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Alcohol Notes

best notes for mono-hydric, di-hydric and multi-hydric alcohols for JEE/NEET

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3 views49 pages

Alcohol Notes

best notes for mono-hydric, di-hydric and multi-hydric alcohols for JEE/NEET

Uploaded by

sakshamshrivastava001
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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[A Tohroduction © Clerciieation Mondhyabs < Mechel, ® DMomenclahire of Mronvkydivic Alecho}, ® Methods Q Rosmatic, | Prepradblon, S Physical Proportion of Alesrs ® chemical Properties 0 Alcon, o Digtnchkon bo Piemony me Sccerele ae rerbiong RYenele ® Nomenclohive SK dihydsse Alechal, Metod 0 Qoeration 8% Vieinad glycols. Plush cal BKeA chemicad Reactions (® Pinaccl — Pinacolone Rearvanerent, Glyrol (TH hyslae aleca\)) 9 o on a er, CER GH lhe Me Phenol iN PPPPPPPPPPPPFIEEIIVANAAAANNAAAA AKER ‘ POA Arteodu clone > Neondde tay be > Dogendi Regertled as hydrony, LPOW Wether he no. of CH Groups Present | Polketbe Peony on 7S Os Many. Alchols Quatre classified 48 fonchydlerc Bs SP ditudere or FHhglvc oF Poluydee devvablve of Atghah'c hapless, ch, On CHa Chg 04 Caso Son ee . Crt = OFF CHOW, FHX\ alcohol bn, -0% i ea ate AMrano\ CH, 0H ch,-0H om Erhylenedicol : ‘i - ol) Places Catycot) Palygharic (Too -0H1) CaAdiny) (Soxvite\) cmt be Pointed ovk hese tek th dihdede , THhydne and, Polyradme Alechele each Or aroup is Altuched fo a dl esen\ Caxbos, aor Yas 15 because the Prederce Of 2 or More, hydwoyy\ ore 04 the Same Coston alom makes the tolecole Unshsble and hence Jmmediotly loses a Moecule of wates te osm an alderde ov kelrane Os A Carbonic Reid, 1 = to, =o a on Awengle | ketone a a) - On—c— on C01 Cerborlayic acid) it “pel a & ve i S| 5 -o=0h —c—on Senna, — C—O y ne | Je Nes oO SEP eee eee ee ere ee ee ee ee rl y s SYNC Meohol — 2 nee Condning One hydrox oo hYsee Mechel this Can SS BYhabe Mechel e WY Avomabiec Aleohels \y Are fev Molecule axe called he divided inky hoo broad Cubygories exanpte - Chor eee ms Methario| yn cs oS aes AEN! eons pa Profan- 2=a\ \ Cron nN EAD Xto Prop) Mi\toho), Chy~ CH~ On Che - Cr, — On, Bhena\ rehanol ies pron) eben 1-0}, I~ prend CHa -|-6] Bengu Meshel or then) pe alleoho), Bi mest hl tect, Qi) Alehatte Meohals — DMeokds in which the hydrorl greop t Weed Tnhed fo an eb Aliph Crein Ore cated Aliphabe Pcchols © Peomanic Bleoral — Alcor tn which the hyglorl group 1S pesca tn We Side Chain OQ Bromabic Hagrocarbor te calles Prvrolie Aohels, wy ClassiPicalion of, Mohobyaric Neohds 5 Monchadiie Neches ave Rother classified as prieres 1Setordavey ard Wexisny Recording OS the on grup is Aitachedl to Pak, Seundiars Onc texviowy, Coesbbon Aho wea pechvely RBC core » & Nomendahre 2G tronshydeic Altea) ) ~° Somman Mame — Alka Deora ) - CHy— ont oe er Mel\\ Alcohol u ee ae e he Chy— Cri — Cs B—< 3 h, 7! Methonell, Fso propyl Oeshol chy 2 (Propan -9- 01] be bed Pleoho! Gay (reared propane -2 o\| NW Carbingl Suter — tr this Sater, methyl ale eh Se Carbine) tortie ot Stee ‘ me yg) Aleohols (CH 5- or) ts caked ) Cavblot cohels Gre Named ad devivahves Of < = Ca— oF Ss Chg ate ee thse ~o4 Gh, —¢ -Oh Cots oO \ \ = es) Garboinal e a, ae = Tinlad Cabins! << faphongl Gabi! ss H Merrouls of, Qrerration een ee mm UY Redvebion 0Q Allele anc Lelong (nideiyde~ 1° hl. Webra TAY | eg ) Red clon Grbsatic Add. [Aad ~ 1° Aono! @ (ii) Redv ction of, @iee [ire Semel} | = * tq MReduchor 08 Aderyse and kelore — 5) Pidergde tam be Reducect km |" Mes) > kolone Can ve Reduced to 2 Alcohol eter kd cas chee gens peak 15, AddRon Ee jn presence of Colulyst VT, pe Pd ee ov Ry Reduction, WH Complex celah hasmide. he Maria endl Lit Hy Cow} LAW —— Rarydnoes Dee or THE DAG ——9 Vales og Alecto! eee Reeeeee en! RY 6) =o Reduction RN. on \ Ha [PE|PA of Heat Linthy Cha, — Li Ate, chs C=O or 7 Wo, MIPELAA gee A Re Te Adee ‘ EES eRe Bc Robo} MeRAWPETPA QZ ZH OH 4° _ Alcohol ® ) © Cha S Ei (ee St Onon taglonexanel Kale heranene at Mecho d, 4 Mechanisy — Lag Sb 4 ALO (Lion norinion Hydede) h asl, CMe. R