06-06-2026

4602CJA101002260003 JM

PART-1 : PHYSICS

SECTION-I

1) The position-time graphs of two cars A and B are straight lines making angles 30° and 60° with
the time axis respectively. The ratio of velocities of A and B is :-

(A)
(B) 1 : 3
(C)
(D) 3 : 1

2) A particle moves along x-axis with speed 6 m/s for the first half distance of a journey and the
second half distance with a speed 3 m/s. The average speed in the total journey is :-

(A) 5 m/s
(B) 4.5 m/s
(C) 4 m/s
(D) 2 m/s

3) An object thrown vertically up from the ground passes the height 5 m twice in an interval of 10 s.
What is its time of flight ?

(A)
(B)
(C)
(D)

4)

A body initially at rest, starts moving along x-axis in such a way so that its acceleration vs
displacement plot is as shown in figure. The maximum velocity of particle is.

(A) 1 m/s
(B) 6 m/s
(C) 2m/s
(D) None
5) The acceleration time graph of a particle is shown in the figure. What is the velocity of particle at

t = 8 s if its initial velocity is 3 m/s ?

(A) 4 m/s
(B) 5 m/s
(C) 6 m/s
(D) 7 m/s

6)

The displacement versus time (s - t) graph of a particle is parabola as shown in figure. Then the
corresponding velocity-time (v - t) graph will be

(A)

(B)

(C)
(D)

7)

For a particle moving along in straight line the velocity graph is as shown in the figure. Find the
ratio of total distance travelled to the magnitude of the total displacement.

(A) 2/3
(B) 5/3
(C) 4/3
(D) None of these

8) One body is dropped while a second body is thrown downwards with an initial velocity of 2 m/s
simultaneously. The separation between them is 18 metres after a time:

(A) 9 s
(B) 4.5 s
(C) 18 s
(D) 9.8 s

9) A stone is dropped from the top of a tower and travels 24.5 m in the last second of its journey. The
height of the tower is: (g = 9.8 m/s2)

(A) 44.1 m
(B) 49 m
(C) 78.4 m
(D) 72 m

10) The position (x) of a particle moving along x-axis varies with time (t) as shown in figure. The
average acceleration of particle in time interval t = 0 to t = 8 s is :-

(A) 3 m/s2
(B) –5 m/s2
(C) –4 m/s2
(D) 2.5 m/s2

11) A particle is projected from the ground with an initial speed of v at an angle θ with horizontal.
The magnitude of average velocity of the particle between its point of projection and highest point of
trajectory is :-

(A)

(B)

(C)

(D) ν cos θ

12) The equation of projectile is y = 16 x – . The horizontal range is :-

(A) 16 m
(B) 8 m
(C) 3.2 m
(D) 12.8 m

13) A particle is projected with velocity from horizontal. What will be the height attained
by it when velocity becomes perpendicular to acceleration :-

(A) 0.8 m
(B) 5 m
(C) 0.4 m
(D) 1.6 m

14) A ball is projected with velocity u at an angle α with the horizontal plane. Its speed when it
makes an angle β with the horizontal is :-

(A) u cos α
(B)

(C) u cos α cos β

(D)

15)

Find time of flight of projectile thrown horizontally with speed 10 ms–1 from a long inclined plane
which makes an angle of θ = 45° with the horizontal.

(A)
(B)
(C) 2 sec
(D) None of these

16) For shown projection from a tower, find time of flight :

(A) 5 s
(B) 8 s
(C) 10 s
(D) 16 s

17) In the given figure, if time taken by the projectile to reach Q is T, then PQ =

(A) Tv sinθ
(B) Tvcosθ
(C) Tvsecθ
(D) Tv tanθ

18) Two men P & Q are standing at corners D & B of square ABCD of side 8 m. They start moving at
t = 0 along the track with constant speed 2 m/s and 10 m/s respectively. The time when they will
meet for the second time, is equal to :

(A) 2 sec
(B) 3 sec
(C) 7 sec
(D) 6 sec

19) A man can row a boat with speed 4 km/hr in still water. If the velocity of water in river is 3
km/hr. The time taken to reach just opposite end is (river width = 500 m)

(A)

(B)

(C) 100 hr
(D) None

20) At a certain instant two particle are 100m and 200m from intersection point as shown in figure.

Find closest distance of approach between the particle

(A) 12.25 m
(B) 13 m
(C) 13.39 m
(D) 14.25 m

SECTION-II

1) A point A moves with a constant speed of 20 m/s such that its velocity vector always maintains an
angle of 60° with line AB as shown in the figure (B is a fixed point). Initial distance between A and B
is 50 m. At what time ( in s) A reaches B ?

