09-11-2025

2401CJA101001250050 JM

PHYSICS

SECTION - I

1) A disc is rolling (without slipping) on a frictionless surface. C is its centre and Q and P are two
points equidistant from C. Let VP, VQ and VC be the magnitudes of velocities of points P, Q and C

respectively, then :

(A) VQ > VC > VP

(B) VQ < VC < VP

(C)
VQ=VP, VC= VP
(D) VQ < VC > VP

2) Find moment of inertia I of the system (Axis is perpendicular to the plane passing through O) :-

(A)

(B)

(C)

(D)

3) A disc moves as shown in the figure, with a velocity of translation of 6v0 of its centre of mass and

an angular velocity of . The distance of instantaneous axis of rotation from its centre of mass is
(A) R
(B) 2R
(C) 3R
(D) 4R

4) A rod of mass m and length ℓ is hinged at one of its end A as shown in figure. A force F is applied

at a distance x from A. The acceleration of centre of mass 'a' varies with x as :

(A)

(B)

(C)

(D)

5) A ball is rolling on the ground. The ratio of speed at P and speed at Q is:
(A)
(B) 2 : 1
(C)
(D) 1 : 2

6) If point A of rod is moving with velocity v0 in right direction then speed of B is :-

(A) v0 tan θ
(B) v0 cot θ

(C)

(D)

7) Consider a body, shown in figure, consisting of two identical balls, each of mass M connected by a
light rigid rod. If an impulse J = MV is imparted to the body at one of its ends, what would be its

angular velocity:-

(A) V/L
(B) 2V/L
(C) V/3L
(D) V/4L

8) In the pulley system shown, if radii of the bigger and smaller pulley are 2 m and 1 m respectively
and the acceleration of block A is 5 m/s2 in the downward direction, then the acceleration of block B

will be:

(A) 0 m/s2
(B) 5 m/s2
(C) 10 m/s2
(D) 5/2 m/s2

9) A small mass m is attached to a massless string whose other end is fixed at P as shown in the
figure. The mass is undergoing circular motion in the x-y plane with centre at O and constant
angular speed ω. If the angular momentum of the system, calculated about O and P are denoted by

respectively, then

(A) do not vary with time

(B) varies with time while remains constant
(C) remains constant while varies with time
(D) both vary with time

10) A particle of mass m moving with velocity u makes an elastic one-dimensional collision with a
stationary particle of mass m. They are in contact for a very brief time T. Their force of interaction

0 0

increases from zero to F linearly in time . The magnitude of F is

(A)

(B)

(C)

(D)

11) Two identical balls are moving as shown. The final speed of ball A & total number of collisions

is. (All collisions are elastic)

(A) u, 3
(B) u, 4
(C) 2u, 2
(D) 2u, 3

12) A uniform solid cone has base radius R and height h. The distance of COM of cone from the
vertex is :

(A)

(B)

(C)

(D)

13) A man of mass M stands at one end of a plank of length L which lies at rest on a frictionless
surface. The man walks to the other end of the plank. If the mass of the plank is M/3, the distance
that the man moves relative to the ground is

(A) 3 L/4
(B) 4 L/5
(C) L/4
(D) none of these

14) A force is applied on the body of mass 2 kg which varies with displacement of body according to
the given graph. If initial kinetic energy is zero then final kinetic energy.

(A) 60 J
(B) 30 J
(C) 100 J
(D) 120 J

15) If a body is moving on a horizontal table with constant velocity, then equilibrium is :-

(A) stable
(B) unstable
(C) neutral
(D) none of these

16) A uniform chain of length L and mass M is lying on a smooth table and one third of its length is
hanging vertically down over the edge of the table. If g is acceleration due to gravity, the work
required to pull the hanging part on to the table is
(A) mgL

(B)

(C)

(D)

17) The potential energy of a particle varies with x according to the relation U(x) = x2 – 4 x. The
point x = 2 is a point of:

(A) stable equilibrium

(B) unstable equilibrium
(C) neutral equilibrium
(D) none of the above

18) The radius of gyration of a disc of mass 'm' and radius R about an axis through its diameter is

(A) R/2

(B)

