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Solution

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26-04-2026

1001CJA101016260002 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) Let P(x) be a polynomial of degree 2 with leading coefficient 1. If P(1) = 2, P(2) = 4, then find P(3)

(A) 4
(B) 6
(C) 8
(D) 3

2) Which one of the following can best represent the graph of quadratic polynomial y = ax2 + bx + c,
where a < 0, c > 0, b < 0

(A)

(B)

(C)
(D)

3) The sum of all distinct real roots of the equation (x – 1) (x – 3) (x – 5) (x – 7) = 9 is

(A) 4
(B) 8
(C) 16
(D) 12

4) If α,β are the roots of quadratic equation ax2 + bx + c = 0, then non zero root of the equation a(x –
α) (x – β) – c = 0 is (b ≠ 0)

(A)

(B)

(C)

(D)

5) If the roots of the equation bx2 + cx + a = 0 are and , then the value of (a + b + c)2 is
Where a,b,c are non-zero real numbers

(A) 2c2 – ab
(B) c2 – 2a
(C) c2 – 4ab
(D) 4c2 – 2ab

6) If logα8 = γ, logβα = –1 and log1/4β = –1 then is equal to -

(A)
(B) 5
(C) 25
(D) 625

SECTION-I (ii)
1) If α, β are roots of x2 + 3x + 1 = 0, then

(A) (7 – α) (7 – β) = 0
(B) (2 – α) (2 – β) = 11

(C)

(D)

2) Let P is a natural number and Q is positive irrational number such that , if


Amax and Amin represents maximum and minimum value of A respectively, then

(A) Pmax = 12
(B) Pmin = 1
(C)
(D)

3) If S is the set of all real numbers 'x' such that , then S contains

(A) (6,∞)

(B)

(C)

(D) (–2, –1)

2
4) If x – 3x + 1 = 0, then the value of is/are

(A) 2
(B)
(C)
(D)

5) Integral value(s) of k for which quadratic equation (k2 + 1)x2 – (4k)x + 2 = 0 always have exactly
one root in the interval (0,1), is/are

(A) 1
(B) 2
(C) 3
(D) 4

6) Let (a – 2)x2 + (b – 3)x + (c – 4) = 0 has three distinct real roots, then

(A) a + b + c = 9
(B) a2 + b2 – c = 9
(C) a + b + 2c = 13

(D)

SECTION-II

1)

If α and β are roots of the equation x2 – 3x + 1 = 0 and an = αn + βn – 1, then the value of is

2) If , then the value of 2 logab

3) Number of values of x, satisfying the equation ||| x – 2| + 6|–2| = 3 is

4) If α,β,γ are roots of cubic x3 – x – 2 = 0, then equation having roots α + β, β + γ, γ + α is x3 + ax +


b = 0, then find b – a ?

5) In a survey it was fond that 21 persons liked product A, 26 liked B & 29 liked C. If 4 liked A & B,
12 liked C & A, 13 liked B & C and 8 liked all three then number of persons who like A and B but not
C.

6) The least value of 'n' such that (n – 2)x2 + 8x + n + 4 > 0 ∀ x ∈ R, where n ∈ N is

PART-2 : PHYSICS

SECTION-I (i)

1) Speed of a particle is given by where t is time. Dimensional formula of β is :-

(A) T–1
(B) T–2
(C) T
(D) T2

2) The value of will be :-

(A)
(B)

(C)

(D)

3) Two vectors and have equal magnitudes. If the magnitude of + is n times the

magnitude of – , then angle between and is :

(A)

(B)

(C)

(D)

4) A ball thrown vertically upwards with a speed of 20 m/s from the top of a tower returns to the
earth in 6 sec. Find the height of the tower ? (g = 10 m/s2)

(A) 40 m
(B) 60 m
(C) 80 m
(D) 100 m

5) The position x of a particle varies with time, (t) as x = at2 – bt3. The acceleration will be zero at
time t equal to :-

(A)

(B) Zero

(C)

(D)

6) A particle is moving with instantaneous velocity v = 3t2 + 6t + 4 m/s then the value of average
velocity from t = 0 to t = 1 sec is:

(A) 2 m/s
(B) 4 m/s
(C) 6 m/s
(D) 8 m/s
SECTION-I (ii)

1) A particle moves on x-axis according to equation x = t2 – 6t + 8, where x is position in metres and


time t in seconds.

(A) The particle crosses origin only once.


