07-06-2026

7501CJA101001260015 JA

PHYSICS

SECTION-I

1)

Velocity of a particle depend on time t according to equation,

V= + bt + The a, b, c and d represents the following quantities in order :-

(A) Distance, distance, acceleration, time
(B) Acceleration, distance, time, distance
(C) Acceleration, distance, distance, time
(D) Distance, acceleration, distance, time

2) If time (t), velocity (v), and angular momentum ( ) are taken as the fundamental units. Then the
dimension of mass (m) in terms of t, v and ℓ is :

(A) [t–1 v1 –2
]
1 2 –1
(B) [t v ]
(C) [t–2 v–1 1
]
(D) [t–1 v–2 1
]

3) If y = sin(x) + ln(x2) + e2x then will be :

(A)
cos x + + e2x

(B)
cos x + + 2e2x

(C)
–cos x + + e2x

(D)
–cos x – + 2e2x

4) Curve of function y = sinx is drawn in figure. Which of the

following is correct about curve :
(A) At x = x1 the slope is +ve and rate of change of slope is also +ve.
(B) At x = x2 the slope is zero and rate of change of slope is also zero.
(C) At x = x3 the slope is zero and rate of change of slope is +ve.
(D) None of these

5) Approx value of is

(A) 1.01
(B) 1.09
(C) 0.99
(D) 0.97

6) The sum of magnitude of two forces acting at a point is 16 N. If the resultant force is 8 N and its
direction is perpendicular the smaller force, then the forces are:

(A) 6 N & 10 N
(B) 8 N & 8N
(C) 4 N & 12 N
(D) 2 N & 14 N

7) ABCD is a parallelogram. Choose the correct option :

(A)

(B)

(C)

(D)

8) If = 4 units , = 10 units & •( + ) = 20 units, find

(A)
(B)
(C) 21 units
(D) zero
9)

Consider the vector diagram showing three vectors lying x-y plane. Then is :

(A)

(B)

(C)

(D)

10) The resultant of two forces 3p and 2p is R. If the first force is doubled keeping same direction,
then the resultant is also doubled. Find the angle between two forces.

(A) 60°
(B) 120°
(C) 150°
(D) 90°

11) The position (x) of a particle moving along x-axis varies with time (t) as shown in figure. The

average acceleration of particle in time interval t = 0 to t = 8 s is :-

(A) 3 m/s2
(B) –5 m/s2
(C) –4 m/s2
(D) 2.5 m/s2

12) Velocity of an object in rectilinear motion is given as function of time by v = 4t – 3t2, where v is
in m/s and t is in seconds. Its average velocity over the time interval from t = 0 s to t = 2 s is

(A) 0 m/s
(B) –1 m/s
(C) 2 m/s
(D) determinable, if initial position is known

13) An object moves with speed v1, v2, and v3 along a line segment AB, BC and CD respectively as
shown in figure. Where AB = BC and AD = 3 AB, then average speed of the object will be :

(A)

(B)

(C)

(D)

14) Figure below shows the velocity-time (v – t) graph of a particle moving along a straight line.
After what time the particle acquires zero displacement?

(A)
(B)
(C)
(D) 6 s

15) A projectile can have the same range R for two angles of projection. If t1​ and t2​ be the times of
flight in two cases, then the product of two times of flight is:

2
(A) t1​t2​ ∝ R
(B) t1​t2​ ∝ R

(C)

(D)

16) The equation of projectile is . The horizontal range is :

(A) 16 m
(B) 8 m
(C) 3.2 m
(D) 12.8 m

17)

A particle is moving along x-axis. Its position is given by x = (where t is time in

second), then :-

List-I List-II
(P) for 0 < t < 1 second (1) particle accelerates
(Q) for 1 < t < 2 second (2) particle retards
(R) for t > 2 second (3) particle is moving towards origin
(S) for t = 1 second (4) particle changes its direction of motion
(A) P → 1;Q → 2;R → 4;S → 3
(B) P → 4;Q → 2;R → 1;S → 3
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 2;Q → 3;R → 4;S → 1

18) A ball is hit by a batsman at an angle of 37∘ as shown in figure. The man standing at P should run
at what minimum velocity so that he catches the ball before it strikes the ground. Assume that
height of man is negligible in comparison to maximum height of projectile.

(A) 3 ms–1
(B) 5 ms–1
(C) 9 ms–1
(D) 12 ms–1

19) The velocity of a body depends on time according to the equation v = 20 + 0.1t2. The body is
undergoing
(A) Uniform acceleration
(B) Uniform retardation
(C) Non-uniform acceleration
(D) Zero acceleration

20) A particle is projected as shown in figure. If the particle strikes at the wall after 1 sec, then the

ratio will be (approximately)

(A) 1
(B) 1.6
(C) 2.6
(D) 3

SECTION-II

1) A projectile is fired into the air from the edge of a 100 m high cliff at an angle of 37° above the
horizontal. The projectile hits a target 400 m away from the base of the cliff. Initial velocity of the
projectile is v0 then = 625 × a find the value of a. (Neglect air friction and assume x-axis to be

horizontal and y-axis to be vertical).

