24-05-2026

1001CJA101029260012 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) A sheet of area 40m2 is used to make an open tank with square base then edge length of base
such that volume of this tank is maximum, is -

(A)

(B) 2
(C)
(D)

2) is equal to :-
(where [·] denotes the greatest integer function)

(A) π + sin2cos2
(B) π – 2 + sin2cos2
(C) π – 2 – sin2cos2
(D) None

3) Area lying between by the curve y = (x2 + 2x)e–x and it's asymptotes is

(A) 1
(B) 2
(C) 4
(D) 6

4) If solution of differential equation is (where 'C' is

arbitrary constant), then the value of 10 K is

(A) 30
(B) 40
(C) 20
(D) 10

SECTION-I (ii)
1) Let be differentiable functions such that f(x) = x3 + 3x + 2, g(f(x)) =
x and h(g(g(x))) = x for all . Then

(A)

(B) h'(1) = 666

(C) h(0) = 16
(D) h(g(3)) = 36

2)

Let [x] denotes the greatest integer less than or equal to x. If f(x) = [x sin (πx)], then f(x) is

(A) Continuous at x = 0
(B) Continuous in
(C) differentiable at x = 1
(D) differentiable in

3) The solution of x2 are

(where 'C' is arbitrary constant)

(A)
(B) x2 y = C

(C)

(D)

4) Which of the following statement(s) is/are correct with respect to the circles S1 ≡ x2 + y2 – 4 = 0
and S2 ≡ x2 + y2 – 2x – 4y + 4 = 0 ?

(A) S1 and S2 intersect at an angle of 90°.

(B)
The point of intersection of the two circle are (2, 0) and .
Length of the common of chord of S1 and S2 is
(C)

(D) The point (2, 3) lies outside the circles S1 and S2.

5) Let y = f(x) be the solution of differential equation such

that then

(A)
the equation has exactly one real solution

(B)
the equation has no real solution
(C) f(1) ≠ f(–1)
(D) f(x) is an odd function

6) is equal to -

(A)

(B)

(C)

(D)

SECTION-III

1) The value of is

2) Value of is K then value of 6K is

3) Let ƒ(x) be a non constant thrice differentiable function defined on 'R' such that ƒ(x) = ƒ(6 – x) and
ƒ'(0) = 0 = ƒ'(2) = ƒ'(5). If n is the minimum number of roots of [ƒ"(x)]2 + ƒ'(x)ƒ"'(x) = 0 in [0, 6] then

value of is

4)

The function attains its local maximum value at x is

equal to

5) Let and ƒ(x) passes through (π,0) then the number

of solutions of the equation ƒ(x) = x3 in x ∈ [0,2π] is

6) Let then the value of [ea] where [.] represents greatest integer function, is

7) Area bounded by 12x – y2 > 0 and y > 2x is

8)

If length of the tangents drawn from P(a, b) to circles x2 + y2 = 1, x2 + y2 – 8x + 15 = 0, x2 + y2 +

10y + 24 = 0 are equal then |ab| is :-

PART-2 : PHYSICS

SECTION-I (i)

1) Calculate the magnetic field at distance y from the centre of the axis of a disc of radius r and
uniform surface charge density σ, if the disc spins with angular velocity ω ?

(A)

(B)

(C)

(D)

2) A conducting circular loop of radius a is connected to two long, straight wires. The straight wires
carry a current i as shown in figure. Find the magnetic field B at the centre of the loop.