(C)

(D) R

19) In the shown figure a cube of mass m is attached with a cylinder of same mass and radius r
through an ideal string-pulley system. The string is wound over the cylinder. If α is the angular
acceleration of the cylinder then the linear acceleration of cylinder ac and the linear acceleration of

cube A, are related as :

(A) ac = A
(B) A = ac/2
(C) ac + rα = A
(D) ac = A + rα

20)

Moment of inertia(kg m2) of solid hemisphere about axis is AA' through center of base shown is
(mass = 5kg, radius= 2m)
(A) 8 kgm2
(B) 4 kgm2
(C) 2 kgm2
(D) 1 kgm2

SECTION - II

1) A uniform cubical block of side 8m is at rest on an inclined plane. Find distance (in meter) of

normal reaction from the centre of block.

2) In the figure shown, what magnitude of force F (in N) applied horizontally at the axle of the wheel
of mass 14 kg, is sufficient to raise the wheel over a step of height h = 1 m ? Take r = 5 m as the

radius. Assuming no slipping over the edge of step.

3) The potential energy (in joules) function of a particle in a region of space is given as : U = (2x2 +
3y3 + 2z); Here x, y and z are in metres. Find the magnitude of x component of force (in newton)
acting on the particle at point P (1m, 2m, 3m).

4) A point mass of 0.5 kg is moving along x-axis as x = t2 where, x is in meters and t is in seconds.
Find the work done (in J) by all the forces acting on the body during the time interval [ 0, 2s].

5) A small cube of mass m << M slides down a smooth circular path of radius R cut into a larger
block of M, as shown in the figure. M is fixed on a table, and cube move without friction. The blocks
are initially at rest, and m starts from the top of the path. The velocity v of the cube as it leaves the
block is . Find the value of n?

CHEMISTRY

SECTION - I

1) In the coordination compound, K4[Ni (CN)6], the oxidation state of nickel is :-

(A) +1
(B) +2
(C) –1
(D) 0

2) Which reaction does not represent autoredox or disproportionation :-

– – –
(A) Cl2 + OH —→ Cl + ClO3 + H2O
(B) 2H2O2—→ H2O + O2
(C) 2Cu+ —→ Cu+2 + Cu
(D) (NH4)2Cr2O7 —→ N2 + Cr2O3 + 4H2O

3) 50 ml of 0.5 M oxalic acid neutralizes 25 ml of NaOH. Then the amount of NaOH in 50 ml -

(A) 80 g
(B) 4 g
(C) 5 g
(D) 40 g

4) In acidic medium, K2Cr2O7 shows oxidising action as represented in the half reaction

X, Y, Z and A are respectively are :

(A) 8, 6, 4 and Cr2O3

(B) 14, 7, 6 and Cr3+
(C) 8, 4, 6 and Cr2O3
(D) 14, 6, 7 and Cr3+

5) The exact volumes of 1 M NaOH solution required to neutralise 50 mL of 1 M H3PO3 solution and
100 mL of 2 M H3PO2 solution, respectively, are :
(A) 100 mL and 100 mL
(B) 100 mL and 50 mL
(C) 100 mL and 200 mL
(D) 50 mL and 50 mL

6) Equivalent weight of NH3 in the change N2 → NH3 is

(A)

(B) 17

(C)

(D)

7) In the reaction, 2Na2S2O3 + I2 = Na2S4O6 + 2NaI, I2 acts as :

(A) reducing agent

(B) oxidising agent
(C) oxidising as well as reducing agent
(D) none of the above

8)

In equation

equivalent weight of H2S (molecular weight of H2S = 34) is

(A) 68
(B) 34
(C) 17
(D) 16

9)

The reaction is balanced if:-

5H2O2 + xBrO2 + 2OH– → xBr– +yO2 + 6H2O;

(A) x = 5, y = 2
(B) x= 2, y = 5
(C) x = 4, y = 10
(D) x = 5, y = 5

10) In the ionic equation 2K+BrO3– + 12H+ + 10e– —→ Br2 + 6H2O + 2K+, the equivalent weight of
KBrO3 will be:
(where M = molecular weight of KBrO3)

(A) M/5
(B) M/2
(C) M/6
(D) M/4

11)

Correct IUPAC name of is:

(A) Benzamide
(B) Benzene carbonyl amine
(C) Benzene carboxamide
(D) Benzene carbyl amine

12)

Double bond equivalent in cyanobenzene is :

(A) 4
(B) 5
(C) 6
(D) 7

13) One among the following is the correct IUPAC name of the compound

(A) N-Formyl aminoethane

(B) N-Ethyl formyl amine
(C) N-Ethyl methanamide
(D) Ethylamino methanal

14) Which of the following compound is wrongly named ?

