Solution
Solution
6250ENP1MAJ1MAINS0106 JM
PHYSICS
SECTION - A
1) In a certain region of space, the potential is given by : V = k[2x2 – y2 + z2]. Then electric field at
the point (1, 1, 1) has magnitude (All parameters are in SI unit)
(A)
(B)
(C)
(D)
2) Find the electric field at point P (as shown in figure) on the perpendicular bisector of a uniformly
charged thin wire of length L carrying a charge Q. The distance of the point P from the centre of the
rod is .
(A)
(B)
(C)
(D)
3) The electric flux from a cube of edge l is . What will be its value if edge of cube is made 2l and
charge enclosed is halved
(A)
(B)
(C)
(D)
4) Two concentric conducting thin spherical shells of radii a and b (b > a) are given charges Q and
–2Q respectively. The electric field along a line passing through centre as a function of distance (r)
from centre is given by :
(A)
(B)
(C)
(D)
5) Let there be a spherically symmetric charge distribution with charge density varying as ρ(r) = ρ0
upto r = R, and ρ(r) = 0 for r > R, where r is the distance from the origin. The electric field
at a distance r (r < R) from the origin is given by :
(A)
(B)
(C)
(D)
6) The figure shows a hollow hemisphere of radius R in which two charges 3q and 5q are placed
symmetrically about the centre O on the planar surface. The electric flux over the curved surface is :
(A)
(B)
(C)
(D)
7) The three charges shown in the figure lie along a straight line. The energy needed to exchange
the position of the central + ve charge with one of the negative charges is
(A)
(B)
(C)
(D)
8) The ratio of charge on left surface of plate A to the charge on the right surface of plate B is :-
(A) 0
(B)
(C)
(D)
9) A very large sphere having charge Q uniformly distributed on the surface is compressed uniformly
till its radius reduces to R. The work done by the electric forces in this process is:
(A)
(B)
(C) ∞
(D) 0
10) In the figure shown below, there are two dipoles P1 and P2 placed in two different types
of orientations. In orientation-1 dipoles P1 and P2 are placed along same axis at a distance x apart
and F1 be the magnitude of interaction force between them. In orientation-2, the two dipoles are
placed parallel to each other at a distance x apart and F1 be the magnitude of interaction force
(A)
(B)
(C)
(D)
11) A non – conducting semicircular disc (as shown in figure) has a surface charge density s. The
ratio of electric field to electric potential at the centre of the disc will be :
(A)
(B)
(C)
(D)
12) The plotting for equipotential lines are shown in the figure.
(A)
(B)
(C)
(D) V = 5x
13) What is the length of the image of the rod in mirror, according to the observer in air? (
(A) μL + L
L+
(B)
Lμ +
(C)
14) A ray of light is incident at the glass–water interface at an angle i, it emerges finally parallel to
15) A biconvex lens is formed with two thin plano-convex lenses as shown in the figure, Refractive
index n of the first lens is 1.5 and that of the second lens is 1.2. Both the curved surfaces are of the
same radius of curvature R = 14 cm. For this biconvex lens, for an object distance of 40 cm, the
(A) –280.0 cm
(B) 40.0 cm
(C) 21.5 cm
(D) 13.3 cm
16) A small bubble lie inside a glass sphere of radius 12 cm and R.I at a distance of 4 cm from the
center. Now it is observed from the left side of bubble O in air. What is distance of image of O from
(B)
(C) 3 cm
(D) 9 cm
17) A hemispherical glass body of radius 10 cm and refractive index 1.5 is silvered on its curved
surface. A small air bubble is 6 cm below the flat surface inside it along the axis. The position of the
18) In the figure shown mirror and observer both are moving towards the object with velocities 5
(A) 4 m/sec
(B) 1 m/sec
(C) 9 m/sec
(D) 14 m/sec
19) The curve of angle of incident versus angle of deviation shown has been plotted for prism. The
(A)
(B)
(C)
(D)
20) Find the minimum value of d so that final image coincide with object :
(A) 60 cm
(B) 20 cm
(C) 30 cm
(D) 50 cm
SECTION - B
1) The angle between the velocity vector of object and image is . Velocity are shown in the figure.
2) 2Two thin conducting shells of radii R and 3R are shown in figure. The outer shell carries a
charge Q = – 6 μC and the inner shell is neutral. The inner shell is earthed with the help of switch S.
3) A rod of mass m (uniformly distributed) and length ℓ is hinged about point O in a uniform vertical
electric field as shown. Linear charge density of rod varies with x as λ = λ0x. Electric field for which
4) A compound microscope has a magnification of 30. Assuming that the final image is formed at the
least distance of distinct vision (25 cm). Find the magnification produced by the objective if focal
length of the eyepiece is 5.0 cm ?