(A) zero

(B)

(C)
(D)

3) A beam of light consisting of red, green and blue and is incident on a right angled prism. The
refractive index of the material of the prism for the above red, green and blue wavelengths are 1.39,

1.44 and 1.47 respectively. The prism will

(A) separate part of the red color from the green and blue colors
(B) separate part of the blue color from the red and green colors
(C) separate all the three colors from the other two colors
(D) not separate even partially, any colors from the other two colors

4) IniItially, switch S is connected to position 1 for a long time shown in figure. The net amount of

heat generated in the circuit after it is shifted to position 2 is :-

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Two liquid A & B of specific heat ratio 1 : 2 are at temperature 2θ and θ respectively. If they are
mixed, then choose CORRECT statement(s) : (ignore any heat loss and liquid does not change its
state)

(A)
if equal amount of them are mixed, then temperature of mixture is

(B)
if equal amount of them are mixed then temperature of mixture is
if the change of temperature in both the liquid is same then ratio of their masses
(C)
 if the change of temperature in both the liquid is same then ratio of their masses
(D)

2) A bar magnet is moved along the axis of copper ring placed far away from the magnet. Looking
from the side of the magnet, an anticlockwise current is found to be induced in the ring. Which of
the following may be true?

(A) The south pole faces the ring and the magnet moves towards it.
(B) The north pole faces the ring and the magnet moves towards it.
(C) The south pole faces the ring and the magnet moves away from it.
(D) The north pole faces the ring and the magnet moves away from it.

3) From a cylinder of radius R, a cylinder of radius R/3 is removed as shown. Current is flowing in

the remaining cylinder is I. The distance OA is equal to . Magnetic field strength at :

(A)
Point B is

(B)
Point B is

(C)
Point A is

(D)
Point A is

4) In the diagram shown, in steady state

(A) Charge on 1 µF capacitor is 1 µC

(B) Charge on 2 µF capacitor is 2 µC
(C) Charge on 3 µF is zero
(D) Potential difference across 2µF capacitor is 2 volt

5) A charged particle of mass m and charge q is released from rest in a uniform electric field E.
Neglecting the effect of gravity, choose the CORRECT statement(s) :-

(A) The force experienced by the charge particle is qE

(B) Momentum of the particle always increases

(C)
Kinetic energy as a function of time will be
(D) The path of the particle will be parabolic.

6) Consider a circuit as shown in figure. Then choose correct statement(s) :-

If 4Ω resistance is shorted (resistance less wire connected in parallel to it), the current through
(A)
battery will increase.
(B) If 4Ω resistor is shorted, the current through 5Ω resistance will increase.
(C) If instead of 4Ω, 5Ω, resistor is shorted, current through battery will decrease.
(D) If instead of 4Ω, 3Ω resistor is shorted, current through battery will decrease.

SECTION-III

1) Two wires are made of two different material and have the same volume. However wire 1 has
cross-sectional area A and wire 2 has cross-sectional area 3A. If the length of each wire increases by
Δx on applying force F, then find ratio of their young's modulus.

2) The square loop has sides of length 2cm. A magnetic field points out of the page and its
magnitude is given by B = (4t2) T. Emf induced in loop is given by x mV at t = 2.5 s. Find the value of
x.

3) Initially capacitor was charged fully by a 100 V battery and at t = 0, switch was closed. Heat

developed in the resistance till 9 µs is given by , where e is exponential

constant. Find the value of η.

4) Two circular coaxial coils of same radius and same number of turns having opposite current in the
magnitude ratio 4 : 1 are placed at some separation apart. At how many points on the common axis
magnetic field will be zero (exclude infinity)? Take separation as where R is radius of coils.

5) A non conducting rod of length 2m is hinged at one end and a charge of is distributed
uniformly over it. At t = 0, it is released from the position shown. There exist a uniform magnetic
field of inside the plane of motion of rod. If mass of rod is 100 g, then find the value of hinge

force (in N) when rod is rotated by due to gravity.

6) Uniform magnetic field B exists in a circular region of radius R. A particle having specific charge

0
enters the region with velocity v as shown. For the particle passes through the

center O of the region. Fill the value of α.

7) Find the magnetic field (in μT) at point A. (Given : Amp. R = 1m)

8) A non-uniform electric field in x-direction is increasing uniformly from 2N/C at x = 1m to 8 N/C

at x = 7m. The center of cube is at x = 2m. If the charge enclosed inside a small cube of side length
10 cm is 8.85 × 10–5n C, the value of n will be.

