01-06-2025

1001CTM404021250006 TM

Physics

1) A particle is moving along x axis with constant acceleration. At t = 0 sec, the particle is at x = 3 m

and = + 4 m/s. The maximum value of x coordinate of the particle is observed 2 sec later.
Starting from t = 0 sec after what time particle reaches its initial position again

(1) 4 sec
(2) 6 sec
(3) 8 sec
(4) 12 sec

2) A ball is thrown upwards from the ground. It crosses a point at a height of 25 m twice at an
interval of 4 secs. The ball was thrown with the velocity of :-

(1) 20 m/sec
(2) 25 m/sec
(3) 30 m/sec
(4) 35 m/sec

3) As shown velocity and acceleration of both block find minimum separation of each block :-

(1) 5
(2) 10
(3) 0
(4) 12.5

4) A particle is moving along a straight line whose velocity-displacement graph is as shown in figure

: A tangent is drawn at point P on the graph. At the point P

(1) the particle is speeding up
(2) numerical value of velocity and acceleration of the particle are equal
(3) numerical value of velocity is more than the numerical value of acceleration of the particle
(4) numerical value of acceleration is more than the numerical value of velocity of the particle

5) A hot air balloon rising with constant acceleration 2m/s2. A person drop the some particle after
regular time interval of 2 sec. Then find distance between 1st & 3rd particle after 5th particle is
dropped.

(1) 328 m
(2) 32 m
(3) 288 m
(4) 248 m

6) A lift A is accelerating vertically upwards with acceleration 5 m/s2 and another lift B is
accelerating downwards with acceleration 5 m/s2. A coin is released from rest (with respect to lift)
from some height in lift A. At that instant velocity of lift A is 8 m/s vertically upwards & velocity of
lift B is 12 m/s vertically downwards. Then velocity & acceleration of coin with respect to lift B at
that instant will be respectively :-

(1) 20 m/s, 20 m/s2

(2) 4 m/s, 15 m/s2
(3) 4 m/s, 5 m/s2
(4) 20 m/s, 5 m/s2

7) The position time graph for two particles P and Q moving in x-direction is shown in figure. Choose

the incorrect alternative.

(1) Initially particle Q leads from a particle P

(2) At time t0 particle P overtakes particle Q.
(3) At time t0 particle Q overtakes particle P.
(4) There is an instant where the distance between the two neither increasing nor decreasing

8) If a particle moves along a straight line according to the law v=2 (x sinx + cos x) then find its

acceleration (i.e. ) at x= π/2:-

(1)

(2)

(3)
(4) zero

9) An aircraft takes off from a horizontal runway with constant speed v, climbing at a constant angle
α to the horizontal. A car is moving on the runway with constant speed u directly towards the front
of the aircraft. The car is distance a from the aircraft at the instant of take-off. Find the distance of
closest approach of the car and aircraft.

(1)

(2)

(3)

(4) None

10) Two stones are thrown up simultaneously from the edge of a cliff 240 m high with initial speed of
10 m/s and 40 m/s respectively. Which of the following graph best represents the time variation of
relative position of the second stone with respect to the first? (Assume stones do not rebound after
hitting the ground neglect air resistance, take g = 10 m/s2) (The figure are schematic and not drawn
to scale)

(1)

(2)

(3)
(4)

11) A particle is thrown vertically upwards from the surface of the earth. Let TP be the time taken by
the particle to travel from a point P above the earth to its highest point and back to the point P.
Similarly, let TQ be the time taken by the particle to travel from another point Q above the earth to
its highest point and back to the same point Q. If the distance between the points P and Q is H, the
expression for acceleration due to gravity in terms of TP, TQ and H, is :-

(1)

(2)

(3)

(4)

12) A particle moves on a straight line, with uniform acceleration –5 m/s2. Distance travelled by it in
three consecutive intervals of 1s are in ratio of 3 : 1 : 1. Then the total distance travelled in three
seconds is :

(1) 25 m
(2) 12.5 m
(3) 22.5 m
(4) 20 m

13)

A particle moves m in South–West direction, 12m in upward direction and then 1m in East
direction. Find the net displacement.

