12-10-2025

1001CJA106216250189 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A plano convex lens has thickness 4 cm. When it is placed on a horizontal table with curved
surface in contact, the apparent depth of the lens is found to be 3cm and if lens is inverted its
apparent depth is found to be 25/8 cm. Find the magnitude radius of curvature of the lens (in cm).

(A) 12.5
(B) 25
(C) 51
(D) 27

2) Due to manufacturing defect, the plane surface of a thin plano-concave lens has been made tilted
at a small angle θ outwards from its usual place. The spherical surface has radius of curvature R and
refractive index of the material of the lens is µ. A parallel beam of light is incident as shown. In the
co-ordinate system shown find co-ordinates of the point where the rays will focus or appear to be

diverging from.

(A)

(B)

(C)

(D)

3) The area of an equilateral triangle is measured by two methods

I. By using edge length 'a' as Area =

II. By using altitude length 'd' as Area =
Both area measurement are done using the same scale. If the fractional error in the measurement of
area in two methods is f1 and f2 then the correct statement is :

(A) f1 = f2

(B)
f1 = f2
f1 =
(C)

f1 =
(D)

4) Two hemispheres made of glass (µ = 1.5) are kept as shown in the figure. The radius of each
hemisphere is R. The image of point O when looked at from the top is at a distance y from O. The

value of y is given by :

(A) 0

(B)

(C)

(D)

SECTION-I (ii)

1) In ordinary Vernier calipers, 10th division of the Vernier scale coincides with 9th division of the
main scale. In a specially designed Vernier calipers the Vernier scale is so constructed that 10th
division on it coincides with 11th division on the main scale. Each division on the main scale equals to
1 mm. The calipers have a zero error as shown in the figure-I. When the Vernier caliper is used to
measure a length, the concerned portion of its scale is shown in figure-II.
(A) Zero error in the calipers has magnitude 0.7 mm.
(B) The length being measured is 1.08 cm.
(C) The length being measured is 1.22 cm.
Though the given Vernier scale does not follow the principle of Vernier scale, yet can be used
(D)
satisfactorily.

2) A light ray propagates in a graded-index (GRIN) medium whose refractive index varies linearly
with height y as n(y) = n0 + βy, β > 0, n0 > 1. (where n0, β are constant) Using geometrical optics,

the ray equation (under paraxial approximation) reduces to where x is the

propagation axis. The initial conditions are y(0) = y0 and y'(0) = θ0 (with |θ0| << 1). Which of the
following statements are correct ?

(A) 0
The trajectory of the ray is y = y cos(kx) + where k = .

(B)
The minimum radius of curvature is given by ρmin = , where Y = .
The ray always bends with the same radius of curvature, independent of its initial displacement
(C)
y0.
(D) None of these

3) There is a specially designed vernier calipers in which 4 main scale division are equal to 10
vernier scale division. In the zero error, 5th and 10th division of vernier scales coincides with 1 mm
and 3 mm mark on scale respectively and zero of the vernier scale is left to the zero of the main
scale. During taking measurement 2nd and 7th divisions of the vernier scale coincide with 23mm and
25mm mark on main scale respectively. (1 main scale division = 1 mm)

(A) Least count of this vernier calipers is 0.6 mm

(B) Instrument has negative zero error of 1mm
(C) Measurement of the length is 22.2 mm
(D) Measurement of the length is 23.2 mm

4) An object of length 1 cm is placed on a principal axis of equi-convex lens of radius 5 cm. Distance
between the lens and object is 20 cm. space between the lens and object is filled with medium of two
different refractive index 2 and 1 as shown in the figure. Boundary of both medium is mid-way
between the object and lens as shown in figure, (consider all rays are paraxial)
(A) The image will be formed at distance of 7.5 cm from the optical centre.
(B) The image will be formed at distance of 10 cm from the optical centre.
(C) The size of the image is 0.5 cm.
(D) The size of the image is 0.4 cm.

5) Consider a vernier caliper in which each 2cm on the main scale is divided into 8 equal divisions
and 6th divisions of vernier scale coincide with 4th divisions of main scale when zeros of both scale are
at same position. The length of an object is measured then it lies between 12th and 13th division of
main scale and 3rd division of vernier scale coincide with main scale division. The which of the
following(s) is/are correct :

(A)
The maximum possible error in the measurement is .

(B)
The maximum possible error in the measurement is .

(C)
The measured length of object is .

(D)
The measured length of object is .

6) A quarter cylinder of glass is placed on a large table and horizontal beam of light is
incident as shown in the figure. Radius of cylinder is R = 10 cm. After refraction through the quarter

cylinder, rays cross x-axis at x = x . then :

(A) Minimum value of x0 is 15 cm.