5)
Three large thick conducting sheets are placed parallel to each other as shown, charge on plates
are 20 µC, –5 µC and – 15 µC and seperation between them is 1 cm and 2 cm respectively. Find the
CHEMISTRY
SECTION - A
1)
Select the correct order for the wavelength of absorption for the given complex:
3- 3- 3+ 3+
(A) [Cr(CN)6] = [CrCl6] = [Cr(NH3)6] = [Cr(H2O)6]
3- 3+ 3+ 3-
(B) [CrCl6] > [Cr(H2O)6] > [Cr(NH3)6] > [Cr(CN)6]
3- 3+ 3+ 3-
(C) [Cr(CN)6] > [Cr(NH3)6] > [Cr(H2O)6] > [CrCl6]
3+ 3- 3+ 3-
(D) [Cr(H2O)6] > [CrCl6] > [Cr(NH3)6] > [Cr(CN)6]
2)
According to the valence bond theory the hybridization of central metal atom is dsp2 for which one of
the following compounds?
(A) NiCl2.6H2O
(B) K2[Ni(CN)4]
(C) [Ni(CO)4]
(D) Na2[NiCl4]
3)
+2
(A) [Cu(NH3)4]
–2
(B) [ZnCl4]
–3
(C) [Cr(C2O4)3]
–3
(D) [Co(CN)6]
4) A complex of molecular formula CrCl3. 6H2O has green colour 0.1 mole of the complex when
treated with excess of AgNO3 gave 28.7 g of white precipitate of AgCl (Molar mass = 143.5 g). The
formula of the complex would be
(A) [Cr(H2O)6]Cl3
(B) [CrCl(H2O)5]Cl2.H2O
(C) [CrCl2(H2O)4]Cl.2H2O
(D) [Cr(H2O)3Cl3]3H2O
5) The 'spin only' magnetic moment [in units of Bohr magneton] µB of Ni+2 in aqueous solution would
be :-
(A) 0
(B) 1.73
(C) 2.84
(D) 4.90
6) Which one of the following lanthanoids does not form MO2? [M is lanthanoid metal]
(A) Pr
(B) Dy
(C) Nd
(D) Yb
(A)
(B)
(C)
(D)
8) Potassium dichromate when heated with concentrated sulphuric acid and a soluble chloride,
gives brown-red vapours of:
(A) CrO3
(B) Cr2O3
(C) CrCl3
(D) CrO2Cl2
10) If solubility of any gas in the liquid at 1 bar pressure is 0.05 mol/lit. What will be its solubility at
3 bar pressure, keeping the temperature constant? (in mol/lit)
11) Total vapour pressure of mixture of 1 mole volatile component A ( = 200 mm Hg) and 3 mole
of volatile component B ( = 160 mm of Hg) is 180 mm of Hg. For such case
12) 3.24 g of Hg(NO3)2 (molar mass = 324) dissolved in 1000 g of water constitutes a solution having
a freezing point of – 0.0558ºC while 21.68 g of HgCl2 (molar mass = 271) in 2000 g of water
constitutes a solution with a freezing point of – 0.0744ºC. The Kf for water is 1.86 K Kg × mol–1.
About the state of ionization of these two solids in water it can be inferred that :-
13) Addition of 4.0 g of a non-volatile solute to 54.0 g water results in a lowering of vapour pressure
by 1.0%. What is the molar mass of the non-volatile solute?
(A) 132
(B) 66
(C) 133.33
(D) 333
14) which of the following aqueous solution will have the highest boiling point?
15) Standard EMF of a galvanic cell involving 2e– transfer is found to be 0.591 V at 25°C. Calculate
equilibrium constant for cell reaction.
(A) 2010
(B) 1020
(C) 10200
(D) 20010
16) What is the standard reduction potential (E°) for Fe3⊕ → Fe? Given that :
Fe2⊕ (aq) + 2e⊝ → Fe(s) ;
Fe3⊕ (aq) + e⊝ → Fe2⊕(aq);
(A) +0.30 V
(B) +0.057 V
(C) –0.057 V
(D) –0.30 V
(A) 0.059 V
(B) 0.0295 V
(C) 0.118 V
(D) – 0.118 V
18) If 0.50 L of a 0.60 M CuSO4 solution is electrolyzed for a period of 30.0 min using a current of
4.60 A. If inert electrodes are used, what is the final concentration of Cu2+ remaining in the solution?
(A) 0.342 M
(B) 0.544 M
(C) 0.389 M
(D) 0.514 M
19) The two aqueous solutions; A(AgNO3) and B(LiCl) were electrolysed using Pt. electrodes. The pH
of the resulting solutions will
2+ –
(A) Sn , MnO4
– 4+
(B) MnO4 , Sn
3+
(C) I2, Fe
2+
(D) I2, Sn
SECTION - B
1) What osmotic pressure would the 1.25 molal sucrose solution exhibit at 25°C? The density of this
solution is 1.34 g/mL.