(A)
; 2-Chloro pentanoic acid

(B)
; 2-Methyl hex-3-enoic acid
(C) CH3CH2CH=CHCOCH3 ; Hex-3-en-2-one

(D)
; 4-Methyl pentanal
15) The IUPAC name of the following structure (CH3)C.C.C.(CH3)CH(CH3) is:

(A) 3-Methylhex-4-yn-2-ene
(B) 3-Methylhex-2-en-4-yne
(C) 4-Methylhex-4-en-4-yne
(D) All are correct

16) Correct IUPAC name for the given compound

(A) 3-Methoxy-5-bromo benzene carbaldehyde

(B) 3-Formyl-5-bromo phenyl methyl ether
(C) 3-Formyl-5-bromo-1- methoxy benzene
(D) 3-Bromo-5-methoxy benzenecarbadehyde

17) Correct IUPAC name of compound is :

(A) 1,2-dimethyl cyclobutene

(B) 2,3-dimethyl cyclobutene
(C) 1,2-dimethyl cyclobut-2-ene
(D) 1,4-dimethyl cyclobutene

18) Which is correct statement for inductive effect?

(A) It is permanent effect

(B) It is temporary effect
(C) It involves delocalisation of σ-bond
(D) It involves delocalisation of π-bond

19)

Arrange in decreasing stability order of carbanion :

(a)

(b)

(c)
(d)

(A) a > b > c > d

(B) b > a > c > d
(C) c > d > a > b
(D) d > c > b > a

20) Decreasing order of stability of carbocation will be:

(1) (2)

(3) (4)

(A) 1 > 2 > 3 > 4

(B) 3 > 1 > 2 > 4
(C) 4 > 3 > 1 > 2
(D) 4 > 1 > 3 > 2

SECTION - II

1) 5.00 mL of 0.10 M oxalic acid solution taken in a conical flask is titrated against NaOH from a
burette using phenolphthalein indicator. The volume of NaOH required for the appearance of
permanent faint pink color is tabulated below for five experiments. What is the concentration, in
molarity, of the NaOH solution ?

Exp. No. Vol. of NaOH (ml)

1 12.5

2 10.5

3 9

4 9

5 9

2) 2 MnO4– + bC2O42– + c H+ → x Mn2+ +y CO2 + z H2O

If the above equation is balanced with integer coefficients, the value of c is _______.
(Round off to the Nearest Integer).

3) The volume of 3 M Ba(OH)2 solution required to neutralize completely 120 mL of 1.5 M H3PO4
solution is.

4) How many of the following are –I-effect showing groups.

(a) –Cl (b) –CH3 (c) –O– (d) –COO–
(e) –CMe3 (f) –F (g) –NH2 (h) –OH

(i) –NO2 (j) –N=O (k)

5) Number of carbon atoms in the principal carbon chain of the given compound in its IUPAC name

will be.

MATHEMATICS

SECTION - I

1) If the lines 2x + 3y + 1 = 0 and 3x – y – 4 = 0, lie along diameters of a circle of circumference

10π, then the equation of the circle is

(A) x2 + y2 + 2x + 2y – 23 = 0
(B) x2 + y2 – 2x – 2y – 23 = 0
(C) x2 + y2 – 2x + 2y – 23 = 0
(D) x2 + y2 + 2x – 2y – 23 = 0

2) The equation of the circle which passes through (1, 0) and (0, 1) and has its radius as small as
possible, is :-

