10-06-2026

7101CJA101001260011 JA

PHYSICS

SECTION-I (i)

1) The resultant of two forces 3p and 2p is R. If the first force is doubled keeping same direction,
then the resultant is also doubled. Find the angle between two forces.

(A) 60°
(B) 120°
(C) 150°
(D) 90°

2) Potential energy of a particle moving along x-axis is given as U = (x3 + 3x2 – 9x + 6) J. Then find
minimum possible value of U

(A) –21J
(B) –4J
(C) 1J
(D) –3J

3)

A particle is moving with a velocity where K is a constant. The general equation for its
path is

(A) y2 = x2 + constant
(B) y = x2 + constant
(C) y2 = x + constant
(D) xy = constant

4)

Acceleration v/s time graph for a particle moving along a straight line is shown in figure. The
particle is initially at rest. Find the time instant(s) in seconds, when the particle is at rest.

(A) t = 0, 1, 2, 3, 4
(B) t = 0, 2, 4
(C) t = 1, 3
(D) None of these

SECTION-I (ii)

1) Figures (i) and (ii) below show the displacement-time graphs of two particles moving along the x-

axis (curves are parabolic). We can say that

(A) Both the particles are having uniform acceleration

(B) Both the particles are having non uniform acceleration
(C) Particle (i) is speeding up.
(D) Particle (ii) is slowing down.

2) The speed of two particles are measured to be and

Then, mark the correct option(s).

(A) The sum of speeds of particles is

(B) The difference of speeds of particles is

(C) The difference of speeds of particles is

(D) The sum of speeds of particles is 16.60 ms–1

3)

For the equation x = AC sin (Bt) + D e(BCt), where x and t represent position and time respectively,
which of the following is/are CORRECT?

(A) Dimension of AC is LT–1.

(B) Dimension of B is T–1.
(C) Dimension of AC and D are same.
(D) Dimension of C is T–1.

SECTION-I (iii)

1) Velocity (in m/s) of a particle moving in a straight line is given by V = (t2 – 2t +1) :-

List–I List–II

(P) Velocity (in m/s) of particle at t = 3 sec is (1) 1

 (Q) Acceleration (in m/s2) of particle at t = 2 is (2) 2

(R) Time when particle is at rest is (3) 3

(S) Magnitude of average acceleration of particle (4)

4
in first one second is
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 4;Q → 2;R → 1;S → 1
(D) P → 1;Q → 4;R → 3;S → 2

2) Match the v-t graph in List-I with corresponding s-t graphs in List-II. (graphs not to scale)

List-I List-II

(P) (1)

(Q) (2)

(R) (3)

(S) (4)

(A) P → 2;Q → 4;R → 3;S → 1

(B) P → 2;Q → 4;R → 1;S → 3
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 3;Q → 1;R → 2;S → 4

3) Match List-I with List-II.

List-I List-II

(a) (i)

(b) (ii)
 (c) (iii)

(d) (iv)

Choose the correct answer from the options given below :

(A) a → iv;b → i;c → iii;d → ii
(B) a → iv;b → iii;c → i;d → ii
(C) a → iii;b → ii;c → iv;d → i
(D) a → i;b → iv;c → ii;d → iii

4) Match the dimensional formula; here y, y1, y2 represents distance, t, t1, t2 represents time. [A]
represents dimension of A.

List-I List-II

0 0
(I) (P) M L T–2

[α] in equation,
(II) (Q) M1L1T1
y = A cos(α2t2)

Dimension of 0 0 0
(III) (R) M L T

[α] in equation, 0
(IV) (S) M LT–1
0 0
(T) M L T–1
(A) I → P;II → Q;III → R;IV → S
(B) I → S;II → T;III → Q;IV → R
(C) I → S;II → T;III → R;IV → T
(D) I → S;II → T;III → R;IV → P

SECTION-II

1) A body covers 12 m in 2nd and 20 m in 4th second. How much distance (in m) will it cover in 4
second after the 5th second?

2) Acceleration of a particle moving in x-y plane varies with time t as

Here a is in m/s2 and t in sec. At time t = 0 particle is at rest at origin. Mass of the particle is 1 kg.
Find the velocity (in m/s) of the particle at t = 2 seconds.
Round of the answer to Nearest Integer.
3) The position co-ordinates of a particle moving in x-y plane are given as x = a cos t, y = a sin t. If

the angle in degree between velocity and acceleration is θ then fill the value of . (where θ is in
degree)

4) The velocity time graph of a linear motion is shown below. The distance from the origin after 8

seconds is x m then find .

