14-06-2026

1001CJA101032260002 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) Given that log2a = s, log4b = s2 and . If can be expressed in terms of

's' as αs3 + βs2 + γs – 3 (a, b, c > 0, c ≠ 1) then

(A) α = –3
(B) β = –10
(C) α + β + γ = 9
(D) γ = 2

2) If f(x) = ax2 + bx + c is such that (f(0))2 + (f(1))2 + (f(–1))2 + 30 = 4f(0) + 10f(1) + 2f(–1) then

(A) Range of f(x) is [1, ∞)

(B) The graph of f(x) is completely above the x-axis
(C) The equation f(x) = 10 has two real & distinct roots
(D) The equation f(x) = sinx has no real roots

3) If domain of the function f(x) = is A then possible value(s) of x ∈ A satisfying the

equation 6{x}2 – 5{x} + 1 = 0 is/are (where {.} denotes fractional part function)

(A)

(B)

(C)

(D)

4) If f : R → [–1, 1], where f(x) = sin , (where [.] denotes the greatest integer function) then

(A) f(x) is into

(B) f(x) is onto
(C) f(x) is one-one
(D) f(x) is many-one

5) If ax + b is remainder when x4 – x2 is divided by x2 – 3x + 2 then

(A) a = 12
(B) b = 12
(C) b = –12
(D) a + b = 0

6) Consider the arrangement and .... so on then correct option's is/are

-

(A) first term of 15th row is 197

(B) first term of 15th row is 201
let ti be the number of terms in ith row then
(C)

(D)
let ti be the number of terms in ith row then

SECTION-I (ii)

1)

List-I List-II

Number of solutions of the equation

(I) (P) 7
sin2x – 2cosx + 4sinx = 4 in the interval [0, 5π] is

Number of values of θ ∈ (0, π) such that

(II) (Q) 2
sin(θ) + sin(4θ) + sin(7θ) = 0, are

Number of values of x ∈ [0, 2π] satisfying the equation

(III) (R) 3
cosx + cos2x + cos3x + cos4x = 0, are

(IV) Number of values of x ∈ satisfying (S) 6

the equation cosx + sinx = 1, are

(T) 1
(A) I → S;II → R;III → Q;IV → P
(B) I → R;II → S;III → P;IV → Q
(C) I → P;II → Q;III → S;IV → R
(D) I → Q;II → S;III → Q;IV → R

2)
 List-I List-II

10th term of the sequences

(I) (P) 1620
S = 1 + 5 + 13 + 29 + ... is

The sum of all the two digit numbers which are

(II) (Q)
not divisible by 2 or 3, is

The sum
(III) (R) 2045
upto ∞ is

(IV) If the first two terms of H.P. are & respectively, (S)
then the harmonic mean of the first four terms, is

(T) 1520
(A) I → R;II → P;III → Q;IV → S
(B) I → R;II → S;III → P;IV → Q
(C) I → Q;II → R;III → S;IV → Q
(D) I → S;II → P;III → Q;IV → R

3)

List-I List-II

(I) (P) (0, 1] ∪ [4, 5)

Domain of , is

(II) (Q) (2, 3)

Domain of , is

(III) (R) [2, ∞)

Domain of , is

(IV) Domain of , (S) [–1, 1]

is

(T) (–∞, 0)
(A) I → S;II → R;III → Q;IV → P
(B) I → Q;II → S;III → P;IV → R
(C) I → R;II → P;III → S;IV → Q
(D) I → R;II → S;III → P;IV → Q

4)

List-I List-II

(I) Range of f(x) = sin(log2x), is (P)

(II) Range of f(x) = sin2x + cos4x, is (Q) [4, ∞)

 (III) Range of f(x) = 4x + 2x + 1, is (R) (1, ∞)

(IV) Range of f(x) = , (S) [–1, 1]

is

(T) (–∞, –1)

(A) I → R;II → P;III → S;IV → Q
(B) I → S;II → Q;III → P;IV → R
(C) I → S;II → P;III → R;IV → Q
(D) I → R;II → S;III → Q;IV → P

SECTION-II

1) If the minimum possible real value of x satisfying the equation

is λ, then find |log2λ|.

