17-08-2025

0999DJA161101250006 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A particle is projected horizontally with speed 10 m/s from a building of height 20 m at t = 0.

Then find out radius of curvature at t = 1 sec. (g = 10 m/s2)

(A)
(B)

(C)

(D) 10m

2) A piece of string of length ℓ which can support a maximum tension T, is used to whirl particle of
mass m in a circular path as a conical pendulum. What is maximum speed with which the particle
may be whirled as a conical pendulum ?

(A)
u=

(B)
u=

(C)
u=

(D)
u=

3)

Which of the following is incorrect about non-uniform circular motion ? (ac = centripetal
acceleration, at = Tangential acceleration) :-

(A)
(B)
(C)
(D)

4) The kinetic energy of a particle moving along a circle of radius R depends on the distance covered
S as K.E. = KS2 where K is a constant. Find the force acting on the particle as a function of S :-
(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A particle P of mass m is attached to a vertical axis by two strings AP and BP of length ℓ each. The
separation AB = ℓ. P rotates around the axis with an angular velocity ω. The tensions in the two

strings are T1 (in AP) and T2 (in BP).

(A) T1 = T2
2
(B) T1 + T2 = mω ℓ
(C) T1 – T2 = 2 mg
BP will remain taut only if
(D)

2) A circular road of radius r is banked for a speed v = 40 km/hr. A car of mass m attempts to go on
the circular road. The friction coefficient between the tyre and the road is negligible.

(A) The car cannot make a turn without skidding

(B) If the car turns at a speed less than 40 km/hr, it will slip down
If the car turns at the constant speed of 40 km/hr, the force by the road on the car is equal to
(C)

If the car turns at the constant speed of 40 km/hr, the force by the road on the car is greater
(D)
than mg as well as greater than

3) A particle is performing circular motion of radius 1m. Its speed is v = (2t2) m/s. Then at t = 1s :
 2
(A) Tangential acceleration, aT = 4 m/s
2
(B) Centripetal acceleration, ac = 4m/s
(C) Net acceleration, m/s2
(D) None of these

4) A particle is in motion on the x-axis. The variation of its velocity with position is as shown. The
graph is circle and its equation is x2 + v2 = 1, where x is in m and v in m/s. The CORRECT

statement(s) is/are :-

(A) When x is positive, acceleration is negative

(B) When x is negative, acceleration is positive

(C)
At Q, acceleration has magnitude m/s2
(D) At S, acceleration is infinite

5) A body moves on a horizontal circular road of radius r, with a tangential acceleration aT.
Coefficient of friction between the body and road surface is µ. It begin to slip when its speed is v,
then:

(A) v2 = µrg

(B)

(C)

(D)
The force of friction makes an angle with direction of motion at point of
slipping.

6) For a curved track of radius R, banked at angle θ (Take v0 = )

a vehicle moving with a speed v0 is able to negotiate the curve without calling friction into play
(A)
at all
a vehicle moving with any speed v > v0 is always able to negotiate the curve, with friction called
(B)
into play
(C) a vehicle moving with any speed v < v0 must have the force of friction into play
 the minimum value of the angle of banking for a vehicle parked on the banked road can stay
(D)
there without slipping, is given by θ = tan–1 µ0 (µ0 = coefficient of static friction)

SECTION-I (iii)

Common Content for Question No. 1 to 2

There is the dip and hump in the road. A car driver applies break to produce uniform deceleration.
His speed is 90 km/h at the bottom point A of dip and 36 km/h at point C at hump as shown in figure.

Total acceleration experienced by passenger is m/s2 at dip and radius of curvature at C is .

B is any point in between dip and hump. Assuming car, driver and passenger as a single rigid body.

1) Find the radius of curvature of point A.

(A) 125m
(B) 150m
(C) 500/ m
(D) 75m

2) Choose the correct statement.

(A) Normal force on car at dip and hump will be same.

(B) Normal force on car at dip will be greater than hump.
(C) Normal force on car will be greater at point B among the point A, B, C.
(D) Normal force on car at hump will be greater than dip.

Common Content for Question No. 3 to 4

A particle continuously moves in a circular path at constant speed in a counter clockwise direction.
Consider a time interval during which the particle moves along this circular path from point P to

point Q. Point Q is exactly half-way around the circle from point P.

3) What is the direction of the average velocity during this time interval ?

(A)
(B)

(C)

(D)

4) What is the direction of the average acceleration during this time interval ?

