01-02-2026

1803CJA101029260008 JM

PART-1 : PHYSICS

SECTION-I

1) The time period of a particle in simple harmonic motion is 8 sec. At t = 0, it is at the mean
position. The ratio of the distance travelled by it in the 1st and 2nd second is :-

(A)

(B)

(C)

(D)

2) A particle executes SHM with time period T and amplitude A. Its displacement from mean position
after a time T/8 passing the mean position is :-

(A)

(B)

(C)

(D)

3) Two particles are performing SHM about same mean position and have same amplitude A. At t =
0 both particle have same velocity and separation between them is then at which time they
cross each other if time period of SHM for both particle is T?

(A)

(B)

(C)

(D)

4) Two blocks of same mass but different density ρ1 & ρ2 are floating in water. Block–2 has higher
fraction of its volume submerged in water. If buoyant force on them are B1 & B2, then
(A) B1 > B2, ρ1 > ρ2
(B) B1 < B2, ρ1 < ρ2
(C) B1 = B2, ρ1 > ρ2
(D) B1 = B2, ρ1 < ρ2

5) A wide tank of cross-section area A, containing a liquid to a height H, has an orifice at its base of

area . The initial velocity of top surface of liquid is

(A)

(B)

(C)

(D)

6) A space 2.5 cm wide between two large plane surfaces is filled with oil. Force required to drag a
very thin plate of area 0.5 m2 just midway the surfaces at a speed of 0.5 m/sec is 1 N. The coefficient

of viscosity in kg-s/m2 is :

(A) 5 × 10–2
(B) 2.5 × 10–2
(C) 1 × 10–2
(D) 7.5 × 10–2

7) A liquid of mass 1 kg is filled in a flask as shown in figure. The force exerted by the flask on the
liquid is :- (g = 10 m/s2) [Neglect atmospheric pressure]

(A) 10 N
(B) greater than 10N
(C) less than 10N
(D) zero

8) The velocity of the liquid coming out of a small hole of a large vessel containing two different

liquids of densities 2ρ and ρ as shown in figure is :-

(A)
(B)
(C)
(D)

9) Angle between two mirrors ‘θ’ and location of object is given in List-I and some possible number
of images are given in List-II.

List-I List-II

(P) θ = 30° and object is on bisector (1) 9

(Q) θ = 36° and object is on bisector (2) 11

(R) θ = 22.5° and object is on bisector (3) 8

(S) θ = 50° and object is on bisector (4) 15

(A) P→2, Q→1, R→4, S→3
(B) P→3, Q→1, R→4, S→2
(C) P→3, Q→1, R→2, S→4
(D) P→1, Q→2, R→4, S→3

10) Pendulum A is a physical pendulum made from a thin rigid and uniform rod whose length is ℓ.
One end of this rod is attached to the ceiling by a frictionless hinge so that rod is free to swing back
and forth. Pendulum B is a simple pendulum whose length is also ℓ. The ratio for small angular
oscillations, is :

(A)

(B)

(C)

(D)

11) A ray is incident on a curved spherical mirror of radius of curvature 10cm along a vector

. The direction of normal at the point of incidence is along the vector as shown

in the figure. The unit vector along the reflected ray is :

(A)

(B)

(C)

(D)

12) A solid cylinder attached to horizontal massless spring can roll without slipping along horizontal

surface. Find time period of oscillation.

(A)

(B)
(C)

(D)

13) A laser light hits the target P after 2 reflection as shown. Find sum of distance AO and BO (Given

PC = 4 m, CM = 16 m, OC = 10 m) :-

(A) 12 m
(B) 16 m
(C) 10 m
(D) 20 m

14) A person walks at a velocity V in a straight line forming an angle θ with the plane of a plane

mirror. The velocity Vrel with which he approaches his image?

