05-07-2026
1603ENTHUSEIIT1 JA
PHYSICS
SECTION - I (i)
1) The electric field at A due to dipole p is perpendicular to p. The angle θ is :-
(A) 0°
(B) 90°
(C) tan–1 2
tan–1
(D)
2)
Consider a cube of side a = 0.1 m placed such that its six faces are given by equations x = 0, x =
+a, y = 0, y = +a, z = 0 and z = +a, placed in electric field given by = N/C. If the
electric flux crossing out of the cube is (10 + β) in the units of 10 N m /C. Then b is equal to :
–4 2
(A) 1
(B) 2
(C) 3
(D) None of these
3) A dipole with dipole moment p is kept on the axis of a charged ring of radius R and charge Q at a
distance R. Force on dipole is
(A)
(B)
(C)
(D) None of these
4) A dipole with dipole moment p is kept on the axis of a charged ring of radius R and charge Q at a
distance R. Force on dipole is
(A)
(B)
(C)
(D) None of these
5) Three point charges 2q, –q and –q are located respectively at (0, a, a), (0, a, –a) and (0, 0, – a) as
shown. The dipole moment of this distribution is :-
(A)
2qa in the y–z plane at tan–1 with z-axis
(B)
in the y–z plane at tan–1 with z-axis
(C) in the x–y plane at tan–1 (4) with y-axis
(D) 4qa in the x–y plane at tan–1 (4) with y-axis
6) In the diagram resistance between any two junctions is R. Equivalent resistance across terminals
A and B is :-
(A)
(B)
(C)
(D)
SECTION - I (ii)
1)
A spherical shell of radius R is given charge 3q on its surface and a point charge q is placed at
distance R/2 from its centre C. Also there is a charge 2q placed outside the shell at a distance of 2R
as shown. Then
The magnitude of electric field at the centre C due to charges on the outer surface of shell is
(A)
before closing the switch S.
The electric potential at the centre C due to charges on the outer surface of shell
(B)
is before closing the switch S.
(C) The electric potential at the centre C due to charges on the outer surface of shell is
after closing the switch S.
(D) Charge flown through the switch in to earth after closing the switch S is 5q
2) Consider the circuit shown in the figure
(A) The current in the 5Ω resistor is 2A
(B) The current in the 5Ω resistor is 1A
(C) The potential difference VA – VB is 7V
(D) The potential difference VA – VB is 5V
3)
Select the correct option for the given configuration.
Hemispherical shell, having surface charge density σ (may be constant
or variable)
(A)
Electric field at O (if σ = σ cosθ) =
0
Electric field at O (if σ = σ0 = constant) =
(B)
(C) 0
Potential at O due to charge on hemisphere if (σ = σ = constant) =
(D) 0
Potential at O due to charge on hemisphere if (σ = σ cosθ) =
4) Figure shows two spheres, each of radius R and carrying uniform volume charge densities +ρ and
–ρ, respectively, are placed so that they partially overlap. Let the vector from the positive centre to
the negative centre is . Then choose the correct statement(s) :-
(A) Electric field inside the overlaped region will be uniform
(B)
Electric field inside the overlaped region is
(C) Electric field inside the overlaped region is zero
(D) Gauss's law can not be applied if only one of the spheres is taken as Gaussian surface.
5) In the figure shown a point charge q is kept at a distance 4R/3 from centre of a conducting solid
sphere 'S' of radius R and having a charge Q. B is a point on the surface of conductor such that BC is
perpendicular to AC. Also line AC is along X-axis. Choose the correct options.
(A)
X-component of electric field at the point B only due to charge of conductor is
(B)
X-component of electric field at the point B only due to charge of conductor is
(C)
Electric potential at the point B only due to charge of conductor is
(D)
Electric potential at the point C only due to charge of conductor is
6) In the circuit shown in the figure
(A) the value of E is 12 V
(B) the value of E is 14 V
(C) the value of I is 1A
(D) the value of I is 5A
SECTION - II
1) The current supplied to the circuit by 10 V cell is I ampere. Assume both cells as ideal find 4I.
2) Find the magnitude of electric field (in N/C) due to a line charge of λ = nC/m at a point P as
shown.
3) A rod of mass 'm' and length '2ℓ' has two equal and opposite point charges of mass 'm' and
magnitude of charge 'q' each. This dipole rod is released from rest in the horizontal as shown in
the figure. If the angular velocity of the dipole about its mid point when it crosses the mean position
is . Find the value of 'x'.