(A)

(B)

(C)

(D)

SECTION-III

1) A particle is moving in a circle of radius R = 2m, with an angular velocity ω = 4 rad/sec and
angular acceleration α = –2 rad/sec2. The number of revolutions made by the particle in 3 seconds is

given by revolutions. The value of n is :-

2) A very small ball of mass 'm = 5 kg' is suspended from point A through an inextensible thread of
length ℓ = 4 m. It lies on the surface of a fixed smooth sphere of radius R = 3 m. The ball is moving
in a circular path with a constant speed v = 1 m/s so that it always maintains contact with the

surface of sphere. Find the normal reaction 'N' (in Newton) acting on the ball. Fill . (g = 10 m/s2)
3) A rod is rotating with an angular velocity of 3πt3 rad/s. The angle rotated by the rod from t = 0 to

the time when it has an angular velocity of 24 π rad/s is given by α π radian. Fill in OMR sheet.

4) A particle starts moving in a non-uniform circular motion, has angular acceleration as shown in
figure. The angular velocity at the end of 4 radian is given by ω rad/s then find the value of ω.

5) A circular platform rotates around a vertical axis with angular velocity ω = 10 rad/s. On the
platform is a ball of mass 1 kg, attached to the long axis of the platform by a thin rod of length 10 cm
(α = 30°). Find normal force exerted by the ball on the platform (in newton). Friction is absent.

6) A disc of radius R has a light pole fixed perpendicular to the disc at the circumference which in
turn has a pendulum of length R attached to its other end as shown in figure. The disc is rotated
with a constant angular speed ω. The string is making an angle 30° with the rod. Then the angular
speed of disc is ω = . Find k :

SECTION-IV

1) A particle is revolving around a circle of radius 1m. Angular velocity of particle ω = 3t2 – 2t
rad/sec (t is in sec) changes with time :

Column-II
Values are in
Column-I
appropriate SI
units

(A) Angular acceleration at t = 1 sec (P) 4

(B) Tangential acceleration at t = 1 sec (Q) 3

(C) Normal acceleration at t = 1 sec (R) 1

(D) Rate of change of angular velocity at t = 2 sec (S) 10

(T) 5

2) A block is placed on a horizontal table which can rotate about its axis. The block is placed at a
certain distance from centre as shown in figure. Table rotates such that block does not slide. Select
possible direction of net acceleration of block at the instant shown in figure.

Column-I Column-II
(A) When rotation is clockwise with constant ω (P) 1
(B) When rotation is clockwise with decreasing ω (Q) 2
(C) When rotation is clockwise with increasing ω (R) 3
(D) Just after clockwise rotation begins from rest (S) 4
(T) None of these

PART-2 : CHEMISTRY
 SECTION-I (i)

1) What volume of 0.2M - KMnO4 solution is required for complete reaction with 20 ml 0.4 M -FeC2O4
solution in presence of H2SO4 ?

(A) 24 ml
(B) 8 ml
(C) 16 ml
(D) 120 ml

2) For the reaction

the incorrect statement in the balanced equation is :

(A) Stoichiometric coefficient of is 6.

(B) Iodide is oxidized.
(C) Sulphur is reduced.
(D) H2O is one of the product.

3) What will be the equivalent weight of H3PO4 in the reaction :

Ca(OH)2 + H3PO4 → CaHPO4 + 2H2O

(A) 98
(B) 49
(C) 138
(D) 28

4) In a chemical reaction,
K2Cr2O7 + xH2SO4 + ySO2 → K2SO4 + Cr2(SO4)3 + zH2O;
the value of x, y and z respectively are :

(A) x = 1, y = 3, z = 1
(B) x = 4, y = 1, z = 4
(C) x = 3, y = 2, z = 1
(D) x = 2, y = 2, z = 1

SECTION-I (ii)

1) Consider the redox reaction 2S2O32– + I2 S4O62– + 2 I– :

2– 2–
(A) S2O3 gets reduced to S4O6
2– 2–
(B) S2O3 gets oxidised to S4O6
–
(C) I2 gets reduced to I
–
(D) I2 gets oxidised to I
2) Which of the following reactions is/are redox ?

(A) 2NaNO3 → 2NaNO2 + O2

(B) KCl + NaNO3 → KNO3 + NaCl
(C) Fe + H2SO4 → FeSO4 + H2
− − −
(D) 4Ag + 8CN + O2 + H2O → 4[Ag(CN)2] + 4OH

3) The correct statement(s) is/are

The n-factor of HNO3 in the following reaction is

(A)
Zn + HNO3 → Zn(NO3)2 + N2O + H2O
(B) The reaction (NH4)2Cr2O7 → N2 + Cr2O3 + H2O is a intramolecular redox reaction

(C)
The equivalent mass of (NH4)2Cr2O7 in option (B) is (if M is molecular mass of (NH4)2Cr2O7)
(D) In the reaction Na + H2 → NaH, H2 acts as oxidising agent

4) Choose the incorrect statement (s) -

(A) 1 mole of ion can oxidized 10 moles of Fe2+ ion in acidic medium
(B) 1 mole of ion can oxidized 12 moles of Fe2+ ion in acidic medium
(C) 2 mole of Cu2U can be oxidized 2.6 moles of ion in acidic medium (Cu2S→Cu2+ + SO2)