(A) 2V sinθ
(B) 2V
(C) 2Vcosθ

(D)
sinθ

15) A plane mirror is moving with velocity . A point object in front of the mirror moves
with a velocity . Here, is along the normal to the plane mirror and facing towards the
object. The velocity of the image is :-

(A)
(B)
(C)
(D)

16) A boy of height 1.5m with his eye level at 1.4m stands before a plane mirror of length 0.75m
fixed on the wall. The height of the lower edge of the mirror above the floor is 0.8m. Then :-

(A) the boy will see his full image.

(B) the boy can’t see his hair.
(C) the boy can’t see his feet.
(D) the boy can see neither his hair nor his feet.

17) A square gate of size 4m × 4m is hinged at topmost point. A fluid of density ρ fills the space left
of it. The force acting 1m from lowest point which can hold the gate stationary is :

(A)

(B)

(C)

(D)

18) There are two identical small holes on the opposite sides of a tank containing a liquid. The tank
is open at the top. The difference in height between the two holes is h. As the liquid comes out of the
two holes, the tank will experience a net horizontal force proportional to :-

(A) h1/2
(B) h3/2
(C) h
(D) h2

19) If the block shown in figure is displaced slightly and released, find the time period of oscillations
of the block :-

(A)

(B)

(C)

(D)

20) If two blocks of mass m1 = 3 kg and m2 = 6 kg are rigidly attached by a spring of constant k =
200 N/m. It is initially compressed by 9 m and then released, find time period of oscillation of two
blocks and ratio of maximum displacement of m1 & m2 from natural length.

(A)
sec, 2

sec,
(B)

(C)
sec, 2

(D)
sec, 9

SECTION-II

1) Two particle are performing SHM along same line about same mean position. Initially both are at
their positive extremes. If time period of each particle is 24 sec and difference of their amplitude is
12 cm then find minimum time (in sec) after which the separation between particles become 6 cm.

2) Two masses 8kg and 4kg are suspended together by a massless spring of force constant 1000
N/m. When the masses are in equilibrium, 8kg is removed without disturbing the system. The
amplitude (in cm) of oscillation is :-

3) The potential energy of a particle of mass 1 kg in motion along the x-axis is given by U = (10 – 10

cos 6x) J. If the period of small oscillations is second, find the value of n.

4) A ray incidents parallel to principal axis on a concave mirror at an angle θ. After two reflections,

reflected ray becomes parallel to incident ray. If θ = (in radian) then find the value of N.

5) If a particle's x-coordinate vary with time as , find time when it is at

moving towards origin.

PART-2 : CHEMISTRY

SECTION-I

1) A 6.90 M solution of KOH in water has 30% of KOH by weight. The density of solution is
[Atomic mass : K = 39]

(A) 3.88 g/ml

(B) 13.88 g/ml
(C) 1.4 g/ml
(D) 1.288 g/ml

2) A mixture of magnesium chloride (MgCl2) and magnesium sulphate (MgSO4) is known to contain
0.6 moles of chloride ions and 0.2 moles of sulphate ions. The number of moles of magnesium ions
present is :
[Atomic mass : Mg = 24, Cl = 35.5, S = 32]
(A) 0.4
(B) 0.5
(C) 1.0
(D) 0.8

3)

List-I (Concentration of aqueous solution) List-II (Density of given solutions is 1.2 g/ml)

(I) 2M NaOH solution (P) 16gm solute in 240gm solution

(II) (Q) 60gm solute in 240 gm solution

KOH solution

(III) (R) 8gm solute in 100 ml solution

CaCO3 solution

(IV) (S) 30 gm solute in 100 ml solution

[Given atomic mass : K = 39, Ca = 40, Na = 23]

(A) I-P, II-R, III-S, IV-Q
(B) I-R, II-S, III-R, IV-S
(C) I-P, II-Q, III-S, IV-R
(D) I-R, II-S, III-P, IV-S

4) Automotive air bags are inflated when a sample of sodium azide (NaN3) is very rapidly
decomposed to sodium and dinitrogen gas, then what mass of sodium azide is required to produce
368 litre of N2(g) with density 1.12 g/L ?
[Given atomic mass : Na = 23]