(B) Maximum value of x0 is ∞
(C) Minimum value of x0 is 12.5 cm.
(D) Maximum value of x0 is 25 cm.

SECTION-II (i)
Common Content for Question No. 1 to 2
A point object is placed at a distance 5R/3 from the pole of a concave mirror. R is the radius of
curvature of mirror. Point object oscillates with amplitude of 1 mm perpendicular to the principal

axis.

1) The amplitude of image is (in mm).

2) Position of image when object is at O is –xR, find X. (Take pole as origin)

Common Content for Question No. 3 to 4

Generally, speed of sound is determined using resonance column experiment. Resonance tube is a
closed organ pipe. So, the series of frequencies at which it can vibrate is

Where, V = speed of sound

leq = effective length of resonance column (It can be changed by changing the height of water level
in it)

Generally. fn = (2n – 1) .

0 0
If the tube resonates with tuning fork of frequency f : (2n – 1) =f

leq = (2n – 1) [Here n represent nth mode]

Apart from this, at the open end, there is some end correction due to no fixed boundary.

(leq + e) = (2n – 1) . [Generally, e = 0.3 d]

In this experiment, errors introduced are due to end effects, due to excessive humidity, temperature
and due to measurement.

3) A resonance column experiment is performed with a tuning fork of frequency (340 Hz ± 1%).
while performing the experiment, first loud sound was heard at 24.0 cm and 2nd at 74.0 cm. The
scale has least count of 0.1 cm. The diameter (in cm) of tube is

4) The maximum permissible error in measurement of speed of sound is (in %).

Common Content for Question No. 5 to 6

A mirror of length 2ℓ meter makes 10 revolutions per minute (anticlockwise sense) about an axis
crossing its mid point O and perpendicular to the plane of the figure. At t = 0, the mirror is
perpendicular to the line OB. There is a light source at point A and an observer at point B of the
circle of radius R meter drawn around centre O (∠AOB= 90°)

5) What is the value of if the observer B sees the image of the light source for the first time
when the angle Ψ = 15° ?

6) How long (in seconds) (0 ≤ ψ ≤ 90°) can the observer continuously see the light source in the

mirror at such a proportion of (as found in above part).

SECTION-II (ii)

1) At the centre of a cylindrical shaped transparent glass there is an opaque metal cylinder. There is
some transparent liquid in the glass around the cylinder. Observing the cylinder from a distant
point, due to the refraction of light, the part of the cylinder in the liquid seems wider. The radius of
the glass tube is 4 cm, the radius of the metal cylinder is 2.5 cm and the refractive index of the liquid

is 1.5. The apparent increase in the diameter (in cm) of the cylinder is cm. Find 'x'.

2) The adjoining fig. shows object O, final image I formed after two refractions and one reflection is

also shown in fig. Then the magnitude of focal length of the mirror (in cm) is (µ of liquid is ). Round
off to nearest integer.

3) A travelling microscope is used to determine the refractive index of a glass slab. If 40 divisions
are there in 1 cm on the main scale and 50 Vernier scale divisions are equal to 49 main scale
divisions, then the least count of the travelling microscope is___ × 10–6 m.

PART-2 : CHEMISTRY

SECTION-I (i)

1) The structure of a carbonyl compound i.e. ___________ is drawn to appear as if four non bridging
CO ligands form a square plane around the metal atom. In fact the four CO groups do not lie in the
same plane as the metal atom, rather they lie about 12 pm from the plane containing the metal on
then side opposite the metal-metal bond towards another CO ligand.
Select which option is best to fill the blank space.

(A) Co2(CO)8 (Solid)

(B) Mn2(CO)10
(C) Fe2(CO)9
(D) Co2(CO)8 (solution)

2)

Select the most appropriate option of observation during the Ist group cations qualitative analysis
with given reagents in sequence.