2) A car moving at 100 m/s comes to rest in 16 m after brakes are applied, if same car moving at 50
m/s then it may come to rest after moving a distance (in m) equal to

3) Position of a particle moving along x axis is given by x = t2 – 4t + 4 meter, the distance travelled
by particle from t = 0 to t = 3 sec is n meter. The value of n is.

4) A particle A is thrown with initial velocity 5 m/s along a frictionless inclined plane of inclination β.
Another particle B is thrown from the same point with initial velocity 10 m/s at an angle α with the
horizontal at the same moment when A is thrown. Both the particle meet again on the inclined plane.

The value of is

5) ABC is an isosceles triangle, right angled at A. Forces of magnitude , 5 and 6N act along
 respectively. The magnitude of their resultant force in N is.

CHEMISTRY

SECTION-I

1) The shortest wavelength in the Lyman series is 911.6 Å. Then the longest wavelength in the
Lyman series is :-

(A) 1215 Å
(B) ∞
(C) 2430 Å
(D) 600 Å

2) The Difference in wavelength of first and last line of lyman series in emission spectrum of He+
would be :

(A)

(B)

(C)

(D)

3) Volume contraction during complete combustion of 30 ml of toluene as per reaction.

(g) + O2(g) → CO2(g) + H2O(l)

(A) 30 ml
(B) 90 ml
(C) 60 ml
(D) 150 ml

4) Find the wavelength of 2nd line of Balmer series of Li2+. [Given : RH = Rydberg constant]

(A)

(B)

(C)
(D)

5) Choose the incorrect statement:

–
(A) The order of velocity of an e is v1 > v2 > v3 > v4 (vn : where n is orbit number for a given atom)
(B) The order of total energy is E1 < E2 < E3 < E4 (En: where n is orbit number for a given atom)
The order of frequency of revolution of electron in H, He+, Li+2, Be3+ species in second Bohr
(C)
orbit is Be3+ < Li+2 < He+ < H
(D) The order of Bohr radius is r1 < r2 < r3 < r4 (rn: where n is orbit number for a given atom)

6) The correct curve for 3p orbital is:

(A)

(B)

(C)

(D)

7) The uncertainty in position of an electron is equal to its de-broglie wavelength. The minimum
percentage error in its measurement of velocity under this circumtance will be approximately:-

(A) 4
(B) 8
(C) 22
(D) 18

8) According to graph,

Where, R2 = Radial probability density r = distance from the nucleus. There is no nodal plane in the
given orbital. Then orbital is:

(A) 3s
(B) 4s
(C)
(D)

9) The ratio of de-broglie wavelength associated with electron & proton i.e. moving with same
velocity -

(A)

(B) 1840

(C)

(D)
3680

10) 0.8 gm of BeCl2 added to water forming 500 mL solution. 20 mL of this solution is taken and
diluted 10 folds. Find moles of Cl– ions in 2 mL of the finally diluted solution :
(Atomic weight Be = 9,Cl = 35.5)

(A) 2 × 10–6
(B) 4 × 10–6
(C) 8 × 10–6
(D) 1 × 10–6

11) What volume of 6.0 M H2SO4 should be mixed with 10 L of 1.0 M H2SO4 to make 20 L of 3.0 M
H2SO4 upon dilution to volume ?

(A) 1.7 L
(B) 5.0 L
(C) 8.3 L
(D) 10 L
12) What volume of and solutions of NaOH should be mixed to prepare 1 L of NaOH solution
whose 300 mL is completely neutralized by 10 mL of 0.5 M H3PO4 solution.[Assuming 100%
dissociation]

(A) 750 mL
(B) 500 mL
(C) 150 mL
(D) none

13) For a reaction aA + bB → cC + dD. If 'x' moles of A and 'y' moles of B are taken initially then
select the incorrect statement.

(A)
If , then 'B' is Limiting Reagent

(B)
If , then 'A' is Limiting Reagent

(C)
there is NO limiting Reagent

(D)
then 'A' is Limiting Reagent

14) Which of the following contains the largest number of atoms -

(A) 11g of CO2

(B) 4g of H2
(C) 5g of NH3
(D) 8g of SO2

15) 10 ml of H2SO4 is mixed with 40 ml of H2SO4. The pH of the resulting solution is [pH =
–log H+]

(A) 1
(B) 2
(C) 2.3
(D) none of these

16) Consider the given reaction

H4P2O7 + 2NaOH → Na2H2P2O7 + 2H2O If 534 gm of H4P2O7 is reacted with 30 × 1023 molecules of
NaOH then total number of molecules produced in the product is
Given that : Atomic masses : P = 31, O = 16, H = 1

(A) 2.5 × NA
(B) 5 × NA
(C) 7.5 × NA
(D) 75 × NA

17) What is the distance of closest approach of an α-particle with energy 2.5 MeV being scattered by
a gold nucleus (Z = 79) ?

(A) 9.1 × 10–13 meter

(B) 9.1 × 10–14 meter
(C) 9.1 × 10–15 meter
(D) 9.1 × 10–16 meter

18) Which of the following is not a conclusion of Rutherford's atomic model -

(A) Most of the part inside an atom is empty

(B) Almost all mass of an atom is concentrated in the nucleus.
(C) The size of nucleus is very small in comparison to the size of atom
(D) Electron revolves around the nucleus in definite orbits.

