Solution
Solution
1701CJA101029260022 JA
PART-1 : MATHEMATICS
SECTION-I (i)
Which of the following options are true with respect to the given functions f(x) and g(x)
(A) f(x) is continuous ∀ x ∈ [0, 2] and not differentiable at atmost 2 points in [0, 2]
(B)
(C) Let Z(x) = and Y(x) = then Z(x) and Y(x) vanish simultaneously at no
real value of x
(D) Number of solutions of f(x) = g(x) is 4
2) Let f : [0,3] → R be continuous and twice differentiable on (0,3). Further f(x) = 0 has exactly four
real roots as x = 0,1,2,3 and g(x) = f"(x) + 2f'(x) + f(x) never vanishes in any of the intervals (0,1) or
(1,2) or (2,3). Which of the following is/are true ?
(A) f'(x) + f(x) = 0, has exactly five solution in (0,1) ∪ (1,2) ∪ (2,3)
(B) f'(x) + f(x) = 0, has exactly one solution in (0,1)
(C) f'(x) + f(x) = 0, has exactly one solution in (2,3)
(D) f'(x) + f(x) = 0, has exactly two solution in (1,2)
3) Let f : → be given by
(A) k4 = 4
(B) k8 = – 16
(C) k12 = 24
(D) k16 = 48
5) For the figure given below if where m and n are relatively prime positive integers then
(A) m + n = 463
(B) n – m = 122
(C) 2m – n = 41
(D) m + n = 465
(A)
(B)
(C)
(D)
SECTION-I (ii)
Let where a < b < c < d. Column-I: contains information about real roots of the
equation; Column-II: contains information about limit of f(x); Column-III: contains information about
increasing interval and decreasing interval of f(x) and f'(x) and information about local minimum
value and local maximum value of f(x)
1)
2)
3)
SECTION-II
1) Let a,b,c be positive real numbers such that . If the minimum value of λ is
'p' then the value of 6p equals
5) If for , then is
6) If cos–1 (2 – x2) + sin–1 (2 – x2) + tan–1 x ≥ have no solution if x < α or x > β (for α < β), then
value of .
PART-2 : PHYSICS
SECTION-I (i)
1) The mechanical energy of a system is given by E = Ax2 + Bv2 where x is the displacement from (x
= 0) and v is the velocity of the body at x then choose the correct statement(s). Assume A and B
positive constant.
(A)
The maximum x coordinate is
(B)
Maximum velocity of the particle during motion is 2
(C) x = 0 is the equilibrium position.
(D)
The acceleration of the system at any point is
2) Two independent harmonic oscillators of equal mass are oscillating about the origin with angular
frequencies 10 rad/s and 20 rad/s and have total energies 5J and 10J, respectively. The variations of
their momenta p with positions x are shown in the figures, then the correct statement (s) is (are)
(A) m = 50 gm
(B) force constant for oscillator with energy of 5J is 5N/m
(C) force constant for oscillator with energy of 10J is 20 N/m
(D) Amplitude for both oscillators is the same
3) A uniform electric field, = – 400 NC–1 is applied in a region. A charged particle of mass m
carrying positive charge q is projected in this region with an initial speed of 2 × 106 ms–1. This
particle is aimed to hit a target T, which is 5 m away from its entry point into the field as shown
(A) the particle will hit T if projected at an angle 45º from the horizontal
(B) the particle will hit T if projected either at an angle 30º or 60º from the horizontal
(C)
time taken by the particle to hit T could be µs as well as µs
(D)
time taken by the particle to hit T is µs
4) Position vector of a particle varies with time as . Then select the correct statement(s):
(A) VP = Vsin60°
(B) VP = V
(C) aP = a
(D)
aP =
SECTION-I (ii)
1) In which of the following case. Real image of virtual object is moving away from mirror/lens:-
2) Which of the following represents real image of real object going towards mirror/lens :-
(A) (IV) (ii) (S)
(B) (II) (i) (R)
(C) (III) (iii) (R)
(D) (I) (iii) (P)
3) Which represents real image of real object going away from mirror/lens :-
SECTION-II
1) Sunlight of intensity 1.3 kW m–2 is incident normally on a thin convex lens of focal length 20 cm.
Ignore the energy loss of light due to the lens and assume that the lens aperture size is much
smaller than its focal length. The average intensity of light, in kW m–2, at a distance 22 cm from the
lens on the other side is _________.
3) A particle is projected from point 'A', that is at a distance 4R from the centre of the earth, with
0
speed v as shown. If the particle passes grazing the earth's surface, then it is found that
. Find the value of N where mass and radius of earth is M and R respectively :
4) Figure shows a binary star system revolving about their COM. The masses of star A & B are 15 ×
1030 kg and 30 × 1030 kg respectively. Find the ratio of area swept by star A to area swept by star B
5) In the figure shown, segments AB, BC, CD and DA, as well as the diagonal segments AC and BD
have a resistance 2Ω each. The mid points of the diagonal wires are soldered with each other. Find
the effective resistance between the mid points of sides AD and CD.
