21-06-2026

1001CJA101029260014 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) If and , then the value of is not equal to

(A) 2
(B) 4
(C) 6
(D) 8

2) If then which of the following is(are) true ?

(A) A is an invertible matrix

(B) trace (adj(adj A)) = 144
(C) trace (adj(adj A)) = 108
(D) |adj A| is less than 400

3) Let f(x) = x + and g(x) = – x, then

(A)
(B)
(C)
(D)

4) Let ƒ(x) = (x – 1) (x + 2) |(x + 2) (x – 3)| + sin|x + 2| + cos|x| – sgn|x|, then f(x) is non derivable at
x=?
(where sgn(.) denotes signum function)

(A) 1
(B) –2
(C) 3
(D) 0

5) Let A and B be two square matrix of order 3 then which of the following statement(s) is(are)
correct ?

(A) ABAT is a symmetric matrix.

(B) AB – BA is a skew symmetric matrix.
(C) If B = |A| A–1, |A| ≠ 0 then adj. (AT) – B is skew symmetric matrix.
(D) If B + AT = O and A is a skew symmetric matrix then B15 is also skew symmetric matrix.

SECTION-I (ii)

1)

List-I List-II

If |A| = 2, then |2A–1| is equal to

(P) (1) 1
(where A is a square matrix of order 3)

(Q) If , then |adj(adj2A)| is equal to (2) 4

(where A is a square matrix of order 3)

If (A + B)2 = A2 + B2 and |A| = 2, then |B| is

(R) equal to (where A & B are square matrices of (3) 8
odd order)

If (I – A)–1 = I + A + A2 + ... +A7 and An = O

(S) (4) 0
then n is (where A is a square matrix)

(5) 2
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 1;Q → 1;R → 4;S → 3

2)

List-I List-II

If y = 2x – 12 is normal to the parabola

(P) (1) 4
y2 = 4x at P(a, b) then (a + b) is

(Q) The equation of tangent of ellipse (2) 5

which cuts off equal intercepts on axes is x + y = p then p is

If a tangent of hyperbola xy = 1 cuts of intercept p1 on

(R) (3) 1
x-axis and p2 on y-axis then p1p2 is

Number of common tangents with positive slope for

(S) (4) 0
the curve and x2 – y2 = 1, is

(5) 2
(A) P → 4;Q → 2;R → 3;S → 5
(B) P → 5;Q → 2;R → 1;S → 3
(C) P → 2;Q → 3;R → 5;S → 4
(D) P → 4;Q → 2;R → 1;S → 3

3)

List-I List-II

If y(x) is the solution of the equation (x + 1) – xy = 1,

(P) (1) 0

y(0) = –1, then is

If (x2 + y2)dy = xydx and y(1) = 1, y(p) = e, then p4 = ke4,

(Q) (2) 1
where k is

(R) If xdy = y(dx + ydy), y > 0, y(1) = 1, y(q) = 2, then q is (3) 2

(S) (4) 4
If xdy + 2ydx = 0, y > 0; y(1) = 1, then is

(5) 9
(A) P → 3;Q → 2;R → 5;S → 4
(B) P → 4;Q → 2;R → 1;S → 2
(C) P → 3;Q → 5;R → 1;S → 4
(D) P → 4;Q → 2;R → 5;S → 3

SECTION-II (i)

Common Content for Question No. 1 to 2

Let A = and f(x) = x3 – 2x2 – ax + b. If A satisfies f(x) = 0, then

1) The value of (a + b + 6c) is

2) , is
(where [x] denotes greatest integer function)

Common Content for Question No. 3 to 4

Let P(x) be a polynomial of degree 3 satisfying P(–1) = 10, P(1) = –6 and P(x) has maxima at x = –1
and P ′ (x) has minima at x = 1, then

3) The absolute value of is -

4) The absolute value of is

Common Content for Question No. 5 to 6

Consider the following matrices

5) The value of det. (P + P2Q2 + P3 + P4Q4 + ...upto 100 terms) is equal to

6) If Q–1 = Q2 – αQ – I (where I is an identity matrix of order 3), then |α| equals

SECTION-II (ii)

