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Problem Set 5

The document contains calculations related to the temperature and specific heat of water, as well as the accumulation of mercury in a lake. It discusses the input-output generation and consumption of mercury, along with critical concentration levels. Additionally, it provides equations and results for the mass of mercury over time and its average volume in the lake.

Uploaded by

Christine Wu
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3 views5 pages

Problem Set 5

The document contains calculations related to the temperature and specific heat of water, as well as the accumulation of mercury in a lake. It discusses the input-output generation and consumption of mercury, along with critical concentration levels. Additionally, it provides equations and results for the mass of mercury over time and its average volume in the lake.

Uploaded by

Christine Wu
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Christine Wa

(ywn26/44EE06)
1 -

°
OH when T = 3 C

· H =

fmCleidT
& oT =
3 % =
3K

>
-
SiPcondition :
Te = 273 15 K .

=> T+ = 273 . 15k + 3k = 278 .


151

>
& Given Vlake =
18900km
↑

>
Prater 1
%
-

53
= Make =
18900Kmx
(10)
m = 1 .
89410 g
1 89x108 89x10" key
T
=

1
.
-

=
.

& Cp(t) :
Specific heat of water at constant pressure

217
(p(t) 4
Ylgk STP condition
>
-

=
. at
(273 .
15 K , latm)

1-89x10xg)(4 21 )dT
·
H =

1 89x10"
ky
=
x 4 211
.

-
(27015 213 15)X -

= 2 .
39x10" kJ

·
Cp(t) at Sip :
from thermoexcel . com
.
2

US Accumulation =
Input-output
(no into
:
generation/consumption assume to = 0
given

· Mine is
-

②
Ming, out = 0 4 .

MHg
linear for m
=> 015-0 4m Leibniz's
5
= 0 .
.

factor
integrating

=> + 0 . um = 0 015
.

,
IF ed =
0

2
.
4t

=>
gayedm 04 0 .
4m = 0 075
. . 24t

=>
((e m/dt 10 015 +de = .

=> eat m e
=
5 .

8 4t
Ce
-

m(t) m(t) 0 1875 +


=+
=> 5 =
=
.

intial condition
IVP t 1
day M(1 0 005
Mg/l
: =
= .

m() 0 187
+ 005
=
.
= 0
.

solve for c =
c =
(0 . 005 -
0 .
1875) eat .

~
-
0 .
27226
-
0 4t =
unit m (Maye)
1875
.

= m(t) = 0 -
0 27226e
day)
. .

- )
=
1

(2) >
-

to exceed critical concentration = 0 02


.
ppb
assume
density of lake constant =

lo%b =
1
ppb
P

0 02
.

=see X
10 gation
/ e x 10mg = 0 02
.

may
>
-

At critical points
- 0 .
4t
0 1875 0 272762 0 02
My
-

. .
= .

solve for =
0 4t 0-4t
272262
.
-

=> 0 .
= 0 1675
.
= e = 0 61522
.

-o + +
=>
In e = I 10 61522) -

= -

0 . 4t = -

0 .
48578

- = 1 .
21445
days
0 4t
1
-
.

m (t) = 0 . 1835 -

0 27226e
.

0 1875 212268 06517


day m(2) May
·
2 : = .
-
0 . - 0 .

day 4 m(4) = 0 13253 M8/e


·

= .

m(6) 1628
day 6 : = 0 .

May
day 8 = m (8) = 0 .

1764M'Y
(10)
day 10 : m = 0 .
18251
M'Y

14388M2Y
0
average =
.

20 volume of dissolved
mercury
:

Vlake 10 I
>
-

=
18900km* x = 1 .
89x10"l
1km

of
=>
mercury 0 14388 89x10t
M/x
mass =
.
1 .

15
719332x10
= 2 .
MG
9
= 2 .
719332x10 g

*
density Phy = 13 6 .
Yus at room
temp (25 %)

=> volume of
mercury
= 2 .

719332x10"gx
100 em
= 1 9995 .
x

x
iVHg = 1 9995
. x 10 km2
9995x10
3 1 .

18900km3
kis
+100 = 1 .
0579X10-9 %

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