Pb+2 Ag+

(i) 2M HCl(aq.)
White PbCl2↓ White Hg2Cl2↓ White AgCl↓
↓
↓ ↓ ↓
(ii) NH4OH
(I) No change No change Dissolve
(excess)
↓ ↓ ↓
↓
Dissolve No change No change
(iii) HOT water
 (i) 2M HCl
White PbCl2↓ White Hg2Cl2↓ White AgCl↓
↓
↓ ↓ ↓
(ii) NH4OH
(II) No change Black Hg↓ + Hg(NH2)Cl ↓ Dissolve
(excess)
↓ ↓ ↓
↓
Dissolve No change No change
(iii) HOT water

(i) 2M HCl
Solution [PbCl4]2– Black Hg↓ + HgCl2 White AgCl↓
↓
↓ ↓ ↓
(ii) NH4OH
(III) No change No change No change
(excess)
↓ ↓ ↓
↓
No change No change Dissolve
(iii) HOT water

(i) 2M HCl
White PbCl2↓ White Hg2Cl2↓ White AgCl↓
↓
↓ ↓ ↓
(ii) NH4OH
(IV) No change No change Dissolve
(excess)
↓ ↓ ↓
↓
Dissolve Black Hg↓ + Hg(NH2)Cl ↓ No change
(iii) HOT water
(A) I
(B) II
(C) III
(D) IV

3)

In the context of variable oxidation state of 3d series metals. Statement given below is not suitable
for which element
"The maximum oxidation state of reasonable stability correspond in value to the sum of the 's' and 'd'
valence electrons".

(A) Titanium
(B) Cobalt
(C) Vanadium
(D) Manganese

4) During the test of phosphate ion we have to add conc. HNO3 and ammonium molybdate solution to
test solution, a _______coloured precipitate is formed during the precipitation reaction. Each oxygen
of phosphate has been replaced by ________group.
Select best option to fill blank space respectively.

(A) White, Mo3O12

(B) Yellow, MoO3
(C) Yellow, Mo3O12
(D) Yellow, Mo3O10

SECTION-I (ii)
1) Consider the following complex salt and select CORRECT statement(s).
Tetraamminediaquacobalt(III) sulphate trihydrate

(A) It is 2 : 3 electrolyte & show geometrical isomerism

Its 1 molal (1m) aqueous solution has Van't Hoff factor = 5 and its 1 molar (1M) 1 litre, solution
(B)
produce three mole BaSO4(s) with excess BaCl2(aq.)
(C) It is diamagnetic & show optical isomerism
(D) It is formula has total seven H2O eight NH3

2) If Potassium iodide is heated with conc. H2SO4 then what is/are the reduced product(s) obtained
by reaction.

(A) I2
(B) SO2
(C) H2S
(D) Sulphur

3) Take 1 mL of an aqueous solution of the nitrate salt and mix the freshly prepared ferrous sulphate
solution thoroughly. Now, add 2 mL conc. H2SO4 slowly along the sides of the test tube dropwise so
that it forms a layer on the top of the liquid already present in the test tube. A dark brown compound
is formed at the junction of the two solutions
Select CORRECT statement(s) :-

(A) Brown compound is nitrosoferrous sulphate i.e. [Fe(NO)]SO4

Observation is same if alternatively first conc. H2SO4 is added om cold solution and then
(B)
FeSO4(aq.) is added along the side of test tube dropwise.
(C) Brown compound form has spin magnetic moment =
(D) Brown compound is not formed if aq. salt is treated with sulphamic acid before test

4) Select option in which Set-I have atleast two species have same coloured in Set-II all the species
have same spin magnetic moment.

Set-I → [V(H2O)6]Cl2 , Mn+3(aq.) , Ni(OH)2

(A)
Set-II → [V(H2O)6]Cl2 , Cr+3(aq.) ,
Set-I → [CoCl4]2– , [Cu(NH3)4]SO4 , KFe[Fe(CN)6]
(B)
Set-II → [CoCl4]2– , [Cu(NH3)4]SO4 , K3[Fe(CN)6]
Set-I → [Mn(H2O)6]+2 , [Co(H2O)6]+2 , [Phenolphthalein (HPh) + K2CO3(aq.)]
(C)
Set-II → [Mn(H2O)6]+2 , [MnCl4]2– , [FeF6]3–
Set-I → [CoCl4]2– , [Co(H2O)6]2+ , Ni(OH)2
(D)
Set-II → [V(H2O)6]Cl2 , [Cu(NH3)4]SO4 , [FeF6]3–

5) Select CORRECT about electrolysis step used during preparation of potassium permanganate -

(A) Electrolysis is used to convert MnO2 to

(B) Electrolysis is perform in alkaline medium
(C) Electrolysis involve Electrolytic oxidation of manganate (VI) ion
(D) H2 is one of the side product

6) Select the CORRECT order of mention properties for the given transition metal or their oxo
anions.

(A)

(B)

(C)

(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

Consider the Chromium (III) complexes [Cr(NH3)5L]+n
where L = Cl– , H2O and NH3
The complex compound absorbs visible energy is given in table for d-d transition.
Match the table to solve given two questions.