(B) The particle comes to rest at t = 2 s and t = 4 s.
(C) The magnitude of velocity is minimum at t = 3 s.
(D) Distance travelled in interval t = 0 to t = 4 s is 10 m.

2) Six particles P1,P2,P3,P4,P5 and P6 are moving along X–axis. Their coordinates in meters, as function
of time (in seconds) are given by :
x1 = 6 + 5t2; x2 = 6 – 5 t2; x3 = 6t + 5t3
x4 = 6t – 5t3; x5 = t – 2t2 + 2t;
3
x6 = t3 + 2t2 – 2t
Select correct alternative (s)–

(A) Particles P1 and P2 are speeding up for t > 0


(B) Distances travelled and magnitude of displacements are equal for P1 and P3 for t > 0.
(C) Particles P5 and P6 are speeding down for t > 0
(D) Particles P3 and P4 are speeding up for 0 ≤ t ≤ 0.5

3) A particle is projected vertically upwards with a velocity u from a point O . When it returns to the
point of projection:

(A) its average velocity is zero


(B) its displacement is zero
(C) its average speed is u/2
(D) its average speed is u

4) Three students are leaning over the edge of a cliff. Each of them release a ball in a different way:
ball A is dropped from rest; ball B is thrown downward with an initial speed of 10 m/s; ball C is
thrown upward with an initial speed of 10 m/s. All three balls eventually strike the ground at the
base of the cliff. Which of the four choices below correctly compare(s) the speeds with which each of
the balls strike the ground ?

(A) Speed of ball A = speed of ball B


(B) Speed of ball B = speed of ball C
(C) Speed of ball A < speed of ball B
(D) Speed of ball A > speed of ball C

5) The vector is rotated through an angle and doubled in magnitude, then it becomes
. The value of x are

(A)
(B)

(C)

(D) 2

6) Three forces of magnitude 3F, 2F and F act on a body as shown in the figure. Mark the incorrect

statement(s).

The resultant force acting on the body is


(A)

The resultant force acting on the body is


(B)

If the direction of force F is reversed then the magnitude of resultant force will remain
(C)
unchanged
(D) If the direction of force F is reversed, then the magnitude of resultant force will increase

SECTION-II

1)

A particle moving with uniform acceleration along a straight line passes three successive points A, B
& C where the distances AB : BC is 3 : 5 & the time taken from A to B is 40 sec. If the velocities at A
& C are 5 m/s & 15 m/s respectively. Total distance from A to C is K × 102 m. Value of K is.

2) A point is moving along x-axis such that its speed is inversely proportional to its x cordinate. At x
= 5, its speed is 2 m/s. Find speed of point (in m/s) when its x co-ordiante is 20m.

3) If and angle between and is 90°, then find the value of

4) If radius of circle is increasing at rate of 2 cm/s, then rate of change of area is when
radius is 2cm. Find n.
5) x and y components of a vector are 4 and 5 respectively. The x and y components of are 7
and 9 respectively. Find length of .

6) The displacement of a particle in straight line is given as function of times as


,s is in m and t is in sec. The particle momentarily comes to rest n number of times. Find the value of
n.

PART-3 : CHEMISTRY

SECTION-I (i)

1) Which of the following match is INCORRECT :

(A) Na > Mg ⇒ 3rd ionisation energy


(B) N > O ⇒ 1st ionisation energy
(C) H < He ⇒ 1st ionisation energy
(D) Ne < Li ⇒ 2nd ionisation energy

2) A(g) → A+(aq) : ΔH = +X

If IE1 of A(g) is Y , then hydration energy of A+ ion is :

(Y – X)
(A)

(B)
(X – Y)
(X + Y)
(C)

X
(D)

3) The shielding nature of d-electron is ______ when principal quantum number is same

(A) More than s-electrons


(B) More than p-electrons
(C) Less than s-electrons
(D) Same as ƒ-electrons

4) Which of the following molecule is hypovalent :-


(A) CH4
(B) H2O
(C) BCl3
(D) PCl5

5) Which of the following process requires the maximum energy input?

(A) O−(g) + e−→ O2−(g)


(B) S−(g) + e−→ S2−(g)
(C) N(g) + e− → N−(g)
− −
(D) P(g) + e → P (g)

6) First, Second, third and fourth IP values are 10 ev, 15 ev, 20 ev and 200 ev. Element can be

(A) Be
(B) B
(C) F
(D) Na

SECTION-I (ii)

1)

Which of the following order(s) is/are CORRECT?