ty ° 0 Beet oy nor ce } Mcnco Y on-c—aA + PL lO )Y h ‘ OMT TIF IPF PEPE PPE EEL ETT TTTVTTTAAAA Loree Hy, ~ 6 © fhechanten ~~ eae See Cees aarcn on 2 ~ ae wh a ~~. No@rty => wHa4’ en rey ~ Ps ag CYA re a Roto ne © =» h mM —> i Cas ” emg G00 Bay » hou 3 R & ha Neem Wate 9 io) 4 . MOBS Rade ; 2 N o ¢ pate Sp-0-C—*k Reo once OH ia aoe x ° ae 1 0 Ch et lo-8- nQx° 5 “aes = WK e V20 wre eNO B(ordy Sia QS Clesifiy the Rowing ok Pimeity Secondary Grd berhar, cw a © Cha Co Chi-O" @ wiez CHB OH chs Chy-Chy ~ oy ’ C45 7° . uk e on ch * eae 43 @ eel © me as © py emer tron Gar COE ap \» > 2 © FE Grr TWenkRy allie oh els | re hie At cools in Healene escauyles — me fe Dd cea ou-che-OK F e che Se , -H= CH OW = O ' = chs = = é Qs Silext 9 Mame tre Qlloatre Compounds according bo Chok Gra “By — bh tH cn chy >> 2- cWovorrdty\ 2 teogP) thse chy CO 3 Ne @¢ Cee as cn thas 2,S di ett) Kerinendi6 chs aa om © or =) 3®romo cadohexanol. by ® SAR Cha = CH ~ ch~Che ~y =H, Hexen-20) on peti Jen. Qukes-Zeno). ® OH3- Ce © Ch, On > 2Bromo 2rd CES Exercise 1 Give SUPAC Mare 8 the Pellossing, Conpoorrch $ a 3 3 \ © Ca EM CH CRE CM27 0s Uechlire 2,3)di ratty Ferkano| C2 Cha chy ® Sy —0-Ch,~Chy chs on a > 746d trelu\ phenol. A : i “4 Oe ie > Hox Pro pme. ® —. TUPAC) 3 \ Pevinol OF i | 2 NiO cactohexane €! 6 OPE ITIL CE PEE EET TTT TTT TTA & NMECRT exercise - } Dre WAC name of Ke Glowing Compounds « ' Ch ~ S i © Cm deee eros 5 2,2,4 hirely) fendan-2 ol i Ch, On Cho » . ce 2 Hac ~ th Chg Retr HCH > 5 -elkal heptane -2M diol ‘ 1 \ = ou On Colts ™ Oty seest a ace > Butane-2,2 dial. -e On oH r De G72 * we Eo cae Gh, -Oh > Propane - 1/2,2 Pel. <6 ® Cehe-O-Gahs ch = cr 7 2 nell Ph evrol eZ ettoay Benzene = ® &hy-0- Ge OD ce D Phersxuheplane 20 S 4 metyl Phenol 3) “ > = a Orr sarema e | on / P =» DEM -bufuae? | =» ch -»> © ey : yous ds mekyl Phens | ) Maron » ene | -= re ‘ \ = ® w gle a ieodieatg! Phove | spre" » W8cHs » | © chs -0-he- Hs » a » Detbosy - 2 meky) PSPpane » # Redudton oR A, H Unmbsraled Ndehyles eronne 7 Ra@ny Ccodivn Lowshyyhisdle)) 2 f 2° alichels & Reduction 0g Aldchyden and Kerones te Vd wal SURRY CLimun Aloriaiun hybicle) & Reduction of Redes neers eS { col Orer % re x __Neblar Giga ha EO 6 Chg —CMy~ ch, —e-1 City - 9 Lindy, cn ~am che (Mak OF x 2 Cha = Ch~ten TARR HA on pon Oe ie Ect aca O- a SLE Corte G Oh PME sn TS Pisthor LIAQHy Mor MaBHy yeduces \svloted Coxbon- Gerben double Bond However 19 Coke OQ, Alpha Rela Uncahswated! edie anc kerore LiAQt, usally Reduces Only the Carbonyl en Whe dovble Bond Srkuebe mae eras ge Stablion?EliQ, Soneshal clifferert, Since Alclehydley Ory More Reaclive thn kelone. D Therefore Ww Core 0 My # Unsaturaked abderydte te Redvchi OQ We Adelade GPR OLCO'G pre Prercinthy « SOPPFTVTF PPP PPP EPP eee TTT TTT TAA AAAANAnr Pei ie A aeean \ Ocean ee een Oko Er ch =ch ~ cn, —Of W109 RP Unsahireted Conboy) on OH Ate, atts. Ch D_Nabry) Aleor4 a + a (OS Saag 0” ee HW hemos elective Reagent - aa ¢ eae Ro cheer c= Al Sata bo sD en aoa os y A-ean oH @ Poo @ oy a+ BBY, ~enctn—t- GH et —Cc~ cCAs~ CH= th © As fers oie Cony On- CMz -Ch, (Vr 9 u Production 02 IRAN , ea Bry, 1 sei OD w h \ h U-Gavloreyclol32{] Mere, # Meexvein Panndog, Vetleay Reockion — cmev) QR Ch, Ar(och (cH) | aR ere * Yeo eee: ioe calarencn, Ny R aw? h | _ Wr Gy Be Oe. xfocr (ers), chy PaO, coh 7 4 the oan Jor on £ Om-b- wy ha th | Oy CUCU eee seeaemdee Neth Oy PS] nh ee Ch &. PL Sey o- ¢~%, aN eC ICrTy g SFO ad 4 We NVA as uh \ | ~o~e- ye a RR Cowes / ae W chy n DI Cranial ‘ 1 ~~ . ) % 2 Canin’ ven iso propenide) ae a cns-t-o+" R WW =~ potaor + Abc Chr 2 | By ~O~ch(crn’) Senos, At Redu clon Coxteorye Raids : ? Cortoxyic Raids can be Xeduced to It Nleohels Noy bidity 3 5 \ Roc—oll ee _ Ee Roe OF LAR HG 8 Sre-e-0H Ary eer Hy0t Clg CH)~ OW > Cortoratic Reid Can also be xeduced to 1 - Meohol with Ban, eee 1 Bato Gbaces Rodeo Hag® 8 Oy ch —€ - 04 Chg che -cha~OM OPPUTP PEPER PP TT eee errerrrnC eee Kee, b$EEELEELEE @ 9 _ory id cn,-04 uf cl ae oH o ° cs 2 chr OM Shey (Hy -OH on xq Ti Reduction 8 eckers eee een Ca peo a) SOU UC eee L EE 20 REA Bovveovit