Column-I
Column-II
(L in given
(λ absorb)
Chromium complex)

(A) L = Cl– (P) 480 nm

(B) L = H2O (Q) 465 nm

(C) L = NH3 (R) 515 nm

Given that :-
h = 6.6 × 10–34 (J-sec) , velocity of light = 3 × 108 m/s
R = 1 × 107 m–1 , NA = 6 × 1023 ; Atomic number of Cr = 24

1) Calculate the crystal field splitting energy (Δ0) in kJ/mole for the complex [Cr(NH3)5L]+n which has
smallest value of 'n' by considering appropriate L in column-I

2) Calculate crystal field stabilization energy (in kJ/mole) for the homoleptic complex.

Common Content for Question No. 3 to 4

Consider information of given two solid salts i.e. salt A and salt B
SALT A - It exist as tetrahydrated form and freely soluble in water, aqueous solution of salt-A
initially produce white precipitated (P1) with NaOH(aq.) , which is rapidly oxidizes on expose to air
and becoming brown precipitate (P2)
Another sample of aqueous salt-A produce white precipitate with BaCl2(aq.) + dil. HCl(aq.). After
separation of white precipitate resulting solution gives coloured sulphide precipitate (P3) with H2S
only in ammonical medium (NH4OH + NH4Cl). precipitate (P3) is soluble in CH3COOH(aq.).

SALT B - It is dissolve in water but when its aqueous solution is treated by KI dropwise initially
black precipitate is form which is rapidly soluble in excess KI to gives orange solution-S1. Another
sample of aqueous solution of salt-B produces white precipitate (Q1) with NaOH. White precipitate
(Q1) produces orange brown solution-S2 with conc. H2O2. Anion of salt-B produce white precipitate
with lead nitrate solution which is soluble on addition of hot water.

3) When acidified aqueous solution of SALT-A is boiled with orange brown solution-S2. What is the
sum of the oxidation number of both the metals of unknown salts (A) & (B) in product side.

4) Find total number of valence electron(s) in diatomic product obtained by the heating of brown
precipitate P2 with anion of SALT-B in acidic medium.

Common Content for Question No. 5 to 6

A silvery colored alloy made up of two metals [P] and [Q]. 10 gram sample of that alloy dissolve in
dil. HNO3 to produce transparent clear solution-[S].

Assume no redox change on passing H2S in step 2 and 100% yield of the all precipitation reaction.

(Given that dmg = dimethylglyoxime , atomic mass of Zn = 65 , Cu = 63.5 , Mn = 55 , Fe =

56 , Sn = 119 , Pb = 207 , Ni = 58.6 , Au = 197 , Ag = 108 , Cd = 112.5 , Hg = 200 , Pt =
195 , Al = 27 , Co = 59 , C = 12 , H = 1 , O = 16 , N = 14 , S = 32 , Cl = 35.5)
5) What is the % of metal (P) by mass in alloy.

6) Write sum of number of unpaired electron(s), number of Metal–Carbon bond(s) and number of
oxygen atom(s) in red precipitate obtained finally which contain metal [Q].

SECTION-II (ii)

1) Find total number of stereoisomers possible for the given three complex salts where "dppe" is
Bis(diphenylphosphine)ethane which is a symmetric bidentate ligand.

• [Co(dppe)3] [Cr(NH2)2(C2O4)2]
• [Co(dppe)2(NH3)2]Cl3
• [Cr(dppe)2(C2O4)]NO3 Given :-

2) Identify Metal-M1 , Metal-M2 and Metal-M3 of 3d series based on following information.

* Comparatively low value of for Metal-M1 is related to the stability of its +2

ion due to half filled symmetrical t2g level.
* For Metal-M2 , its highest oxidation state is not represented in simple halides but observed in
oxides and some oxo halides.
* Dipositive aquated ion of Metal-M3 has same colour as tripositive aquated ion of Metal-M1 and
complexes of Metal-M3 are useful in polymerisation of alkynes
Write some of atomic number of M1 + M2 + M3 = ?

3) In the scheme of given reactions identify X and Y and answer the question given below based on
the properties of X and Y.

Metal halide Green precipitate (P) + Filtrate (Q)

(P) X (a coloured species in solution) yellow ppt.

