30/12/2025 A

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MM : 693 Solution Practice sheet Time : 180 Min.

Solution

1. 0.2 molal aqueous solution of K3[Fe(CN)6] ionizes to 40%. 6. 3.6 g of glucose is present in 250 ml aqueous solution.
Depression in freezing point of solution will be (Kf(H2O) = The osmotic pressure of the solution at 27 °C will be (R =

1.86 K molal–1) 0.082 L atm K–1 mol–1; molar mass of glucose = 180 g
mol–1)
(A) 0.82 K
(A) 4.0 atm
(B) 0.45 K
(B) 3.0 atm
(C) 1.23 K
(C) 2.0 atm
(D) 0.63 K
(D) 5.0 atm
2. 3.7 g of calcium hydroxide is dissolved in 100 g of water.
Assuming the base to be 80% ionised, the freezing point 7. If molality of aqueous solution of glucose (C6H12O6) is
of the solution will be (Kf for water = 1.86 K mol–1 kg) 1.0 then the mass percentage of glucose in the solution
will be
(A) –2.79°C
(A) 25.50%
(B) –0.9°C
(B) 10.52%
(C) –2.418°C
(C) 15.25%
(D) –0.744°C
(D) 20.25%
3. Condition which is not obeyed by an ideal solution will be
8. The mass of urea to be dissolved in 100 g of water (Kb =
(A) Δmix H = 0
0.52 K kg mol–1) to prepare a solution having boiling point
(B) Δmix S = 0 101°C, is
(A) 10.26 g
(C) Δmix V = 0
(B) 4.2 g
(D) Psolution = PA + PB
(C) 11.54 g
4. If the vapour pressure of CH3Cl and CH2Cl2 are 360 mm
(D) 14.66 g
and 480 mm of Hg respectively at a given temperature. If
202 g of CH3Cl is mixed with 170g of CH2Cl2 at the same 9. Vapour pressure of dilute aqueous solution of glucose is
temperature, then vapour pressure of the solution will be 750 mm of mercury at 373 K. The mole fraction of solute is

(A) 420 mm (A)

1

76

(B) 400 mm
(B)
1

7.6
(C) 480 mm
(D) 360 mm (C) 1

38

5. If the Henry's law constant for the solubility of O2 gas in (D)

1

10

water at 25°C is 5.0 × 106 atm. The mole fraction of O2 in

10. The colligative property widely used to determine molar
air is 0.2. The number of moles of O2 from air dissolved in mass of polymers is
10 moles of water at 25°C and 4 atm pressure is
(A) Osmotic pressure
(A) 1.6 × 10–6
(B) Elevation in boiling point
(B) 2.4 × 10–5 (C) Depression in freezing point

(C) 5.2 × 10–3 (D) Relative lowering of vapour pressure

(D) 3.2 × 10–4

1
11. A solution of 18% (mass/vol) glucose is isotonic with x% 17. A solution is made by two volatile components
(mass/vol) KCl solution. If KCl is 90% dissociated, then
A (P° = 100 mm Hg) and B (P°B = 200 mm Hg) . Find
value of x is (Mol. mass of KCl = 74.5 g mol–1)
​A

out the mole fraction of A in vapour phase if solution is

(A) 2.67 made by mixing equal moles of A and B.
(B) 4.35 (A)
1

(C) 3.92
(B) 1

(D) 3.12 3

(C)
2

12. The solution which shows positive deviation from Raoult’s 3

law is
(D) 1

(A) CH3COCH3 + C6H6

4

18. The Van't Hoff factor (i) for a dilute aqueous solution of the
(B) HCl + H2O strong electrolyte Na3AlF6 is
(C) C6H6 + C6H5CH3 (A) 10
(D) CH3COCH3 + C6H5NH2 (B) 5

13. At 79ºC the vapour pressure of pure liquid 'A' is 520 mm of (C) 4
Hg and that of pure liquid 'B' is 1000 mm of Hg. If a
(D) 3
mixture of A and B boils at 79ºC at 760 mm of Hg then the
mole percent of A in the solution is 19. If two volatile liquids A(P ° = 540 torr) and B(P ° = 420
A B
(A) 25% torr) are mixed in the molar ratio of 2 : 1 then total vapour
pressure of solution is
(B) 50%
(C) 48% (A) 100 torr

(D) 52% (B) 200 torr

(C) 600 torr
14. 0.1 molal solution of which compound will have highest
boiling point? (consider complete dissociation of (D) 500 torr
electrolytes)
20. A solution containing 2 g per 100 mL of urea (molecular
(A) Glucose
mass = 60 g mol–1) is isotonic with a 5% (w/v) solution of
(B) KCl a non-volatile solute. The molecular mass of this non-
volatile solute is
(C) CaCl2
(A) 175 g mol–1
(D) CH3COONa
(B) 200 g mol–1
15. If an azeotropic solution of two liquids has higher boiling
point than either of solute and solvent, then the solution (C) 350 g mol–1
(A) Is immiscible
(D) 150 g mol–1
(B) Shows positive deviation from Raoult’s law
21. If degree of dissociation of CH3COOH is 0.2 then its
(C) Shows negative deviation from Raoult’s law
abnormal molar mass is
(D) Follow Raoult’s law
(A) 30 g mol–1
16. Which one of the following electrolytes has the maximum
value of van't Hoff factor? (B) 48 g mol–1

(A) K4 [Fe (CN)6 ], 50% ionised

(C) 50 g mol–1
(B) K2 SO4 , 80% ionised
(D) 72 g mol–1
(C) K3 [Fe (CN) ], 60% ionised
6
22. Let gas(A) present in air is dissolved in 20 moles of water
(D) Al ( NO3 )3 , 70% ionised
at 298 K and 20 atm pressure. The mole fraction of gas
(A) in air is 0.2 and the Henry's law constant for solubility
of gas(A) in water at 298 K is 1 × 105 atm. The number of
mole of gas (A) dissolved in water will be