Blac ‘ aceon Nal eeot, pon. —or + Pom ch,—Ch,—04 {Propane ® St RR eee ay geal, Bs G2 C5 Oars & Cag on (ebanod) = Tig Method invowes Whe seduction of Coaley Fo abtohe tis Nea Ord reQlvxing adeche\ . Ae a miehre OR hoo Alcohol 's Oolein One Drom the Acy\ qroug Amd Olney by Alkows group. Mechanic - This Reaclon belied We octde ‘mn Several Step involin the Vradfeor of Le aba lime ad the Altohol pare Ob & pron dona bo the lntptedial Redicle Anton Pus Shaor as below rechansn 2 SET (ingle Clectren Hemiflev) Nasr War + e= Sh i ne 0 } A a ae gph, Reo! eS CaN ae: Guson . b e os bo WS ee ee pe ie B-Ch,- 0h Reduction with UW pthy % \ pkoom lilly], tenor = HOM 1° Altohe\ (— Aliche: Linen, == H< Ake 32 io a'o- to, Blok SS Sn, ee er te fn salg DoH n bs * pec —O ® Cabalytic hydrogenation Copper Cromike ° u ud» Cal, Oy co ~ Chp — Ch, oH Cra -Cy~— C—O Cotte 4 DH, > Cs Che Che aro is 2 S28 (60 me. 4 From Grignaxck Reqagnt (Rosmabovety 17/2" wok : UL > Be Pest Stee of tee Reachion ty the Mudleophilic Bs ie Gaignerd Reagent Te tre Carvery Grup Yo Gorm aeduct. vadrolysis oR adduct yield a Neohel. al fad Pe a fe 5 wohan Ndeude React este Grgrard Reger’ CA-rgr j ea) 2 Ned pote Kekone Preach tity Grignerel Reaget be fom & Aluohel us oc & s- Oxewe Reg - SHPPPPYRrrPrer rrr rrerrrerrerragaqceccqge 1 ongby 5 at ° \) Oy 7 7 S65 MW 2a *~ Ch,— Mes Seca heen > Heol, oy De o _ ™ One re e ~ ~ Q ° Cresc =H Chetan om —-e-H > 11307 \ af Alesto’ ~ CMs = e Or: 3 chy - Mae on ~~ aa TSWROa On oe Cicer Ncohe! is = chy = i ty se © Pate il hehe Veron 12 Oy" 1 Secter, GF res Pe my ( ‘on YK $f? ; ZN pioorot RK Filermabon of Aeohot by Akenes — (onyrediial Alkene — Pei tule) D By Aad Camlyed Hycttabon. Creak folr) ® Oy vigdeo Borabion Seidalhen (Axi Mart Roles BD Oay Meveoralion Redvclion (Penh Role) © Gy ded Cakdaged Heydvathon — sy fechanicus SED Poodmnation oR Alkere fo Bos Corbocation by cletiphi le lech wh, Hs) gcp@® Nrcleophitic Ahact oR, wore on Combe calor Sep@) B deprivation Yo Qeors Alcohol. ee eee eee Ree eee 24 Yall Gon | aa a? 2 ee / H® Z ce HR Poa te Cm Teme CACera\) Lor! ENCE ei tbe Dame Oe CHUM Aer Cha~Chp—Oby 7 5 oa on Ofteno) Che~Ch= Ch, + hed © TSS el (ongarmeh cx) Wegn Creare) Ee a | on ye Cm Chs—c= th, k120 > ce ae che Crs t ' On H Ch ho fa? Vets a CO Ci yn AF MEchowse — 1 rS > Chath = Ch, & W2O ———> : oy © SPD Genser, + — _° cha fe — chy yet NIA ou Wem oraay de See Sa ae peu aa cro=c —¢th, Ware) Neal ds o® nucleophl east Se i h So ay Oye Oy oe ay eae Propn -2~0) ror PrP OPP PP PP TPP TTT TTA Bowers wig alcohol prepared by Beach, " ~ 4 Show Wow ane the Ppt cra Prepare S % Lulkbye, seagen! om = [Link] sel) Chy—ch—~Ch,—o4 Wy Q tiie 3908 iM 7 = chs eer = > Aay Chyth— tral 4 Hen cig Che Hens ated, Cre-Ch- Chor, = “8 hs hq (oh) Gx taby edn ch.0H ‘3 Sh weho + (J 5 6 as. ry ecre hon, SO Theat Net tote Slee chore of the Products of Ke Alon 5 J) crgchecht, —_brolh®) ce-ch ~ 0% é sf a UU UCC CeCe ees ae af a \ ; WY dheobiysalbidwe v/DelelaonmReachions ® Che~crach, Bale on oti Ft Iwalon Ong-ch,~ thoy Nee Lr MH. BH, : Unsynn erica Pins mate Rude ¥ u VA h @cehs-c Eee, Bake ohn CLL v 2 % Chy nbz] en toe Vea cet hol oh 1 =e thy wen Chy Ge ® a Syeaddihon __y ws ay mG yi Tee SER UDATONI fe > :o tate [bndo[or ae nas Pea ie b ae & 5 SOP KPT PPP PPP EPPO Pee eT TTT TTT TAA = Oxy Mescurabion Reduction - (ome \ yoo 0) Ung CH cyto lttaty dnsdy VG fieth ; Los) POY (rina wrd Lgl £% ~s sae ey * ? zo) ss 1 aul f : chy Z SG cope vi (Sia octarprlrba ‘ 120 easel : ; = fo398 pailxo8 =H eplossiow ‘ ieriee, See , p 4 tos 4 4 = a bo yrs Geant) Hci ) CY WHS? tesa, 8 h aed ~~ WD¥,0, babha eye? one ‘20, Ok = Oe s mibsnoh —H Yo ogee ned me = é =» > thy oe ~ Chae Me Ch, >) Os — aa ch, ath > @ Ch uh on ~ Cm Em thm chy haetaso, Eo = Dadra re Sere hep csr Ask ) ba, Chbsbel eaodgadeehwH law OnE Om ADD -ertuer =» => » 8 et eat 2 ou ” Pa , Rr 49319 wodden ola aol 4g > etaic 4 FR, 08h wo) “en ob tks G00 zn) ud go) Ss) “lA BD A oda pa donprd Nia > 0979 IQ 0-4 a » ah 262198 IF a wep ornlhwr2 pikes a) HPN OW C pyre bb was nen) » HPHYSECAL Properties ©f, Neshels O Phystead Sake & A ordi nc