(A) x2 + y2 – 2x – 2y + 1 = 0
(B) x2 + y2 – x – y = 0
(C) 2x2 + 2y2 – 3x – 3y + 1 = 0
(D) x2 + y2 – 3x – 3y + 2 = 0

3) If the lines 3x – 4y + 10 = 0 and 3x – 4y –15 = 0 are tangents to a circle, then the radius of
the circle is :-

(A) 5
(B) 25/2
(C) 5/2
(D) None of these

4) If the circle x2 + y2 = 4 and

 x2 + y2 + 6x + λy + λ = 0
intersect orthogonally, then λ is

(A) 4
(B) –4
(C) 6
(D) –6

5) If the circles x2 + y2 + x + c = 0 and the x2 + y2 + y + c = 0 touch each other then the value of |c|
is

(A)

(B)

(C)

(D) 1

6) The number of integral values of 'c' for which the circle x2 + y2 – 4x – 6y + c = 0 does not touch or
intersect the coordinate axes and point (2, 2) lies inside the circle is

(A) 2
(B) 3
(C) 4
(D) 5

7)

The number of common tangents to the circle x2 + y2 – 4x – 6y – 12 = 0 and x2 + y2 + 6x + 18y + 26

= 0, is

(A) 3
(B) 4
(C) 1
(D) 2

8) If the ordered pair (x, y) satisfies x2 + y2 = 9, then the largest value of the expression x2 + 2y2 + 4x
equals

(A) 22
(B) 27
(C) 24
(D) 36

9) The equation of the circle passing through the point (–1, –3) and touching the line 4x + 3y – 12 =
0 at the point (3, 0) is :-
(A) x2 + y2 – 2x + 3y – 3 = 0
(B) x2 + y2 + 2x – 3y – 5 = 0
(C) 2x2 + 2y2 – 2x + 5y – 8 = 0
(D) None of these

10) The equation of the bisector of the angle between the lines 4x + 3y – 6 = 0 and 5x + 12y + 9 = 0
which contains the origin, is

(A) 7x + 9y – 3 = 0
(B) 9x – 7y + 3 = 0
(C) 7x – 9y + 3 = 0
(D) 7x – 9y – 3 = 0

11) If (α,1–α) falls inside the angle made by the line and y = 3x, x > 0,, then α belongs
to

(A)

(B) (3,∞)

(C)

(D) (2,3)

12) Locus of the point P(2t2 + 2, 4t + 3) where t is a variable is

(A) y2 = 8x
(B) (y – 3)2 = 8(x – 2)
(C) (x – 3)2 = 8(y – 2)
(D) y – 3 = 2(x – 2)

13) Let P be any moving point on the circle x2 + y2 – 2x = 1, and AB be the chord of contact of pair of
tangents drawn from this point to the circle x2 + y2 – 2x = 0. The locus of the circumcentre of the
triangle CAB (C being centre of the circles is)

(A) 2x2 + 2y2 – 4x + 1 = 0

(B) x2 + y2 – 4x + 2 = 0
(C) x2 + y2 – 4x + 1 = 0
(D) 2x2 + 2y2 – 4x + 3 = 0

14) If p and q are the lengths of the perpendiculars from the origin on the lines, xcosecα – ysecα =
kcot2α and xsinα + ycosα = ksin2α respectively, then k2 is equal to :

(A) 4p2 + q2
(B) 2p2 + q2
(C) p2 + 2q2
(D) p2 + 4q2

15) A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct points P and
Q. If O is the origin and the rectangle OPRQ is completed, then the locus of R is :

(A) 2x + 3y = xy
(B) 3x + 2y = xy
(C) 3x + 2y = 6xy
(D) 3x + 2y = 6

16) Locus of point of intersection of two mutually perpendicular lines one belonging to the family (3x
– 4y + 1) + α(x + y – 2) = 0 & other belonging to the family (4x + 3y – 14) + β(2x + 5y) = 0 (α, β
being parameters) is given by -

(A) x2 + y2 – 6x + y + 3 = 0
(B) x2 + 6x + y + 3 = 0

(C)

(D) 3x + 4y = 11

17) Distance of the point (2, 5) from the line 3x + y + 4 = 0 measured parallel to the line 3x – 4y + 8
= 0 is -

(A)

(B)

(C) 5
(D) None of these

18) If P(6, 1) be the orthocentre of the triangle whose vertices are A(5, –2), B(8, 3) and C(h, k), then
the point C lies on the circle.

