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The document contains a series of mathematical and physics problems, including equations, assertions, and geometric progressions. It also features questions related to projectile motion, forces, and chemical compositions. Each question is followed by multiple-choice answers, indicating a structured format for assessments in mathematics and physics.

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0% found this document useful (0 votes)
3 views37 pages

Solution

The document contains a series of mathematical and physics problems, including equations, assertions, and geometric progressions. It also features questions related to projectile motion, forces, and chemical compositions. Each question is followed by multiple-choice answers, indicating a structured format for assessments in mathematics and physics.

Uploaded by

mishraashesh1310
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

05-07-2026

1001CJA101034260001 JA

PART-1 : MATHEMATICS

SECTION-I

1) If one root of the equations ax2 + bx + c = 0 and bx2 + cx + a = 0 is common, then the value of

is
(where a, b, c are non-zero real numbers)

(A) 1
(B) 3
(C) 9
(D) 16

2) The sum of infinitely many terms of a geometric progression is 3 times the sum of even numbered
terms. If the first terms is non zero, then the common ratio of the geometric progression is

(A)

(B)

(C)

(D)

3) Assertion (A) : The value of is 10.


and
Reason (R) : , where N > 0, a > 0 & a ≠ 1.

(A) A is True, R is True ; R is a correct explanation for A.


(B) A is True, R is True ; R is NOT a correct explanation for A.
(C) A is True, R is False
(D) A is False, R is True

4) Let A1, A2, A3...An and H1, H2,...,Hn are n arithmetic means and harmonic means between two

positive number a and b. Then the value of is :-

(A)
(B)

(C)

(D)

5) The value of the sum is equal to

(A) 5
(B) 4
(C) 3
(D) 2

6) Let , then range of f(x) is -

(A)
(B)
(C)
(D)

7) Suppose a1, a2, ..., an, ... be an arithmetic progression of natural numbers. If the ratio of the sum of
the first five terms of the sum of first nine terms of the progression is 5 : 17 and 110 < a15 < 120,
then the sum of the first ten terms of the progression is equal to -

(A) 290
(B) 380
(C) 460
(D) 510

8) If a, b, p, q are positive real numbers such that 2, a, b, 3 are in harmonic progression. If geometric

mean of a & b is , where p & q are relatively prime, then

(A) p + q = 5
(B) q – p = 5
(C) 2p – q = 5
(D) q = 9

9) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II
(A) (I) 5
The value of is equal to

(B) The value of (II) 3


is equal to

The sum of the real roots of the equation


(C) (III) 2
is equal to

(D) (IV) 1
is equal to
(A) A→II, B→III, C→I, D→IV
(B) A→II, B→IV, C→I, D→III
(C) A→IV, B→I, C→II, D→III
A→II, B→IV, C→III, D→I
(D)

10) |x2 – 4x + 3| = |x2 – 5x + 4| solution set for x is

(A) {1, 5}

(B)

(C)

(D) {3, 5}

11) If , then xy + yz + zx is equal to

(A) –1
(B) 0
(C) 1
(D) 2

12) The number of solutions of the equation 3cos2x = 8sinx in [0,π] is-

(A) 1
(B) 2
(C) 3
(D) 4

13) If log2(4cosx – 4)2 = 2log2(2cosx), then the given equation has -

(A) number of solutions in [0, π] is 1


(B) number of solutions in [0, π] is 0
(C) number of solutions in [0, 2π] is 1

(D)
each of the principal solution is greater than

14) Maximum value of the expression cosθ – sin2θ – 2, θ ∈ , is -

(A)

(B) –1

(C)

(D) 1

15) Statement-1 : If the equations ax2 + bx + c = 0 and x2 + px + p2 = 0 has one root common then

. (where a, b, c, p, ∈ R –{0})
and
Statement-2 : Condition for one root common between the equations a1x2 + b1x+ c1 = 0 and a2x2 +

b2x + c2 = 0 is .