emppuure , lowes alcohols ave Gounless Vquids waits shrek Smell andi borning faute - Te Highes members ave Colovorlese , cdurless Vea Solicl. @ Hydregen Randing t Since aleehels Conluin a by wogen obtudhed!! ho edive RYE oho, Hrere(oke, extensive Skorgly dechone Bess cesioo = Bording CCCoXS arong abeobel Melecctes, Ae a vesult Alcohsls exigk 0 absociated Molecules Baker He. Aiscrele (Monomet<) melecs\es O4 show beloto, oF cone) ee Se. sein ey «REA ss ace 2h see BE HO) conemadnt = Oe ¢ oo 1 \ 1 | ee nS Te R R »Some Important Samp Fonseqyrencts of H- Bonding ave discessed below. > Clack Che Cites CHy-Ch_ Chg~0— Ch * “(ehh Ricohol 1 Rrepane, + mettyl ichionde Brretty! eles a ue as is Me BE (1) ey vl © Bathing Qoieds — Fe Boiling, Points oQalebds ase mech higher Moo Vyeleocestons , Mui hwlide?, ond @thers of, Conprsalte Koleeuler Popsed- QS’ Berm pe? + Re Boiling Poi of Alcchels Can be easily explained en the bar's ©f ‘levmoledur - Bonding existing us frei rolecdles. Guile q lage aromnt oR ences b needed bs Break these exknsive 1 Togen Cards tohich held a larg rembes Of, order, tlecoles regetrer: As beoulk, tery Baling eos A Puch highek Khan Hydrecarbots, eters ot Alky) halides (68 Gorgorsble Noreesles Nov) whch do ro Grn H-Bon Arowgst isomeric ahcohds , the BP derenre wilh byanch in gelve bo Commergudira, decveade Th Surface ares ie RP decrege jy eee Pama > Senn dart > ver vorry & PPPP PMT Perera rrr 1 = a CECE ECEEEE eee eee eee eee eee es; OtsdigchachsoH (Ch) Mrechpor — CMgcHoh Clas. (Ch 2 Coty \-Buranot Deh Propane 2 Cle) few cabal Qe. mum Be- Benk BP-33ik RBr-ascnK + Horsevey tata Inbrense ini Pde clean tress), Points Sipeo“e Xeaplar \nceetbt, 4 Me 4: i CHg 0H ChicHOF CHatheCl or Cha ch, th, Ch, oly tekst aleohot ehyl aleohol (-Propine\ 1— Beko! Be. Besk . Qprasvk BEB Ko —-ppeBIo.K— @Sarobitthy — The teers alcchas orehiquy Sie vin foal e beh hey Slobiliky decreases withthe Trevecd? in Soleculay Meus OD tre dleaol- “he Sotilily Of oleohols in ai ts chic Yo dre Qosrcdiow & hydrogen Bonds’ blo Netro) duel ede rolecule a oe ke & & es Se Ss WSL. he Pp eet =O HO \ t 1 1s, ee R nH RK H fe ome extent of) Sdobivthy OR Any cleohd in eles te pend tte ads ky Capabilities of tls telecon regen Tydroge- Bon Ea wit, aay : Rs the molecules trons indeed es ee Hx cetoe pak (ie eli gry) Werone larges hich vesisks jue Losmosion Arycbyer bonds, rath bale Moletded 2° 3% Alkohol . Uy Reaction vals Active. Metals (hed abr) > Pia Read wath Bene etal the Scdtum, Polhato’, fhegnassun cin Aeonim VO Rom Whe Corres Ponelig, Mel oyele tats evalobon BORN cra REO ee AN = OF adv Chyeor + Na Trak, State Matusid re } Athan ie SEO (xiens~d) ge eny |” Be Ces as iv 1 Ibs rhea Y ( ‘ie - > : 2 ay Daohetiidobe of Nyroxd 22 Ong nae gi 9 atte Alay’ eke toade? > Fese Neadlion Suge d bot aleohs Orve Cclelle Mire yndd clas 940292! 2 yt s9g378~ 4p wry? Y od ‘ es ey nD yi pas Jona stin9h deaf rodencorby! y diSbfesl foal pax f le ve 2's} a, et Compuixison OQ Retdiby of, Poe andl @2 Altos = D Te carat Sree ey Alechals Rslows,, He Or dey > ot Pyia5 32°_be dnet ‘ bbe Se 2 Te Gare Sens OR Alcantctes ao 1 Roc —bh + HSs —— Red BY 2 (Suen Roe a ’ aaa sca hae hen Cuca » p 2 Nhe &- Mtohals ore Verselile Compoond bey React Bok os Murleopii, = ded cleckropinies The Band blo OF 1S bisken When alcohols seack 2 os Mucleophite. = we” Meohot os (Mucleophle , > bat “Ss ) DEeeencal = RO ste CO aca” R68 ee a) Nudeoy'ite P< Qrdronakd alcohols as Clechooyhk i) = a -> - H ef x Rocha Ty, —> Reth,—Rr + has ele chnyWle uy Reachio its Gri ae Regent = d Acohols being ccldte Reack vs Qrgrerd Reagents Lohich eek as Serorg Rares fern alkanes \ Rongk a RON —— R-H + RON Rgnaxd | ae crate mg Vet) emcee tyr ORG Crs —egt® 4 Mnyg—s Chat heBa a £ : | Cn ~ dye * h-C=Se-Chy eS hy — rar + 4,0 —— Ch + maoer, +5 Cry + Ob etuuueruad (TY Ree atten ‘sath Cambor nic fotds — an Medals Keach esitty Canvas eAslel TArgebrene 8g Fes Areps °C, Cheat Be eee wt E Lv Ble Sz, Ur=ch ae + CMs =o SOE ae Se thes 7 z v ehene 7 ¢ to estes Concertreed HaS0y os Dry Hot, ges Catelags'h b° gor v Oss Cxanple ~ : forse 9 oe 5 ~ aes ath Ao 0-%Xy - Key Points - NO-A <_adatatng ages . - Zz 5 Rook + Ho- A SH, go QR 4 HO oc a ee og nobel dc ¥ ee ae e hy G5 On Cna- Ch 50 e + Cha hf 0> ee AS = 4 ehvoxsy ebhare (Dreths! etter) e “ons Come HaS0 cr eeeO) ws k oo 2 aoe wn e ae Wish Taunt aierdaeo O>%2 e e e e e& e oli mn a® Ree oy =o Cre tra B Oaths Opens ap A dveiod yropeo bdmgiey we ; mY /O ° e J 1 + a ; ~ —— pros + > Rol x« WO- c- a e Aicoral convene Peles e 20% Wppo-w4 gd- —_N0-¥]_ + DPOWE & a eA G8 pet + pD e— ath Dery yy (estes) 13 GX SS9- 9 4 (ND DSI + 84a — ond a i. FOC) prt + D¢@—— ON + We.) a _ e g % PI CHa an OH Hohe thy pas Cretth, ONES Ohy- Ch, ~ O- = Chyy Err) ocelot Chal Chranobr a q 8 3 ‘ h 8 Rec-fon 4 Roc — Re! Gre tidy, eon Oe Cue ae) Ach annulvide - ro et 4 ch T W “Gh, MES CaM MD —[Link] SUC, clea) 2 Qeevie Aryetside ° # Anbydede ack a dehy s abies eget HMrecharin \ a Tes A Seka a0. Ron 4 Mo—c-@ =—— K-0-07" 8 VuS0y <= Wt 4 FEOF oy 4 Lis ORCS R-Br 4 HE CRG Yo soni u hi lege kyo ‘etre Retorance hoag boh Rete eh @n” keane, ar aT poe- 8h + Ws R58 ) H Ps Chath + HO = \ iB sehy nc Pa Hu “a Chy~C - O-U— eee eee CTC C ECE EEEE “8 \ & boo os Cehasl acelste) OY Seolopte traces Sudies g. have ConQismed tha ees Qh cafion ees Ceaseine of He OF Bord 08 Aleokel and C+OM Sod of hetds Os Svogested ky above Mechanism ° Que 250, s Oe ch, ted Rens) Cohis 0 0 _— L Kemi v oe * Wot cH Cts re Cn + 4,0 Bw Ne co =Ch, Che— oh + Hof ~O3 We Ge ° Uh Reladsue Denes, of Gabseylic Acids and aleohols — eg v ne Sou + HO 4 chy Ch, a 5 eo Sr Sth woe Rad > gy, 7 frsceoo N= Coon ‘af Mi a CH Chg (shee Wederance) lovence, Pishol en, oy 5 cHy—cny- OM > Com,chon > CChs)s CoH e a 8 Why Pecichon with actd Chiedde aud Acid anhydricle , > tohen obcavals ave Hetated epity aetel chloride C8 qoid artudaia- He H afom of tre on group IS replaced by the acy aroor @ 2) \o er esters. this Reaction is called Raahon, + the actd halide and anhidiide used axe Accel chloride ano Arete Prnyglvide Reapechvely, be Reachon is useall Homedl 04 Reehation Haseves Ih verge) chlowde Is Used He Reaction i Called enzo4\ab on, Pare) adobe! oh Ais us Cured out in He Pregence ee shy ow ae, or dt Pores| Avitin e, + Dea geyedou of Alcovel is vs ably, Ousted cut 0 Predence of Apreous ie ico Bangy Griese 15° wor Yodlly hphelysed BY Alle OPP PPP PPP PP PPP HKSTTTTTTTIUVAVILAANs Se Gay a pn ere aN ) ee ererEyeas Gone May Qe dy FH 9 RL on A Ges ® Bag mR A Gein en 7 . 3 ed me haude ahh wee’ —fawhe , g-e- o- #4 “fa ss (x: ha, by 2) Gress » Qs . iS Ro agen atetthts REBAR, ahead Se fad anhydride Ms (ectew) . So FH Read on vith Reid Halide — o ling eu + we-e aS eae peecn 4 HK i Red hoade i if rn ‘o ———— Chane —Oena-Ch, + NCp LR + MQ -Cing~Che cS 2 a 6 fet geben & HB Cry-cy etree cree F By! ace Cyne Chas) ehrearccihe W) Scholten Baumann Reacko> —— D> Tre Reucion 0G AMechols with bergey\ cliowide and ll denvabves in Presence OR Ageous Madht is ced Schohin Caumann fxr. S ° \ tect + HO~ Cry Chy Madr We ie ass Beazeud Chloviee eluate SEER RE eee ees QD Resietian Laving Hee Cleavage 08 tow Bono! ~ ; *) Biorols underge a no. of RM invdeivy Ke dleavage of CoH : Bond In tris Reaction Whe Owes of, Fleachivthy Of Alcohol Qiks Ne order — Ld! ‘ W Reoiddion tally Holegen Aciol ; meen 1c * D Altobals Reack catty Mato gen Qatd to Govt alley! Oe : 4 é Te osdex of Reochviby Q Kollegen hei - é WE > HSe D tek é (with Regd — ‘ Chs-Or>—oy g peg oabncee | cyg—cho~ cl t 29) gover © ee hs 2S, @ Cha-ch oh + HCk pie a RC ZO) é chs e cis) cn of ch + Hed 7 a eee aS - é€ On, ¢ [on th = Or 3 e a. u & ” (to HO é Chs-ch-6H + Wey ——> Chy-Chy— Be + Had e e Meclunisr > Prirery aleohols Keact ett Halogen acids ba SN? Méebsnis<@s UNI Secondary alechol ad teshony aeohels tere to St) thecluniny, HER —a) bO 4 © SO? rechomism 5 Ht ; Fe cH 87 Rite By 4 HO SB Ro MOK, Prbmalrd) 19. Alegbol. ean: ch ‘ i re chee thy a va tac hy = Cty Un Cha a : Che —5Cha dl Ghen.