2) If α, β are the roots of the equation x2 – 6x + 4 = 0 then find the value of

3) If the domain of the real valued function f(x) = + x2 ℓn (x + 4) is (a, b] then (b – a) =

4) If f(x) = is a one-one function, then find the number of possible

integral values of 'a'.

5) Find the number of solutions of the equation 4[x] = x + {x}, (where [.] & {.} denotes greatest
integer & fractional part functions respectively)

6) If & , then find the value of A2 + B2.

7) Find the number of solution(s) of equation x2 + 48 + {x} + {–x} = 14x (where {x} denotes
fractional part of x)

8) For an increasing G.P. a1, a2, a3, ..., an, if a6 = 4a4, a9 – a7 = 192, then the value of , is

PART-2 : PHYSICS

SECTION-I (i)
1) Symbolic objects are constructed out of sticks of equal length and mass. The location of the centre
of mass is described using the coordinate system depicted in the sample.

The centre of mass lies at x = 0, y = 0. Consider following symbols :

(A) The centre of mass is at x > 0 and y = 0 for symbol (P)

(B) The centre of mass is at x = 0 and y > 0 for symbol (R, T)
(C) The center of mass is at x > 0 and y > 0 for symbol (Q, S)
(D) The centre of mass is at x = 0 and y = 0 for symbol (T)

2) The engine of a car of mass 2000 kg has a normal rated power 80 kW. It experiences a constant

resistive force which is of its weight when it is travelling on a straight road. Now, this car
accelerates from rest at 2 m/s2.

(A) The maximum duration of uniform acceleration will be 5 second.

(B) The maximum velocity during the uniform acceleration will be 10 m/s.
(C) The maximum velocity of the car will be 20 m/s.
(D) The maximum velocity of the car will be 10 m/s.

3) Calculate the following for the situation shown:

(A) Speed at D is .
(B) Normal reaction at D is 3mg.

(C)
Height H is .
(D) Normal reaction at D is 4mg.

4) Potential energy of system is given by U = (–x3 + 10)J then :-

(A) Force at origin is zero

(B) Force at x = 1 is
(C) If Kinetic energy at origin is zero then kinetic energy at x = 1 is 1J
(D) If Kinetic energy at origin is 20J then kinetic energy at x = 1 is 21J

5) On a train moving along east with a constant speed v, a boy revolves a bob with string of
length on smooth surface of a train, with equal constant speed v relative to train. Mark the correct

option(s).

(A) Maximum speed of bob is 2 v in ground frame.

(B)
Tension in string connecting bob is at all the moments.

(C)
Tension in string is at all the moments.
(D) Minimum speed of bob is zero in ground frame.

6) A car runs around a curve of radius 10 m at a constant speed of 10 ms–1. Consider the time
interval for which car covers a curve of 120° arc :-

(A) Resultant change in velocity of car is ms–1

(B) Instantaneous acceleration of car is 10 ms–2

(C)
Average acceleration of car is ms–2
(D) Instantaneous and average acceleration are same for the given period of motion.

SECTION-I (ii)

1) ACB is a smooth quarter circular path of radius R. Four forces are acting at a particle placed at A,
F1 is always horizontal, F2 is always vertical, F3 is always tangential to path, F4 is always directed

from particle's position to point B. Magnitude of all forces are equal to F.

List-I List-II

(I) work done by F1 is (P) FR

(II) work done by F2 is (Q)

 (III) work done by F3 is (R)

(IV) work done by F4 is (S)

(T) Zero
(A) I → P;II → P;III → R;IV → Q
(B) I → Q;II → T;III → R;IV → S
(C) I → Q;II → P;III → T;IV → R
(D) I → R;II → T;III → Q;IV → S

2) In the given figure.

List-II
(values in
List-I
appropriate SI
unit)

If F = 50 N, θ = 53°
(I) (P)
and then acceleration of block is

If F = 100 N, θ = 37° and µ = 1.5

(II) (Q)
then acceleration of block is

If F = 200 N, θ = 53° and µ = 1.0

(III) (R)
then acceleration of block is

If F = 110 N, θ = 90° and µ = 0.2

(IV) (S)
then acceleration of block is

(T)
(A) I → Q;II → S;III → P;IV → R
(B) I → S;II → R;III → P;IV → Q
(C) I → Q;II → Q;III → R;IV → S
(D) I → R;II → Q;III → T;IV → S

3) A particle is suspended from a string of length R. It is given a velocity at the bottom.