2)
H+(aq) | H2(1 atm) | Pt half cell and its half cell potential is found to be 0.7714 V. If ,
the pH of H+/H2 half cell will be :-
[Give answer as a closest integer]
5) The current of 9.65 A flowing for 10 min deposits 3.0 g of a metal. The equivalent weight of the
metal is
MATHS
SECTION - A
(A) 1
(B) –1
(C) 6
(D) –6
2) If A and B are square matrices of same order and AB = A, BA = B, then (A + I)5 is equal to (where
I is unit matrix)
(A) I + 5A
(B) I + 60A
(C) I + 16A
(D) I + 31A
(A) (299)2
(B) (300)2
(C) (150)2
(D) (301)2
(A) 1
(B) 2
(C) 4
(D)
(A) –2
(B) –3
(C) –4
(D) –5
6)
7) Let R = {(P, Q) | P and Q are at the same distance from the origin} be a relation, then
the equivalence class of (1, –1) is the set :
(A) S = {(x, y) | x2 + y2 = 2}
(B) S = {(x, y) | x2 + y2 = 1}
(C) S = {(x, y) | x2 + y2 = }
(D) None
8)
If R = {(x, y) : x, y ∈ Z, x2 +3y2 ≤ 8} is a relation on the set of integers Z, then the domain of R–1 is :
(A) {–1, 0, 1}
(B) {0, 1}
(C) {–2, –1, 0, 1, 2}
(D) {–2, –1, 1, 2}
(A) 1
(B) x
(C) 1+x
(D) none of these
10) If , then is
(A)
(B)
(C)
(D)
12) If ; then
(A) 0
(B) 9
(C) 7
(D) 8
(A) 10
(B) 8
(C) 50
(D) 25
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
(B)
π–
π+
(C)
π+
(D)
, is equal to
(A)
(B)
(C)
(D)
(A)
(B)
(C) cot–12
(D)
(A) 0
(B) 1
(C) π
(D) – π
(A)
(B)
(C)
(D)
SECTION - B
1)
3) Let R1 and R2 be relations on the set {1, 2, …, 50} such that is a prime and n ≥ 0
is an integer} and is a prime and n = 0 or 1. Then, the number of elements in R1 –
R2 is _____.
5)
Let A be a matrix of order n × n such that |A|=2. If the determinant of the matrix Adj (2. Adj(2A-1)). is
284, then n is equal to _______________.
ANSWER KEYS
PHYSICS
SECTION - A
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C A A C B C B B A C C B B B A B D A B
SECTION - B
Q. 21 22 23 24 25
A. 2 2 3 5 0
CHEMISTRY
SECTION - A
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B C B C D D D C B A B A A B C C D D A
SECTION - B
Q. 46 47 48 49 50
A. 29 9 3 3 50
MATHS
SECTION - A
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D B C C A A A B D C D C C C A B A C C
SECTION - B
Q. 71 72 73 74 75
A. 2 5 8 4 5
SOLUTIONS
PHYSICS
1)
at point (1,1,1)
2)
sinθ =
3)
Conceptual
4)
Conceptual
5) Total charge Q =
0
= 4πρ
6)
Conceptual
7)
Ui =
Uf =
Uf – Ui =
8)
10)
Conceptual
11)
Conceptual
Since,
.......(ii)
Hence .......(iii)
Adding Eqs. (i) and (iii),
Length of Image = L +
14) From snell's law at any interface μsinθ = constant. μg × sin i = 1 × sin90°.
Concept:
Equivalent Focal Length of a lens with different refractive indices.
Solution:
The lens acts as two plano-convex lenses joined together. The total power is the sum of the
powers of the two surfaces.
Calculation:
1. Net Power (P):
4. Result: v = 40 cm
⇒
so distance from centre
Concept
Mirror formula for the silvered spherical surface and plane–refraction formula.
Solution
v = 20 cm
acts as object for plane surface
18)
Conceptual
19)
Conceptual
v = –60 cm
This image position will act as object for mirror. To coincide final image with object, the light
rays must retrace their path for which object for mirror must be at its center of curvature
hence,
|v| + d = R
60 + d = 80
d = 20 cm
21)
τ=
τ=
& Put τ =
24)
Conceptual
25)
CHEMISTRY
26)
27)
28)
n = 2,
31) Yb is the only element that do not form MO2 type oxide
32)
Factual
33)
34) (1)
(2)
(3) Due to hygroscopic nature of Na2Cr2O7, it cannot be used as a primary standard in
volumetric analysis.
