10-05-2026

1001CTM404021260004 TM

Physics

1) The roots of the quadratic equation 3x2 + 4x – 4 = 0

(1)

(2)

(3)
–

(4)

2) The approximate values of cos 1° is.

(1)

(2)

(3) 1

(4)

3) Evaluate :

(1)

(2)

(3) 1

(4)

4) If the product of roots of the quadratic equation given below is 4, then find the value of m is.
2x2 + 8x – m3 = 0

(1) –2
(2) –1
(3) 1
(4) 2

5) α and β are the roots of 4x2 + 3x + 7 = 0, then the value of is

(1)

(2)

(3)

(4)

6)

Column I Column II

(A) cos 53° (P)

(B) sin 217° (Q)

(C) cot 143° (R)

(D) sin 143° (S)

(T)

(1) A → P, B → R, C → S, D → Q
(2) A → R, B → S, C → Q, D → T
(3) A → T, B → P, C → Q, D → R
(4) A → Q, B → P, C → R, D → Q

7) If and . The value of A and B respectively

(1) 18°, 24°

(2) 24°, 18°
(3) 20°, 20°
(4) 18°, 36°

8) If , then value of 10tanθ is

(1) 12
(2) 24
(3) 6

(4)

9) The value of sin 60o + cos 30o is

(1) 1
(2)
(3) 2

(4)

10) If , what is the value of tanθ in the first quadrant ?

(1) 1

(2)

(3)
(4) 2

11) Find the value of tan75°

(1)

(2)

(3)

(4)

12) The value of sin480° is

(1)

(2)

(3)

(4)

13) When a clock shows 4 o'clock, how much angle do its minute and hour needles make?

(1) 20°

(2)

(3)

(4) 160°

14) If then the value of A is

(1) 7
(2) 1
(3) 5
(4) 25

15) If then the value of cotθ is

(1)

(2)

(3)

(4)

16) Sin 1o× Sin 2o × Sin 3o ....... Sin 180o is?

(1)

(2) 0
(3) 1
(4) –1

17)

If α, β are the roots of x2 – 8x + p = 0 and α2 + β2 = 40, then the value of p is

(1) 8
(2) 10
(3) 12
(4) 14

18) – sin θ is not equivalent to ?

cos
(1)

cos
(2)

(3) sin (θ – π)
(4) sin (θ + π)

19) Value of sin(–420°) cos(390°) + cos(–660°) sin(330°) is :

(1) 0
(2) –1
(3) 1

(4)

20) Determine the value of tan2x if

(1)

(2)

(3)

(4)

21) If and , the value of is

(1) 1
(2) 0.90
(3) 0.80
(4) 2

22)

The expression ax = b is equivalent to -

(1) logax = b
(2) logxa = b
(3) logab = x
(4) logba = x

23) Find

(1) e2
(2) 2e
(3) e
(4) 2

24)

The maximum value of y = sin(x) cos(x) is :

(1)

(2)
(3)

(4)

25)

Which of following is possible :-

(1) sin θ >1

(2) sin θ ≥ –1
(3) tan θ > ∞
(4) None

26) sin2 233° = ?

(1)

(2)

(3)

(4)

27) If θ = rad then the value of θ in degree is

(1) 760°
(2) 560°
(3) 660°
(4) 460°

28) In the shown diagram arc length (ℓ) in cm will be:

(1) 18π
(2) 6π
(3) 9π
(4) 12π

29) Value of sin 22.5° is :-

(1)

(2)

(3)

(4)

30) Value of sin(45°+ θ) cos(15°+ θ) – cos(45°+ θ) sin(15°+ θ) is :-

(1) 1

(2)

(3)

(4)
–

Chemistry

1)

The total no. of protons, electrons and neutrons in 12 g of 6C12 is :-

(1) 1.084 × 1025

(2) 6.022 × 1023
(3) 6.022 × 1022
(4) 18

2)

Arrange the following in order of increasing Masses:-

(i) 1 Mole of oxygen gas
(ii) 1 Molecule of oxygen gas
(iii) 10–10 g of iron
(iv) 1 g-atom of nitrogen atom

(1) i < ii < iii < iv

(2) i < iii < iv < ii
(3) iii < iv < ii < i
(4) ii < iii < iv < i

3) How many molecule are present in one mL of water vapours at STP :-

(1) 1.69 × 10+19

(2) 2.69 × 10–19
(3) 1.69 × 10–19
(4) 2.69 × 10+19

4) Which one of the following is not a mixture ?