(A) 0.638 kg
(B) 1.2 kg
(C) 1.5 kg
(D) 5 kg

5) 25.4 gm of iodine and 14.2 gm of chlorine are made to react completely to yield a mixture of ICl
and ICl3. Ratio of moles of ICl & ICl3 formed is (Atomic mass : I = 127, Cl = 35.5)

(A) 1 : 1
(B) 1 : 2
(C) 1 : 3
(D) 2 : 3

6) 200 ml, 2M Li3PO4 solution is 80% ionised then find sum of mol of all ions in solution :-

(A) 1.6
(B) 1.28
(C) 8
(D) 6.4

7) A quantity of 27.6 g of K2CO3 was treated by a series of reagent so as to convert all of its carbon to
K2Zn3[Fe(CN)6]2. The mass of the product formed is (K = 39, Zn = 65, Fe = 56)

(A) 139.2 g
(B) 11.6 g
(C) 69.6 g
(D) 23.2 g

8) Most stable carbocation is :

(A)

(B)

(C)

(D)

9) Which of the following carbocation can rearrange.

(A)

(B)

(C)

(D) None of these

10) Select the incorrect statement about FCC (ABCAB…) structure.

(A)
Distance between nearest octahedral void and tetrahedral void is

(B)
Distance between two nearest tetrahedral void is

(C)
Distance between two nearest octahedral void is

(D)
Distance between layer A and B is

11) Identify the correct statement.

(A) Concentration of schottky defects depends on temperature.

(B) Both frenkel and schottky defects are mobile.
(C) Diffusion in crystalline solids is mainly due to presence and mobility of point defects.
(D) All of these

12) Identify chiral compound?

(A)

(B)

(C)

(D)

13) Using the following information determine the boiling point of a mixture contains 1560 gm
benzene and 1125 gm chlorebenzene, when the external pressure is 1000 torr. Assume the solution
is ideal.
Given : Molar mass of benzene = 78 gm/mole
Molar mass of chlorobenzene = 112.5 gm/mole
 Vapour pressure of
Vapour pressure of
Temperature (ºC) benzene (torr)
chlorobenzene (torr)

80 750 120

90 1000 200

100 1350 300

110 1800 400

120 2200 540

(A) 120°C
(B) 110°C
(C) 90°C
(D) 100°C

14) Statement-1 :
(I) and (II) are optically active molecules.
Statement-2 : Molecules containing plane of symmetry or centre of symmetry or both cannot
be optically active.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1
(C) Statement-1 is false, statement-2 is true
(D) Statement-1 is true, statement-2 is false

15) Select the correct order among the following :

(A) B-F distance in is lesser than in BF3.

There is no change in bond angle in B(OH)3 due to back bonding as compared to the case if
(B)
back bonding is not present.
(C) Electron affinity of P is more than that of N.
(D) First ionisation energy of Cu is more than that of Zn.

16) Select the correct stability order among the following.

(A) Aℓ+3 < Ga+3 < In+3 < Tℓ+3

(B) CF2 < CCl2 < CBr2 < CI2
(C) Si+2 < Ge+2 < Sn+2 < Pb+2
(D) P+5 < As+5 < Sb+5 < Bi+5

17) Assertion : ICl3 readily dimerize into I2Cl6 which is a planar molecule and having
multicentered bond.
Reason : The main reason for dimerization is to achieve complete octet.

(A) Assertion and Reason both are true and the Reason is a correct explanation of Assertion.
(B) Assertion and Reason are true but Reason is NOT correct explanation of Assertion.
(C) Assertion is true but the Reason is false.
(D) Assertion is false but the Reason is true.

18) Correct statement is ?

(a) In B2H6 maximum six atoms can be accommodated in one plane
(b) In Al2Cl6 octet is incomplete
(c) In Al2(CH3)6 total twenty two 2c – 2e bond are present.
(d) In Be2H4 two 3c – 2e bond present.