(A) Statement-1 is True, Statement-2 is True


(B) Statement-1 is False, Statement-2 is False
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

16) Range of is -

(A) (0, 1)
(B) (1, ∞)
(C) (–1, 0)
(D) (–∞, –1)

17) If (upto 'n' terms) = , then the number of terms


in sequence -

(A) 10
(B) 15
(C) 17
(D) None of these

18) If α, β are the root's of quadratic equation x2 – 4x + 1 = 0 such that an = αn + βn, then value of

is
(A) 4
(B) 6
(C) 5
(D) 8

19) In triangle ABC, if AC = 8, BC = 7 and D lies between A and B such that AD = 2, BD = 4, then
the square of length CD equals

(A) 42
(B) 56
(C) 48
(D) 51

20) The angles A, B and C of a triangle ABC are in A.P. and a : b = 1 : . If c = 4 cm, then the
square of area (in sq. cm) of this triangle is :

(A) 8
(B) 12
(C) 15
(D) 18

SECTION-II

1) Let a1 and a2 be two values of a for which the expression can


be factorised into two linear factors then the product (a1.a2) is equal to :

2) The number of integral values of a ∈ [–5, 5] for which the equation x2 + 2(a – 1)x + a + 5 = 0 has
one root smaller than 1 and the other root greater than 3 is

3) If a > 0, then minimum value of a + 2a2 + a3 + 15 + a–1 + a–3 + a–4 is

4) The maximum value of is equal to

5) If cos (α + β) = , sin (α – β) = & α, β lie between 0 & , then the value of 33(tan 2α) is

PART-2 : PHYSICS

SECTION-I

1) If A and B are projected simultaneously such that they collide at the highest point of particle 'A',
the value of will be :-

(A) 1
(B) 2

(C)

(D) cannot be determined

2) The equation of trajectory of a projectile is given by the equation, . Find the


maximum height reached by the projectile :-

(A) m
(B) 30 m
(C) m

(D)

3) Assertion : A body may be acclerating even when it is moving with constant speed.
Reason : When the direction of motion of the body is changing, the body must have acceleration.

(A) Assertion is True, Reason is True ; Reason is a correct explanation for Assertion.
(B) Assertion is True, Reason is True ; Reason is not a correct explanation for Assertion.
(C) Assertion is True, Reason is False.
(D) Assertion is False, Reason is True.

4) The acceleration vs time graph of a particle moving in straight line is given, then velocity -

time graph will be:

(A) Circle
(B) Parabola
(C) Straight line
(D) Ellipse

5) A particle A moves with velocity from a point (4, 5). At the same instant a particle B,
moving in the same plane with velocity , passes through a point C (2, –1)

(A) particles A & B collide at time t = 2sec


(B) particles A & B collide at time t = 3/2 sec
(C) particles never collide
(D) cannot be determined

6) Two small spheres of mass m connected by a string of length 2ℓ are kept on a smooth surface. A
vertical force F is applied at the middle of the string. What is maximum value of F for which the

spheres do not lose contact with the surface ?

(A) 2mg
(B) mg

(C)

(D) 4mg

7) A uniform heavy rope of mass 10kg is being pulled by a force 100 N, tension at its mid point, is :-

(A) 25 N
(B) 50 N
(C) 75 N
(D) 100N

8) In the given figure take upwards direction positive. All acceleration are given just after cutting

spring/string, select the correct statement:

(A) If spring is cut then aA = aB = g/3


(B) If spring is cut then aA = aB = g/2
(C) If string is cut then aA = 2g, aB = –g
(D) If string is cut then aA = –2g, aB = –g

9) A Particle is projected with initial velocity at an angle such that it grazes the top of two poles of
same height at time 2 and 6 sec. First pole is at distance 35 m from the point of projection. Then
match the list-I and List-II :-

List-I List-II
(P) Time of flight (in sec) (1) 80
(Q) Height of the pole (in m) (2) 70
Maximum height reached
(R) (3) 8
by particle (in m)
(S) Distance between two poles (in m) (4) 60
(A) (P) - (3) ; (Q) - (2) ; (R) - (4) ; (S) - (1)
(B) (P) - (3) ; (Q) - (4) ; (R) - (2) ; (S) - (1)
(C) (P) - (2) ; (Q) - (4) ; (R) - (1) ; (S) - (3)
(D) (P) - (3) ; (Q) - (4) ; (R) - (1) ; (S) - (2)

10) Two blocks of masses m and 2m are connected by a light string passing over a friction less
pulley, as shown in figure. If the system is released, the blocks move with an acceleration equal to :-

(A)

(B)

(C)

