24-06-2026

7601CJA101022260006 JM

PHYSICS

SECTION-I

1) Two conducting shells of radii r and 5r are arranged as shown in figure. If charge –Q is given to

outer shell then charge on inner shell which is grounded is

(A)

(B)

(C) +Q
(D) -Q

2) A spherical shell of radius R carries a uniformly distributed charge q. The electrical forces arising
cause the expansion of the shell. The mechanical stress in the shell is

(A)

(B)

(C)

(D)

3) A bullet of mass m and charge q is fired towards a solid uniformly charged sphere of radius R
and total charge +q. If it strikes the surface of sphere with speed u, find the minimum speed u
so that it can penetrate through the sphere. (Neglect all resistance forces or friction acting on bullet

except electrostatic forces)

(A)
(B)

(C)

(D)

4) The electric potential V as a function of distance (x) (metre) is given by V= (5x2 + 10x − 9) volt.
The value of electric field at x = 1m is:

(A) -20 volt/m

(B) 6 volt/m
(C) 11 volt/m
(D) -23 volt/m

5) A dipole is placed at origin of co-ordinate system as shown in figure. Electric field at point P (0, y)

is given as (P is the dipole moment)

(A)

(B)

(C)

(D)

6) Two short electric dipoles are placed as shown. The energy of electric interaction between these

dipoles will be

(A)

(B)

(C)
(D)

7) The electrostatic potential V at a point on the circumference of a thin non-conducting disk of

radius r and uniform charge density σ is given by equation V = 4σrk. Which of the following
expression correctly represents electrostatic energy stored in the electric field of a similar charged
disk of radius R?

(A)

(B)

(C)

(D) None of these

8) The three point charges shown in the figure lie along a straight line. The energy needed to
exchange the position of the central + ve charge with one of the negative charges is

(A)

(B)

(C)

(D)

9) Consider a square of length ℓ. 4 small dipoles of strength P and 2P at kept at each corner of a
square as shown. A point charge Q is kept at centre. The magnitude of force experienced by point

charge Q is

(A)

(B)
(C)

(D) None of these

10) Four equal charges of magnitude q as shown in fig. Now the charge at center C is taken to

infinite slowly, then work done by external force will be -

(A)

(B)

(C)

(D)

11) In an ink-jet printer, an ink droplet of mass m is given a negative charge q by a computer-
controlled charging unit, and then enters at speed v in the region between two deflecting parallel
plates of length L separated by distance d (see figure below). All over this region exists a downward
electric field which you can assume to be uniform. Neglecting the gravitational force on the droplet,
the maximum charge that can be given so that it will not hit a plate is close to :

(A)

(B)

(C)

(D)

12) Three large conducting sheets of area A placed parallel to each other at finite distance
contain charges Q, - 2Q and 3Q respectively. Then magnitude of electric field at point P is
(A)

(B)

(C)

(D) 0

13) Which of the following is true for the figure showing electric lines of force? (E is electrical field,

V is potential)

(A) EA > EB
(B) EB > EA
(C) VA > VB
(D) VB = VA

14) Time taken by the planet to cover path ABC is t1 & time taken by the planet to cover path C D A

is t2 :-

(A) t1 = t2
(B) t2 > t1
(C) t1 > t2
(D) cannot be determined

15) Energy required to move a body of mass m from an orbit of radius 2R to 3R.
(A)

(B)

(C)

(D)

16) A particle of mass m is located at a distance r from the centre of a shell of mass M and radius R.
The force between the shell and mass is F(r). The plot of F(r) vs r is

(A)

(B)

(C)

(D)

17) A sphere of uniform density ρ has within it a spherical cavity whose centre is at a distance a
from the centre of the sphere. The gravitational field within the cavity is

(A) non-uniform and zero at the center of the cavity.

(B) zero at every point inside the cavity.
(C) uniform and not zero.
(D) same magnitude but has different direction at different points.

18) A planet of mass m is moving in an elliptical orbit round the sun (mass M) as shown in the figure.

