MARKINGSCHEME
SESSION- ENDINGEXAMINATION
CLASS-XI, SUB: CHEMISTRY
[Link]. ANSWERS MARKS
1 4 Significant figures 1
2 Iodine 1
3 Ca(OH)2, C2H2 ½ + 1/2
4 +1 1
5 Basic strength increases by going down 1
6 (a) % by mass = ppm/104 = 15/104 = 15 x 10-4 ½+½
(b) m = 15 x 10-4 x 1000/119.5 x 100 = 1.225 x 10-4 ½+½
7 Mass of 1 drop of water = volume x density ½+½
= 0.1 x 1 = 0.1 g ½+½
No. of molecules = mass x Na/molar mass = 0.1 x 6.022 x 1023/18 = 3.34x1021
8 Structure and name of but-2-ene 1+1
OR
(i)Correct reaction 1
(ii)Structure of cyclopropinium ion 1
3+¿+ 2H O ¿
9 1
2
+ ¿+ H 2 O2 → 2Fe ¿
¿
(i) 2 Fe2+¿+2 H
(ii) 2 KMnO 4 +3 H 2 O2 →2 KOH +2 MnO2 +2 O2+ 2 H 2 O 1
10 (a) Isopropyl cyclohexane 1
(b) 2,3-Dimethylbutane 1
11 (a) It is average isotopic mass 1
(b) 1,2,15,17 ½ each
12 (a) Paschen, Brackett, Pfund ½
(b) V=c/λ= 3.29x1015[1/9-1/n2] 1
3x108/1285x10-9=3.29x1015[(n2-9)9n2] 1/2
n=5
13 Li2O, MgO, AlI3, SiO2, PF5 or PF3, O2F2 or OF2 ½ each
14 Sp2 hybridization change into sp 3 into diboren 1
sp3d, sp3, sp2, sp3d
½ each
15 (a) Propene will decolourise water 1
(b) Mass of OC, w= 0.15 g, mass of AgBr, w1= 0.12 g 1
AgBr ≡ Br 1
188g 80g
% of Br = 80xw1x100/188xw = 34.04%
16 (a) Presence of any foreign substance in water which leads todegrade the 1
quality so as top constitute a hazard or impair the usefulness of water.
Oxygen reaches water in two ways:
(i) Dissolution of atmospheric oxygen at water surface 1
(ii) Release of oxygen by aquatic plants.
(b) BOD takes no. of days while COD can be determined in a short time. 1
17 (a) Leads to common ion effect & increase in ionic product which precipitates 1
NaCl 1
(b) Lewis Acid- BF3, AlCl3, CO2, Na+ 1
Lewis base- NH3, Cl-
18 (a) But-2-ene 1
Reaction of ozonolysis 1
(b)Because resonance delocalization of electron it gates extra stability 1
1
19 (a) Correct example
(b) Correct balancing 1/2×4
20 (a) On the basis of Fajan’s rule Li+ ion will be with more polarization power 1
due to small size .
(b) To stop oxidation by Oxygen of atmosphere.. 1
(c) Be2+ is small in size so undergoes hydration in water. 1
BeCl2 + 4H2O [Be(H2O)4]2+ + 2Cl-
Or
(a) Be & Mg.
(b)Due to very low ionization energy. 1
(c) Due to strong polarizing action of Li+, lattice energy of Li2CO3 will be 1
lower and with strong lattice energy of Li2O formed. 1
21 K.E= ½ mv2 1
V=√(2K.E/m)
= √(2 x 4.55 x 10-25)/(9. 1 x 10-31)
103 m/s
Momentum, =mv 1
=9.1 x 10-31 x 103
= 9.1 x 10-28 kg m/s
Wavelength, λ= h/mv
= 6.629 x 10-34 .
1
9.1 x 10-31 x 103
=7.28 x 10-7 m
22 (1) During equilibrium forward and backward both reaction proceed ½
continuously. 1/2
One example
(2) 2NO(g) + Br2 2NOBr
t=0 0.0878 0.0437 0 1
teq 0.087-2x 0.0437-x 2x 1
2x=0.0518 or x= 0.0259mol
So eq. amount of Br2 = 0.0178mol and NO = 0.0352mol
23 (i) Surface tension 1
(ii) Residual unbalanced force acting on upper surface 1
(iii) Liquid state 1
(iv) Devotional attitude of general public , love to God 1
24 (a) Correct structure 2
(b) (i) Na2B4O7.10H2O heat
→
Na2B4O7 + 10 H2O
1
Na2B4O7 NaBO2 + B2O3
1
(ii) Act as weak acid in water
B(OH)3 + H2O [B(OH)4]- + H+
1
(iii) 2Al + 2NaOH + 6H2O 2Na[Al(OH)4] + 3H2
OR
2
(a) Correct resonating structures
1
(b) (i) Due to formation of inert Al2O3 at the inner surface
1
(ii) NaOH reacts with Al to produce H2 which imparts pressure.
1
(iii) Al is a good conductor of electricity and does not get affected in air.
25 (a) (b) Any two correct differences 2
(c) Cd-Ca = 0 ∆H=+3.3kcal
Cd Ca ∆H=+3.3kcal 1×3
Since [Link] changes to Ca with change =+3.3 kcal
Therefore 1.0gm changes to 3.3/12=0.275 kca
OR
(a)∆G= ∆H─ T∆S 1
=─10500 ─273×─44.1=1539.3 1
Value is positive so it is not spontsnous
(b)When ∆E=0 i.e, for isothermal process q=-w 1
(a) (i) ∆G will be negative when T∆S> ∆H 1
(ii) ∆G will be negative when T∆S< ∆H 1
(
26 (a) Because it gives a mixture of alkanes with low yieldof the required one. 1
(b) Sodium salt of ethanoic acid CH3COONa
CH3COONa + NaOH CH4 + Na2CO3 1
(heated with sodalime at 630 K) 1
(c ) Product ‘A’ will be 3-Ethylpent-2-ene, (CH3CH2)2C=CHCH3 1+1
OR
(a) It is a weak acid so does not reacts with NaOH or KOH but reacts with 1
NaNH2. 1
(b) Alkane is cyclohexane and alkene is CH3CH2CH2CH2CH=CH2 (n-Hexene) or
any other correct example. 1
Cyclohexanol is an alcohol and aliphatic in nature while phenol is aromatic.
(c ) Correct isomers with structure. Trans-isomer will have higher melting 2
point.