(Q) Y (at STP Y is a elemental gas and gives blue-coloration with KI-starch paper)

A = Number of species among the following which on reaction with X (aq.) , changes the color of X
(aq.) solution in acidic medium.
H2S , Fe2(SO4)3 , FeSO4 , SO2 , SnSO4 , NaNO2 , ZnSO4 , n-propanol , Pb(NO3)2
B = Number of halides among F– , Br– , I– which can be oxidized by Y

Find the sum of (A + B)

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let tangents PA and PB be drawn to the parabola (y – 2)2 = 8(x – 3) from a variable point P(h, 2 –
2h), h ∈ R. If chord AB passes through a fixed point (5, 2) then area of ΔPAB is

(A) sq. units

(B) sq. units
(C) sq. units

(D)
sq. units

2) If f(x, y)
= where y ≥ 0 and x ∈ [–4, 4], then minimum value of f(x, y) is -

(A) 10
(B)
(C)
(D)

3) If length of the tangent drawn from focus of the hyperbola (x – 2y + 3)2 – (8x + 4y + 4)2 = 20 to its

director circle is where p & q are coprime then (p + q) is -

(A) 21
(B) 19
(C) 5
(D) 3

4) If radius of a circle which touches both the circles x2 + y2 – 8y + 12 = 0 and x2 + y2 – 12x + 27 = 0

and their direct common tangent is then (λ + p) is -

(A) 53
(B) 54
(C) 55
(D) 56
 SECTION-I (ii)

1) If A(x1, y1) and B(x2, y2) are the end points of latus-rectum of an ellipse x2 + 2y2 – 2x – 3 = 0, (x1, x2
> 0) and AB is also latus-rectum of a parabola whose vertex is V(x3, y3) (x3 < 2) and if P(x4, y4) is a
point in the director circle of the ellipse, from where perpendicular tangents are drawn to the
parabola, then

(A) number of integral value of y4 is 3

(B) number of integral value of y4 is 5

(C)
x1 + x2 + x3 =
(D) x1 + x2 + x3 =

2) If 3x – 4y + 20 = 0 and 4x + 3y – 15 = 0 are asymptotes of a hyperbola and transverse axis whose

length is passes through (1, 12), then

(A) length of latus rectum is

(B) sum of the abscissae of the foci is 0
(C) sum of the ordinates of the foci is 10
area of the Δ formed by asymptotes and a tangent to the hyperbola at the point whose abscissa
(D)
is 300π is 200 sq. units

3) If common chord AB of the curves y2 = 8x and (a > 0) is also their focal and AB is
subtending an angle θ at the origin 'O' then

(A)
eccentricity of the hyperbola is

(B)
length of conjugate axis is
(C) area of ΔAOB is 8 sq. units

(D)

4) Let P(a, b) (a ∈ I & a < 0) be a common point of the curves

and . If chords through P to the curve

C1, meet it at A1, A2, ... An and the straight lines perpendicular to these chords at A1, A2, ... An passing
through a fixed point Q(c, d), then -

(A) 5(c + d) = 29
(B) 5(c + d) = –24
(C) distance between Q and nearer focus of the curve C2 is 4

(D)
distance between Q and nearer focus of the curve C2 is

5) If the ellipse 4x2 + 64y2 – 20x + 192y + 105 = 0 is confocal with a hyperbola having same
principal axes and where eE and eH are eccentricities of ellipse and hyperbola
respectively, then -

(A) length of conjugate axis of the hyperbola is more than length of its transverse axis.
(B) length of conjugate axis of the hyperbola is less than length of its transverse axis.

(C)
latus rectum of the hyperbola is .

(D)
latus rectum of the hyperbola is times latus rectum of the ellipse.

6) If C is the locus of centre of a circle which cuts the circle S : x2 + y2 – 6x + 12y + 37 = 0 at P(5,
–4) orthogonally, then identify which of the following statement(s) is(are) correct ?

(A) If director circle of S cuts the locus C at Q then PQ is .

(B) If director circle of S cuts the locus C at Q then PQ is 4.
Radius of a circle which is concentric with S and cuts the curve C at R such that Q(in option A)
(C)
is the mid point of P & R is .
Radius of a circle which is concentric with S and cuts the curve C at R such that Q (in option A)
(D)
is the mid point of P & R is .

SECTION-II (i)

Common Content for Question No. 1 to 2

Consider a circle and ellipse as

S : x2 + y2 – 4x – 5 = 0 ; E :
If AB is common chord of both the curves with negative gradient then -

1) Product of the length of the perpendiculars upon chord AB from foci is

2) Distance between the point of intersection of common tangents and centre of the circle is -

Common Content for Question No. 3 to 4

Let C1 : and C2 : x2 = λ(y + 1) be tangent to each other and A and B are their points of
contact.

3) If (α, β) is the point of intersection of normals drawn at their points of contact for λ > 0 then

is -

4) If area enclosed by the parabola (for λ < 0) and the line AB is S then is
Common Content for Question No. 5 to 6
Let two different tangents be drawn from a point (–2 + 2cosθ, sinθ) to the curve 2y = .