(D) g

11) At a given instant, A is moving with velocity of 5 m/s upwards. What is the velocity of B at that

time ? (pulley and strings are ideal) :-

(A) 15 m/s ↓
(B) 15 m/s
(C) 5 m/s ↓
(D) 5 m/s

12) A block rests on a horizontal surface. A horizontal force F is applied on the block. The
acceleration (a) produced in the block as a function of applied force (F) has been shown. The
coefficient of static and kinetic friction between the block and the surface are equal. The mass of the

block is

(A) 2 kg
(B) 6 kg
(C) 4 kg
(D) 7 kg

13) Find normal contact force between 2kg & 3kg blocks :-

(A) 30 N
(B) 7.5 N
(C) 6N
(D) 15 N

14) If block is at rest on rough inclined plane then find net contact force on block exerted by incline

plane :-

(A) 16 N
(B) 12 N
(C) 20 N
(D) 30 N

15) For a particle in uniform circular motion, the acceleration at a point P(R,θ) on the circle of
radius R is :- (Here θ is measured from the x-axis)

(A)

(B)
(C)

(D)

16) Two particles tied to different string are whirled in a horizontal circle as shown in the following
figure. The ratio of lengths of the string so that they complete their circular path with equal time

period, is :-

(A)

(B)

(C) 1
(D) None of these

17) If angular velocity of a disc depends on angle rotated as , then its angular
acceleration α at rad is :

(A) 8 rad/s2
(B) 10 rad/s2
(C) 12 rad/s2
(D) None of these

18) A disk having plane parallel to the horizontal is moving such that velocity of point P w.r.t. ground
is m/s as shown in figure. If radius of disk is R = 1 m and the angular speed of disk about vertical

axis passing through disk is ω = 2 rad/sec, the velocity of centre of disc in m/s is :-

(A)
(B)
(C)
(D) None

19) Particle A is moving in a horizontal plane with constant velocity V as shown. Another particle B
is moving in a circle with same speed V. At the moment when A is diametrically opposite to B, the
radius of curvature of B as seen by A will be (Radius of circle is R)

(A) R
(B) R/2
(C) 2R
(D) 4R

20) Figure shows the force vs displacement graph of a particle moving along a straight line. The
work done in displacing the particle from x = 0 to x = 35 is close to :-

(A) 250 J
(B) 267 J
(C) 275 J
(D) 262 J

SECTION-II

1) A ball is thrown from the top of 36 m high tower with velocity 5 m/s at an angle 37° above the
horizontal as shown. Its horizontal range (in meters) on the ground is closest to :- [ g = 10 m/s2]

2) A girl standing on road holds her umbrella at 45º with the vertical to keep the rain away. If she
starts running without umbrella with a speed of , the rain drops hit her head vertically.

The speed of rain drops with respect to the moving girl is . Find n.
3) Ball A is projected from tower of height 30 m and B is projected horizontally at 6 m/s. A and B
collide in air. The separation between the towers is d = 10x meters. What is the value of x ?

4) If contact force between 2kg and 4kg is f1 and between 4kg and 6kg is f2, find out (f1 + f2.)

5) An aircraft executes a horizontal loop at a speed of 720 km/h with its wings banked at 15°. What
is the approximate radius (in km) of the loop?

PART-3 : CHEMISTRY

SECTION-I

1) The simplest formula of a compound containing 50% of element X (atomic mass = 10) and 50% of
the element Y (atomic mass = 20) by weight is :

(A) XY
(B) X2Y
(C) XY2
(D) X2Y3

2) To obtain maximum mass of NO2 from a given mass of a mixture of NH3 and O2, the ratio of mass
of NH3 to O2 should be
NH3 + O2 NO2 + H2O

(A)

(B)

(C)

(D) None of these

3) For a binary liquid solution of 'A' and 'B'. = vapour pressure of pure 'A'. = vapour pressure
of pure B. XA= mole fraction of A in liquid phase YA= mole fraction of 'A' vapour phase.
Column-I Column-II

P. (ideal liquid solution) 1. YA > XA

Q. Azeotropic mixture 2. XA = YA

Equimolar ideal mixture of 'A' and B with


R. 3. YB > YA

Negative
S. 'A' and 'B', 100 torr, has 4.
total vapour pressure 140 torr deviation

(A) P - 4, Q - 3, R - 2, S - 1
(B) P - 2, Q - 1, R - 4, S - 3
(C) P - 1, Q - 2, R - 3, S - 4
(D) P - 3, Q - 1, R - 2, S - 4

4) Calculate freezing point of 0.2 molal aq. solution of a mono protic acid HX( = 20%)
(kf for water = 1.86 KKg/mol)

(A) 273.4464
(B) 272.5536K
(C) 262.15K
(D) 270.152K

5) Find weight in gram of glucose (Mw = 180) that should be dissolved in 100 gm water in order to
produce a solution with a difference of 105ºC between its boiling point and freezing point
temperatures.
(Take Kf = 2 K-kg/mole, Kb = 0.5 K-kg/mole)

(A) 360 gm
(B) 72 gm
(C) 36 gm
(D) 180 gm

6) For which of the following aqueous solutions freezing point is maximum ?