(1) Tap water

(2) Distilled water
(3) Salt in water
(4) Oil in water

5) Match the following prefixes with their multiples :-

(a) Micro (i) 10–12

(b) Mega (ii) 10–6

(c) Giga (iii) 106

(d) Pico (iv) 109

(1) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
(2) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
(3) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
(4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)

6) Assertion: Components of a homogeneous mixture can be separated by using physical methods.

Reason: Composition of homogeneous mixture is uniform throughout as the components react to
form.

(1) Both assertion and reason are true and reason is the correct explanation of assertion.
(2) Both assertion and reason are true, but reason is not the correct explanation of assertion.
(3) Assertion is true, but reason is false.
(4) Both assertion and reason are false.

7) The number of neutrons in 5 g of D2O (D is ) are :

(1) 0.25 NA
(2) 2.5 NA
(3) 1.1 NA
(4) 1.5 NA

8) Find the incorrect relation?

(1) 1 amu = 1.67 × 10–24 g

(2) 1 eV = 1.6 × 10–19 J
(3) 1 erg = 107 J
(4) 1 atm = 760 torr

9) Which of the following is an example of compound ?

(1) Salty water

(2) Air
(3) Acetic acid
(4) Oxygen gas

10) Equal masses of O2, H2 and CH4 are taken in a container. The respective mole ratio of these
gases in container is -

(1) 1 : 16 : 2
(2) 16 : 1 : 2
(3) 1 : 2 : 16
(4) 16 : 2 :1

11) Aspirin has the formula C9H8O4. How many atoms of oxygen are there in a tablet weighing 360
mg?

(1) 1.204 × 1023

(2) 1.08 × 1022
(3) 1.204 × 1024
(4) 4.81 × 1021

12) The largest no. of molecules are in:

(1) 36 g H2O
(2) 28 g CO
(3) 46 g C2H5OH
(4) 54 g N2O5

13)

A recorded Fahrenheit value in laboratory is 122 degrees. Its corresponding kelvin temperature is:-

(1) 32
(2) 273
(3) 52
(4) 323

14) Convert 5g/cm3 in kg/m3 :-

(1) 103 kg/m3

(2) 10–3 kg/m3
(3) 5 × 103 kg/m3
(4) 5 × 10–3 kg/m3

15) Which of the following is not a fundamental unit :-

(1) Mole
(2) Kilogram
(3) Gram
(4) Candela

16) Convert 3800 mm of Hg pressure into atm. pressure

(1) 1.5 atm

(2) 5 atm
(3) 3 atm
(4) 7.5 atm

17) which is the correct SI unit ?

Column- I Column-II
(P) Volume (a) kg/m3
(Q) Density (b) m3
(R) Temperature (c) candela
(S) Luminous intensity (d) kelvin
(1) P → b, Q → a, R → d, S → c
(2) P → b, Q → a, R → c, S → d
(3) P → c, Q → b, R → a, S → d
(4) P → d, Q → a, R → b, S → c

18) Convert 3 × 1017 nm into metre :

(1) 3 × 108 m
(2) 3 × 10–8 m
(3) 3 × 10–11 m
(4) 3 × 10–14 m

19) Arrange following prefix in increasing order -

deci, nano, kilo, milli

(1) kilo < nano < deci < milli

(2) kilo < nano < milli < deci
(3) nano < deci < milli < kilo
(4) nano < milli < deci < kilo

20) The number of Cl– and Ca+2 ions respectively, in 222g. of CaCl2 are :
(1) 4NA, 2NA
(2) 2NA, 4NA
(3) 1NA, 2NA
(4) 2NA, 1NA

21) The number of hydrogen atoms present in 25.6 g of sucrose (C12H22O11) which has a molar mass
of 342.3 g, is :

(1) 22 × 1023
(2) 9.91 × 1023
(3) 11 × 1023
(4) 44 × 1023

22) Given below are two statements:

Statement-I : 1g each of O2 and O3 contains and atoms respectively.

