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Solution

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sachinaanand14
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© All Rights Reserved
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Available Formats
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01-06-2026

6250ENP1MAJ1MAINS0106 JM

PHYSICS

SECTION - A

1) In a certain region of space, the potential is given by : V = k[2x2 – y2 + z2]. Then electric field at
the point (1, 1, 1) has magnitude (All parameters are in SI unit)

(A)
(B)
(C)
(D)

2) Find the electric field at point P (as shown in figure) on the perpendicular bisector of a uniformly
charged thin wire of length L carrying a charge Q. The distance of the point P from the centre of the

rod is .

(A)

(B)

(C)

(D)

3) The electric flux from a cube of edge l is . What will be its value if edge of cube is made 2l and
charge enclosed is halved

(A)

(B)
(C)
(D)

4) Two concentric conducting thin spherical shells of radii a and b (b > a) are given charges Q and
–2Q respectively. The electric field along a line passing through centre as a function of distance (r)
from centre is given by :

(A)

(B)

(C)

(D)

5) Let there be a spherically symmetric charge distribution with charge density varying as ρ(r) = ρ0

upto r = R, and ρ(r) = 0 for r > R, where r is the distance from the origin. The electric field
at a distance r (r < R) from the origin is given by :

(A)

(B)

(C)

(D)
6) The figure shows a hollow hemisphere of radius R in which two charges 3q and 5q are placed
symmetrically about the centre O on the planar surface. The electric flux over the curved surface is :

(A)

(B)

(C)

(D)

7) The three charges shown in the figure lie along a straight line. The energy needed to exchange
the position of the central + ve charge with one of the negative charges is

(A)

(B)

(C)

(D)

8) The ratio of charge on left surface of plate A to the charge on the right surface of plate B is :-

(A) 0

(B)
(C)

(D)

9) A very large sphere having charge Q uniformly distributed on the surface is compressed uniformly
till its radius reduces to R. The work done by the electric forces in this process is:

(A)

(B)

(C) ∞
(D) 0

10) In the figure shown below, there are two dipoles P1 and P2 placed in two different types
of orientations. In orientation-1 dipoles P1 and P2 are placed along same axis at a distance x apart
and F1 be the magnitude of interaction force between them. In orientation-2, the two dipoles are
placed parallel to each other at a distance x apart and F1 be the magnitude of interaction force

between them. The value of F1 and F2 respectively are

(A)

(B)

(C)

(D)

11) A non – conducting semicircular disc (as shown in figure) has a surface charge density s. The
ratio of electric field to electric potential at the centre of the disc will be :
(A)

(B)

(C)

(D)

12) The plotting for equipotential lines are shown in the figure.

(a) Find V = f(x, y).

(A)

(B)

(C)

(D) V = 5x

13) What is the length of the image of the rod in mirror, according to the observer in air? (

refractive index of the liquid is μ)

(A) μL + L
L+
(B)
Lμ +
(C)

(D) None of these

14) A ray of light is incident at the glass–water interface at an angle i, it emerges finally parallel to

the surface of water, then the value of µg would be :–

(A) (4/3) sin i


(B) 1/sin i
(C) 4/3
(D) 1

15) A biconvex lens is formed with two thin plano-convex lenses as shown in the figure, Refractive
index n of the first lens is 1.5 and that of the second lens is 1.2. Both the curved surfaces are of the
same radius of curvature R = 14 cm. For this biconvex lens, for an object distance of 40 cm, the

image distance will be

(A) –280.0 cm
(B) 40.0 cm
(C) 21.5 cm
(D) 13.3 cm

16) A small bubble lie inside a glass sphere of radius 12 cm and R.I at a distance of 4 cm from the
center. Now it is observed from the left side of bubble O in air. What is distance of image of O from

the center of sphere.