5) A Physical quantity P is given as - where, SI unit; SI

unit; SI unit. Find the percentage error in calculation of P.

6) x and y components of a vector are 4 and 5 respectively. The x and y components of are 7
and 9 respectively. Find length of .

CHEMISTRY

SECTION-I (i)

1) Choose the incorrect statement.

(A) Cl– > K+ > Ca2+ : Ionic radius

(B) Ni < Cu < Zn : Atomic radius
(C) F < Cl : Electron affinity
(D) F– > Cl– : Ionization energy

2) Saponification is the reaction of a strong base with vegetable oils and animal fats. It is used in
making soaps. A sample of vegetable oil weighing 2 gm is added to 25 ml, 0.4 M KOH. After
saponification in complete, 8 ml, 0.25M H2SO4 is needed to neutralize excess base. Find the
saponification number, which is defined as the weight in mg of KOH consumed by 1 gm oil (K = 39)

(A) 336
(B) 224
(C) 168
(D) 448
3) Which of the following match is incorrect :

(A) Na > Mg ⇒ 3rd ionisation energy

(B) Pd > Ag ⇒ 1st ionisation energy
(C) H < He ⇒ 1st ionisation energy
(D) Ne < Li ⇒ 2nd ionisation energy

4) The Difference in wavelength of first and last line of lyman series in emission spectrum of He+
would be :

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Which of the following statement(s) is/are correct?

(A) Proton has high value of e/m as compared to He-nucleus

If the uncertainties in the position and momentum are equal then the uncertainty in the velocity
(B)
=
If for some reason the potential energy of an electron in the Ist shell of H-atom becomes
(C)
–54.4 eV then the I.E. of the electron is +27.2 eV
If for some reason the potential energy of an electron in the 1st shell of H-atom becomes –54.4
(D)
eV then the energy required to remove the electron from the 2nd shell will be 6.8 eV

2) Which are correct match ?

(A) O < C < S < Se — Atomic size

(B) Na < Al < Mg < Si — Ist I.P
(C) MgO < SrO < Cs2 O < K2 O — Basic character
(D) P4 O10 > SO3 > Cl2 O7 - Acidic character

3) 4 g of hydrogen is ignited with 4 g oxygen. Following reaction takes place

Select the correct statement(s).

(A) Oxygen is limiting reactant

(B) Hydrogen is limiting reactant
(C) 4 g of hydrogen reacts with 2g oxygen
(D) 4.5 g of water will be formed

SECTION-I (iii)

1) Match the list -

List-I List-II

(P) Angular probability is independent of θ & ϕ (1) 5d

(Q) (2) 5p

(R) Two maxima in 4πr2R2 vs r graph. (3) 4s

(S) (4) 3p

(A) P → 3;Q → 4;R → 1;S → 2

(B) P → 3;Q → 4;R → 2;S → 1
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 2;Q → 3;R → 4;S → 1

2) Match the following:

List–I List–II

(P) Same number of unpaired electrons are (1)

Na+, Mg2+, F¯
present in (excluding zero)

(Q) Same number of electrons in s & p (2)

F¯, Mg, O2–
subshells.

(R) Same number of electrons with the (3)

Mg, Ne, O2–
ℓ=1

(S) Same number of total electrons (4) Li, Na, K

(5) F, Cl , Br
(A) P → 1, 2, 5;Q → 3, 4;R → 1;S → 4
(B) P → 4, 2;Q → 1, 3;R → 2, 3;S → 1, 4, 5
(C) P → 4, 5;Q → 1;R → 1, 2, 3;S → 1
(D) P → 3, 5;Q → 1, 2;R → 3, 4;S → 1, 3, 4

3)

List-I List-II
 (P) 3.42g C12H22O11 in 100ml solution (1) 0.2 M

(Q) Mole fraction of C2H5OH (aqueous solution) = 0.2 (2) 0.17 m

(R) 18g C6H12O6 in 500ml solution (d = 1.2g/ml) (3) 0.05 m

(S) 6g urea (NH2CONH2) dissolved in 2 kg water (4) 0.1 M

(5) 13.9 m
The correct option is :
(A) P → 5;Q → 1;R → 2;S → 4
(B) P → 4;Q → 3;R → 1;S → 5
(C) P → 4;Q → 5;R → 1, 2;S → 3
(D) P → 3;Q → 5;R → 2;S → 3

