e–)

Correct answer C (XeF6)

46)

Ans. 17

47)

Ans. 4

48)

Ans. 1

49)

Ans. 5
 50)

MATHS

51)

Ans. 2b = a + c

52)

Ans. 3

53)

Ans. 3

54)

Ans. 7

55)

Ans. 0, 6

56)

Ans. b > 0

57)

Ans. a < 2

58)

Ans. a < 2

59)

Ans. 2/3
60)

Ans. 3

61)

Ans. 6

62)

Ans. -5050

63)

Ans.

64)

Ans. 2

65)

Ans. 1

66)

Ans. -4

67)

Ans.

68)

Ans. irrational roots

69)
x2 – (α2 + β2)x + α2β2 = 0
x2 – [(α + β)2 – 2αβ]x + α2β2 = 0

=0
2 2 2 2
a x – (b – 2ac)x + c = 0
70)
when x2 – 5x + 5 = 1
or x2 – 5x + 5 = –1, x2 + 4x – 60 = even
or x2 + 4x – 60 = 0, x2 – 5x + 5 ≠ 0

⇒
Sum of all values = 3

71)

Ans. 4

72)

Ans. 1

73)

Ans. 1

74)

Ans. 5

75)

Let |x–2| = t (t ≥ 0)
t2 + t – 2 = t = 1 ; t = –2
So, t = 1(only) ⇒ |x–2| = 1 ⇒ x = 3 ; x = 1
Sum of all real roots = 3 + 1 = 4.