(D) 2 mole of Cu2U can be oxidized 8/3 moles of ion in acidic medium (Cu2S→Cu2+ + SO2)

5) Reduction of the metal centre in aqueous permanganate ion involves

(A) 3 electrons in neutral medium

(B) 5 electrons in neutral medium
(C) 3 electrons in alkaline medium
(D) 5 electrons in acidic medium

6) A solution of KHC2O4.H2C2O4.2H2O is 0.1 M when used as an acid. The same solution will be

(A) 0.4 N when used as reducing agent

(B) 0.6 N as an acid
(C) 0.3 N as an acid
(D) 0.4 N as an acid

SECTION-I (iii)

Common Content for Question No. 1 to 2

Redox is a reaction in which both oxidation and reduction will take place simultaneously. It is
obvious that if one substance gives electron there must be another substance to accept these
electrons. In some reactions same substance is reduced as well as oxidised, these reactions are
termed as disproportionation reactions. For calculating equivalent mass in redox reaction change in
oxidation number is related to n-factor which is reciprocal of molar ratio.

1) n-factor for the following reaction :

FeS2 → Fe3+ + SO2

(A) 3
(B) 9
(C) 11
(D) 13

2) n-factor of KMnO4 in acidic medium will be :

(A) 1
(B) 3
(C) 5
(D) 7

Common Content for Question No. 3 to 4

Column-II
Column-I Column-III
(oxidation number agent is
(1 mole of each oxidizing) (Reducing agents)
taken)

(A) KMnO4 (acidic) (P) O.N of Mn = 4 (1) 3 mole of FeSO4

0.5 mole of I2 changes to

(B) KMnO4 (neutral) (Q) O.N of Mn = 7 (2)
HIO3

(C) MnO2 (acidic) (R) O.N of Cr = 6 (3) 1 mole of K2C2O4

(D) K2CrO4 (acidic) (S) O.N of Cr = 7 (4) 1.5 mole K2SO3

3) Which of the following is correct ?

(A) A ; P ; 2
(B) A ; Q ; 4
(C) B ; Q ; 1
(D) B ; Q ; 3

4) Which of the following is correct ?

(A) A ; Q ; 3
(B) C ; P ; 3
(C) C ; P ; 4
(D) C ; Q ; 1

SECTION-III
1) A solution of Na2S2O3 is standardised iodometrically against 3.34 g of pure KBrO3 (converted to
Br⊝), requiring 40 mL Na2S2O3 solution. What is the molarity of Na2S2O3 solution ? (molar mass of
KBrO3 = 167 g mol–1)

2) In neutral or faintly alkaline solution, 8 moles permanganate anion quantitatively oxidize

thiosulphate anions to produce X moles of a sulphur containing product. the magnitude of X is

3) The oxidation number of phosphorus in Ba(H2PO2)2 is

4)

It required 40.05 mL of 1 M Ce4+ to titrate 20 mL of 1 M Sn2+ to Sn4+. What is the oxidation state of
the cerium in the product.

5) V ml of 0.2 M Na2S2O3 is completely oxidised to sulphate ion with 0.4 M, 40 ml of KMnO4 in faintly
alkaline medium. Find the value of 'V' in ml.
Mark your answer as sum of digit

6) The value of n in the equation,

+ 14H+ + ne¯ → 2Cr3+ + 7H2O is:

SECTION-IV

1) A sample of raw material contain NaNO3 also contains NaIO3. The NaIO3 can be used as a source
of iodine, produced in the following reactions :
IO3– + HSO3– → I– + SO42– ..... (1)
I– + IO3– → I2 + H2O ..... (2)
One litre of sample solution containing 396 g of NaIO3 is treated with stoichiometric quantity of
NaHSO3. Now a substantial amount of same solution is added to reaction mixture to bring about the
reaction (2) to completion
(Molar mass : I = 127, Na = 23, S = 32, O = 16)

Column-I Column-II
–
(A) n-factor of IO3 in reaction (2) (P) 6
–
(B) Number of moles of HSO3 used in reaction (1) (Q) 1.2

(C) Moles of I2 produced (R) 2

–
(D) Equivalents of IO3 used in reaction (2) (S) 5

(T) 3

2) Match equivalent mass of underlined species, assume M is the required molar mass.