19) The correct order of energy of following spectral lines is -

(A) 1 > 3 > 2 > 5 > 4

(B) 3 > 1 > 2 > 4 > 5
(C) 3 > 2 > 1 > 4 > 5
(D) 5 > 4 > 3 > 2 > 1

20) A 20 ml mixture of N2 and O2 having an average vapour density of 14.5 is heated in a closed
vessel to form NO2 gas. If the final volume of the reaction mixture is 18.5 ml then, which statement
is TRUE

(A) Final mixture contains only 2 ml of NO2

(B) Reaction is only 40% complete
(C) Average vapour density of final mixture is 34
(D) Mole fraction of N2 in the final mixture is 0.73

SECTION-II

1) The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is equal to .
The value of 10x is ________ . (a0 is radius of Bohr's orbit) (Nearest integer) [Given : π = 3.14]
2) The given graph represents a comparison of the radial probability distribution of the two orbitals
X and Y, belongs to same shell that can hold maximum 8 electrons.
(i) If number of nodal planes for X = a
(ii) If number of radial nodes for Y = b

Then the value of .

3) Find the molarity of 5.6% w/v KOH if density of solution is 1.4 g/ml :

4) In the reaction : 2Al + Cr2O3 —→ Al2O3 + 2Cr, 49.8 g of Al reacted with 200.0 g Cr2O3. How much
grams of reactant remains at the completion of the reaction ? (molecular wight of Cr2O3 = 152)

5) When photons of wavelength λ = 124 nm is subjected on Cu plate (work function = 5.00 eV) then
photoelectrons emitted. Find out the maximum kinetic energy (eV) of ejected photo electron. (use hc
= 1240 eV-nm)

MATHEMATICS

SECTION-I

1) The complete set of solution of is

(A)

(B)

(C)

(D)

2) Maximum value of the expression f(x) = (x ∈ R) is :

(A) 3
(B) 4

(C)

(D)
3) If graph of y = ax2 + bx + c is as shown in figure, then-

(A) abc > 0

(B) abc < 0
(C) ab2c < 0
(D) ab > 0

4) The value of p for which the sum of the squares of the roots of equation x2 – (p + 3)x + (5p – 2) =
0 assume its least value is –

(A) 1
(B) 2
(C) 3
(D) 4

5) If a, b, c are real, then a (a - b) + b (b - c) + c (c - a) = 0, only if :

(A) a + b + c = 0
(B) a = b = c
(C) a = b or b = c or c = a
(D) a - b - c = 0

6) The equation ax4 – 2x2 – (a – 1) = 0 will have four real and distinct roots if

(A) a < 0 and a ≠ –1

(B) a > 0 and a ≠ 1
(C) 0 < a < 1
(D) a ∈ R – {0}

7) The complete set of values of 'a' for which the equation 2x2 – 2(2a + 1)x + a(a – 1) = 0 has roots α
and β satisfying the condition α < a < β are -

(A) (–3,0)
(B) (0,∞)
(C) (–∞,–3)
(D) (–∞,–3) ∪ (0,∞)

8) If a – 2b + 4c < 0 and quadratic equation ax2 + bx + c = 0 has non-real roots then which of the
following option INCORRECT?

(A) ac > 0
(B)

(C) b > a + c

(D)

9) If , a, b > 0, a ≠ b, then the value of a : b is -

(A) 1 : 16
(B) 1 : 4
(C) 4 : 1
(D) 16 : 1

10) If A = {x : x = 4n + 1, n ≤ 5, n ∈ N} and B {3n : n ≤ 8, n ∈ N}, then A – (A – B) is :

(A) {9, 21}

(B) {9, 12}
(C) {6, 12}
(D) {6, 21}

11) If exactly one root of the equation lies in [0, 1), then complete range of k
is-

(A)
(B)
(C)
(D)

12) If 3α2 – 6α + 5 = 0 & 3β2 – 6β + 5 = 0, α ≠ β, then value of is -

(A)

(B)

(C)

(D)

13) If a, b, c ∈ Q, then the roots of the equation (a + b – c)x2 + (b + c – a)x – 2b = 0 are -

(A) rational
(B) irrational
(C) imaginary
(D) real and lie on opposite side of unity

14)

The complete set of real 'x' satisfying ||x –1| –1| ≤ 1 is :

(A) [0, 2]
(B) [–1, 3]
(C) [–1, 1]
(D) [1, 3]

15) If α and β are the roots of equation x2 – 5x – 3 = 0

and An = αn + βn, also An+2 + µAn+1 + νAn = 0,
(n ∈ N) then (µ + ν) is equal to-

(A) 0
(B) 1
(C) 8
(D) –8

16) If A and B are two sets containing 5 and 7 elements respectively, then maximum and minimum
number of elements in A ∪ B respectively are –

(A) 7,5
(B) 12,5
(C) 7,0
(D) 12, 7

17) If the equation x3 + 2x2 – 4x + 5 = 0 has roots α,β and γ then the value of

is equal to

(A) 52
(B) 104
(C) –104
(D) –78

18) If roots of the equation ax2 + bx + c = 0 are α,β. Then is

equal to -

(A) a2
(B) c2

(C)
(D)