Then the angular momentum of the planet may be written as

(A)

(B)

(C)

(D) L = 0

19) Two frictionless tunnels AB and AC are dug inside the earth as shown in the figure. A is at R/2
distance from centre of earth along the line connecting centre and B. A particle of mass m1 is
projected along AB and another particle of mass m2 is projected along AC such that both escape.
Then ratio of their minimum velocities, so that particle escapes the gravitional field of earth, is

(A) 1 : 1
(B) 1 : 2
(C) 2 : 1
(D) 3 : 1

20) Imagine a new planet having the same density as that of Earth but it is 3 times bigger than the
Earth in size. If the acceleration due to gravity on the surface of Earth is g and that on the surface of
the new planet is g', then

(A) g' = 3g
g' =
(B)

(C) g' = 9g
(D) g' = 27 g

SECTION-II

1) A neutral conducting solid sphere of radius 2m is placed such that its centre is 4m from a point
charge q = 2mC. The electric field intensity just outside at a point A on the sphere is found to be 2
 0

N/C. If the induced charges per unit area at A is xε . Find the value of x.

2) Electric field in a region is given by . The charge enclosed in the cube of side 1m

oriented as shown in the diagram is given by α∈ . Find the value of α.

3) Figure shows a binary star system revolving about their COM. The masses of star A & B are 15 ×
30 30
10 kg and 45 × 10 kg respectively . Find the ratio of area swept by star A to area swept by star B

about their common COM in a common time interval.

4) Two large spherical object of mass M each (uniformly distributed) are fixed as shown in figure. A
small point mass m is projected from point A heading towards center C2 of second sphere. The

minimum velocity of point mass so that it can reach upto second object at point B is then
calculate n. [Points A & B lie at surfaces of spheres and neglect other gravitational forces]

5) A comet is in elliptical orbit around the sun. In this orbit the comet's smallest distance from the
sun is 72 × 106 m and its largest distance from the sun is 144 × 106 m. The ratio of comet's
maximum speed to the minimum speed in the orbit is : (Neglect the presence of all bodies other than
the sun and comet).
 CHEMISTRY

SECTION-I

1) Determine the potential of the following cell :-

Pt | H2(g, 0.1 bar) | H+ (aq, 10–3 M) || (aq, 0.1 M), Mn2+ (aq, 0.01 M), H+ (aq, 0.01 M) | Pt

Given : V

(A) 1.54 V
(B) 1.48 V
(C) 1.84 V
(D) none of these
0
2) Electrode potentials (E ) are given below :
Cu+ / Cu = + 0.52 V,
Fe3+ / Fe2+ = + 0.77 V,
I2 (s) / I– = + 0.54 V,
Ag+ / Ag = + 0.88 V.
Based on the above potentials, strongest reducing agent will be :

(A) Cu+
(B) Cu
(C) Ag+
(D) Ag

3) Calculate the equilibrium constant for

Hg22+ → Hg + Hg2+
Given :\(\eqalign{ & \left[ {{E^\circ}_{Hg_2^{2 + }/Hg} = 0.78V\left( {{E^\circ}_{H{g^{ +
2}}/Hg} = 0.85V} \right)} \right. \cr & \left. {\left( {\dfrac{{2.303RT}}{{nF}} =
\dfrac{{0.06}}{n}} \right)} \right] \cr} \)
(log2 = 0.3, log3 = 0.4)

(A) 5 × 10–3
(B) 6 × 10–3
(C) 7 × 10–3
(D) None of these

4)

Which of following graph correctly illustrater the dependence of the cell voltage, Ecell on the pH for
the reaction
2Ag+ (aq) + H2(g) —→ 2Ag(s) + 2H+(aq)
if other species are unity :-
(A)

(B)

(C)

(D)

5) Zn | Zn2+ (C1)|| Zn2+ (C2)|Zn for this cell ΔG is negative if -

(A) C1 = C2
(B) C1 > C2
(C) C2 > C1
(D) None

6) For the reduction half reaction At pH = 3 at

298 K, electrode reduction potential is (Consider quinone and hydroquinone have identical
concentration)

(A) 1.123 V
(B) 1.42 V
(C) 1.36 V
(D) 1.3 V

7) For lead storage battery pick the correct statements.

A. During charging of battery, PbSO4 on anode is converted into PbO2.
B. During charging of battery, PbSO4 on cathode is converted into PbO2.
C. Lead storage battery consists of grid of lead packed with PbO2 as anode.
D. Lead storage battery 38% solution of sulphuric acid as an electrolyte.
Choose the correct answer from the options given below.