(A) H2O < H2S < H2Se (Acidic)


(B) Li < Be < B < C (IE1)
(C) Al2O3 < MgO < Na2O < K2O (Basic)
(D) Li+ < Na+ < K+ < Rb+ (Ionic radius)

2) Select the CORRECT combination(s) of given order and their reason :-

(A) Size of Al > Size of Ga [Reason : Lanthanoid contraction]


(B) Size of Mn+2 < Size of Mn+7 [Reason : Lesser nuclear charge]
(C) Size of H– > Size of H [Reason : Greater electronic repulsion]
(D) [IE]Tl > [IE]Ga [Reason : d-contraction]

3) The number of d-electron in Fe2+ (Z = 26) is equal to

(A) p-electrons is Ne (Z = 10)


(B) s-electrons in Mg (Z = 12)
(C) d-electrons in Fe (Z = 26)
(D) p-electrons in Cl (Z = 17)

4) Two elements have same set of principal quantum number and azimuthal quantum number for
their last electron. Then select the correct statement -

(A) both elements belong to same period


(B) both must have same value of magnetic quantum number also
(C) both must belong to same block
(D) last electron of both is present in same subshell

5) Select the CORRECT order(s) according to the stated property.

(A) < < < < : Ionic mobility


(B) > > > > : Hydration energy
(C) NaF < MgO < AℓN : Lattice energy
(D) Mn+2 > Fe+3 > Cr+3 (number of unpaired e¯)

6) Select CORRECT order of acidic strength -

(A) N2O5 > CO2


(B) SO3 > SO2
(C) N2O4 > N2O5
(D) SO2 > CO2

SECTION-II

1) Total number of elements which have less I.E1 than N.


Be, B, C, F, P, He

2) Number of elements having positive ΔHe.g. in the following set of elements are -
Li, Be, B , C, N, O, Ne, Mg

3) Find the total number of electrons in Cl have Zeff less than 10, when σ is calculated by slater's
rule.

4) For Selenium (Z = 34) how many electrons are present with magnetic quantum number = 2 ?

5) Bond length of A - A bond is 124 pm and bond length of B-B bond in 174 pm. The bond length (in
pm) of A-B bond in AB molecule if percent ionic character of A-B bond is 19.5% is ______.

6) The value of n + ℓ for the subshell which is filled at last in 5th period.
ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. C A D B C D

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. B,C,D A,B,C B,C B,D B,C A,B,C

SECTION-II

Q. 13 14 15 16 17 18
A. 8.00 3.00 0.00 3.00 6.00 5.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A A D B A D

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. C,D A,B A,B,C B,C A,D B,C,D

SECTION-II

Q. 31 32 33 34 35 36
A. 8.00 0.50 3.00 8.00 5.00 2.00

PART-3 : CHEMISTRY

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A B C C A B

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. A,C,D C A,B,C A,C,D A,B,C A,B,D
SECTION-II

Q. 49 50 51 52 53 54
A. 4.00 4.00 7.00 2.00 140.00 6.00
SOLUTIONS

PART-1 : MATHEMATICS

1) Let g(x) = P(x) – 2x


⇒ P(x) – 2x = (x – 1) (x – 2)
P(x) = 2x + (x – 1) (x – 2)
⇒ P(3) = 6 + (2) (1) = 8

2)

3) (x2 – 8x + 7) (x2 – 8x + 15) = 9


put x2 – 8x = y ∴ (y + 7) (y + 15) = 9
y2 + 22y + 96 = 0
(y + 16) (y + 6) = 0
(x2 – 8x + 16) (x2 – 8x + 6) = 0
x1 = 4, x2 + x3 = 8

4) ax2 + bx + c = a(x – α) (x – β)
⇒ ax2 + bx = a(x – α) (x – β) – c

5) Product of the roots =

∴ and a – 1 =

∴ one root is
This root satisfies bx2 + cx + a = 0

(a + b)2 + 2c(a + b) + 4ab = 0


a2 + b2 + c2 + 2ab + 2bc + 2ca = c2 – 4ab
(a + b + c)2 = c2 – 4ab

6) log1/4β = –1 ⇒β=4

logβα = –1 ⇒
γ = logα8 = log1/48 =

Now +1=4+1=5

β2 + 4γ2 = 16 + 4 = 25

∴ = = 625

7) x2 + 3x + 1 = (x – α) (x – β)
Put x = 2 ⇒ 11 = (2 – α) (2 – β)
α2 + 3α + 1 = 0, β2 + 3β + 1 = 0
α2 = –(3α + 1), β2 = –(3β + 1)