Statement-II : 1g each of O2 and O3 contains same number of molecules.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(1) Statement-I and II both are correct.

(2) Statement-I is correct while II is incorrect.
(3) Both Statement-I and II are incorrect.
(4) Statement-I is incorrect and II is correct.

23) The ratio of oxygen to hydrogen atom in (NH4)3PO4 :-

(1) 3 : 1
(2) 1 : 1
(3) 3 : 4
(4) 1 : 3

24) Match the column:

Column-I Column-II

(A) Amount in gram in 20 mol H2SO4 (P) 20 NA

(B) No. of mol of H2O in 540 g (Q) 6.02 × 1013

(C) No. of atoms in 10–10 g H2 (R) 30

(D) No. of amu in 20 g (S) 1960

(1) (A) → (S), (B) → (R), (C) → (Q), (D) → (P)
(2) (A) → (P), (B) → (R), (C) → (S), (D) → (Q)
(3) (A) → (R), (B) → (S), (C) → (P), (D) → (Q)
(4) (A) → (P), (B) → (R), (C) → (Q), (D) → (S)
25) One atom of an element x weighs Number of moles of atoms in its 20 kg is :

(1) 4
(2) 40
(3) 100
(4) 500

26) The charge present on 1 mole electrons is :

(1) 96500 Coulombs

(2) 965 Coulomb
(3) 1.60 × 10-19 C
(4) 0.1 Faraday

27) Which of the following has highest mass ?

(1) One gram atom of Iron

(2) 5 moles of N2
(3) 1024 carbon atoms
(4) 44.8 lit of He at STP

28) The total number of atoms of all elements present in 2.5 mole of ammonium dichromate (NH4)2
Cr2O7 is :

(1) 2.86 × 1025

(2) 19
(3) 6.023 × 1023
(4) 84 × 1023

29) Which one of the following gas contains the same number of molecules as 16 g of oxygen gas?

(1) 16 g of O3
(2) 16 g of SO2
(3) 32 g of SO2
(4) All the above

30) Which of the following statements are incorrect.

(a) One-twelfth of the mass of one carbon-12 atom is amu
(b) 1 mol of water molecules = water molecules
(c) 12-g of C-12 is 1amu
(d) Mass of 1amu is 1.67 × 1027 kg.

(1) a, b, c, d
(2) a, b, d
(3) c & d
(4) b & d

Mathematics

1) If n is an odd natural number, 32n + 22n is always divisible by

(1) 13
(2) 5
(3) 17
(4) 19

2) If x, y ∈ N satisfying x2 – y2 = 143 then 2x + 3y is

(1) 25
(2) 27
(3) 9
(4) 31

3) If x + iy = where x, y ∈ R, then x + y =

(1) 1
(2) 0
(3) –1
(4) 2

4) (i10 + 1) (i9 + 1) (i8 + 1) ............(i + 1) equals where

(1) –1
(2) 1
(3) 0
(4) 1

5) If x + y = a and x2 + y2 = b, then (x3 + y3) is

(1) ab
(2) a2 + b
(3) a + b2

(4)

6) If the conjugate and the reciprocal of a complex number Z = x + iy are equal where x, y ∈ R, then

(1) x + y = 1
(2) x2 + y2 = 1
(3) x – y = 1
(4) none of these

7) If the real number x, y , z satisfying the

equations and then (x + y + z) equals to

(1) 24
(2) 12
(3) 10
(4) 9

8) If a, b, c, ∈ R where a + b + c = 25 and

then value of

will be

(1) 247
(2) 622
(3) 647
(4) 673

9) If n is any positive integer, then (34n – 43n) is always divisible by

(1) 7
(2) 17
(3) 112
(4) 145

10) If z = then real part of z is

(1) 2

(2)

(3)

(4) 0

11) The conjugate of is

(1)

(2)
(3)

(4)

12) If (12 + 22 + 32 + ........ +102) = 385, then the value of (22 + 42 + 62 + .......+ 202) is

