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0% found this document useful (0 votes)
3 views29 pages

Solution

The document contains a series of physics, chemistry, and mathematics problems, each with multiple-choice answers. It includes questions on topics such as motion, thermodynamics, chemical reactions, and geometric properties. The problems are structured to assess knowledge in various scientific and mathematical concepts.

Uploaded by

nikhilog7
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

21-01-2026

2302CJA101003250044 JA

PART-A-PHYSICS

SECTION-I(i)

1) A trolley is moving horizontally with a constant velocity of v m/s w.r.t. earth. A man starts
running from one end of the trolley with a velocity 1.5v m/s w.r.t. to trolley. After reaching the
opposite end, the man return back to starting end and continues running with a velocity of 1.5 v m/s
w.r.t. the trolley in the backward direction. If the length of the trolley is L then the displacement of

the man with respect to earth during the process will be :

(A) 2.5L
(B) 1.5L

(C)

(D)

2) A small block of mass m is kept on a rough inclined surface of inclination θ fixed in a elevator. The
elevator goes up with a uniform velocity v and the block does not slide on the wedge. The work
done by the force of friction on the block in time t will be

(A) zero
(B) mgvt cos2θ
(C) mgvt sin2θ
(D) mgvt sin2θ

3) A disc of radius R is rolling without slipping with an angular acceleration on a fixed horizontal
plane. Four points are marked at the end of horizontal and vertical diameter of a circle on the
disc. If horizontal vertical direction are chosen as x and y axis as shown in the figure, then
acceleration of points and 4 are and respectively, at the moment when angular
velocity of the disc is Match the following
Column - I Column - II

A P

B Q

C R

D S

T None of these
(A)
(B)
(C)
(D)

4) A hollow sphere of radius R is filled completely with an ideal liquid of density ρ. Sphere is moving
horizontally with an acceleration 2g, where g is acceleration due to gravity in the space. If minimum

pressure of liquid is P , then pressure at the centre of sphere is :-

(A) P0 + pgR
P0 + pgR
(B)

P0 + pgR
(C)

(D)

5) There are three identical particles of masses M as shown in the given arrangement and the only
forces present are mutual gravitational force of attraction. Kinetic energy of the system would be
(tringle is equilateral)

(A)

(B)

(C)

(D) None of these

6) A long metallic bar is carrying heat from one of its ends to the other end under steady-state. The
variation of temperature θ along the length x of the bar from its hot end is best described by which
of the following figures ?

(A)

(B)

(C)
(D)

SECTION-I(ii)

1) A rod is hinged as shown. A particle of same mass collides with its end and sticks with it. Choose

the correct option(s)

(A)
Angular veocity of rod just after collision is
(B) Angular momentum of rod + particle is conserved about hinge.
(C) Linear momentum of rod + particle is conserved
(D) During collision kinetic energy of rod + particle is conserved

2) An elastic spring of force constant k and natural length 3 ℓ0 is cut into two parts so that their
natural lengths are 2ℓ0 and ℓ0 respectively. One end of these springs are attached to points P and Q,

on a fixed vertical wall and tied with a block of mass m.

(A) In equilibrium the distance of block from the vertical wall is 4ℓ0/3.
(B) In equilibrium the distance of block from the vertical wall is 5ℓ0/3.
(C) The force constant of shorter part of the spring is 3k.
(D) The force constant of larger part of the spring is 2k/3.

3) In which of the following cases, the work done by the gas during the entire cycle is negative?
(A)

(B)

(C)

(D)

4) A poorly designed electrostatic device contain steel and copper bolt having gap between them is
21.55µm at 27°C. Choose the correct statement(s) :- [αsteel = 3.55 × 10–5 k–1, αcopper = 6 × 10–5 k–1]

(A) The temperature at which gap between them is filled is 28°C


(B) The temperature at which gap between them is filled is 27.5°C
(C) Change in length in steel is 3.55 µm
(D) Change in length in copper is 13.55 µm

5) For the given situation :

(A) acom = 0
(B) vcom = 4.5 m/s
(C) vA/B = 3 m/s at t = 0
(D) Velocity of A when slipping stops = 4.5 m/s

6) The spring balance A reads 2kg with a block M suspended from it. A balance B reads 5 kg when a
beaker with liquid is put on the pan of the balance. The two balances are now so arranged that the
hanging mass is inside the liquid in the bearker as shown in the figure. In this situation,

(A) The balance A will read more than 2 kg.


