30-05-2026

4602CJA101001260004 JA

PART-A-PHYSICS

SECTION-I(i)

1) A particle is projected at an angle θ above the horizontal with a speed u. After some time the
direction of its velocity makes an angle ϕ above the horizontal. The speed of the particle at this
instant is :-

(A)

(B)

(C)

(D)

2) A ball is projected from point A with velocity 10 m/s perpendicular to the inclined plane as shown
in the figure. The maximum height achieved by the projected with respect to inclined plane is :-

(Take g = 10 m/s2)

(A) 12.5 m
(B) 10 m
(C) 6.5 m
(D) 6.25 m

3) A car travels a distance of 2000 m. If the first half distance is covered at 40 km/hour and the
second half at velocity v and if the average velocity is 48 km/hour, then the value of v is :-

(A) 56 km/hour
(B) 60 km/hour
(C) 50 km/hour
(D) 48 km/hour

4) A body is dropped from a balloon moving up with a velocity of 4ms–1 when the balloon is at a
height of 120.5 m from ground. The distance of separation between the body and the balloon after 5s
is :- (Take g = 9.8 m/s2)
(A) 122.5m
(B) 100.5 m
(C) 132.5 m
(D) 112.5m

5) The area of acceleration-position (a-x) graph of a particle moving in a straight line gives :

(A) Final velocity

(B) Displacement
(C) Change in velocity
(D) None of these

6) Consider a hypothetical planet, the value of whose acceleration due to gravity on its surface is 8
m/s2. A small ball is thrown vertically upwards from its surface with some initial velocity. The
distance travelled by the ball in the last two seconds of its ascent is :-

(A) 5 m
(B) 16 m
(C) 10 m
(D) 4 m

SECTION-I(ii)

1) A 600 m wide river flows towards South at 4 m/s. A small motor boat travels at 5 m/s in still water

& points in such a direction so that it will travel towards East relative to land.

(A) The speed of boat relative to land is 3 m/s.

(B) The speed of boat relative to land is m/s.
(C) The time taken by boat to cross the river is nearly 200 second.
(D) The time taken by boat to cross the river is nearly 100 second.

2) Two cars 1 and 2 move along the same straight highway. Their position from a fixed origin varies
according to the following laws respectively.

(A) The time when they meet is 2 s.

(B) Distance travelled by car 1 is more than magnitude of displacement of car 2.
(C) The magnitude of relative velocity when they meet is 10 m/s
(D) The magnitude of relative acceleration when they meet is 4 m/s2.

3) If T is the total time of flight, h is the maximum height and R is the range for horizontal motion,
the x and y co-ordinates of projectile motion and time t are related as
(A)

(B)

(C)

(D)

4) A small ball of weight 10 N is suspended by two cords A and B as shown in the figure. Values of

tensions in the strings :-

(A) TA is 6 N.
(B) TB is 60 N.
(C) TB is 8 N.
(D) TB is 20 N.

5) A cubical box dimension L = 5/4 metre starts moving with an acceleration = 0.5 m/s2 from the
state of rest. At the same time, a stone is thrown from the origin with

velocity with respect to earth. Acceleration due to gravity The stone just touches
the roof of box and finally falls at the diagonally opposite point then :

(A)
v1 =
(B) v2 = 5

(C)
v3 =

(D)
v3 =

6) A wedge of mass m1 and a block of mass m2 are in equilibrium as shown. Inclined surface of the
wedge has an inclination α with the horizontal. Each surface is frictionless. The normal reaction on
the wedge at different surfaces may be

(A) m2g cos α

(B) m2 g sin α cos α
2
(C) m1g + m2 g cos α
(D) m1g + m2g sin α cos α

SECTION-III

1) A particle of mass 1 kg is thrown vertically upward from ground such that it remains in air for 4
sec. Magnitude of its average velocity for 4 seconds when it reaches the ground again is

2) A particle moves in a straight line, its position (in m) as function of time is given by x = (at2 + b).
What is average velocity in time interval t = 3 sec to t = 5 sec in m/s. (Where a and b are constants
and a = 1 m/s2, b = 1 m.)

3) The hour hand of a clock is long. Find the displacement (in cm) of the tip between 1:00
pm to 4:00 pm.