(1) 770
(2) 1155
(3) 1540
(4) 385 × 385

13) The expression simplifies to

(1) 4
(2)
(3)
(4) 6

14) Square root of 5 + 12i is

(1) ± (3 + 2i)
(2) 3 + 2i
(3) – (3 – 2i)
(4) 3 – 2i

15) If x is a natural number which is a perfect square then the value of x + must end in

(1) 0 or 5
(2) 0 or 1 or 9
(3) 0 or 2 or 6
(4) 0 or 4 or 8

16) The value of sum where i = is

(1) i
(2) i – 1
(3) –i
(4) 0

17) The value of – is

(1) 2
(2) –1
(3)
(4) 1

18) If 4a2 + 9b2 – 12a + 12b + 13 = 0 then a + b equal to

(1)

(2)

(3)

(4)

19) The polynomial P(x) = ax3 + 3x2 – 3 and Q(x) = 2x3 – 5x + a when divided by (x – 4) leaves same

remainder, then value of is

(1) 1
(2) 2
(3) 3
(4) 4

20) For all real values of a, b and c the value of expression a2 + b2 + c2 – ab – bc – ca is always

(1) positive
(2) negative
(3) zero
(4) none negative

21) If , then is

(1) 115
(2) 117
(3) 123
(4) 118

22) The quotient when 100100 is divided by 5050 is

(1) 5050
(2) 50100
(3) 20050
(4) 40050
23) Number of natural number 'n' for which is a natural number is

(1) 2
(2) 3
(3) 4
(4) 6

24) If 1x3y6 is a five digit number where x and y are digits and y exceeds x by 6. If this number is

divisible by 18 then the value of is

(1) 3
(2) 5
(3) 7
(4) None of these

25) is equal to

(1) 1
(2) 0
(3) i
(4) –i

26) If 3a = 9b = 27c and abc = 288, then equals

(1)

(2)

(3)

(4)

27) = .........

(1)

(2)

(3)

(4)
28) If z = 1+ i, then the multiplicative inverse of z2 is where

(1) 2i
(2) 1 – i
(3) –i/2
(4) i/2

29) The value of x3 – x2 + 2x + 10, when x = 1 + i

(1) 5
(2) 6
(3) 3
(4) 1

30) The least positive integer k, such that 2 divides k, 3 divides k + 1, 4 divides k + 2, 5 divides k +
3 and
6 divides k + 4 is

(1) 62
(2) 120
(3) 720
(4) 52
 ANSWER KEYS

Physics

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 3 3 3 1 2 4 1 2 2 2 2 2 3 3 2 2 3 2 2 2
Q. 21 22 23 24 25 26 27 28 29 30
A. 2 3 4 1 2 3 3 2 3 3

Chemistry

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. 1 4 4 2 2 3 2 3 3 1 4 1 4 3 3 2 1 1 4 1
Q. 51 52 53 54 55 56 57 58 59 60
A. 2 3 4 1 4 1 2 1 3 3

Mathematics

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. 1 2 2 3 4 2 4 3 2 3 2 3 2 1 3 2 4 4 2 4
Q. 81 82 83 84 85 86 87 88 89 90
A. 3 3 4 3 2 2 2 3 2 1
 SOLUTIONS

Physics

1) 3x2 + 4x – 4 = 0
3x2 + 6x – 2x – 4 = 0
3x(x + 2) – 2(x + 2) = 0
(3x – 2) (x + 2) = 0

2)

3) {∵ cos (90° – θ) = sin θ}

4) On comparing
2x2 + 8x – m3 = 0
and
ax2 + bx + c = 0
We get a = 2, b = 8 and c = – m3
Given : Product of the roots is 4.
Then,

Multiply each side by (–2).

m3 = –8
m3 = (–2)3
m = –2

5)

Explain Question:
Calculating the sum of the reciprocals of the roots for a quadratic equation.

Concept:
Relation between Roots and Coefficients.

Solution:

The expression is equivalent to . We find the sum and product of the roots using
the coefficients a, b, and c from the standard form ax2 + bx + c = 0.
Calculation:
• Step 1: Identify coefficients from 4x2 + 3x + 7 = 0: a = 4, b = 3, c = 7
• Step 2: Sum of roots

• Step 3: Product of roots

• Step 4: Substitute into

Final Answer: Option (2)

6) Explain Question:
Matching trigonometric ratios of various angles to their numerical values.