1) If , where C is constant of integration and α, β >

0, then the value of |5(β – α)| is

2) Let A be a 3 × 2 matrix, B be a 2 × 3 matrix and C be a 3 × 4 matrix. How many of the following

matrix multiplications are defined ? (Where MT denotes the transpose of a matrix M)
(i) A B (ii) BA (iii) BTB
(iv) ATB (v) ATBT (vi) ABTC
T
(vii) ABC (viii) C A (ix) ATBTCT
(x) CTAB (xi) CB (xii) BTATC
(xiii) ATABBT (xiv) CTBTAT (xv) CTBT

3) Let f : [0, 2π) → R be given as f(x) = sinx ∀ , f(x) + f(π – x) = 2 ∀ and f(x) =
f(2π – x) ∀ x ∈ (π, 2π) and if the area bounded by curve y = f(x) and x-axis is kπ square units then k is

4) Number of 3 × 3 real matrices A = [aij] such that aij + aji = 0 for all i, j = 1, 2, 3 and |aij| ∈ {0, 1,
2, 3, 4, 5, 6, 7, 8, 9} is equal to

PART-2 : PHYSICS

SECTION-I (i)

1) Growth of current in two different L-R circuits are depicted by the i–t graphs shown. Angle
subtended by the curves with time axis at time t = 0 are also shown in the graph. τ1 and τ2 are time
constants for the circuits 1 and 2 respectively. Choose the correct alternative :-
(A)

(B)

(C) Initial rate of charging of capacitor for circuit-2 is 3 times that of circuit-1
(D) Initial rate of change of current for circuit-2 is 3 times that of circuit-1

2) A conducting loop is pulled with a constant velocity towards a region of uniform magnetic field of
induction B as shown in the figure. Then the current involved in the loop is (d > r)

(A) clockwise while entering

(B) anti-clockwise while entering
(C) zero when completely inside
(D) clockwise while leaving

3) A proton is moving in gravity free space having a uniform electric field, E, of unknown magnitude
and direction. There is a uniform magnetic field of 0.01 T pointing in the y-direction. The proton
moves in the x-direction at a constant velocity of 10 km/s. All directions are with respect to the usual
right handed x-y-z coordinate system. Which of the following is/are correct?

(A) Ez = 100 V/m

(B) Ez = –100 V/m
(C) Ex = 100 V/m
(D) Ex = 0

4) Charge is sprayed onto a large non conducting belt above the left hand roller. The belt carries
charge with a uniform surface charge density σ, as it moves with a speed v between the rollers as
shown. The charge is removed by a wiper at right hand roller. For a point just above the sheet mark
the correct option.

(A)
magnetic field is , out of the plane of the page, parallel to axis of roller.
(B) magnetic field is µ0σ, out of the plane of the page, perpendicular to axis

(C)
electric field is perpendicular to the plane of sheet
If an electron moves parallel to V just above the sheet it will experience an upward magnetic
(D)
force.

5) Figure shows the circuit diagram of a potentiometer apparatus. P is the point, where jockey would
touch potentiometer. (Length of potentiometer wire = 10 m, resistance of potentiometer wire = 450

Ω and 10V battery is ideal.)

(A) Potential gradient of potentiometer wire at null deflection would be 0.9 V/m.
(B) For any location of P, we can not have null deflection point.
(C) For a particular point P, current at point 1 can be made zero, but never at point 2.
(D) For P coinciding with B current at point 1 would be in vertically upwards direction.

SECTION-I (ii)

1) A conducting loop moves in xy-plane with velocity as shown. A uniform magnetic field exists
in whole region and a uniform magnetic field exists in addition for all x > 0. (At shown instant)
 List–I List–II

(P) , (1) potential

(Q) , (2) potential

(R) , (3) no induced current

(S) , (4) induced current flows from Q to P

(5) induced current flows from P to Q

(A) P → 1;Q → 3,1;R → 2;S → 3
(B) P → 2,3;Q → 1,3;R → 2,5;S → 1,4
(C) P → 2,3;Q → 3;R → 2;S → 5
(D) P → 1;Q → 2;R → 4;S → 5

2)

List-II (W is work
List-I (Pressure vs volume
done by gas, Q is heat
graph)
supplied to gas)

(P) (1) W > 0

(Q) (2) W < 0

(R) (3) Q > 0

 (S) (4) Q < 0

(5) ΔU = 0
(A) P → 1,2;Q → 3,4;R → 1,5;S → 3,4
(B) P → 1;Q → 3;R → 2;S → 4
(C) P → 1,3;Q → 2,4;R → 2,4,5;S → 1,3
(D) P → 2;Q → 4;R → 1;S → 3

3) The list-I is having the graph of either electrostatic field or its magnitude versus position on x-axis
and magnetic field or its magnitude versus position on the x-axis for the system indicated in list-II.