(A) x2 + y2 – 65 = 0
(B) x2 + y2 – 74 = 0
(C) x2 + y2 – 61 = 0
(D) x2 + y2 – 52 = 0

19) If the equation x2 + kxy + y2 – 5x – 7y + 6 = 0 represents a pair of straight lines, then the value
of k is –

(A)

(B)

(C)
(D)

20) Line x + αy =1 cuts the circle x2 + y2 – 4x–2y +1= 0 at two points A and B such that Chord AB
subtends an angle of 90° at origin then sum of possible values of α is

(A) –1
(B) 1
(C) 2
(D) 4

SECTION - II

1) If xy – 2x – 3y + 6 = 0 are pair of normals to a circle which intersects the circle x2 + y2 – 2x – 2y –

2 = 0 orthogonally and having radius r, then is equal to

2) A line segment through a point P cuts a given circle in 2 points A & B, such that PA = 16 & PB =
9, find the length of tangent from points to the circle

3) The length of the common chord of the circle

x2 + y2 + 2x + 3y + 1 = 0 and x2 + y2 + 4x + 3y + 2 = 0 is

4) The co-ordinates of a point P(p, q) on the line 4x – y = 10 such that |PA – PB| is maximum where A

is (2, 3) and B is (1, –2), then the absolute value of is :

5) Consider a family of lines (2k + 1)x + (3k – 2)y + (3 – 8k) = 0 where k ∈ R. The minimum area of
the triangle formed by a line of given family with positive semi axes is equal to
 ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D C C A B A D C B D C C A C D A A D A

SECTION - II

Q. 21 22 23 24 25
A. 3.00 105.00 4.00 4.00 2.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B D B D C D B C B A C C C B B D D A C D

SECTION - II

Q. 46 47 48 49 50
A. 0.11 16.00 90.00 7.00 5.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B C A B A A A A A A B A A B A C A C C

SECTION - II

Q. 71 72 73 74 75
A. 0.25 12.00 2.82 to 2.83 7.33 or 7.34 4.00
 SOLUTIONS

PHYSICS

1) Question Explanation: The problem asks to determine the relationship between the
velocities of points P, Q and C on a disc rolling without slipping.

Concept: This question is based on Rolling motion without slipping

Solution:
For the disc rolling without slipping, distances OP < OC < OQ angular velocity ω is same.
Linear velocity v = rω

∴ VP < VC < VQ or VQ > VC > VP

​
Final Answer: Option (1)

2) Question Explanation: The problem asks to find the moment of inertia I of the system
about an axis perpendicular to the plane and passing through point O. The system consists of
two rods, each of mass m and length l.

Concept: This question is based on Moment of inertia.

Solution:
I = I1 + I2

​
2 2 2
where x = l + l /4

I= ml2

Final Answer: Option (4)

3) Question Explanation: The problem asks for the distance of the instantaneous axis of
rotation (IAR) from the centre of mass of a disc. The disc has a transitional velocity of 6V0 and
an angular velocity of 2V0/R

Concept: This question is based on Instantaneous axis of rotation

​Solution:
Instantaneous axis of rotation lies above the centre of mass where v – ωr = 0
⇒

Final Answer: Option (3)

4) Explanation : We are given that a rod is free to rotate about the one of its end. We have to
calculate the acceleration of centre of mass in terms of x.
Concept : Torque and its angular acceleration.
Solution : Torque about hinge point 'A'

This is net

∴ Fx =

So, the acceleration of centre of mass of rod =

⇒
So, the graph between acm v/s x should be straight line.

Final Answer : Option (3) is correct answer.

5) Question Explanation:
The problem asks to find the ratio of speeds at point P and point Q for a ball rolling on the
ground without slipping.

Concept:
This question is based on concept of instantaneous centre of rotation.