Match the following :

 List-I List-II

(I) Velocity at B (P) 7 mg

(II) Velocity at C (Q)

(III) Tension in string at B (R)

(IV) Tension in string at C (S) 5 mg

(T) None of these

(A) I → R;II → Q;III → P;IV → T
(B) I → Q;II → S;III → R;IV → P
(C) I → Q;II → T;III → P;IV → S
(D) I → P;II → Q;III → S;IV → R

4) A block of mass m kg is sliding from rest on an inclined rough surface of inclination θ = 37° as
shown in the figure under the action of three forces; weight, normal and frictional force only. The
magnitude of forces are 20 N, 40 N and 50 N not necessarily in the same order. The value of g is 10
m/s2. Now match the physical quantity in List-I with their magnitude in List-II in SI unit and select
the correct answer using the codes given below the lists: (assume that the coefficient of kinetic

friction is less than 1).

List–I List–II

(I) Mass of the block (A) (P) 2

(II) Acceleration of block (A) (Q) 4

(III) Net force acting on the block during motion (R) 5

Coefficient of friction between inclined surface

(IV) (S) 10
and block A is μ, then value of 8μ will be.

None of
(T)
these
(A) I → R;II → P;III → S;IV → Q
(B) I → P;II → Q;III → R;IV → S
(C) I → S;II → P;III → Q;IV → T
(D) I → R;II → P;III → R;IV → Q

SECTION-II
1) A ball is projected horizontally at 5 m/s from the top of a tower of height 160 m. Find horizontal
distance (in m) covered by the ball when it strike on horizontal ground. (Take : g = 10 m/s2)

2) A boat is moving with a velocity with respect to ground. The water in the river is moving
with a velocity with respect to ground. The relative velocity of the boat with respect to water
has magnitude :-

3) An elevator is moving upward with a constant speed of 10 m/s. A man standing in the elevator
drops a coin from a height of 2.5 m from floor of elevator. The coin reaches the floor of the elevator

after a time sec. What is the value of t?

4) A block of length 30 cm is placed on a smooth table. It is being pulled from both the ends as
shown in the figure. Find the tension(in N) in rod at a distance 10 cm from left end A.

5) Two identical bead of mass m are connected by a light string, can slide on a smooth ring. Both are
released from rest from the position shown in figure. Find initial acceleration (in m/s2) of bead A.
6) Two springs are connected as shown in figure and the force F is applied at one end as shown in
figure. What is the ratio (U1/U2) of potential energy stored in the springs? ( K1 = 8 units and K2 = 20

units)

7) A particle of mass m moving along a straight line experiences force F which varies with the

0
distance x travelled as shown in the figure. If the velocity of the particle at x is , velocity at

4x is , then value of p is :-

8) A plank P and block Q are arranged as shown on a smooth table top. They are given velocities 3
m/s and 6 m/s respectively. The length of plank is 1m and block is of negligible size. After some time
when the block has reached the other end of plank it stops slipping on plank. Find the coefficient of
friction between plank P and block Q if mass of plank is double of block.

PART-3 : CHEMISTRY

SECTION-I (i)

1) Which of the following statement(s) regarding atomic and ionic radii is/are correct?

For the isoelectronic species O2–, F–, Na+ and Mg2+, the order of ionic radius is O2– > F– > Na+ >
(A)
Mg2+.
(B) A cation is smaller in size than its parent neutral atom.
(C) An anion is smaller in size than its parent neutral atom.
(D) Atomic radius generally decreases on moving from left to right across a period.

2) For the reaction A → B, the rate law expression is = k [A]1/2. If initial concentration of [A] is
[A]0, then
(A)
The integrated rate expression is k =

(B)

The graph of vs t will be

(C)
The half life period,

(D)
The time taken for 75% completion of reaction

3) For a first order reaction A(g) → 2B(g) + 2C(g) at constant volume and 300K, total pressure at the
beginning (t = 0) and at time t = 30 sec are 1 atm and 1.75 atm respectively. Initially only gas A is
present. The correct option(s) is/are : (Assume that all gases behave ideally)
Given : ln 2 = 0.7, ln 3 = 1.1 and ln 10 = 2.3

(A) Initial rate of formation of C is zero.

