29-12-2025

2302CJA101001250048 JM

PART-1 : PHYSICS

SECTION-I

1) Three rods of the same dimension have thermal conductivities 3K, 2K and K. They are arranged as
shown in fig. Given below, with their ends at 100°C, 50°C and 20°C. The temperature of their

junction is :-

(A) 60° C
(B) 70° C
(C) 50° C
(D) 35° C

2)

A cylindrical metal rod of length L0 is shaped into a ring with a small gap as shown. On heating the
system

(A) x decreases, r and d increase

(B) x and r increase, d decreases
(C) x, r and d all increase
(D) Data insufficient to arrive at a conclusion

3) The density of water at 20ºC is 0.998 gm/cm3 and at 40ºC is 0.992 gm/cm3. The mean coefficient
of cubical expansion (in per ºC) is :-

(A) 1 × 10–4
(B) 2 × 10–4
(C) 3 × 10–4
(D) 6 × 10–4

4) A cylinder of radius R made of a material of thermal conductivity K1 is surrounded by a cylindrical

shell of inner radius R and outer radius 2R made of a material of thermal conductivity K2. The two
ends of the combined system are maintained at two different temperatures. There is no loss of heat
across the cylindrical surface and the system is in the steady state. The effective thermal
conductivity of the system will be :-

(A)

(B)

(C)

(D)

5) Two metallic blocks M1 and M2 of same area of cross-section are connected to each other (as
shown in figure). If the thermal conductivity of M2 is K then the thermal conductivity of M1 will be :

[Assume steady state heat conduction]

(A) 10 K
(B) 8 K
(C) 12.5 K
(D) 2 K

6) The plots of intensity versus wavelength for three black bodies at temperatures T1, T2 and T3

respectively are as shown. Their temperature are such that

(A) T1 >T2 > T3

(B) T1 >T3 > T2
(C) T2 >T3 > T1
(D) T3 >T2 > T1

7) The temperature of a body in air falls from 40°C to 24°C in 4 minutes. The temperature of the air
is 16°C. The temperature of the body in the next 4 minutes will be :

(A)
°C

(B)
°C

(C)
°C
(D)
°C

8) A closed vessel A having volume V contains N2 at pressure P and temperature T. Another closed
vessel B having the same volume V contains He at the same pressure P but temperature 2T. The
ratio of masses of N2 and He in the vessels A and B is :

(A) 1 : 2
(B) 3 : 2
(C) 5 : 2
(D) 14 : 1

9)

Two identical glass bulbs are interconnected by a thin glass tube. A gas is filled in these bulbs at
NTP. If one bulb is placed in ice and another bulb is placed inside hot bath, then the pressure of the
gas becomes 1.5 times. The temperature of hot bath will be

(A) 100°C
(B) 182°C
(C) 256°C
(D) 546°C

10) Three samples of the same gas A, B and C(γ = 3/2) have initially equal volume. Now the volume
of each sample is doubled. The process is adiabatic for A isobaric for B and isothermal for C. If the
final pressures are equal for all three samples, the ratio of their initial pressures are:-

(A)
(B)
(C)
(D)

11) An ideal gas is taken through the cycle A → B → C → A as shown in figure. If net heat supplied to

the gas in the cycle is +5J than work done during the process C → A is :-

(A) – 5 J
(B) – 10 J
(C) – 15 J
(D) – 20 J
12) 20 gm of water at 30°C is mixed with 5 gm of ice at –10°C. Find the final temperature of mixture
(in °C) if latent heat of fusion of ice is 80 cal/gm, specific heat of water = 1 cal/gm°C, specific heat of
ice = 0.5 cal/gm°C.

(A) 0°C
(B) –5°C
(C) 7°C
(D) 10°C

13) Water in a lake starts freezing at some time when the outside temperature –θ°C. The time taken
in freezing of initial x thickness of lake is 2 hrs. Then how much extra time it will take to freeze extra
2x thickness?

(A) 4 hrs
(B) 9 hrs
(C) 16 hrs
(D) 18 hrs

14) One mole of a gas expands with temperature according to the relation V = kT2/3, Calculate work
done when the temperature changes by 60 Κ.