(A) B, D only
(B) B, C only
(C) B, C, D only
(D) A, B, D only

8) The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The
amount of PbSO4 electrolyzed (in g) during the process is : (Molar mass of PbSO4 = 303 g mol–1)
(A) 22.8
(B) 15.2
(C) 7.6
(D) 11.4

9) In electrochemical corrosion of metals, the metal undergoing corrosion :

(A) acts as anode

(B) acts as cathode
(C) undergoes reduction
(D) None

10) If the standard reduction potential for four divalent elements X, Y, Z, W are – 1.46 V, –
0.36V, 0.15 V and – 1.24 V respectively, then :-

(A) X will displace Z+2 from aqueous solution

(B) Y will displace Z+2 from aqueous solution
(C) W will displace Z+2 from aqueous solution
(D) All the above statements are correct

11)

The calomel electrode is reversible with respect to

2+
(A) Hg2
(B) H+
(C) Hg2+
(D) Cl–

12) Given:
(i)
(ii)
Electrode potential, E° for the reaction, will be

(A) 0.52 V
(B) 0.50 V
(C) 0.30 V
(D) 0.38 V

13) Using same quantity of current, which among Na, Mg and Al is deposited less (by mass) during
eletrolysis of their molten salts :-

(A) Na
(B) Mg
(C) Al
(D) All in same

14) Sodium metal is produced commerciall by the electrolysis of molten sodium chloride and
chlorine is produced as a by product. How many litres of chlorine at 1.8 atm and 27°C will be
produced if a current of 1.0 × 103 A is passed through NaCl (ℓ) for 9.65 h ?

(A) 2463
(B) 460
(C) 1800
(D) 1231.6

15) If 0.50 L of a 0.60 M CuSO4 solution is electrolyzed for a period of 30.0 min using a current of
4.60 A. If inert electrodes are used, what is the final concentration of Cu2+ remaining in the solution?

(A) 0.342 M
(B) 0.544 M
(C) 0.389 M
(D) 0.514 M

16) Equivalent conductivity of BaCl2, H2SO4 and HCl, are x1, x2 and x3 S cm2 eq–1. If specific
conductance of BaSO4 is x S cm–1, then Ksp of BaSO4 is –

(A)

(B)

(C)

(D)

17) Identify the correct statement :

(A) m increases with increase in temperature.

(B) m decreases with increase in temperature.
(C) Specific conductance increase with decrease in concentration.
(D) Specific conductance decreases with increase in temperature.

18) In a Cu-voltameter, mass deposited in 30s is 'm' gm. If the time-current graph is shown in the
following figure What is the electrochemical equivalent of Cu?

(A)

(B)

(C)

(D)

19) 40 mL of a mixture of CH3COOH and HCl (aqueous solution) is titrated against 0.1 M NaOH

solution conductometrically. Which of the following statement is correct?

(A) The concentration of CH3COOH in the original mixture is 0.005 M

(B) The concentration of HCl in the original mixture is 0.005 M
(C) CH3COOH is neutralised first followed by neutralisation of HCl
(D) Point 'C' indicates the complete neutralisation HCl

20) Which of following type of plot would you expect from the titration of AgNO3 against KCl
solution?

(A)

(B)
(C)

(D)

SECTION-II

1) I2(s) | I– (0.1M) half cell is connected to

H+(aq) | H2(1 atm) | Pt half cell and its half cell potential is found to be 0.7714 V. If ,
the pH of H+/H2 half cell will be :-
[Give answer as a closest integer]

2) Assume a cell with the following reaction

Cu(s) + 2Ag+(1 × 10–3 M) → Cu2+(0.250 M) + 2Ag(s)

Ecell for the above reaction is ___________V. (Nearest integer)

[Given : log 2.5 = 0.3979, T = 298 K]

3) A current is passed through 2 voltameters connected in series. The first voltameter contains
XSO4(aq.) and second has Y2SO4(aq.). The relative atomic masses of X and Y are in the ratio of 2 : 1.
The ratio of the mass of X liberated to the mass of Y liberated is:

4) The conductivity of pure water in a conductivity cell with electrodes of cross-sectional area 4 cm2
and 2 cm apart is 8 × 10–7 S cm–1.
The value of current that would flow through the cell under an applied potential difference of 1 volt
is 1.6 × 10–X amp. The correct value of X is:

5) Potassium chlorate is prepared by electrolysis of KCl in basic solution as shown by following

equation. 6OH– + Cl– → ClO3– + 3H2O + 6e–
A current of xA has to be passed for 10h to produce 10.0g of potassium chlorate. the value of x is
_______. (Nearest integer) (Molar mass of KClO3 = 122.6 g mol–1, F = 96500 C)

MATHEMATICS
 SECTION-I

1)
is :

(A) 0

(B)

(C)

(D)

2) Let = 5 for some r, p ∈ R. If the set of all possible values of

2
q, such that the roots of the equation rx – px + q = 0 lie in (0, 2), be the interval (a, β], then 4(α + β)
equals.

(A) 11
(B) 13
(C) 17
(D) 21

3) If = m, then a + b + m is equal to:

(A) 5
(B) 6
(C) 8
(D) 10

4) Evaluate :

(A)

(B)

(C)

(D)
5) If

(A) a = 1, b = 1
(B) a = 1, b = 2
(C) a = 1, b = -2
(D) none of these

6) is equal to –

(A)

(B)

(C) 1
(D) None of these

7) Find :

(A) 0
(B) 1
(C) 1/2
(D)

8)

(A) e2
(B) e

(C)

(D) none of these

9)

(A)

(B)

(C)

(D)
10) Find limn→∞​ + limx→0

(A) 5/6
(B) 1/3
(C) 1/2
(D) 1

11) Evaluate limx→0

(A) 1/2
(B) -1/2
(C) 0
(D) -1

12) limx→0

(A) 1/32
(B) 1/16
(C) 1/64
(D) 1/4

13) The value of limx→∞​ is:

(A) a
(B) a/2
(C)
(D) 0

14) Evaluate limx→0​

(A) 1/8
(B) 1/4
(C) 1/2
(D) 1/16

15) Evaluate :

(A)
(B) 2
(C)

(D)

16) The value of limx→a​ is:

(A)

(B)

(C)

(D)

17) If Then the value of a is

(A)

(B)

(C)

(D)

18) n ∈ ℕ is equal to

(A)
(B) 1

(C)

(D) 0

19) If then the value of

equals :

(A) e
(B)
(C)
(D)

20) is equal to

(A) log 12
(B) log [Link] 4
(C) (log [Link] 4)-1
(D) –6log [Link] 4

SECTION-II

1) where α, β R, then find the value of (α +2β)

2) , then the value of is

3) If a and b are chosen randomly from the set A = {1,2,3,4,5,6} with replacement. If probability

that is [H.C.F(p,q) = 1] then (q – p) is

4) Value of the limit

5) is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A B A D B A C D B B D A C A A C B A A

SECTION-II

Q. 21 22 23 24 25
A. 2 2 9 8 2

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B B D C A A C A D D A C A D C A B B C

SECTION-II

Q. 46 47 48 49 50
A. 3 3 1 6 1

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C B C C B B A D A B A B A A A C A A D

SECTION-II

Q. 71 72 73 74 75
A. 5 16 8 2 1
 SOLUTIONS

PHYSICS

1)

Conceptual

2)

3)

Conceptual

4)

Conceptual

5)

Explaining the Question :-

We have to find field due to a dipole at a general position
Concept:-
Electric field due to a dipole
Solution :-

Do the components of dipole and find field due to each separately

E1 =

E2 =
=

Final Answer :- ( )

6)

Question Explanation: Two short electric dipoles of moments p₁ and p₂ are placed at an
angle θ. Find their interaction energy.

Concept: This question is based on dipole–dipole interaction energy in electrostatics:

Solution:
Potential energy of P2 in the field of P1

Final Answer: option (2)

7)

Conceptual

8)

Conceptual

9) The net field at centre is zero.

10)

11)

w = PEi –PEr = q [Vi– Vf] = q

work done = J

12)

13) Density of electric field lines is proportional to electric field intensity. Also potential
decrease in direction of electric field.

14) Question Explanation:

Comparing the time taken to travel different parts of an elliptical orbit.

Concept:
Kepler's Second Law.

Solution:
Since A1 > A2 so T1 >T2
Final Answer:
Correct option is (3).

15)

Conceptual

16)

Conceptual

17)

Question Explanation:
The question asks the nature of gravitational field inside an off-centre spherical cavity in a
uniform sphere.
Concept:

Using superposition principle and r inside a solid sphere.