(A) 0.1 M urea


(B) 0.1M NaCl
(C) 0.05 M AlCl3
(D) 0.15 M glucose

7)

Which of the following is CORRECT set up quantum number for the last entering electron in 'Fe'.
(A)
n → 4, ℓ → 0, m → 0, s →

(B)
n → 3, ℓ → 1, m → 0, s →

(C)
n → 3, ℓ → 2, m → –1, s →

(D)
n → 3, ℓ → 2, m → –3, s →

8) Select among the following the species having the highest number of exchanges in 3d-subshell

(A) Cr+1
(B) Co+2
(C) Cr+3
(D) Mn+3

9)

Which of the following element has maximum number of electrons in ℓ = 2 subshell ?

(A) 46Pd
(B) 57La
(C) 29Cu
(D) 24Cr

10) The spin only magnetic moment (in B.M.) of Eu+3 in ground state is : (Atomic number of Eu = 63)

(A)
(B)
(C)
(D)

11) Molecule showing exception to lewis octet rule is

H2O,
(A)

(B) CO2, O3
(C) BCl3, XeF6
(D) PCl3, KCl

12) Which of the following statement is correct.

(A) Total number of electrons in a subshell is (2ℓ +1)


(B) pz, and orbitals are non axial.
Only s-orbital has directional properties while p, d and f-orbitals have non directional
(C)
properties.
(D) Spin multiplicity of subshell having ℓ = 1 in N-atom is 4

13) Assertion : An atom having three electrons in outermost shell and ns2np6nd10 configuration in
penultimate shell, belongs to p-block Reason : Because above element belongs to 3rd period.

(A) Assertion and Reason both are true and the Reason is a correct explanation of Assertion.
(B) Assertion and Reason are true but Reason is NOT correct explanation of Assertion.
(C) Assertion is true but the Reason is false.
(D) Assertion is false but the Reason is true.

14) Which of the following carbanion intermediate is least stable -

(A)

(B)

(C)

(D)

15) Which of the following has longest C=C bond length?

(A) H2C = CH2


(B) CH3–CH=CH2

(C)

(D)

16) Select the correct order of heat of hydrogenation?

(I) (II)

(III) (IV)
(A) I > II > III > IV
(B) IV > III > II > I
(C) II > III > IV > I
(D) II > III > I > IV

17) Which of the following represent incorrect order.

(A)

Order of stability of free radicals

(B)

Order of stability of anions

(C)

Order of stability of carbocations

(D)

Order of acidic strength

18) Which pair of compounds is not correctly matched with their isomerism?

(A)
& : Position isomers

(B)

& : Chain Isomers


(C)

& : Functional Isomers

(D)

& : Tautomers

19) These questions contains, Statement-I (assertion) and Statement-II (reason).


Statement-I : Penta-1,3-diene is less stable than Penta-1, 4-diene.
Because
Statement-II : Penta-1,3-diene has greater number of resonating structures and delocalised
electron cloud,

(A) Statement-I is True, Statement-II is True ; Statement-II is a correct explanation for Statement-I
Statement-I is True, Statement-II is True ; Statement-II is NOT a correct explanation for
(B)
Statement-I
(C) Statement-I is True, Statement-II is False.
(D) Statement-I is False, Statement-II is True.

20) The correct stability order of the following resonating structures is :

(I) (II) (III) (IV)

(A) (I) > (II) > (IV) > (III)


(B) (I) > (III) > (II) > (IV)
(C) (II) > (I) > (III) > (IV)
(D) (III) > (I) > (IV) > (II)

SECTION-II

1) 1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg mol–1) and 100
g of acetone (Kb = 1.7 K kg mol–1). The acid is known to dimerize in benzene but remain as a
monomer in acetone. The boiling point of the solution in acetone increases by 0.17°C.
The increase in boiling point of solution in benzene in °C is x × 10–2. The value of x is
_______.(Nearest integer) [Atomic mass : C = 12.0, H = 1.0, O= 16.0]

2) The number of chlorine atoms in 20 mL of chlorine gas at STP is a Χ 1021. (Round off to the
Nearest Integer).
Then the value of 'a' is.
[Assume chlorine is an ideal gas at STP
R = 0.083 L bar mol–1 K–1, NA = 6.023 ×1023]
3) Out of given seven species, how many specie(s) is/are hypervalent?
BF3, SF4, ClF3, CH4, SiCl4, ,

4) Which out of the following options are INCORRECT?