8) P + Q =

Pmax + Qmin = 12 +
Pmax = 12, Qmin =

Pmin + Qmax = 1 +
Pmin = 1 Qmax =

9)

(3|x| – 2) (|x| – 1) < 0

Hence < x < 1 or –1 < x <

10) x2 – 3x + 1 = 0
11)
f(0).f(1) < 0
⇒ 2.[k2 + 1 – 4k + 2] < 0
⇒ k2 – 4k + 3 < 0
⇒ k ∈ (1, 3)
Now check
(I) if k = 1 then quadratic
2x2 – 4x + 2 = 0
⇒ (x – 1)2 = 0

reject
(II) if k = 3 then quadratic
5x2 – 6x + 1 = 0
⇒ (5x – 1) (x – 1) = 0

accept


integers = 2, 3

12) a = 2, b = 3, c = 4 now check options

13) α + β = 3, αβ = 1
∴ α2 + β2 = 7 ∴ a1 = 2, a2 = 6
Also αn – 3αn – 1 + αn – 2 = 0
And βn – 3βn – 1 + βn – 2 = 0
∴ (αn + βn) – 3(αn – 1 + βn – 1) + (αn – 2 + βn – 2) = 0
∴ (αn + βn – 1) – 3(αn – 1 + βn – 1 – 1) + (αn – 2 + βn – 2 – 1) = 1
∴ an – 3an – 1 + an – 2 = 1
∴ an = 1 + 3an – 1 – an – 2
∴ a3 = 17, a4 = 46, a5 = 122


14)

a=2

2logab = 2log2 =3

15) |||x – 2| + 6| – 2| = 3
⇒ ||x – 2| + 6| = 5
⇒ |x – 2| + 6 = 5 or –5
⇒ |x – 2| = –1 or –11
(reject)
No. of solution = zero

16) α + β + γ = 0
⇒ α + β = –γ, β + γ = –α , γ + α = –β
Use transformation
y = –α
α = –y put in given equation
–y3 + y – 2 = 0
⇒ y3 – y + 2 = 0
a = –1 , b = 2
b–a=3

17)

18) (n – 2)x2 + 8x + n + 4 > 0 ∀ x ∈ R


⇒ 64 – 4(n – 2)(n + 4) < 0 ⇒ 16 – (n2 – 2n – 8) < 0
⇒ n2 + 2n – 24 < 0
⇒ (n + 6)(n – 4) > 0 ⇒ n > 4 as n ∈ N ⇒ n ≥ 5.

PART-2 : PHYSICS

19) Power of any nuber should be dimensionless and as so


0 0 0
βt = M L T
0 0
β = M L T–1
20)

Correct Answer is (A)

21) …(i)

P2 + Q2 + 2PQcosθ = n2(P2 + Q2 – 2PQcosθ)


Using (i) in above equation

22)

Initial velocity: u = + 20 m/s (taken as positive since it is the initial direction)


Total time of flight : t = 6 sec
Acceleration due to gravity : g = 10 m/s2 (a = −10 m/s2)
Total displacement : s = − H (where H is the height of the tower)

–H = (20)(6) + (–10) (6)2


–H = 120 – 5(36)
–H = 120 – 180
–H = –60m
H = 60m

23) x = at2 – bt3


v = 2at – 3bt2

a = 2a – 6bt = 0 ⇒

24)
vavg = = 1 + 3 + 4 = 8 m/s.

25) x = t2 – 6 t + 8 ⇒ v = 2t – 6 ⇒ a =2
(A) x = 0 ⇒ t = 2s and 4s (not correct)
(B) v = 0 ⇒ t = 3s (not correct)
(C) |v| = 0 ⇒ t = 3s (correct)

(D)
x0 = 8 , x3 = –1 (when changes direction)
x4 = 0 ⇒ distance = 10 m (correct)

26) For P1 : = 10t,


For P2 : = –10t, = –10
2
For P3 : = 6 +15t , =30t
2
For P4 : = 6 –15t , = –30t
2
For P5 : = 3t – 4t + 2, = 6t – 4
2
For P6 : = 3t + 4t –2, = 6t + 4

27) In complete trip, displacement = 0 ⇒ Average velocity = 0

Average speed = =

28) v depend on u

29)

Correct Answer is (A,D)

30)

31)

Correct Answer is 8

32)

Correct Answer is 0.50


33)
If angle between is π/2.