List-I List-II

(P) (1)
Two infinite wires kept parallel to z-axis carrying
current along +z-direction.

(Q) (2)
Two infinite wires are kept parallel to z-axis. One
carrying current in +z-direction, other carrying
current in –z-direction.

(R) (3)
Two point charges each of magnitude +Q
are kept at points (–a, 0) and (a, 0).

(S) (4)
Two point charges, +Q and –Q are kept at points
(–a, 0) and (a, 0) respectively

(5)
Two infinite non-conducting rods are
kept parallel to the y-axis, each carrying
uniform charge density +λ.
(A) P → 1,5;Q → 3;R → 4;S → 2,4
(B) P → 4;Q → 2;R → 1,3,5;S → 1,3,5
(C) P → 2;Q → 4;R → 2;S → 5
(D) P → 5;Q → 1;R → 2;S → 4

SECTION-II (i)

Common Content for Question No. 1 to 2

In space, magnetic field is everywhere ⊥ to plane of paper & directed away from the reader. The
magnetic field is B = αx, α = 0.2 T/m. A rectangular loop of side 0.2 m and 0.3 m is in xy plane and is
being pulled with a constant speed of 10 m/s as shown. Resistance of loop is 0.8 Ω.

1) The magnitude of induced current in the loop is ____A.

2) The rate at which work is done by the external agent is ______mW.

Common Content for Question No. 3 to 4

The capacitor 'C' is initially uncharged. Switch S1 is closed for a long time while S2 remains open.
Now at t = 0, S2 is closed while S1 is opened. All the batteries are ideal and connecting wires are

resistanceless. (R = 1000 ohm, E = 5 volts, C = 1000 microfarad)

3) Find the current (in mA) at time t = 0 (just after S2 is closed).

4) Find the heat developed till time t = 5 RC ln 2 in resistance 3R (in µJ).

Common Content for Question No. 5 to 6

Two particles are performing SHM on x-axis about same mean position with the amplitude A and

time period T. Position of those are given as and

5) Both particles meet at t = nT for the first time then n is.

6) First time when separation between two particles is maximum is mT then value of m is

SECTION-II (ii)

1) A capacitor of capacity is charged to a potential difference of 12 V. It is then connected

across an inductor of inductance 0.6 mH. What is the current (in A) in the circuit at a time when the
potential difference across the capacitor is 6.0 V ?

2) A wheel with six spokes is positioned perpendicular to a uniform magnetic field B of magnitude
0.5 T. The field is directed into the plane of the paper and is present over the entire region of the
wheel as shown in the figure. When the switch S is closed, there is an initial current of 6A between
the axle and the rim; and the wheel begins to rotate. The resistance of the spokes and of the rim is
negligible. The radius of the wheel is 0.2 m. Calculate the initial torque (in Nm) on the wheel.

3) An ac circuit is shown in figure. then what will be average power

dissipated, in Watt in the circuit.

4) A transverse traveling sinusoidal wave on a string has a frequency of 100 Hz and an amplitude of
2.0 mm. What is the maximum acceleration (in m/s2) of any point on the string? (Take π2 = 10)

PART-3 : CHEMISTRY

SECTION-I (i)

1) 2K2Cr2O7 2X + Y + Z
2KMnO4 P+Q+R
If order of molecular weight is X > Y > Z and P > Q > R, then which of the following statement is
CORRECT regarding above information

(A) Oxidation state of central metal atoms are same in X and P.

(B) Molecular weight of Z and R is same.
(C) Molecular weight of Q is greater than Y.
(D) The colour of Y and P almost same.