According to the mentioned properties.
(i) F– < Cl– < H– < Br– < I– (order of ionic size)
(ii) IE1 of ion M+2 > EA1 of M+3 . (IE = ionisation energy, EA = electron affinity)
(iii) S > Se > Te > O (order of EA)
(iv) Li < Be < B < C (order of electronegativity)
(v) Mg+2 < Na+ < F– (order of ionic size)
(vi) For Li ; IE1 < EA1

5) How many of the following compounds will show resonance

(A) (B)

(C) (D)

(E) (F)

(G) (H)

(I)
ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A D B D B B B B B B B A B C B A A D B

SECTION-II

Q. 21 22 23 24 25
A. 5 4 22 2 56

PART-2 : PHYSICS

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B A B C A B D D C A C D C D B C C D B

SECTION-II

Q. 46 47 48 49 50
A. 12 30 3 40 15

PART-3 : CHEMISTRY

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C C B C A C B B A C D C C C B A A D B

SECTION-II

Q. 71 72 73 74 75
A. 13 1 3 3 6
SOLUTIONS

PART-1 : MATHEMATICS

1)

Question Explanation: Evaluate an algebraic expression based on a common root condition.

Concept: Condition for one common root using determinants.

Solution:

ax2 + bx + c = 0
bx2 + cx + a = 0

⇒ (ac – b2) (ab – c2) = (a2 – bc)2


⇒ a2bc – ac3 – ab3 + b2c2 = a4 + b2c2 – 2a2bc
⇒ a4 + ac3 + ab3 – 3a2bc = 0
⇒ a(a3 + c3 + b3 – 3abc) = 0
⇒ (a + b + c) = 0 or a : b : c (a ≠ 0)
⇒ ∴ a3 + b3 + c3 = 3abc

Squaring the result: = 9.

Final Answer: Option (3)

2) S1 = a + ar +ar2 + ...∞

S2 = ar + ar3 + ar5 + ... ∞

Given S1 = 3S2

3)
4) A2 = =

⇒ H2 =

So, A2H2 =

Final Answer: The correct option is (2).

5)

(1) A.G.P.

(2)
subtract (2) from (1)

S=2

Final Answer

The correct option is (4)

6)
x≠2

xy – y = x – 3
x|y – 1| = y – 3

Range = R–{1, –1}

7)
⇒ d = 4a
a15 = a + 14d = 57a
Now, 110 < a15 < 120
⇒ 110 < 57a< 120
⇒a=2∴d=8
8) 2, a, b, 3 ...H.P.

...A.P.
Let common difference of AP = D

∴ &


∴ geometric mean of a and b

⇒ p = 9, q = 14

9) (A)

(B)
(C) Taking log both side base '10'

⇒ x = 1, or x = 4 ; sum = 5

(D)

10)

|x2 – 4x + 3| = |x2 – 5x + 4|
|(x – 3)(x – 1)| = |(x – 4)(x – 1)|
Squaring
(x –3)2(x –1)2 = (x – 4)2(x – 1)2
(x –1)2 [(x – 4)2 – (x –3)2]

(x –1)2(2x – 7) (–1) = 0 x = 1, x =

11)
xy + yz + zx = 0

12) 3(1 – S2) = 8S


3S2 + 8S – 3 = 0
3S2 + 9S – S – 3 = 0
3S(S + 3) – (S + 3) = 0

⇒ ⇒ two solutions

13) log2(4cosx – 4)2 = log2(2cosx)2


⇒ (4cosx – 4)2 = (2cosx)2

14) Let ƒ (θ) = cosθ – sin2θ – 2

ƒ(θ) = cos2θ + cosθ – 3 =



15) Statement-1 :
Equation ax2 + px + p2 = 0 has
D1 = p2 – 4p2 = –3p2 (–ve)
so roots are imaginary and we know that, if roots are imaginary, then both the roots will be

common so we can say .


Statement-2 :
The given condition is valid for two roots common.

16) f(x) = secx + tanx =

17)

Question Explanation: Solve the telescoping series by rationalizing the denominators.