4)

List-I List-II

Number of electron in Na(11) having

(P) (1) 4
|m| = 1

Number of orbitals in S(16) having

(Q) (2) 15
(n + ) ≤ 3

Number of maximum possible

(R) electrons having S = +1/2 spin in (3) 6
Cr(24)

Maximum degeneracy for n = 4 for

(S) (4) 12
Sc+3

(5) 7
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 4;Q → 2;R → 1;S → 5
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 1;Q → 3;R → 2;S → 5

SECTION-II

1)

'α particle' of 3.6 MeV are fired towards nucleus , at point of closest separation distance between
–14
'α particle' and 'X' is 1.6 × 10 m. Calculate atomic number of 'X'
[Given : 1/4πε0 = 9 × 109 in S.I. units]
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.

2) The figure shows a sample of H-atoms having electron revolving in higher orbit ‘n’.
 If this electron makes transition from this orbit ‘n’ to ground state, No. of
paschen lines emitted are.

3) The percent yield for the following reaction carried out in carbon tetrachloride (CCI4) solution is
80% (the remaining amount of reactants are left over unreacted in the reaction)
Br2 + CI2 2BrCI
If the amount of BrCI formed from the reaction of 0.025 mol Br2 and 0.025 mol CI2 is 'x'. If the
amount of Br2 left unreacted is 'y'. Find x/y. (Answer in terms of nearest integer)

4) An organic compound contains 40% C, 6.66% H and remaining is oxygen. Its vapour density is 60
and molecular formula is CxH2yOz. Then (x+y+z)/3 is

5) What is group number of element 'Unp' in long form of periodic table ?

6) The number of pairs, in which EA of the second element is more than that of the first element is :
[O, S], [C, N], [O, N], [N, P], [Cl⊕, F⊕], [K⊕, Na⊕]

MATHEMATICS

SECTION-I (i)

1) If x,y,z are positive real numbers such that , then value

of , is

(A) 10
(B) 5
(C) 343
(D) 125

2) If x3 + y3 + 15xy = 125 where x ≠ y, then value of x + y is equal to-

(A) –10
(B) 5
(C) –5
(D) 10
3) The number of positive integer pairs (x, y) satisfying x2 – y2 = 2010 is

(A) 0
(B) 2
(C) 5
(D) more than 5

4) If roots of equation x3 – 2x + 3 = 0 are α, β & γ then value of

is equal to-

(A) 2
(B) 3
(C) 4
(D) 6

SECTION-I (ii)

1) Let , then

(A) n(A) = 1
(B) n(A) = 2
(C) sum of all distinct elements of A is 0.
(D) Sum of all distinct elements of A is 2.

2) Consider the equation |x – 6| + |x – 2| – |x – 4| = k

Identify the correct statement(s)

(A) Equation has exactly two positive solutions for k = 4 whose sum is 12
(B) Equation has exactly three positive solutions for k = 4 whose sum is 12
(C) Equation has exactly four solutions for k = 3 whose sum is 17
(D) Equation has exactly four solutions for k = 3 whose sum is 16

3) Value(s) which does not occur in the range of is/are-

(A) 3
(B) 1

(C)

(D)

SECTION-I (iii)
1) Let ƒ(x) = x2 + 5x + 1 and α, β are roots of equation ƒ(x) = 0, then
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II
Graph of ƒ(x) is symmetric with respect to
(P) (1) 7
x = k, then value of |2k| is
Let graph of ƒ(x) intersect x-axis at P and Q,
(Q) (2) 6
if length PQ is d then is equal to
(R) Minimum integral value of ƒ(x) is m then |m| is (3) 5
Number of integral values of x which satisfying
(S) (4) 4
ƒ(x) < 7 is
(5) 8
(A) P → 3;Q → 4;R → 1;S → 2
(B) P → 3;Q → 1;R → 3;S → 2
(C) P → 2;Q → 1;R → 1;S → 4
(D) P → 2;Q → 1;R → 3;S → 4

2) The quadratic equations x2 – 8x + a = 0 and x2 – bx + 16 = 0 have one root in common and the
other roots of both of these equations are integers in the ratio 3 : 4, then
Match List-I with List-II and select the correct answer using the code given below the list.