(B) The balance B will read more than 5 kg.
(C) The balance A will read less than 2 kg and B will read more than 5 kg.
(D) The balance A and 8 will read 2 kg and 5 kg respectively.

SECTION-III

1) A solid floats with 1/3 of its volume immersed in liquid-A and with 3/5 of its volume immersed in
liquid-B. A homogenous mixture is created by mixing equal volumes of both liquid-A and B, then

fraction of solid immersed in mixture is a/b. Fill the value of in OMR.

2) Two moles of a diatomic gas undergoes two process in succession. Starting from temperature T1,
it is first heated at constant volume until its pressure is tripled. It is further heated at constant
pressure until its volume is doubled. What is the average molar heat capacity for the whole process?
If your answer is nR, where R is universal gas constant. Round off n to nearest integer.

3) Heat is supplied at a constant rate to a cube of ice which is melting at rate of 0.2 gm/sec. It melts
completely in 40 sec. What will be the rate of rise of temperature (in °C/sec) after melting is
completed? (Lf = 80 cal/gm, Sw = 1 cal/gm°C)

4) In the figure as shown, a triangular portion is cut from a circular disc of radius R. The distance of

centre of mass of the remaining portion from the centre of disc is . Calculate
5) A solid cone of circular cross-section having base radius R, height ℓ and mass m is suspended
from its base as shown in the figure. The material of cone has Young's modulus Y. The elastic

potential energy stored in the cone is , the value of k/2 is.

PART-B-CHEMISTRY

SECTION-I(i)

1) The major product of the following reaction is:

(A)

(B)

(C)
(D)

2) The increasing order of nucleophilicity of the following nucleophiles is :


(a) (b) H2O

(c) (d)

(A) (b) < (c) < (a) < (d)


(B) (a) < (d) < (c) < (b)
(C) (d) < (a) < (c) < (b)
(D) (b) < (c) < (d) < (a)

3)
Correct IUPAC name of compound is :

(A) 1,2-dimethyl cyclobutene


(B) 2,3-dimethyl cyclobutene
(C) 1,2-dimethyl cyclobut-2-ene
(D) 1,4-dimethyl cyclobutene

4) 100 g CaCO3 is taken in a closed container (15 litres), heated at 1000 K and equilibrium attained
according to reaction. If 75% of CaCO3 was decomposed at
equilibrium. The value of KP is :

(A) 4.1
(B) 8.2
(C) 15
(D) 0.41

5) In hydrogen atom, two electrons move around the nucleus in circular orbits of radii R and 4R.
Find the ratio of the time taken by them to complete one revolution ? (Considering Bohr's atomic
theory is applicable)

(A) 1 : 4
(B) 4 : 1
(C) 1 : 8
(D) 8 : 1

6) Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of metal
is approximately. [At. wt. Cl = 35.5]

(A) 21
(B) 54
(C) 27
(D) 37

SECTION-I(ii)

1) Which of the following orbital(s) have 'xy' as their nodal plane ?

(A) pz
(B) dxz
(C) dyz
(D)

2) Choose isoelectronic pair(s) .

XeF4 ,
(A)

(B) , XeO3
(C) NOF, O3
(D)

3) Select correct statement(s) about photoelectric effect -

If green light ejects photoelectron from metal 'M' , then red light never eject photoelectrons for
(A)
metal M
If green light ejects photoelectron from metal 'M' then red light may not eject photoelectrons
(B)
even if it has high intensity for metal M
If green light ejects photoelectron from metal 'M' with low photocurrent then more photo
(C)
intense blue light must have high photocurrent for metal M
If green light ejects photoelectron, then blue light must eject photoelectron with more energy
(D)
for metal M

4) An ideal gas undergoes adiabatic expansion against constant external pressure. Which of the
following is incorrect :

(A) Temperature of the system decreases.