2) A person walking at the rate of 3km/hour, the rain appears to fall vertically. When he increase his
to speed 6 km/hr it appears to meet him at angle of 45° with vertical. The speed of rain is . Find
n.

3) A ball is projected from the origin. The x and y co-ordinates of its displacement are given by x = 3t
and y = 4t – 5t2. Find the velocity of projection (in m/s)

4) Figure shows a projectile thrown with speed u = 20 m/s at an angle 30° with horizontal from the
top of a building 40 m high. Then the horizontal range of projectile is (take ) (in m) : (g

= 10 m/s2)

5) A cannon ball has the same horizontal range 24 m for two angles of projections (say θ and ).
If H1 and H2 be the maximum heights in the two possible paths, then find the value of in
meters.

PART-2 : CHEMISTRY

SECTION-I

1)

Calculate the wavelength associated with a proton moving at 1.0 × 103 ms–1 :-

(A) .032 nm
(B) .40 nm
(C) 2.5 nm
(D) 14.0 nm

2)

Column-II
Column-I
[4πr2 ψ2(r) Vs ‘r’]
 (i) 2s (P)

(ii) 4s (Q)

(iii) 3d ('R)

(iv) 4p (S)

(A) i-S, ii-Q, iii-P, iv-R

(B) i-P, ii-S, iii-R, iv-Q
(C) i-P, ii-Q, iii-S, iv-R
(D) i-P, ii-R, iii-S, iv-Q

3) Which rule or principle is not followed by configuration :

(A) Hund's rule

(B) Aufbau principle
(C) Pauli's exclusion principle
(D) All of these

4) Photon of which light has maximum energy :-

(A) Red
(B) Blue
(C) Violet
(D) Green

5) Which of the following sets of quantum numbers represent an impossible arrangement :-

n l m ms

(A) 3 2

(B) 4 0 0

(C) 3 2

(D) 5 3 0

(A) A
(B) B
(C) C
(D) D

6) In which transition minimum energy is emitted :-

(A)
(B)
(C)
(D)

7) Let be the frequency of the series limit of the Lyman series, be the frequency of the first line
of the Lyman series, and be the frequency of the series limit of the Balmer series :-

(A)
(B)
(C)
(D)

8) Which of the following species is isoelectronic with Ne?

(A) O2–
(B) Mg2+
(C) Na+
(D) All of these

9) If uncertainty in position is double to that of uncertainty in momentum for a mass particle, then
uncertainty in velocity will be :

(A)

(B)

(C)

(D)

10) Given that in H-atom, the transition energy for n=1 to n=2 is 10.2 eV, the energy for the same
transition in Be3+ is

(A) 20.4 eV
(B) 30.6 eV
(C) 40.8 eV
(D) None of these

11)
A dye absorbs a photon of wavelength re emits the same energy into 2 photons of wavelengths
respectively correct relation for is

(A)

(B)

(C)

(D)

12) The work function for a metal is 4 eV. To emit a photo-electron of zero velocity from the surface
of the metal, the wavelength of incident light should be :-

(A) 2700 Å
(B) 1700 Å
(C) 5900 Å
(D) 3100 Å

13) If power of A bulb is 80 watt and wavelength of emitted radiation is 5000 Å, find number of
photons emitted per second :-

(A) 2 × 1010
(B) 2 × 1030
(C) 12 × 1010
(D) None of these

14) In Photoelectric effect, the photo current :

(A) Increases with increase of frequency of incident photon

(B) Decreases with increase of frequency of incident photon
(C) Does not depends on the frequency of photon but depends only on the intensity of incident light
(D) Depends both on intensity and frequency of the incident photon

15) Which of the following sets of quantum numbers are not possible :-

(A) n = 3, l = 2, m = 0, s = – 1/2
(B) n = 3, l = 2, m = –2, s = – 1/2
(C) n = 3, l = 3, m = –3, s = + 1/2
(D) n = 3, l = 1, m = 0, s = + 1/2

0
16) The wave function ψ of 2s – orbital is given by At r = r ,
radial node is formed. Which of the following is correct?