6) In the circuit shown in figure, if the internal resistance of the sources are negligible, then
maximum power generated in R is approximately (n + 13) W, where n being an integer. What is the
value of n?
PART-3 : CHEMISTRY
SECTION-I (i)
1) When XY2(s) is dissolved in water at 27°C, [X2+] becomes 10–2M at equilibrium. At 37°C the vapour
pressure of this solution in water is 99.829 mm Hg. Given: Vapour
pressure of pure water at 37°C = 100 mm Hg. Both X2+ and Y– are non-volatile. (ℓn2 = 0.7)
Which of the following are correct :
–6
(A) KC at 300 K = 4 × 10
(B) Enthalpy of given reaction = 32.5 kcal/mol.
(C) Enthalpy of given reaction = 39.06 kcal/mol.
–5
(D) KC at 310 K = 1.6 × 10
(C)
(A)
(B)
(C)
(D)
4) For the following compounds, the correct statement(s) with respect to nucleophilic substitution
reactions is(are)
5) Analytical reagent sodium nitroprusside used for the test of sulphide ion. Which of the following
property is/are correct for the mentioned reagent.
(B)
: Stability order
(C) HCℓ < HBr < HI < HF (order of melting point)
(D) H2S < H2Se < H2Te < H2O ( Heat of vapourization)
SECTION-I (ii)
1) Correct combination is :
2) Correct combination is :
3) Correct combination is :
Process 1 → 3 is
(III) (iii) W = 0 and ΔH = 0 (R)
adiabatic
Process 1 → 4 is
(IV) (iv) q = 0 and w = 0 (S)
isothermal
SECTION-II
1)
For the reversible reaction the values of k1 and k2 are 2 × 10–3 sec–1 and 3 ×
10–3 sec–1 respectively. If initial concentration of A is 1M, then find time (in minutes) when
concentration of B becomes 0.3 M. [ℓn2 = 0.69].
3) How many compound shows more rate of reaction towards NaI/dry acetone than CH3CH2CH2Cl :
4) Find out number of reactions those proceed with retention of configuration only :
(G) (H)
5)
Number of compounds which slowly racemise on addition of SbCl5, Where reaction take place in
following manner
(i) (ii)
(iii) (iv)
(vii) (viii)
6) x = the number of molecules of triprotic acid are formed by complete hydrolysis of one molecule
of P4O8
y = the number of molecules of acid are formed by complete hydorlysis of one molecule of γ–SO3.
Find the ratio of y/x.
ANSWER KEYS
PART-1 : MATHEMATICS
SECTION-I (i)
Q. 1 2 3 4 5 6
A. A,B,C B,C A,B,C,D A,B A,C A,C
SECTION-I (ii)
Q. 7 8 9 10 11 12
A. B B B A B A
SECTION-II
Q. 13 14 15 16 17 18
A. 2.00 4.00 25.00 6.00 2.50 4
PART-2 : PHYSICS
SECTION-I (i)
Q. 19 20 21 22 23 24
A. A,C,D A,B,C B,C B,D B,D A,B,C
SECTION-I (ii)
Q. 25 26 27 28 29 30
A. B C A B A D
SECTION-II
Q. 31 32 33 34 35 36
A. 130 3.00 2.00 2.25 1.25 2.00
PART-3 : CHEMISTRY
SECTION-I (i)
Q. 37 38 39 40 41 42
A. A,C A,B,C,D C A,B,C A,B,C,D B,C
SECTION-I (ii)
Q. 43 44 45 46 47 48
A. D B C C A D
SECTION-II
Q. 49 50 51 52 53 54
A. 4.6 6.00 6.00 2.00 3.00 1.5
SOLUTIONS
PART-1 : MATHEMATICS
1) consider f(x) in [0,1] f1(t) = 3t2 – 2t + 1 > 0 ∀ t ∈ (0,1) ⇒ f is in (0,1) Maximum occurs at
∀t∈R
G is an increasing function in [1,2] ⇒ minimum occurs when t = 1
2)
3)
for x < 0, f(x) is continuous
and and
Hence, Range of f(x) in (–∞,0)
f'(x) = 7(x + 1)6 – 2x2 which changes sign in (–∞,0)
⇒ f(x) is non-monotonic in (–∞,0)
4) y = e–x cosx
y1 = –[e–xcosx + e–xsinx]
y3 = 2(e–xcosx – e–xsinx)
y4 = –4e–xcosx ⇒ y4 = –4y ⇒ y4 + 4y = 0
k4 = 4 y8 + 4y4 = 0 ⇒ y8 – 16y = 0
cosine
2 2 2
Adding 2(cx + ay + bz) cos α = a + b + c
6) We must have
(p – 1)(q + 2) = 0 & (p – 1)(p2 + p – 1) = 0
⇒p=1
Now, g(x) = –4x2 + (2q + 1)x – 5
∴ ⇒
⇒ (p + q) can be or
7)
We cannot be sure about the coordinates of P and Qas they depend on a,b,c and d
8)
We cannot be sure about the coordinates of P and Qas they depend on a,b,c and d
9)
We cannot be sure about the coordinates of P and Qas they depend on a,b,c and d
10)
Solution:
(I)
As :
As :
(III)
Check at x = –1
LHL = .