(A) a, b, d
(B) b, c, d
(C) a, b, c
(D) a, c, d

19) Select the CORRECT radii order –

(A) K > Ca > P > Mg > N

(B)

(C)
(D) Co ≃ Ni ≃ Zn

20) Which of the following order is correct :-

(A) S > O > Se > Te [electron affinity]

(B) Sn < Pb (IE1)
(C) Electronegativity of F in Pauling scale < Electronegativity of O in Pauling scale
(D) C < N < O (Ionisation energy)

SECTION-II

1) Calculate molarity of final solution obtained by mixing I and II HNO3 solution.

Solution I II

12.6 6.3
%
 d (in g/mL) 1.5 1

Volume (in L) 5 5

2) A vessel fitted with a weightless, frictionless piston of 0.246 m2 area of cross section contains
excess concentrated HCl. The piston moved 0.1 m outward when 0.075 kg of iron fillings were added
at 300 K and 1 atm pressure. The solution left behind was found to contain iron as Fe(II) only. If %

purity of iron in iron fillings is y% then find nearest integer value of ?

(Assume gas/gases behaves/behave ideally and impurity does not react with conc. HCl and initial
volume is negligible ).
(Given : R = 0.082 L-atm/K-mol, Fe = 56)

3)
Possible number of alcohol (including stereoisomers) in above reaction

4) Number of pair(s) in which ionic size of second specie is more than that of first specie.
(F–, Cl–) ; (Fe+2, Fe+3) ; (O2–, N3–) ; (Ca+2, K+) ; (Na+, Rb+) ; (I–, H–)

5) Find the number of chemical species, in which 2pπ–3dπ back bond is present
B(OH)3, N(SiH3)3, P(CH3)3, N(GeH3)3, BeCl2, O(SiH3)2, BCl3

PART-3 : MATHEMATICS

SECTION-I

1) Period of f(x) = sgn([x] + [–x]) is equal to (where [.] denotes greatest integer function)

(A) 1
(B) 2
(C) 3
(D) does not exist

2) If domain of f(x) is [1, 3], then the domain of f(log2(x2 + 3x – 2)) is

(A) [–5, –4] ∪ [1, 2]

(B)
[–13, –2] ∪
(C) [4, 1] ∪ [2, 7]
(D) [–3, 2]

3) Consider the function f : R R defined as .

Assertion (A): f(x) is not one-one.
Reason (R): f(x) is not onto.

(A) Both A and R are true and R is the correct explanation of A

(B) Both A and R are true but R is NOT the correct explanation of A
(C) A is true but R is false
(D) A is false and R is True

4) The domain of the function is

(A) [2, 3]
(B) [–2, 4]
(C) [–2, 2] ∪ [3, 4]
(D) [–2, 1] ∪ [2, 4]

5) Let f(x) be defined on [–2, 2] and is given by f(x) = , then f(|x|) is defined as

(A)

(B) f(|x|) = x – 1 ∀ x ∈ R

(C)

(D) None of these

6) The function f(x)= sin – cos is

(A) non periodic

(B) periodic with period 2(n!)
(C) periodic with period 2[(n + 1)!]
(D) periodic with period n!

7) Let f1(x) =
f2(x) = f1(–x) for all x
f3(x) = –f2(x) for all x
f4(x) = f3(–x) for all x
Which of the following is necessarily true ?

(A) f4(x) = f1(x) for all x

(B) f1(x) = –f3(–x) for all x
(C) f2(–x) = f4(x) for all x
(D) f1(x) + f3(x) = 0 for all x

8) The complete set of values of the expression is (where {.} represents fractional part
function)

(A) (–∞, 0) ∪ (1, ∞)

(B) (0, ∞)
(C) (e, ∞)
(D) (0, e)

9) Let f(x) =

List-I List-II

(A) Set of all solution of inequation f(x) < 0 is (I)

(B) Set of all solution of inequation f(x) > 1 is (II)

(C) Set of all solution of inequation f(x) < 2 is (III)

(D) Set of all solution of inequation 1 < f(x) < 2 is (IV)

(A) (A) – IV, (B) – III, (C) – II, (D) – I

(B) (A) – IV, (B) – II, (C) – I, (D) – III
(C) (A) – II, (B) – IV, (C) – III, (D) – I
(D) (A) – IV, (B) – II, (C) – III, (D) – I