4) Distance travelled by the particle (in m) moving under gravity upward direction in last second is :-
(Take g = 10 m/s2)

5) How much tension is there in the string connecting both blocks (All surfaces are smooth)

PART-B-CHEMISTRY

SECTION-I(i)

1) The Difference in wavelength of first and last line of lyman series in emission spectrum of He+
would be :

(A)

(B)
(C)

(D)

2) The percentage of orbitals occupied by electron out of total orbitals present upto the outer most
filled shell of Fe atom

(A) 50%
(B) 70%
(C) 25%
(D) 35%

3) The correct curve for 3p orbital is -

(A)

(B)

(C)

(D)

4) Which of the following match is incorrect :

(A) Na > Mg ⇒ 3rd ionisation energy

(B) Pd > Ag ⇒ 1st ionisation energy
(C) H < He ⇒ 1st ionisation energy
(D) Ne < Li ⇒ 2nd ionisation energy

5)

In the formation of X+2(g) from X+(g) , 4 eV energy is absorbed, which would be equal to :

+
(A) |ΔHe.g| of X (g)
+2
(B) IE of X (g)
(C) IE of X(g)
+2
(D) |ΔHe.g| of X (g)

6) Which of the following element having electron affinity greater than S

(A) O
(B) Se
(C) Te
(D) None of these

SECTION-I(ii)

1) For the three graphs given below of radial probability distribution and distance, which of the
following option(s) is/are correct?

(A) Graph A may be for 3d orbital

(B) Graph B may be for 3p orbital
(C) Graph C may be for 3p orbital
(D) Graph C may be for 3s orbital

2) A sodium street light gives off yellow light that has a wavelength of 600 nm. Then (For energy of

a photon take E = )

(A) frequency of this light is 7 × 1014 s–1.

(B) frequency of this light is 5 × 1014 s–1.
(C) wave number of the light is 3 × 106 m–1.
(D) energy of the photon is approximately 2.07 eV.

3) In a hydrogen like sample two different types of photons A and B are produced by electronic
transition. Photon B has it’s wavelength in infrared region. If photon A has more energy than B, then
the photon A may belong to the region

(A) ultraviolet
(B) visible
(C) infrared
(D) None

4) Which of the following has same value of orbital angular momentum ?

(A) 1s
(B) 2s
(C) 3s
(D) 4s

5) Which of the following statements are correct for an electron that has the quantum number n = 4
and m = 2 ?

(A)
The electron may have the quantum number, ms = +
(B) The electron may have the quantum number, =2
(C) The electron may have the quantum number, m = 2
(D) The electron may have the quantum number, = 0, 1, 2.

6) Select the incorrect order of I.E.:-

(A)
(B)
(C)
(D)

SECTION-III

1) Total spectral lines observed in between 11th excited state and 3rd energy level in a sample of H-
atom emission spectrum are. Fill your answer as sum of digits (excluding decimal places) till
you get the single digit answer.

2) On a metal with work function 2.0 eV light of wavelength 400nm falls, maximum velocity of
ejected photoelectrons are 6.22 × 10x m/s. Hence x is.

3) The number of elements from the following group having I.E. greater than O (Z = 8)
Li, Be, B, C, N, F, Ne, S, Si

4) The number of waves in the fourth Bohr orbit of hydrogen is.

5) The number of paired electrons in oxygen atom is:

PART-C-MATHEMATICS

SECTION-I(i)

1)

In a G.P., first term is 1. If 4T2 + 5T3 is minimum then its common ratio is

(A)

(B)

(C)

(D)

2) If b is the arithmetic mean between a and x; b is the geometric mean between 'a' and y; 'b' is the
harmonic mean between a and z, (a, b, x, y, z > 0) then the value of xyz is

(A) a3
(B) b3

(C)

(D)

3) The geometric series a + ar + ar2 + ..... + ∞ terms has the sum 7 and the terms involving even
powers of r has the sum 4. The value of is

(A) 1
(B) 2
(C) 3
(D) 4

4) Let , then is

(A) 1

(B)

(C) 2

(D)
5) Minimum value of cos2θ + cosθ for all real values of θ is-

(A)

(B) 0
(C) –2
(D) None

6) If f(θ) = (tan θ/2) (1 + sec θ) then f(15º) is equal to :-

(A)
(B)
(C)
(D) None

SECTION-I(ii)

1) Which of the followings is/are CORRECT

(A)

(B)

(C)

(D)

2) If (sin x + sin 2x + sin 3x)2 + (cos x + cos 2x + cos 3x)2 = 1 then cos x can have the value equal to

(A) 1
(B) 0

(C)

(D) -1

3) If a, b, c are in H.P., then

(A)
are in H.P.