(A) 8 × 10–5

(B) 4 × 10–4

(C) 8 × 10–4

(D) 6 × 10–5

2
23. An aqueous solution of a nonvolatile solute boils at 30. 24 g of difluoroacetic acid in 400 g of water has observed
101.20°C. At what temperature the solution will freeze? freezing point depression by 1.4°C. The van't Hoff factor
(Given: Kb = 0.512 K kg mol–1 and Kf = 1.86 K kg mol–1) for difluoroacetic acid is (Kf of water = 1.86 K kg mol–1;
Atomic weight of F = 19)
(A) –2.17°C
(A) 1.20
(B) –1.2°C
(B) 1.05
(C) –3.46°C
(C) 1.45
(D) –4.36°C
(D) 0.85
24. A solute AB2 dissociate 50% and associate 30%
(trimerize). The value of vant Hoff factor will be 31. Henry’s law constant (KH) for the following gases, He, N2
and O2 are 144.97, 76.48 and 34.86 kbar respectively at
(A) 3
293 K. The correct order of solubility is
(B) 2.2
(A) N2 > O2 > He
(C) 1.8
(B) He > O2 > N2
(D) 1.2
(C) O2 > N2 > He
25. The values of observed and calculated molecular weights
of silver nitrate are 90 and 170 respectively. The degree of (D) He > N2 > O2
dissociation of silver nitrate is
32. Which of the following gas is most soluble in water at 298
(A) 80%
K?
(B) 75.46%
(A) Carbon dioxide
(C) 95.73%
(B) Formaldehyde
(D) 88.89%
(C) Vinyl chloride
26. Molality of aqueous solution of urea is 3. The mass (D) Methane
percentage of urea in the solution is
33. Given below are two statements. One is labelled as
(A) 10.5%
Assertion (A) and other is Reason (R).
(B) 25.25% Assertion (A): For negative deviation from Raoult's law
Vsolution < VA + VB.
(C) 12.25%
Reason (R): There is decrease in change of Gibb's free
(D) 15.25% energy on mixing of component A and B which form a
solution, exhibits negative deviation from Raoult's law.
27. Vapour pressure of a binary solution of A and B (in mm In the light of above two statements choose the correct
Hg) is equal to 140 + 120 XA. Pure form vapour pressures option.
of A and B respectively are
Both Assertion & Reason are true and the reason is
(A)
(A) 140 mm Hg, 260 mm Hg the correct explanation of the assertion
(B) 260 mm Hg, 140 mm Hg Both Assertion & Reason are true but the reason is not
(B)
the correct explanation of the assertion
(C) 240 mm Hg, 120 mm Hg
(C) Assertion is true statement but Reason is false
(D) 120 mm Hg, 240 mm Hg
(D) Both Assertion and Reason are false statements
28. The mixture of solution that forms minimum boiling
azeotrope is 34. Given below are two statements. One is labelled as
Assertion (A) and other is Reason (R).
(A) Ethanol and water
Assertion (A): Solubility of gases in liquid decreases with
(B) Nitric acid and water rise in temperature.
Reason (R): Solubility of gases in liquid is an exothermic
(C) Benzene and Toulene process so solubility decreases with rise in temperature,
(D) Bromoethane and Chloroethane according to Le-chatelier's principle.
In the light of above two statements choose the correct
29. Which of the following statements is correct regarding a option.
solution of two components A and B exhibiting positive
deviation from ideal behaviour? Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
(A) ΔmixV = 0 at constant T and P.
Both Assertion & Reason are true but the reason is not
(B)
Intermolecular attractive forces between A-A and B-B the correct explanation of the assertion
(B)
are equal to those between A-B. (C) Assertion is true statement but Reason is false
Intermolecular attractive forces between A-A and B-B (D) Both Assertion and Reason are false statements
(C)
are stronger than those between A-B.

(D) ΔmixH = 0 at constant T and P.

3
35. Arrange the following aq. dilute solution in the increasing 41. Molality of 0.1 M NaOH aqueous solution of density 1.2
order of vapour pressure g/ml is
(a) 10% (w/v) glucose
(b) 10% (w/v) sucrose (A) 0.084 m
(c) 10% (w/v) urea (B) 0.168 m
(A) (a) < (b) < (c) (C) 0.042 m
(B) (a) < (c) < (b) (D) 0.021 m
(C) (c) < (b) < (a) 42. Incorrect match is
(D) (c) < (a) < (b) (A) CHCl3 + CH3COCH3 (negative deviation)
36. The percentage of phenol dimerised in benzene if 18.8 g (B) HF + ROH (positive deviation)
of phenol in 1 kg benzene exhibits a freezing point
depression of 0.70 K, is (C) ROH + ROR (positive deviation)
K−kg
(Given that kf benzene = 5.12 mol
and MW of phenol = (D) Phenol + aniline (negative deviation)
94)
43. When CO2 (g) is dissolved in water, heat is liberated. The
(A) 64% solubility of CO2 (g) will increase at
(B) 73% (A) High pressure, low temperature
(C) 91% (B) Low pressure, low temperature
(D) 47% (C) Low pressure, high temperature
37. The vapour pressure of a solution of a non-volatile solute (D) High pressure, high temperature
B in a solvent A is 90% of the vapour pressure of the
solvent at the same temperature. If the molecular weight of 44. The molecular weight of benzoic acid in benzene as
the solvent is 0.3 times the molecular weight of the solute, determined by depression in freezing point method
then the ratio of weight of solvent to solute is corresponds to
(A) 0.2 (A) Solvation of benzoic acid
(B) 0.15 (B) Trimerization of benzoic acid
(C) 5.7 (C) Dimerization of benzoic acid
(D) 2.7 (D) Ionization of benzoic acid

38. 0.01 m aqueous solution of K3[Fe(CN)6] freezes at – 45. A : When red blood cells are placed in distilled water,
water flows into the cells.
0.062°C. Kf for water is 1.86 K kg mol–1. The apparent
R : Direction of osmosis is from hypertonic solution to
percentage dissociation of salt will be hypotonic solution.
(A) 77.7 Both Assertion & Reason are true and the reason is
(A)
(B) 59.8 the correct explanation of the assertion

(C) 47.7 Both Assertion & Reason are true but the reason is not
(B)
the correct explanation of the assertion
(D) 22.3
(C) Assertion is true statement but Reason is false
39. A : Heat is evolved when anhydrous form of salt gets
hydrated. (D) Both Assertion and Reason are false statements
R : Hydration involves bond formation between water and 46. Relative lowering of vapor pressure of a solution
ions of salt. containing non-volatile solute can be expressed as (A -
Both Assertion & Reason are true and the reason is solvent, B - solute)
(A)
the correct explanation of the assertion (A) Both (C) and (D)
Both Assertion & Reason are true but the reason is not
(B) (B) Ps = P
∘
XB
the correct explanation of the assertion A