(B) The relation PVγ = constant will be valid (where P and V are gas variables)
(C) ΔE + PextΔV = 0
(D) Enthalpy of the gas remains unchanged.

5)

Which is/are correct statements about 1.7 g of NH3 :

(A) It contain 0.3 mol H – atom


(B) It contain 2.408 × 1023 atoms
(C) Mass % of hydrogen is 17.65%
(D) It contains 0.3 mol N-atom

6) 20 gm of CuSO4 sample is allowed to react wtih excess of KI solution so that I2 produced is

estimated by Hypo solution, for this , 200 ml of Hypo solution is used. Which of the following
is/are correct (Atomic wt. Cu = 64) ?

(A) Weight of pure CuSO4 is 3.2 g in sample


(B) % purity of CuSO4 sample 32%
(C) 0.01 moles of I2 produced
(D) 0.04 moles of KI is used with CuSO4

SECTION-III

1) Find ΔG(J/mol) for the reaction at 300kPa & 27ºC when all gases are in stoichiometric ratio of
moles. N2O4(g) → 2NO2(g) [ln2 = 0.7]

Given :

R = 8 J/mol-K
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

2) Total number of nodes present in 5s orbital -

3) Br2(ℓ) reacts with Cl2(g) to form BrCl and BrCl3, simultaneously. How many moles of Cl2(g) reacts
completely with 3 moles of Br2(ℓ) to form BrCl and BrCl3 in 5 : 1 molar ratio?

4) What is the degree of freedom of NH3 at room temperature ?

5) Given the following empirical formula and molecular weight, find the number which when
multiplied to empirical formula will change it into molecular formula:

Empirical formula Molecular weight

CH2 84

PART-C-MATHEMATICS

SECTION-I(i)

1) If x = then value of (1 + x)48 is :-


(A) 5
(B) 25
(C) 125
(D) 625

2) If 2sin2 θ = 3 cos θ where θ ∈ [0, 2π], then θ =

(A)

(B)

(C)

(D) None

3) Value of expression is :-

(A)
(B)
(C)
(D)

4) 17C15 + 18C16 + 19C17 + 20C18 + 21C19 + 22C20 =

40
(A) C35
22
(B) C15
(C) 1091
(D) 253

5) The number of ways to give away 20 identical apples to 3 boys, each boy receiving at least 4
apples is :

10
(A) C8
(B) 90
22
(C) C20
(D) 50

6) The equation of ellipse, whose focus is (1, 0), the corresponding directrix is x = 4 and its
eccentricity is a root of equation is

(A)
(B)
(C)
(D)
SECTION-I(ii)

1) N = 22. 33.54.7, then -

(A) Number of proper divisors of N(excluding 1 & N) is 118


(B) Number of proper divisors of N(excluding 1 & N) is 120
(C) Number of unordered positive integral solutions of xy = N is 60
(D) Number of unordered positive integral solutions of xy = N is 120

2) Let P be the point on the parabola y2 = 4x which is at the shortest distance from the center S of
the circle x2 + y2 – 4x – 16y + 64 = 0. Let Q be the point on the circle dividing the line segment
SP internally. Then-

SP =
(A)

(B) SQ : QP =
(C) the x-intercept of the normal to the parabola at P is 6
the slope of the tangent to the circle at Q is
(D)

3) If a hyperbola passes through the foci of the ellipse and its transverse and conjugate
axis coincides with the major and minor axis of the ellipse and product of their eccentricities is 1,
then -

equation of hyperbola
(A)

equation of hyperbola
(B)

(C) focus of hyperbola (5, 0)


focus of hyperbola
(D)

4) Let C and C1 be circles of radii 1 and r > 1 respectively touching the coordinate axes. Then which
of the following statement(s) is (are) correct ?

(A)
If C passes through the centre of C1 then r equals .
(B) If C and C1 touch each other then r equals .
(C) If C and C1 are orthogonal then r equals .
(D) If C and C1 have longest common chord then r equals 3.

5) Let distance between parallel tangents of ellipse x2 + 2y2 = 2 is . If quadrilateral ABCD is


formed by these tangents, then
(A) ABCD is a parallelogram.