Concept:
Trigonometric Quadrants and Reference Angles.

Solution:
Determine the quadrant of each angle to find the sign (positive/negative) and use reference
angles (37° or 53°) to find the value.
Calculation:

(A) cos 53° : 1st quadrant (positive). Value is . → (Q)

(B) sin 217°: 3rd quadrant (negative). sin(180° + 37°) = – sin 37° = . → (P)

(C) cot 143° : 2nd quadrant (negative). cot(180° – 37°) = – cot 37° = . → (R)

(D) sin 143°: 2nd quadrant (positive). sin(180° – 37°) = sin 37° = → (Q)

Final Answer: Option (4)

7) If
2A + B = 60° ...(1)
and .
3A – B = 30° ...(2)
From eqn (1) & eqn (2)
A = 18° and B = 24°

8)

9) We know,

So :
10) Given , we know from the standard angle values that θ = 30o (since ).

Now .

11) tan75 = tan (45 + 30)

12) = sin480
= sin (360 + 120)
= sin 120
= sin (90 + 30)
= cos30

13) From diagram angle

14)

15) Question Explanation: Finding the cot thetha value from a given trigonometric ratio
equation.
Concept: Trigonometric Ratios and Algebra (Cross-Multiplication).
Solution: The easiest way to solve this is to first find the value of tan(θ) . After finding tan(θ)
we use the reciprocal identity tan(θ) = 1/ cot (θ) to get the final answer.
Given equation , (sinθ + cosθ) / (sinθ - cosθ) = 11/5
Applying Cross-Multiplication
5(sin(θ)+ cos (θ) = 11(sin(θ) – cos (θ)
 5 sin (θ)+ 5 cos (θ) = 11sin (θ) – 11 cos (θ)
Separating cos and sin theta term
11 cos (θ) + 5 cos (θ) = 11sin (θ) - 5 sin (θ)
16 cos (θ) = 6 sin (θ)
16 / 6 = tan (θ)
Now we will use reciprocal property so
Cot (θ) = 1 / tan (θ)
Cot (θ) = 6 / 16 = 3/ 8
Cot (θ) = 3 / 8
Final answer = 3 / 8 , option (2)

16)

(zero)
sin 180o= 0 (zero)

17) Question Explanation: Finding 'p' using roots and an equation.

Concept: Relation between roots and coefficients of a quadratic equation.
Solution:
For a quadratic equation ax2 + bx + c = 0, the sum of roots and the product of
roots is c/a. Use the identity to find 'p'.
Calculation:
Given equation: .
Comparing with .
Sum of roots: .
Product of roots: .
Given: .
Using the identity:

Final Answer: Option (3)

18) Question Explanation: Identifying which option is NOT equivalent to .

Concept: Angle Transformation Identities

Solution: We check each option using the angle identities: .

. . Only is
equivalent to , not .
Calculation:

A. (Equivalent)

B. (Not Equivalent)
C. (Equivalent)
D. (Equivalent)
Final Answer:
Option: (2)

19) Question Explanation: Simplifying a trigonometric expression.

Concept: Trigonometric identities and periodicity.
Solution
The expression is .
1. Simplify Angles

A.

B.

C.

D.

2. Substitute and Calculate

Final Answer: Option (2)

20)

21)

22)

logab = x
 23)

24) Question Explanation : In this question we need to tell the maximum value of the given
function y = sin(x) cos(x)
Concept : Trigonometric Identity
Solution :
y = sin(x) cos(x)

(dividing and multiplying by 2)

∴ ymax =
Final Answer : Option (1)

25) Question Explanation:

Identifying possible values for trigonometric functions.
Concept:
Range of Trigonometric Functions.
Solution:
The sine of an angle is a ratio that always stays within a specific numerical range. While sine
cannot exceed 1, it can certainly be greater than or equal to -1.
Constraint: The range of .
Option 1: is impossible.
Option 2: is always true for any real angle .
Option 3: is mathematically undefined.
Final Answer:
Option (2)

26)

sin 233° = (90 × 2 + 53)

= sin 53 =

sin2 233 =

27) Question Explanation : We are supposed to convert the angle θ = in

degrees.
Concept : Radian to Degree conversion.