(A)

(B)

(C) 3 cm
(D) 9 cm

17) A hemispherical glass body of radius 10 cm and refractive index 1.5 is silvered on its curved
surface. A small air bubble is 6 cm below the flat surface inside it along the axis. The position of the

image of the air bubble made by the mirror is seen :

(A) 16 cm below flat surface


(B) 20 cm below flat surface
(C) 30 cm below flat surface
(D) 14 cm below flat surface

18) In the figure shown mirror and observer both are moving towards the object with velocities 5

m/sec and 4 m/sec. Velocity of image of O w.r.t. observer is

(A) 4 m/sec
(B) 1 m/sec
(C) 9 m/sec
(D) 14 m/sec

19) The curve of angle of incident versus angle of deviation shown has been plotted for prism. The

value of refractive index of the prism used is :

(A)
(B)

(C)

(D)
20) Find the minimum value of d so that final image coincide with object :

(A) 60 cm
(B) 20 cm
(C) 30 cm
(D) 50 cm

SECTION - B

1) The angle between the velocity vector of object and image is . Velocity are shown in the figure.

Then the value of α is.

2) 2Two thin conducting shells of radii R and 3R are shown in figure. The outer shell carries a
charge Q = – 6 μC and the inner shell is neutral. The inner shell is earthed with the help of switch S.

Find the charge attained by the inner shell (in μC).

3) A rod of mass m (uniformly distributed) and length ℓ is hinged about point O in a uniform vertical
electric field as shown. Linear charge density of rod varies with x as λ = λ0x. Electric field for which

rod remain horizontal is . Find value of n.

4) A compound microscope has a magnification of 30. Assuming that the final image is formed at the
least distance of distinct vision (25 cm). Find the magnification produced by the objective if focal
length of the eyepiece is 5.0 cm ?

5)

Three large thick conducting sheets are placed parallel to each other as shown, charge on plates
are 20 µC, –5 µC and – 15 µC and seperation between them is 1 cm and 2 cm respectively. Find the

ratio of electric field at B to that of electric field at A :-

CHEMISTRY

SECTION - A

1)

Select the correct order for the wavelength of absorption for the given complex:

3- 3- 3+ 3+
(A) [Cr(CN)6] = [CrCl6] = [Cr(NH3)6] = [Cr(H2O)6]
3- 3+ 3+ 3-
(B) [CrCl6] > [Cr(H2O)6] > [Cr(NH3)6] > [Cr(CN)6]
3- 3+ 3+ 3-
(C) [Cr(CN)6] > [Cr(NH3)6] > [Cr(H2O)6] > [CrCl6]
3+ 3- 3+ 3-
(D) [Cr(H2O)6] > [CrCl6] > [Cr(NH3)6] > [Cr(CN)6]

2)

According to the valence bond theory the hybridization of central metal atom is dsp2 for which one of
the following compounds?

(A) NiCl2.6H2O
(B) K2[Ni(CN)4]
(C) [Ni(CO)4]
(D) Na2[NiCl4]

3)

Which of the following compounds shows optical isomerism ?

+2
(A) [Cu(NH3)4]
–2
(B) [ZnCl4]
–3
(C) [Cr(C2O4)3]
–3
(D) [Co(CN)6]

4) A complex of molecular formula CrCl3. 6H2O has green colour 0.1 mole of the complex when
treated with excess of AgNO3 gave 28.7 g of white precipitate of AgCl (Molar mass = 143.5 g). The
formula of the complex would be

(A) [Cr(H2O)6]Cl3
(B) [CrCl(H2O)5]Cl2.H2O
(C) [CrCl2(H2O)4]Cl.2H2O
(D) [Cr(H2O)3Cl3]3H2O

5) The 'spin only' magnetic moment [in units of Bohr magneton] µB of Ni+2 in aqueous solution would
be :-

(A) 0
(B) 1.73
(C) 2.84
(D) 4.90

6) Which one of the following lanthanoids does not form MO2? [M is lanthanoid metal]

(A) Pr
(B) Dy
(C) Nd
(D) Yb

7) Which one of the following is a d-block element?