Solution:

Field from the Large Sphere at P:

The gravitational field inside a uniform sphere at a distance $r$ from its center is:
Field from the "Negative" Cavity Sphere at P:
Similarly, the field due to a sphere of density at a distance s from its center is:

Resultant Field at P:

From the vector triangle OCP, we know that .

Final Answer:
Option (3)

18)

Conceptual

19)

Escape velocity is independent of mass and location

20) Solution:

⇒g = G ρπ R

Final Answer: The correct option is (1).

21)

Conceptual

22)
ϕ = (6y) Area – (4x) Area
= 6 × 1 × (1)2 – 4 × 1 × (1)2

0
⇒ q = 2ε
23) Rate of area swept
(r = distance from COM)

24) Question Explanation:

A small mass m is projected from point A towards point B, passing between two massive
spheres. The goal is to find the minimum velocity required to reach point B.

Concept:
This question based on gravitational potential energy and energy conservation

3. Solution:
Using the conservation of mechanical energy:
EA = EB
Total Energy at A :

Gravitational Potential Energy due to two spheres:

Solving for v0, the given equation is:

EA = EB

So M = 8
 Final Answer : 8

25)
By conservation of angular momentum
mv1r1 =mv2r2

=2

CHEMISTRY

26) Anode : H2(g) → 2H+ (aq) + 2e– ; Eº = 0.0 V

Cathode : + 8H+(aq) + 5e– → Mn2+ (aq) + 4H2O(l) ; Eº = 1.51 V
Ecell = ERP(RHS) – ERP(LHS)

= 1.51 –
= 1.48 V

27) Reducing agent have low Reduction potentials

R.P↑.R.P.↓
Cu+/Cu = 0.52 (min among them)
Cu

28) + 2e– → 2Hg ...(1)

Hg+2 + 2e– → Hg ...(2)
(1) + (2)
→ Hg + Hg+2 E° = 0.78 – 0.85
⇒ – 0.07 V

– 0.07 = 0.03 log K

–2.3 = log K
K = 10–2.3
⇒ 10–3 × 10+0.7
= 6 × 10–3

29)

Ecell = log
Ecell ⇒

pH Ecell

30) Question Explanation : Find condition for this cell when ΔG is negative.

Concept : Concentration Cell (E°cell = 0).

Solution : For ΔG to be negative, the cell potential must be positive (Ecell > 0).

Nernst equation for a concentration Cell : Ecell = log

For ECell > 0 : log >0⇒ > 1 ⇒ C2 > C1.

Final Answer : Option (3)

31) Question Explanation : Calculate electrode reduction potential of quinhydrone electrode

at given pH using Nernst equation

Concept : For redox reactions involving H+, electrode potential depends on pH as per Nernst
equation.

Solution: (Summary table)

Final Answer : Option (1)

32)

Question Explanation: The question asks to identify the correct statements regarding the
operation and composition of a lead storage battery. To solve this, we must examine the
chemical processes that occur at the electrodes during charging and discharging, as well as
the standard materials used in the battery's construction.
Concept: A lead storage battery is a secondary cell, meaning it can be recharged by passing
an electric current through it in the opposite direction.
 A. Construction: It consists of a lead anode and a grid of lead packed with lead dioxide ( ) as
the cathode.
B. Electrolyte: The electrodes are immersed in a 38% solution of sulphuric acid ( ).
C. Discharging: Chemical energy is converted to electrical energy. PbSO4 is formed at both
electrodes, and the concentration of H2SO4 decreases.
D. Charging: Electrical energy is used to reverse the chemical reactions. The PbSO4 is converted
back to Pb at the anode and PbO2 at the cathode.

Solution:

A. Statement A: During charging, PbSO4 at the anode is reduced to metallic Pb . Therefore,

Statement A is incorrect.
B. Statement B: During charging, PbSO4 at the cathode is oxidized to PbO2. Therefore, Statement
B is correct.
C. Statement C: The grid of lead packed with PbO2 serves as the cathode, while the anode is lead.
Therefore, Statement C is incorrect.
D. Statement D: The electrolyte used is indeed a 38% solution of sulphuric acid. Therefore,
Statement D is correct.

By evaluating these points, only statements B and D are accurate.