(B)

(C)
are in G.P.

(D)
are in H.P.

4) Let Sn be the sum of the first n terms of an arithmetic progression. If S3n = 3S2n, then the value of
 is less than :

(A) 6
(B) 4
(C) 7
(D) 8

5) Let a, b, c be distinct real numbers in G.P. & a + b + c = bx then x can not be

(A) –1
(B) 0
(C) 2
(D) 3

6) If first and (2n – 1)th terms of an A.P., G.P. and H.P. are equal and their nth terms are a, b, c
respectively where a, b, c are positive real numbers then -

(A) a + c = 2b
(B) a ≥ b ≥ c
(C) a + c = b
(D) b2 = ac

SECTION-III

1) Maximum value of the expression is equal to

2) If sin3x + Asin2x + Bsinx = Csin3x, ∀ x ∈ R, then the value of |A + B + C| is

3) If
Where Natural numbers.
Then A + B = ?

4) Sum of all possible values of is (wherever defined)

5) If x = 30º, then the sum of series 1 + cos2x + cos22x + cos32x+.......upto infinite term is
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. B D B A D B

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,C A,B,D A,B A,C A,B,C A,B,C

SECTION-III

Q. 13 14 15 16 17
A. 0 8 6 5 4

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. A A D A D D

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. A,B,D B,D A,B,C A,B,C,D A,B,C A,C,D

SECTION-III

Q. 30 31 32 33 34
A. 9 5 3 4 6

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. B D A C A B

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,B,C B,D A,B,C,D C,D A,B,C,D B,D
 SECTION-III

Q. 47 48 49 50 51
A. 2 7 3 2 2
 SOLUTIONS

PART-A-PHYSICS

1)

u cos θ = v cos ϕ

2) Uy = 10 m/s
ay = – g cos 37° = – gy
Vy2 – Uy2 = – gy Hmax

Hmax = = = 6.25.

3) Average velocity =

⇒ V = 60 km/hr

4) Sbody = ut + = 4 × 5 – × 9.8 × 25
= –102.5 m
Thus body is 102.5 m below the initial position
Sballoon = 4 × 5 = 20 m
∴ Separation = 20 + 102.5 = 122.5 m

5) Area of

acceleration position =
New Sol.

Area =

6) = × 8 × (2)2 = 16 m

7) Sol.
vb = 3m/s

8)

x1 = 5t + 2 t2
(B) t = 0 x = 0
t = 2 x = 18
∴ Δx =18
x2 = 24 – 3t
t = 0 x = 24
t = 2 x = 18
∴ Δx = 6
(C) v1 = 5 + 4t at t = 2; v1 = 13
v2 = –3
∴ vrel = 10 m/s
(D) a1 = 4
a2 = 0
∴ arel = 4 m/s2

9)

so
10)

11)

H=
⇒ uy = 5m/s

T= 1 sec

α=4×t– a × t2 (as in × direction)

= 4x × 1 – × (0.5) × 12 ux = 3/2 m/sec

Along 2 axis = u2 × 1 ⇒ v2 = 5/4 m/sec

12)

N3 = m2 g cos α
N3 sin α = N1
N2 = m1g + N3cosα
⇒ N1 = m2 g sinα cos α
⇒ N2 = m1 g + m2g cos2α
 13) After 4 sec. displacement of particle is zero, so magnitude of average velocity is zero.

14) (x = at2 + b) a = 1, b = 1
(x = t2 + 1) ⇒ v = 2t

Average velocity =8

15)

16)

17)
4–T = 2a
T–4 = 2a
a = 0, T = 4
Ans. 4

PART-B-CHEMISTRY

18)

Explanation Question: Question is asking about difference in wavelength of first and last line
of Lyman series for H+.
Concept: This question is based on atomic line spectrum.
 Solution: Wave length =
Wave number for a line in spectrum

Z = 2 Lyman series n1 = 1
First line n2 = 2, last line n2 = ∞

So,

Final Answer: Option (1).