(A)
(B)
(C)
(D)

8) Potassium dichromate when heated with concentrated sulphuric acid and a soluble chloride,
gives brown-red vapours of:

(A) CrO3
(B) Cr2O3
(C) CrCl3
(D) CrO2Cl2

9) Which of the following statements is false :-


(A) has a Cr – O – Cr bond
(B) is tetrahedral in shape
(C) Na2Cr2O7 is a primary standard in volumetry
(D) K2Cr2O7 is less soluble than Na2Cr2O7

10) If solubility of any gas in the liquid at 1 bar pressure is 0.05 mol/lit. What will be its solubility at
3 bar pressure, keeping the temperature constant? (in mol/lit)

(A) 1.5 mol/lit


(B) 0.15 mol/lit
(C) 0.5 mol/lit
(D) 2.5 mol/lit

11) Total vapour pressure of mixture of 1 mole volatile component A ( = 200 mm Hg) and 3 mole
of volatile component B ( = 160 mm of Hg) is 180 mm of Hg. For such case

(A) There is positive deviation from Raoult's law.


(B) Force of attraction between A & B is stronger than between A and A or B and B.
(C) There is negative deviation from Raoult's law.
(D) Enthalpy of mixing of these two liquids A & B is negative.

12) 3.24 g of Hg(NO3)2 (molar mass = 324) dissolved in 1000 g of water constitutes a solution having
a freezing point of – 0.0558ºC while 21.68 g of HgCl2 (molar mass = 271) in 2000 g of water
constitutes a solution with a freezing point of – 0.0744ºC. The Kf for water is 1.86 K Kg × mol–1.
About the state of ionization of these two solids in water it can be inferred that :-

(A) Hg(NO3)2 and HgCl2 both are completely ionized


(B) Hg(NO3)2 is fully ionized but HgCl2 is fully unionized
(C) Hg(NO3)2 and HgCl2 both are completely unionized
(D) Hg(NO3)2 is fully unionized but HgCl2 is fully ionized

13) Addition of 4.0 g of a non-volatile solute to 54.0 g water results in a lowering of vapour pressure
by 1.0%. What is the molar mass of the non-volatile solute?

(A) 132
(B) 66
(C) 133.33
(D) 333

14) which of the following aqueous solution will have the highest boiling point?

(A) 34.2% (w/w) Sugar


(B) 18% (w/w) Glucose
(C) 6.00% (w/w) Urea
(D) All the same

15) Standard EMF of a galvanic cell involving 2e– transfer is found to be 0.591 V at 25°C. Calculate
equilibrium constant for cell reaction.

(A) 2010
(B) 1020
(C) 10200
(D) 20010

16) What is the standard reduction potential (E°) for Fe3⊕ → Fe? Given that :
Fe2⊕ (aq) + 2e⊝ → Fe(s) ;
Fe3⊕ (aq) + e⊝ → Fe2⊕(aq);

(A) +0.30 V
(B) +0.057 V
(C) –0.057 V
(D) –0.30 V

17) A cell is constituted as follows


Pt|H2 (1 atm) |HA1| |HA2| H2 (1 atm) | Pt
The pH of two acids solutions HA1 and HA2 are 5 and 3 respectively. The emf of the cell is -

(A) 0.059 V
(B) 0.0295 V
(C) 0.118 V
(D) – 0.118 V

18) If 0.50 L of a 0.60 M CuSO4 solution is electrolyzed for a period of 30.0 min using a current of
4.60 A. If inert electrodes are used, what is the final concentration of Cu2+ remaining in the solution?

(A) 0.342 M
(B) 0.544 M
(C) 0.389 M
(D) 0.514 M

19) The two aqueous solutions; A(AgNO3) and B(LiCl) were electrolysed using Pt. electrodes. The pH
of the resulting solutions will

(A) increase in A and decrease in B


(B) decrease in both
(C) increase in both
(D) decrease in A and increase in B.

20) Given are E° values for some half reactions


I2 + 2e– → 2I– ; E° = 0.54 V
MnO4– + 8H+ + 5e–→ Mn2+ + 4H2O ; E° = 1.52 V
Fe3+ + e– → Fe2+ ; E° = 0.77 V
Sn4+ + 2e– → Sn2+ ; E° = 0.1 V
The strongest reductant and oxidant respectively are :

2+ –
(A) Sn , MnO4
– 4+
(B) MnO4 , Sn
3+
(C) I2, Fe
2+
(D) I2, Sn

SECTION - B

1) What osmotic pressure would the 1.25 molal sucrose solution exhibit at 25°C? The density of this
solution is 1.34 g/mL.