(B) Rate of formation of B decreases with time.
(C) Rate constant for formation of B is 1.2 min–1.
(D) Partial pressure of B at t = 140 sec is 1 atm.

4) Which carbocation(s) is/are more stable than :

(A)

(B)

(C)

(D)

5) Which of the following statement(s) regarding ground - state electronic configurations is / are
correct ?

(A) The ground-state configuration of Cu (Z = 29) is [Ar] 3d10 4s1.

(B) The ground-state configuration of K (Z = 19) is [Ar] 3d1.
(C) The Fe2+ ion (Z of Fe = 26) has the configuration [Ar] 3d6.
(D) A neutral phosphorus atom (Z=15) has three unpaired electrons in its ground state.
6) Which pair of compounds is/are correctly written with their isomerism?

(A)
& : Position isomers

(B)

& : Chain Isomers

(C)

& : Functional Isomers

(D)
& : Geometrical Isomers

SECTION-I (ii)

1) Match each period-3 element in List-I with its approximate first ionization energy (kJ/mol) in List-
II, and choose the correct option.

List-I List-II

(P) Na (1) 496

(Q) Mg (2) 738

(R) Al (3) 577

(S) Si (4) 786

(5) 1000
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 1;Q → 3;R → 2;S → 4
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 1;Q → 2;R → 4;S → 3

2)

List-I List-II
(Graphs for reaction : A → (Coordinates, y-axis vs. x-
Products) axis)
 (P) (1) In [A] vs. t (order = 1)

(Q) (2) t1/2 vs. [A0] (order = 1)

(R) (3) r vs. t (order =1)

(S) (4) r vs. t (order = 0)

(5) r vs. [A] (order =1)

(A) P → 1;Q → 4;R → 3;S → 5
(B) P → 2;Q → 1;R → 5;S → 3
(C) P → 5;Q → 2;R → 1;S → 4
(D) P → 3;Q → 4;R → 2;S → 5

3)

List-I List-II

(P) –NO2 (1) –I

⊖
(Q) –O (2) +I

(R) (3) –M

(S) (4) +M

(5) +H
(A) P → 2;Q → 4;R → 3;S → 1
(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 5;Q → 2;R → 5;S → 3
(D) P → 4;Q → 2;R → 1;S → 4

4)

List-I List-II
 Alkene do not have hyper
(P) (1)
conjugation

(Q) (2) More stable alkene

Minimum heat of
(R) (3)
hydrogenation

Maximum heat of
(S) (4)
hydrogenation

(5) Aromatic carbocation.

(A) P → 1;Q → 2;R → 4;S → 5
(B) P → 2;Q → 2;R → 3;S → 1
(C) P → 3;Q → 4;R → 1;S → 4
(D) P → 3;Q → 2;R → 5;S → 1

SECTION-II

1) For the principal quantum number n = 4, the maximum number of electrons in an atom that can
have spin quantum number ms = +1/2 is N. Find N.

2)

In the following reaction : xA —→ yB

log = log + 0.3010 where –ve sign indicates rate of disappearance of the reactant then

ratio of will be :

3) V1 ml of 0.2 M NaNO3 and V2 ml of 0.1 M Ca(NO3)2 solution are mixed so that in resulting solution,

the concentration of –ve ion is 50% greater than the concentration of +ve ion then find ?

4) A sea diver is using a gas mixture of N2, O2 and He. This mixture contains 40% He, 40% O2 and
20% N2. If solubility of O2 (in terms of mole fraction) in blood at depth of 50 m is and total
4
pressure is 8 atm at this point (assume T = 37°C). Write your answer as × 10 . Given Henry
constant for O2 is 2.026 × 103 MPa. (Use : 1 atm = 1.013 × 105 Pa)

5) The number of resonanting structure of given compound

6) In how many species lone pair(s) is/are delocalised

(i) (ii) (iii) (iv)

7) Consider an ion of Iron(II) (Fe2+, atomic number z = 26) in its ground state. Let X be the number
of electrons having the azimuthal quantum number l = 2. Let Y be the total number of electrons in
the ion having the magnetic quantum number ml = 0 . Calculate the minimum numerical value of
(X×Y).