-Crs ey, ss ) 0° a +) Opt eho, =» ; es, OReddion wh Ply PELs ond Sot, —— W Readion salt PELs apron +) PCy ed R-Gh + byPo, Chy~ Che OF 4) PAs > chy chy Ch tHe Py TE chantsr - = a R OL Seep or » rae RS poll bug a hate wae © A o * ca i Seq-@® CCee CS On ee) > CLR [Link]~ b> + a ! + tro a HO~ pow tt Recietion lth (CLs — Het Rol & Pols ——5 Rca 4 Pocks + SMechanisn- weed eee rele * Geac® Ree we Or nec ae eS cer a o Ws ce a Meese Pesca + PSP R CE, eR + we +t ReocBon wi SOCk, ———— Roon + Sofe, AME, Rich + Shes THIS s ° Pe. eee 8s? 8 ch “te " St due bo en? a Goa, - ge =—tS0= cae, Heodtons Walyiey Bah Ae ood Hughes) Qrovp — ® De hydsabion & Alcohol. Renee rE Ay aN @ Ovidleho» @ Dohragitor blo (°, 2° ard TF Alco @ Debydreotror ef, Aeotsl — 9 RAPE eclesle —ch,—O Con 12504 A Chy—chy Sees cec cee? Che=CH, +tRD Ci — Che ie Teal . Rs + SA coy ante | SHPO PPP PPP P Pee eee TTT TTT TVA iy 1 i Mani ee red SU ec TS chy Oe -t —&: tsoy sens, + HO 5 ere OR Suppor 8 above Mecheanist~ CCL EL i) Reters R Pa dave ease oR debyinabiar 6b, Alechols > SLY osdes SR, Cersho cabin se fe DeNO Ty = Guat “s ~e 2 be eaye eo debhycsodion aloo Qelloss ~ = area) eo ® Reerevewgenaut Of Cxberabors - Rormation 8) UMeXpecled Prec ke & Ongena Checheor, Gre WS, oy, c= cln ~Chy Cha aN 2 ® Oe eh = chs yo Chy chy a Che oh re ae ® Overtake, demydiesso, t Cha —Ch—ch- che ee > Chy~Chach~ Chy O.n 4 1 bax yor.) cn e ing & Cms—chy—C Un Oh Gare bra$0, ow ; ; : v ® ee Bercy, Cow hey, Ch, 4 Chs os 5 & (my — chr, —¢- Cus Gre He$04) out eUee eee eee eek Okidabor - | Q Co B64 | PRR SaCtoes eas CNR eee Ogee) Meshot Aldeydle areborye Med z an oxidisi ora =) RetasPiedt KaCwO, 0 Alkaline kmndr, o- HNO; oF W202 0 D Chyna 0H fewditiod ‘i t 4 > Hhosieen On ays Aine WACROe Pei. 5» & M yee ee crO 7 owe My he ee zal Ch oe cee 4 Fee Loh, Se pa et, Ch, ec = ‘he, a: Plkens wes > a > oid. > Ons —chy— b= Ory —Chy RS, Chg ~Chp— © Cha ~Cha hy ie V2 pratre ao) Phe wk ee) * Rein, of Hot (ave R-Chy-on C4. S23 o I Rtn 4hO Ch, Cu, SRK 6 Cuz thy -oh Cu. S28 ch teh + Heo Behradros eration eo Cima Ry Bashy coo the n (ee 6 oF Chg Ory Esty # Mhy—eyd CPMP HPP HP HPP PP TERETE TENET TCC Cg ~ nea = Ca SRK oe = iid Sem Os Gane gcc ZOU = Tp ~ J thild_oxidaky S ooo Pie ee chat es » ; / = | ae : Leo x 4 PCC will nk React waite bu S 0 is rguatds laps Pag Alesal (Cg? Aleck) on cHa— = Ch Velox Me = 7 a alale ~ Roe oh -. a 5 4 R- con Reo, . f+ T , a \ 2 \fs5 | fot Be i RMA An so'dsert a ns ec RY, Hw ae > s{BFPRnnad oon oat preneox lonows ive leno E ee : Jha , | pipe © Ee: Woe ti am a eaal ie eR. Sacoes} eh 288955 No ncdonarlerbae Nyloted us [HORE » Rre--s00% fir eV, gabon lor suey] "OY ” N04 R—c~1005 Notii-g Char = [folralic Nea ; ml: & (Noihwic eid NEO (fjord) — SO : z |» q (Reedoatsi) ye ,Nonvce™ a aol 1 80 | eB; : Clarlers — Blood Red Oh = We 2 Gluy Cob D Lucer B(Ch Wa Conca otis = e * Loco, Reagent > Tk is mixore Of Aug 2nCa + fon Hee, 3 Chis ) ch, Ch-c~jon + A Arh \ “s a + Hce Sach ame Camas 4 A20 2 Coe creat Turbidity chy a OLIES fidy Zee, Chy YW Abies Sox, Oe + Ind u Torii, afte Gt ninuke_ * Ue Oe on Hel Paty ee ‘ . ile Renchion af Deed Temp. A Some Comme sally Teportact Aileohels| ———___— D Mettonc\ and; ethanol cre Grong He hoo Commereidly Inpared Oeohole .) 1 = oof ® Metrano} => : 7 methanol hy xh also Linus cd’ toood Spixik, Loos prodiced by derrocive dis billaton 8 wood . Today , most 0 fue Melano) js Produced by Catalye Wudrogenahon of Carboy heraxice, at high pressure acl bryptehe ond 74 He iprsence df 2nQ5 Cxilog Catalyst 0-9-4 oH 9D 34. on, CHrdasbuis), L cio Qo ~Beo Ahr» DRAM HMHPHP HHH HHH HM HHRARMeeaaeeeaaHeHeee TU bb ddbe ®@ gy, = + Bhudect Alecho|, ——— 2S ey Grieg he gh eo0r clad ro di fereik > Coyoon cron Of, WHety, molecrles Called Aiigpphict Sas we? forma R dilydeve ale ig (Chir, (or>s We 23.5 s F se + Nomecahaye > Coomon Nabe Soe 18S alyeot ' S® TPAC Name DS Avane-diot : * oh ! Lt a ay crarat ) ee ye td ce tron © HO-Ch2— Chy~Ch, Oh Ce Be : ~ i ‘ Tindtiatenedyco } ) (erajore gues boil) Propwene Ae Lerepeney-\a Aa) = st enodands. etal orale 7) ; Saas ccs S br Ok Sere ss + methods wsmabion 08 ViGinal Siysoh ig © Be Neyroifadion of alleene SO By Hayter oC Are de m9 Hydrcdes ick Nisinal di helo cdllrane. @ B Moleculaay ¥dOchion of Cab Casbny) Compound, ‘ © Reachon oR Vy2"di Kerone