10) For x ∈ R – {0, 1}, let f1(x) = , f2(x) = 1 – x and f3(x) = be three given functions. If a
function, J(x) satisfies (f2oJof1)(x) = f3(x) then the value of J(3) is equal to

(A)

(B) 0
(C) –2

(D)

11) If g(x) = x2 – x + 1 and f(x) = , then -

(A) Domain of f(g(x)) is [0, 1]

(B)
Range of f(g(x)) is
(C) f(g(x)) is one-one function
(D) f(g(x)) is unbounded function

12) Which of the following represent the graph of the function f(x) = ?
[Note : [k] denotes greatest integer less than or equal to k and {k} denotes fractional part of k.]

(A)

(B)

(C)

(D)

13) Which of the following functions is one-one ?

(A) f : R → R defined as f(x) =

(B) f : [–1, ∞) → (0, ∞) defined by f(x) =

(C) f : [3, 4] → [4, 6] defined by f(x) = |x – 1| + |x – 2| + |x – 3| + |x – 4|
(D) f(x) =

14) The total number of solutions of [x]2 = x + 2{x}, where [.] and {.} denote the greatest integer
function and fractional part, respectively, is equal to

(A) 2
(B) 4
(C) 6
(D) None of these

15) Let f(x) = x4 – 2x2 + 5 be defined on [–2, 2]

Statement-I : The range of f(x) is [2, 13].
Statement-II : The greatest value of f is attained at x = 2.

(A) Statement-I is True, Statement-II is True, Statement-II is a correct explanation for Statement-I
Statement-I is True, Statement-II is True, Statement-II is not the correct explanation for
(B)
Statement-I
(C) Statement-I is True, Statement-II is False
(D) Statement-I is False, Statement-II is True

16) Sign of the expression (x – 1)(x – 3)(x – 4)(x – 6) + 10 is

(A) Positive for all real values of x

(B) Negative for all x ∈ R
(C) Can be positive, negative or zero
(D) Can't say

17) If f(x) = x2 + 2bx + 2c2 and g(x) = –x2 – 2cx + b2 are such that min.(f(x)) > max.(g(x)), then the
relation between b and c is

(A) no relation

(B)

(C)
(D)

18) Let where a > 0 and g(x) =( (f |x| ) – | f (x)| )/2. Then the
function g : [ –a, a] → [ –a, a] is

(A) neither one-one nor onto.

(B) both one-one and onto.
(C) one-one.
(D) onto.

19) Let A = {1, 2, 3, …, 9} and let P(A) denote the power set of A. If the number of functions
such that is mn, m and and m is least, then m + n is equal to

(A) 72
(B) 74
(C) 76
(D) 44

20) Let A = {1, 2, 3, 4} and B = {1, 4, 9, 16}. Then the number of many-one functions f : A → B such
that 1 ∈ f(A) is equal to :

(A) 127
(B) 151
(C) 163
(D) 139

SECTION-II

1) Let α, β, γ and δ be the roots (real or non real) of equations x4 – 3x + 1 = 0. The value of α3 + β3 +
γ3 + δ3 is

2) If α, β are the roots of the equation x2 – 3x – 15 = 0 and f(n) = αn + βn, then

is equal to

3) The value of is equal to (where [.] denotes the greatest integer function)

4) If (sin–1a1 + sin–1a2) (sin–1a3 + sin–1a4) (sin–1a5 + sin–1a6) = π3, then the value of is

5) Let A = {(x, y) : 2x + 3y = 23, x, y ∈ N} and B = {x : (x, y) ∈ A}. Then the number of one-one
functions from A to B is equal to _____.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B A D A B A B A B C D A A B C B C A A

SECTION-II

Q. 21 22 23 24 25
A. 4 8 3 4 1

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D B A A A B B D C B D C D C C C C D C B

SECTION-II

Q. 46 47 48 49 50
A. 2 5 3 4 2

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A B C C C B A D A A C C B D A D A B B