8) Calculate total number of inner transition elements discovered till now.

 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,C,D A,B,C,D A,B,C,D A,D A,C,D A,C

SECTION-I (ii)

Q. 7 8 9 10
A. B A D C

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 3.00 257.00 5.00 7.00 1.00 2.00 2.00 2.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,D A,B,C A,C,D A,B,C,D A,C,D A,B

SECTION-I (ii)

Q. 25 26 27 28
A. A C A A

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 28.28 10.00 1.00 24.00 5.00 2.50 11.00 0.30

PART-3 : CHEMISTRY

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,B,D A,B,D B,C A,B,D A,C,D A,B,C,D

SECTION-I (ii)

Q. 43 44 45 46
A. A A B A
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 16.00 0.50 2.00 1.60 10.00 3.00 66.00 28.00
 SOLUTIONS

PART-1 : MATHEMATICS

1) = 2log2a + 5log2b – 4log2c ....(i)

2
Now log4b = s

= s2 ⇒ log2b = 2s2

∴ (i) can be written as

= –3s3 + 10s2 + 2s – 3

2) ((f(0))2 – 4f(0) + 4) + ((f(1))2 – 10f(1) + 25) + ((f(–1))2 – 2f(–1) + 1) = 0

(f(0) – 2)2 + (f(1) – 5)2 + (f(–1) – 1)2 = 0
⇒ f(0) = 2, f(1) = 5 & f(–1) = 1
f(0) = 0 ⇒
f(1) = a + b + c = 5 ⇒ a + b = 3
f(–1) = a – b + c = 1 ⇒ a – b = –1
⇒ a = 1, b = 2
∴ f(x) = x2 + 2x + 2
= (x + 1)2 + 1
(A) Range of f(x) is [1, ∞)
(B) Since D < 0, a > 0, the curve is completely above the x-axis
(C) f(x) = 10
⇒ x2 + 2x + 2 = 10
⇒ x2 + 2x – 8 = 0
D > 0 ⇒ Roots are real & distinct
(D) f(x) = sinx

Both the curves do not intersect

 ∴ No solution

3) 10x – x2 ≥ 0 ⇒ x ∈ [0, 10]

6{x}2 – 5{x} + 1 = 0

⇒ {x} = ,

⇒x=n+ or x = n +

4) f(x) = sin =
many one & into function

5) x4 – x2 = P(x)(x – 1) (x – 2) + ax + b
⇒ a + b = 0 and 2a + b = 12 ⇒ a = 12 = –b

6) First term of nth row = nth term of series 1, 2, 5, 10....

Applying method of difference
Sn = 1 + 2 + 5 + 10 + ..... + Tn
Sn = 1 + 2 + 5 + ....... + Tn–1 + Tn
Subtracting
0 = 1 + (1 + 3 + 5 + ...... + (n – 1) terms) – Tn
⇒ Tn = 1 + (1 + 3 + 5 + ...... + (n – 1) terms)

Tn = 1 + (2 + (n – 2)2) = 1 + (n – 1)2
∴ T15 = 1 + 142 = 197
Now, number of terms of first row t1 = 1 & t2 = 3
t3 = 5 ..... and so on

Final Answer: Option (A) & (C)

7) (I) sin2x – 2cosx + 4sinx = 4, x ∈ [0, 5π]

2sinx cosx – 2cosx + 4(sinx – 1) = 0
2cosx(sinx – 1) + 4(sinx – 1) = 0
⇒ (sinx – 1) (2cosx + 4) = 0
⇒ sinx = 1 or cosx = –2 (not possible)

⇒ x = (4n + 1) , n ∈ I
 ∴ Number of solutions in [0, 5π] are 3
(II) sinθ + sin4θ + sin7θ = 0, θ ∈ (0, π)
2sin4θ cos3θ + sin4θ = 0
sin4θ(2cos3θ + 1) = 0

sin4θ = 0 or cos3θ =

, n ∈ I or 3θ = 2kπ ± ,k∈I

Number of values of θ ∈ (0, π) are 6.