List- I List- II

(P) Value of b is (1) 11

(Q) Value of a is (2) 10

(R) Common root is (3) 12

(S) (a + b) is a multiple of (4) 6

(5) 2
(A) P → 3;Q → 4;R → 4;S → 4,5
(B) P → 2;Q → 3;R → 5;S → 1,5
(C) P → 5;Q → 2;R → 5;S → 1,5
(D) P → 4;Q → 4;R → 3;S → 5,2

3) The values of k ∈ R for which

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

sum of roots of x2 + (2 – k – k2)x – k2 = 0

(P) (1) –4
is zero

The roots of x2 + (2k – 1)x + k2 + 2 = 0

(Q) (2) 1
are in ratio 1 : 2

Sum of the square of the roots of

(R) (3) 5
x2 – (k – 2)x – k – 1 = 0 assume the least value
 kx2 – (k + 1)x + 2k – 1 = 0
(S) (4) –3
has equal roots

(5) 0
(A) P → 2;Q → 1;R → 3;S → 2
(B) P → 1;Q → 3;R → 3;S → 4
(C) P → 2;Q → 1;R → 2;S → 2
(D) P → 4;Q → 2;R → 3;S → 1

4) Let
Match the expressions/statements in Column I with expressions/statements in Column II.

Column–I Column–I

(A) If , then f(x) satisfies (P) 0 < f(x) < 1

(B) If 1 < x < 2, then f(x) satisfies (Q) f(x) < 0

(C) If 3 < x < 5, then f(x) satisfies (R) f(x) > 0

(D) If x > 5, then f(x) satisfies (S) f(x) < 1

(A) A → P;B → Q;C → R;D → S
(B) A → Q;B → P;C → R;D → S
(C) A → P, R, S;B → Q, S;C → Q, S;D → P, R, S
(D) A → Q, S;B → P, R, S;C → Q, S;D → P, R, S

SECTION-II

1) Let f(x) be polynomial of degree 5 with leading coefficient unity such that f(1) = 5; f(2) = 4; f(3) =
3; f(4) = 2; f(5) = 1 then value of f(6) is

2) The sum of all real values of x satisfying the equation is

3) The number of solutions of 3|x| (||x|2 – 4|x| + 3|) = 1 is

4) Let 'α' and 'β' are the roots of quadratic x2 – 5x – 1 = 0 then the value of is
equal to :

5) Let p, q ∈ {1, 2, 3, 4}. Then number of equation of the form px2 + qx + 1 = 0, having real roots, is

6) If ax9 + bx8 + 1 is divisible by x2 – x – 1 then value of 'a' is :-

 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B C A B

SECTION-I (ii)

Q. 5 6 7
A. A,C,D A,B B,C

SECTION-I (iii)

Q. 8 9 10 11
A. C B B C

SECTION-II

Q. 12 13 14 15 16 17
A. 136.00 8.00 6.00 9.00 300.00 5.00

CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. B C A A

SECTION-I (ii)

Q. 22 23 24
A. A,B,C,D A,B A,D

SECTION-I (iii)

Q. 25 26 27 28
A. C C C D

SECTION-II

Q. 29 30 31 32 33 34
A. 2.00 3.00 6.00 4.00 5.00 4.00

MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. B B A D

SECTION-I (ii)

Q. 39 40 41
A. B,C A,D B,D

SECTION-I (iii)

Q. 42 43 44 45
A. B B C C

SECTION-II

Q. 46 47 48 49 50 51
A. 120.00 2.00 8.00 27 7.00 21
 SOLUTIONS

PHYSICS

1)

Explanation :- resultant of two forces gets double when we double first vector, then angle has
to find according to given data
Concept :- Addition subtraction.
Solution :-
R2 = 9p2 + 4p2 + 12p2 cos θ ... (i)
4R2 = 36p2 + 4p2 + 24 p2 cos θ ... (ii)
from equation (i) & (ii) equating value of R2
13p2 + 12p2 cos θ = 10p2 + 6p2 cos θ
3p2 = – 6p2 cos θ

cos θ =
θ = 120°
Final answer :- 120°

2)

U = x3 + 3x2 – 9x + 6

x2 + 2x – 3 = 0
x2 + 3x – x – 3 = 0
x(x + 3) – 1(x + 3)=0
x = 1, x = –3

So at x = 1

x = 1 is minima
So 'U' is minimum at x = 1
Umin = 13 + 3(1)2 – 9(1) + 6
=1+3–9+6=1J