5) If θ ∈ (aπ, bπ) then a + b is

6) If cosθ = and acute angle between tangents is then is -

SECTION-II (ii)

1) Let x – y + 7 = 0 and 2x + y + 14 = 0 be two tangents to a parabola at points P & Q respectively

and x – 3y – 7 = 0 is also a tangent to the same parabola at its vertex. The value of (where
S is the focus)

2) If distance between parallel normals drawn to the curve x2 – 6y2 – 2x – 24y – 26 = 0 at the points

P(α) and Q(β) is then |α – β| = where a, b are coprime then (a + b) is -

3) Let S1 be a circle with radius and centred at (2, 0). A tangent line L is drawn to the circle at
P(a, b) (a < 0) which intersects the y-axis Q(0, 6). A circle S2 touches the line L at Q and also
S1 externally at R. If radical axis of S1 & S2 meets PQ at T(c, d) then (c + d) is -
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B B D C

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. A,C A,B B,D A,C A,C C,D

SECTION-II (i)

Q. 11 12 13 14 15 16
A. 0.42 to 0.43 0.71 to 0.72 3.33 1.40 1.41 1.00

SECTION-II (ii)

Q. 17 18 19
A. 5 18 5

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 20 21 22 23
A. B B B D

SECTION-I (ii)

Q. 24 25 26 27 28 29
A. A,B,D B,C,D A,B,C A,C B,C,D A,C,D

SECTION-II (i)

Q. 30 31 32 33 34 35
A. 230.00 to 231.00 -307.00 to -306.00 10.00 14.00 82.10 to 82.60 4.00

SECTION-II (ii)

Q. 36 37 38
A. 11 76 8

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 39 40 41 42
A. B D D D

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. B,C B,C,D B,C A,D A,C A,D

SECTION-II (i)

Q. 49 50 51 52 53 54
A. 3.37 or 3.38 4.24 0.50 4.00 3.50 1.60

SECTION-II (ii)

Q. 55 56 57
A. 10 4 3
 SOLUTIONS

PART-1 : PHYSICS

1)

App depth 3cm = ⇒µ=

We use refraction formula for apparent depth as

µ1 = ; u = – 4cm ; R = – R

µ2 = 1 ; v =

R = 25 cm

2) The plane surface is AB. n is normal to the surface. Angle of incidence i = θ

sinθ = µsinr
⇒ θ = µr

∴ Deviation δ = θ – r =
Now consider refraction at the curved surface

∴v=

∴ X co-ordinate of the image is

Snell's law gives µsinδ = 1. sinr'

⇒ µ.δ = r'
⇒ r' = (µ - 1)θ
Rays appear to be diverging from A.
BA = |v|r'

∴ Co-ordinates of point A are

3) Area A = A=

f1 = f2 =
Measurements is done using same scale
Δa = Δd
af1 = df2

⇒ af1 = af2
⇒ f1 = f2,
Hence option (D) is correct.

4)
Image will be formed after 3 refractions for surface 1
u = –R, µ1 = –1.5, µ2 = 1, radius = –R

v=

For surface 2
u = –R, µ1 = 1, µ2 = 1.5, radius = +R

v = –3R
For surface 3
u = –4R, µ1 = 1.5, µ2 = 1, R = ∞
v=

Distance of image from point O is

5)

Correct Answer is (A,C)

0
6) General solution is y(x) = y cos(kx) + .

ρ∝ , so curvature is strongest, at turning points (max |y|).

Radius depends on y(x), hence on y0, θ0.
Correct option (A), (B), (C)

7)

Correct Answer is (B,D)

8)

Correct Answer is (A,C)

9) 1 M.S.D. = = = 0.25 cm

1 V.S.D. = × 1M.S.D. =

L.C. = 1 M.S.D. – 1 V.S.D. =

Now, reading of object's length = (12 × M.S.D.) + (3 × L.C.)