SECTION-II

Q. 71 72 73 74 75
A. 9 8 8204 1 24
 SOLUTIONS

PART-1 : PHYSICS

1)

Correct Answer is (D)

2) x = A sin ωt =

3) Phase difference between to particle SHM

Phase travelled by

P or Q =

So time =

4)

B = mg ⇒ B1 = B2
ρ1V1g = B = ρwvLDg

⇒ ρ2 > ρ1
5)

⇒ ....(1)
Equation of continuity

⇒ V2 = 3V1 ....(2)
From (1) & (2)

6) Velocity gradient =
as force on the plate due to viscosity is from upper as well as lower portion of the oil, equal
from each part,

Then,

⇒ η = 2.5 × 10–2 kg – sec/m2

7)

Correct Answer is (A)

8)

Correct Answer is (B)

9) For (A) = 12 ⇒ Number of images = 11

For (B) = 10 ⇒ Number of images = 9

For (C) = 16 ⇒ Number of images = 15

For (D) = 7.2 ⇒ Number of images = 8

10)

&

11)

12)

13) Correct Answer is (A)

14)

15)

Correct Answer is (B)

16)

or MP = 1.6m > 1.4m

Hence, the boy can not see his feet

17) Torque on gate due to fluid

Torque due to Force = (F) (L – 1)

Where B = Breadth = 4m, L = length = 4m

18)
19)
2ky = 2kz
y=z
F as block = – ky
Constraint ⇒ x = y +2z
x = 3z = 3y

20) T = ,
m1A1 = m2A2

21) Separation is half after phase changes by

μ=7

22)

23)

u = 10 (1 – cos 6x)J

⇒ F = –60 sin 6x
∵x→ 0
F = –360 x
⇒ mω2 = 360
ω2 = 360
 ω= =

⇒n=3

24)

Correct Answer is 4

25) By putting , we get phase of

=
⇒t=1

PART-2 : CHEMISTRY

26) Weight of KOH in 1 litre solution = 6.9 × 56 = weight of solution

∴ weight of solution =

∴ density of solution =

∴ density of solution =

27)

28) (I) 2M aq. NaOH solution (d = 1.2 gm/ml)

2 moles NaOH present in 1l(1000 ml) solution
or 2 moles NaOH(80 gm) in 1200 gm solution
1000 ml solution → 80 gm NaOH
100 ml solution → 8 gm NaOH
1200 gm solution → 80 gm

240 gm solution → gm NaOH

(II) 8% aq. KOH (d = 1.2 gm/mol)

8 gm KOH in 100 ml solution
8 gm KOH in 120 gm solution
16 gm KOH in 240 gm solution

(III) solution (d = 1.2 gm/ml)

100 gm solution contains 25 gm CaCO3
 400 gm solution → 100 gm (1 mole) CaCO3

240 gm solution → = 60 gm CaCO3

solution → 25 gm CaCO3

(IV) :
i.e 1 mole C3H7OH + 10 mole H2O
↓ ↓

240 gm solution = 200 ml solution

29) 2NaN3 → 2Na + 3N2

1.12 = , m = 368 × 1.12

30) I2 + Cl2 —→ ICl + ICl3

0.1mol 0.2 mol x mol y mol
⇒ 0.2=x+y ⇒ x=0.1
0.4=x+3y ⇒ y=0.1

31)

Li3PO4 → 3Li+ + PO43–

0.4 mole
0.4–0.4×0.8 3×0.4×0.8 0.4×0.8
0.96 + 0.32 = 1.28

32)
Since C atoms are conserved, applying POAC for C atoms,
Moles of C in K2CO3 = Moles of C in K2Zn3[Fe(CN)6]2
1 × Moles of K2CO3 = 12 × Moles of K2Zn3[Fe(CN)6]2
(Q 1 mole of K2CO3 contains 1 moles of C)

wt. of K2Zn3[Fe(CN)6]2 =

33) The correct answer is option (D)

34) The correct answer is option (C)

35) Distance between two nearest tetrahedral voids is

36) Such vacancies are called schottky defects, and their concentration depends on
temperature:
N = Ns exp(-∆G/RT)
Where N is the number of lattice vacancies per unit volume, Ns is the number of atom sites per
unit volume. ∆G is the molar free energy of formation of vacancies. Both Frenkel and Schottky
defects in crystals are mobile, jumping from one lattice site to a neighboring with frequencies
that depend on the temperature and the strengths of the atomic forces. Diffusion in crystalline
solids is largely due to the presence and mobility of point defects; it is a thermally activated
process, just like the rates of chemical reactions.