(1) 13 m
(2) 17 m
(3) 14 m
(4) 18 m

14) A particle is moving along a curved path with constant speed then :

(1) Velocity of particle is constant

(2) Acceleration of particle is zero.
(3) Acceleration of particle is non-zero.
(4) None of these.

15) You throw a ball upward in the presence of uniform gravity. After half of the time to reach the
highest point, the ball has covered :-

(1) half the distance to the top

(2) more than half the distance
(3) less than half the distance
(4) it depends on how fast you throw the ball.

16) A ball is thrown vertically upward. Which of the graph represent speed-time graph of ball during
its flight (air resistance neglected) :

(1)

(2)

(3)

(4)

17) A car travels 30 km at a uniform speed of 40km/h and the next 30 km at a uniform speed of 20
km/h. Find its average speed (in km/hr).

(1)

(2)

(3)

(4)
18) Which of the following x–t graphs represent a constant velocity motion?

(1)

(2)

(3)

(4)

19) A particle is projected vertically upwards from a point A on the ground. It takes t1 time to reach
a point B but it still continues to move up. If it takes further t2 time to reach the ground from point B
then height of point B from the ground is :

(1)

(2) gt1t2

(3)
(4)

20) A motor car covers part of total distance with v1 = 10 km/hr, second part with v2 = 20

kh/hr and rest part with v3 = 60 km/hr. What is the average speed of the car ?

(1) 18 km/hr
(2) 45 km/hr
(3) 6 km/hr
(4) 22.5 km/hr

21) Three small snails are each at a vertex of an equilateral triangle of side 60 cm. The first sets out
towards the second, the second towards the third and the third towards the first, with a uniform
speed of 5 cm min–1. During their motion each of them always heads towards its respective target
snail. If snails are considered as point mass how many times does each snail circle their ultimate
meeting point.

(1) 10
(2) 8
(3) 12
(4) none of these

22) A proton moves along the x-axis according to the equation , where x is in metres
and t is in seconds. Calculate the average velocity of the proton during the first 3.0 s of its motion.

(1) 40 m/s
(2) 80 m/s
(3) 20 m/s
(4) none of these

23) Two bodies are projected vertically upwards from one point with the same initial velocities v0,
the second τ sec after the first. How long after will the bodies meet?

(1)

(2)

(3)

(4) none of these

24) A particle moves a distance x in time t according to equation x = (t + 5)–1. The acceleration of the
particle is proportional to :

(1) (velocity)3/2
(2) (distance)2
(3) (distance)–2
(4) (velocity)2/3

25)

A particle starts from rest (at x = 0) when an acceleration is applied to it. The acceleration of the
particle changes with its co-ordinate as shown in the fig. Find the speed of the particle at x = 10m.

(1) 12 m/s
(2) 24 m/s
(3) 72 m/s
(4) none of these

26) The velocity time graph for two particles (1 and 2) moving along X axis is shown in fig. At time t
= 0, both were at origin.
During first 4 second of motion what is maximum separation between the particles?

(1) 8 m
(2) 10 m
(3) 4 m
(4) none of these

27) A person stands in an elevator. Starting at rest at t = 0 the elevator moves upwards, coming to
rest again at time t = t0. The acceleration of the elevator during this period is shown graphically

0
below. The total distance traveled by the elevator is s . The value of is.
(1) 4
(2) 6
(3) 9
(4) 8

28) There is an inclined surface of inclination θ. A smooth groove is cut into it forming an angle α
with AB as shown in figure. A steel ball is free to slide along the groove. If the ball is released from

the point O. Find the speed when it comes to A.