= 12 × +3×

=3+ = cm

10) For (x0)max consider a ray very close to X-axis then at curve surface

⇒ f = 15 cm
∴ (x0)max= 10 + 15 = 25 cm
11)

Correct Answer is (0.42 to 0.43)

12)

Correct Answer is (0.71 to 0.72)

13) I1 = 24 cm ; I2 = 74 cm ; f0 = 340 cm

I1 + e = ......(i)

I2 + e = ......(ii)
(3I1 – I2) + 2e = 0

⇒e=
⇒ e = 1cm
and d × 0.3 = e

14) I1 = 24.0 cm, ΔI1 = 0.1 cm

I2 = 74.0 cm, ΔI2 = 0.1 cm

0
f = 340 ± 1%,

= 1% +
Percentage error = 1.4%

15)
∠AOC = ∠COA1 = 15°
∴ ∠OBA1 = 30°
And ∠OCB = 45°
Applying sine rule
16)

∠OBC =
∴ ∠OCB = 135°

sin (Ψ' – 45°) =

Ψ' – 45° = 30°
Ψ' = 75°
Mirror is rotated by 75° – 15° = 60°
Speed of mirror = 60°/sec
So it will take 1 sec to rotate by 60°

17) The ray coming from P forms the image at P1. The OP1 is the radius of the cylinder an

observed from outside, nsini = sinθn ⇒ OP = nr = 3.75 cm

The apparent insane in the distance = 2(OP1 – OP) = 2(3.75 – 2.5) cm = 2.5

18) Apparent distance of object, u = 15 + = 39.93 cm.

Apparent distance of image v = 15 + × 25 = 33.75 cm.

From mirror formula ; ⇒ f = 18 cm.

19) MSD =
50VSD = 49MSD
 LC = MSD – VSD

= MSD – MSD

= = 5 × 10–6 m

PART-2 : CHEMISTRY

20)

21)

PbCl2 is soluble in hot water.

22) Ti = TiO2 (+4)

V=

23)

(NH4)3 [P(Mo3O10)4]

24)

[Co(NH3)4(H2O)2]2(SO4)3.3H2O

25) SO2 and I2 are the major product of reaction but some HI, SO2 , H2S and sulphur are also
form in reaction.

26)

The correct answer is option (A), (B), (C)

27)

[V(H2O)6]Cl2 (Violet)
Mn+3 (Violet)
Ni(OH)2 (Green)
[Mn(H2O)6]+2 (Blue)
[Co(H2O)6]+2 (Blue)
[Phenolphthalein (HPh) + K2CO3(aq.)] (Pink)

28) The correct answer is option (B),(C),(D)

29)

The correct answer is option (A), (C), (D)

30)

1. [Cr(NH3)5Cl]+2

λ1 = 515 × 10–9 m

2. [Cr(NH3)5H2O]+3

λ2 = 480 × 10–9 m

3. [Cr(NH3)6]+3

λ = 465 × 10–9 m

C.F. stabilization energy for complex number 3 = –3 × –0.4 Δ0

C.F. stabilization energy 306.5 = –306.5

31)

Theory based

32) SALT A = MnSO4

SALT B = BiCl3
Brown ppt. P2 = MnO2
Orange brown solution (S2) =
 33) SALT A = MnSO4
SALT B = BiCl3
Brown ppt. P2 = MnO2
Orange brown solution (S2) =

34)

Molar mass of Ni(dmg)2 = 58.6 + 2[(4×2) + (7× 1) + (2×14) + (2 × 16)] = 288.6 g/mol
Given Mass of Ni(dmg)2 = 8.7 g
Mole of Ni(dmg)2 = 0.03014
Mass of Ni = 0.03014 × 58.6 = 1.76 g
Total mass of copper = 10 – 1.76 = 8.24 g
% of copper = 82.40%

35)

The correct answer is 4.00

36)

I → S.I. = 6
II → S.I. = 3
III → S.I. = 2

37) M1 = V
M2 = Mn
M3 = Ni

38)

P → Cr(OH)3
Q → Cl–
Yellow ppt. → PbCrO4

PART-3 : MATHEMATICS

39) y = 2 – 2x ⇒ 2x + y = 2
(y – 2)2 = 8(x – 3)
focus : S ≡ (5, 2) ⇒ AB is focal chord
Directrix : x – 3 + 2 = 0 ⇒ x = 1
∴ P ≡ (1, 0)

Area of ΔPAB =
40)
= AD

41)

(x – 2y + 3)2 – 16(2x + y + 1)2 = 20

Director circle is :

∴
∴p+q=3

42) S1 : x2 + (y – 4)2 = 4
S2 : (x – 6)2 + y2 = 9

⇒
∴ λ + p = 56
43) (x – 1)2 + 2y2 = 4

focus : x – 1 = ±ae ⇒

focus of the parabola & ellipse coincide

& Directrix is :
x1 + x2 + x3 = +1+ +1+ =2
+ ⇒ (C)
Director circle is : (x – 1)2 + y2 = 6
⇒ + y2 = 6 ⇒ y2 = 6 – (2 + 4 – )= ≃ 5.656
∴ No. of integral values of y4 is 5
{–2, –1, 0, 1, 2}