4)
An infinitely long uniform line charge distribution of charge per unit length lies parallel to the y-
axis in the y – z plane (see figure). If the magnitude of the flux of the filed through the
rectangular surface ABCD lying in the x – y plane with its centre at the origin is
then the value of n is
5) A electric dipole of dipole moment is placed in a uniform electric field of
in such a way that dipole moment is along electric field. The work done in rotating
dipole by 180° in this field will be ________ mJ.
6) Four resistances are connected in a circuit as shown in the following diagram. The value of the
current in ampere in 4ohm resistance is :–
CHEMISTRY
SECTION - I (i)
1) Which of the following Werner’s complex has least electrical conductivity ?
(A)
(B)
(C)
(D)
2) In the following reaction sequence in aqueous soluiton, the species X, Y and Z respectively, are :-
3–
(A) [Ag(S2O3)2] , Ag2S2O3, Ag2S
5–
(B) [Ag(S2O3)3] , Ag2SO3, Ag2S
3–
(C) [Ag(SO3)2] , Ag2S2O3, Ag
3–
(D) [Ag(SO3)3] , Ag2SO4, Ag
3) Relative decrease in vapour pressure of an aqueous solution containing 2 moles [Cu(NH3)3Cl]Cl in
3 moles H2O is 0.50. On reaction with excess of AgNO3, the solution will form (assuming no change
in degree of ionisation of substance on adding AgNO3) :
(A) 1 mol AgCl
(B) 0.25 mol AgCl
(C) 5 mol AgCl
(D) 0.40 mol AgCl
4) Which of the following represent pair of enantiomers
(A)
(B)
(C)
(D)
5) In which of the following reaction only retention of configuration take place :
(A)
(B)
(C)
(D)
6) The major product of the following reaction is :-
(A)
(B)
(C)
(D)
SECTION - I (ii)
1) Which of following is/are more reactive than benzene towards electrophilic substitution.
(A)
(B)
(C)
(D)
2) Which of the following reaction equilibrium is favoured in forward direction?
(A)
(B)
(C)
(D)
3)
The correct statement(s) concerning the structures E, F and G is (are)
(A) E, F and G are resonance structures
(B) E, F and E, G are tautomers
(C) F and G are geometrical isomers
(D) F and G are diastereomers
4) Solution-I (S-I) = 0.2 M HCl (aq.)
Solution-II (S-II) = 0.2 M BOH (aq.)
Solution-III (S-III) = 1 litre solution- I + 1 litre solution- II. (Assume no hydrolysis takes place)
Considering solute to be non-volatile and solution to be ideal, select the incorrect statements.
(A) Order of osmostic pressure is S-II < S-I<S-III
(B) Order of vapour pressure is S-I < S-III <S-II
(C) Order of boiling point is S-II < S-III<S-I
(D) Order of freezing point is S-I< S-II < S-III
5) Find correct statements for Coordination compounds.
(Pt = 78, Cu = 29, Ni = 28, Fe = 26, Co = 27)
2+
(A) [PtCl2(NH3)2] & [Cu(NH3)4] are square planar complexes.
3–
(B) In [Fe(C2O4)3] , geometrical isomerism does not exist while optical isomerism exists
– 2–
(C) CO bond order : [Ni(CO)4] > [Co(CO]4] > [Fe(CO)4]
(D) [Ni(Cl2)(PPh3)2] has two geometrical isomers.
6) The reagent (s) that can selectively precipitate S2– from a mixture of S2– and in aqueous
solution is (are)
(A) CuCl2
(B) BaCl2
(C) Pb(OOCCH )
3 2
(D) Na2[Fe(CN)5NO]
SECTION - II
1)
Find the number of correct order(s) regarding their given property :
(I) (Acidic strength)
(II) (Resonance energy)
(III) (Stability of diene)
(IV) (Basic strength)
(V) (Stability of alkene)
(VI) (Stability of anion)
2)
How many alkenes are possible on dehydrohalogenation of following compound :
3)
The nitration will mainly take place at position
4) Equal mass of A & B are present in liquid solution then total pressure exerted by vapours is X
torr, Give the value of .
[A = 80 gm/mol, B = 120 gm/mol]
5) Number of ions which are identified by dil. HCl from the following.
(i) SO42– (ii) CO32–
(iii) SO32– (iv) HCO3–
(v) NO2– (vi) NO3–
(vii) CH3COO– (viii) PO43–
6) How many species are coloured ?