(C) Assertion is true statement but Reason is false (C)

P
A
− Ps

=
nB

Ps nA

(D) Both Assertion and Reason are false statements ∘

PA − Ps nB
(D) =
40. When n2 moles of non-volatile solute are dissolved in n1 PA
∘
nA

moles of solvent, then vapour pressure of pure solvent

(po) changes to p (vapour pressure of solution). The
correct relation(s) for such solution is/are

(A) pº = p x1
(B) All of these
∘

(C) p −p

p
=
n2

n1

(D) p −p

p
=
n2

n1 + n2

4
47. A : For dilute solutions, partial pressure of the gas is 52. At 2 atm pressure, mole of O2(g) dissolved in 10 moles
directly proportional to the mole fraction of the dissolved water at 293 K is (Henry’s constant for O2(g) in water is
gas in the solution.
R : At a given temperature, He gas is less soluble than 0.3 × 105 atm)
CO2 gas in water.
(A) 6.67 × 10–3
Both Assertion & Reason are true and the reason is
(A) (B) 6.67 × 10–5
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is not (C) 6.67 × 10–4
(B)
the correct explanation of the assertion
(D) 6.67 × 10–6
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements 53. 100 ml of 2 M NaOH solution is mixed with 900 ml of 4 M
NaOH solution. The molarity of the resultant solution will
48. A : The breathing apparatus used by Scuba divers be
contains air diluted with helium.
R : Presence of helium reduces the high concentration of (A) 2.8 M
nitrogen in blood and the painful medical condition ''bends'' (B) 3.2 M
is avoided.
(C) 3.4 M
Both Assertion & Reason are true and the reason is
(A) (D) 3.8 M
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is not 54. The solution of acetone in aniline
(B)
the correct explanation of the assertion (A) Obeys Raoult’s law
(C) Assertion is true statement but Reason is false
(B) Have ΔHmix and ΔVmix value zero
(D) Both Assertion and Reason are false statements
(C) Show a positive deviation from Raoult’s law
49. The ratio of van’t Hoff factors of acetic acid in benzene
(D) Show a negative deviation from Raoult’s law
and water (assuming complete association and
dissociation respectively) is equal to 55. For an ideal solution of two volatile liquids A and B, the
(A) 1 graph of vs gives intercept equal to (x and y are
1

y
1

xA
A

mole fractions in liquid and vapour phase)

(B)
1

2
o o
p −p

(C) 2 (A) A

p
o
B

(D)
1
o o
p −p
4
(B) B

p
o
A

50. The solution which forms minimum boiling azeotrope is o

p

(A) CHCl3 + CHBr3 (C) p

B

o
A

(B) HNO3 + H2O p

o

(D) p
A

o
B

(C) HCl + H2O

56. Consider the following statements
(D) C6H5OH + H2O I. Pressure does not have any significant effect on
solubility of solids in liquids.
51. Vapour pressure of carbon tetrachloride at a particular II. Higher the value of KH at a given pressure, the lower is
temperature is 400 mm of Hg. A non-volatile, non-
electrolyte solid weighing 0.8 g when added to 77 g of the solubility of the gas in the liquid.
carbon tetrachloride the vapour pressure of the solution III. At high altitudes the partial pressure of oxygen is high
becomes 390 mm of Hg. The molar mass of solute is than that at the ground level.
The correct statement(s) is/are
(Molar mass of CCl4 is 154 g mol–1. Assume solution to
be dilute.) (A) Only I
(B) I and II
(A) 120 g mol–1
(C) Only III
(B) 64 g mol–1
(D) II and III
(C) 50 g mol–1
57. The mass of urea required in making 5 kg of 5 molal
aqueous solution is
(D) 32 g mol–1
(A) 1500 g
(B) 1000 g
(C) 1154 g
(D) 1254 g

5
58. The gas in tanks used by scuba divers of breathing 63. 36% (
w
) solution of glucose is
v
contains
(A) 1.25 M
(A) 78% N2
(B) 2.0 M
(B) 11.7% He
(C) 2.25 M
(C) 32.1% O2
(D) 3.0 M
(D) Both (B) & (C)
64. Select the incorrect statement among the following.
59. Which among the following is an incorrect statement about
Henry’s law constant (KH)? Solutions which show a large positive deviation from
(A) Raoult's law form minimum boiling azeotrope at a
Different gases have different KH values at same specific composition
(A)
temperature (B) Azerotropes solution have constant boiling point
(B) KH is a function of nature of the gas At azeotropic composition, the liquid and vapour have
(C)
the same composition
Higher is the value of KH at a given temperature and
(C) Azeotropes can be separated into components by
pressure, higher is the solubility of the gas (D)
fractional distillation
KH value of a particular gas increases with increase in
(D) 65. Select the incorrect statement among the following.
temperature at constant pressure
Osmotic pressure property cannot be used to
60. Among the following which gas will show maximum (A)
determine molar mass of polymers
negative deviation at moderate pressure?
Solution of low osmotic pressure than the other is
(A) He (B)
known as hypotonic
(B) O2 Solution of more osmotic pressure than the other is
(C)
(C) CH4 known as hypertonic
(D) Osmotic pressure is a colligative property
(D) CO2
66. A : In case of negative deviations from Raoult's law, the
61. A 5 M aqueous solution of AgNO3 and 10 M aqueous intermolecular attractive forces between A – A and B – B
solution of NaCl are connected by a semipermeable are weaker than those between A – B.
membrane as shown in the figure. R : Abnormal molar mass, which is related to van't Hoff
factor, is the experimentally determined molar mass.
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is not
(B)
the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements
67. Concentrated HNO3 solution is 63% HNO3 by mass and
has a density of 1.4 g/ml. The molarity of this solution in
terms of HNO3 as solute is
The precipitate of AgCl will be formed in (A) 1.4 M
(A) Chamber 1 (B) 6.3 M
(B) Chamber 2 (C) 12.6 M
(C) Simultaneously in both the chambers (D) 14 M
(D) None of the chambers 68. Which among the following aqueous solutions has highest
62. Among the following which solution shows positive freezing point? (Given Kf of water = 1.86 K kg mol–1)
deviation from Raoult’s Law?
(A) 0.1 m glucose solution
(A) H2O + HCl
(B) 0.1 m NaCl solution
(B) HNO3 + H2O
(C) 0.1 m CaCl2 solution
(C) CH3COCH3 + CS2 (D) 0.2 m NaOH solution
(D) n-pentane + n-hexane