34)

Correct Answer is 8

35)

Correct Answer is 5

36)

Since the particle comes to rest, Therefore,


t2 – 3t + 2 = 0
(t – 1) (t – 2) =
T = 1s and 2s
Hence, the particle comes to rest twice.
∴n=2

PART-3 : CHEMISTRY

37)

Explain the question: Identify incorrect ionization trend.

Concept: Configuration and IE trends.

Solution:
The third ionization energy (IE3) is the energy required to remove an electron from a dipositive
cation (M2+).
Comparing the electronic configurations: Na2+ is [1s22s22p5] (isoelectronic with Fluorine),
while Mg2+ is [1s22s22p6] (stable noble gas configuration isoelectronic with Neon).
Removing an electron from a completely filled, highly stable noble gas subshell in
Mg2+ requires significantly more energy than from the partially filled subshell in Na2+; thus,
the correct order is Mg > Na.
This makes Statement 1 the incorrect match.
Regarding the other options: Pd(4d10) has a higher IE1 than Ag(4d105s1) because removing a
4d electron is harder than a 5s electron; He is higher than H due to noble gas stability and
higher Z; and IE2(Li)(1s2 → 1s1) is much higher than IE2(Ne)(2p5 → 2p4) because the 1s electrons
are much closer to the nucleus.

Final Answer: Option (1)

38)

The correct answer is option (B)

39) Explain Question : We have to compare shielding/ constant (σ) of given electron.
Concept : This question is based on shielding/ constant (σ).
Solution :
σ order : se– > p'e > d'e > f'e
Reason: left to right orbitals become more diffused.

Final answer : Option (3)

40)

Question Explanation: Question is asking about to choose hypovalent.


Concept: This question is based on octet rule.
Solution:

The correct option is (3).

41)

Concepts : Comparison of 2nd EA vs. 1st EA of stable/half-filled configurations.

Solution:

A. O− and S− involve 2nd EA, which is always endothermic. Between them, O− is smaller and
thus has higher repulsion.

B. N has a 2p3 (half-filled) configuration. Its 1st EA is slightly endothermic but much less
than the 2nd EA of Oxygen.

C. Therefore, O−→O2− requires the most energy.

Correct Answer:option 1

42) It has three valence electrons.

43)

The correct answer is option (A),(C),(D)

44)

The correct answer is option (C)

45)

The correct answer is option (A),(B),(C)

46)

The correct answer is option (A),(C),(D)

47) < < < < (Radius)


+2 +3 +3
Mn = Fe > Cr (number of unpaired e¯)

48)

The correct answer is option (A),(B),(D)

49)

Question Explanation:
Count how many elements from the given list have a first ionization energy (I.E1) lower than
that of nitrogen (N).

Concept: This question is based on Periodic Trends, First Ionization Energy.

Solution:
First ionization energy (I.E1) is the energy required to remove the outermost electron from an
atom.
Nitrogen has a high I.E1 because it has a stable half-filled 2p3 configuration.

Now compare each element with nitrogen:


A. Be → larger size and paired electrons → I.E1 < N

B. B → electron removed from 2p orbital → I.E1 < N

C. C → less stable than half-filled N → I.E1 < N

D. P → larger atom than N → I.E1 < N

E. F → very small size, high nuclear charge → I.E1 > N

F. He → noble gas, extremely stable → I.E1 > N

So, 4 elements (Be, B, C, P) have lower first ionization energy than nitrogen.

Final Answer: 4.00

50) Explain Question:


Number of elements having position eletron give enthalpy.

Concept:
Periodic trends in Electron affinity.

Solution:
Be, N, Ne, Mg → ΔHeg = (+) ve

Final Answer: 4

51) Question Explanation: Count electrons in Chlorine experiencing low effective nuclear
charge.
Concept: Slater's Rule for
Solution: Chlorine (Z=17) has the configuration .
We calculate for each subshell using .

A. For 1s:
B. For
C. For

Calculation: Only the 7 electrons in the n = 3 shell less than 10.


Final Answer: 7.00

52)

53) Question Explanation: Calculating bond length of a heteronuclear diatomic molecule.


Concept: Schomaker and Stevenson Equation.
Solution: The bond length of a heteronuclear molecule AB depends on the covalent radii of
A and B and their electronegativity difference. First, we find the electronegativity difference
using the given percent ionic character, then apply the bond length formula.

Calculation:

1. Covalent Radii:
2. Electronegativity Difference: Using Hannay-Smith Equation: 19.5
Solving gives
3. Bond Length

Final Answer: 140 pm

54)

The correct answer is 6.00

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