toily grand aia) owuuwess ® Hudiroxu\abion 08, Aikene — > Vicinah Col Can be Conwicierthay/ Prepaisedt ip cas oy Alene eithew buy Meeakmen talk Calol’i clttuke Aaouiedvs Alea.) Sahut$or Rh KO ; f > Pamisivn Rormamnel (Bueyer+ Reagent) OF Sy, treatment edly OsOr Allowed by Hydolysts peily, an CaAvecss Hm 08 | Mag SOz oF Wah 50, vA | © Se Bakathe Cored the Reachion dayeres Trough indesrediahe fovea. eR, Capdte Strodore Magnet Sruchire), Wich offs op on Subs\yront Mupdrolysss QXe Vici neh Qlycol TTTTAAALAANNS * Sein chenistay— i 5 Sinke An Perey Hee’ Reaction a Cyclic Shw dere 1S Gowned ao & Qn intesmediote thereQore Bott tee seathons Awe Syn Arordahon Peacess, Hat 15 the boo hypleseisl GPL AEC adeled & 1 MY , a ie Sane Side 8 the doable Bord to affowet S30 mW e aycs\ cp ae t e e Crcange 8 i f ocner's Rent on = DsOu , MeMsOs FeO on = 7! aR. 9b BAA. 2 y i a gore Cay Jer ow Ch : a on (Ae 9Pe 3 bhropyp 4 Hoe e ea e a rs a i ° ee Mechanisu- 5K S xe nye _ Coad me > \ WZ SS me es LY Qeic oan een | =, Ch Canc a a on Of ee HH QD y Paine H \ of oF a thy ow S@ By Mydiealss 1s 0 > Aad os Ose Cakeiised hudicolust s Aytel, 16 Cove See wes ‘ 8 x Medanise fo cd Kens 1,2 die yank & RPonide Chy— Wa \ \ at oh a cca eae eo ib un” [ites OF) aS K-10. comme? 4 S 07 on "voy ot’ & Ce SCerons? bw Bt, f ae 7 ste \ a acre 2 ‘i Ox es ao, /, oe e Gh, Cee ioe a! h Cporid e AVE Vidined 28 ou ay en har gy T Chacon, Hecate hed, 0. el ema i One , Chy— Oy (ernare) Fexficehic held ee Saar tat A. < Raves Aetd Ow ine “Oe J Feshencta? Kh" o ue ar tr-chspperbora: . ) Si ‘ ‘ ¢ : Cae era € Ys e s () Steweochenis Oe m= cree eG, ho LEO, © Gitagiecioae eee centetnnarn?oxcceedan é t BS a » » oh 0 mcp@p ak (eS Baager Ree, Le . ~ 6, w Br [no 3 or > < (tae i) a : Oo i \ RB tugirtgds 0g Vidmal didatige alkane — So 7 Og eau! le - \ 10 + [Link], tO |5--—_» ‘iad a nat cH, — Gx Or chomart zo Bi MWe cules Redy dion Of, Cartoon Gmpourds RY > o C=O 1g [ Gen 2ene RY 2 “ mel ing Er co a ~ Rs ee i. ( hep a7 tg? Ne -on ies R few Prodle Seer sail Ch S K My benzene, fh g@ chy ne th2=¢=0 oe) Ch a.” fs \ Cho eS Se ements e scent Clt 8-0 on > | © Rede ation R \,2 di Melone solty Origners Reawent — eg & is Cie —~emehs J 2] a RA p Regt HC-Chy 0 v ho eres cHcty il p ier THE aa Women, J Dake th) on Oh gx 8 cage ee ene uaadasisy Oo la ae "p Gis Sas Chem F~E-ch dl 4 he ge OMe ame CS C— Gh 2 OC vn the ) if a A ae yg ges Be cu dots O ch=th- Cho CG 1 a) 1 nO- >) ' Ho ~~ o SOL -¢-th; EEE Chet ae ris. dn 04 srl) gun SAPP HPP PPP PRP RR Ohne an ~~ tr hig eb a , Lo Pysleal Propexdses Tail bippesloun phen 4276 po) Sate cdove, Coous eh. Chane | 2-21 6 9% Mqutd wily Socet task. By Re quid wil, Soee ety ~on group im Its PPO Viscoshhy > Because of, tre Foaeune 6 REY Meat fo — Proiecole, ethane “1,2 ~ diol undesgoed Krol deel Bere 3 Ps Hagoeegen Bonding. As a vesult, ethane ao ait ; Pe Highly aasociated ound thus th hase igh ViSHS ah —evoups , fe -(, P°@sdvviimy > Reowse of the: Prebente *h fon ts & eee 2- | eel fers hydvogen ends tle” osabes » Be NS ie or 0, aa sn unset futher, being a pols Se forrd, dio\ is Waly soble in uodek fos 8 Kadals Web Th ts lasetuble in Non- falas and userkly pela O ChiovoQosm . ether ek. hep ® RVing Point S Doe fo ealtndve intesmoleculas pense bonding We BR og ethene 12 diSliis Qullechin (sxx). " CUTE SCO © Aldehyde and Metre rote o mer ae rstiglene celiac Fo eae Ore oxidised by Sele te aldehgle at Kehoe " O-chy Chs SeOz Cho _—> \ ' ° 44) Cho cho Y wo 5 Hck ot 2 ‘ Q -.D Ch, o oof BB thet er chs, ° © 0 eee UCC CCC W Chemicef Rerction 08 1 Rents stn Neve Oetiyl: @ Readion SH hyglrgaen halide, & Renchon est Pets ACt, ® Rea chon, csihs Socg,.,., © Reaction ect. fo Nulla © React, esti, Menodegbanylte Actel ® Reoebion tH, Adee keksne, hype. cmcl) kekone, ® Belasdae Hon, } 5 i ® Orucabon clean of - Kol, vi ig flydse 224 -pntbwod Motel, fend Doe Dkeackio. with Achve Melk Charlot oe , 1 San i> Mot VA Qpen) eet ot EREERS 51 tonto ge Bi Ch, —oH ‘ Aycotede @ Recon tolth Hadrgen halide © tolh Hag Che. Ch, -ck pee a | ct ines, wed On, 0 Ch oH Ch,= co CMowohagtein Crslene di clloricle W) Soler voit HOE Chl-OH \ * UNG, ___, Che — Br Ch, —dH Ch, By Ch,— 0H th, —B:" Nat Mono Sodivn O sediue ayolte TET TT CTC CTT! coer rrPrrrrrrrrrrrerrrs »> > ole HE Oy » ral - cnt! ae ehalene = , SOUP —> ie s70 Al os Ch, — 01 Chi, Chen » a! ch, — Uf a : Ces ns ee eO Reastion WM, Poly ( PLLs “> ® Ch ~ on ‘. | Fo Cc ee Cig CR 44 a ee aN (@Aes,) Chy, HCL ) “s " a) Ons © (ist siyoit, tract Ch, — On ) . 