Final Answer: Option (1)

33) A. Question: The anodic half-cell of lead-acid battery is recharged using electricity of 0.05
Faraday. The amount of PbSO4 electrolyzed (in g) during the process is: (Molar mass of PbSO4
= 303 g mol–1)

C. Given Data:

A. Charge passed = 0.05 Faraday

B. Molar mass of PbSO4 = 303 g/mol

D. Concept:

A. Faraday's Laws of Electrolysis:

E. Mathematical Calculation:

Anodic Reaction: The reaction at the anode during recharging is:

PbSO4(s) + 2e- → Pb(s) + SO4^2-(aq)

A. This shows that 2 moles of electrons are involved in the electrolysis of 1 mole of PbSO4.

B. Moles of electrons: 0.05 Faraday means 0.05 moles of electrons.

Moles of PbSO4 electrolyzed: Since 2 moles of electrons electrolyze 1 mole of PbSO4, 0.05 moles of
electrons will electrolyze:

moles of PbSO4 = (0.05 mol electrons) / (2 mol electrons/mol PbSO4) = 0.025 mol

C. Mass of PbSO4 electrolyzed:

mass of PbSO4 = moles of PbSO4 * molar mass of PbSO4 mass of PbSO4 = 0.025 mol * 303 g/mol
= 7.575 g ≈ 7.6 g
F. Final Answer: 7.6 g

34)

A. Question Explanation:

We need to determine the electrochemical role of the metal that is corroding. This involves
understanding the processes of oxidation and reduction in corrosion.

B. Given Data:

A. Electrochemical corrosion of metals

C. Concept: Corrosion

D. Solution:

A. In corrosion, the metal loses electrons, meaning it undergoes oxidation.

B. Oxidation occurs at the anode.

C. Therefore the metal that corrodes acts as an anode.

E. Final Answer:

The correct answer is option (1): acts as anode

35)

X, Y, W will displace Z+2

36)

Question Explanation:
Identify the ion with respect to which the calomel electrode shows reversible behavior.

Concept:
An electrode is reversible with respect to the ion whose concentration directly affects its
electrode potential.

Solution (summary table):

 Feature Calomel Electrode

Electrode reaction

Potential depends on Cl– ion concentration

Reversible with respect to Cl– ion

Final Answer : Option (4)

37)

38)

Deposited amount ∝ Eq. wt. (E)

w=
w∝E

Eq. wt is least for Al =

39) (a) equivalents of Cl2 produced

moles of Cl2 = 180

so
= 2463 L

40)

Equvalent of deposit

Cu+2 =

Moles of Cu+2 deposite =

Molarity of Cu+2 deposit =

Remain Molarity = 0.6 – 0.085 = 0.51

41) ×2
for sparingly soluble salt

or

42)

Explain Question:
Identify the correct statement

Concept:
Molar conductance

Solution:
The correct statement is that molar conductivity (Λ ) increases with an increase in
temperature.
Analyze statement 1: Molar conductivity (Λ ) increases with an increase in temperature due to
the increased kinetic energy and mobility of ions, as well as a decrease in the solvent's
viscosity.
Analyze statement 2: This statement is the opposite of statement 1 and is incorrect because
molar conductivity increases, not decreases, with increasing temperature.
Analyze statement 3: Specific conductance ( ) is the conductance of a unit volume of solution.
When concentration decreases (dilution), the number of ions per unit volume decreases, so the
specific conductance decreases. Thus, this statement is incorrect.
Analyze statement 4: Specific conductance increases with an increase in temperature because
ionic mobility increases. Therefore, the statement that it decreases with increasing
temperature is incorrect.

Final Answer: Option(1)

43) Total charge passed in 30 sec.

= × 100 × 10 + 100 × 10 + 100 × 10 + × 100 × 10

= 3 × 100 × 10mA × s
= 3000 × 10–3amp s = 3C
W = ZQ

So, Z =

44) From the given graph 2 ml NaOH solution is used for neutralisation of HCl and 3 ml NaOH
solution is used for neutralisation of CH3COOH.
∴ Mole of HCl = Mole of NaOH used
M × 40 = 0.1 × 2
M = 0.005
∴ Mole of CH3COOH = Mole of NaOaH used
M × 40 = 0.1 × 3
M = 0.0075
HCl is strong acid and will be neutralised first.