6
69. Which of the following change will increase the vapour 75. Increase in the temperature of an aqueous solution will
pressure of one molal aq. KI solution? cause
(A) Adding HgI2 (A) Decrease in the mole fraction

(B) Adding one molal aq. KI (B) Decrease in molarity

(C) Adding I2 (C) Decrease in molality

(D) Decrease in to (W/W)
(D) Adding NaI
70. A : For 0.1 M aq. NaOH and for 0.1 M aq. CH3COOH 76. The normality of 5 molal H2SO4 solution if density of
solution, the ebullioscopic constant is different. solution is 1.8 g/cm3 is
R : Ebullioscopic constant depends on the nature of
(A) 18 N
solute.
(B) 12 N
Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion (C) 9 N
Both Assertion & Reason are true but the reason is not (D) 10 N
(B)
the correct explanation of the assertion
77. Solubility of a gas in a liquid is increased by
(C) Assertion is true statement but Reason is false
(A) Increase in temperature
(D) Both Assertion and Reason are false statements
(B) Increase in pressure
71. A : People taking a lot of salt or salty food experience
water retention in tissue cells and intercellular space. (C) Increase in KH value
R : There is phenomena of osmosis in tissue cells and (D) Increase in amount of liquid
intercellular space.
78. If the molality of NaOH in D2O is 20 m, then difference
Both Assertion & Reason are true and the reason is
(A) between mole fractions of D2O and NaOH will be
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is not (A) 2

(B)
the correct explanation of the assertion
7

(C) Assertion is true statement but Reason is false (B) 5

(D) Both Assertion and Reason are false statements (C) 1

72. The vapour pressure of the solution of two liquids. A (P0 =

(D)
3

100 mm of Hg) and B (P0 = 120 mm of Hg) is found to be

7

110 mm of Hg. When XA = 0.6, the result shows that 79. A : Mass percentage of 2 m glucose solution is 28.5%.
R : Molality is the mole of the solute present in 1 kg of the
(A) Solution shows positive deviation solution.
(B) Solution shows negative deviation Both Assertion & Reason are true and the reason is
(A)
(C) Solution exhibits ideal behaviour the correct explanation of the assertion

Solution will show positive deviation for lower Both Assertion & Reason are true but the reason is not
(B)
(D) concentration and negative deviation for higher the correct explanation of the assertion
concentrations (C) Assertion is true statement but Reason is false
73. Identify the incorrect statement. (D) Both Assertion and Reason are false statements
At constant T and P, ΔGmix will be negative for an 80. A solution containing 20 g/dm3 of glucose (C H O ) is
(A) 6 12 6
ideal solution
W
The volume of a solution cannot be less than the sum isotonic with 4% ( ) solution of a strong electrolyte of
V
(B) of volumes of the pure solvent and solute used to
prepare the solution type AB. The molar mass of the electrolyte is

An ideal binary solution will gradually become richer in (A) 1440 g mol–1
(C) the less volatile component if such a mixture is boiled
(distilled) (B) 720 g mol–1

An ideal binary solution (P

0
≠ P
0
) cannot form an (C) 360 g mol–1
(D) A B

azeotropic mixture
(D) 220 g mol–1
74. When mercuric iodide is added to the aqueous solution of
potassium iodide, the
(A) Boiling point of solution remains same
(B) Freezing point of solution remains same
(C) Freezing point of solution is raised
(D) Freezing point of solution is lowered

7
81. The boiling point of 0.14 mol kg–1 solution of A B C is 87. The mole fraction of urea in its 2 molal aqueous solution is
2 4 2
greater than equimolal solution of A6B12 in water. Which (A) 0.0177
one of the following statements may be correct in this (B) 0.0215
case?
(C) 0.0347
Molecular mass of A2B4C2 is greater than the
(A) (D) 0.0415
molecular mass of A6B12

A6B12 is undergoing dissociation in water whereas 88. If 2 g urea is added to 100 g of water (Kf = 1.86 Kkg/mole),
(B) then how much ice will separate out at –10°C?
A2B4C2 undergoes no change
(A) Zero
Molecular mass of A2B4C2 is less than the molecular
(C) (B) 93.8 g
mass of A6B12

A2B4C2 is undergoing dissociation in water whereas (C) 9.38 g

(D) (D) 4.82 g
A6B12 undergoes no change

82. Select the process in which final vapour pressure is more 89. 2 L of 1 M HCl solution is mixed with another 3 L of 2 M
than initial vapour pressure? HCl solution. If obtained solution is diluted by adding 5 L
water, then the molarity of resultant solution will be
(A) 0.01 mol NaCl added to 0.01 M NaCl(aq)
(A) 1.6 M
(B) 0.01 mol sugar added to 100 ml H2O
(B) 3.2 M
100 mole H2O added to 100 ml 0.01 M KCl (aq)
(C) (C) 0.8 M
solution
(D) 0.4 M
(D) 0.1 mol sugar added to 0.1 M NaCl solution
90. 100 ml of 2 M H2SO4 is diluted by water so that the final
83. The freezing point depression constant of H2O is 1.86 K
molarity becomes 0.4 M. The volume of water added to
kg mol–1. When 3.42 g of Al2(SO4)3 is dissolved in 90 g the initial solution is
H2O, the freezing point of solution becomes –0.50 °C. The (A) 500 mL
van't Hoff factor for Al2(SO4)3 is [Given : Molar mass of
(B) 350 mL
Al2(SO4)3 = 342 g/mole]
(C) 550 mL
(A) 3.52
(D) 400 mL
(B) 2.42
91. The degree of association of an electrolyte is α and its
(C) 5 van’t Hoff factor is i. The number of solute particles
(D) 4.12 combine to form one molecule in associated form will be

84. Aqueous solution of which of the following has lowest (A) i – α – 1

freezing point? (Kf(H2O) = 1.86 K molal–1) (B)
α

i−1+α

(A) 0.1 m NaCl (C) i−1+α

(B) 0.01 m NaCl α

(D) i−α
(C) 0.001 m NaCl
(D) 0.0001 m NaCl 92. If 'i' is the van't Hoff factor and 'α' is degree of dissociation
of weak electrolyte AxBy, then relation between 'α' and 'i'
85. Mass of a non-volatile solute (molar mass = 45 g mol–1) is
that should be dissolved in 90 g water to reduce its vapour i−1

pressure to 75% is (A) α =

(x+y)