Solution:
Final Answer:
The correct option is (1)

6)
v0 cos θ = v1 sin θ
v1 = v0 cot θ

7) Given system of two particles will rotate about its centre of mass.

Initial angular momentum = MV

Final angular momentum = 2Iω = 2M ω

By the law of conservation of angular momentum

8) Given

9) The torque about O is zero, but about P is non-zero.

As must be a variable.

10)

Explain the question : We have to find the magnitude F0 in graph where F-t graph is given.
Concept : This question is based on collision
Solution :-
for one dimensional head on elastic collision the blocks interchange their velocities
Final answer : option (2)

11)

Explain Question :
The problem involving elastic collisions between two identical balls and a wall. The problem
asks for the final speed of ball A and the total number of collisions.

Concept :
This question is based on collision (Elastic).

Solution :

After Ist collision between B & wall

After IInd collision between A & B

After IIIrd collision between B & wall

Final answer : (4)

12) Explanation Question:

Calculate the center of mass distance from the vertex of solid cone.
Concept:
This question is based on Calculation of center of mass.
Solution:
• Taking a disc of by thickness at a height y.

By similar Δ ...(1)
Let the mass of solid cone be m

∴ dm =
Put value of r from eqn(1)

dm =
Now yc =

yc =
Final Answer: (3)

13)
Δrcm = 0
m1Δr1 + m2Δr2 = 0

Distance moved by centre of mass

Therefore distance move by man w.r.t. ground

14) Question Explanation: Find the final speed of a body given the F−x graph and initial
kinetic energy.
Concept: Work-Energy Theorem (Wnet​=ΔKE).
Solution: KEfinal​=Area. Area is 100J.

15) Question Explanation: Determine the type of equilibrium for a body moving on a
horizontal table with constant velocity.
Concept: Equilibrium (Constant Velocity).
Solution:
\( F_{\text {net }}=0(\mathrm{~W}=0) . \) Neutral equilibrium.

16)

Mass of hanging chain =

17)

Explanation : In this question for expression of potential energy is given and it asks to find
the type of equilibrium at x = 2.
Concept : This question is based on potential energy.
Solution :
U(x) = x2 – 4x

F=
at eqm ΣF = 0
So –(2x – 4) = 0
x=2

at x =2, U is minimum.
Hence stable equilibrium.

Final Answer

The correct option is (1)

18)

19)

Ans:- (D)

ac – rα = A
ac = A + rα

20)

21) τcm = 0

22) F(r – h) > mg

 23) U = (2x2 + 3y3 + 2z)

Fx = –4x

24) m = 0.5 kg
x = (t2 + 2t)m
v = (2t + 2)m/s
a = 2 m/s2
F = ma = 2 × 0.5 = 1N
∵ F= constant

= 1 × (x2 – x0) × cos0

= 1 × (22 + 2 × 2 – 0)
=4+4
W = 8J

25) Let v1 and v2 be the final velocities of the small and large blocks with respect to the
ground.
Momentum conservation : mv1 = Mv2
Energy conservation :

After solving,

CHEMISTRY

26)

Question Explanation: Determine the oxidation state of nickel in the coordination compound.
Concept: Oxidation State in Coordination Compounds.
Solution: In the coordination compound K4​[Ni(CN)6​], the oxidation state of Ni is calculated by
balancing the charge contribution from the potassium ions (K) and the cyano ligands (CN).
Calculation:

A. Ion Components: The compound ionizes as 4K+ and [Ni(CN)6​]4−.

B. Ligand Charge: The cyano ligand (CN−) has a charge of −1.

 C. Calculate Ni O.S. (x): For the complex ion [Ni(CN)6​]4−:
x + 6(−1) = −4
x − 6 = −4
x = +2

Final Answer: +2

27)

Question Explanation: Identify the reaction that is NOT a disproportionation reaction.

Concept: Disproportionation Reaction (Autoredox).