(III) cosx + cos2x + cos3x + cos4x = 0, x ∈ [0, 2π]
(cosx + cos4x) + (cos2x + cos3x) = 0

or or

∴ Number of values of x ∈ [0, 2π] are 7

(IV) cosx + sinx = 1,

sinx = 1 – cosx

or

⇒ or

⇒ x = 2nπ, n ∈ I or x = (4k + 1) , k ∈ I

x = 0,

∴ number of values of x ∈ are 2.

8) (I) S = 1 + 5 + 13 + 29 + ...
Let Tn = a.2n + b
T1 = 2a + b = 1
T2 = 4a + b = 5
⇒ a = 2, b = –3
∴ Tn = 2.2n – 3
T10 = 2 × 210 – 3 = 2045
(II) Sum of all the two digit natural numbers =
Sum of all the two digit natural numbers either divisible by 2 or 3
= S(div. by 2) + S(div. by 3) – S(div. by 6)

= (10 + 98) + (12 + 99) – (12 + 96)

= 3285
∴ Sum of all the 2-digit natural numbers not divisible by 2 or 3
= 4905 – 3285 = 1620

(III)

...

(IV) For H.P., T1 = , T2 =

∴ For corresponding A.P.,
T1 = 2, T2 = 3, d = 1
∴ T3 = 4, T4 = 5
∴ First four terms of H.P. are

H.M. =

9) (I) f(x) =
⇒ –log0.3(x – 1) ≥ 0 ⇒ log0.3(x – 1) ≤ 0 ⇒ x – 1 ≥ 1 ⇒ x ≥ 2
& x2 + 3x + 14 > 0 ⇒ x ∈ R
∴ x ∈ [2, ∞)

(II) f(x) =

⇒ 0 ≤ 1 – x2 ≤ 1
⇒ –1 ≤ x2 – 1 ≤ 0
⇒ x ∈ [–1, 1]
(III)

⇒ 0 < 5x – x2 ≤ 4
⇒ –4 ≤ x2 – 5x < 0 ⇒ x2 – 5x + 4 ≥ 0 & x2 – 5x < 0
⇒ x ∈ (0, 1] ∪ [4, 5)
(IV) f(x) = log10(1 – log10(x2 – 5x + 16))
1 – log10(x2 – 5x + 16) > 0 ⇒ 0 < x2 – 5x + 16 < 10
⇒ x2 – 5x + 16 > 0 ⇒ ∀ x ∈ R
& x2 – 5x + 6 < 0 ⇒ x ∈ (2, 3)

10) (I) y = sin(log2x)

–∞ < log2x < ∞ ∴ y ∈ [–1, 1]
(II) y = sin2x + cos4x ⇒ y = cos4x – cos2x + 1

0 ≤ cos2x ≤ 1

(III) y = 4x + 2x + 1

∴ f(x) is increasing
As x → –∞, f(x) → 1
As x → ∞, f(x) → ∞
∴ y ∈ (1, ∞)

(IV)
4 ≤ x2 – 2x + 5 < ∞

4≤y<∞
⇒ y ∈ [4, ∞)

11) log2(log2x)2 – log2 =1

⇒ (log2x)2 – 2log2x – 3 = 0
log2x = 3, –1
x = 8,

But x = does not satisfy the given equation

∴λ=8
∴ |log28| = 3

12) α2 – 6α + 4 = 0
α2 – 4α + 4 = 2α
(α – 2)2 = 2α
⇒ (α – 2)16 = 28.α8 ....(1)
β2 – 6β + 4 = 0
β(β – 6) = –4

β–6= ....(2)

∴E=

13) 5 – 4x – x2 ≥ 0
⇒ x2 + 4x – 5 ≤ 0
⇒ (x + 5) (x – 1) ≤ 0
⇒ –5 ≤ x ≤ 1
&x+4>0
⇒ x > –4
∴ Domain is (–4, 1]

14) f(x) = x3 + (a – 3)x2 + x + 5

If f(x) is one-one then
f ′ (x) ≥ 0 ∀ x ∈ R or f ′ (x) ≤ 0 ∀ x ∈ R
Case-I : f ′ (x) ≥ 0
⇒ (4a – 7)x2 + 2(a – 3)x + 1 ≥ 0 ∀ x ∈ R