(1)
(2)

(3)

(4)

29) In a car race, car A takes time 't0' less than the car B and passes the finishing point with a
velocity 'v' more than the velocity with which the car B passes the point. Assuming that the cars
start from rest travels with constant accelerations a1 and a2, then :

(1)
(2) v = (2a1 + a2)t0
(3)
(4) None of these

30) A particle 'A' starts moving from point A with constant velocity 4 m/s along x-axis. Another
particle 'B' initially at rest starts moving along x-axis after (8/3) sec after the start of A, with
acceleration varying as a = 4(3 – t) m/s2. Based on the above information, answer the following
questions.
Magnitude of the relative velocity of the two particles when they meet for the first time is :

(1) 16 m/s
(2) 12 m/s
(3) 20 m/s
(4) 18 m/s

Chemistry

1) An oxidising agent react completely with 100 ml of acidified 0.1M KI (aq.) then for which of the
following oxidising agent, moles used will be least -

(1) KMnO4
(2) K2Cr2O7
(3) MnO2
(4) KIO3

2) aMnO4– + bI– + cH+ → dMn2+ + eI2 + fH2O

In above balanced reaction value of will be

(1) 1.3
(2) 1.2
(3) 8
(4) 5

3)

Equivalent weight of H2SO4 in the following reaction

Pb(s) + PbO2(s) + H2SO4 → PbSO4 + H2O is -

(1) 98
(2) 49
(3) 196
(4) 80

4) When a hydrocarbon A undergoes combustion in the presence of air, it requires 9.5 equivalents of
oxygen and produces 3 equivalents of water. What is the molecular formula of A?

(1) C8H6
(2) C9H9
(3) C6H6
(4) C9H6

5) A mixture of NaHC2O4 and KHC2O4. H2C2O4 required equal volumes of 0.2 N KMnO4 and 0.12 N
NaOH separately. What is the molar ratio of NaHC2O4 and KHC2O4. H2C2O4 in the mixture?
(1) 6 : 1
(2) 3 : 1
(3) 1 : 3
(4) None

6) Match the column.

(1) P–4, 5; Q–2; R–1; S– 3

(2) P–1, 5; Q–1; R–3; S– 4
(3) P–4, 5; Q–1; R–1; S– 4
(4) P–4, 5; Q–2; R–1; S–3

7) (A) HOCl + H2O2 → H3O+ + Cl– + O2

(B) I2 + H2O2 + 2OH– → 2I– + 2H2O + O2
Choose the correct option.

(1) H2O2 acts as reducing and oxidising agent respectively in equation (A) and (B)
(2) H2O2 acts as oxidising agent in equation (A) and (B)
(3) H2O2 acts as reducing agent in equation (A) and (B)
(4) H2O2 act as oxidizing and reducing agent respectively in equation (A) and (B)

8) How many mililiters of 0.1 M H2SO4 must be added to 50 ml of 0.1 M NaOH to give a solution that
has a concentration of 0.05 M in H2SO4.

(1) 40 ml
(2) 50 ml
(3) 200 ml
(4) 100 ml

9) H2O2 oxidises MnO2 to in basic medium. H2O2 and MnO2 react in the molar ratio of (H2O2 is
reduced into H2O):-

(1) 1 : 1
(2) 2 : 3
(3) 2 : 1
(4) 3 : 2

10) What volume of 0.2N KMnO4 solution is needed for complete reaction with 6.64 g Fe0.9O1.0, in
acidic medium ? (Fe = 56)

(1) 280 ml

(2)

(3)

(4) 350 ml

11) One gram of commercial AgNO3 is dissolved in 50 mL of water. It is treated with 50 mL of a KI

solution. The silver iodide thus precipitated is filtered off. Excess of KI in the filtrate is titrated with
M/10 KIO3solution in presence of 6 M HC1 till all I– ions are converted into ICI. It requires 50 mL of
M/10 KIO3 solution. Twenty milliliters of the same stock solution of KI requires 30 mL of M/10 KIO3
under similar conditions. The percentage of AgNO3 in the sample is

(1) 85
(2) 80
(3) 75
(4) 90

12) The oxidation number of sulphur in S8, S2F2 and H2S respectively are :

(1) 0, + 1 and – 2
(2) + 2, + 1 and – 2
(3) 0, + 1 and + 2
(4) – 2, + 1 and – 2

13) ions are reduced in acidic condition to Mn2+ ions whereas they are reduced in neutral
condition to MnO2. The oxidation of 25 ml of a solution X containing Fe2+ ions required in acidic
condition 20 ml of a solution Y containing ions. What volume of solution Y would be required
2+
to oxidize 25 ml of solution X containing Fe ions in neutral condition?

