02-06-2025

2701CJA101001250005 JA

PART-1 : PHYSICS

SECTION - I(i)

1)

In a hypothetical set of units

1 star joule = 103 joule
1 star Newton = 104 Newton
1 star second = 10 second
Then one meter is equivalent to

(A) 100 star meter

(B) 1000 star meter
(C) 10 star meter

(D)
star meter

2) In a certain system of units, 1 unit of time is 20 sec, 1 unit of mass is 20 kg and 1 unit of length is
20 m. In this system, one unit of power will correspond to

(A) 20 watts

(B)
watts
(C) 400 watts
(D) 1 watts

3) In the following four figures, a function y = f(x) and are plotted by solid and dashed lines
respectively. Which of them shows correct figure?

(A)

(B)
(C)

(D)

4) In the given figure length of sides AB, BC, DE and DC are 15 cm, 30 cm, x and (x+5) respectively.

Which of the following statements is true?

(A) x = 2 cm
(B) x = 3 cm
(C) x = 4 cm
(D) x = 5 cm

5)

A physical quantity A is related to four observable a, b, c and d as follows, , the percentage

errors in measurement of a, b, c and d are 1%, 3%, 2% and 2% respectively. What is the maximum
percentage error in the quantity A?

(A) 12%
(B) 7%
(C) 5%
(D) 14%

6)

(A) x ex (2 sin x + x sin x + x cos x)

(B) x ex (2 sin x + x sin x – cos x)
(C) x ex (2 sin x + x sin x + cos x)
(D) None of these

SECTION - I(ii)

1)

The energy of a particle is given by

Where x is a distance from fixed point. Which of the following has dimension of energy.

(A)

(B) CB2
(C) ABC
(D) C

2) Select correct alternative(s)

(A) There can be a physical quantity which has no unit & dimensions.
(B) A physical quantity can have unit without having dimensions.
(C) A physical quantity can have dimensions without having unit.
If a physical quantity depends on three physical quantities, out of which two have same
(D)
dimensions, the formula cannot be derived by theory of dimensions.

3)

The velocity, acceleration and force in two systems of units are related as under

(i)
(ii) a' = (αβ)a

(iii)

All the primed symbols belong to one system and unprimed ones belong to the other system. α and β
are dimensionless constants. Which of the following are correct:

(A) Length standards of the two systems are related by

(B)
Mass standards of the two systems are related by :

(C)
Time standards of the two systems are related by

(D)
Momentum standards of the two systems are related by

4) A paper helicopter with rotor radius r and weight W is dropped from a height h in air with a
density of ρ. Assuming that the helicopter quickly reaches terminal velocity, a function for the time
of flight T can be found in the form
T = khαrβρδWω.
where k is an unknown dimensionless constant, α, β, δ, and ω are constant exponents to be
determined. Experimental observation show that α = β. Mark the CORRECT statement(s) :

(A) α = –1
(B) α = 1
(C) β = 1
ω=
(D)

5) A function , Choose correct option(s).

(A)

(B)

(C) y at x = 4 is 16

(D)

6) Which of the following combinations of three dimensionally different physical quantities P,Q,R can
nerver be a meaningful quantity ?

(A) PQ – R

(B)

(C)

(D)

SECTION-II

1)

If and where a is a constant, find at .

2)

The fuel consumption rate (Litres of fuel consumed per second) of a large ship is given
by where v is its speed in m/s. For a particular journey, from city A to city B, the captain wishes to
consume as less fuel as possible. Find the speed with which the ship must travel (in m/s)

3)

Find the area enclosed between the x-axis, the y-axis, the graph of y = sec2x and the line

4) As shown in figure below water is draining from a conical tank with 12 feet height and diameter 8
feet into a cylindrical tank that has a base with area 400 square feet. The depth h, in feet of the
water in the conical tank is changing at rate of 2 feet per second. The rate of change of height of
water in cylindrical tank (when h = 3ft) is ft/sec, then value of x is

5) The energy E of an oscillating body in simple harmonic motion depends on its mass m, frequency
n and amplitude A as E = k(m)x(n)y(A)z. Find the value of (2x + y + z) [Amplitude is distance]

6) . Find c.

PART-2 : CHEMISTRY

SECTION - I(i)

1)

Which of the following order is/are CORRECT ?

(A) Li+ < Na+ < K+ : Hydrated radius

(B) Na+ < Mg+2 < Al+3 : Ionic radius
(C) F < Cl > Br : Electron affinity
(D) Cl – OH < Br – OH < I – OH : Acidic character

2) Which of the following statement is CORRECT.