AgCl, CaC2O4, Fe4[Fe(CN)6]3, [Cu(NH3)4](NO3)2, Zn2[Fe(CN)6], [Ni(DMG)2], NO2, CrO42–
MATHS
SECTION - I (i)
1) If the function is continuous at x = π, then k equals -
(A)
(B)
(C) 2
(D) 0
2) Let ƒ(x) = and g(x) = . If ƒ(g(x)) is continuous at x = 1
then
(A)
(B)
α= ,β=5
(C)
α= ,β=–5
(D)
α = , β = 10
3)
Let k be a non-zero real number. If
f(x) =
is a continuous function, then the value of k is
(A) 1
(B) 2
(C) 3
(D) 4
4) Let ƒ (x) = , then ƒ (x) is continuous at :-
(A) only one point
(B) only two points
(C) only three points
(D) infinite number of points
5) The value of is
(A) 1
(B) e
(C) e2
(D)
6) If the function is continuous at x = 0, then the value of a is equal to
:
(A) 32
(B)
(C)
(D)
SECTION - I (ii)
1) Let cos for x ≠ 1. Then
(A) does not exist
(B) does not exist
(C)
(D)
2) If f(x) = is
(A) when x < 1
(B) when
(C) when
(D)
when x > 16
3) If where & , then the
possible value(s) of α is/are
(A)
(B)
(C)
(D)
4) For the function ƒ(x) = |x + 3| – |x + 1| – |x – 1| + |x – 3|, identify correct option(s)
(A) Range of ƒ(x) is (–∞, 4]
(B) maximum value of ƒ(x) is 4
(C) ƒ(x) = 4 has infinite solutions
(D) ƒ(x) = 0 has infinite solutions
5) Let [x] be the greatest integer function is
(A) not continuous at any point
(B) continuous at
(C) discontinuous at 2
(D) differentiable at
6) does not exist when -
where [x] denotes step up function & {x} fractional part function.
(A) f(x) = [[x]] – [2x–1], c = 3
(B) f(x) = [x] – x, c = 1
(C) f(x) = {x}2 – {–x}2, c = 0
(D)
f(x) = ,c=0
SECTION - II
1) Let . If ƒ(x) is continuous at x = 0 then the value of (α + β) is
2) Let ƒ : R → R be a function defined by . The value of is equal
to
3) Let ƒ(x) = ax + b, with a, b real numbers, ƒ1(x) = ƒ(x) & ƒn+1(x) = ƒ(ƒn(x)); n ∈ N.
If ƒ7(x) = 128x + 381, then (a + b) is
4) If and , then is equal to
5) If ƒ(x) = x11 + x9 – x7 + x3 + 1, then ƒ(sin–1(sin3)) + ƒ(tan–1(tan3)) is equal to
6) If , then 24ℓ, is
ANSWER KEYS
PHYSICS
SECTION - I (i)
Q. 1 2 3 4 5 6
A. D A C C B D
SECTION - I (ii)
Q. 7 8 9 10 11 12
A. A,C,D A,C A,C A,B B,C B,D
SECTION - II
Q. 13 14 15 16 17 18
A. 9.00 3.00 12.00 6.00 18.00 2.00
CHEMISTRY
SECTION - I (i)
Q. 19 20 21 22 23 24
A. C A A C A B
SECTION - I (ii)
Q. 25 26 27 28 29 30
A. A,B,C,D B,C B,C,D A,B,C A,B,C A,C
SECTION - II
Q. 31 32 33 34 35 36
A. 4.00 8.00 4.00 6.00 5.00 5.00
MATHS
SECTION - I (i)
Q. 37 38 39 40 41 42
A. A A C B B B
SECTION - I (ii)
Q. 43 44 45 46 47 48
A. A,C A,C,D B,C B,C,D B,C,D B,C
SECTION - II
Q. 49 50 51 52 53 54
A. 0.00 2.00 5.00 1.00 2.00 6.00
SOLUTIONS
PHYSICS
1) tan θ =
tan θ = 2 cot θ
θ=
2)
Correct answer is (1).
3)
Correct answer is (3).
4) Correct answer is (3).
5) (0, a, a); (0, a, –a); (0, 0, –a)
& tan–1 with z-axis in y-z plane
6)
Explain Question :- A network of resistors is given in which the resistance between any two
junctions is R. We are asked to find the equivalent resistance between the terminals A and B.
Concept :-This question is based on series- parallel combination reduction.