(1) 10.4 ml
(2) 12.89 ml
(3) 33.3 ml
(4) 23.9 ml

14) A mixture of 0.02 mole of KBrO3 and 0.01 mole of KBr was treated with excess of KI and
acidified. The volume of 0.1 M Na2S2O3 solution required to consume the liberated iodine will be :
BrO3– + I– → Br– + I2

(1) 1000 mL
(2) 1200 mL
(3) 1500 mL
(4) 800 mL

15) Dichloroacetic acid (CHCl2COOH) is oxidised to CO2, H2O and Cl2 by 600 meq of an oxidising
agent. Same amount of acid can neutralize how many moles of ammonia to form ammonium
dichloroacetate :

(1) 0.0167
(2) 0.1
(3) 0.3
(4) 0.6

16) Percentage loss in mass on heating mixture of Na2CO3 & CaCO3 containing equal mass of the two
components will be

(1) 44%
(2) 22%
(3) 35%
(4) 50%

17) A given initial mass of KClO3 on 50% decomposition produces 67.2 litre oxygen gas at 0°C and 1
atm. The other product of decomposition is KCl. The initial mass of KClO3 (in gm) taken is.

(1) 245
(2) 122.5
(3) 490
(4) None of these

18) The conversion of oxygen to ozone 3O2 → 2O3 occurs to the extent of 15% only. The mass of
ozone that can be prepared from 67.2 L of oxygen at S.T.P. will be -

(1) 14.4 gm
(2) 96 gm
(3) 640 gm
(4) 64 gm

19) In the reaction

xHI + yHNO3 —→ NO + I2 + H2O

(1) x = 3, y = 2
(2) x = 2, y = 3
(3) x = 6, y = 2
(4) x = 6, y = 1

20) 17 g AgNO3(aq) mixed with 58.5 g NaCl(aq) to form AgCl (white ppt). The mass of AgCl which
can be obtained through this reaction is
Given : (Atomic mass of Ag = 108)

(1) 14.35g
(2) 0.1435g
(3) 1.435g
(4) 5.85g

21) Iodobenzene is prepared from aniline (C6H5NH2) in a two step process as shown here.

In an actual preparation, 9.30 g of aniline was converted to 16.32 g of iodobenzene. The percentage
yield of iodobenzene is (I = 127)

(1) 8%
(2) 50%
(3) 75%
(4) 80%

22) One litre of an acidified solution of KMnO4 containing 15.8 g of KMnO4 is decolourised by
passing sufficient amount of SO2. If SO2 is produced by roasting of iron pyrites (FeS2), what will be
the amount of pyrites required to produce the necessary amount of SO2? The reaction involved are -
(Atomic mass, K = 39, Mn = 55)

(1) 10 g
(2) 12 g
(3) 15 g
(4) 17 g

23) For the given series of reaction at constant temperature and pressure, NH3(g) + O2(g) →
NO(g) + H2O(ℓ)
NO(g) + O2(g) → NO2(g)
If 100 ml of NH3 is sparked with 300 ml of O2 then volume contraction after the reactions will be :