44) Angle bisector between asymptotes –

+ve ⇒ x + 7y – 35 = 0 (conjugate axis)

–ve ⇒ 7x – y + 5 = 0 (Transverse axis)
centre is : (0, 5)
ℓ(TA) = ℓ(CA) = ℓ(LR) =

co-ordinates of foci : x = 0 ± aecosθ =

y = 5 ± aesinθ =

∴ ,
# Sum of the abscissae of the foci = 0
# Sum of the ordinates of the foci = 10
# Required area of the Δ = a2 = 200 sq. units

45) ⇒ b2 = 4a, ae = 2
b2 = O2(e2 – 1)
4a = 4 – a2
⇒ a2 + 4a + 4 = 8
(a + 2)2 = 8

∴
Ar(ΔAOB) = × 2 × 8 = 8 sq. units

46)

∴c+d=4+ = ⇒ (A)

Distance b/w Q & S is

47)

⇒
⇒ & ⇒ aH < bH

Latus rectum of the hyperbola is

48)
Required locus is the tangent at P itself.
S : (x – 3)2 + (y + 6)2 = 8
Director circle : (x – 3)2 + (y + 6)2 = 16
∴ PQ = 4

49)

Solving both the curves, get

(5, 0), &

Equation of chord AB :

y–0= (x – 5)

Now,

= 3.375

50)

Clearly common tangents are x = 5, y = ±3

∴ Print of intersection of common tangents (5, 3) & (5, –3)
∴ Distance b/w (2, 0) & (5, 3) is = ≃ 4.242

51)

Solving both the curves

y2 = 3λy + 3λ – 3
y2 – 3λy + 3(1 – λ) = 0
D = 0 ⇒ 9λ2 – 4.3(1 – λ) = 0
⇒ 3λ2 + 4λ – 4 = 0
(3λ – 2)(λ + 2) = 0

λ = –2,
λ>0

Prints of contact

,
Normal at A to the hyperbola

⇒
∴

52)

Solving both the curves

y2 = 3λy + 3λ – 3
y2 – 3λy + 3(1 – λ) = 0
D = 0 ⇒ 9λ2 – 4.3(1 – λ) = 0
⇒ 3λ2 + 4λ – 4 = 0
(3λ – 2)(λ + 2) = 0

λ = –2,
λ<0
x2 = –2(y + 1)
Prints of contact are
A ≡ (–2, 3), B ≡ (2, 3)
Required area = area of the shaded

region = × (4 × 2) = ≡S

∴ =4

53)
4y2 = x2 – 4

x2 – 4y2 = 4 ⇒

solving &
get x = 0, –2
Now,
–2 + 2cosθ = 0 ⇒ cosθ = 1
–2 + 2cosθ = –2 ⇒ cosθ = 0

θ∈

∴a+b= = 3.50

54)
4y2 = x2 – 4

x2 – 4y2 = 4 ⇒
solving &
get x = 0, –2
Now,
–2 + 2cosθ = 0 ⇒ cosθ = 1
–2 + 2cosθ = –2 ⇒ cosθ = 0

θ∈

⇒ ⇒

⇒
∴ angle b/w tangents,

55)

L1 : x – y + 7 = 0
L2 : 2x + y + 14 = 0
L3 : x – 3y – 7 = 0
T be the point of intersection of L1 & L2
T ≡ (–7, 0)
Print of intersection of L1 & L3 is A ≡ (–14, –7)
Print of intersection of L2 & L3 is B ≡ (–5, –4)
St. line ⊥or to L1 & paring through A is x + y + 21 = 0
St. line ⊥or to L2 & paring through B is x – 2y – 3 = 0
focus S will be (–13, –8)
Now [Link] = ST2
∴

56)

x2 – 2x + 1 – 6(y2 + 4y + 4) = 3
⇒
Normal at P(α) → axcosα + bycotα = a2 + b2
Normal at P(π – α) → axcosα + bycotα = –(a2 + b2)
∴ Distance b/w parallel normals

∴ Absolute difference b/w α and β = |α – β| = ≡

⇒a+b=4

57)

S1 : (x – 2)2 + y2 = 20

(0, 6) ⇒
4m2 + 36 + 24m = 20(1 + m2)
16m2 – 24m – 16 = 0
2m2 – 3m – 2 = 0
(2m + 1)(m – 2) = 0

,m=2

⇒ b – 6 = 2a & ⇒ 2b = –a + 2
⇒ a = –2, b = 2
T will be the mid point of PQ
⇒ c = –1, d = 4
∴c+d=3