(A) 75 g i−1
(B) α =
(x+y−1)
(B) 45 g
1−i
(C) 25 g (C) α =
(x+y−1)

(D) 15 g i−1
(D) α =
(x+y+1)
86. Which of the following forms azeotropic mixture?
(A) 90% ethanol + 10% water 93. The mole fraction of urea in its 0.1 molal aqueous solution
is
(B) 75% nitric acid + 25% water
(A) 1

(C) 80% ethanol + 20% water 655.5

(B)
1
(D) 68% nitric acid + 32% water 596.5

(C) 1

556.5

(D) 1

535.5

8
94. If 50% of acetic acid dimerises in a solvent and rest [Link] pH of 'C' molar HA(weak acid) aqueous solution is 2 and
ionises, then its van’t Hoff factor is the van't Hoff factor is 1.01 then value of C is
(A) 1 (A) 1
(B) 1.25 (B) 2
(C) 0.75 (C) 4
(D) 2 (D) 8
95. Select the correct statement among the following. [Link] below are two statements one is assertion (A) other
is reason (R)
Plant cell when placed in hypotonic solution, it will Assertion (A): The composition of the components in
(A)
shrink vapour phase is same as that of in the liquid phase of an
Osmotic pressure associated with 0.9% mass/volume azeotropic mixture.
(B) of NaCl solution is equivalent to fluid inside the blood Reason (R): Azeotropic mixture strictly follows Raoult's
cell law.
In the light of above statements choose the correct
As compared to other colligative properties, magnitude answer.
(C) of elevation in boiling point is large even for very dilute
solution Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
Molal elevation constant always larger than molal
(D) Both Assertion & Reason are true but the reason is not
depression constant (B)
the correct explanation of the assertion
96. If the molality of the solution is 0.70, then relative lowering
of the vapour pressure of an aqueous solution containing (C) Assertion is true statement but Reason is false
non-volatile solute is approximately (D) Both Assertion and Reason are false statements
(A) 0.01
[Link] graph between PTotal (Total vapour pressure of
(B) 0.50 solution) and XB (mole fraction of solute) is given below (
(C) 0.80 P
o o
is Vapour pressure of pure liquid A and P is vapour
A B
(D) 0.40
pressure of pure liquid B)
97. What will be the concentration of chloride ion if 200 mL of
0.2 M CaCl2 is mixed with 300 mL of 0.1 M NaCl solution?

(A)
11
M
5

(B) 11

50
M

(C) 22

49
M

(D) 1

50
M

98. A 10% aqueous solution (by mass) of urea has boiling

point 374.11 K. The boiling point of 10% glucose (by
mass) in water is (Boiling point of water is 373.15 K)
The slope of graph is
(A) 373.47 K
o o
(B) 375.25 K (A) P − P
A B

(C) 374.91 K
o o
(D) 373.15 K (B) PB − PA

99. Relative lowering in vapour pressure of a solution o o

containing 1 mole K2SO4 in 52 mol H2O is (K2SO4 is (C) P + P
A B
100% ionised)
o o
(A) 2

55
(D) P
A
+ P
B

(B) 3

55
[Link] liquids ‘A’ and ‘B’ form a solution and it is observed
(C) 1 experimentally that P < x P and P < x P . Solution
A A
o
A B B
o
B
55
will show
(D)
1

2 (A) Lower boiling point than expected

Weaker forces of interaction between A and B than
(B)
those of A-A and B-B
(C) Volume of the solution phase decrease
(D) Positive deviation

9
104.C6H5–COOH (Benzoic acid) dimerises 50% in benzene [Link] osmotic pressure of 0.05 M monobasic acid having
and it ionises 20% in water. The ratio of van’t Hoff factors pOH = 12 at 25°C is
in dimerisation verses ionisation is (A) 2.75 atm
(A) 5 : 8 (B) 1.47 atm
(B) 8 : 5 (C) 1.55 atm
(C) 2 : 3 (D) 2.50 atm
(D) 1 : 1
[Link] of an aqueous solution in which mole fraction of
[Link] which of the following boiling point of solution will not be glucose is 0.1, is
increased? (A) 6.17 m
(A) Addition of NaCl in aqueous solution of urea (B) 0.72 m
(B) Addition of Na2SO4 in aqueous solution of glucose (C) 2.17 m
(C) Addition of HgI2 in aqueous solution of Kl (D) 12.34 m

(D) Addition of KNO3 in aqueous solution of sugar [Link] a solution of volatile liquids, the partial vapour
pressure of each component in the solution is
[Link] freezing point will be observed for which aqueous
solution? (A) Inversely proportional to temperature

(A) 0.1 M K4[Fe(CN)6] (B) Inversely proportional to its mole fraction

(C) Directly proportional to total number of moles
(B) 0.5 M NaCl
(D) Directly proportional to its mole fraction
(C) 0.2 M CaCl2
[Link] correct order of solubility of He, CO2 and O2 in water
(D) 0.01 M Urea
at 298 K and 1 atm is
[Link] composition of nitric acid and water mixture is (A) He > O2 > CO2
(by mass)
(A) 50% nitric acid and 50% water (B) O2 > CO2 > He

(B) 1% nitric acid and 99% water (C) CO2 > O2 > He
(C) 99% nitric acid and 1% water (D) CO2 > He > O2
(D) 68% nitric acid and 32% water [Link] the degree of dissociation of HA is 0.3, then the ratio of
108.A solute having 100 u molecular mass tetramerise in its observed osmotic pressure to calculated osmotic pressure
solution. If the degree of association is 0.25 then the is
abnormal molecular mass of solute in the solution is (A) 1
(A) 100 u (B) 1.3
(B) 123 u (C) 0.83
(C) 176 u (D) 0.6
(D) 400 u [Link] in weight by volume of 0.6 M AgNO3(aq)
[Link] of the following aqueous solutions has highest (molar mass of AgNO3 = 170 g/mol) is
vapour pressure?
(A) 17%
(A) 0.02 M glucose at 20°C
(B) 10.2%
(B) 0.005 M MgCl2 at 15°C (C) 8.6%
(C) 0.05 M KCl at 60°C (D) 5.1%
(D) 0.005 M MgCl2 at 60°C [Link] freezing point depression of aqueous solution of 0.2 m
110.A gas ‘x’ is dissolved in water at 2 bar pressure. Its mole aluminium sulphate is 1.674 K then the van’t Hoff factor
fraction is 0.02 in solution. The mole fraction of water will be
when the pressure of gas is doubled at the same (Kf of water = 1.86 K kg mol–1)
temperature is
(A) 3.5
(A) 0.04
(B) 4.5
(B) 0.02
(C) 2.5
(C) 0.98
(D) 3.9
(D) 0.96