(B)
area of quadrilateral ABCD is

(C)
slope of tangents are
(D) slope of tangents are ±3

6) If extremities of latus rectum of a hyperbola are (3, 5), (3, –1), (–1, 5), (–1, –1) and its transverse
axis is parallel to x-axis, then

(A) its eccentricity is 2


(B) its eccentricity is greater than 2

(C)
one of its directrix is

(D)
one of its directrix is

SECTION-III

1)

If and , then the value of is

2) In a ΔABC, with usual notations, if 8b = 5c and ∠C = 2∠B, then the value of 25 cos C is equal to

3) Consider the family of circles passing through two fixed points A and B.
Then the distance between the points A and B is

4) y + x = 0 & y – x = 0 are tangent at the vertex & axis of a parabola respectively and y = 2x + 3 is
a tangent to the same parabola, the coordinate of whose focus is (a, b), then 6(a + b) is equal to

5) If the straight lines 7x – 2y + 10 = 0 and 7x + 2y – 10 = 0 and y + 2 = 0 form an isosceles triangle


of area 2k, then the value of k is ___.
ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. D D A C C D

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,B A,C B,D A,C A,B,C,D B,C

SECTION-III

Q. 13 14 15 16 17
A. 5 3 2 6 5

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. C A D A C C

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. A,B,C A,B,C B,C,D B,D A,B,C A,C,D

SECTION-III

Q. 30 31 32 33 34
A. 3 4 4 6 6

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. C B B C A D

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,C A,C,D A,C A,B,C,D A,B,C A,C,D
SECTION-III

Q. 47 48 49 50 51
A. 3 7 6 4 7
SOLUTIONS

PART-A-PHYSICS

1) Question Explanation:
Find man's net displacement w.r.t Earth after running forward and back on a moving trolley.

Concept:
Velocity of man = Velocity of trolley + Velocity of man WRT trolley

Solution:
Forward run:

Velocity of man = 2.5 v ; time

Backward run:

Velocity of man = –0.5 v; time

Net displacement:

Final Answer: the correct option is (4).

2)

Question Explanation : The question asks to find the work done by the frictional force on a
block resting on an inclined plane inside an elevator moving upward with constant velocity.
Concept : This question is based on work done by friction force.
Solution : Force of friction along incline : f = mgsin θ
Vertical component of friction: fy = f sinθ = mgsin2θ
Displacement of block in time t : d = v × t
Work done by friction: W = fy × d = (mgsin2θ) × (v × t)
Final Answer : Option (4)

3) For (A): Acceleration of 1 w.r.t. centre of mass

For (B):
For (C):

For (D):

4)
Explanation Question: Variation of pressure is to be analysed in accelerated liquid.
Concept: This question is based on accelerated liquid.
Solution:
—→ 2g

Final Answer
The correct option is (3)

5) Question Explanation:
Finding the kinetic energy of a system of three identical masses in a stable circular orbit.

Concept:
Virial Theorem & Gravitational Potential Energy.

Solution:
For a system of particles moving under a force that varies as 1/r2 (like gravity), the Virial
Theorem states that the average total kinetic energy is related to the average total potential
energy by 2〈K.E.〉 = −〈P.E.〉. Since the particles are in a stable circular orbit, their energies
are constant. We first calculate the total potential energy of the system.
The system consists of three pairs of masses. The distance between each pair is 'a'.
Total Potential Energy (P.E.):

Applying Virial Theorem:

Final Answer:
Correct answer is (3).

6) Question Explanation: The question asks for the temperature-distance graph for a
metallic bar under steady-state heat conduction.

Concept: Steady-state heat conduction and temperature gradient.

Solution:

Under steady state

Slope of θ v/s x graph should be constant & represents a straight line.


Final answer: option (4)

7)

about hinge there is not external angular impulse.

8)

Explanation Question:

An elastic spring is cut into two parts of different length and attached to a mass as shown in
figure, it is asked to choose the correct options.

​Concept:
This question is based on spring and spring force.