19) Question Explanation: Calculate % of orbitals occupied by electron for Fe atom.

Concept: Electronic configuration.

Solution:
Fe = 1s2 2s2 2p6 3s2 3p6 4s2 3d6
outer most orbit n = 4
Total orbital 1s = 1
2s + 2p = 4
3s + 3p + 3d = 9
4s + 4p + 4d + 4f = 16
_________
30
Occupied orbital
1s = 1
2s = 1
2p = 3
3s = 1
3p = 3
3d = 5
4s = 1
________
15

Final Answer: The correct option is (1)

20)
Question Explanation: Identifying the correct radial probability distribution curve for a 3p
orbital.

Concept: Atomic Orbitals and Quantum Mechanics.

Solution: The radial probability distribution function, 4πr2ψ2(r), gives the probability of finding
an electron in a spherical shell of thickness dr at a distance r from the nucleus. For a 3p
orbital, the number of radial nodes is n−l−1=3−1−1=1. The graph of 4πr2ψ2(r) vs. r for a 3p
orbital will start at zero, show two peaks (maxima), and have one point where the probability
is zero (a node) between the peaks. Graph (D) correctly depicts this feature.
Final Answer: The curve in option (D)

21)

Explain the question: Identify incorrect ionization trend.

Concept: Configuration and IE trends.

Solution:
The third ionization energy (IE3) is the energy required to remove an electron from a dipositive
cation (M2+).
Comparing the electronic configurations: Na2+ is [1s22s22p5] (isoelectronic with Fluorine),
while Mg2+ is [1s22s22p6] (stable noble gas configuration isoelectronic with Neon).
Removing an electron from a completely filled, highly stable noble gas subshell in
Mg2+ requires significantly more energy than from the partially filled subshell in Na2+; thus,
the correct order is Mg > Na.
This makes Statement 1 the incorrect match.
Regarding the other options: Pd(4d10) has a higher IE1 than Ag(4d105s1) because removing a
4d electron is harder than a 5s electron; He is higher than H due to noble gas stability and
higher Z; and IE2(Li)(1s2 → 1s1) is much higher than IE2(Ne)(2p5 → 2p4) because the 1s electrons
are much closer to the nucleus.

Final Answer: Option (1)

23)

Explanation Question :
The element with E.A high than S in group-16.

Concept :
This question is based on S have most E.A in their group.
Solution :

Final Answer:
The correct option is (4)
24)

Graph A does not have any radial node, it may represent : 1s, 2p, 3d…..
Graph B is having one node, it may represent : 2s, 3p, 4d…..
Graph C is having two node, it may represent : 3s, 4p, 5d…..

25)

Explanation: Calculate frequency, wave number and energy for λ = 600nm

Concept: This question is based on Planck quantum theory
Solution:

= = = 5 × 1014 sec–1

E= = 2.07 eV

= 1.67 × 106 m–1

Final Answer: option (2), (4)

26)

Photon A Photon B
↓ ↓
Has more energy I.R region
↓
Will have lesser
wave length

27) Question Explanation: Find orbitals with same value of orbital angular momentum.
Concept : This question is based on Quantum numbers.

Solution: Orbital angular momentum = for 1s, 2s, 3s, 4s ( = 0)

orbital angular momentum =

All orbitals have same value.
The correct options are (1), (2), (3) and (4)

28)
 Question Explanation:

Select correct statement for electron having n = 4 and m = 2.

Concept:

This question is based on Quantum number.

Solution:

n ℓ m s may be + or –
4 0 0
1 –1, 0, +1
2 –2, –1, 0, +1, +2
3 –3, –2, –1, 0, +1, +2, +3
Therefore all statements are correct.

Final Answer:

The correct options are (1, 2, 3 & 4).

29) Question Explanation: Question is asking about incorrect order of ionization energy.
Concept: This question is based on successive ionization energy.
Solution:
Cl⊕ Cl Cl– iso-protonic
Z 17 17 17 iso-protonic
e 16 17 18

So, Cl⊕ > Cl > Cl– is correct.

But incorrect will be 1, 3, 4
Final answer: The correct option are (1), (3), (4).

30) Question Explanation:

Find total number of spectral lines.

Concept:
This question is based on line spectrum of hydrogen.