(A) r0 = 2a0
(B) 2r0 = a0
(C) r0 = 3a0
(D) None of these is correct

17) The quantum number of four electrons are given below -

I. n = 4, l = 2, ml = – 2, ms = – ½
II. n = 3, l = 2, ml = 1, ms = + ½
III. n = 4, l = 1, ml = 0, ms = + ½
IV. n = 3, l = 1, ml = 1, ms = – ½
The correct order of their increasing energies will be -

(A) IV < III < II < I

(B) IV < II < III < I
(C) I < II < III < IV
(D) I < III < II < IV

18) Electronic configuration have violated

have violated

(A) Hund's rule

(B) Pauli's principal
(C) AUFBAU principle
(D) (n + l) rule

19) Which of the following have µ = 4.85 B.M.?

(A) Co+2
(B) Mn+2
(C) Fe
(D) Cr

20) For an electron, with n = 3 has only one radial node. The orbital angular momentum of the
electron will be :

(A) 0

(B)

(C)

(D) 3

SECTION-II

1) The number of electrons for Zn+2 cation that have the value of azimuthal quantum number equals
to zero is
2) Find total number of species having magnetic moment value B.M. among following species
Fe+2, Cr, Cr+3, Ti+2, Mn+2, V+3

3) The maximum number of electrons present in ‘P’ (Phosphorus) having (l + m = 0) is/are :

4) The sum of radial nodes for 3s, 2p, 4d and 5f orbital is______.

5) A transition for H-atom from second to first orbit has the same wavelength as from nth orbit to
second orbit for He+ ion. The value of n is______.

PART-3 : MATHEMATICS

SECTION-I

1) The interior angles of a convex polygon form an arithmetic progression with a common difference
of 4°. Determine the number of sides of the polygon if its largest interior angle is 172° :-

(A) 14
(B) 12
(C) 16
(D) 13

2) If the 4th, 7th and 10th terms of a G.P. be a, b, c respectively, then the relation between a, b, c is
:-

(A)
b=
(B) a2 = bc
(C) b2 = ac
(D) c2 = ab

3) If the sum of n terms of an A.P. is 3n2 + 5n

and tm = 164, then m = :-

(A) 26
(B) 27
(C) 28
(D) None of these

4) If 1 + sin3x + sin6x + sin9x + ...... ∞ = 2,

then value of 9 sinx – 3 sin3x is equal to

(A) 6
(B) 8
(C) 10
(D) 14

5) Three numbers are in G.P. If we double the middle number, we get an A.P. ; the common ratio of
the G.P. is equal to :-

(A) 5 ±
(B)
(C)
(D)

6) If x2y3 = 6, then minimum value of 3x + 4y and x, y ∈ R+ is:

(A) 110
(B) 32.43
(C) 10
(D) 23.34

7) If are in A.P. and

then is equal to

(A) 76
(B) 64
(C) 98
(D) 38

8)

The A.M. and H.M. of two positive numbers are 16 and 12 respectively, then there G.M. is :-

(A) 8
(B)
(C) 14
(D) None

9) If 1.3 + 2.32 + 3.33 +......+n.3n =

then (a, b) is

(A) (n–2, 3)
(B) (n–1,3)
(C) (n,3)
(D) (n+1,3)

10)
If the sum of infinity of the series

then 'd' is

(A) 2
(B) 4
(C) 8
(D) None of these

11)
when simplified reduced to:

(A) sin x cos x

(B) – sin2 x
(C) – sin x cos x
(D) sin2x

12) The value of cos12° + cos84° + cos156° + cos132° is

(A)

(B)

(C) 1

(D)

13) tan 20° + tan 40° + tan40°

is equal to

(A)
(B) 1

(C)

(D)

14) If y = (1 + tan A) (1 + tan B),

where A + B = , then (y + 1)y =

(A) 6
(B) 9
(C) 1
(D) 2
15) Find in degrees the angle subtended at the center of a circle of diameter 50 cm by an arc of
length 11 cm. :-

(A) 35°
(B) 125°

(C)

(D)

16) cos2 + cos2 + cos2 + cos2 =

(A) 1
(B) 0
(C) 2
(D) –1

17) is equal to :-

(A)

(B)

(C)
(D) None

18) If 3sinθ + 5cosθ = 5, then 5sinθ – 3cosθ equals:

(A) ±1
(B) ±2
(C) ±3
(D) 0

19) log10 tan 1° + log10 tan 2° + log10 tan 3°

+ .............. ............. + log10 tan 89° =

(A) 1
(B) 45 log10 (tan 1°)
(C) 45 log10 (tan 89°)
(D) 0

20) Value of sin20° sin40° sin60° sin80° is :-

(A)

(B)

(C)

(D)

SECTION-II

1) +.......upto ∞ terms

2)

There are nAM's between 1 & 31 such that 7th mean : (n – 1)th mean = 5 : 9, then find the value of n.