Formula: 1 radian = degrees

Solution:
 ∵ 1 radian = degrees

∴ radians = × degrees = 660 degrees

Final Answer : Option (3)

28) Explain the question : In this question, we have to find the arc length.
Concept : This question is based on arc length.

Solution :
Arc length = θ × radius (θ = angle in radian)

⇒ Arc length, cm
Final answer : 2

29) cos2A = 1 – 2sin2A

cos45° = 1 – 2sin2(22.5°)

2 sin222.5° =

30) Explanation: We have given a sin(A - B) indentity.

Formula: sin(A - B) = sin A cos B – cos A sin B
Calculation:
sin(45°+θ) cos(15°+ θ) – cos(45°+ θ) sin(15°+ θ)
= sin (45°+ θ – 15° – θ)

= sin (30°) =
Answer is option 3.

Chemistry

31)

total (P + e– + n) ⇒ 6 + 6 + 6 ⇒ 18 mol
⇒ 18 × 6.023 × 1023 ⇒ 1.084 × 1025

32) (i) 1 Mol of oxygen gas = 32 g

(ii) 1 Molecule of oxygen gas = g

(iii) 10–10 g of iron = 10–10 g
(iv) 1 g atom of nitrogen atom = 14 g
 33) 22.4 L water vapour has = 6.023 × 1023 molecule

1mL has =

34)

All the impurities of distilled water has been removed by distillation. Thus distilled water is a
compound not mixture.

35) NCERT Pg. # 23, Q. 1.13

(a) Micro (ii) 10–6

(b) Mega (iii) 106

(c) Giga (iv) 109

(d) Pico (i) 10–12

36)

Assertion is true, but reason is false because in homogenous mixture, components doesn't
react.

37)

Moles of D2O = =

∴ Molecules of D2O = NA
Then no. of neutron in D2O

= NA × 10 = 2.5 NA

38)

Question Explanation : We need to find incorrect unit conversion relation.

Concept : Inter conversion of units.

Solution :

Relation between erg and Joule –

1J = 107 erg

In option (3) :-

1 erg = 107 J (Incorrect)

Final Answer: option (3)

39)

Explain Question:
We are asked to identify which option is a compound.

Concept:
Mixture, Element, Compound

Solution:
Mixture = made of two or more substances mixed physically (e.g., salty water, air).
Element = pure substance made of one kind of atom (e.g., oxygen gas).
Compound = substance formed by chemical combination of elements in fixed proportion (e.g.,
acetic acid, CH3COOH).

1. Salty water → mixture

2. Air → mixture

3. Acetic acid → compound

4. Oxygen gas → element

Final Answer:
Option (3)

40)

Question Explanation:

Equal masses of O₂, H₂ and CH₄ are taken. We need their mole ratio.

Concept:

Moles = given mass / molar mass.

Solution:

Molar mass of O₂ = 32 g, Molar mass of H₂ = 2 g, Molar mass of CH₄ = 16 g

For equal masses (say 32 g each):

Moles of O₂ = 32 / 32 = 1

Moles of H₂ = 32 / 2 = 16

Moles of CH₄ = 32 / 16 = 2
So ratio = 1 : 16 : 2

Final Answer:
Option (1)

41) Question Explanation:

The question provides the formula of aspirin and the mass of an aspirin tablet and asks for the
number of oxygen atoms.

Concept:
Molar mass = ∑(atoms × atomic mass)

Moles =
Number of O atoms moles × NA x 4 (4 O atoms per molecule)

Solution:
Formula of aspirin = C9H8O4
Molar mass = (9 × 12) + (8 × 1) + (4 × 16) = 108 + 8 + 64 = 180g/mol
Mass of tablet = 360mg = 0.36g
Moles of aspirin = 0.36/180 = 0.002mol
Number of O atoms = 0.002 × 6.022 × 1023 × 4 = 4.81 × 1021 atoms

Final answer: Option (4). 4.81 × 1021

42)

Question is Asking About :-

To determine largest no. of molecules in following.