19) The largest interval in which x lies satisfying x12 – x9 + x4 – x + 1 > 0 is :

(A)
(B)
(C)
(D) none of these

20) Number of integral values of x satisfying is

(A) 0
(B) 1
(C) 3
(D) 5

SECTION-II

1) Let and , then value of x + y is

2) If complete solution set of inequality is [a,b], then (b – a) is

3) Let A = {1,2, {3,4}}. How many of the following statements are incorrect ?
(i) {3,4} ⊂ A (ii) {3,4} ∈ A (iii) {{3,4}} ⊂ A (iv) 1 ∈ A
(v) 1 ⊂ A (vi) {1,2,5} ⊂ A (vii) {1,2,3} ∈ A (viii) {1,2,3} ⊂ A
(ix) ϕ ∈ A (x) ϕ ⊂ A (xi) {ϕ} ⊂ A

4) If (x – 3)(x + 2)(x + 3)(x + 8) + 56 = (x2 + qx + r)(x + b)(x + d), then determine |r + 5b + 5d| and
q, r, b, d ∈ Q

5) If a679b is a five digit number that is divisible by 72, then a + b is equal to

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D D B C A A A A C B B A C C B D C B C B

SECTION-II

Q. 21 22 23 24 25
A. 5.00 4.00 5.00 3.00 5.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A B D C D B C B C C A D B B C B D B D

SECTION-II

Q. 46 47 48 49 50
A. 3155.00 16.00 1.00 60.00 5.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A B B B C D D D A D B A B D D B C C A

SECTION-II

Q. 71 72 73 74 75
A. 3.00 1.00 7.00 3.00 5.00
 SOLUTIONS

PHYSICS

1)

Explanation Question: Velocity of particle is given and we have to represent quantities in

order
Concept: This question is based on dimension analysis
Solution:

[b] = ⇒ acceleration
–1
[c] = LT T = L ⇒ Distance
[d] = T ⇒ Time

[a] = ⇒ Distance
Final Answer
The correct option is (4)

2)

Explaining the Question : We need to find the dimension of mass (M) in terms of time (t),
velocity (V) and angular momentum (ℓ).
Concept:- This question is based on Dimensional analysis
Solution : [M] = [t]a [V]b [ℓ]c
Substitute the dimensions
[M1] = [T1]a [LT–1]b [ML2T–1]c
0 0
[M1 L T ] = [Mc Lb+2c Ta–b–c]
Compare powers of M, L and T on both sides
c=1 b + 2c = 0 a–b–c=0
b + 2(1) = 0 a – (–2) –1 = 0
b = –2 a = –1
Substitute the value of a, b and c
m = t–1 V–2 ℓ1
Final Answer :- Hence, the correct option is (4)

3) y = sin x + ℓnx2 + e2x

= cos x + + 2e2x

= cos x + + 2e2x

4)

Correct answer is (C)

5)

Question Explanation : Find the approximate numerical value of the cube root of 1.03 using
suitable mathematical approximation.
Concept: Binomial approximation
Solution:

Write . For small . Here and . Thus

Higher-order terms are very small and can be neglected, making this a good approximation.

Final Answer: Option (1)

6) F1 + F2 = 16 ....(1)
2 2 2
F1 + 8 = F2
F22 – F12 = 64 ....(2)

By solving equation (1) & (2)

F2 = 10 N and F1 = 6 N

7) ....(1)
....(2)
Adding (1) & (2)

8)

Question Explanation: The question asks to find the magnitude of B.

Concept: Vector Algebra and Dot Product properties.
Solution:

Final Answer: Option (1)

9)

10) Explanation :- resultant of two forces gets double when we double first vector, then angle
has to find according to given data
Concept :- Addition subtraction.
Solution :-
R2 = 9p2 + 4p2 + 12p2 cos θ ... (i)
4R2 = 36p2 + 4p2 + 24 p2 cos θ ... (ii)
from equation (i) & (ii) equating value of R2
13p2 + 12p2 cos θ = 10p2 + 6p2 cos θ
3p2 = – 6p2 cos θ

cos θ =
θ = 120°
Final answer :- 120°

11) aavg =

12)

0 m/s

13)

AB = x
BC = x
AD = 2x + CD = 3x
CD = x

<v> =

Final Answer : The correct option is (3)

 14)
Displacement = 0
Area under v – t curve = 0

15) Correct answer is B

16) Correct answer is D

17) v = t2 – 3t + 2 = (t – 1) (t – 2)
0 < t < 1 sec, v = +ve but decreasing because at t = 1 sec, v = 0 and particle is changing its
direction.
1 < t < 2 sec, v = – ve ⇒ Particle is moving towards origin.
t > 2 particle accelerates

18) Correct answer is B

19) Explain the question

We must identify the type of acceleration for the motion v = .