(A) 10 R
(B) 30 R
(C) 40 R
(D) 20 R

15) One mole of an ideal gas is carried through a thermodynamic cycle as shown in the figure. The
cyclic process consists of an isochoric, an isothermal and an adiabatic process. Find adiabatic

coefficient of gas :

(A)

(B)

(C)

(D)

16) Heat energy of 735 J is given to a diatomic gas allowing the gas to expand at constant pressure.
Each gas molecule rotates around an internal axis but do not oscillate. The increase in the internal
energy of the gas will be:

(A) 525 J
(B) 441 J
(C) 572 J
(D) 735 J

17) A Polyatomic gas with six degrees of freedom does 75 J of work when it s expanded at constant
pressure. The heat given to the gas is -

(A) 400 J
(B) 500 J
(C) 100 J
(D) 300 J

18) A Carnot engine with efficiency 50% takes heat from a source at 600K. In order to increase the
efficiency to 70%, keeping the temperature of sink same, the new temperature of the source will be

(A) 300K
(B) 900K
(C) 1000K
(D) 360K

19) A hypothetical gas expands adiabatically such that its volume changes from 8 litres to 27 litres.

If the ratio of final pressure of the gas to initial pressure of the gas is , then the ratio of will
be:

(A)

(B)

(C)

(D)

20) The height at which the weight of a body becomes 1/9th its weight on the surface of earth (radius
of earth is R) :-

(A) h = 3R
(B) h = R
h=
(C)

(D) h = 2R

SECTION-II
1) A body weighs 63 N on the surface of the earth. What is the gravitational force on it due to the
earth at a height equal to half the radius of the earth ?

2) The internal energy of air in 4 m × 4 m × 3 m sized room at 1 atmospheric pressure will be ___ ×
106 J.
(Consider air as diatomic molecule)

3) 2 kg of ice at –20°C is mixed with 5 kg of water at 20°C in an insulating vessel having a negligible
heat capacity. Calculate the final mass of ice in the vessel :- (It is given that the specific heat of
water and ice are 1 kcal/kg-°C and 0.5 kcal/kg-°C respectively and the latent heat of fusion of ice is
80 kcal/kg)

4) Heat needed to convert 1 kilogram ice at 0°C to steam at 100°C is :-

5) The coefficient of thermal conductivity of copper is 9 times that of steel. In the composite
cylindrical bar shown in the figure, what will be the temperature at the junction of copper and

steel? (Ans in °C)

PART-2 : CHEMISTRY

SECTION-I

1) Which of the following is correct order of stability :-

(A) I > III > II > IV

(B) I > II > III > IV
(C) III > I > II > IV
(D) I > IV > III > II

2) Correct order of Acidic strength :

(A) C2H5OH < CH3COOH < C6H5OH

(B) C6H5OH < CH3COOH < C2H5OH
(C) CH3COOH < C6H5OH < C2H5OH
(D) C2H5OH < C6H5OH < CH3COOH

3)

Which carbocation is least stable ?

(A)

(B)

(C)

(D)

4) In which of the following more acidic compounds:-

(A)

(B)

(C)

(D)

5) In which of the following more basic compound :-

(A)

(B)

(C)

(D)

6) In which of the following compound least stable :-

(A)

(B)

(C)

(D)

7) Most acidic - hydrogen is :-

(A)

(B)
(C)

(D)

8) Acidic order is :-

(A) (B)

(C) (D)

(A) C > B > A > D

(B) B > C > A > D
(C) A > B > C > D
(D) D > A > C > B

9) The inductive effect :-

(A) Implies the atom's ability to cause bond polarization

(B) Increases with increase of distance
Implies the transfer of pair of electrons from more electronegative atom to the lesser
(C)
electronegative atom in a molecule
Implies the transfer of pair of electrons from lesser electronegative atom to the more
(D)
electronegative atom in a molecule

10) In which of the following more acidic hydrogen :-

(A) II
(B) I
(C) III
(D) I and II

11) Due to the presence of an unpaired electron, free radicals are:

(A) Chemically inactive, Diamagnetic
(B) Chemically reactive, Paramagnetic
(C) Chemical reactive, Diamagnetic
(D) Chemical inactive, Paramagnetic

12) Which of the following is most acidic compound.