2) Select CORRECT statement about hydrolysis of BCl3 and NCl3

(A) NCl3 is hydrolysed and gives HOCl but BCl3 is not hydrolysed.
(B) Both NCl3 and BCl3 on hydrolysis gives HCl
(C) NCl3 on hydrolysis gives HOCl but BCl3 gives HCl
(D) Both NCl3 and BCl3 on hydrolysis gives HOCl

3) Choose the incorrect statement(s)-

– 2+
(A) 1 mole of MnO4 ion can oxidize 10 moles of Fe ion in acidic medium
2– 2+
(B) 1 mole of Cr2O7 ion can oxidize 12 moles of Fe ion in acidic medium
– 2+
(C) 2 mole of Cu2S can be oxidized by 2.6 moles of MnO4 ion in acidic medium (Cu2S→Cu + SO2)
2– 2+
(D) 2 mole of Cu2S can be oxidized by 8/3 moles of Cr2O7 ion in acidic medium (Cu2S→Cu + SO2)

4) 2,3-Dimethylbutane-2,3-diol
(P) should be -

(A) Ethaneamine
(B) Acetone
(C) Ethanal
(D) Ethanenitrile

5)
Which of the following is/are correct regarding product (P), (Q), (R), (S) and (T).

(A) Product Q also formed when P react with HBr/CCl4

(B) R is digrignard product.
(C) Product S is ethyne.
(D) Product T is ethanal.

SECTION-I (ii)

1) Match the reactions with the nature of process involved.

List-I List-II

(P) Cu2S → Cu (1) Calcination

(Q) CaCO3 → CaO (2) Carbon reduction

(R) Fe2O3 → Fe (3) Froth flotation

(S) Red Bauxite → [Al(OH)4]– (4) Leaching

(5) Self reduction

(A) P → 5;Q → 1;R → 2;S → 4
(B) P → 5;Q → 1;R → 4;S → 2
(C) P → 5;Q → 4;R → 1;S → 2
(D) P → 4;Q → 1;R → 5;S → 2

2)

List-I (mixing of volatile

liquid A and B List-II
respectively)

Acetone +
(P) (1) Volume contraction is zero
chloroform

Strong interaction between A and B

(Q) CCl4 + SiCl4 (2) in solution than interaction in pure A
& pure B liquids.

Observed vapour pressure >

(R) HCl + H2O (3) theoretical vapour pressure of
solution.

(S) CCl4 + CHCl3 (4) Forms maximum boiling azetrope

Neither heat absorbed nor heat

(5) evolved during mixing of liquids to
form solution.
(A) P → 2;Q → 1;R → 4;S → 5
(B) P → 4;Q → 5;R → 2;S → 3
(C) P → 2;Q → 3;R → 4;S → 5
(D) P → 4;Q → 1;R → 5;S → 3

3)

List-I List-II
(Compound/Functional (Properties/Test show by
group) compound )

(P) Ethyl alcohol (1) Gives NaHCO3 test positive

Gives CAN test (Cerric

(Q) Benzoic acid (2)
ammonium nitrate test) positive

+M showing group is present at

(R) Aniline (3)
benzene ring.

On reaction with NaOH + CaO/Δ

(S) Toluene (4)
Toluene is formed

+H showing group is present at

(5)
benzene ring.
(A) P → 2;Q → 3;R → 5;S → 4
(B) P → 2;Q → 3;R → 5;S → 1
(C) P → 2;Q → 1;R → 3;S → 5
(D) P → 2;Q → 1;R → 3;S → 4

SECTION-II (i)

Common Content for Question No. 1 to 2

The complex [Cr(NH3)6]+3 is a inner orbital complex with CFSE equal to –1.2Δ0. The Mn+2 and
Fe+2 form outer orbital complex with NH3 ligand then.

1) How many following statement(s) is/are correct for the complex [Cr(NH3)6]+3 ? (i) It is diamagnetic

with configuration
(ii) It is paramagnetic with configuration
(iii) It is paramagnetic with magnetic moment of order 4
(iv) It is an outer orbital complex
(v) It has d2sp3 hybridisation

2) How many following statement(s) is/are correct for octahedral complex of ammine of Fe(II) and
Fe(III)?
(i) Both Fe(II) and Fe(III) form outer orbital complex with NH3
(ii) Both form inner orbital complex with NH3
(iii) Fe(II) form outer while Fe(III) form inner orbital complex with NH3
(iv) Both are diamagnetic
(v) Both are paramagnetic

Common Content for Question No. 3 to 4

A sample of oxygen gas undergoes a cyclic process as shown on P-T diagram below. [Given : R =
25/3 J/mol-K, ln2 = 0.7, ln3 = 1.1]

3) Work done by the gas in complete cyclic process (in J/mol) is ______.

4) Molar heat (in kJ) required to change state A to B is ______.