(1) 150 ml
(2) 125 ml
(3) 175 ml
(4) None of these

24) 64 g of a mixture of NaCl and KCl were treated with concentrated sulphuric acid. The total mass
of metal sulphates obtained was found to be 76 g. What are the mass percent of NaCl in the mixture.
The reactions are,
2 NaCl + H2SO4 —→ Na2SO4 + 2 HCl ;
2 KCl + H2SO4 —→ K2SO4 + 2 HCl
(1) 42.89 % NaCl
(2) 84.9 % NaCl
(3) 31.5 % NaCl
(4) 63.1 % NaCl

25) An unknown gaseous hydrocarbon and oxygen gas are mixed in volume ratio 1 : 7 and exploded.
The resulting mixture upon cooling occupied a volume of V mL, half of which got absorbed in aq.
KOH (absorbs CO2) and the remaining half was absorbed in alkaline pyrogallol solution (absorbs O2).
Assuming all volumes to be measured under identical conditions :

(1) The molecular formula of hydrocarbon can be C2H6

(2) The resulting mixture obtained after cooling contains 50% O2 and 50% CO by mole.
(3) The molecular formula of hydrocarbon can be C3H4
(4) Molecular mass of hydrocarbon is definitely less than 28 u.

26) A hydrocarbon CxH12(g) and O2(g) were taken in a closed rigid flask at 400K. When sparked they
reacted to form CO2(g) and H2O(g) and no reactants left after the reaction. The pressure in the flask
is increased by 20%. The value of 'x' is :

(1) 5
(2) 6
(3) 12
(4) None of these

27) Molarity and molality of pure CH3COOH are respectively.

(1) 16.67 , 25
(2) 25 , 16.67
(3) 50 , 33.3
(4) 25 both

28) If excess water is added into a bottle sample labelled as “112% oleum” and is reacted with 1.06
gm Na2CO3, then find the volume of CO2 evolved at 1 atm and 300 K temperature after completion
of the reaction. [Assume oleum to be in excess]

(1) 12.3 L
(2) 0.246 L
(3) 24.6 L
(4) 2.46 L

29) Three samples of H2O2 which are labeled as 10 vol., 20 vol. and 30 vol. are mixed by taking 100
ml of each and the mixture is diluted to 1000 ml. The molar concentration of the resultant solution is
: [Consider vol. strength at STP]

(1) 0.893 M
(2) 0.53 M
(3) 11.2 M
(4) 1.0 M

30) 100 ml of 2.45% (w/v) H2SO4 solution is mixed with 200 ml of 7% (w/w) H2SO4 solution (density =
1.4 gm/ml) and the mixture is diluted to 500 ml. What is the molarity of the diluted solution?

(1) 0.25 M
(2) 1.0 M
(3) 0.75 M
(4) 0.45 M

Mathematics

1) If (x – c)2 is a factor of (x5 – 5qx + 4r), where c ≠ 0 then value of q5 is

(1) r5
(2) r4
(3) c4 + r4
(4) c4

2) In a certain town, 25% families own a cell phone, 15% families own a scooter and 65% families
own neither a cell phone nor a scooter. If 500 families own both a cell phone and scooter, then the
total number of families in the town is

(1) 10000
(2) 20000
(3) 30000
(4) 40000

3) If λ is the minimum value of expression

|x – p| + |x – 15| + |x – p – 15| for x in the

range p ≤ x ≤ 15 where 0 < p < 15. Then

(1) 2
(2) 6
(3) 1
(4) 3

4) Find the modulus of the sum of all solutions to

(1) 6
(2) 5
(3) 7
(4) 3

5) Let P(x) be the polynomial of degree 9 that satisfies for k = 1,2,3,...,10. Find
P(11).