2)

What is the sum of primary & secondary valency of 'M' in [M(en)2(C2O4)]NO2.

3) Which of the following ions are diamagnetic


Tb2⊕, Ce4⊕, Yb2⊕, Lu3⊕,Pr2⊕, Nd2⊕, Pm2⊕, Sm2⊕, Gd3⊕

4) I2(s) | I– (0.1M) half cell is connected to

H+(aq) | H2(1 atm) | Pt half cell and its half cell potential is found to be 0.7714 V. If ,
the pH of H+/H2 half cell will be :-
[Give answer as a closest integer]

5) The current of 9.65 A flowing for 10 min deposits 3.0 g of a metal. The equivalent weight of the
metal is

MATHS

SECTION - A

1) If , then |A2011 – 5A2010| is equal to

(A) 1
(B) –1
(C) 6
(D) –6
2) If A and B are square matrices of same order and AB = A, BA = B, then (A + I)5 is equal to (where
I is unit matrix)

(A) I + 5A
(B) I + 60A
(C) I + 16A
(D) I + 31A

3) Matrix Aλ = , λ ∈ N then the value of |A1| + |A2| + |A3| + ...... + |A300| is :-

(A) (299)2
(B) (300)2
(C) (150)2
(D) (301)2

4) If (x1 – x2)2 + (y1 – y2)2 = a2 ;


(x2 – x3)2 + (y2 – y3)2 = b2 ;
(x3 – x1)2 + (y3 – y1)2 = c2 and

k (a + b + c)(b + c – a)(c + a – b)(a + b – c)


then the value of k is :-

(A) 1
(B) 2
(C) 4

(D)

5) If P λ4+qλ3+rλ2+sλ+t = ; then P is equal to :-

(A) –2
(B) –3
(C) –4
(D) –5

6)

If the system of equation


x–ky+z=0; kx+3y–kz=0; 3x+y–z=0

have non trivial solution then all values of k will be:-


(A) {2, –3}
(B) R–{2,–3}
(C) R–{2}
(D) None of these

7) Let R = {(P, Q) | P and Q are at the same distance from the origin} be a relation, then
the equivalence class of (1, –1) is the set :

(A) S = {(x, y) | x2 + y2 = 2}
(B) S = {(x, y) | x2 + y2 = 1}
(C) S = {(x, y) | x2 + y2 = }
(D) None

8)

If R = {(x, y) : x, y ∈ Z, x2 +3y2 ≤ 8} is a relation on the set of integers Z, then the domain of R–1 is :

(A) {–1, 0, 1}
(B) {0, 1}
(C) {–2, –1, 0, 1, 2}
(D) {–2, –1, 1, 2}

9) If , then fof(x) is given as

(A) 1
(B) x
(C) 1+x
(D) none of these

10) If , then is

(A)

(B)

(C)

(D)

11) If f : [–4, 4] → R, where

f(x) = sinx + cosx +


(where [.] = G.I.F. ) is an even function then
(A) a ∈ (0, 257]
(B) a ∈ [257, ∞)
(C) a ∈ (257, ∞)
(D) a ∈ (0, 257)

12) If ; then

(A) 0
(B) 9
(C) 7
(D) 8

13) tan2 (sec–16) + cot2(cosec–14) is equal to

(A) 10
(B) 8
(C) 50
(D) 25

14) The domain of the function is

(A)

(B)

(C)

(D)

15) The solution of the equation is

(A)
(B)
(C)
(D)

16) The value of cot–1 - cot–1 is equal to


(A)
π–

(B)
π–
π+
(C)

π+
(D)

17) Considering the principal values of the inverse trigonometric functions,

, is equal to

(A)

(B)

(C)

(D)

18) The value of , is

(A)

(B)

(C) cot–12

(D)

19) The value of tan–11 + tan–12 + tan–13 is-

(A) 0
(B) 1
(C) π
(D) – π

20) If then f(x) is

(A)

(B)
(C)

(D)

SECTION - B

1)

Number of functions which has/have the same range?