Common Content for Question No. 5 to 6

An optically active bicyclic compound P (C10H16O having two six membered ring) contains a ketone
carbonyl group when P is treated with different reducing agents it gives different products
according to reagent nature.

5) Determine the total number of sp2 hybridised carbon atoms present in one molecule of compound
P.

6) Calculate degree of unsaturation of product Q (Alcohol) when compound P is reduced by NaBH4 in

CH3OH.

SECTION-II (ii)

1) The total number of correct statements from the following

(A) Cu+ ion disproportionates in to Cu+2 and Cu in H2O.
(B) The value of standard electrode potential for Ni is more negative than expected from the trend.
(C) Scandium is not a a transition element because it does not show variable oxidation states
(D) V2O5 reacts with alkalies as well as acids to give and respectively
(E) Green manganate is paramagnetic with one unpaired electron but the permanganate is
diamagnetic.
(F) First I.E order for 12th group is Zn > Hg > Cd

2) The rate constants for two parallel reactions were found to be 1.0 × 10–2 L mol–1 sec–1 and 3.0 ×
10–2 L mol– sec–1. If the corresponding energies of activation of parallel reaction are 60 kJ mol–1 and
70 kJ mol–1 respectively. The apparent overall activation energy of reactions is ______ kJ mol–1.

3) Consider the following data at constant pressure 1 atm and 27°C.

Heat of formation of CO2(g) = –393.0 kJ/mol
Heat of formation of H2O(ℓ) = –286.0 kJ/mol
Heat of combustion of C6H6(ℓ) = –3267 kJ/mol
Calculate molar heat of formation (in kJ mol–1) of C6H6(ℓ) at constant volume and 27°C.

Use : J/mole-K

4) The sum of total number of carbonyl groups (>C=O) present in the major products X and Y in the
following reactions is _______.
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4 5
A. A,C,D A,B,D A,C B,C,D C,D

SECTION-I (ii)

Q. 6 7 8
A. A D C

SECTION-II (i)

Q. 9 10 11 12 13 14
A. 30.00 12.00 8.50 2.40 0.00 1.00

SECTION-II (ii)

Q. 15 16 17 18
A. 5.00 11.00 2.00 6859.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22 23
A. B,D B,C,D B,D A,D A,C,D

SECTION-I (ii)

Q. 24 25 26
A. B C B

SECTION-II (i)

Q. 27 28 29 30 31 32
A. 0.15 18.00 1.00 5625.00 0.42 to 0.45 0.17 to 0.20

SECTION-II (ii)

Q. 33 34 35 36
A. 0.60 0.06 120.00 800.00

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 37 38 39 40 41
A. A,B,D C A,B,C D B,C,D

SECTION-I (ii)

Q. 42 43 44
A. A B C

SECTION-II (i)

Q. 45 46 47 48 49 50
A. 2.00 2.00 166.66 or 166.67 2.08 1.00 2.00

SECTION-II (ii)

Q. 51 52 53 54
A. 4.00 67.5 58.50 4.00
 SOLUTIONS

PART-1 : MATHEMATICS

1)

Using the property

⇒ I1 = I2

2)

|A| = 18

adj (adjA) = |A|n–2 A =

|adj A| = |A|n–1 = 182 = 324

3) Solution :

(A)

(D) DNE

(B)

(C)

Put x = –t ;

Final Answer : Option (A), (C)

4) f(x) is non-differentiable
at –2, 3 and 0

5)

(A) (ABAT)T = ABTAT which is not symmetric.

(B) (AB – BA)T = (AB)T – (BA)T = BTAT – ATBT
∴ AB – BA is not symmetric.
(C)
adj AT – B = adjAT – adj. (A) (∵ adj AT = (adj A)T)
((adj A)T – adj A)T = adj. A – (adj.A)T
∴ adj. (AT) – B is skew symmetric.
(D) B + AT = O and AT = –A
⇒B=A
B15 = A15, A is skew symmetric
∴ A15 is also skew symmetric.