Concept

Acceleration a =

Solution

V = 20 + 0.1 t2 → Positive

= 0 + 0.2 t
↓
Positive
V and a are positive so body is accelerating and a is not constant so it has non-uniform acceleration.
Final answer : Option(3)

20)
Given Time t = 1 sec

⇒ x = 40m

and also

y= 25 m

21)

y = x tan θ –
y = – 100, x = 400, θ = 37°
after solving v0 = 3125

22)

Explain Question:
Calculating stopping distance based on initial velocity and deceleration.
Concept
Equations of Motion (Stopping Distance)
Solution:
For a constant braking force (deceleration), the stopping distance (u2) is directly proportional
to the
square of the initial velocity (u2). If the speed is halved,
the stopping distance reduces to one-fourth of its original value.
Calculation: Given: u1 = 100 m/s, s1 = 16 m, u2 = 50 m/s s. Using the relation s ∝ u2:

Final Answer: 4 m

23) x = t2 – 4t + 4
v = 2t – 4
v = 0 at t = 2 sec, particle turns back at
t = 2 sec.
 x0 = 4, x2 = 0, x3 = 1

24)
uBcos(α + β) = uA

cos(α + β) = α+β=

25) Explanation Question: We have to find the magnitude of resultant force

Concept: This question is based on vectors addition
Solution:

= –4i – 3j

Final answer: 5.

CHEMISTRY

26)

Explain the question: Find longest Lyman wavelength.

Concept: This question is based on Rydberg formula for wavelength.

Solution:
In the Lyman series (n1 = 1), the shortest wavelength (λmin) corresponds to the transition from

n2 = ∞ to n1 = 1, expressed as .
The longest wavelength (λmax) corresponds to the first line transition from n2 = 2 to n1 = 1,

where .

Combining these gives the relation λmax = λmin.

Substituting the given value, λmax = × 911.6 Å ≈ 1215.46 Å, which matches option 1.
 Final Answer: Option (1)

27)

Explanation Question: Question is asking about difference in wavelength of first and last line
of Lyman series for H+.
Concept: This question is based on atomic line spectrum.

Solution: Wave length =

Wave number for a line in spectrum

Z = 2 Lyman series n1 = 1
First line n2 = 2, last line n2 = ∞

So,

Final Answer: Option (1).

28) Question Explanation: Calculating volume change in toluene combustion.

Concept: Stoichiometry of Gaseous Reactions.
Solution: The volume contraction is the difference between the volume of gaseous reactants
consumed and the volume of gaseous products formed. First, write the balanced chemical
equation for the complete combustion of toluene (C7​H8​), then use stoichiometry to find the
volumes.
C7H8 + 9O2 7CO2 + 4H2O
Initial vol. : 30ml 9 x 30 = 270ml
final vol. : 0 0 (7 x 30) = 210 ml
volume contraction = Vi – Vf
= (30 + 270) – (210) = 90 ml
Final Answer:
The correct option is (2)
Final Answer: 90 ml

29) Explanation Question: Find wavelength of 2nd line of balmer series of Li+2
Concept: Line spectrum of atom.
Solution:
 Final Answer

The correct option is (4)

30)

Frequency ∝

31)

Explaining question:
Question in asking about correct curve for 3p orbital.

Concept:
This question is based on graphs of solution of schrodingers wave equation for 3p orbital.

Solution:

Explaining question: Question in asking about correct curve for 3P orbital.

Concept: Graphs of solution of schrodinges wave equation for 3P orbital.

Solution: Correct curve for 3P orbital for R(s), Ψ2 & 4pr2Ψ2(r) vs r.

Final answer : (4)

32)

Δx · Δp =

Δp = ⇒ =

⇒ =

= 8%

33) Since, it is starting from origin therefore it cannot be s-orbital. Among these options dz2
orbital does not have nodal plane. From graph, we can see there are two radial nodes, hence
5dz2.

34) Question Explanation:

Ratio of de-Broglie wave length for electron and proton.
Concept:
This question is based on de-Broglie hypothesis.
Solution:

since velocity of both e- & p is same and mp = 1840 me

Final Answer:
The correct option is (2)

35) Question Explanation : Calculation of moles of specific ions in a solution after

preparation and subsequent dilution steps.
Concept : Molarity and Dilution Principle
Solution :

Moles of mol. Molarity = M.

M.

After 10-fold dilution, M.

Moles in 2 mL = mol.
Final Answer : Option 3

36)

Let 'V' L of 6M H2SO4 was taken

37) Question Explanation:

Calculate volume of solution.
Concept:
This question is based on Mixing and dilution.
Solution:
3 NaOH + H3PO4 Na3PO4 + 3H2O
Total m moles of H3PO4 = (10 × 0.5) = 5
require NaOH = 15 m moles
for molarity of NaOH required =

2V1 +

V1 = , V2 = 3V1 V1 + V2 = 1000 mL 4V1 = 1000 mL V1 = 250 mL , V2 = 750 mL

Final Answer:
The correct option is (1).