PART-3 : CHEMISTRY

SECTION-I (i)

1) Which of the following are low spin as well as paramagnetic complexes?

(A)
(B)
(C)
(D)

2) Which of the following reaction is correct ?

(A)

(B)

(C)
(D)

3) In which of the following reaction hydrocarbon is formed as product-

(A)

(B)

(C)

(D)

4) A gas undergoes change from state A to state B. In this process , the heat absorbed and work
done by the gas is 5 J and 8 J, respectively. Now gas is brought back to A by another process during
which 3 J of heat is evolved. In this reverse process of B to A:-

(A) 10 J of the work will be done by the surrounding on gas.

(B) 6 J of the work will be done by the surrounding on gas.
(C) 10 J of the work will be done by the gas.
(D) 6 J of the work will be done by the gas.

SECTION-I (ii)

1) Carbon reduction method is employed for commercial extraction of metal from amongst these :

(A) haematite
(B) cassiterite
(C) iron pyrite
(D) corundum

2) Select the CORRECT statement.

(A) Chelation effect is maximum for five & six membered rings
(B) Greater the charge on the central metal cation, greater the value of Δ (CFSE)
In complex ion [CoF6]3–, F– is a weak field ligand, so that Δoct < P (Pairing energy) and it is low
(C)
spin complex.
⊕
(D) [CoCl2(NH3)2 (en)] complex ion will have four different isomers.

3)
Select incorrect statement regarding product P.

(A) Product (P) on treatment with Br2/CCl4 gives meso product

(B) Product (P) on treatment with (i) B2H6/THF (ii) H2O/CH3COOH gives 1, 1-dimethyl cyclohexane
(C) Product (P) on reaction with (i) B2H6/THF (ii) H2O2, gives racemic mixture
(D) Product (P) on reaction with (i) Hg(OAc)2, H2O (ii) NaBH4, gives 1, 2-dimethylcyclohexanol

4) For the reaction sequence given below, the correct statement is/are-

(A) Product (P) can be formed when product (Q) react with Br2/CCl4
(B) Product (Q) can be formed when product (R) react with alc. KOH/Δ
(C) Iodocyclohexane can be formed when product (R) react with NaI/acetone
(D) Cyclohexa-1, 3-diene can be formed when product (P) react with EtO⊖/Δ (excess)

5) 3.00 mole of PCl5 kept in 1L closed reaction vessel was allowed to attain equilibrium at 380 K.
Calculate composition of the mixture at equilibrium.
PCl5(g) PCl3(g) + Cl2(g)

(A) [PCl5] = 1.41 M

(B) [PCl3] = 1.59 M
(C) [Cl2] = 1.41 M
(D) [Cl2] = 1.59 M

6) Consider the following 1st order reaction and the accompanying concentration time plot.
A4(g) → 4A(g)
Which of the following regarding decomposition reaction is/are correct?
[Given ln2 = 0.70, ln5 = 1.60]

(A) At 30 hr, 20% reaction is complete

(B) Half-life of the reaction is 105 hrs.
(C) Rate of decomposition of reactant decreases linearly with time.
(D) Changing initial concentration will change the time at which two curves intersect.

SECTION-III

1) How many compound(s) gives product on hydrolysis in which pπ-dπ bond(s) present?
SO2Cl2, SOCl2, POCl3, XeF2, N2O5, P4O6, SF4, BCl3

2)

How many of them are sulphide ore ?

Iron Pyrite, Chalcopyrite, Galena, Chalcocite, Magnetite, Cinnabar, Sphalerite, Alumina, Siderite,
Calamine, Malachite.