3)

Here,

= Ky and = Kx
 ydy = xdx

Integrating both sides

or y2 = x2 + constant

4)

Explanation Question:
Given acceleration-time graph, find times when particle velocity is zero, starting from rest.
Concept:
This question is based on Velocity = area under acceleration-time curve; zero velocity when
net area = 0
Solution:
Particle is initially at rest. Velocity at any time t is integral of acceleration:

From the a-t graph, particle returns to rest when total area under curve sums to zero.
Observing the graph, this occurs a t = 0, 2, 4 seconds.
Final Answer: (2)

5) Question Explanation: Two displacement-time curve is given for two particles along the x-
axis. It is also given that curves are parabolic then we have to select correct alternatives.

Concept: This question is based on graph analysis of kinematics variables.

Solution: (II) from figure (ii), as time increases, the slope of x-t curve decreases i.e., or
velocity decreases. Hence acceleration is negative means speed decreases but acceleration is
constant because x-t curve is parabolic (x t2).

(I) For figure (i), as t increases, the slope increases means velocity increases i.e., particle is
speeding up but again with constant rate.
⇒ a = constant

Final answer: The correct option are (1), (3) and (4).

6) (1) The sum of speeds of particles is

(2) The difference of speeds of particles is

7) Question Explanation: Identify the correct statements about the dimensions of constants
in the given equation.
Concept: Dimensional Homogeneity
Solution:
[X] = [A.C] = [D] = L
& [Bt] = 1
[B] = [T–1]
[BCt] = 1
∴ [C] = 1

Final Answer The correct options are (2), (3)

8) V = (t2 – 2t + 1)
At t = 3 sec, V = 4

a= = 2t – 2
at t = 2 sec, a = 2
when V = 0 ⇒ (t2 – 2t + 1) = 0

aav =

9)

Slope of S – t gives V – t

(P)

(Q)

(R)

(S)
(B) P → (2), Q → (4), R → (1), S → (3)

10)
(a)
Option (iv)
(b)
Option (iii)
(c)
Option (i)
(d)
Option (ii)

11) Question Explanation: The question asks to match dimensional formulas.

Concept: Principle of Homogeneity and Dimensional Analysis.
Solution:

(I)
(II) y = A cos (α2t2) ⇒ a2T2 = dimensionless

So, α2T2 = 1 ⇒

(III)
⇒ This complete function of log is dimensionless
(IV) y2 = y1 (1 + α (t2 – t1))
⇒ Here α (t2 – t1) is dimensionless
⇒ αT = 1 ⇒ [α] = T–1
Final Answer: Option (3)

12) Given

We know that

Solving equations (i) and (ii), we get

Now distance covered in 4 second after 5th

second

13)

14)
 15) × 4 × 1 + 4 × 2 + ×1×4+ ×2×1+2×2+ × 2 ×1
= 12 + 6 = 18

=9

16) ;

17)

Therefore =5

CHEMISTRY

18) Explain Question: Choose the incorrect statement.

Concept: atomic/ionic radii.
Solution:
1. (lonic Radius) - CORRECT
These are isoelectronic species (all have 18 electrons). For isoelectronic ions, the radius
decreases as the atomic number (number of protons) increases.
- has the fewest protons and the largest radius.
- has the most protons, pulling the electrons in most tightly, resulting in the
smallest radius.
2. (Atomic Radius) - INCORRECT
In the first transition series (3d), atomic radius generally decreases from left to right due to
increasing nuclear charge. However, toward the end of the series (Ni, Cu, Zn), the shielding
effect and electron-electron repulsions in the fully or nearly fully filled d-orbitals cause the
radius to level off or even increase slightly. Specifically, Zinc (Zn) is larger than Copper

Cu because its d -subshell is completely filled , leading to increased inter-electronic

repulsion.
3. (Electron Affinity) - CORRECT
While electron affinity generally decreases down a group, Chlorine has a higher electron
affinity than Fluorine. This exception occurs because Fluorine's small size leads to significant
electron-electron repulsion in its compact 2p subshell, making it harder to add an extra
electron compared to the larger 3 p subshell of Chlorine.

4. (Ionization Energy) - CORRECT

The ionization energy of an anion ( ) is equal to the electron affinity of the neutral atom (X).
Since the electron affinity of Chlorine is greater than that of Fluorine ( ), the energy
required to remove an electron from (its ionization energy) is higher than that of . Thus,
is the correct trend for ionization energy of these anions.