(A)

(B)

(C)

(D) CH3–CH2–CH2–OH

13) Which of the following is most basic species.

(A)

(B)

(C)

(D)

14) Which of the following pairs of structures do not represent resonating structures ?

(A)

(B)

(C)

(D)

15) Which among the following compound is most basic ?

(A)
(B)

(C)

(D)

16) A free radical is not :-

(A) Contain even number of electrons

(B) long live species
(C) Diamagnetic
(D) all of these

17) When acetyl chloride and anhydrous aluminium chloride are used in Friedel Crafts acetylation
reaction, the electrophile is :-

(A)

(B)

(C)

(D)

18) The decreasing order of reactivity towards electrophilic substitution reaction of the following

compounds is

(A) 1 > 3 > 4 > 2

(B) 4 > 1 > 3 > 2
(C) 4 > 1 > 2 > 3
(D) 4 > 2 > 1 > 3

19) Which of the following compound will most easily be attacked by an electrophile?
(A)

(B)

(C)

(D)

20) In which of following Aromatic Ring is most activated for Aromatic electrophilic substitution.

(A)

(B)
(C)

(D)

SECTION-II

1) Find out the double bond equivalent (DBE) value of the given following compound:

2) Total number of electrophiles present in the following are :-

3) Consider the following groups

(a) How many groups can show –I effect

(b) How many groups can show –M effect
Find (a + b).

4) Sum of α-hydrogens in :
(i) + (ii) = ?

5) How many groups (attached with benzene ring) can show +M effect?

PART-3 : MATHEMATICS

SECTION-I

1) If the vertex of parabola is (2, 3) and directrix is 3x + 4y + 7 = 0 then the length of its latus
rectum is :-

(A) 5
(B) 10
(C) 20
(D) None

2) The latus rectum of the parabola whose focal chord is PSQ, such that PS = 3, QS = 2, S is focus, is
given by:-

(A)

(B)

(C)

(D) None of these

3) If (4, –8) is one end of focal chord of parabola y2 = 16x then equation of tangent at other end of
focal chord is

(A) y – x = 4
(B) x + y = 4
(C) x + y = 12
(D) y = 2x

4) The focal distance of a point on parabola y2 = 8x is 8, then the point may be :-

(A) (2, 4)

(B)

(C)

(D)

5) The normal at the point (at12, 2at1) on a parabola meets the parabola again in point (at22, 2at2)
then:-

t2 = t1 –
(A)

t2 = –t1 –
(B)

t2 = –t1 +
(C)

(D) None of these

6) The equation of parabola whose vertex is at (5, 4) and focus at (3, 4) is-

(A) y2 – 8y – 8x + 40 = 0
(B) y2 – 8y + 8x – 8 = 0
(C) y2 – 8y + 8x – 24 = 0
(D) None of these

7) The normal at the point P (ap2, 2ap) meets the parabola y2 = 4ax again at Q(aq2, 2aq) such that
the lines joining the origin to P and Q are at right angle. Then-

(A) p2 = 2
(B) q2 = 2
(C) p = 2q
(D) q = 2p

8) If the equation of the parabola, whose vertex is at (5, 4) and the directrix is 3x + y – 29 = 0, is x2
+ ay2 + bxy + cx + dy + k = 0 then
a + b + c +d + k is equal to

(A) 575
(B) –575
(C) 576
(D) –576

9) Equation of a common tangent to the circle, x2 + y2 – 6x = 0 and the parabola, y2 = 4x is :

(A)
(B)
(C)
(D)

10) The area (in square units) of an equilateral triangle inscribed in the parabola y2 = 8x, with one of
its vertices on the vertex of this parabola is :

(A)
(B)
(C)
(D)

11) If one end of a focal chord of the parabola, y2 = 16x is at (1, 4), then the length of this focal
chord is :

(A) 20
(B) 22
(C) 24
(D) 25

12) From the point (4, 6) a pair of tangent lines are drawn to the parabola, y2 = 8x. The area of the
triangle formed by these pair of tangent lines & the chord of contact of the point (4, 6) is :