(4) Solubility order : K2Cr2O7 < Na2Cr2O7
⇒
∴ x = 0.05 × 3 = 0.15 mol/litre
Concept:
Raoult’s Law, Deviation from Ideal Solution, Enthalpy of Mixing
Solution:
First, calculate mole fractions:
Total moles
Since:
Observed pressure (180) > Ideal pressure (170)
In positive deviation:
A–B intermolecular forces are weaker than A–A and B–B
Enthalpy of mixing is positive
Final Answer: Option(1).
1 + 2α = × 100
1 + 2α =
2α = 3 – 1
α = = 1 ⇒ 100%
For HgCl2
ΔTf = 1.86 ×
1 + 2α =
=
1 + 2α = 1
2α = 0
α=0
Hence Hg(NO3)2 is fully ionised but HgCl2 is unionized.
38) Conceptual
39) Conceptual
40) E°cell =
0.591 =
log10K = 20
K = 1020
41)
Cathode :
________________________________
________________________________
= 0.118 volt
43)
Equvalent of deposit
Cu+2 =
44)
A(AgNO3)
Anode :– OH– → O2
Cathode :- Ag+ → Ag
45)
Question Explanation: Find the strongest reductant and the strongest oxidant from the given
standard reduction potentials.
Concept: This question is based on standard reduction potential (E°) and oxidizing-reducing
strength.
Solution:
Given half-reactions (all E° are reduction potentials):
I2 + 2e– → 2I– ; E° = 0.54 V
MnO4– + 8H+ + 5e–→ Mn2+ + 4H2O ; E° = 1.52 V
Fe3+ + e– → Fe2+ ; E° = 0.77 V
Sn4+ + 2e– → Sn2+ ; E° = 0.1 V
• Strongest oxidant → species with highest E° (most easily reduced) ⇒ MnO4– (E° = 1.52 V)
• Strongest reductant → species whose oxidation is easiest, i.e. whose corresponding reduction
E° is lowest ⇒ SN2+ (from SN4+/ SN2+, E° = 0.10 V )
46)
47)
Question Explanation:
Find the sum of primary valency and secondary valency of metal M in the complex
[M(en)2 (C2O4)]NO2.
Concept:
Solution:
The complex cation is [M(en)2 (C2O4)]+ since is the counter ion.
Oxidation state of M :
Let oxidation state =x
x + 2(0) + (–2) = + 1
x = +3
So, primary valency =3
Coordination number:
Final Answer: 9
48)
0
Ecell = 0.7714 = 0.533 – × log[10–2 × a 2]
0.7714 – 0.533 = –0.0591 × log[H+] × 0.1
= 0.0591 × (+1) + 0.0591 × pH
pH 3
50)
MATHS
51)
Conceptual
52) AB = A, BA = B A(BA) = A2
AB = A2 ⇒ A2 = A ⇒ A3 = A ⇒ A4 = A
⇒ A5 = A .....
(A + I)5 = 5C0A5 + 5C1A4I + 5C2A3I + 5C3A2I + 5C4AI + 5C5I
= I + 31A
53)
Conceptual
54) area of Δ =
= ∵s=
55) Method-Ι
Divided by λ4 nd take
Take P = ⇒
Method-II
Applying R1→R1–R2, R2→R2–R3
56)
Conceptual
57)
Conceptual
58)
Conceptual
59)
60)
Conceptual
⇒0≤
⇒ a > x4 + 1
⇒ a > 257
∴ aε (257, ∞)
=8
63)
Conceptual
64)
Conceptual
65)
66)
Concept:
Inverse trigonometric substitution
Solution:
⇒ Let sin–1(x) = θ
⇒ x = sinθ, then
68)
69) tan–1(1) + tan–1(2) + tan–1(3) = π
70)
Replacing we get
71)
72)
73)
Question Explanation : We need to calculate the number of ordered pairs in the set
difference R1–R2 where R1 and R2 are relations on the set A={1,2,…,50} involving powers of
prime numbers.
Concept: Set Difference and counting elements in Relations.
Solution:
Let A={1,2,…,50}.
The relation R1–R2 consists of elements such that p is a prime, n ≥ 2, and pn ∈ A.
____
Evaluating possible pairs based on prime p :
For p = 2 :
(Note: )
⇒ Number of pairs = 4
For p = 3 :
(Note: )
⇒ Number of pairs = 2
For p = 5 :
⇒ Number of pairs = 1
For p=7 :
For prime p ≥ 11 :
Final Answer : 8
75)
Now,
So, n = 5