⇒ 4a – 7 > 0 ⇒ ....(i)
&D≤0
4(a – 3)2 – 4(4a – 7) ≤ 0
a2 – 10a + 16 ≤ 0
....(ii)
(i) ∩ (ii) ⇒ a ∈ [2, 8]
Case-II : f ′ (x) ≤ 0
⇒ (4a – 7)x2 + 2(a – 3)x + 1 ≥ 0 ∀ x ∈ R

⇒ 4a – 7 < 0 ⇒ & .... (iii)

D ≤ 0 ⇒ (a – 2) (a – 8) ≤ 0 ....(iv)
(iii) ∩ (iv) ⇒ a ∈ ϕ
∴ Number of possible integral values of 'a' are 7.

15) 4[x] = x + {x}

let x ∈ I
∴ 4x = x + 0 ⇒
let x I,
x = I + f, 0 < f < 1
4I = I + f + f

3I = 2f ⇒ f =

0< <1 ⇒0<I<

⇒I=0
⇒f=0
∴x=I+f=0
But x I
∴ x = 0 is rejected

16) A =

B=

A2 + B2 =

= 3 + 2cos + 2cos + 2cos

=3+2

17) x2 + 48 + {x} + {–x} = 0

Let x ∈ I, then x2 – 14x + 48 = 0
or x = 8 or 6
x ∉ I, then x2 – 14x + 49 = 0 or x = 7
Not possible

18) Let common ratio is r

a1r5 = 4a1r3 a1r8 – a1r6 = 192
r2 = 4 ⇒ r = 2 256a1 – 64a1 = 192
192a1 = 192
a1 = 1
 =2

PART-2 : PHYSICS

19)

Correct answer are A,D.

20) Feng –
since a = 2 m/s2
∴ Feng = 8000
∴ At max velocity during acceleration,
Feng × v = 80,000 ⇒ vmax = 10 m/s
t = 5 sec. Also maximum velocity is achieved when loss of power due to resistive force equal
power supplied

∴ At max velocity,
⇒ vmax = 20 m/sec

21)

Correct answer are A,C,D.

22)
K+U=E

23) Question Explanation: A boy revolves a bob with respect to the train, on smooth surface
of the train, which is also moving with constant velocity then correct option has to be find
Concept: This question is based on Dynamics of circular motion
Solution:

Maximum speed = 2V
Minimum Speed = 0
Final Answer: Therefore required answer are (1), (3) and (4)
24)

Correct Answer are A,B.

25)

Correct Answer is (A).

26) Question Explanation : The problem asks to match different scenarios of force, angle
and friction with the resulting acceleration of a 10 kg block.
Concept: “This question is based on friction, acceleration, Newton's second law”

Solution:
If Fsinθ < mg then
Fsinθ + N = mg
N = mg – F sinθ
(f)max = µN

and acceleration =
if Fsinθ > mg then
N=0;f=0

Case (1): F = 50 N, θ = 53°, μ = , m = 10 kg

a= = 2m/s2 or 2i
Case (2): F = 100 N, θ = 37°, μ = 1.5, m = 10 kg

a= = 2m/s2 or 2i
Case (3): F = 200 N, θ = 53°, μ = 1.0, m = 10 kg

ay =

ax =

a= = 655 m/s2

Case (4): f = 110 N, θ = 90°, μ = 0.2, m = 10 kg

fy (110 N) > mg (100N)

ay = fy – mg = = 1 m/s2, ax = 0
Final Answer: The correct option is (3)

27)
Work energy theorem A to B

Work energy theorem A to C

At B

At C

28)

Correct Answer is (A).

29) t = & R = vxt

30) =

31)

2.5 =
t = 1 sec.

32)

Correct Answer is 24.

33)
for A T cos 45 = ma for B mg – T cos 45 = ma

34)
 35)

Correct Answer is 11.

36)

m × 6 + 2m × 3 = 3m × VC
VC = 4
with respect to P
0 = 32 – 2 × (3µg/2) × L
µ = 0.3

PART-3 : CHEMISTRY

37) (A) All four are isoelectronic (10 electrons); radius falls as nuclear charge rises → O2– > F–
> Na+ > Mg2+. Correct.
(B) Losing electrons raises the effective nuclear charge felt per electron, so a cation is smaller.
Correct.
(C) An anion is larger than its parent atom, so this is Incorrect.
(D) Across a period the radius decreases as effective nuclear charge rises. Correct.