Concept: Rationalization and Summation of Series.

Solution: The term of the series is .

Rationalizing :

Summing up to n terms (Sn):


Given

Final Answer: 10

18) Explain question:

Finding the value of


Concept:
newton's formula.

Solution:
Since α, β are roots of the Q.E. x2– 4x + 1 = 0
So, by newton's formula,
⇒ an+2 – 4an+1 + an = 0
now for n = 2022
⇒ a2024 – 4a2023 + a2022 = 0


Final Answer: Option (4)

19) Using cosine rule in ΔABC

...(1)
cosine rule in ΔADC

...(2)
from (1) and (2)

68 – CD2 = 17
CD2 = 51 or

20) , by sine Rule

sin A =
⇒ A = 30°, a = 2 , b = ,c=4

Δ= = sq. cm

21) 2x2 + 3xy + y2 + ay + 3x + 1

a = 2, h = , b = 1, g = , f = , c = 1
for two linear factors Δ = 0
or abc + 2fgh – af2 – bg2 – ch2 = 0

⇒ 2a2 – 9a + 10 = 0
⇒ a1a2 = 5

22)

Question Explanation: Finding the count of integers 'a' where roots lie outside the interval
(1, 3).

Concept: Location of roots for a quadratic equation.

Solution:
ƒ(1) < 0
1 + 2a – 2 + a + 5 < 0

...(1)

ƒ(3) < 0
9 + 6a – 6 + a + 5 < 0
7a + 8 < 0

...(2)
(1) ∩ (2)

Integers = –5, –4, –3, –2

Final Answer: 4

23)

If a > 0 then minimum value of


a + 2a2 + a3 + 15 + a–1 + a–3 + a–4 is
Conisder a, a2, a2, a3, a–1, a–3, a–4
Apply AM ≥ GM
⇒ a + 2a2 + a3 + a–1 + a–3 + a–4 ≥ 7
⇒ a + 2a2 + a3 + a–1 + a–3 + a–4 ≥ 22
min value = 22

24) –5 ≤ 3cosx + 4sinx ≤ 5

25) cos (α + β) = 4/5 ...(1)

∴ tan (α + β) = ...(2)
sin (α – β) = 5/13 ...(3)

∴ tan (α – β) = ...(4)
Now tan 2α = tan {(α + β) + (α – β)}

PART-2 : PHYSICS

26)

(Vy)1 =(Vy)2
V1sin30° = V2

27) =
on comparing, θ = 60°,

28) Correct Answer is (A)

29) Acceleration-time graph is linear, so v-t graph will be parabolic


30)

4 + 2t = 2 + 4t 5 – 3t = –1 + t
2 = 2t 6 = 4t
t = 1sec t = 3/2 sec
at t = 1, at t =3/2 sec

31) F = 2T sinθ ......(1)

Tsinθ + N = mg ...(2)
∴ Fmax = 2 mg

32) 100 = Ma

&T=

33)
When string is cut, T = 0

34)
Explain Question : A particle is projected in vertical plane such that it grazes the top of two
poles at time 2 and 6 sec we have to match the list I to list II.
Concept : This question is based on Projectile motion.

Solution :
Time of flight
= TOA + TAB + TBC
= 2 + 4 + 2 = 8 sec
height is equal at t = 2 & t = 6 sec

y = vy × 2 – g × 2 2 = v y × 6 – g × 62
180 – 20 = 4vy
160 = 4 vy

vy = 40 vx =

R = 140
distance between poles
ΔE = 140 – 70 = 70 m
Height of pole

Final answer:
option (4) is correct.

35) a =

36)
3T(5) – TV = 0
V = 15 m/s

37) fmax = 6N
when F = 18N, a = 3 m/s2
F – fmax = ma
18 – 6 = 3(m)
m = 4 kg

38) 30 = 6a, N = 3a

39)

Question Explanation: The question asks to find the total force exerted by a surface on a
stationary object.
Concept: Contact force
Solution:

Fcontact = m·g = 2 kg · 10 m/s2 = 20 N


Final Answer: Option (3)

40)

41) T1cos(30) = mg
T1sin(30) = mω2L1sin30

tan(30) =
⇒ ω2L1 = sec(30) × g
ω2 × L2 = sec(45) × g
42) Question Explanation: We need to find angular acceleration at θ = 1 rad.