6) (P) |A| = 2
(Q)

(C) (A + B)2 = A2 + B2
⇒ AB + BA = 0
⇒ |AB|=|–BA|= –|BA|= –|AB|
⇒ |AB| = 0
⇒ |B|= 0
(S) ⇒ (I – A)(I – A)–1
= (I – A)(I + A + A2 + ... + A7)
⇒ I = (I + A + A2 + ... + A7)
– A – A2 – A3 – ... – A8
= I – A8
∴ LHS = RHS, iff A8 = 0 ⇒ n = 8

7) (P) (am2, –2am)

(Q)

(R) tangent
x + yt2 = 2ct
y=0 x=0

p1 = 2ct p2 =
p1p2 = 4c2 = 4
(S) By Geometry

8) (P)
IF =

y(0) = –1 ⇒ c = 0
y(x + 1)e–x = –e–x
(Q) y = tx ⇒

If y = e ⇒
x4 = 9e4
ke4 = 9e4 ⇒ k = 9

(R)
y(1) = 1 c = –2

If y = 2 ⇒ , x=0

(S)

x2y = k

y(1) = 1 ⇒ k = 1 ⇒ x2y = 1 ⇒

9)

f(0) = 0 is the characteristic equation

⇒ |A – xI| = 0 ⇒ a = 14, b = 22, c = –1
Alternative : sum of roots = sum of diagonal elements and product of roots = value of the
determinant.

10)

f(x) = 0 is the characteristic equation

⇒ |A – xI| = 0 ⇒ a = 14, b = 22, c = –1
Alternative : sum of roots = sum of diagonal elements and product of roots = value of the
determinant.
11) P ″ (x) = a(x – 1)

P ′ (x) =

P ′ (1) = 0 ⇒ b =

∴ P ′ (x) =

P(x) =
P(–1) = 10 ⇒ 5a + 6c = 60
Given P(1) = –6
⇒ –11a + 6c = –36
∴ a = 6, c = 5
P(x) = x3 – 3x2 – 9x + 5 ⇒ P(2) = –17
P ′ (x) = 3x2 – 6x – 9 ⇒ P ′ (1) = –12

12) P ″ (x) = a(x – 1)

P ′ (x) =

P ′ (1) = 0 ⇒ b =

∴ P ′ (x) =

P(x) =
P(–1) = 10 ⇒ 5a + 6c = 60
Given P(1) = –6
⇒ –11a + 6c = –36
∴ a = 6, c = 5
P(x) = x3 – 3x2 – 9x + 5 ⇒ P(2) = –17
P ′ (x) = 3x2 – 6x – 9 ⇒ P ′ (1) = –12

13)

As, P2 = P and Q2 = I,
so det. (P + P2Q2 + P3 + P4Q4 +....upto 100 terms)
= det. (P + P + P + P +.... upto 100 terms)
= det. (100 P) = (102)3 det (P) = 0 [Given, P is a square matrix of order 3]
(As, |P| = 0)

14)

As Q2 = I ⇒ QQ = I ⇒ Q = Q–1
So, Q–1 = Q2 – αQ – I ⇒ Q = Q2 – αQ – I ⇒ (1 + α)Q = Q2 – I (As, Q2 = I)
 ⇒
∴ α = –1

15) x = t2

⇒ α = 2009, β = 2008.
Now check

16)

use the basic rule of multiplication of two matrices.

17)

Area =
= 1 + π – 1 + π – 1 + 1 = 2π sq. units

18) A is a skew symmetric matrix

∴ number of such matrix = 19 × 19 × 19 = 6859

PART-2 : PHYSICS

19) ,

I1 =

I2 =
20) By Lenz' law induced current will oppose change in flux.

21) =
E = VBsin90° = 104 × 10–2 = 100 V/m
along (–z) direction

22) Question Explanation:

A charged belt with surface charge density σ moves with speed v. It behaves like a current
sheet. We determine the magnetic field produced and the direction of force on an electron.
Concept:
A moving charged surface produces surface current .

Magnetic field of a current sheet: .

Magnetic force: .
Solution:
Surface current density:

Magnetic field:

The field is parallel to the roller axis (from right-hand rule).

Force on electron:

Using right-hand rule and considering negative charge, the force on the electron is upward.
Final Answer: Correct options: 1 and 4.

23) = 0.9 V/m

For secondary circuit, potential to be balanced is :

hence it can be balanced, but current at 2 will always flow.

24) Induced current is only due to component of fields along z-axis.

25) (A) volume increases so W > 0

PV product increases so temperature increases
ΔU > 0 so ΔQ > 0
(B) Volume decreases so W < 0
PV product decreases so temperature decreases
ΔU < 0 so ΔQ < 0
(C) Cycle is anticlockwise W < 0
Wcycle = Qcycle
(D) Isobaric process with increases in pressure
so W > 0 & Q > 0

26)

(P) Use right hand screw rule

(Q) Use right hand screw rule

(R) In right of +Q E = +ve

In left of + Q E = –ve

(S) No neutral point here

(T)
Best possible option (B).