Solution :-
→ →
For R and in parallel equivalent resistance
Final answer :- (4)
7)
Correct answer is (1), (2) and (4).
8)
Current get divided equally of each node.
(A)
(B) VA – VB = 10 – 3 = 7V
9)
(B) the small segment is a ring so for ring
=
(A) if
(C) distance of charge from O is same
(D)
=
Q=
10)
Assuming over lapped area to be filled with +r & – r & calculating field at P.
∴ Eresult = =
11)
Correct answer is (2) and (3).
12)
Correct answer is (2) and (4).
13)
applying KCL at junction A & B ;
I= &I=
we get, x = &I=
14)
15)
∴ Using conservation of energy,
Here,
16)
Hence
17) Solution will be 18.00.
18)
Solution will be 2.00.
CHEMISTRY
19)
Explanation Question: We have to find which complex has least electrical conductivity
Concept: Based on werver theory
Solution:
Conductivity µ no. of ion
[Co(NH3)3Cl3] → 0 ion
Final Answer: Option (3)
20) Question Explanation:
Identify X, Y, and Z in the silver-thiosulfate reaction.
Concept:
Reaction of with excess and subsequent hydrolysis.
Solution:
Step 1: When silver nitrate is added to an excess of sodium thiosulfate, a soluble complex X is
formed, resulting in a clear solution:
Step 2: Adding more ions causes the precipitation of silver thiosulfate Y, which is a white
solid:
Step 3: Silver thiosulfate is unstable in aqueous solution. "With time," it undergoes hydrolysis
(disproportionation) to form silver sulfide Z, which is a black precipitate:
Final Answer: The correct option is (1).
21)
Correct answer is (1).
22)
Explanation of Question: Question is asking about identification of enantiomeric pair.
Concept: This question is based on stereoisomeric relationship between compounds.
Solution:
23)
Explain Question :
Asking the stereochemical concept [retention of configuration] in given reactions of alcohol.
Concept :
This question is based on SN2 mechanism.
Stereochemistry of SN2 reaction → Inversion of configuration (Walden inversion)
Solution :
If nucleophile attack at chiral atom in SN2 reaction then inversion of configuration is observed
otherwise retention of configuration is seen in the product.
(1)
(2) Inversion in product
(3) Inversion in product
(4) Inversion in product
Final Answer : (1)
24) Question Explanation:
The question asks for the major product of a two-step reaction: first, the addition of HCl to an
alkene followed by an intramolecular FC reaction.
Concept: This question is based on
A. Electrophilic Addition to Alkenes (Markovnikov's Rule)
B. Friedel-Crafts Alkylation, (Intramolecular EAS).
Solution: Reactions are as follows:
Final Answer: Option (2)
25) More the α–H more will be reactivity for Aromatic electrophilic substitution.
26)
Correct answer is (2) and (3).
27)
E, F and E, G are tautomers.
F and G are geometrical isomers and diastereomers.
28) S-I : effective molarity = 0.4 M
S-II : effective molarity = 0.2 + x = 0.24 M
S-III : effective molarity = 0.2 M
⇒ x = 0.04
∴ [BCl] =
Now, conc. S- III < S - II < S- I
29) (A) Pt(78) [Xe]54 4f14 5d9 6s1
0
Pt2+ 5d8 6s
It has dsp2 hybridisatio, square planar shape.
Cu(29) [Ar] 3d10 4s1
0
Cu2+ 3d9 4s
[Cu(NH3)4]2+
It has dsp2 hybridisation, square planar shape.
(B) [Fe(C2O4)3]3– is
M(a – a)3 type complex.
(C) CO bond order : [Ni(CO)4] > [Co(CO]4]– > [Fe(CO)4]2–
Because e– density ox central metal increase then synergic bonding increases so CO bond
order increases.
(D) [Ni(Cl)2(PPh3)2] has two geometrical isomers.
[Ni(Cl)2(PPh3)2] ⇒ Td ⇒ No G.I.
30) (A)
(B)
(C)
(D)
31)
Solution will be 4.00.
32)
Question Explanation:
The question asks how many distinct alkenes (including geometrical and optical isomers) are
formed when the given alkyl chloride undergoes dehydrohalogenation.
Concept:
Dehydrohalogenation, E2 Elimination, Geometrical Isomerism, Optical Isomerism
Solution:
Elimination of HCl can occur from different β-hydrogen positions, giving three different alkene
skeletons.
• One alkene has both geometrical isomerism as well as optical isomerism , giving 4 products.