Solution:

(3ℓ0)k = (2ℓ0)k1 = (ℓ0)k2

k2 = 3k

2x – 2ℓ0 = 2ℓ0 – x
3x = 4ℓ0

Final Answer
The correct option are (1), (3)

9) Convert to PV graph and solve


10) Explain question : We are given a electrostatic device in which steel and copper bolt are
used. We have to choose correct option(s).
Concept : This question is based on thermal expansion.
Solution :
Δℓ = 21.55 = Δℓs + ΔℓC
Δℓ = 21.55 = ℓsαsΔT + ℓCαCΔT
ΔT = 1°C
Tf – 27 = 1°C
Tf = 28°C
Final answer : 1, 3

11) Fext = 0 ⇒ acom = 0

/s
= 6 – 3 = 3 m/s

12)
spring balance A read less than 2kg

balance B reads more then 5 kg

13) ρ → density of solid

ρA = 3ρ ; ρB =

rmixture = ⇒ ⇒

Fraction of solid submerged in mixture=

Answer a = 3, b = 7;

14)

Explain Question : The problem asks to find the molar heat capacity or for the entire process
involving a diatomic ideal gas undergoing two successive processes (1) constant volume
process (Heated until its pressure is tripled) (2) constant pressure (further heated until its
volume is doubled). We need to find value of n.
Concept : Molar heat capacity, constant volume & constant pressure process.
Solution :
ΔQ = nCV2T1 + nCP(3T1)

ΔT = 5T1

∴C=

= = 3.1 R
Final answer : The average molar heat capacity for the whole process is 3.1 R, Rounding n to the
nearest integer gives the answer as 3.

15)

...(i)
0.2 × 40 = m
m = 8 gm

...(ii)
(i) / (ii)

1=

16)
Here α = 3
β=4

=
17)

Weight of OCD =

Stress at CD =

=
Total elastic energy

PART-B-CHEMISTRY

18)

Explaining the Question :- Question is asking about electrophilic substitution reaction of


given benzene.
Concept :- This Question is based on Electrophilic substitution reaction of benzene.
Solution :-

Final Answer :- (3)

19)
ione pair donating tendency on oxygen is reduced, nucleophilicity reduced b < c < a < d
20)

Explanation Question: To write IUPAC name of the given compound


Concept: This question is based on nomenclature of cycloalkenes

Solution:
1,4-Dimethyl cyclobutene

Final Answer option : (4)

21)

= 4.1 atm

22)

Question Explanation: Find the ratio of time.


Concept : This question is based on Bohr Model
Solution:

Time period of Revolution =

z=1

Final Answer:
option (3)

23) Question Explanation:


Using composition data of two compounds to find atomic weight.

Concept:
This question is based on Valency and Atomic Mass.
Solution:

V.D. = , M’ = 132
metal chlroide MCln
⇒ M + n × 35.5 = 132 ... (1)
Metal oxide M2On

⇒ ...(2)
Solving (1) and (2)
M = 27

Final Answer:
The correct option is (3)

24) Orbital Nodal Plane


Pz xy
dxy xz & yz
dyz xy xz
Final Answer: Option (1, 2 & 3)

25) Question Explanation: Identifying pairs with the same number of total electrons.
Concept: Isoelectronic Species
Solution: Isoelectronic species are atoms, molecules, or ions that have the same number of
electrons. To find them, we sum the atomic numbers of all atoms in the species and adjust for
any ionic charge.

Final Answer: Options 1, 2, & 3

26)

27)

In adiabatic expansion, q = 0. So ΔE = W = –Pext ΔV.


Irreversible adiabatic So PVγ = constant not valid.
Since q = 0, so gas does work by utilizing its internal energy.
So, T decreases and also enthalpy (H) decreases.

28)
0.1 moles of NH3 contains :
(A) 0.3 mole H-atoms
(B) Number of atoms
= 0.1 × (4 × 6 × 1023 ) ⇒ 2.4 × 1023

(C) % Mass of Hydrogen =


(D) 0.1 moles of NH3 contains 0.1 mole N-atoms.

29) 2CuSO4(aq.) + 4KI(aq.) —→ Cu2I2↓ + I2 + 2K2SO4


I2 + 2Na2S2O3 —→ Na2S4O3 + 2NaI

mole of I2

wt. CuSO4 = 0.02 × 160 = 3.2g

30) ΔG = ΔGº + RT ln Q
ΔGº = 2ΔGfº(NO2) – ΔGfº (N2O4) = 0

ΔG = 8 × 300 ln = 3360 J

31) Question Explanation:


Find total number of nodes in 5s

Concept :
This question is based on Nodes.