Final answer: option (2)

19) Ans. (3)

2 excess KOH + H2SO4 → K2SO4 + 2H2O
4 millimole 2millimole
Total KOH taken = 10 millimole
Saponification no. = (6 × 56) / 2 = 168

20)

Explain the question: Identify incorrect ionization trend.

Concept: Configuration and IE trends.

Solution:
The third ionization energy (IE3) is the energy required to remove an electron from a dipositive
cation (M2+).
Comparing the electronic configurations: Na2+ is [1s22s22p5] (isoelectronic with Fluorine),
while Mg2+ is [1s22s22p6] (stable noble gas configuration isoelectronic with Neon).
Removing an electron from a completely filled, highly stable noble gas subshell in
Mg2+ requires significantly more energy than from the partially filled subshell in Na2+; thus,
the correct order is Mg > Na.
This makes Statement 1 the incorrect match.
Regarding the other options: Pd(4d10) has a higher IE1 than Ag(4d105s1) because removing a
4d electron is harder than a 5s electron; He is higher than H due to noble gas stability and
higher Z; and IE2(Li)(1s2 → 1s1) is much higher than IE2(Ne)(2p5 → 2p4) because the 1s electrons
are much closer to the nucleus.

Final Answer: Option (1)

21)

Explanation Question: Question is asking about difference in wavelength of first and last line
of Lyman series for H+.
Concept: This question is based on atomic line spectrum.

Solution: Wave length =

Wave number for a line in spectrum
 Z = 2 Lyman series n1 = 1
First line n2 = 2, last line n2 = ∞

So,

Final Answer: Option (1).

22)

Question Explanation:
Select the correct statements.

Concept:
This question is based on Heisenberg's uncertainty principle.

Solution:

(1)

(2) Δp.Δx ≥
Δx = Uncertainty in position
Δp = Uncertainty in momentum
Since, Δx = Δp

m2Δv2

(3) PE = 2TE

∴ = –27.2 eV (Ist shell) (n = 1)

(4)
T.E of H-atom in 1st shell is -27.2 eV
 So E2 = -27.2 ×
E2 = –6.8 eV
So + 6.8 eV energy is required to remove electron from 2nd shell.

Final Answer:
The correct options are (1, 2, 3, 4)

23) A → Correct : Atomic size → increases down the group and decreases along the period.
So, O < C < S < Se
B → Correct: 1st IP → Increases along the period. Also fully / half filled configuration has more
I.P.
than next neighbour.
So, Na < Al < Mg < Si
C → Incorrect : Basic character → Increases down the group.
So, Cs2 O > K2O
D → Incorrect : Acidic character is higher for higher oxidation state.
So, P4 O10 < SO3 < Cl2 O7→ correct order.
+5 +6 +7

24) Question Explanation:

Finding the limiting reactant and product mass in a redox reaction.

Concept:
Limiting Reagent and Stoichiometry.

Solution:

z 4 g of H2 will completely react with 32 g of O2, but only 4 g of O2 is

present. Hence, O2 is limiting reactant.
Since, 32 g of O2 produces 36 g of H2O

Hence 4 g of O2 will produce of H2O

Final answer: Option (1,4)

25) Explanation Question: Choose correct statement.

Concept : This question is based on schrodinger wave equation
Solution :
(P) For s-orbital angular probability is independent of θ and ϕ ⇒ 4s
(Q) Radial nodes = 2
Radial nodes = n – ℓ – 1
For 5d ⇒ 5 – 2 – 1 = 2
For 5p ⇒ 5 – 1 – 1 = 3
For 4s ⇒ 4 – 0 – 1 = 3
For 3p ⇒ 3 – 1 – 1 = 1
(R) Number of maxima in 4πr2R2 v/s r graph = n – ℓ
for two maxima ⇒ n- l = 2
for 3p ⇒ 3-1 = 2
(s) Radial nodes = 3
4s, 5p
Final answer : 3

26) Question Explanation: Identify correct matches with given properties.