• Second alkene shows only E/Z isomerism → 2 products.
• Third alkene forms a chiral alkene without geometrical isomerism → 2 optically active
products.
Total alkenes = 4 + 2 + 2 = 8
Final Answer: 8
33)
Solution will be 4.00.
34) Explain the question: Calculate the total vapor pressure of a solution with equal masses
of A and B.
Concept: Raoult's Law and Dalton's Law of Partial Pressures.
Solution: From the given pressure-composition graph, the vapor pressure of pure liquid
is 40 torr, and the vapor pressure of pure liquid is 30 torr. Since the solution
contains equal masses (let's say 'w' grams) of A and B, we first calculate their mole fractions.
The moles of A are , and the moles of B are . The mole fraction of A is
. Consequently, the mole fraction of B
is 0.4 . The total pressure X is calculated using Raoult's and Dalton's laws:
. Substituting the values, we get
torr. The question asks for the value of .
The value of X/ 6 is 36/6 = 6
Final Answer: 6
35) Question Explanation:
Identification of acidic radicals using dilute hydrochloric acid.
Concept: Preliminary Test for Acidic Radicals (Group I).
Solution:
Dilute HCl decomposes salts of weaker acids to evolve characteristic gases.
• Included:
.
• Excluded: require concentrated H2SO4 or specific individual
tests for identification.
Calculation:
Identifiable ions: (ii), (iii), (iv), (v), (vii)
Total count = 5
Final Answer: 5
36)
Solution will be 5.00.
MATHS
37)
38)
Correct answer is (1).
39) Since f(x) is a continuous function
∴ f(x) = f(0)
⇒ = 12
⇒ 4k = 12 ⇒ k = 3
40) ƒ (x) is continuous at those points where
x3 + 3x2 + 6x – 4 = 4x2 + 11x – 1
x3 – x2 – 5x – 3 = 0
(x – 3)(x + 1)2 = 0
x = –1 & 3
41) Ans. (2)
42)
Correct answer is (2).
43) Solution:
Final Answer: Option (1), (3)
44)
Correct answer is (1), (2) and (4).
45)
As
as
46)
Question Explanation: Analyze a multi-modulus function to find its range and solution
behavior.
Concept: Piecewise Modulus Functions and Graph Analysis.
Solution:
The function is analyzed by breaking it into intervals based on its critical points: -3, -1, 1, and
3. By checking each interval, we determine the function's behavior (constant or linear), which
reveals the range and the nature of its solutions.
f(x) = |x + 3| – |x + 1| – |x – 1| + |x – 3|
x 3
f(x) = x + 3 – x– 1 – x + 1 + x – 3 = 0
1 x<3
f(x) = x + 3 – x – 1 – x + 1 – x + 3 = 6 – 2x
–1 x < 1
f(x) = x + 3 – x – 1 + x – 1 – x + 3 = 4
–3 x < – 1
f(x) = x + 3 + x + 1 + x – 1 – x + 3 = 2x + 6
x<–3
f(x) = – x – 3 + x + 1 + x – 1 – x + 3 = 0
Range = [0,4]
f(x)max = 4
f(x) = 4 for x ∈ [–1,1]
f(x) = 0 for x ∈ (–∞,–3] ∪ [3,∞)
Final Answer: Options (2,3,4)
47) f(x)
f(x) continous at
f(x) dis continous at x = 2
f(x) differentiable at
48) (A) as
(B) f(x) = [x] – x = – {x} ; Clearly,
(C) as
(D) as
49)
so α + β = 0,
50) ƒ(x) + ƒ(1 – x) =
51)
f1(x) = ax + b
f2(x) = a(ax + b) + b = a2x + b(1 + a)
f3(x) = a(a2x + b(1 + a)) + b
= a3x + b(1 + a + a2)
.
.
f7(x) = a7x + b(1 + a + a2 ..... a6) = 128x + 381
a7 = 128
& b(1 + a + a2.....a6) = 381
So, a = 2
& b(1 + 2 + 4 + 8 + 16 + 32 + 64) = 381
b=
a+b=2+3=5
52)
=1
53) sin–1(sin3) = π – 3
tan–1(tan3) = 3 – π
so ƒ(π – 3) + ƒ(3 – π)
Let (π – 3) = t
ƒ(t) + ƒ(–t) = 2
54)
= vr – vr+1
t0 + t1 +....... + tn = v0 – vn+1
∴ 24ℓ = 6