(i) f(x) = (ii) f(x) =

(iii) f(x) = (iv) f(x) =

2) If the range of is {a,b,c} and (where [.] denotes greatest integer


function) then is equal to

3) Let R1 and R2 be relations on the set {1, 2, …, 50} such that is a prime and n ≥ 0
is an integer} and is a prime and n = 0 or 1. Then, the number of elements in R1 –
R2 is _____.

4) If A is a square matrix of order 3 such that |A| = 2, then | (adj A–1)–1 | is

5)

Let A be a matrix of order n × n such that |A|=2. If the determinant of the matrix Adj (2. Adj(2A-1)). is
284, then n is equal to _______________.
ANSWER KEYS

PHYSICS

SECTION - A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C A A C B C B B A C C B B B A B D A B

SECTION - B

Q. 21 22 23 24 25
A. 2 2 3 5 0

CHEMISTRY

SECTION - A

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B C B C D D D C B A B A A B C C D D A

SECTION - B

Q. 46 47 48 49 50
A. 29 9 3 3 50

MATHS

SECTION - A

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D B C C A A A B D C D C C C A B A C C

SECTION - B

Q. 71 72 73 74 75
A. 2 5 8 4 5
SOLUTIONS

PHYSICS

1)

at point (1,1,1)

2)

sinθ =

3)

Conceptual

4)

Conceptual

5) Total charge Q =

0
= 4πρ
6)

Conceptual

7)

Ui =

Uf =

Uf – Ui =

8)

9) (WAB)electric force = UA – UB = 0 – = [∴ UA = 0 as sphere is large]

10)

Conceptual

11)

Conceptual

12) (A) Since V varies linearly with x with a rate of we have


V = 5x + C;
where x = 0, V = 5 or C = 5
Then, V2 = 5x+ 5 .......(i)

Since,
.......(ii)

Hence .......(iii)
Adding Eqs. (i) and (iii),

13) Since Apparent depth =

Length of Image = L +

14) From snell's law at any interface μsinθ = constant. μg × sin i = 1 × sin90°.

15) Explain Question:


Finding the image distance for a composite biconvex lens using surface power.

Concept:
Equivalent Focal Length of a lens with different refractive indices.

Solution:
The lens acts as two plano-convex lenses joined together. The total power is the sum of the
powers of the two surfaces.
Calculation:
1. Net Power (P):

2. Focal Length (F): F = = 20 cm


3. Lens Formula: Using u = – 40 cm and F = 20 cm

4. Result: v = 40 cm

Final Answer: Option (2)


16)


so distance from centre

17) Explain question


Light frim the bubble goes through the glass, reflects from the silvered curved surface acting
as a convex mirror, and then emerges through the flat face.
We must find where the final image is seen by an observer in air.

Concept
Mirror formula for the silvered spherical surface and plane–refraction formula.

Solution

v = 20 cm
acts as object for plane surface

20 cm below plane surface

Final Answer: Option (2)

18)

Conceptual

19)

Conceptual

20) For lens,


u = –15 cm
f = +20 cm

v = –60 cm
This image position will act as object for mirror. To coincide final image with object, the light
rays must retrace their path for which object for mirror must be at its center of curvature
hence,
|v| + d = R
60 + d = 80
d = 20 cm

21)

taking dot product cosθ is zero

22) Potential V of inner shell is zero.

23) For rotational equilibrium torque of electric field


should be equal and opposite to torque of weight
Torque on small element dq.
dτ = Edq x

τ=
τ=

& Put τ =

24)

Conceptual

25)

CHEMISTRY

26)

Δ0 = CN- > NH3 > H2O >Cl-


Δ0 α 1/lambda.

27)
28)

29) CrCl3.6H2O + AgNO3 (excess) → AgCl


0.1mol 28.7g

No. of moles of AgCl = 0.2 mol


Hence it required 2 mole free Cl atom.