37)

The correct answer is option (C)

38) Moles of Benzene =

Moles of Chlorobenzene =

Moles fraction of Benzene =

Moles fraction of Chlorobenzene =

Total pressure at 100oC =

(P1X1 + P2X2) = 1000 torr
∴ Boiling point = 100oC

39) Statement-1 :

Statement-2 :

40)

Electron affinity of nitrogen is negative.

Zn has pseudo inert gas configuration
 41) The correct answer is option (C)

42) ICl3 already has expanded octet hence completion of octet is not the driving force for
dimerization.

43)

Al2Cl6 has complete octet.

44)

Theory based

45)

E.A. = S > Se > Te > O

ENMulliken = 2.8 × ENPauling
EN of C : sp > sp2 > sp3

46) Molarity of I solution

Molarity of II solution

47) Fe + 2HCl → FeCl2 + H2(g)

48) The correct answer is (3)

49) Theory based

50) N(SiH3)3, O(SiH3)2

PART-3 : MATHEMATICS

51) Let f(x) = sgn([x] + [–x])

Hence f(x) is periodic with period 1.

52) 1 ≤ log2(x2 + 3x – 2) ≤ 3
⇒ 2 ≤ (x2 + 3x – 2) ≤ 8
⇒ –5 ≤ x ≤ –4 and 1 ≤ x ≤ 2

53) Given, f : R R;
f(x) = x / (1+x2)
Taking x1 = 4, x2 = (1 / 4) R
f(x1) = f(4) = 4/17
f(x2) = f(1/4) = (4/17) (x1 x2)
f is not one-one
A is true
Let y R(co-domain)
f(x) = y

Since, ,

So range
Range (Co-domain)
f is not onto.
R is true
R is not the correct explanation for A.

54) f(x) =
The first part is real outside (2, 3) and the second is real in [–2, 4] so that the domain is [–2, 2]
∪ [3, 4].

55) We have f(x) =

f(|x|) =
⇒ f(|x|) = |x| – 1, 0 ≤ |x| ≤ 2
(as –2 ≤ |x| ≤ 0 is not possible)

⇒ f(|x|) =

56) Since the period of sinx is 2π so the period of sin is = 2(n!).

The period of cos is
2(n + 1)! The period of f(x) = l.c.m.
(2(n!), 2(n + 1!) = 2(n + 1)!

57)

58) 0 ≤ {x} < 1

0 ≤ e{x} < e
ℓn 0 < ℓn (e{x}) < ℓn e
–∞ < ℓn(e{x}) < 1

and

59) (A) f(x) < 0 ⇒

(B) f(x) > 1 ⇒

(C) f(x) < 2 ⇒

(D) 1 < f(x) < 2 ⇒

60) Given f1(x) = , f2(x) = 1 – x and f3(x) =

Now x → , J(x) = = f3(x)

J(3) =

61) f(g(x)) =

(A) Domain of f(g(x)) : x – x2 ≥ 0 ⇒ x ∈ [0, 1]

(B) Range of f(g(x)) : g(x) = x2 – x + 1, x ∈ [0, 1]

⇒ g(x) =

Now, ,
∵ f(g(x)) is decreasing.

Max. value of f(g(x)) = at x =

Min. value of f(g(x)) = 0 at x = 1
(C) ∵ g(x) is many one in [0, 1]
∴ f(g(x)) is many one.
(D) Hence f(g(x)) is bounded.