3) Consider the following set of reactions:

(i) Ag2S + NaCH → [Ag(CN)x]–n
(ii) Au + NaCN + O2 [Au(CN)y]–n
(iii) [Ag(CN)x]±n Ag ↓ + [Zn(CN)z]–m
(iv) [Ag(CN)y]±n Au ↓ + [Zn(CN)z]–m
(Where m, n, x, y and z, all are positive integers.)
What is the value of (x + y + z – 2n + m)?

4)
Number of HI consumed during the given reaction.
5)
Calculate total number of hyperconjugating structures (In which C-H bond involve) in major product-

6) Pure gas ‘A’ was taken in a closed container at a initial pressure of 5 atm. The pressure in the
container changed due to following reactions

If the total pressure due to mixture of gases A, B, C and D was found to be 10 atm, in which partial

pressure due to gas C was 3 atm. Find KP for first equilibrium , in atm2 ?

7) In CCP unit cell, the largest sphere which may fit in a tetrahedral void has radius 100 pm, then
largest sphere which may fit in octahedral void of same unit cell without disturbing the lattice has

radius 'X' pm then find value of ? [Given, ]

8) The plot of log kf versus for a reversible reaction A(g) P(g) is shown.

Pre-exponential factors for the forward and backward reactions are

15 –1 11 –1
10 s and 10 s , respectively. If the value of log K for the reaction at 500 K is 6, the value of | log
kb | at 250 K is ______.
[K = equilibrium constant of the reaction
kf = rate constant of forward reaction
kb = rate constant of backward reaction]
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. A B C A

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. B,C A,B,D A,C,D A,C,D A,C C,D

SECTION-III

Q. 11 12 13 14 15 16 17 18
A. 7 5 6 1 3 2 3 5

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22
A. C A A C

SECTION-I (ii)

Q. 23 24 25 26 27 28
A. B,C B,C A,C B,C A,B,C A,B

SECTION-III

Q. 29 30 31 32 33 34 35 36
A. 9 8 3 2 4 2 3 3

PART-3 : CHEMISTRY

SECTION-I (i)

Q. 37 38 39 40
A. D D B B

SECTION-I (ii)

Q. 41 42 43 44 45 46
A. A,B A,B,D A,B A,B,C,D A,B,D A,B
 SECTION-III

Q. 47 48 49 50 51 52 53 54
A. 5 6 8 5 6 9 4 5
 SOLUTIONS

PART-1 : MATHEMATICS

1) Let length of base be x and height be y

v = x2y
x2 + 4xy = 40

2)

3)

Required area A = = 4 Ans.

4)
5)

Given
g(f(x))=x

⇒ g'(f(x)) · f'(x) = 1 ⇒ g'(f(x)) =

⇒ g'(x3 + 3x + 2)=

put x = 0 we get
option A is wrong
* h(g(g(x))) = x; given
Put x = f(x)
⇒ h(g(g(f(x))))=f(x); given
⇒ …(1)
3
put x = 3 h(g(3)) = f(3)=3 + 3 × 3 + 2 ⇒
put x = f(x) in eq. (1)

⇒
⇒

⇒
⇒ h'(x) = f'(f(x))·f'(x)
⇒ h'(x)=f'(x3 + 3x + 2)·(3x2 + 3)
put x = 1
⇒ h'(1) = f'(6)·6
⇒ h'(1) = 111 × 6
⇒

6)

Also x sin πx –ve less than 1

f(x) = [x sin π x] = –1
Thus f(x) is constant function and equal to 0 in closed internal (–1, 1)
Constant function is continuous and differentiable in this internal
⇒ [–1, 1]

7) Question Explanation:
Solving First order higher degree differential equation.

Concept:
Solution of differential equation.

Solution:
x3y = C y = Cx2

Final Answer: Option(1,3,4)

8)
Clearly
⇒ Two circles intersect orthogonally.
Equation of common chord is S1 – S2 = 0
⇒ x + 2y – 4 = 0

Now C1 M =

∴ Length of common chord =

Clearly S1 (2, 3) > 0 and S2 (2, 3) > 0
So, the point (2, 3) lies outside the circles S1 & S2

Final Answer: The correct option is (1), (3) and (4).