30) Ni+2 4s2 3d8

n = 2,

31) Yb is the only element that do not form MO2 type oxide

32)

Factual

33)

34) (1)
(2)
(3) Due to hygroscopic nature of Na2Cr2O7, it cannot be used as a primary standard in
volumetric analysis.
(4) Solubility order : K2Cr2O7 < Na2Cr2O7

35) p = KH × solubility (x)


⇒ 1 = KH × 0.05 ....(i)
⇒ 3 = KH × x ....(ii)


∴ x = 0.05 × 3 = 0.15 mol/litre

36) Question Explanation:


The question gives vapour pressures of pure components and the observed total vapour
pressure of their mixture. We must determine whether the solution shows positive or negative
deviation from Raoult’s law and related properties.

Concept:
Raoult’s Law, Deviation from Ideal Solution, Enthalpy of Mixing

Solution:
First, calculate mole fractions:
Total moles

According to Raoult's law:

But observed total vapour pressure = 180 mm Hg

Since:
Observed pressure (180) > Ideal pressure (170)

Therefore, the solution shows positive deviation from Raoult's law.

In positive deviation:
A–B intermolecular forces are weaker than A–A and B–B
Enthalpy of mixing is positive
Final Answer: Option(1).

37) For Hg(NO3)2


ΔTf = i × Kf × m

0.0558 = (1 + 2α) × 1.86 ×

1 + 2α = × 100

1 + 2α =
2α = 3 – 1

α = = 1 ⇒ 100%
For HgCl2

ΔTf = 1.86 ×

1 + 2α =

=
1 + 2α = 1
2α = 0
α=0
Hence Hg(NO3)2 is fully ionised but HgCl2 is unionized.

38) Conceptual

39) Conceptual

40) E°cell =

0.591 =
log10K = 20
K = 1020

41)

Fe2⊕ (aq)+ 2e⊖ → Fe (s)


Fe3⊕ (aq) + e⊖ → Fe2⊕ (aq)
Fe3⊕ (aq) + 3e⊖ → Fe (s)
42) Anode :

Cathode :
________________________________

________________________________

= 0.118 volt

43)

Equvalent of deposit

Cu+2 =

Moles of Cu+2 deposite =

Molarity of Cu+2 deposit =

Remain Molarity = 0.6 – 0.085 = 0.51

44)

A(AgNO3)
Anode :– OH– → O2
Cathode :- Ag+ → Ag

[OH–] ↓, pOH , PH↓ B(LiCl)


Anode :– Cl– → Cl2
Cathode :– H+ → H2
[H+] ↓, pH

45)

Question Explanation: Find the strongest reductant and the strongest oxidant from the given
standard reduction potentials.

Concept: This question is based on standard reduction potential (E°) and oxidizing-reducing
strength.

Solution:
Given half-reactions (all E° are reduction potentials):
I2 + 2e– → 2I– ; E° = 0.54 V
MnO4– + 8H+ + 5e–→ Mn2+ + 4H2O ; E° = 1.52 V
Fe3+ + e– → Fe2+ ; E° = 0.77 V
Sn4+ + 2e– → Sn2+ ; E° = 0.1 V

• Strongest oxidant → species with highest E° (most easily reduced) ⇒ MnO4– (E° = 1.52 V)
• Strongest reductant → species whose oxidation is easiest, i.e. whose corresponding reduction
E° is lowest ⇒ SN2+ (from SN4+/ SN2+, E° = 0.10 V )​​

Final Answer: Option (1)

46)

47)

Question Explanation:
Find the sum of primary valency and secondary valency of metal M in the complex
[M(en)2 (C2O4)]NO2.

Concept:

A. Primary valency = oxidation state of the metal ion.


B. Secondary valency = coordination number of the metal (total number of donor atoms directly
to the metal).
C. en (ethylenediamine) is a bidentate neutral ligand.
D. (oxalate) is a bidentate anionic ligand.