(A) Mg+2 has greater ionic radius than Li+

(B) Shielding constant value for 4s & 3d e– is same in scandium
(C) H– is the smallest anion in periodic table
(D) Aℓ3+ has greater ionic radius than F–

3) The correct statement among following is (consider sign also)

IE1 = First ionisation energy
EGE1 = First electron gain enthalpy
EA1 = First electron affinity

(A) IE1 of element M(g) = EGE1 of M(g)

(B) IE1 of element M(g) = EA1 of M(g)
+
(C) IE1 of element M(g) = |EGE1 of M (g)|
+
(D) IE1 of element M(g) = EGE1 of M (g)

4) Correct diagram of acidic strength of oxides is :-

(A)

(B)

(C)

(D)

5)

Select the INCORRECT statement ?

(A) The third ionisation energy of carbon is less than that of third ionisation energy of Beryllium.
(B) The first ionisation energy of C2+ ion is greater than that of first ionisation energy of N2+ ion
(C) The second ionisation energy of Mg is greater than the second ionisation energy of Na
(D) The second ionisation energy of nitrogen is less than that of second ionisation energy of fluorine
6)

Which of the following statement is INCORRECT ?

(A) A cation is smaller than an anion if they are isoelectronic

(B) Out of second period anion, fluoride ion is large in size
(C) All transition metals are paramagnetic
(D) Metallic radius of an element (‘X’) is higher than its covalent radius

SECTION - I(ii)

1) Which of the following statements is correct for the part of the periodic table given below where

all elements are of 'p' block elements :

(A) 'C' is isoelectronic with A2+

(B) The number of valence shell electron of Q is identical with P– & O+
If Q is of 3rd period element then difference of atomic number of P and A is identical with that
(C)
of O & R.
(D) The expected difference in IE1 values is maximum for C and M.

2) Successive ionisation energies for some elements are listed below, from which predict that the
elements are of same group in the following options.

IE1 IE2 IE3 IE4 IE5 IE6 IE7

J : 14.534 29.601 47.448 77.472 97.888 552.057 667.029
K : 8.151 16.345 33.492 45.141 166.77 205.05 246.52
L : 17.422 34.970 62.707 87.138 114.240 157.161 185.182
M : 10.486 19.725 30.18 51.37 65.023 220.43 263.22
N : 11.26 24.383 47.887 64.492 392.077 489.981

(A) J and K
(B) K and N
(C) L and M
(D) J and M

3)

Choose the INCORRECT order of hydrated size of the ions -

(A)
(B)

(C)

(D)

4) If effective nuclear charge differs by 0.15 between three consecutive elements in periodic table
then incorrect statement regarding these elements is / are

(A) Must be d-block elements

(B) Shielding constant (σ) increases by 0.85 from chromium to manganese
These three elements can have any value of maximum principle quantum number of valence
(C)
shell except 1, 2 and 3
(D) The last electron entering in these three elements have different values of n + ℓ

5) If

Select the CORRECT statement(s) using above given information.

(A) IE1 of N > x kJ/mol

(B) IE1 of O > x kJ/mol
(C) x > y
(D) z > y

6) The correct statements is/are :-

(A) 'N' is lesser electron affinity than 'O' atom

(B) P has more ionisation energy than 'S' atom
(C) Oxides of 'P' and 'S' are acidic in nature
(D) Mn2O7 is a amphoteric oxide

SECTION-II

1)

Find value of (X–5Y) where

X = Atomic number of an element which has highest electron affinity in entire periodic table
Y= Atomic number of an element which has highest ionisation energy in entire periodic table

2) Among the following, find out the total number of process associated with the formation of NaCl
from elemental form of reactants.
Ionisation energy of sodium, electron affinity of sodium, electronegativity of chlorine, bond
dissociation energy of chlorine, sublimation enthalpy of sodium, lattice energy of NaCl.

3)
Find the sum of the 'σ' & Zeff on the last e entered in Fe.

4)

Count the number of incorrect statement among the following :-

(A) The first ionisation potential of Al is less then the first ionisation potential of Mg
(B) Ionic radius of free H– is more than that of Br–
(C) The formation of S2– from sulphur atom is an endothermic process
(D) The first ionisation energies of carbon, silicon, germanium, tin, and lead change as C > Si > Ge
> Sn < Pb
(E) Down the group, electronegativity decreases from B to Tl
(F) Among oxides, CO is neutral, GeO is acidic and SnO is amphoteric.
(G) The 4f-and 5f-inner transition series of elements are placed separately in the periodic table to
maintain its structure.