3)

a1, a2, a3……, an are in A.P. and

a1 + a3 + a5 + a7 + a9 = 20 then a5 is:

4) In a triangle ABC,
if ∠C = 135° then (1 + tan A) (1 + tan B)
is equal to

5) If tanA + cotA = 4; then tan4A + cot4A equals :-

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C C A D A B A A B C D A D C C D D B C

SECTION-II

Q. 21 22 23 24 25
A. 5.00 3.00 5.00 69.28 or 69.29 6.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C B C C D A D B D D D D C C A B A C C

SECTION-II

Q. 46 47 48 49 50
A. 6.00 2.00 9.00 4.00 4.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C B A D C A B D A D A A B D C B C D C

SECTION-II

Q. 71 72 73 74 75
A. 2.0 14.00 4.00 2.00 194.00
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

3) …(1)
t2 – t1 = 10 …(2)
solving (1) and (2)
T = t1 + t2 =

4)

a=v

Area of Δ =

(1) (1)
v=1

5)

Area in a-t graph = change in velocity

vf – 3 = 4 ⇒ vf = 7 m/s

6)

s = –t2 + ct
v = –2t + c
So, (1)
7)

A1 = × 2 × 4 = 4
A2 = 1 × 4 = 4, A3 = (–2) (2) = –2
Distance = |A1| + |A2| + |A3|
=4+4+2
= 10 m
|Displacement| = A1 + A2 + A3
=4+4–2
=6

8) S1 – S2 = (u1 – u2)t
18 = (2 – 0)t
t=9s

9)

–24.5 = 0 +
n = 3 sec

S = ut +

–h = 0 +
h = 44.1 m

10)

11) Initial velocity =

Final velocity =
12) y = 16x –

y = (tan θ) x –

tan θ = 16
u2cos2θ = 4

u2cosθ =

R=

=
= 12.8 m

13) = 0.8 m

14) v cos β = u cos α

v=

15)

Time of Flight =
= 2 sec.

16) By using s = ut + at2 in vertical direction

–100 = 40(t) + (–10)T2

⇒ T2 – 8T – 20 = 0 Þ T = 10s
17)

18) Relative speed of Q w.r.t P = 8 m/s.

Therefore, They meet after

Required time

19)

20)

Consider A at rest now w.r.t. A, B is moving at angle 30° with OB

From ΔBOC

and

from ΔADC

= 13.39 m to 13.50 m

21)
Component of velocity of particle along AB
 22)
vr =

23) vx = = 3 and

vy= = 4 – 10t = 4 – 10(0) = 4

v= = (32 + 42) = 5 m/sec

24) – 40 = 20 sin 30° t – gt2 ⇒ t = 4 sec R = U cos θ × t = = =m

25)

PART-2 : CHEMISTRY

26)

λ=

27)

Total numbers of peaks in radial probability distribution function curve = n – ℓ

28) Configuration does not follow Aufbau principle.

29) Violet

30) C

31)

32)

33) Correct option is (4)

34) Δx = 2.Δp

Δx . Δp =

Δv =

35) None of these

36)

37) + KE (but KE = 0);

λ=
= 3.1 × 10–7 m = 3100 Å

38)

N = 20.2 × 1019 photons.

 39) Hint : Intensity ∝ number of photoelectron.
Photoelectric current does not increase with the increase in frequency of incident light.

40)

n = 3, l = 0, 1, 2
l = 0, n = 0
l = 1, m = +1, 0, –1

l = 2, n = – 2, –1, 0, +1, +2

41) At r = r0

It is possible only when

∴ r0 = 2a0

42) (I) n = 4, l = 2 ⇒ 4d
(II) n = 3, l = 2 ⇒ 3d
(III) n = 4, l = 1 ⇒ 4p
(IV) n = 3, l = 1 ⇒ 3p
According to (n + l) rule
3p < 3d < 4p < 4d
IV < II < III < I

43) According to Hund's rule filling must be for d8.

44) Fe : 4s2 3d6

No. of unpaired = 4
µ = 4.85 B.M.