(A) 2
(B) 4
(C) 8
(D) None of these

13) Length of the normal chord of the parabola, y2 = 4x, which makes an angle of with the axis of
x is :

(A) 8
(B)
(C) 4
(D)

14) The equations of the sides AB and AC of a triangle ABC are (λ + 1)x + λy = 4 and λx + (1 – λ)y +
λ = 0 respectively. Its vertex A is on the y-axis and its orthocentre is (1, 2). The length of the tangent
from the point C to the part of the parabola y2 = 6x in the first quadrant is :
(A) 2
(B) 4
(C)
(D)

15) If y = mx + 4 is a tangent to both the parabolas, y2 = 4x and x2 = 2by, then b is equal to :

(A) 128
(B) –64
(C) –128
(D) –32

16) The length of the latus rectum of the parabola 169 {(x + 1)2 + (y – 3)2} = (5x – 12y + 17)2 is

(A)

(B)

(C)

(D)

17) The equation of directrix of parabola x2 + 8y – 2x = 7 is :-

(A) y = –3
(B) y = 3
(C) x = –3
(D) x = 3

18) The equation of a parabola is

y2 + 8x – 12y + 20 = 0 then -

(A) its vertex is (2, 6)

(B) its focus is (1, 6)
(C) its latus rectum is 4
(D) None

19) The length of the chord intercepted by the parabola y2 = 4(x – 1) is

(A)

(B)

(C)

(D)
20) Let P be the point (1, 0) and Q a point on the locus y2 = 8x. The locus of mid point of PQ is

(A) y2 – 4x + 2 = 0
(B) y2 + 4x + 2 = 0
(C) x2 + 4y + 2 = 0
(D) x2 – 4y + 2 = 0

SECTION-II

1) If y = mx + 5 is a tangent to the parabola y2 = 4x, then find the value of 100m2.

2) The area of the triangle formed by the lines joining the vertex of the parabola x2 = 8y to the
extremities of its latus-rectum and latus-rectum is :

3) If the locus of vertices of the family of parabolas is xy = K, then the value of

64(K) is

4) In a parabola y2 = 18x, Equation of directrix is x = –k then '6k' is

5) Find the abscissa of the middle point of the chord of the parabola y2 = 16x, the equation of which
is
2x – 3y + 8 = 0
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C C B B B C D D B A C C C D A D C B D

SECTION-II

Q. 21 22 23 24 25
A. 28 12 1 716 75

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D D A A A C A A C B C A A A D B C D C

SECTION-II

Q. 46 47 48 49 50
A. 11 3 6 15 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B A D B C A D A B D A B C C D B A B A

SECTION-II

Q. 71 72 73 74 75
A. 4 8 105 27 14
 SOLUTIONS

PART-1 : PHYSICS

1)

Let the temperature of junction be θ then according to the following figure.

H = H 1 + H2

⇒ 300 – 3θ = 3θ – 120 ⇒ θ = 70°C

2) On heating the system; x, r, d all increases, since the expansion of isotropic solids is similar
to true photographic enlargement.

3)

ρ2 – ρ1 = (t2 – t1) ρ1γ

γ=

4)

The two cylinders are in parallel. Therefore, equivalent thermal resistance is given by

where and
Here, l1 = l2 = l, A1 πr ;
2

A2 = π[(2R)2 – R2] = 3πR2

and A = π(2R)2 = 4πR2

5)
6) According to Wien's law and from the
figure therefore T1 > T3 > T2.

7)
T1 = 24°C; T2 = 40°C, t = 4, TS = 16°C

Now

24 – T =

8) For N2 :

For He :

9)

Quantity of gas in these bulbs is constant, i.e, initial no. of moles in both the bulbs = final
number of moles.