(1)

(2)

(3)

(4)

6) Let

and

then is

(1) 1
(2) 2

(3)

(4) 3

7) The domain of the function f(x) = is

(1) (1, 4)
(2) (–2, 4)
(3) [2, 4)
(4) None of these

8) If then the value of expression

(1) 4
(2) 5
(3) 3
(4) 10

9) Out of 30 students in a room, 20 know English, 8 know Sanskrit and 25 know Hindi, 20 know at
least two of the above three languages and 6 know all three languages. Number of students who
know at least one of these three languages is :

(1) 25
(2) 26
(3) 27
(4) 30

10) Let X and Y be two non-empty sets such that and for some
non-empty set A. Then

(1) X is proper subset for Y

(2) Y is proper subset of X
(3) X = Y
(4) X and Y are disjoint sets

11) If two sets A and B have 99 elements in common, then the number of elements common to the
sets
A × B and B × A is :

(1) 299
(2) 100
(3) 992
(4) 18

12) Range of function ƒ(x) = is given by

(1) (0, ∞)

(2)

(3) [1, 2]

(4)

13) If f(x) = , then number of integeral values of x in the domain of f(x) is -

(where [x]-greatest integer function)

(1) 8
(2) 5
(3) 12
(4) 6

14) A polynomial P(x) leaves remainders 9x – 3 and 15x – 15 when divided by x2 – 3x + 2 and
x2 – 6x + 8 respectively. Let f(x) be the remainder polynomial when P(x) is divided
by (x – 1)(x – 2)(x – 4) then the value of f(3) is -

(1) 25
(2) 26
(3) 27
(4) 28
15) If for all x ∈ R, then range of 'a' is -

(1) (–∞, 1)

(2)

(3)

(4)

16) The number of solutions of the equation

||x – 2| – 5| = 5, is:

(1) 0
(2) 1
(3) 2
(4) 3

17) Solve .

(1) 2
(2) 10
(3) Both (A) and (B)
(4) None of these

18) The minimum value of cos(cosx) is :

(1) 0
(2) –cos 1
(3) cos1
(4) –1

19) If x, y, z are real numbers such that

4x2 + y2 + z2 – 4x + 6y – 2z + 11 = 0
then value of 2x – y – z is

(1) 5
(2) 1
(3) 2
(4) 3

20) If , then the value of a + b + c (where a, b, c ∈ N and are relatively prime)

(1) 70
(2) 45
(3) 50
(4) 40

21) (3 + 1) (32 + 1) (34 + 1) (38 + 1) (316 + 1) + The value of x is

(1) 32
(2) 64
(3) 48
(4) 24

22) The value of

is

(1) 0
(2) –1
(3) 1
(4) None of these

23) |x – 1 | + |x–3| ≤ 2; then x ∈

(1) [1, 3]
(2) [2, 4]
(3) [4, 12]
(4) No Solution

24) The sum of all the roots of the equation is :

(1)
(2)
(3)
(4)

25) The solution set of inequality is

(1)

(2)
(3)

(4)

26) Values of x satisfying the equality

|x2 + 8x + 7|=|x2 + 4x + 4| + |4x + 3| for are

(1)

(2)

(3)

(4)

27) The range of the function

, where [ ] is greatest integer function, is

(1) [0, 1]
(2) [–1, 1]
(3) {0}
(4) None of these

28) Range of is

(1) [0, 1]
(2) [0, 2]

(3)

(4) [1, 2]

29) If A = {x : x2 = 1} and B = {x : x4 – 10x2 + 9 = 0}, then A Δ B is equal to :

(1) {3, –3}

(2) {–1, 1}
(3) {–1, 1, 3, –3}
(4) None of these

30) The polynomials and , when divided by (x - 4) leave the

same remainder. Then the value of k is

(1) 2
(2) 1
(3) 0
(4) –1
 ANSWER KEYS

Physics

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 1 3 1 4 3 4 3 4 1 3 2 2 1 3 2 1 2 3 4 1
Q. 21 22 23 24 25 26 27 28 29 30
A. 4 2 2 1 1 3 2 1 1 2

Chemistry

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. 2 3 1 1 2 3 3 4 4 4 1 1 3 2 2 2 3 1 3 1
Q. 51 52 53 54 55 56 57 58 59 60
A. 4 3 3 1 3 2 2 2 2 4

Mathematics

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. 2 1 4 3 4 2 3 2 3 3 3 2 2 4 3 4 3 3 4 2
Q. 81 82 83 84 85 86 87 88 89 90
A. 1 1 1 1 2 3 3 2 1 2
 SOLUTIONS

Physics

1)

t = 4s

2)

3)

at t = 2sec

= 20 – 10 = 10
so minimum separation of each block
= 15 – 10 = 5m

4)

5)
5th particle dropped at t = 8 sec.