RHL = .
.
Since , the function is continuous at .
Check at x = 1
LHL = .
RHL = .
Value f(1) = 0.
Since , the function is continuous at x = 1.
There are no other points of discontinuity within the intervals because the base
functions are continuous on their respective domains.
Total Points of Discontinuity = 0
Right Derivative: . As , .
Differentiating: .
As , the term . Since the derivatives don't match (one is 0 , the other is
), it is non-differentiable at x = 1.
Non differentiable at x = 1, –1, –1/2. (3 Points)
Match: (III) → (i), (P)
11)
12) (I) f(x) = ||x – 6| – |x – 8|| – |x2 – 4| + 3x – |x – 7|3 is continuous x ∀ ∈ R and not
differentiable at x = –2, 2 & 7
{(I) (i) (P)}
(II) f(x) = (x2 – 9)|x2 + 11x + 24| + sin|x – 7| + cos|x – 4| + (x – 1)3/5 sin(x – 1) is continuous ∀ x
∈ R and not differentiable at x = –8 & 7
{(II) (i) (R)}
(III)
Let g(x) =
so differentiable at x = I and for {sin x}{cos x}
Doubtful points for non differentiability are
is discontinuous at
13)
so
15)
⇒ f(x) is decreasing.
f(x) = ℓn 3 ⇒ x =
g′(y) =
⇒ g′(ℓn 2) =
⇒
∴ g²(ℓn 2) – g′(ℓn 2) =
∴ p + q = 25
⇒ (a – b)(a – b2) = 0
∴ Possible ordered pairs are
(0, 0), (1, 1), (2, 2), (3, 3), (4, 4), (4, 2)
17) Put
then
for
⇒ tan–1 x ≥ –3 ≤ –x2 ≤ –1
∴
∴ have no solution for x < 1 or
So, αmax = 1 and βmin =
PART-2 : PHYSICS
19)
⇒a=
mv2 = Bv2 ⇒ m = 2B
∴a=–
20) ,
2b = a
2ma × 10 = a
m =1 = 0.05 kg
21) Question Explanation : We have to choose the correct options regarding the motion of
the charged particle in uniform electric field which is aimed to hit a target T.
Concept : Motion of a charged particle in uniform electric field.
Solution : Force on charged particle in uniform electric field = qE
qEy = may (along y-direction)
ay = – 400 × 1010 [qEy = may]
Range of particle = 5m
R=5=
sin 2θ =
2θ = 60°, 120 ⇒ θ = 30°, 60°
For same range two angles are possible with different time of Flight
Time of flight
(for θ = 30°)
Time of flight
(for θ = 60°)
22)
x = 3t ⇒ x2 = 9t2
equation of parabola
Hence particle is not moving in circle
Radius of curvature =
23)
x + Rθ = constant
At θ = 60°, VP = V and
aP =
25)
26)
27)
28)
29)
pi = pf
...... (ii)
if then particle crosses the ring and again it's velocity start increasing and
finally becomes v and that of ring becomes zero.
pi = pf ⇒ mv = mv1 + mv2 ....... (i)
...... (ii)
31)
∴ Ratio of area =
Let energy incident on lens be E.
∴ Given
So final,
E = A × 1.30
Also
∴ Average intensity of light at 22 cm =
32)
34)
35)
Since it is symmetric about AB
RAB = 1.25
36)
The two cells in the circuit can be replaced by a single cell of emf E, where
Internal resistance
The power generated in R is maximum when r = R
Maximum power
∴15 = n + 13 (given)
∴n = 2
PART-3 : CHEMISTRY
37)
38)
39)
(A) Methyl-3-nitrobenzenecarboxylate
(B) Ethyl-3-phenylbenzene-1-carboxylate
(C) Ethyl-2-methyl-2-(3-nitrophenyl)propanoate
(D) 1,1,1-Trichloro-2, 2-bis(4-chlorophenyl) ethane
40) Ans. Official Answer Key as per JEE Adv. : ABC or ABCD
41)
(B)
(C) HCℓ < HBr < HF < HI (Melting point)
43)
44)
46)
47)
48)
49)
50)
x = 2, y = 2, z = 1, w = 1
51) More rate of reaction towards NaI/dry acetone than CH3 – CH2 – CH2 – Cl
* SN2 mechanism will be followed
* CH3 – CH2 – CH2 – Cl is 1° so less sterically crowded and more better leaving group will give
more rate
(i) 2° So γ(i) < r0 γ(i) rate of Ist compound with NaI/Acetone
γ0 rate of CH3 – CH2 – CH2 – Cl
0
(ii) γ(i) > γ * Better leaving group
0
(iii) γ(iii) > γ * SP2 hybridised carbon
0
(iv) γ(iv) > γ * Due double bond conjugation
2
* SP carbon –I effect
* These factor will stablise the -ve charge developed during transition state
* Better leaving group
(v) γv > γ * conjugation and –I effect of Benzene ring will stablize the
transition state in SN2 reaction
* Better leaving group
(D)
(E) Inversion will takes place
(G) Retension
(H)
In ACD (3) retension takes place