10
[Link] molar mass of acetic acid which is dimerizes [Link] statement among the following is
75% in benzene solvent, is
A mixture of 68% nitric acid and 32% water by mass
(A)
(A) 60 forms maximum boiling azeotropes
(B) 96 The components of azeotropes cannot be separated
(B)
by fractional distillation
(C) 37.5
At azeotropic composition, the liquid and the vapour
(D) 30 (C)
have the same composition
[Link] of the following is not an application of Henry's law? Solution which shows negative deviation from Raoult's
(D)
law, form minimum boiling azeotrope
(A) Solubility of CO2 in soft drinks [Link] the given pair of solutions are separated by the
(B) Tanks used by scuba divers are filled with diluted air semipermeable membrane, then in which of following,
osmosis will not take place?
(C) Symptoms of anoxia at high altitude
(A) 0.2 M glucose and 0.2 M K2[PdCl4]
(D) Cooking in a pressure cooker
(B) 0.1 M NaCl and 0.5 M urea
120.A : Osmotic pressure is proportional to the molality of the
solution. (C) 0.3 M [Co(NH3)6]Cl3 and 0.4 M CaCl2
R : Osmotic pressure is independent of temperature.
(D) 0.4 M sucrose and 0.1 M MgCl2
Both Assertion & Reason are true and the reason is
(A) [Link] freezing point of the solution containing 0.25 moles of
the correct explanation of the assertion
CH3COOH in 500 g of water is equal to –1.15ºC. The
Both Assertion & Reason are true but the reason is not
(B) fraction of CH3COOH that undergoes dissociation is
the correct explanation of the assertion
(Given: Kf for water = 1.86 K kg mol–1)
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements (A) 0.33

[Link] 25°C, the highest value of molal depression constant is (B) 0.42
for which solution? (C) 0.24
(A) 0.1 M of glucose (D) 0.71
(B) 0.2 M of NaCl 128.A solution of urea received from some research laboratory
(C) 0.3 M of CaCl2 has been marked mole fraction (x) and molality (m) at
10°C. While calculating its molality and mole fraction in the
(D) All the above have same values laboratory at 24°C, you will find

[Link] the molality of NaOH in D2O is 2 m, then mole fractions (A) Mole fraction (x) and molality (m)
of D2O will be (B) Mole fraction (2x) and molality (2m)

(A) 1 (C) Mole fraction (x/2) and molality (m/2)

26

(D) Mole fraction (x) and molality (2m)

(B) 1

52
[Link] a homogeneous solution, the uniformity is observed in
(C)
49 its
50

(A) Composition as well as properties

(D) 25

(B) Only composition

26

[Link] exerted by vapours above the surface of liquid in (C) Only properties
liquid gas equilibrium depends on
(D) Neither composition nor properties
(A) Temperature
[Link] weight of NaCl and KCl are dissolved separately in
(B) Surface area equal volumes of solutions, then the molarity
(C) Nature of liquid
(A) Will be equal for the two solutions
(D) Both (1) and (3)
For NaCl solution will be greater than that of KCl
(B)
[Link] order of freezing points of equimolal aqueous solution
solutions is C < A < B. For KCl solution will be greater than that of NaCl
The correct order of their boiling point is (C)
solution
(A) A < C < B (D) For NaCl solution will be half of that of KCl solution
(B) B < C < A
(C) B < A < C
(D) A < B < C

11
[Link] much NaCl is to be dissolved in 60 g water to form a [Link] two solutions of concentration C1 and C2 (C1 > C2)
solution of 20% by mass? are separated by semipermeable membrane then
(A) 12 g (A) Flow of solvent molecules occurs from C2 to C1 only
(B) 1.2 g
(B) Flow of solvent molecules occurs from C1 to C2 only
(C) 15 g
Flow of solvent molecules occurs from C1 to C2 and
(D) 1.5 g (C)
C2 to C1 also
[Link] two liquids A (boiling point = t1°C) and B (boiling point =
(D) Flow of solute molecules occurs from C1 to C2
t2°C) on mixing forms azeotropic solution which shows
positive deviation from Raoult's law, then boiling point of [Link] the mass ratio of methanol and water in a solution is 4 :
azeotropic solution will be [Given, t1 > t2) 9, then the mole fraction of methanol in the solution will be

(A) > t1
(A) 0.4
(B) > (t1 + t2) (B) 0.1
(C) = t1 (C) 0.6
(D) < t2 (D) 0.2

133.A : When ethanol is added to water, boiling point of water [Link] osmotic pressure of 60% solution of glucose is 1.2 atm
increases. and that of 6.84% solution of cane sugar is 2.5 atm. The
R : When a volatile solute is added to a volatile solvent, osmotic pressure of the mixture containing equal volumes
elevation in boiling point is observed. of the two solution is

Both Assertion & Reason are true and the reason is (A) 7.40 atm
(A)
the correct explanation of the assertion (B) 3.70 atm
Both Assertion & Reason are true but the reason is not (C) 1.85 atm
(B)
the correct explanation of the assertion
(D) 2.50 atm
(C) Assertion is true statement but Reason is false
[Link] the following statements.
(D) Both Assertion and Reason are false statements
(a) CaCl2 undergoes 60% dissociation in water. The value
[Link] the correct statement of i for CaCl2 is 2.2.
(b) Ethanoic acid undergoes 60% dimerisation in benzene.
In reverse osmosis movement of solute particles The value of i is 0.7.
(A) occurs from high concentration to low concentration
(c) For dissociation i > 1 and for association i < 1.
through semi permiable membrane
The correct statements are
In reverse osmosis movement of solute particles (A) (a) and (b)
(B) occurs from low concentration to high concentration
through semi permiable membrane (B) (b) and (c)
Due to reverse osmosis raw mangoes shrivel when (C) (a) and (c)
(C)
pickled in brine
(D) (a), (b) and (c)
The direction of osmosis can be reversed if a pressure
larger than osmotic pressure is applied on solution [Link] the following two statements.
(D) Statement I: Molecules of ethanoic acid dimerise in
which is separated from solvent through semi
permiable membrane benzene due to H-bonding.
Statement II: Due to association, the number of particles
[Link] correct order of osmotic pressure of given aqueous is reduced.
solution is (consider 100% dissociation of electrolytes) Select the correct option among the following.
(A) 1 M glucose > 1 M sugar > 1 M KCl > 1 M CaCl2 (A) Both statements I and II are correct