Solution:
n2 = 12 (11th excited state)
n1 = 3

Spectral lines =
 or 4 + 5 = 9

Final Answer:
The correct answer is 9

31) Question Explanation: Finding the exponent of the maximum velocity of photoelectrons.
Concept: Photoelectric Effect and Kinetic Energy
Solution: Given: work function = 2.0 eV and wavelength = 400nm
Energy of incident photon (E):

Maximum Kinetic Energy :

Convert to Joules:

Maximum Velocity :

Comparing with 6.22 10x, we find x = 5.

Final Answer: (5)

32)

Question Explanation: Count elements whose first ionization energy (IE1) is greater than
oxygen (O).
Concept: IE increases across a period; exceptions include higher IE of N (half-filled p3 ) and
noble gases (Ne).

Solution (Summary Table):

Element IE1 compared to O Result

Li Lower x
Be Lower x
B Lower x
C Lower x
N Higher ü
F Higher ü
Ne Much higher ü
S Lower x
Si Lower x
 Final answer: 3

33) Explain Question: Find how many de Broglie waves fit into the 4th Bohr orbit of
hydrogen.

Concept: Bohr's quantization condition:

2πrn = nλ
where n is the principal quantum number, representing the number of de Broglie wavelengths
in the orbit.

Solution:
According to Bohr's postulate, an electron in the nth orbit accommodates exactly n de Broglie
wavelengths.
For the 4th orbit (n = 4):
Number of waves = n = 4
Final Answer: (4)

34) O = 1s22s22p4

PART-C-MATHEMATICS

35)

4T2 + 5T3 = 4r + 5r2

5r2 + 4r is minimum at

36) 2b = x + a .....(1)
2
b = ay ....(2)

b= ....(3)

x = 2b – a; y=

and = +

⇒z=

∴ xyz = (2b – a) ·

= Ans.

37) Ans. (1)

 ⇒ ⇒

⇒a–r=1

38)

39) cos2θ + cosθ

2cos2θ – 1 + cosθ
\(2\left[ {{{\left( {\cos \theta + \frac{1}{4}} \right)}^2} - \frac{1}{2} - \frac{1}{{16}}}
\right]\)
\(2\left[ {{{\left( {\cos \theta + \frac{1}{4}} \right)}^2} - \frac{9}{{16}}} \right]\)
\(2{\left( {\cos \theta + \frac{1}{4}} \right)^2} - \frac{9}{8}\)

40) Mean deviation =

41)

Concept : We know that

cosecθ, sinθ is +ve in Ist, IInd Quadrant
cosθ, secθ is +ve in Ist, IVth
tanθ, cotθ is +ve in Ist, IIIrd

Solution : Option (A) sin 225o = sin(180 + 45o)

= - sin 45o =
Option (B) cosec (390o) = cosec(360 + 30o)
= cosec 30o = 2

Option (C) tan = tan = tan =

Option (D) cot = =

Hence (A) (B) (C) is correct

42) Simplifying 2 cos2x + 2cosx = 0

cos x = 0 or cos x = –1

43) a, b, c are in H.P. ⇒ are in A.P.

are in A.P.

are in A.P. [subtracting 1 from each term]

 are in A.P.

Thus are in H.P.

and are also in H.P.

also

Lastly,

are in G.P.

44) Let a be first term and d be common diff. of this A.P.

Given S3n = 3S2n

⇒ 2a + (3n – 1)d = 4a + (4n – 2)d

⇒ 2a + (n – 1)d = 0

Now,

45)

46) Let α be the first and β be the (2n – 1)th term of an A.P. G.P. and H.P., then α, a, β will be in
A.P. a, b, b will be in G.P. and α, c, β in H.P.
Hence a, b, c are respectively A.M., G.M. and H.M. of α and β.
Since A.M. ≥ G.M. ≥ H.M. ⇒ a ≥ b ≥ c

Again a = , b2 = αβ and c =
∴ b2 = ac

47) = (sinx + cosx)2 < 2

48) (sinx)(3 – 4sin2x + 2Acosx + B) = Csin3x
3sinx – 4sin3x + 2Asinxcosx + Bsinx = Csin3x
sinx(B + 3) – 4sin3x + 2Asinxcosx = Csin3x
⇒ B = –3, C = –4, A = 0
⇒ |A + B + C| = 7

49) Use

50) Possible values 3, –1

51) Put x = 30º