5) The number of process that are definitely exothermic (Energy is released) out of the
following processes are:

(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii) ΔHf of H+(g)
(viii)

6)

Find the number of elements, whose E.N. on pauling scale is greater than 'B'

S , N , Cl , F , C , Al , Mg

PART-3 : MATHEMATICS

SECTION - I(i)

1) If , then the least and the highest values of 4x2 are :

(A) 36 & 81
(B) 9 & 81
(C) 0 & 81
(D) 9 & 36
2) If and is an odd integer then number of possible values of α is

(A) 1
(B) 2
(C) 3
(D) 4

3) The sum of the solutions of the equation 9x - 6.3x + 8 = 0 is

(A) log3 2
(B) log3 6
(C) log3 8
(D) log3 4

4) The complete solution set of the inequality (|x - 1| - 3) (|x + 2 | - 5) < 0 is (a, b) (c, d) then the
value of |a| + |b| + |c| + |d| is

(A) 14
(B) 15
(C) 16
(D) 17

5) If then the value of x2 is .

(A)

(B)

(C)

(D)

6) Suppose n be an integer greater than 1 and let Suppose b = a2 + a3 + a4 + a5 and

c = a10 + a11 + a12 + a13 + a14. Then (b -c) equals

(A)

(B)

(C) - 1
(D) - 2
 SECTION - I(ii)

1) Consider the equation ||x -1| - |x+2|| = p. Let p1, be the value of p for which the equation has
exactly one solution. Also p2 is the value of p for which the equation has infinite solution. Let α be
the sum of all the integral values of p for which this equation has solution then

(A) p1 = 0
(B) p2 = 3
(C) α = 6
(D) p1 + p2 = 4

2) A and B are two sets such that n(A) = 3 and n(B) = 6 then

(A) minimum value of n(A B) = 6

(B) minimum value of n(A B) = 9
(C) maximum value of n(A B) = 6
(D) maximum value of n(A B) = 9

3) In a survery, it was found that 21 persons liked product A, 26 liked product B and 29 like product
C. If 14 persons liked products A and B, 12 liked products C an A, 13 persons liked products B and C
and 8 liked all the three products then which of the following is (are) true?

(A) The number of persons who liked the product C only = 12

(B) The number of persons who like the products A and B but not C = 6
(C) The number of persons who liked the product C only = 6
(D) The number of persons who like the products A and B but not C = 12

4) Let a > 2, be a constant . If there are just 18 positive integers satisfying the inequality (x -
a) (x - 2a) (x - a2) < 0 then which of the option(s) is/are correct?

(A) 'a' is composite

(B) 'a' is odd
(C) 'a' is greater than 8
(D) 'a' lies in the interval (3, 11)

5) Consider rectangle with sides 5 cm & 3 cm. An insect runs around the rectangle in such a way
that it is always at a distance of 2 cm from its sides. If it travel a distance a + bπ cm in one round,
then -

(A) a + b = 18
(B) a - b = 12
(C) a + b = 20
(D) a - b = 14

6) In given figure 'O' is centre of given circle of radius 6 cm and , then

(A)
Lenth of are = 8π cm

(B)
Lenth of are = 4π cm
(C) AB = BC → ar
(D) AB = BC → ar ar

SECTION-II

1) Evaluate the product

2) The value of the expression + + + , is

3) If X = (31/4 + 1)(31/2 + 1) (3 + 1)(32 + 1)(34 + 1)(38 + 1), then x can be written as (where a is

a multiple of such that ), then (a, b) is equal to

4) Let r(x) is remainder, when polynomial P(x) = e.x135 + e11 .x125 - e21.x115 - e131. x5 + 1 is divided by x3
- e2x, then the value of loge(r(e)) is [Note: e denotes Napier's constant]

5) The value of is

6) An unknown polynomial P(x) = x2 + bx +c, yields remainder R1 upon division by (x - 3) and R2

upon division by (x - 5). If R1 = R2 = 1, then b + c is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION - I(i)

Q. 1 2 3 4 5 6
A. C D A D D A

SECTION - I(ii)

Q. 7 8 9 10 11 12
A. A,B A,B,D A,B,C,D B,C B,C,D C

SECTION-II

Q. 13 14 15 16 17 18
A. 1.73 4.00 1.00 5.00 6.00 8

PART-2 : CHEMISTRY

SECTION - I(i)