(B) 1 M glucose = 1 M sugar = 1 M KCl = 1 M CaCl2 (B) Statement I is correct but statement II is incorrect
(C) Statement I is incorrect but statement II is correct
(C) 1 M glucose = 1 M sugar < 1 M KCl < 1 M CaCl2
(D) Both statements I and II are incorrect
(D) 1 M glucose = 1 M sugar > 1 M KCl > 1 M CaCl2

[Link] elevation constant depends on

(A) Molar mass of solvent
(B) Boiling point of pure solvent
(C) Enthalpy of vaporisation of solvent
(D) All of these

12
[Link] Henry’s Law constant for some gases in water. [Link] of solution on mixing
Gas Temperature/K KH /Kbar (A) Increases for both ideal and non-ideal solution
Ar 298 40.3 (B) Decreases for both ideal and non-ideal solution
CO2 298 1.67 Increases for ideal solution but decreases for non-ideal
(C)
solutions
HCHO 298 1.83 × 10–5
Decreases for ideal solution but increases for non-
CH4 298 0.413 (D)
ideal solutions
Arrange these gases in increasing order of solubility in
water 149.0.15 M Glucose solution and 0.05 M SrCl2 solution are
separated by a semi-permeable membrane in a container.
(A) CO2 < Ar < HCHO < CH4 For this system, the correct statement is
(B) Ar < CO2 < HCHO < CH4 Water flows from SrCl2 solution towards Glucose
(A)
solution
(C) CO2 < Ar < CH4 < HCHO
Water flows from Glucose solution towards SrCl2
(D) Ar < CO2 < CH4 < HCHO (B)
solution
[Link] the following statements There is no movement of any solution across the
(i) The solutions which show a large positive deviation (C)
membrane
from Raoult’s law form minimum boiling azeotrope.
(ii) Two solutions having same osmotic pressure at a given Osmotic pressure of Glucose solution is lower than
(D) osmotic pressure of SrCl solution
temperature are called isotonic solutions. 2
(iii) Kf is independent of solute concentration.
150.A : Ethylene glycol is used as coolant in car radiators
The correct statements is/are
under the name of coolant Prestone.
(A) (i) & (ii) only R : Lower the vapour pressure of a given substance,
smaller will be its boiling point.
(B) (ii) & (iii) only
Both Assertion & Reason are true and the reason is
(C) (i), (ii) & (iii) (A)
the correct explanation of the assertion
(D) (ii) only Both Assertion & Reason are true but the reason is not
(B)
[Link] osmotic pressure of 18% (w/v) solution of glucose at the correct explanation of the assertion
27ºC is (C) Assertion is true statement but Reason is false
(A) 24.63 atm (D) Both Assertion and Reason are false statements
(B) 30.25 atm 151. 2 × 10–3 mol kg–1 solution of a coordination compound
(C) 19.19 atm AB4C4 in water shows a fall in freezing point by 0.0108°C.
(D) 20.41 atm The structure of the compound will be (given Kf = 1.860

[Link] values of observed and calculated molecular weights Km–1)

of silver nitrate are 90 and 170 respectively. The degree of (A) [AB4C2] C2
dissociation of silver nitrate is
(B) [AB4C]C3
(A) 80%
(B) 75.46% (C) [AB4]C4

(C) 95.73% (D) [AB4C3]C

(D) 88.89% 152.A : Higher the value of KH (Henry’s constant) of a gas at a
[Link] freezing point of water is depressed by 0.37°C in a 0.01 given pressure, lower is the solubility of the gas in a liquid.
molal NaCl solution then freezing point of 0.02 molal R : Value of KH of a gas depends on the nature of the gas.
solution of urea is depressed by
Both Assertion & Reason are true and the reason is
(A)
(A) 0.37°C the correct explanation of the assertion
(B) 0.74°C Both Assertion & Reason are true but the reason is not
(B)
the correct explanation of the assertion
(C) 0.185°C
(C) Assertion is true statement but Reason is false
(D) 0.57°C
(D) Both Assertion and Reason are false statements
[Link] boiling points of liquids A, B, C and D are 63°C, 97°C,
101°C and 85°C respectively. Which of the following will [Link] mole fraction of a solute in benzene is 0.2, then the
have highest vapour pressure at room temperature? vapour pressure of this solution will be (given that vapour
pressure of pure benzene is 500 mm of Hg)
(A) A
(A) 450 mm of Hg
(B) B
(B) 425 mm of Hg
(C) C
(C) 400 mm of Hg
(D) D
(D) 300 mm of Hg

13
[Link] fraction of carbon in diamond is 160.0.5 M AgNO3 and 1 M KI are mixed in 1 : 3 volume ratio.
(A) 0.5 The depression of freezing point of the resulting solution
will be [Kf(H2O) = 1.86 K kg mol–1] (Assume dilute
(B) 1
solution)
(C) 0.25
(A) 0.279 K
(D) 0.34
(B) 27.9 K
[Link] the following Assertion (A) and Reason (R) and
(C) 0.0279 K
choose the correct option.
Assertion (A) : More the value of KH (Henry's Law (D) 2.79 K
Constant) , lesser will be solubility of gas in water.
[Link] freezing point of an aqueous solution (in °C) having
Reason (R) : CO2 is more soluble than H2 in water
6% urea and 18% glucose by weight is (Given, Kf water =
Both Assertion & Reason are true and the reason is 1.86 K kg mole–1)
(A)
the correct explanation of the assertion
(A) –4.89
Both Assertion & Reason are true but the reason is not
(B) (B) –3.51
the correct explanation of the assertion
(C) Assertion is true statement but Reason is false (C) –2.44
(D) Both Assertion and Reason are false statements (D) –1.22

[Link] of aqueous solution having mole fraction of solute [Link] the given properties of solution, how many are
equal to 0.1 is colligative properties?
(A) 5.55 m Osmotic pressure, Relative lowering in vapour pressure,
Boiling point, Elevation in boiling point, Vapour pressure
(B) 6.17 m
(C) 2.78 m (A) 3