Concept :-
no. of molecules = n. NA

Solution/Explanation/Calculation :-
(A) w = 36 g H2O

no. of molecules NA = 2NA (largest)

(B) w = 28 g Co

no. of molecules
(C) w = 46 g C2H5 OH

no. of molecules NA = NA
(D) w = 54g N2O5

no. of molecules

Hence, option (1) is correct.

43)

°C = 50
K = °C + 273
K = 50 + 273 = 323 K

44) Question Explanation : The question asks to convert density from gram per cubic
centimetre to kilogram per cubic metre.
Concept : Unit conversion of density.
Solution :

5 g/cm3 = 5000 kg/m3

Final Answer : Option (3)

45) Question Explanation:

Question asks which give unit is not a basic (fundamental) SI unit.

Concept:
SI fundamental unit.

Solution:
7 fundamental units :– Mole, Kilogram, Candela, Meter, Second, Ampere, and Kelvin.
→ Gram is a unit of mass, gram not a fundamental unit, it is a sub–multiple of the fundamental
unit (Kilogram).

Final Answer: Option (3)

46)

Question Explanation : We have to convert a given pressure in mm of Hg into atmospheric

pressure unit.

Concept : This question is based on Pressure unit conversion.

Solution :
∵ 760 mm Hg = 1 atm

1 mm Hg = atm

3800 mm Hg = × 3800 = 5 atm.

3800 mm Hg = 5 atm.

Final Answer: option (2)

47)

Volume (P) → m3 (b)

Density (Q) → kg/m3 (a)
Temperature (R) → kelvin (d)
Luminous intensity (S) → candela (c)

48) Question Explanation:

The question asks to convert nanometers to meters.

Concept: Unit conversion

Solution:
1 nm = 10–9 m .
We are given 3 × 1017 nm and asked to convert it to meters.

3 × 1017 nm × = 3 × 108 m
Final answer: Option (1)

49)

nano (10–9) < milli (10–3) < deci (10–1) < kilo (103)

50) Number of molecules = mole × NA

In CaCl2 number of Cl– ion = 2 × 2 × NA = 4NA

number of Ca2+ ion = 1 × 2 × NA = 2NA

51) Number of moles of sucrose

=
Number of moles of hydrogen atom = 0.075 × 22
Number of atoms of hydrogen = 0.075 × 22 × 6.023 × 1023
= 9.9 × 1023

52)

Number of atoms = n × NA × atomicity

Number of atoms of O2 =

Number of atoms of O3 =
Same number of atoms in 1 g O2 & O3 but different number of molecules.
Statement-I is incorrect Statement-II is incorrect.

53) (NH4)3PO4 One molecule contains 12 hydrogen atom with 4 oxygen atoms.
54)

Explain the question : We need to match the items in column-I with their correct values in
column-II.
Concept : This question is based on mole concept, atomic mass and avogadro's number.
Solution :-
Given:
(A) Amount in gram in 20 mol H2SO4
molar mass of H2SO4 = 98g/mol
Mass = 20 × 98 = 1960 g ⇒ (S)
(B) Number of moles of H2O in 540 g
Molar mass of H2O = 18 g/mol

n= mol ⇒ (R)
(C) Number of atoms in 10–10 g Hz
Mass of 1 H atom = 1g/mol N_A = 1/6.022 × 1023g ≈ 1.66 × 10–24 g

Number of atoms = ≈ 6.02 × 1013 ⇒ (Q)

(D) Number of amu in 20 g
Number of amu = 20 × NA = 20 × 6.022 × 1023 ⇒ (P)
Final answer :- (1)

55) Atomic mass of element x

Number of moles of x

56)

96500 Coulombs

Q = 1.6 × 10-9 C × 6.02 × 1023

= 96500 (approx.)
= 1 Faraday

57)

(1) One gram atom of Iron = 56 g

(2) 5 mole of N2 = 5 × 28 = 140 g
(3) 1024 carbon atom = 1024 × 12 × 1.66 × 10-24 g = 20 g
(4) 44.8 L He at STP = 2 × 4 g = 8 g

58) 1 mol (NH4)2 Cr2O7 ⇒ 19 NA atoms

2.5 mol (NH4)2 Cr2O7 ⇒ 19 × 2.5 × NA atoms

59) 16 g of oxygen gas,

 & 32 g of SO2 also contains =
both will contain same number of molecules.