9)

⇒C=0

∴
put 2x5 + 5x–2 = t2
⇒ (10x4 – 10x–3)dx = 2tdt

⇒ (x4 – x–3)dx =

10) Given limit

11)

Question Explanation: Evaluate a telescoping sum involving inverse tangent.

Concept: Telescoping Sum of Inverse Trigonometric Functions.

Solution:

Term setup: .

Summation: .

Simplifying sum: .
Final expression: .

Final Answer: 7

12)
using L'Hospital Rule
13) Question Explanation: Find the value of where n is the minimum number of roots of
the given differential expression.

Concept: Rolle's Theorem and Symmetry.

Solution:
ƒ(x) = ƒ(6 – x)
ƒ'(0) = ƒ'(2) = ƒ'(5) = 0
ƒ'(x) = –ƒ'(6 – x)
ƒ'(6) = ƒ'(4) = ƒ'(1) = 0 = ƒ'(3)
h(x) = ƒ"(x)2 + ƒ'(x)ƒ"'(x)

ƒ'(x) = 0 has 7 roots

ƒ"(x) = 0 has min of 6 roots
h(x) = 0 has min of 12 roots

Final Answer: 6

14)

Let
By Leibniz Rule:
...........(1)

For critical points, put :

Analyze sign change of F'(x) around critical points:

Note: is always , so the sign depends on (x – 1)(5x – 7).
- For x < 1 :

- For

- For (and ):
Since changes from positive to negative at x = 1 :
is a point of local maximum.

15)
ƒ(x) = x2sin2x + c
ƒ(π) = 0 ⇒ c = 0
ƒ(x) = x3sin2x
Number of solution of ƒ(x) = x3
⇒ x3sin2x = x3 ⇒ and sin2x = 1

⇒
Total = 3

16)
1 < 1 + x6 < 2 {x∈(0, 1)}

⇒
a

e0.707 < ea < e

2.027 < ea < 2.7

17)

Area

18) Question Explanation: We have to find |ab| where P(a, b) is radical center of given
circles.
Concept: Radical axis and radical center
Solution:
If tangents from a point to different circles are equal, then the point lies on the radical axis of
each pair of circles.
 Hence, the required point is the radical center of the three circles.
Given circles:

Radical axis of C1 and C2 :

Subtract C1 from C2 :
⇒
Radical axis of C1 and C3 :
Subtract C1 from C3 :

⇒
∴ Radical center is the Intersection point of radical axes:

Final Answer: 5

PART-2 : PHYSICS

19)

Magnetic field an axis of ring

For elemental ring

For elemental ring

20)

21)
45° > θC 45° ≤ θC
sin 45° > sin θC sin 45° ≤ sin θC

red green & blue

22) Ui =

Uf = , ΔU =
Qin = +Cε1, Qf = –Cε2, ΔQ =
= C(ε2 + ε1)
Work done by battery
Wb = ε2ΔQ = C(ε2 + ε1)ε2
Heat generated = Wb – ΔU

23)
2θ – T = 2T – 2θ

T=
and MASΔT = MB2SΔT

24) Lenz law

25) Magnetic field inside the cavity remains constant

26)

In steady state
Potential difference across 2mF capacitor = 1V
Charge on 2µF capacitor = 2µC
Charge on µF = Charge on 3µC= 0

27) Force on the charge = qE

As particle starts from rest, thus momentum will always increase

v = u + at =
∴ K.E. =

28)

Initially Req of circuit = =

(A) When 4Ω is shorted

Req = = = 1.48 Ω
Req circuit decrease so current through battery increase.
(B) Initially current through 5Ω is zero after short circuit to 4Ω, some current will pass through
5Ω
(C) If 5Ω is shorted, then there is no change in circuit.
(D) on shorted 3Ω, Req will decreases so current through battery will increase.