38) aA + bB → cC + dD
x mole y mole

this ratio is compaired

(1) then 'B' is Limiting Reagent

(2) the 'A' is Limiting Reagent

(3) then NO. Limiting Reagent

39) Level : Easy

Concept :

No. of moles =
no. of atoms is a molecule = atomicaly no. of molecules
Solution :

(A) 11g of Co2 n=

no. of atoms = [NA = 6.023 1023]

3NA = NA

(B) 4g of H2 n= =2
no. of atoms = 2 2NA = 4NA

(C) 5g of NH3 n=

no. of atoms = NA = NA

(D) 8g of So2 n=

no. of atoms =
hence, highest no. atoms are present in option (B)

40)
 Question Explanation: Calculating the pH of a solution formed by mixing two solutions of the
same strong acid.

Concept: pH of a Mixed Strong Acid Solution

Solution :

∴ pH = 2
Final answer : 2

41) Explain Question:

Find number of molecule.
Concept:
Based on calculation mole.
Solution:

H4P2O7 + 2NaOH → Na2H2P2O7 + 2H2O

2.5 5
∴ NaOH is L.R
total mole of products = 2.5 + 5
= 7.5
total number of molecule present = 7.5NA
Final answer: Option (3)

42) Question Explanation: Calculate the closest distance of approach for an alpha particle.
Concept: Rutherford Scattering Experiment
Solution: At the closest distance (r0), all Kinetic Energy of the alpha particle is converted into
Electrostatic Potential Energy.

F = ma
N = kg ms–2
1 eV = 1.6 × 10–19J
2.5 MeV = 2.5 × 1.6 × 10–19 × 106 J or kg m2s–2

r = 9.1 × 10–14 m
 Final Answer: 9.1 × 10–14 meter

43)

Rutherford's atomic model does not explain that electron revolves around the nucleus in
definite orbits

44) Explain Question:

Ordering the energy of different electron transitions based on their starting and ending energy
levels.
Concept:
Hydrogen Spectrum (Energy Levels)
Solution:
Energy difference is primarily determined by the final shell . Transitions ending at
lower shells release significantly more energy.
Group 1 : Lines 3 and 1. These are Lyman series (highest energy). Line 3 starts from
a higher level than Line 1, so Energy(3) > Energy(1).
Group 2 : Lines 2 and 4. These are Balmer series (lower energy than Lyman). Line 2
starts from higher up than Line 4, so Energy(2) > Energy(4).
Group 3 : Line 5. This is Paschen series (lowest energy here).
Overall Order: 3 > 1 > 2 > 4 > 5.
Final Answer:
Option (2)

45)

Question Explanation: Question is asking about which statement is TRUE

Concept: This question is based on average vapour density of final mixture and mole fraction.
Solution:

1. Initial Mixture Composition:

The average molar mass (Mavg) is twice the vapour density:

Using the total initial volume and molar masses of and :

Let volume of , then .

So, initial volumes are and .

2. Reaction Stoichiometry:

The balanced equation is:

Let a ml of react. According to the coefficients:
N2 reacted = a; O2 reacted = 2a; NO2 formed .
Final volumes:
 3. Finding Volume Change:

Total final volume

4. Final Composition and Verification:

Mole fraction of N2 = (Volume of N2) / (Total Volume ) = 13.5/18.5 ≈ 0.73.

% Completion (based on O2) .
Final Vapour Density = (Total mass / Final volume) / 2 = (580/18.5)/2 ≈ 15.67.

Final Answer: Option (4) is correct.

46)

Question explanation: Find 10x for electron KE in 2nd orbit.

Concept: Bohr's quantization:

Solution: According to Bohr's model, the kinetic energy (KE) of an electron

is From the angular momentum quantization condition, . For a hydrogen atom, the
radius of the n orbit is rn = n a0. For the second Bohr orbit (n = 2), r2 = 22a0 = 4a0 .
th 2

Substituting v into the KE formula gives

0
. Plugging in n = 2 and r = 4a :

Comparing this to the given form we find x = 32π2. Taking π = 3.14,x = 32 × (3.14)2 ≈
32 × 9.8596 = 315.5072. Therefore, 10x = 3155.072. Rounding to the nearest integer, we get
3155 .

Final answer : 3155

47) X = 2p
Y = 2s
a = 1, b = 1

48) Question Explanation:

 Find molarity of solution.

Concept:
Concentration term.

Solution:

Final Answer: 1.

49) Question Explanation:

Calculating the mass of excess reactant left after reaction.

Concept:
Stoichiometry and Excess Reagent.

Solution:
2Al + Cr2O3 —→ Al2O3 + 2Cr

L.R.
= 0.92 = 1.31 SO Al is L.R.
So for consumed mass of Cr2O3

so remained mass = Total mass - consumed mass

= 200 - 140.178
= 59.822g

Final answer: 60

50)
KEmax = 5

MATHEMATICS

51) Case I : When x – 1 < 0

and x2 – 6x + 8 > 0
Inequalities is always true

⇒ solution in this case (–∞,1] ............ (A)

Case II : x –1 > 0
⇒ x2 – 2x + 1 < x2– 6x + 8

⇒x <

⇒ .......................(B)

(A) U (B):
Final Answer: Option (3)

52)

...(1)
x + 4x + 5 = (x + 2)2 + 1
2

⇒ x2 + 4x + 5 ∈ [1, ∞)

⇒ ∴

53) Question Explanation: Determine the product sign of quadratic coefficients.