60) (a) One-twelfth of the mass of one carbon-12 atom is amu → correct
(b) 1 mol of water molecules = water molecules → correct
(c) 12-g of C-12 is 1amu → incorrect
(d) Mass of 1amu is 1.67 × 1027 kg. → incorrect

Mathematics

61) 32n + 22n is always divisible by 32 + 22 if n is odd.

62) x2 – y2 = 11 × 13
(x – y) (x + y) = 11 × 13
x + y = 13
x – y = 11
on solving x = 12 and y = 1
2x + 3y = 27

63) x + iy = ×

x + iy =

x + iy =

x+y=

64) (i10 + 1) (i9 + 1) (i8 + 1) ..... (i + 1)

i10 = i2 = – 1
(–1 + 1) (i + 1) (1 + 1) ......... (i + 1) = 0

65) x + y = a, x 2 + y2 = b
(x + y)2 = a2
b + 2xy = a2

xy = ... (i)
x + y = (x + y) (x2 + y2 – xy)
3 3

x3 + y3 =

x3 + y3 =
66) x – iy =
(x – iy) (x + iy) = 1
x2 + y2 = 1

67)
x+y+z+2 = 25
x + y + z = 25 – 16 = 9

68) a + b + c = 25 ...(i)

...(ii)
multiply (i) & (ii)

3+ = 650

69) 34n – 43n, for n ∈ I+ divisible by

34 – 43 = 17.

70) z =

z=

Re (z) =

71) = =

× =

z=

conjugate =

72) 22 + 42 + 62 + .............+ 202

= 22[12 + 22 + ..............+ 102]
= 4 × 385 = 1540

73)

⇒
74) a + ib =
(a2 – b2) + i (2ab) = 5 + 12i
a2 – b2 = 5 .... (i)
2ab = 12 .... (ii)
2 2
a + b = 13 .... (iii)
Add (i) and (iii)
2a2 = 18
a2 = 9 ⇒ a = ± 3
on solving b2 = 4 ⇒ b = ± 2
∴ = ±(3 + 2i)

75) For x = 4, 9, 16, x + ends in 0, 2, and 6.

76)
(i + i2) + (i2 + i3) + (i3 + i4) + .......... +(i13 + i14)
(i + i2 + ...........i14) + (i2 + i3 + ............i13)
(i – 1) + (0) = i – 1

77) –

–
– =1

78) 4a2 – 12a + 9 + 9b2 + 12b + 4 = 0

(2a – 3)2 + (3b + 2)2 = 0
2a – 3 = 0 and 3b + 2 = 0

a= and b =

a+b=

79) P(4) = Q(4)

64a + 45 = 108 + a
63a = 63
a=1

∴ = =2

80) a2 + b2 + c2 – ab –bc – ca =
a2 + b2 + c2 – ab – bc – ca = ≥ 0
non negative
81)

∴ x2 + = 7 and x3 + = 18

= 126

x5 + + = 126

x5 + = 123

82) = = 5050 × 450 = 20050

83) =n+1+
This should be natural number if 12/n is an integer. For n = 1, 2, 3, 4, 6, 12 is will be natural

so total 6 values n, is natural n.

84) 1 + x + 3 + y + 6 = x + y + 10 → divisible by 9 also

x + y = 8 or 17 ... (i)
y–x=6 ... (ii)
on solving y = 7 and x = 1

∴ =7

85)

86) 3a = 9b = 27c
3a = 32b = 33c
⇒ a = 2b = 3c ... (i)
abc = 288

= 288
a = 12, b = 6, c = 4
87) = = =

88) z = 1 + i
z2 = 2i

Multiplicative inverse of 2i of

89) (x – 1)2 =
x2 – 2x + 1 = – 3
x2 – 2x + 4 = 0
x(x2 – 2x + 4) + x2 – 2x + 10
x(0) + (–4) + 10 = 6

90) k must be 62