Solution: A disproportionation reaction involves a single element changing to both a higher

and a lower oxidation state. Find the one where two different elements change O.S.
(intermolecular redox) or no O.S. change occurs (non-redox).
0 0
A. Cl2 + OH– ⟶ Cl– + ClO3– + H2O:Cl → Cl–1 (Reduced) and Cl → Cl+5 (Oxidized). (Disproportionation)

0
B. 2H2O2 ⟶ H2O + O2:O–1 → O–2 (Reduced) and O–1 → O (Oxidized). (Disproportionation)

0
C. 2Cu+ ⟶ Cu+2 + Cu:Cu+1 → Cu+2 (Oxidized) and Cu+1 → Cu (Reduced). (Disproportionation)

0
D. (NH4)2Cr2O7 ⟶ N2 + Cr2O3 + 4H2O:N–3 → N (Oxidized) and Cr+6 → Cr+3 (Reduced). (Intramolecular
Redox/Decomposition)

Final Answer: (NH4)2Cr2O7 ⟶ N2 + Cr2O3 + 4H2O

28) Question Explanation: Calculate the mass of NaOH in 50 mL of the solution, using
titration data with oxalic acid.

Concept: Acid-Base Titration (Law of Equivalence).

Solution: Equate the equivalents of oxalic acid (H2​C2​O4​, n = 2) and NaOH (n = 1) to find the
molarity of NaOH. Then calculate the mass in 50 mL.

Molarity of NaOH(MNaOH):

MAcid VAcid nAcid = MBase VBase nBase

0.5M × 50 mL × 2 = MNaOH × 25 mL × 1 ⟹ MNaOH = 2M
Mass of NaOH in 50 mL: Molar MassNaOH = 40 g/mol.
Mass = M × VL × MNaOH = 2M × 0.050 L × 40 g/mol = 4 g

Final Answer: 4 g

29) The balanced reaction is,

X = 14
Y=6
A=7

30) H3PO3 + 2NaOH → Na2HPO3 + 2H2O

50 ml 1M
1M V=?

⇒
H3PO2 + 2NaOH → NaH2PO3 + H2O
100 ml 1M
2M V=?

31) Question Explanation: Calculate the equivalent weight of NH3​ in the reaction N2​ → NH3.

Concept: Equivalent Weight in Redox Reaction.

Solution:

nf = 3

32) Question Explanation: Determine the role of I2​ in its reaction with Na2​S2​O3​.

Concept: Oxidizing and Reducing Agents in Redox Reaction.

Solution:
2Na2 S2O3 +
nf = 2 oxidising agent

33)

Ans. (C)
C is the correct answer

34) 5H2O2 + 2BrO2 + 2OH– → 2Br– + 5O2 + 6H2O;

35)
∴ (V.f.) BrO3– = 5
∴ Eq wt = M/5
36)

Ans. (C)
C is the correct answer

37)

Ans. (C)
C is the correct answer

38) Explain the question : Naming a secondary amide.

Concept : This question is based on IUPAC nomenclature of amides.
Solution : For secondary amides, the alkyl group attached to the nitrogen atom is treated as a
substituent, indicated by the prefix "N–". The parent amide is named from the carboxylic acid
part.

Acid part : methanoic acid (methanamide)

Substituent on N: ethyl. Name : N-Ethylmethanamide
Final answer : 3

39)
2 Methyl pent-3-ynoic acid

40) OR

41)

Ans. (D)
D is the correct answer

42)
Lowest locant is (1, 4) instead of (2, 3)

43)

Ans. (A)
A is the correct answer
 44)

Ans. (C)
C is the correct answer

45)

Ans. (D)
D is the correct answer

46) Volume of NaOH consumed = 9N

Eq. of H2C2O4 = Eq. of NaOH

5 × 10–3 × 0.1 × 2 = 9 × 10–3 × x × 1

x = = 0.11 molar
molarity of NaOH = 0.11 molar

47)

+16H+
Coff. of H+ = 16

48)

N=(Basicity or acidity)×M

49) (a), (f), (g), (h), (i), (j), (k)

50)

Ans. (5.00)
(5.00) is the correct answer

MATHEMATICS

51) Centre of circle is the point of intersection of the given lines (1, –1)
Here 2πr = 10π
r=5
Hence the cirlce is (x – 1)2 + (y + 1)2 = 25

52) The radius will be minimum, If the given points are the end points of a diameter.
53) Given lines are parallel
Hence dist. between lines = diameter of circle