Concept: Graph of quadratic expression.
Solution:
• The parabola opens upward. ⇒ a > 0
• The graph crosses the y-axis above the origin ⇒ c > 0
x–coordinate of vertex is positive

⇒ and a > 0
⇒b<0
∴ abc < 0
and ab2c > 0
and ab < 0
Final Answer : Option (2)

54)

Question Explanation: Finding the value of a parameter for the minimum sum of squares of
roots.

Concept: Relation between roots and coefficients.

Solution:
Let roots are α and β then
α2 + β2 = (α + β)2 – 2αβ = p2 – 4p+13
= (p – 2)2 + 9
α2 + β2 is minimum when p = 2

To find the least value of a quadratic , we use .

Final Answer: 2

55)

a(a – b) + b (b – c) + c (c – a) = 0

(a2 + b2 + c2 – ab – bc – ca) = 0
(a – b)2 + ( b – c)2 + (c – a)2 = 0
a=bb=cc=a
a=b=c

56) ax4 – 2x2 – (a – 1) = 0

Putting x2 = y, the given equation in x reduces to
ay2 – 2y – (a – 1) = 0 ...(1)
The given biquadratic equation will have four real and distinct roots, if the quadratic equation
(1) has two distinct and positive roots,
For that, we must have
D>0
⇒ 4 + 4 (a) (a –1) > 0
⇒ a2 – a + 1 > 0, which is true ∀ a ∈ R
Product of roots > 0

⇒
⇒0<a<1
sum of roots > 0

⇒
⇒a>0
Hence, the acceptable values of a are
0 < a < 1.

Final Answer: option (3)

57) 2ƒ(a) < 0 ⇒ ƒ(a) < 0

∴ 2a2 – 2(2a + 1)a + a(a – 1) < 0
\(a \in \left( { - \infty , - 3} \right) \cup \left( {0,\infty } \right)\)

58) Explain Question: In this question we have given relation a – 2a + 4c < 0 and quadratic
equation ax2 + bx + c = 0 has non real roots and choose the incorrect options.
Concept:
(1) This question is based on sign of quadratic expression.
(2) ax2 + bx + c = 0 has non real roots D < 0.
Solution: Given quadratic equation ax2 + bx + c = 0 has non real roots so graph of quadratic
expression lie completely above x - axis or completely below x - axis.

Here a < 0
Option (1) at x = 0, f(0) < 0 ⇒ C < 0 ⇒ ac > 0 (Correct)

Option (2) D < 0 ⇒ b2 – 4ac < 0 ⇒ (Correct)

Option (3) f(–1) < 0 ⇒ a – b + c < 0 ⇒ b > a + c (Correct)

Option (4) Since a < 0, c < 0 ⇒

⇒ Option (4) is incorrect
Final Answer: (4)

59)

Explain question : We have given a relation in terms of a and b and we have to find a : b.
Concept : This question is based on ratio and proportion.
Solution :-

Given :

⇒
using componendo and dividendo

⇒
a : b = 16 : 1

Final answer :- Option (4)

60)

Question Explanation: Evaluate a set operation involving two sets defined by algebraic rules.
Concept: Set Difference and Set Union
Solution: The expression A–(A–B) simplifies to A∩B.
A = {5,9,13,17,21},
B = {3,6,9,.........,24}
A∩B={9,21}
Final Answer : Option (1)

61) Solution :

Case – I
Exactly one root in (0,1)
⇒

⇒
⇒
⇒k>0
Case – II
When one root is equal to 0, then put x = 0
0–0 + 2k –1 = 0
⇒k=0
Now the equation is
x2 – x = 0
x = 0, 1
Hence, at k = 0, exactly one root in [0, 1)
So, from case – I & case – II

Final Answer : Option (4)

62) Question Explanation: Finding the value of a symmetric expression using roots of a
quadratic.
Concept: Roots of Quadratic Equation
Solution: Since α and β satisfy the same quadratic equation 3x2 – 6x + 5 = 0, they are its
roots.
The sum of roots α + β = –(–6)/3 = 2 and the product of roots αβ = 5/3.

Use

and

Required value
Final Answer: Option (2)

63)

Question Explanation: Determining the nature of roots for a quadratic with rational
 coefficients.

Concept: Rational Roots and Sum of Coefficients.

Solution:

Equation: .

Sum of coefficients: .

Since the sum is 0, one root is .

Product of roots .

As , the roots are rational.

Final Answer: option (1)

64) Solution:
Given: ||x –1| –1| ≤ 1
⇒
⇒
⇒
⇒
Final Answer: Option (2)

65)

Answer -8

66)

Question Explanation: Find the maximum and minimum number of elements in the union of
two sets.
Concept: Range of Cardinality of Union
Solution: The cardinality of the union n(A∪B) ranges between max(n(A),n(B)) (minimum union
size, maximum intersection) and n(A)+n(B) (maximum union size, minimum intersection ϕ).

Calculation: Given: n(A)=5,n(B)=7.

A. Maximum n(A∪B): Occurs when n(A∩B)=0.

n(A∪B)max​=n(A)+n(B)=5+7=12

B. Minimum n(A∪B): Occurs when n(A∩B) is maximized to min(5,7)=5.

n(A∪B)min​=n(A)+n(B)−n(A∩B)max​=5+7−5=7
 The maximum and minimum number of elements are 12 and 7.