45) Orbital angular momentum =

46)

47)
⇒ 2 unpaired e–

48) 1. Question Explanation

We are asked to find the maximum number of electrons in a phosphorus atom (P) that have
specific values for the azimuthal quantum number (1) and the magnetic quantum number (m),
where l + m = 0
 2. Given Data

A. The element is Phosphorus (P).

B. The condition for the electrons is l + m = 0

3. Concept

A. Quantum Numbers:

n: Principal quantum number (energy level)

1: Azimuthal quantum number (subshell: s, p, d, f, etc.)
m: Magnetic quantum number (specific orbital within the subshell)
s: Spin quantum number

A. l and m Values:

For l = 0 (s subshell): m = 0
For l = 1 (p subshell): m = - 1, 0, +1
For l = 2 (d subshell): m = - 2, - 1, 0, +1, +2

A. Pauli Exclusion Principle: No two electrons in an atom can have the same set of all four
quantum numbers.

4. Mathematical Calculation

A. Determine possible combinations for l + m = 0

l=0m=0
l=1m=-1

A. Consider Phosphorus (P):

Electronic configuration of P: 1s2 2s2 2p6 3s2 3p3

We need to find electrons where l + m = 0
l = 0 m = 0 This corresponds to the s subshells (1s, 2s, 3s). Each s subshell can hold a maximum
of 2 electrons.
l = 1, m = -1: This corresponds to one of the orbitals in the p subshells (2p and 3p). Each orbital
can hold a maximum of 2 electrons.

A. Calculate the total number of electrons:

2 electrons from each of the three s subshells (1s, 2s, 3s) = 2 × 3 = 6 electrons
3 electrons from the p orbital with l = 1 and m = - 1 = 3 electrons

A. Total electrons with l + m = 0 : 6 electrons (from s subshells) + 3 electrons (from p orbital) =

9 electrons

5. Final Answer
The maximum number of electrons in Phosphorus (P) having l + m = 0 is 8.

49) Radial nodes

Sum of total radial nodes = 2 + 0 + 1 + 1 = 4.

 50)

PART-3 : MATHEMATICS

51)

⇒
ℓ = 172º and d = 4º
∴ On solving n = 12

52) Let first term of G.P. = A and common ratio = r

n–1
We know that nth term of G.P. = Ar
Now t4 = a = Ar , t7 = b = Ar and t10 = c = Ar9
3 6

Relation b2 = ac is true because b2 = (Ar6)2 = A2r12 and ac = (Ar3) (Ar9) = A2r12

Aliter : As we know, if p, q, r in A.P., then pth, qth, rth terms of a G.P. are always in G.P.,
therefore,
a, b, c will be in G.P. i.e. b2 = ac.

53) tm = Sm – Sm–1
∴ 164 = 3m2 + 5m – 3(m–1)2 – 5(m–1) = 6m + 2
∴ 6m = 162 or m = 27

54) ⇒ 9 sinx – 3sin3x = 6

55) Let the numbers be a, ar, ar2

Given that a, 2 ar, ar2 are in A.P.
∴ 2(2 ar) = a + ar2
⇒ r2 – 4 r + 1 = 0

⇒ r=

56) Let using are five positive number

AM ≥ GM
3x + 4y
3x + 4y ≥ 10

57)

58)

G2 = A.H.

59)

60)
(A.G.P.)

⇒ 36 + 4d = 44
⇒ 4d = 8
⇒d=2

61)

sin2x

62)

Answer is

63)

Answer is
64) If A + B = , then (1 + tan A) (1 + tan B) = 2
∴ Reqd = (2 + 1)2 = 9

65) θ = ⇒ θ=

∴θ= =

66) cos2 + cos2 + cos2 + cos2

= + =2

67)

68) 3sinθ + 5cosθ = 5 ...(i)

Let 5sinθ – 3cosθ = x ....(ii)
squaring & adding ; 34 = 25 + x2 ⇒ x = ±3

69) log10 {tan 1° tan 2° tan 3° ...... tan 89°} = log10 1 = 0

70) ∵ sin(60 – θ) sin(θ) sin(60 + θ) =

71) .......(1) .......(2)

⇒
S=2

72)

1, A1, A2, A3, ......, An, 31

∴ d=

⇒
⇒ 4 + 68d = 5nd

⇒ + 68 = 5n
⇒ 146n = 2044
⇒ n = 14

73)

a1 + a3 + a5 + a7 + a9 = 20
⇒ 5a1 + 20d = 20
a1 + 4d = 4
a5 = 4

74) ∵ ∠C = 135° ⇒ A + B = 45°

⇒ (1+tanA) (1+tanB) = 2

75) Given tanA + cotA = 4

on squaring, tan2A + cot2A + 2 = 16
Again squaring, tan4A + cot4A = 194.