Concept: Apply concept of quantum no. and filling of electrons.
Solution:
• (P) Unpaired Electrons : Set (4) (Li, Na, K - ns1) and (5) (F, Cl, Br - np5) both have exactly 1
unpaired electron.
• (Q) Same electron in s and p subshells : Set (1) contains isoelectronic ions (Na+, Mg2+, F–).
They share the identical configuration 1s2 2s2 2p6, meaning they all have equal s (4) and p (6)
counts relative to one another.
• (R) Same l = 1 (p) electrons : Sets (1), (2) and (3) all revolve around the stable sp6 core.
Every species listed in these options has exactly options has exactly 6 p-electrons.
• (S) Same Total Electrons : Set (1) is the only isoelectronic set (all have 10 electrons.
Final Answer: Option (3)

27)

(I)

(II)

(III)

(IV)

28) The correct answer is option (D)

29)

Question Explanation: Find atomic number of 'X'

Concept: Closest distance of approach

Solution:
Energy K = 3.6 MeV = 3.6 × 106 × 1.6 × 10–19 J

Distance of closest approach:

Sum of digits of 20 is 2 + 0 = 2

Final Answer: 2

30) Question Explanation: Question is asking about number of orbit by given diagram of
wave.
Concept : This question is based on de-Broglie principle.
Solution:
Number of wave = number of orbit number = 6
n2 = 6, n1 = 3 (Paschen series)
Number of paschen lines emitted = (6 – 3) = 3
Final Answer : 3

31)

Question Explanation:
Find ratio of amount from percentage yield.

Concept:
This question is based on percentage yield.

Solution:
Br2 + Cl2 2BrCI
1 mol 1 mol 2 mol
0.025 0.025 0.05
Theoretical yield = 0.05 mol

Actual yield = = 0.04 mole

Br2 left unreacted = 0.025 – 0.02 = 0.005 mol

Final Answer:
The correct answer is 6

32)

Molecular formula of a compound is integral multiple of its empirical formula

C = 40%, H = 6.66%, O = 53.34%
EF = CH2O
V.D. = 60, [Link] = 2 × 60 = 120.

M.F = CH2O × 4 = C4H8O4 = CxH2yOz

So, x = 4, y = 4 and z = 4
∴ x + y + z = 4 + 4 + 4 = 12
 Final ans.

33) Explain the question : Finding group of element 'UnP'

Concept : This question is based on long form of periodic table.
Solution :
'UnP' E.C. = [Rn]Sf14 6d3 7S2
1OS
So group No. = 2+3
=5
Final answer : 5

34) Explain the question : Choosing pairs of element in which EA of second element is more
than first.
Concept : This question is based on electron affinity.
Solution :
[O, S] ⇒ O < S all 3rd period elements in p-block have more EA compared to 2nd period
elements
[C, N] ⇒ C > N
[O, N] ⇒ O > N
[N, P] ⇒ N < P
[Cl⊕, F⊕] ⇒ Cl⊕ < F⊕ |IE (A)| = |EA (A⊕)|
[K⊕, Na⊕] ⇒ K⊕ < Na⊕
Final answer : 4

MATHEMATICS

35) Question Explanation : In this question we have to find value of given expression.
Concept : Properties of logarithm.
Solution :

=
=
=
= 24 – 33 + 42 = 16 – 27 + 16 = 32 – 27 = 5
Final Answer : Option (2)

36)

Explanation of Question: In this question we have a cubic equation in terms of x and y and
we have to find value of (x + y)

Concept: “This question is based on factorization”.

Solution: Given x3 + y3 + 15xy = 125, x ≠ y
⇒ (x)3 + (y)3 + (–5)3 = 3 (x) (y) (–5)
⇒ As we know
if a3 + b3 + c3 = 3abc
then a + b + c = 0 or a = b = c
So, x + y – 5 = 0 or x = y = – 5
⇒ x + y = 5 as x ≠ y
required x + y = 5

Final Answer: The correct option is (2)

37)

Explain question : We have to find number of possible order pair(x,y) where x, y ∈ I+. for the
given equation.
Concept : This question is based on number system.
Solution :
Since x2 – y2 is even
⇒ either both x & y are even or both x & y are odd
⇒ x + y and x – y both are even in both the cases
⇒ x2 – y2 is divisible by 4
but 2010 is not divisible by 4 hence no solution.

Final answer : option (1)

38)

Question Explanation: Finding the value of a symmetric expression using Vieta's relations.

Concept: Relation between roots and coefficients of a cubic.

Solution: Given equation:

Roots are .

A. Sum of roots:

B. Product of roots taken two at a time:

C. Product of roots:

Since :

A.