(D) 3.08 m (B) 4

(C) 1
[Link] concentration term is temperature independent?
(D) 2
(A) Molarity
163.A : Osmotic pressure of 0.1 M NaCl is equal to that of 0.1
(B) (
W

W
)% M glucose solution.
R : When molarity of two solutions is same then their
(C) (
W
)%
osmotic pressure are same.
V

Both Assertion & Reason are true and the reason is

(A)
(D) Normality the correct explanation of the assertion
158.A : An increase in surface area increases the rate of Both Assertion & Reason are true but the reason is not
(B)
evaporation. the correct explanation of the assertion
R : Stronger the inter-molecular attractive forces, slower is (C) Assertion is true statement but Reason is false
the rate of evaporation at a given temperature.
(D) Both Assertion and Reason are false statements
Both Assertion and Reason are true and the reason is
(A)
the correct explanation of the assertion [Link] properties of solution depends on
Both Assertion and Reason are true but the reason is (A) Nature of solute particles
(B)
not the correct explanation of the assertion
(B) Number of solute particles
(C) Assertion is true statement but Reason is false
(C) Number of solvent particles
(D) Both Assertion and Reason are false statements
(D) Volume of the solution
159.A : The osmotic pressure of a solution is the excess
pressure that must be applied to a solution to prevent [Link] a dilute solution ratio between vapour pressure of
osmosis. solution and solvent is 7:8. If solvent is water then molality
R : For dilute solution osmotic pressure is proportional to of solution will be
molarity. (A) 7.94 m
Both Assertion and Reason are true and the reason is (B) 17.2 m
(A)
the correct explanation of the assertion
(C) 3.97 m
Both Assertion and Reason are true but the reason is
(B) (D) 16.8 m
not the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

14
[Link] a solute AB2, 40% dissociates (behaving as ternary [Link] below are two statements one is assertion (A) other
electrolyte) and 60% dimerizes then its van't Hoff factor 'i' is reason (R)
is Assertion (A): Aquatic species are more comfortable in
cold water than in warm water.
(A) 1 Reason (R): Solubility of oxygen in water decreases with
(B) 1.4 increase in temperature.
In the light of above statements choose the correct
(C) 1.5 answer.
(D) 0.7 Both assertion and reason are correct statements, and
(A)
reason is the correct explanation of the assertion.
[Link] the following statements
I. Pressure does not have any significant effect on Both assertion and reason are correct statements, but
(B)
solubility of solids in liquids. reason is not the correct explanation of the assertion.
II. Higher the value of KH at a given pressure, the lower is
(C) Assertion is correct, but reason is wrong statement.
the solubility of the gas in the liquid.
III. At high altitudes the partial pressure of oxygen is high (D) Assertion is wrong, but reason is correct statement.
than that at the ground level.
[Link] boiling point of 0.1 m aqueous solution of an
The correct statement(s) is/are
electrolyte was 100.0832 °C. If the electrolyte dissociates
(A) Only I 60% in the solution, then electrolyte may be (Given : Kb =
(B) I and II 0.52 K kg mol–1)
(C) Only III (A) AB
(D) II and III (B) AB2
[Link] pressure of liquid does/do not depend(s) on (C) AB3
(A) Surface area (D) A2B2
(B) Temperature
[Link] 36 g of a solute having the empirical formula CH2O
(C) Nature of liquids is dissolved in 1.20 kg of water, the solution freezes at –
(D) All of these 0.93ºC. What is the molecular formula of the solute? (Kf =
1.86 K kg mol–1)
[Link] inorganic precipitate acts as semipermeable
membrane? (A) C3H6O3
(A) Calcium sulphate
(B) C4H8O4
(B) Nickel phosphate
(C) CH2O
(C) Barium oxalate
(D) C2H4O2
(D) Copper ferrocyanide
175.A : Pressure does not have any significant effect on
170.A solution containing 4 g of PVC in 2 litre of dioxane solubility of solids in liquids.
(industrial solvent) was found to have an osmotic pressure
R : Solids and liquids are highly incompressible.
3 × 10–4 atm at 27ºC. The molar mass of the polymer
(g/mol) will be Both Assertion & Reason are true and the reason is
(A)
the correct explanation of the assertion
(A) 1.6 × 104
Both Assertion & Reason are true but the reason is not
(B)
the correct explanation of the assertion
(B) 1.6 × 105
(C) Assertion is true statement but Reason is false
(C) 1.6 × 103
(D) Both Assertion and Reason are false statements
(D) 1.6 × 102
[Link] pressure of solution containing 3.6 g glucose and
[Link] the incorrect statement 1.2 g of urea in 250 ml at 27ºC approximately will be

Elevation in boiling point is the result of lowering in (A) 2.8 atm

(A) vapour pressure, when a non-volatile solute is added (B) 3.9 atm
to a solvent
(C) 4.2 atm
Lowering of vapour pressure for a dilute solution of
(B) non-volatile solute is directly proportional to the mole (D) 5.1 atm
fraction of the solute
[Link] of the following is used as antifreeze in automobile?
Boiling point of the sugar solution is larger than that of
(C)
the pure solvent
(A) Phenol
Vapour pressure of the sugar solution is greater than
(D) (B) Ethylene glycol
that of pure solvent
(C) Acetone
(D) Benzene

15
178.A: Mass%, ppm and normality are independent of [Link] I: Dissolution of gas in liquids is an exothermic
temperature. process.
R: Volume depends on temperature and the mass does Statement II: Solubility of gases in liquid decreases with
not. rise in temperature.
In the light of the above statements, choose the correct
Assertion and reason both are correct statements and answer from options given below.
(A)
reason is correct explanation for assertion.
(A) Statement-I is incorrect but statement-II is true
Assertion and reason both are correct statements but
(B)
reason is not correct explanation for assertion. (B) Both statement-I and statement-II are true
Assertion is correct statement but reason is wrong (C) Both statement-I and statement II are false
(C)
statement.
(D) Statement-I is correct but statement-II is false
Assertion is wrong statement but reason is correct
(D)
statement.
[Link] (A): The molar mass of proteins is mostly
calculated by finding out the value of ΔTb.
Reason (R): Kb depends on molar mass of protein.

Both Assertion & Reason are true and the reason is

(A)
the correct explanation of the assertion
Both Assertion & Reason are true but the reason is not
(B)
the correct explanation of the assertion
(C) Assertion is true statement but Reason is false
(D) Both Assertion and Reason are false statements

16