Q. 19 20 21 22 23 24
A. C B C A C B

SECTION - I(ii)

Q. 25 26 27 28 29 30
A. B,D B,D B,C B,D A,C,D A,B,C

SECTION-II

Q. 31 32 33 34 35 36
A. 7.00 4.00 26.00 1.00 5.00 5.00

PART-3 : MATHEMATICS

SECTION - I(i)

Q. 37 38 39 40 41 42
A. C B C C C C

SECTION - I(ii)

Q. 43 44 45 46 47 48
A. A,B,C A,D A,B B,D B,C B,C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 104 2 4 0 5 8
 SOLUTIONS

PART-1 : PHYSICS

1) L ∝ EaFbTc
L = (ML2T–2)a (M1L1T–2)bTc
L = Ma+b L2a+b T–2a–2b+c
a+b=0
2a + b = 1
–2a – 2b + c = 0
2a – a = 1
a=1
b = –1 and c = 0
∴ L = EaFbTc = E1F–1 or length = energy/force
(1 star meter) = (1 star joule)1 (1 star N)–1
= (103) (104)–1 [(Joule)1 (N)–1]
1 star meter = 10 –1 m
∴1 m = 10 star meter

2)

n1u1 = n2u2
ML2T–3 = 20kg (20m)2 (20sec)–3

= kgm2sec–3
= 1 watt

3)

4)

5)

14%

6)

y = x2ex sin x

= 2x ex sin x + x2ex sin x + x2excos x

= xex [2sinx + x sin x + x cos x]

7)
[x] = [B] = [B + x] & [E] = = [Cx2e–Fx]

8)

Ans: 1, 2 & 4

9)

....(iii)

Dividing eq. (iii) by (ii), we get :

Dividing eq. (i) by (ii), we get :

Now, gives :

Now

10)

11)

Ans: 2, 3 & 4

12)

13)

1.73

14)
 4.00

15)

1.00

16) New Ans. 20 by Rupendra Sir

17) By using dimensional analysis

ML2T–2 = Mx(T–1)y(L)z = MxLzT–y
⇒ x = 1, z = 2, y = 2
⇒ 2x + y + z = 2 × 1 + 2 + 2 = 6

18)

PART-2 : CHEMISTRY

19)

F < Cl > Br : Electron affinity

20)

Shielding constant value for 4s & 3d e– is same in scandium

21)

IE1 of element M(g) = |EGE1 of M+(g)|

22)

23)

The second ionisation energy of Mg is greater than the second ionisation energy of Na

24)

Out of second period anion, fluoride ion is large in size

25)

Ans: 2 & 4

26) J : Number of valence e–s = 5 K : Number of valence e–s = 4

L : Number of valence e–s > 7 (no sharp pump in the given data)
M : Number of valence e–s = 5
N : Number of valence e–s = 4

27)
∴ Size of hydrated ion ∝ ϕ

28)

Ans: 2 & 4

29)

|ΔH| = x = |IE1 of 'O'|

|ΔH| = y = |EA1 of 'O'|
|ΔH| = z = |EA2 of 'O'|
(A) IE1 of 'N' > IE1 of 'O' (x)
(B) IE1 of 'O' = x
(C) |IE1 of 'O'| (x) > |EA of 'O'| (y)
(D) |EA2 of 'O'| > |EA1 of 'O'|
Hence given A, C, D statements are correct.

30)

Ans: 1, 2 & 3

31)

7.00

32) Ionisation energy of sodium, bond dissociation energy of chlorine,

sublimation enthalpy of sodium, lattice energy of NaCl.

33)

26.00

34)
 (a) Mg = 1s2 2s2 2p6 3s2 ; Al = 1s2 2s2 2p6 3s2 3p1 As electron is to be removed from stable
completely filled s-orbital of Mg as compared to partially filled p-orbital of Al.
(b) Li+ due to small in size attracts more no. of water molecules and thus have bigger hydrated
ion.
(c) and (d) are also correct statements.

35)

5.00

36)

S, N, Cl, F, C
having more value of electronegativity on Pauling scale as compared to B.

PART-3 : MATHEMATICS

37)

0 & 81

38)

39)

log3 8

40)

16

41)

42)

-1

43)

Ans : A, B & C
44)

Ans: A & D

45)

Ans: A & B

46)

Ans: B & D

47)

Ans: B & C

48)

Ans: B, C & D

49)

104

50)

51)

53)

54)