Solution:
The complex cation is [M(en)2 (C2O4)]+ since is the counter ion.
Oxidation state of M :
Let oxidation state =x
x + 2(0) + (–2) = + 1
x = +3
So, primary valency =3
Coordination number:

en : 2 ligands × 2 donor atoms = 4

: 1 ligand × 2 donor atoms = 2


Total coordination number = 6
So, secondary valency = 6
Sum of primary and secondary valency
3+6=9

Final Answer: 9

48)

Ion Configuration Unpaired Electron


2⊕
Tb 4f9 5
4⊕
Ce [Xe] 0
2⊕ 14
Yb 4f 0
3⊕ 14
Lu 4f 0
2⊕ 3
Pr 4f 3
2⊕ 3
Nd 4f 4
Pm2⊕ 4f5 5
2⊕ 6
Sm 4f 6
3⊕ 7
Gd 4f 7
4⊕ 2⊕ 3⊕
Ce , Yb , Lu are diamagnetic due to absence of unpaired electron

49) Pt | H2 (1 atm) / H+ (a0M) || I–(0.1M) | I2(s)


(C) I2(s) + 2e– → 2I–
(A) H2(g) → 2H+ + 2e–
H2(g) + I2(s) → 2H+ aq + 2I–

0
Ecell = 0.7714 = 0.533 – × log[10–2 × a 2]
0.7714 – 0.533 = –0.0591 × log[H+] × 0.1
= 0.0591 × (+1) + 0.0591 × pH
pH 3

50)

MATHS
51)

Conceptual

52) AB = A, BA = B A(BA) = A2
AB = A2 ⇒ A2 = A ⇒ A3 = A ⇒ A4 = A
⇒ A5 = A .....
(A + I)5 = 5C0A5 + 5C1A4I + 5C2A3I + 5C3A2I + 5C4AI + 5C5I
= I + 31A

53)

Conceptual

54) area of Δ =

= ∵s=

55) Method-Ι

Divided by λ4 nd take

Take P = ⇒

Method-II
Applying R1→R1–R2, R2→R2–R3

after expansion coefficient of λ4 is (–4)

56)

Conceptual

57)
Conceptual

58)

Conceptual

59)

Hence (B) is the correct answer.

60)

Conceptual

61) f(x) = f(–x)

⇒0≤
⇒ a > x4 + 1
⇒ a > 257
∴ aε (257, ∞)

62) sin–1x1 + sin–1x2 + ...... + sin–1x20 = 10π

∴ sin–1x1 = , ...... ; sin–1x20 =


x1 = 1 = x2 = ...... = x20

=8

63)

Conceptual

64)

Conceptual

65)
66)

67) Question Explanation:


Simplifying inverse trigonometric expression using substitution

Concept:
Inverse trigonometric substitution

Solution:

⇒ Let sin–1(x) = θ
⇒ x = sinθ, then

Final Answer: Option (2)

68)
69) tan–1(1) + tan–1(2) + tan–1(3) = π

70)
Replacing we get

From these equations we get

71)

Domain is R–{–1}; Range = R – {0}


Domain is x R; Range = (0, 1]
Domain is [0, ); Range = (0, 1]
Domain is (– , 3); Range = (0, )]

72)

73)

Question Explanation : We need to calculate the number of ordered pairs in the set
difference R1–R2 where R1 and R2 are relations on the set A={1,2,…,50} involving powers of
prime numbers.
Concept: Set Difference and counting elements in Relations.
Solution:
Let A={1,2,…,50}.
The relation R1–R2 consists of elements such that p is a prime, n ≥ 2, and pn ∈ A.
____
Evaluating possible pairs based on prime p :
For p = 2 :

(Note: )
⇒ Number of pairs = 4
For p = 3 :

(Note: )
⇒ Number of pairs = 2
For p = 5 :

⇒ Number of pairs = 1
For p=7 :

For prime p ≥ 11 :

Total number of elements

Final Answer : 8

74) ∴ | adj A–1| = |A–1|2 =

∴ | (adj A–1)–1| = =|A|2 = (2)2 = 4

75)

Now,

So, n = 5

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