Final Answer: 12, 7

67) x3 + 2x2 – 4x + 5 = (x – α) (x – β) (x – γ)
Put x = 2 we get 13 = (2 – α) (2 – β) (2 – γ)
Now α3 + 5 = –2α2 + 4α = 2α(2 – α)

So

= 8(2 – α) (2 – β) (2 – γ)
= 8 × 13 = 104

68) Question Explanation: We have to solve ax2 + bx + c = 0 for given expression.

Concept: This question is based on relation between roots and coefficients.

Solution: Roots α, β of ax2 + bx + c = 0

aα2 + bα + c
α(aα + b) = – c

... (i)
2
and aβ + bβ + c = 0

... (ii)

Now,

Final answer: The correct option is (3).

69) Explain Question:

We need to find the interval of x for which the polynomial x12 – x9 – x4 – x + 1 is positive.
Concept:
Algebraic Inequalities
Solution:
Let ƒ(x) = x12 – x9 – x4 – x + 1. We analyze three cases :
Case 1 : x ≤ 0
⇒ ƒ(x) ≥ 1 > 0.
Case 2 : 0 < x < 1
Group terms as : ƒ(x) = x12 + x4(1 – x5) + (1 – x).
Since 0 < x < 1 ⇒ x5 < 1, each term is positive.
⇒ ƒ(x) > 0.
Case 3 : x ≥ 1
Group terms as : ƒ(x) = x9 (x3 – 1) + x(x3 – 1) + 1.
Since x ≥ 1 ⇒ x3 ≥ 1, all terms are non-negative.
⇒ ƒ(x) ≥ 1 > 0.
Combining all cases, ƒ(x) > 0 for all real numbers.

Final Answer: Option (3)

70)

Question Explanation: Solving a rational inequality to find integer solutions for x.

Concept: Solving Rational Inequalities using Wavy Curve Method.
Solution:

Rearrange:

⇒ >0

⇒
Using Wavy Curve Method

∴ x ∈ (–2, –1) ∪ (–2/3, –1/2)

Integral Values: There are no integers between –2 and –1, nor between –2/3 and –1/2.
Number of integral value of x = 0
Final Answer: Option (1)

71)

Question Explanation:

We have to find value of (x + y) after simplify the given value of 'x' and 'y'.
 Concept:

This question is based on Surds.

Solution:

Let A = x + y
A3 = x3 + y3 + 3xy(x + y)

A
A3 = 36 + 3(–1)1/3A

A3 + 3A = 36
(A – 3)(A2 + 3A + 12) = 0
⇒ A = 3 or x + y = 3

Final Answer: 3

72)
valid for x ∈ [3,8]
⇒

⇒ where x ≥ 6
⇒ x2 – 11x + 28 ≥ 0
⇒ x ≤ 4 or x ≥ 7
⇒

73)

Question Explanation: In this question, we have to given a set and ask for how many
statements are incorrect.
Concept: This question is based on set theory
(1) x ∈ A ⇒ x is element of A
(2) If x ∈ A then {x} ⊆ A
(3) ϕ ⊂ A for any set A
(4) ϕ is empty set
Solution:
given set is A={1,2,{3,4}}
(i) {3,4} ⊂ A (false)
∵ {3,4} element of A not a subset
(ii) {3,4} ∈ A (true)
(iii) {{3,4}} ⊂ A (true)
(iv)
(v) I ⊂ A (false) as
(vi) {1,2,5} ⊂ A (false)
As 5 is not an element of A
(vii) {1,2,3} is not an element of A. therefore (false)
(viii) 3 is not an element of A therefore {1,2,3} ⊄ A (false)
(ix) Empty set is not a element of A (false)
(x) empty set is a subset of every set ⇒ True
(xi) {ϕ} is not subset of A
false statements are: (i), (v), (vi), (vii), (viii), (ix), (xi).
Final Answer: 7

74) Question Explanation: In this question, we have a equation (identity) and we have to find
unknown.

Concept: This question is based on equations reducible in quadratic equation.

Solution:
(x – 3)(x + 2)(x + 3)(x + 8) + 56
= (x2 + 5x – 24)(x2 + 5x + 6) + 56
Put x2 + 5x + 6 = t
t(t – 30) + 56 = (t – 2)(t – 28)
= (x2 + 5x + 4)(x2 + 5x – 22)
= (x + 1)(x + 4)(x2 + 5x – 22)
= (x + 1)(x + 4)(x2 + 5x – 22)
b, d = 1, 4 r = –22
required |r + 5(b + d)| = |–22 + 5(5)|
= |3|
=3

Final answer is 3.

75) Explain question : Number is divisible by 9 and 8

Concept : This question is based on divisibility test.
Solution :
The Number is divisible by 8 if last three digits are divisible by 8 i.e. 79b is divisible by 8 ⇒ b =
2
For divisible by 9
a + 6 + 7 + 9 + b is divisible by 9
⇒ a + 24 is divisible by 9
⇒a=3
⇒a+b=5
Final answer : 5