Concept:
Solution:
ω = θ2 + 2θ. Differentiate and substitute θ = 1

ω(1) = 12 + 2(1) = 3, = 2θ + 2 ⇒ 2(1) + 2 = 4,

α = ω. ⇒α=ω. = 3 × 4 = 12 rad/s2
Final Answer: The correct option is (3).

43)

Explanation Question: A disk is rotating with same angular speed and we have to find
velocity of centre of disk
Concept: This question is based on kinematics of object
Solution:

Final Answer:
The correct option is (3)

44) |Velocity of B w.r.t. A| = VBA = 2V


Now, acceleration of B w.r.t.
A = acceleration of B w.r.t. the centre

=
∴ (RB)A = 4R

45)

Question Explanation : Calculate the work done from x = 0 m to x = 35 m using the given
Force–Displacement (F–x) graph.
Concept : Work done by a variable force equals the area under the F–x graph.
Solution :
The graph is divided into three regions:
From 0–10 m (triangle):
½ × 10 × 10 = 50 J
From 10–25 m (rectangle):
15 × 10 = 150 J
From 25–35 m (trapezium):
½ × (10 + 3.33) × 10 ≈ 66.67 J
Total Work Done
W = 50 + 150 + 66.67 ≈ 266.67 J
Final Answer : Option (2)
46) –36 = 3t – 5t2 ⇒ t = 3s
Range = 4 × 3 = 12 m

47)

48) VAB =

T=
30 = 24T

49)

50) Explanation:
In this question, an aircraft is moving in a horizontal circular loop with a given speed while its
wings are banked at a certain angle. We have to find the radius of the circular path.
Concept:
This question is based on circular motion of an aircraft and banking of planes, where the
horizontal component of lift provides the centripetal force.
Solution:
Speed of aircraft:
v = 720 km/h = 720 × (5/18) = 200 m/s
Let the banking angle be θ = 15°.
For a banked aircraft in horizontal circular motion:
Horizontal component of lift provides centripetal force,
Vertical component balances weight.
So,
tanθ = (centripetal force) / (weight)
tanθ = (mv² / R) / (mg)
⇒ tanθ = v² / (Rg)
⇒ R = v² / (g tanθ)
Substitute values:
v = 200 m/s
g = 9.8 m/s²
tan15° ≈ 0.268
R = (200)² / (9.8 × 0.268)
R ≈ 40000 / 2.63
R ≈ 1.52 × 10⁴ m
Final Answer:
Radius of the loop ≈ 1.5 × 10⁴ m (about 15 km)

PART-3 : CHEMISTRY

51)

% Atwt Simple Ratio

x 50 50/10 5 2

y 50 50/20 2.5 1

Ans. X2 Y

52)

The correct answer is option (C)

53) P. , so A is more volatile


Q. Azeotropic mixture has same composition in vapour and liquid phase
R. Component 'B' is more voltaile

S. (PT)=140<
140<50+100

54) Explain Question :


Calculate freezing point of solution
Concept :
Depression in freezing point with 'i'.
Solution :

= 1 + 0.2 (2 –1)
i = 1.2
ΔTf = ikf m

273 – Tf = 0.4464
Tf = 273 – 0.4464
= 272.5536K
Final Answer option (B)
55) Question Explanation:
Question is asking about the weight in gram of glucose.
Concept:
This question is based on elevation in boiling point and depression in freezing point.
Solution:
Tb = ΔTb + Tb° Tf = Tf° - ΔTf ∴ (Tb° = 100° C Tf° = 0°C)
Tb – Tf = 105 ⇒ ΔTb + 100 – (–ΔTf) = 105
⇒ ΔTb + ΔTf = 5
⇒ 2.5m = 5 ⇒ m = 2 molal

m= ⇒ W = 36 gm
Final Answer: The correct option is (C)

56) Question Explanation:


Compare freezing points of given solutions. The solution with the smallest freezing point
depression will have the maximum freezing point.
Concept:
Solutions, Colligative Properties, Depression In Freezing Point, Van't Hoff Factor
Solution:
Freezing point depression:

For comparison (same solvent), compare . Smaller im gives smaller and hence higher
freezing point.
Compute i for each:
Urea: non-electrolyte, i = 1
Glucose: non-electrolyte, i = 1
NaCl: strong electrolyte,
AlCl3 : strong electrolyte,
Now compare im:
1. 0.1 M urea:
2.
3. :
4. 0.15 M glucose:
Smallest im is for 0.1 M urea, so it has the smallest and hence maximum freezing point.
Final Answer: Option (A)

57)

Explain the question: Find Fe 's last entering electron QNs.