442 o “s es )iRecchiary wlth) SOC eee He a» Cha OH stoh 0 [ s s» \ Fale OC eae) Ce) ~» Ch, —0H | 4, S02 4 Hee Cha —C.9 & =» eo © Reachion vothy Hog re—OH HOL-) 100, Chih Holt! 10, = 490A 1-95 S ® Redchor ‘uty mono carboxaic Pent Ch, 0H é hol c— 0 \ e 3 @gnatan FoF are EH) Aeros, oe I a i aol: Che O53 Cor ‘Q~ o HN Glycol diaceeuby euuueeeue ® Reachio Ch hy OH \ Fey wilh Ndeh des and KeloneA —— Cy sha 2 i" ye A Ante Gre IS faciek 7 Sol wer Ry P Phene \ R Siiptonte a0 [ceett c Alcetal | tet | Pts a Cho. ny Ch O11 R A Y ee ee vend ® Deby disakion ®@ Retion R Heat — a 773k NS Co no eNO De Cele a p@plene alicot Ow Raby Zeta — Qs' HS + ‘ wt he [OFF- AZ c8. —— op. oh In J. ‘Oh pO~ ! oe) uw @wvt Cones HSOu “> ab = NO — AD ans Cone Ha5Oz oh sos on “Ino = che— Ch. 5 vAshoth /o94)0 ele te a [Netdderge] e Ca dio XneJ 7PM MPP PP PP PPP PP Re TT TENT TTT ee CE é S & Esa g z £ ne (t ge are Or ae A r Shak cg 0h | os ee : ROH chy hash «) 0 YtheLsyery on,” : > Dietaglene glycol @) Oxdoton~ ) "d 5 QIN Jory ! D> Oridalion of) aluccl. gives, The) Vavichy, (64 «difperer Preducte Sera Stor wes eration Rte Past Oind the, ape, R Reagent sed xe a ae i. © Or \dation Wich the CHC Bond Remains inlact —~ ° Ch, ~oH . Roe i (om rae Cod j fot | OAS hnvo, at 2 Ch,~07 coh ch, — 0H octet Ret § in Dyce lh E te Sei Glyorodi c Reid Cro! 0 Coon Oa OSE cho Coot lyoxoS, oxalic Reid CCC CSCC CEE EEE EELELEEEE 2 rider, Tnvavieg Qistion OR C=C Bord Holding the hyybrony) | Arn ~ ; ma" Wr agytcl on orldation tah Aq cquerears GI” of Rorviedic Fel | » Prsoqy oF PHOCOCHSS, Led Kenrweelate, Wn an rgtnic Solvent BR Undergo Geto OR CH~E Rend lending Jo He Rowrehon OC, Ridebyde , Ketones or Bok, depadig vp on the glycol. bungee | o See pasion — 9 Ke Ovidation of 1aidaith Reyiedic Reid be gue Conor ' : ¥ W Or Pounel SS IAG Sore Yee eubled a Maloy rade Reachion, a o a These, Mager dre Specify « oo A 2cabycot Spbiirg tech & ex) Gn ovidise 1,2 AWyeol bot Wl 1,3 ov higher alycol . > Bexde 2 aycol BIO, Gin abso Ding okout the Oxidablue Close ge t,2 Aiiddewde 37100} Wekowey elo bol 40 ey Akdelyd ee ydeoru, feclone Kul rok 08 Aude GY Road estes , Acid OL Wydro ey eters og of Wytrony Acekaf ab HTOy \ c ee @b (o-¥ cr TCD ee ia a Dey of (Aiterycte a fone Keep DIAPHHP HP HP HOP HP KOR Rnennannnnnagragra LEE EE Pe PORE ERROR CORREO eeee K Chy~2 on a M ~4 on hort Ho ~chy \ Chit eee ESO fn Ranchers, ) ho-Ch ov Vteher ctiah 7 + q 8 h~ = co EEO Nord ger We ° W d Goryoxeeid) 8 Un—t Hr. 2 1 ch Lon (, 2- Ketone) c-K ° y 9 4 to. ey. = ae a ee H-c-0h 4 y-beon t Heh (a - by Arwoxyculdebyde) nh yw oa 9 g E04 Peereeeecon co Hoe oF c=0 h-¢e—0H { V1 (aL Hyhranys keaton) a Pinacohes Pinpiclone Reachon s! ~ 5 Sopsitured Meinal diols ave weferedl Yo a Finacols fost ioe ‘XiB dh Meti\ ulane 2.3) diel Losally Called Pinacolh is heute! ~ Oi, Gucerheted MeSoy 4k Unclergoes delydaadia wikis roleculed y, mo Berm every ohg meting! Kelone(abre called gina coleg) — Peartgres Ne Ske Wochen teh a Sy ' “3 : ies Rewwrargerent 1S On| tah mdeulay process By ae cm @ oR ths a \ = 7 OG, 4 De. a uae sar 6 Ot eee eat ‘ia rn @H A 6H ba ® Mew Paint >: Rosmation of Sle Carbo cations i) ) “ a) ) ss 3 x higharong aphiese) » ra Cha Caches ce con Oa He ne OMI Soon <= on Cia thy 0 oS aa Ha Soy SS WO 4 nso . $3 tty Ga gng e Ce iets Cha ic ery ICSC cr, is BO ory etl ee ie oe? ye » ALA 8-8 1 wor oh = » ~ FL on, =» Opt —echeh, ee : Ca, © S ly |X P-rehox B® Mabry httode DP chlorophens| < Phery! < tbe! a a => » ® th a Pst dace By on Ou ® Hy Och © See, e t% (ens) Co Che nih bow ppd OAC = thy , Or : Ho AE ee ee ie) ‘ OH On ne A: Ochs ‘ 0. q ay Tera Err O% CF + AhO Oh Oh Zon ws 100, NO,

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