S1 =
S1 = 84 – 32g
= 84 – 320 .....(i)

S3 = 4u + 16 + 4(u + 8) – × g × 16
S3 = 4u + 16 + 4u + 32 – 8g
= 8u + 48 – 80 = 84 – 32 ...(ii)
S = S3 – S1
= 84 – 32 – (84 – 320)
= 288 m Ans.

7) At t = 0, VQ > VP
At t = t0, xP = xQ and VP > VQ

8)

= =2x v cosx

9)

12) For backward journey x = 5(1)2 = m

So, total distance = 5x

= m

13)

South-West = ; = 12 m upward = 12 , = 1 m East = 1

 , = 13m

14) Velocity of particle is changing

15)

distance travelled in half the time is,

which is more than half the maximum height.

16)

v = u – gt (for upward motion)

(v –t) → straight line
for downward motion v as vf = 0

17)

We known that,
So, let the time taken to cover first 30 km is t1

hours = hours
and let the time taken to cover next 30 km is t2

hours = hours

So, the total time = hours

Average speed = =

Average speed = km/hr.

20)

Chemistry

31) gm equivalent of oxidising agent = gm equivalent of KI

moles × n factor = gm eq. of KI = 0.1 × 1

moles ∝
32) If reaction is balanced
2MnO4– + 10I– + 16H+ → 2Mn2+ + 5I2 + 8H2O

34)

⇒ x = 8, y = 6

37) (A) In this equation, H2O2 is reducing chlorine from +1 to –1.

(B) I2 + H2O2 + 2OH– → 2I– + 2H2O + O2
In this equation, H2O2 is reducing iodine from 0 to –1.
In (A) reduction of HOCl occurs so it will be a oxidising agent hence H2O2 will be a reducing
agent.
In (B) reduction of I2 occurs so it will be a oxidising agent and H2O2 will be a reducing agent.

38) H2SO4 + 2NaOH → Na2SO4 + 2H2O

0.1 × V 50 × 0.1 – –
0.1 × V – 2.5 5 – 5 2.5 5

= 0.05
0.1 V – 2.5 = 0.05 V + 0.05 × 50
(0.1 – 0.05)V = 2.5 + 2.5

V= = 100 ml

39) n1 × 2 = n2 × 3

40)

V = 350 ml

41) Let KI solution is M molar so [Link] = 20 × M

Given, KIO3:

⇒20 × M =
⇒ Molarity of KI = 0.15 M

[Link]: 5 10
⇒ AgI= 0.3 × 50–10=5 [Link]
⇒ % AgNO3 = 85%

43)

Solution X solution Y (O.A)

2+
Fe → Fe3+ MnO-4
M1 M2
25 ml 20 ml
solution X and solution y reacted completely in Acidic medium -
mili Eq. of solution x mili Eq. of solution y
M1 × 1 × 25 = M2 × 5 × 20 ___(i)
Again, solution X completely reacts in Neutral medium with solution Y Let volume of Y will be
V ml so,
mili Eq. of solution x mili Eq. of solution y
M1 × 1 × 25 = M2 × 3 × V ___(ii)
from (i) and (ii)
M2 × 5 × 20 = M2 × 3 × V

ml = 33.3 ml

44)

BrO3– + 6I– → 3I2 + Br–

moles of I2 = 3 × moles of KBrO3
∴ moles of I2 = 0.02 × 3 = 0.06
Eq. of I2 = Eq. of Hypo
0.06 × 2 = 0.1 × V
V = 1.2 L = 1200 mL.