Concept: Aufbau principle & quantum rules.

Solution:
Iron (Z = 26) has a ground-state electronic configuration of 1s22s22p63s23p64s23d6. According
to the Aufbau principle, the 4s subshell fills completely before electrons begin to occupy the
3d subshell.
Therefore, the differentiating (last) electron enters the 3d subshell. For a 3d electron, the
principal quantum number n is 3 and the azimuthal quantum number ℓ is 2. The magnetic
quantum number m must satisfy the condition –ℓ ≤ m ≤ + ℓ, which allows values {–2, –1, 0,
+1, +2}.
Option (C) provides a valid set with n = 3, ℓ = 2, m = –1, while Option (D) is physically
impossible because m = –3 exceeds the allowed range for ℓ = 2.

Final Answer: Option (C)

58)

Explain the question: Identify the ion with the highest number of electron spin exchanges
(parallel pairs).

Concept: Exchange Energy (Pairs = for each spin set).


Solution:

A. Co+2(3d7) : Configuration has 5 Up (↑) and 2 Down (↓) electrons.

B. Exchanges = (UP) Down ) = 10 + 1= 11.


C. : Configuration has 5 Up (↑).
D. Exchanges = .
E. Others: has 6 exchanges; 3 has 3 .

59)

The correct answer is option (B)

60) Explain question : We have to calculate spin only magnetic moment (in BM) of Eu+3 ion.
Concept : This question is based on magnetic moment (µ).
n = No. of unpaired e(s)
Solution :

Eu+3 = 4f6
µ=
=
=

Final answer : Option (A)

61)

Question Explanation: Question is asking about to choose pair of compounds which show
exception to Lewis acid.
Concept: This question is based on octet rule.
Solution:
Correct answer is
BCl3, XeF6
The correct option is (C)

62) N = 1s2 2s2 2p3

Total spin = 3 ×

spin multiplicily is

63) atom can't be 3rd period element as 3rd period element can't have 3d-orbitals in it's
penultimate shell

64)

The correct answer is option (C)

65)

Explain Question : To find out the compound which have longest C = C bond length

Concept : Bond length and bond strength

Solution : C = C bond length in alkene ∝ hyperconjugation

Has highest degree of hyperconjugation because six hyperconjugated hydrogen.


So it has longest C = C bond length

Final Answer : Option(3)

66)

The correct option is (B)


67) Solution:
1. +I group increases stability of free radical so correct order is D > C > B > A
2. Option 2 (Para-substituted): This order is correct. Anion stability increases with electron-
withdrawing groups and decreases with electron-donating groups .

3. Option 3 (Cresols): This order is correct. Methyl groups are electron-donating ( +1 and
hyperconjugation), which stabilize carbocation.

4. Option 4 (Chlorophenols): This order is correct. For halogens, the -1 effect dominates. Since
the inductive effect is distance-dependent, the acidity follows: o-chlorophenol > m-
chlorophenol > p-chlorophenol > phenol.

Final Answer: Option(1)

68) In option (A) compounds are chain isomers

69) Penta-1,3-diene is resonance stabilized

70)

Question Explanation:
The question asks to arrange the given resonance structures of the same molecule in the
correct order of stability by comparing charge distribution and bond characteristics.

Concept:
Resonance, Resonance Structure Stability, Formal Charge, Electronegativity, Octet Rule

Solution:

(I) Has negative charge on N and octet of all atoms is complete, most stable.

(II) Negative charge on nitrogen and positive on carbon, but carbon lacks
octet → less stable.

(III) All atoms have complete octet, negative charge on carbon (less preferred
but acceptable) less stable than (I).

(IV) Negative charge on carbon and positive on nitrogen (less preferred), but
Nitrogen lacks octet → least stable.

Hence, the stability order is: (I) > (III) > (II) > (IV)

Final Answer: Option (2)

71) With benzene as solvent


ΔTb = i Kb m

… (1)
With Acetone as solvent
ΔTb = i Kb m
0.17 = … (2)
(1) / (2)

ΔTb = 13 × 10–2
⇒ x = 13

72) PV = nRT

∴ Number of Cl2 molecules, N = 5.3 × 1020


Hence, Number of Cl-atoms = 1.06 × 1021 ≈ 1 × 1021

73)

The correct answer is 3

74)

(i), (ii), (vi) are incorrect

75) A,B,C,D,E,F

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