10) Let the initial pressure of the three samples be

and , then , and
⇒

11) dQ = dU + dW
5 = Q + WAB + WBC + WCA
 5 = (2 – 1) + 0 + WCA
WCA = – 5 Joule

12) Let final temparature be T °C

20 × 1 × (30–T) = 5 ×1/2 × 10 + 5 × 80 + 5 × 1 × (T-0)
600 – 20T = 25 + 400 + 5T
T = 7°C

13) time taken in freezing

x1 x2 time

0 x t = 2 hr

X x + 2x = 3x t'

14)

15) BC :
P0V0 = 3P0V1

V1 =
AC :

3γ = 6
γℓn 3 = ℓn 6

16)
Given, Q = 735 J
Process is isobaric process.
So, ....(i)
Change in internal energy
...(ii)
Dividing equation (i) by (ii), we get

(diatomic gas)

17)

ΔQ = dv + dw
Δw = PΔv = nRΔT
For one mole Δw = RΔT = 75J

and dv =
here n = 1 F = 6
dv = 3RΔT
dv = 3 × 75 = 225
ΔQ = 225 + 75 = 300J

18)

Efficiency of carnot engine =

In first case

In second case

19)

V1 = 8L, V2 = 27L,
In adiabatic process,
PV = constant
20) g' = , g' =

1+ =3
h = 2R

21) Weight of the body, W = 63 N

Acceleration due to gravity at height h from the Earth's surface is given by the relation:

g' =
where
g = Acceleration due to gravity on the Earth's surface
Re = Radius of the Earth

For h =

g' =
Weight of a body of mass m at height h is given as :

W' = mg = = =

= = 28 N

22) To find the internal energy of gas in the room.

23) Heat gained = Heat lost

Let m kg ice melts into water
m × 80 + 2 × 0.5 × [0 – (–20)]
= 5 × 1 × [20 – 0]
80 + 20 = 100

ice
Thus, final mass of water
 = 5 + 1 = 6 kg

24) Heat required to melt 1 kg ice into water at

0°C = 80 kcal
Heat required to raise temperature of 1 kg water from 0°C to 100°C
= mS.Δt = (1 kg) × (1 kcal/kg°C) × (100 – 0)
= 100 kcal
Heat required to convert 1 kg boiling water into steam at 100°C
= mL = 1 kg × 536 kcal/kg
= 536 kcal
Thus, total heat required to convert 1 kg of ice at 0°C into steam at 100°C
= 80 + 100 + 536 = 716 kcal

25)

Temperature of interface,

Given, KCu = 9Ks, so

if Ks = K1 = K, then KCu = K2 = 9K

PART-2 : CHEMISTRY

26) Stability of carbocation ∝ + m1 + I1 + h ∝

27)

28) → Bridgehead carbocation is unstable

29)
30) More basic because ℓ.p. is localised.

31) Anti-Aromatic least stable.

32)

33) Acidic strength α stability of conjugate base

34) Inductive effect is polarization of 6 electron due to difference of electronegative.

35)

36) Stability of carbocation

> > >

37) Acidic nature stability of conjugate base of the compound.

Stability order of conjugate base.
38) The E.N. of carbon are less among these species so more basic.

39)
These are tautomers. Because the change in the position of proton (H+) & electron so it is not a
pair of resonating structure.

40)

41)

Theory Based

42) Friedel Crafts acetylation reaction

electrophile =

43) –CH3 is electron donating group, shown + I effect.

–NO2 is electron withdrawing group as well as shown – M effect.
– Cl shows –I effect and is a weak deactivating group so the order of reactivity towards
electrophilic substitution reaction is
 44) Higher the electron density in the benzene ring more easily it will be attacked by an
electrophile. Phenol has the highest electron density amongst all the given compound.

45) Conceptual

46) The double bond equivalent (DBE) value of the given compounds is 11.

47) are electrophiles.

48) 4 + 2 = 6

49)
Total = 10 + 5 = 15

50)

(i), (ii), (iv) and (vi)

PART-3 : MATHEMATICS

51) Here

52)

53)

Method-1
As AB is focal chord
t1t2 = –1
2
(at1 , 2at1) ≡ (4, – 8)

2at1 = –8 ⇒ t1 =
t1 = –1
So t2 = +1
⇒ (at22, 2at2) = (4(1)2, 2 × 4 × (1)) = (4, +8)
tangent at B:
(+8)y = 8(x + 4)
y=x+4
Method-2
When we draw the graph of following parabola. We can see that the point A(4, –8) is one end
of latus rectum.
So the other end of this focal chord will be other end of latus rectum, which is B(4, 8)
Equation of tangent at B(4, 8) is