Solution:
Total number of radial nodes
=n–ℓ–1=5–0–1=4
Total number of angular nodes = 0
Total number of nodes = 4 + 0 = 4

Final Answer : 4

32) 3Br2 + 4Cl2 → 5 BrCl + BrCl3

33)

Question Explanation: Determine the total degrees of freedom for an NH3​ molecule at room
temperature.
Concept: Degrees of freedom (f=3N−k)
Solution: NH3 is a non–liner molecule
Translational DOF = 3
Rotational DOF = 3
Vibrational DOF (at room temp.) = 0
So total DOF = 6
Final Answer : 6

34) Question Explanation:


Find the number which when multiplied to empirical formula will change it into molecular
formula.

Concept:
This question is based on empirical formula and molecular formula.

Solution:

n=

Final Answer: 6

PART-C-MATHEMATICS

35) x =

x=

x=
x + 1 = 51/16
(x+1)48 = 53 = 125

36) 2(1 – cos2 θ) = 3 cos θ


2 cos2 θ + 3 cos θ – 2 = 0
(2 cos θ – 1) (cos θ + 2) = 0

37)

=
= – tan (62° – 2°) =

38) 17C15 + 18C16 + 19C17 + 20C18 + 21C19 + 22C20


= 17C2 + 18C2 + 19C2 + 20C2 + 21C2 + 22C2

=
= 136 + 153 + 171 + 190 + 210 + 231 = 1091
39) x1 + x2 + x3 = 8 ⇒ ∴ n+r–1Cr–1 = 10C2 = 10C8

40)

41) N ≡ 22 . 33 . 54 . 71
Total no. of divisor
= (2 + 1)(3 + 1)(4 + 1)(1 + 1)
= 3 × 4 × 5 × 2 = 120
& no. of proper divison = 118
option A is correct
Now if N = xy
⇒ N can be expressed as a product of two no. in how many ways.

which is equal to

Final Answer: options (1), (3)

42)
y2 = 4x
point P lies on normal to parabola passing through centre of circle
y + tx = 2t + t3 ...(i)
3
8 + 2t = 2t + t
t=2
P(4, 4)

SP =
SP =
SQ = 2
⇒ PQ = –2

To find x intercept
put y = 0 in (i)
⇒ x = 2 + t2
x=6
∵ Slope of common normal = –t = –2
∴ Slope of tangent =

43) Eccentricity of ellipse =


Eccentricity of hyperbola = and it passes through (±3, 0)

⇒ its equation

where ⇒ b2 = 16

⇒ and its focii are (±5, 0)

44)

C : (x – 1)2 + (y – 1)2 = 1
C1 : (x – α)2 + (y – α)2 = α2, α > 1

(A)
(B) C C1 = r +1
⇒ 2 (r – 1)2 = (r + 1)2

(C) Using condition of orthogonality, we get


2r (1) + 2(r) (1) = r2 + 1 ⇒
(D) Equation of common chord is
(x2 + y2 – 2x– 2y + 1) – (x2 + y2 – 2rx – 2ry + r2) = 0 ⇒ 2 (r – 1) x + 2 (r – 1) y + (1 – r2) = 0
As (1,1) lies on it ⇒ r = 3

45) Let equation of tangents



Area =

46) ae = 2,
a(e2 – 1) = 3

2e2 – 3e – 2 = 0
2e2 – 4e + e – 2 = 0
⇒ e = 2 (–½ rejected)
foci (3, 2), (–1, 2) ⇒ center (1, 2)

⇒ directrix are and

47)

48)

49)

or
which if of the form
All the circles pass through the point of intersection of the
circle
Solving, we get

or

and
Hence,

50) Intersection point of tangent at vertex & give tangent is (–1, 1).
perpendicular from focus on given tangent meets it at tangent at vertex.

⇒ focus is the intersection point of y = x &

⇒ coordinate of focus is

⇒ 6(a + b) = .

51)

2k = 14
k=7

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