45) Fact

46) Pt | H2 (1 atm) / H+ (a0M) || I–(0.1M) | I2(s)

(C) I2(s) + 2e– → 2I–
(A) H2(g) → 2H+ + 2e–
H2(g) + I2(s) → 2H+ aq + 2I–

0
Ecell = 0.7714 = 0.533 – × log[10–2 × a 2]
0.7714 – 0.533 = –0.0591 × log[H+] × 0.1
= 0.0591 × (+1) + 0.0591 × pH
pH 3

47)

48)
AX = 2AY

49)

50) Given balanced equation is

 → 10g KClO3 ⇒ in obtained
→ from the above reaction, it is concluded that by
6F charge 1 mol KClO3 is obtained.
→ By the passage of 6F charge = 1 mol KClO3

∴ By the passage of

Now

⇒
OR

X = 1.311
Ans.(1)

MATHEMATICS

51)

52)

⇒
∴ Dr → 0 ∴ Nr → 0 ⇒ r = 1

⇒
⇒ 2+p=5
⇒p=3
Now, quadratic equation is x2 – 3x + q = 0
its both roots lie in (0, 2)

D ≥ 0, f(0) > 0, f(2) > 0

⇒ 9 – 4q ≥ 0 and θ > 2

⇒θ∈

α = 2, β = ⇒

53) ∵ Denominator = 0 at x = 2
⇒ Numerator = 0 at x = 2
⇒ 23 – 5(2)2 + a(2) + b = 0
⇒ 2a + b = 12 ... (1)

∴m=

⇒m=

⇒m=
∵ Denominator = 0 at x = 2
⇒ Numerator = 0 at x = 2
⇒ 3(2)2 – 10 (2) + a = 0 ⇒ a = 8
put a = 8 in (1), we get b = – 4

∴ ⇒m=2
∴a+b+m=6

54) Conceptual

55)

Conceptual
56)

where

57)

Question Explanation: Finding the limit of a sum of square root fractions.

Concept: Sandwich Theorem for sequences

Solution: Each term in the summation is bounded by the smallest term (where the
denominator is largest) and the largest term (where the denominator is smallest). By
multiplying these bounds by the number of terms n, we find that both limits converge to 1 as
.

Calculation: Smallest term: , Largest term:

and

Final Answer: option (2) 1

58) Conceptual

59)

60)
Question Explanation: Calculating a combined limit using sum of squares and
rationalization.

Concept: Sum of First n Squares and Algebraic Limits.

Solution:

Part 1: Let

Using :

Part 2: Let

Rationalizing the numerator:

Total Limit:

Final Answer: Option (1)

61)

Question Explanation: Evaluating a limit involving a composite trigonometric function.

Concept: Standard Trigonometric Limits for and .

Solution:

Let

Multiply and divide by :

Let . As :
Final Answer: -1/2

62)

Question Explanation: Simplifying a trigonometric expression using factorization to apply

standard limits.

Concept: Factorization of Trigonometric Limits.

Solution:

Factorize the numerator:

Substitute into the limit:

Apply :

Final Answer: 1/32

63)

Question Explanation: Evaluation of a limit at infinity involving a radical expression.

Concept: Rationalization Method for Limits at Infinity.

Solution: Multiply and divide by :

Divide numerator and denominator by x:

As , terms with and approach 0:

Final Answer: a/2

64)

Question Explanation: Evaluating a nested trigonometric limit using standard limit results.

Concept: Standard Limit of as .

Solution:

Let

Multiply and divide by :

Let As :

Final Answer: 1/8

65)

Conceptual

66)

Question Explanation: Evaluating a limit involving fractional powers using standard limit
formulas.

Concept: Standard Limit Formula .

Solution:

Given:
Step 1: Divide numerator and denominator by (x–a).

Step 2: Apply the formula .

A. Numerator:

B. Denominator:

Step 3: Simplify the expression.

Final Answer:

67)

68)

=
=

69) Solution : (A)

70) Ans (D)

Given limit can be written as

71)
72)

73)

74)

Conceptual

75) Explain Question:

Find the given limit.

Concept:
Use of standard limit & L Hospital rule.

Solution:

0
ℓ1 = e = 1

⇒
ℓ1 + ℓ2 = 1
Final Answer: 1