B.
Substitute into the expression:

= -3(-2) = 6

Final Answer: 6

39) Let and ab = 1

Let ax = t
Given equation become

or

Solutions of the given equation is x = 2 or 2.

⇒ A = {–2, 2}

40) Solution :
ƒ(x) = |x – 6| + |x – 2| – |x – 4|
Case 1: x<2

Case 2: 2≤x<4

Case 3: 4≤x<6

Case 4: x≥6
for k = 4 ⇒ three solutions 0, 4, 8
In which two positive solutions whose sum is 12
for k = 3 ⇒ four solutions 1, 3, 5, 7
whose sum is 16
Final Answer : Option (1) and (4)

41)

. Also

Range of

42)

(I) ƒ(x) is symmetric with respect to

∴ 2k = –5
(II)
∴

(III) Range
∴ m = –5
(IV) ƒ(x) < 7
x2 + 5x – 6 < 0
(x + 6)(x – 1) < 0
∴ x ∈ (–6, 1)

43)
By (2) & (4) ⇒ a = 12
∴ Equation x2 – 8x + a = 0 is x2 – 8x + 12 = 0
New roots are x = 2 or 6.
If common root α = 2, then β = 2 for which we get 3β & 4β both are integers.

But, if common root is α = 6, then β = for which (4β) is not integer.

Hence, common root is 2.
∴ a = 12 & b = α + 4β = 2 + (4(2) = 10
∴ (a + b) = 12 + 10 = 22

44)

Question Explanation: Match the condition on roots of quadratic equations with values of k.
Concept: Relation between roots.
Solution:
(P) sum of roots of x2 + (2 – k – k2)x – k2 = 0 is zero
⇒ Sum of roots = –(2 – k – k2) = 0
⇒ (k + 2) (k – 1) = 0
⇒ k = 1, – 2
(Q) Let one root is α then other root is 2α
Sum of roots = α + 2α = –(2k – 1) ⇒ 3α = 1 – 2k
and product of roots = α(2α) = k2+ 2 ⇒ 2α2 = k2 + 2

⇒
⇒ k2 + 8k + 16 = 0
⇒ k = –4
(R) x2 – (k – 2)x – k – 1 = 0
Let roots are α and β
α + β = k – 2, αβ = –k – 1
α2 + β2 = (α + β)2 – 2αβ
α2 + β2 = (k – 2)2 + 2(k +1)
= k2 – 2k + 6 = (k – 1)2 + 5
so for k= 1 it assume least value
(S) kx2 – (k + 1)x + 2k – 1 = 0
For equal roots D = 0
(k + 1)2 – 4k(2k – 1) = 0
7k2 – 6k – 1 = 0 ⇒ (7k + 1) (k – 1) = 0

Final Answer: Option (3)

45)

for and x > 5;

⇒
⇒

Now,

(A) If ;
Hence, also
(B) If ;
(C) If ;
(D) If ;
Hence, also, .

46)

Question Explanation: Determining the value of a polynomial using root-based construction.

Concept: Factor Theorem and Polynomial Construction.

Solution:

Let .

Since 1, 2, 3, 4, 5 are roots and the leading coefficient is 1:

To find f(6):

f(6) = 120

Final Answer: 120

47)

Question Explanation: Finding real roots for an exponential equation of the form .

Concept: Properties of Exponents and Bases

Solution: Given:

A. Case 1: Exponent is zero

(Both valid as base )

 B. Case 2: Base is 1
(Already counted)

C. Case 3: Base is -1

Check exponent at (Even integer, so x = 1 is valid)

Real values of x are: 3, -2, 1

Sum: 3 + (-2) + 1 = 2

Final Answer: 2

48) 3|x| (||x|2 – 4|x| + 3|) = 1

49) Solution:

50) Solution :
px2 + qx + 1 = 0
For real roots, q2 – 4p ≥ 0
so possible values of (p, q) are (1, 4), (2, 4), (3, 4), (4, 4), (1, 3), (2, 3), (1, 2)
so number of equations are 7.

51)

Question Explanation: Finding the value of 'a' using roots of a divisor polynomial.

Concept: Remainder Theorem and Divisibility.

 Solution:

Now aα9 + bα8 + 1 = 0

...(1)

and aβ9 + bβ8 + 1 = 0

⇒ aβ + b + ...(2)

a = (1) (3) (7) = 21