38) (A)

(B)
y = c + mx

(C) at

(D) at t = 75% A =
=

39) A(g) → 2B(g) + 2C(g)

t=0 1 atm
t = 30 sec 1 – x 2x 2x Ptotal = 1.75 = 1 + 3x
x = 0.25

kA =
For PB = 1 atm = 2x

40) Explanation Question: To select carbocations which are more stable than
Concept: This question is based on stability of carbocation
Solution:

(1) (2) (3) (4)

(1), (2) and (4) are more stable than

Final Answer option : (1)(2)(4)

41) (A) Cu : expected [Ar] 3d94s2 shifts to the fully-filled [Ar] 3d104s1(extra stability). Correct.
(B) K (Z = 19) : 4s is filled before 3d, so the 19th electron enters 4s → [Ar] 4s1, not [Ar] 3d1.
Incorrect.
(C) Fe = [Ar] 3d6 4s2 ; the 4s electrons are lost first → Fe2+ = [Ar] 3d6. Correct.
(D) P = [Ne] 3s2 3p3 ; the three 3p electrons occupy separate orbitals (Hund) → 3 unpaired.
Correct.
∴ correct statements : A,C,D

42) The correct answer is option (A,B,C,D)

43) Values : Na 496, Al 577, Mg 738, Si 786 kJ/mol.

Anomaly: IE1(Mg) > IE1(Al) because Al's 3p1 electron is easier to remove than Mg's 3s2
electron.
So P → 1, Q → 2, R → 3, S → 4, i.e. option (A)

44) The correct answer is option (A)

45)

The correct answer is option (B)

46)

The correct answer is option (A)

47) For n = 4, number of orbitals = n2 = 16, so total electrons = 2n2 = 32.

Each orbital holds one electron with ms = +1/2 → N = 16 (i.e. 16.00).

48)

= = = 0.50

49) Let V1 mL of NaNO3 is mixed with V2 mL of Ca(NO3)2

m M of NaNO3 mixed = 0.2 × V1
m M of Ca(NO3)2 mixed = 0.1 × V2
∵ Mole ratio of Ca2+ : NO3– in Ca(NO3)2 is 1 : 2
∴ Molarity of NO3– in mixture = [NO3–] of NaNO3 + [NO3–] of Ca(NO3)2

= =
Similarly, Molarity of Na+ and Ca2+ in mixture

Now, given that, molarity of NO3– = molarity of Na+ and Ca2+

50)
51)

The correct answer is (10)

52)

The correct answer is (3)

53) The ground - state electronic configuration of a neutral Fe atom (Z=26) is 1s2 2s2
2p6 3s2 3p64s2 3d6.
For the Fe2+ ion, two electrons are removed from the outermost 4s orbital, making the
configuration : 1s22s22p63s23p6 3d6.
Finding X :
The azimuthal quantum number l = 2 corresponds to d-orbital electrons. From the
configuration, there are 6 electrons in the 3d subshell. Thus, X = 6.

Finding Y :
We must count all electrons with magnetic quantum number m1 = 0 across all subshells.
-s-orbitals (l=0) only have ml = 0 : 1s2(2e¯), 2s2(2e¯), 3s2 (2e¯). Total from s-orbitals = 6.
-p-orbitals (l=1) have m1 = –1,0, + 1. The 2p6 and 3p6 subshells are fully filled, so each
contributes 2 electrons with ml = 0. Total from p-orbitals = 4.
–d-orbital (l = 2) have ml = –2,–1,0,+1,+[Link] 3d6 subshell has 6 electrons. Following Hund's
rule, all 5 degenerate orbitals are singly occupied first, and the 6th electron pairs up in one of
the orbitals (conventionally m1=–2 or +2). Therefore, the m1 = 0 orbital contains exactly 1
electron.
Total Y = 6 + 4 + 1 = 11.
Final Calculation :
X × Y = 6 × 11 = 66.

54)

The correct answer is 28.00