62) f(x) =
∴ option (C) is correct

63) (a) f(x) =

 when x=0 then f(0) = 2
when x>0 then f(x) =

when x<0 then f(x) =

Hence, f(x) is many-one

(b) We have f(x) = , x ∈ [–1, ∞)
clearly f(–1) = e2 = f(1)
also x2 + |x| ≥ 0 ∀ x ∈ [–1, ∞]
⇒ Rf = [1, ∞)
∴ f(x) is many-one into function
(c) f(x) = |x – 1| + |x – 2| + |x – 3| + |x – 4|, x ∈ [3, 4]
∴ f(x) = (x – 1) + (x – 2) + (x – 3) – (x – 4)
= (3x – 6) – (x – 4)
f(x) = 2x – 2, which is increasing function
Rf = [4, 6]
Clearly, f(x) is one-one onto function.
(d) f(x) =
For domain, ℓn(cos(sinx)) ≥ 0
⇒ (cos(sinx)) ≥ 1
⇒ cos(sinx) = 1 ;
∴ sinx = 0
⇒ x = nπ, n ∈ I
Rf = {0}
since f(x) = 0
Thus, f(x) is many-one function

64) [x]2 = x + 2{x}

⇒ [x]2 = [x] + 3{x}

⇒ {x} =

⇒0≤ <1
2
⇒ 0 ≤ [x] – [x] < 3

⇒ [x] ∈
⇒ [x] = –1, 0, 1, 2

⇒ {x} = , 0, 0, , (respectively)
⇒x= , 0, 1,

65) f ′ (x) = 4x3 – 4x = 4x (x – 1) (x + 1)

The critical points of f are 0, –1, 1
But f(0) = 5, f(1) = 4, f(–1) = 4, f(2) = 13
So the range of f is [4, 13] and greatest value of f is at x = 2

66) (x2 – 7x + 6) (x2 – 7x + 12) + 10

Taking first and last terms together and middle terms together.
Now make quadratic in x2 – 7x = t.
We get, (t + 6) (t + 12) + 10
= t2 + 18t + 83
D = –4 < 0
Hence value is always positive ∀ x ∈ R

67) We have f(x) = x2 + 2bx + 2c2 = (x + b)2 + 2c2 – b2

⇒ min f(x) = 2c2 – b2
Also g(x) = –x2 – 2cx + b2
= b2 + c2 – (x + c)2
so max g(x) = b2 + c2
Since min f(x) > max g(x),
so 2c2 – b2 > b2 + c2

68) y = f(x)

y = f|x|

y = |f(x)|
g(x) =

69) f : A → P(A)

That means ‘a’ will connect with subset which contain element ‘a’.
Total options for 1 will be 28. (Because 28 subsets contains 1)
Similarly, for every other element
Hence, total is 28 × 28 × 28 × 28 × 28 × 28 × 28 × 28 × 28 = 272
Ans. 2 + 72 = 74

70) Total = 44
One-one = 4!
Many-one = 256 – 24 = 232
Many-one which 1 ∉ f(A)
= [Link] = 81
232 – 81 = 151

71) α4 – 3α + 1 = 0α4 = 3α – 1
α3 + β3 + γ3 + δ3

[α4βγδ + β4αγδ + γ4αβδ + δ4αβγ]

[(3α – 1)βγδ + (3β – 1)αγδ + (3γ – 1)αβδ + (3δ – 1)αβγ]

[12αβγδ – Σαβγ] = =9

72)
73)

= 2.1 + 22.2 + 23.3 + 24.4 + ... + 29.9 + 10

74) (sin–1a1 + sin–1a2) (sin–1a3 + sin–1a4) (sin–1a5 + sin–1a6) = π3

is possible when
a1 = a2 = a3 = a4 = a5 = a6 = 1
⇒

75)

2x + 3y = 23
x=1 y=7
x=4 y=5
x=7 y=3
x = 10 y=1
A B
(1, 7) 1
(4, 5) 4
(7, 3) 7
(10, 1) 10
The number of one-one functions from A to B is equal to 4!