Hence r = (dist. between lines)

= =

54)

55) Ans. (2)

Radical axis is x – y = 0
It is common tangent

56)

So, 2 values of (c)

57)

C1(2, 3) and C2(–3, –9)

r1 = = 5, r2 = =8
C1C2 = = 13
C1C2 = r1 + r2 touching externally.
⇒ 3 common tangents

58)

Expression = x2 + 2y2 + 4x = 9 + y2 + 4x
= 9 + 9sin2q + 4(3 cosq) = 9 + 9(1 – cos2q) + 12cosq
= 18 – 3[3cos2 q – 4cos q]

= 18 – 3 × 3
= 18 – 9

= 18 + 4 – 9 = 22 – 9
Clearly maximum value = 22

59) Let the equation be x2 + y2 + 2gx + 2fy + c = 0

it passes through (–1, –3) and (3, 0) therefore
10 – 2g – 6f + c = 0 ....(i)
9 + 6g + c = 0 ....(ii)
slope of tangent = –4/3

⇒ 3g – 4f + 9 = 0 ....(iii)
solving g = –1, f = 3/2, c = –3

60) Equation of bisector of the angle between the lines is

it's contain origin, we take '+' sign

13 (– 4x – 3y + 6) = 5(5x + 12y + 9)
⇒ 77x + 99y – 33 = 0
⇒ 7x + 9y – 3 = 0.

61) Ans. (1)

62) Solution:
P(2t2 +2, 4t + 3) = P (h, k)
h = 2t2 + 2, k = 4t + 3

⇒ (y – 3)2 = 8(x – 2)

Final Answer:
option (2)
63)

64) First line is

⇒ xcosα – ysinα =

⇒ ...(i)
second line is xsinα + ycosα = ksin2α
⇒ q = |ksin2α| ...(ii)
Hence 4p2 + q2 = k2 (From (i) & (ii))

65) Equation of PQ is

passes through (2, 3) so

So locus
3x + 2y = xy

66) For the first family, lines always pass through (1, 1) & for the second family, lines always
pass through (5, –2).
Hence locus of point of intersection of perpendicular lines is a circle whose diametric ends are
(1, 1) & (5, –2).
i.e. (x – 1)(x – 5) + (y – 1)(y + 2) = 0
or x2 + y2 – 6x + y + 3 = 0
67)

Equation of AB : -

∴ Solve 3x + y + 4 = 0
3x – 4y + 14 = 0

B (x,y) = (–2, 2)
⇒

68)

Slope of AD = 3

Slope of BC
equation of BC = 3y + x – 17 = 0
slope of BE = 1
Slope of AC = –1
equation of AC is x + y – 3 = 0
point C is (–4, 7)

69) Δ must be zero

70)

Homogenize x2 + y2 – 4x –2y + 1= 0 with line x + αy=1 gives

x2 + y2 –4x (x + αy) –2y (x + αy)+ (x + αy)2 = 0
For angle to be 90°, we need coeff of x2 + coeff of y2 = 0
(1– 4 +1) + (1–2α +α2) =0
⇒α2 –2α–1= 0
Sum = 2

71)

x(y – 2) – 3(y – 2) = 0
x = 3; y = 2
centre (3, 2)
x2 + y2 – 6x – 4y + c = 0
x2 + y2 – 2x – 2y – 2 = 0
2(3 + 2) = C – 2
C = 12
x2 + y2 – 6x – 4y + 12 = 0

72) As we know

[Link] = PT2 = (Length of tangent)2

Length of tangent = = 12

73)

common chord : S1 – S2 = 0

length =

74)
∵ |PA – PB| < AB {∵ In ΔABP}
⇒ |PA – PB|max. = AB {when A, B, P are collinear}
75) ∵ (2k + 1)x + (3k – 2)y + (3 – 8k) = 0
⇒ (x – 2y + 3) + k(2x + 3y – 8) = 0
⇒ L1 + λ L2 =0

equation of line : y – 2 = m(x – 1)

∴ X-intercept = & Y-intercept = 2 – m

∴ (Area)least = [4 + 4] = 4 Ans.