27)
εnet = 0.6 α = 0.12

28) P = i2R = 0.152 × 0.8 = 225 × 8 × 10–5

= 1.8 × 10–2 J = 18 mJ

29) Correct answer is (1.00).

30)

equation of charge of capacitor

at t = 5 RC ℓn 2

31)

Phase travelled

32)

Phase travelled

time taken

33) C = 2μF
 q0 = 24µC, q = 12 µC

i=

i=

34)

35)

As
Given V0 = ,

= = 50

Also,

36) a = –ω2x
amax = –ω2A
= (2π × 100)2 × 2 × 10–3
= 80π2

PART-3 : CHEMISTRY

37)

X : K2CrO4, Y : Cr2O3, Z : O2
P : K2MnO4, Q : MnO2, R : O2

38)

Question Explanation: Comparison of hydrolysis products for BCl3 and NCl3.

Concept: Mechanism of Hydrolysis.
Solution: In BCl3, water attacks vacant p-orbitals of Boron producing HCl. In NCl3, water
attacks Cl (due to vacant d-orbitals on Cl and polarity) producing HOCl.
NCl3 + H2O → HOCl + NH3
BCl3 + H2O → B(OH)3 + HCl
Final Answer: NCl3 on hydrolysis gives HOCl but BCl3 gives HCl

39)

The correct answer is option (A), (B), (C)

40) The correct answer is option (D)

41)

42)

Cu2S → Cu : Self reduction

CaCO3 → CaO : Calcination
Fe2O3 → Fe : Carbon reduction
–
Red Bauxite → [Al(OH)4] : Leaching

43) (P) CH3COCH3 + CHCl3 (negative deviation) 2, 4

(Q) CCl4 + SiCl4 (ideal solution) 1, 5
(R) HCl + H2O (negative deviation) 2, 4
(S) CCl4 + CHCl3 (positive deviation) 3

44) The correct answer is option (C)

0 0 0 0

45) [Cr(NH3)6]+3 Cr+3 ⇒ [Ar]3d3 4s 4p 4d 4f ⇒

inner orbital complex with d2sp3 hybridisation
⇒ 3 unpaired e– = paramagnetic
⇒μ= = B.M.
46)

Explain Question:
Analyzing the nature of ammine complexes of Fe(II) and Fe(III).

Concept:
Crystal Field Theory (CFT).

Solution:
NH3 is a weak field ligand for Fe2+ but acts as a strong field ligand for Fe3+.
Fe2+ (d6) with NH3 forms a high-spin, outer orbital complex (sp3d2) and is paramagnetic (4
unpaired electrons).
Fe3+ (d5) with NH3 forms a low-spin, inner orbital complex (d2sp3) and is paramagnetic (1
unpaired electron).
Correct statements are: (iii) and (v).
Calculation:

Fe(II) : [Ar]3d6; NH3 (WFL) → (Paramagnetic, Outer orbital).

Fe(III) : [Ar]3d5; NH3 (SFL) → (Paramagnetic, Inner orbital).

Final Answer: 2.00

47) AB isochoric process WAB = 0

BC isothermal process WBC = –nRT ln = –1000 J/mol = –1 kJ

CA isobaric process WCA = –nRΔT = = 0.83 kJ

Wtotal = –0.166 kJ/mol

48) AB isochoric process qV = ΔU = nCV,mΔT = 1 × 2.5 × (400 – 300) = 2083.33 J = 2.08

kJ/mol

49) The correct answer is (1.00)

50) Possible structure of compound P = and

Both are optically active
DOU of P = 3
Number of sp2C ⇒ 1
 and

51)

The correct answer is (A), (B), (D), (E)

52) Ea = = 67.5 kJ mol–1

53)
ΔCH(C6H6) = 6 × ΔfH(CO6) + 3 × ΔfH(H2O) – ΔfH(C6H6)
–3267 = 6 × (–393) + 3 × (–286) – ΔfH(C6H6)
6C(s) + 3H2(g) → C6H6(ℓ)
ΔH = ΔU + Δn0RT

ΔU = 51 + 7.5 = 58.5 kJ/mole

54)