29)

30) ϕ = 4t2 × 2 × 2×10–4

e=

31) Total energy in the capacitor =

At any time t, energy stored in capacitor =

Thus energy dissipated in resistor =

= [τ = 9 µs]
At time 9 µs = τ,

Heat developed in capacitor =

=
∴η=3

32)

33) When rod is rotated by ,

FB =

Ny – mg – FB =

Ny = + FB + mg
= 0.1 × 15 × 1 + 0.1 × 15 × 1 + 1
= 4N

34) R = 2r sin θ
 35)

Use

36)

Electric field is increasing uniformly according to |E| = 1 + x

total flux = +E2A – E1A

= [(1 + x2) – (1 + x1)]A

= (x2 – x1)A = (10 cm) (100 cm2) = 10–3m3
Qenc = 10–3 ∈0 = 8.85 × 10–15 C

PART-3 : CHEMISTRY

37)

The correct answer is option (D)

38)

39)

40) State change from A to B, qAB = +5 J & WAB = –8J (work done by gas)
So ΔUAB = qAB + WAB = 5 – 8 = –3J
ΔUAB = –3J
Now gas is back brought to A from B
 qBA = –3J (Heat evolved)
wBA = ?
ΔUBA = –ΔUAB
qBA + wBA = – ΔUAB
–3J + wBA = –(–3J)
wBA = 6J (work done by surrounding)

41) Question Explanation: Identify the ores/compounds from which metal is extracted
commercially using the Carbon reduction method.

Concept: Carbon Reduction (Smelting).

Solution:
(A) Haematite ⇒ IRON ORE ⇒ carbon reduction
(B) cassiterite ⇒ TIN ORE ⇒ carbon reduction
(C) iron pyrite ⇒ Not Used for iron making due to High Sulphr Content
(D) corundum ⇒ Al2O3 Electrolytic Reduction (hall heroult process)

42) (C) is high spin complex

(D) 3 G.I., one optically active (cis-form)

43)

(A)

(B)

(C) + Enantiomer
(D)

44)

(A)

(B)

(C)

(D)

45)

The correct answer is option (A), (B), (D)

46)

At 30 hr, a – x = 4x ⇒ x = ,i.e. 20% A4 decomposed.

K × 30 = ⇒ t1/2 = ≈ 105 hr
47) SO2Cl2, SOCl2, P4O6, SF4, POCl3

48) Explain Question:

Count sulphide ores in the given list.

Concept:
Sulphide ores contain metal combined with sulfur (s)

Solution:
• Iron Pyrite → FeS2 → sulphide
• Chalcopyarite → CuFeS2 → sulphide
• Galena → PbS → sulphide
• Chalcocite → Cu2S → sulphide
• Magnetite → Fe3O4 → oxide
• Cinnabar → HgS → slphide
• Sphalerite → ZnS → sulphide
• Alumina → Al2O3 → oxide
• Siderite → FeCO3 → carbonate
• Calamine → ZnCO3 → carbonate
• Malachite → Cu2CO3(OH)2 → carbonate

49) x= 2, y = 2, z = 4.
n = 1, m = 2

50)

51)

, have 6 hyperconjugating structures

52) Question Explanation:

Question is asking about KP for first equilibrium , in atm2

Concept:
This question is based on simultaneous equilibrium.
Solution:
 PT = 10
5 – x + x + y + 2x – y + y = 10
y + 2x = 5 .......(i)
2x – y = 3 .....(ii)
y = 1, x = 2

Kp = =
Final Answer: 9

53)

54)

Keq =

At 500 K 106 = ⇒ Kb = 103

We know log Kb = log Ab –

3 = 11 –
(Ea)b = 8 × R × 500 × 2.303

log K250 – 3 = 8 × 500 ×

log K250 = –5
|log K250| = 5