(8)y = 8(x + y)
y=x+4

54) Here x1 + a = 8
⇒ x1 = 6 ( a = 2)
⇒ Points may be (6, 4 ) and (6, –4 )

55) Standard result

56) eqn of parabola is

(y–4)2 = –8(x–5)
y2 + 16 – 8y = –8x + 40
y2 + 8x – 8y – 24 = 0

57) Normal at point P(ap2, 2ap) meets again parabola at Q (aq2, 2aq)

∴ q = –p –
⇒ pq = –p2–2 …(1)
∴ Normal chord subtend right angle at origin
∴ pq = –4 from eqn (1)
p2 = 2
58) Vertex (5,4)
Directrix : 3x + y – 29 = 0
Co-ordinates of B (foot of directrix)

x = 8, y = 5
S = (2, 3) (focus)
Equation of parabola
PS = PM
so equation is
x2 + 9y2 – 6xy + 134x – 2y – 711 = 0
a+b+c+d+k
= 9 – 6 + 134 – 2 – 711 = – 576

59) (Reference to Allen Module)

Equation of tangent to y2 = 4x is y = mx + 1/m ... (i)
(i) is a tangent to x2 + y2 – 6x = 0

Equation of tangents are

and

60) (Reference to Allen Module)

Length of side of equilateral triangle inscribed in a parabola

61) (Reference to Allen Module)

Given parabola: y2 = 16x
One end of focal chord: (1, 4)
t = 1/2
Length of focal chord
62) y2 = 8x ...(1)
Equation chord of contact from R on y2 = 8x
6y = 4(x + 4)
3y = 2x + 8 ...(2)
Solving (1) & (2)

we have
y2 – 12y + 32 = 0
(y – 8) (y – 4) = 0
y = 4, 8

comospandingly & 8 respective

so coordinate of P & Q are

so are at are

63) Equation of normal which makes an angle with x-axis.

y = mx – 2am – am3
here a = 1 & m = 1
So equation of normal is
y=x–2–1
y=x–3 ...(1)
2
Solve (1) with y = 4x we get
(x – 3)2 = 4x

(x – 1) (x – 9) = 0
So point of contact arc
(1. –2) (9, 6)
So distance between point

Option (B) is correct.

64)

65) y = mx + 4 is tangent to y2 = 4x

⇒ m=

is tangent to x2 = 2by

⇒
⇒ D=0
b2 + 128b = 0
⇒ b = – 128, 0
b ≠ 0 ⇒ b = –128

66)

Given parabola is

By definition of parabola
Focus : (–1, 3)
Directrix : 5x – 12y + 17 = 0
LR = 4a = 2 (2a)
= 2 (distance of focus from directrix)

67) Given parabola is (x – 1)2 = –8(y – 1)

compare with x2 = –4AY ⇒ A = 2
its directrix is Y = A ⇒ y – 1 = 2

68) Given parabola is (y – 6)2 = – 8 (x – 2)

Compare it with Y2 = – 4AX
⇒ vertex is (2, 6), focus is (0, 6)
and L.R. = 8

69) y = (x – 2) passes through the focus of y2 = 4(x – 1)

i.e. (2, 0). So length of focal chord
= 4acosec2α = 4 × 1 × cosec260°

70)

Given P = (1, 0), let Q = (h, k)

Since Q lies on y2 = 8x
∴ K2 = 8h ...(i)
Let (α, β) be the midpoint of PQ

∴α=
2α – 1 = h 2β = k.
Putting value of h and k in (i)
(2b2) = 8(2α – 1) ⇒ β2 = 4α – 2
⇒ y2 – 4x + 2 = 0.

71) is tangent to y2 = 4x

72)
x2 = 4(2)y

Area of
=8
73) Equation of the parabola is

where vertex is

So,

74)

75)

Let P(h, k) is middle point of chord using T = S1, equation of chord is

ky – 8(x + h) = k2 – 16h

Comparing with given equation 2x – 3y + 8 = 0