45)
∴ v.f. of dichloroacetic acid = 2 (4 – 2) + 2 (0 – (–1)) = 6
m. eq. of dichloroacetic acid = [Link]. of oxidising agent = 600

∴ m. moles of dichloroacetic acid = = 100

CHCl2COOH + NH3 → CHCl2COONH4
From reaction, [Link] of NH3 = [Link] of dichloroacetic acid = 100

∴ Moles of NH3 = = 0.1

46) Assume total mass = 200 gm

∴ Mass of CaCO3 = 100 gm
Then loss in mass = 44 gm
∴ Percentage loss = 22%

47)

48)

(A) 3O2 2O3

3 mol
= 67.2 lit = 14.4 gm

53) 2NH3(g) + → 2NO(g) + 3H2O(ℓ) [Link] reaction

100 ml 300 ml
vol. after reaction
0 (300 – 125) 100

NO(g) + O2(g) → NO2(g)

100–x 175– x
0 125 100
Volume contraction = 400 – 225 = 175

54) Consider that mass of NaCl = xg

∴ Moles of NaCl will be = and moles of KCl will be =

By using POAC for Na and K
∵ Moles of NaCl × 1 = Moles of Na2SO4 × 2

or Moles of Na2SO4 = Moles of NaCl ×

∵ Moles of KCl × 1 = Moles of K2SO4 × 2
or Moles of K2SO4 = Moles of KCl ×
Total weight of Na2SO4 and K2SO4 is 76 g

Hence × × 142 + × × 174 = 76

⇒ 1.2137 × 74.74 – 1.1678 x = 76
⇒ 0.0459 x = 1.26
⇒ x = 27.45 g

% mass of NaCl = ×100 = 42.89%

% mass of KCl = 100 – 42.89 = 57.11%.

55) CxHy + O2 → xCO2 + H2O (ℓ)

i a 7a 0

f 0 xa

Given :
∴ 8x + y = 28
Only C3H4 hydrocarbon satisfies the above relation.

56) CxH12 + (x + 3)O2 → xCO2 + 6H2O

At 400 K H2O is gaseous
Let

X=6

57) M = ; M=

58)

Na2CO3,+ H2SO4 → Na2SO4 + H2O + CO2

106 g 0.01mole

= = 0.01 × 24.6
= 0.01 mole = 0.246

59)

= 0.53 M
 60)

Mathematics

71)

=992

72)

Let x ∈ [–2, 2]
2
y =4+
&
⇒

⇒ Range is

73)
=
=
=

74)

x2 – 3x + 2 = (x – 1)(x – 2)
x2 – 6x + 8 = (x – 2)(x – 4)
∴ P(1) = 9x – 3|x=1 = 6
P(2) = 9x – 3|x=2 = 15
or
P(2) = 15x – 15|x=2 = 15
& P(4) = 15x – 15|x=4 = 45
The remainder polynomial f(x), which can be obtained when P(x) is divided by (x – 1).(x – 2).(x
– 4) will be of degree at most 2.
∴ Let f(x) = ax2 + bx + c
∵ P(1) = f(1) = a + b + c = 6
P(2) = f(2) = 4a + 2b + c = 15
& P(4) = f(4) = 16a + 4b + c = 45
By solving a = 2, b = 3, c = 1
∴ f(x) = 2x2 + 3x + 1
∴ f(3) = 2×32 + 3×3 + 1 = 28
75)

⇒ (a – 1)x2 – x – 3 < 0
a – 1 < 0 & D = 1 + 12(a – 1) < 0

76) |x – 2| = 10 or 0 ⇒ x = 2, 12 or –8
Hence 3 solutions.

78)

minimum cos (cos x)

as maximum (cos x) = 1
⇒ minimum {cos (cos x)} = cos (1).

82)

⇒0

84) For x ≤ 3 or x ≥ 5
x2 – 8x + 15 – 2x + 7 = 0

For 3 < x < 5, x2 – 8x + 15 + 2x – 7 = 0

x=4
Hence sum =