Column-I (Reaction) Column-II (Equivalent masss)

 (A) Zn + HNO3 → Zn(NO3)2 + NH4NO3 + H2O (P)

(B) H2O2 → H2O + O2 (Q)

(C) (NH4)2Cr2O7 → N2 + Cr2O3 + H2O (R)

(D) P4 + NaOH + H2O → PH3 + NaH2PO2 (S)

(T)

PART-3 : MATHEMATICS

SECTION-I (i)

1) If 3|cos x| + 4|sin y| = 7, x, y [0, 2π], then number of ordered pairs (x, y) is equal to –

(A) 4
(B) 5
(C) 6
(D) 8

2) The number of solution of equation sin10 2x = 1 + cos10 x in [0, 10π] is equal to –

(A) 10
(B) 20
(C) 5
(D) 0

3) General solution of the equation 2cos3x = sinx is (where n ∈ I) -

2nπ +
(A)

nπ +
(B)

2nπ –
(C)

nπ –
(D)

4) Sum of solutions of the equation tanx + secx = 2cosx lying in the interval [0, 2π] is

(A) π
(B)

(C)

(D) 2π

SECTION-I (ii)

1) Number of solutions of the equation 3cosθ + sinθ = 1 in the interval , is -

(A) an even integer

(B) an odd integer
(C) a prime number
(D) a composite number

2)

Let θ1,θ2 ∈ [0,π] such that sin2θ1 + sin2θ2 = 2sinθ1 + 2sinθ2 , then which of following may be possible-

(A) θ1 + θ2 = 0
(B) θ1 + θ2 = π
(C) θ1 + θ2 = 2π

(D) θ + θ =
1 2

3) For the equation 4cos3x – 4cos2x – cos(π + x) – 1 = 0

(A) The number of solution in the interval (0,315) is 50

(B) The number of solution in the interval (0,315) is 51
(C) The arithmatic mean of all the solution in the interval (0,315) is 51π
(D) The sum of all the solution in the interval (0,315) is (51 × 52)π

4) Given where x ∈ R possible values of k for which given equation

has solution

(A)

(B)

(C)
(D)

5) If and sinx, cosx, sinx + cosx are in G. P. in that order, then

(A)
common ratio of G.P.

(B)
common ratio of G.P. =

(C)

(D)

6) cos4x cos8x – cos5x cos9x = 0 if

(A) cos 12x = cos14x

(B) sin13x = 0
(C) sinx = 0
(D) cosx = 0

SECTION-I (iii)

Common Content for Question No. 1 to 2

Consider cos2θ – sin2θ = ;θ∈ . On the basis of above information, answer the
following questions :

1) Number of values of θ satisfying the given equation is -

(A) 2
(B) 3
(C) 4
(D) 5

2) The difference between greatest and least value of θ is -

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

Let ℓ = sin2πx – sin2πy and m = (x – y).

3) If and , then ordered pair (x, y) can be -

(A) (–1, 1)

(B)

(C)

(D)

4) If ℓ = 1, then number of possible value of m is, where x, y ∈ [0, 2π]

(A) 0
(B) 1
(C) 4
(D) more than 4

SECTION-III

1) If (θ ≠ nπ, n ∈ I) are in geometric progression then number of values of θ

in [–2π, 3π] is

2) If |sin 2x| = 1, then numbers of solutions in interval is

3) Number of positive integral values of k for which equation 2sinθ + 3cosθ + 1 = k has a solution ∀
θ∈R

4) Number of solutions of the equation sin2x + sinx – 2 = 0 in [0, 4π] is

5) The number of solution of equation , lying in [0, 2π], is

6) Find the number of solutions of the equation (sin x – 1)3 + (cos x – 1)3 + (sin x)3 = (2 sin x + cos x –
2)3 in [0, 2π].

SECTION-IV

1)

Column-I Column-II

If y = cos 2 (45° + x) + (sinx – cosx) 2 then a possible

(A) (P) 1
value of y can be

(B) (Q) 2
A possible value can be
 If x2 + y2 = 1 and P = (3x – 4x3)2 + (3y – 4y3)2 then P is
(C) (R) 3
less than

(D) If tan50° – tan40° = k tan10° then the value of k is (S) 4

(T) 5

2)

Column-I Column-II

The number of real roots of the equation cos7x + sin4x = 1

(A) (P) 1
in (–π, π) is

The number of solutions of the equation |cotx| = cotx +

(B) (Q) 2
(0 < x < π) is

The number of solution(s) of equation in (0, 3π) sin2x +

(C) (R) 0
3sec2x = –(tan2x + cot2x) is

The number of values of x ∈ [–2π, 2π], which satisfy cosec

(D) (S) 3
x = 1 + cotx

(T) 5
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A C D C

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. B,C,D B,D A,B A,B,C C,D A,C

SECTION-I (iii)

Q. 11 12 13 14
A. A B B D

SECTION-III

Q. 15 16 17 18 19 20
A. 5 5 6 6 5 2

SECTION-IV

Q. 21 22
A. A->P,B->P,C->R,D->S A->R,B->S,C->Q,D->P

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 23 24 25 26
A. A C B A

SECTION-I (ii)

Q. 27 28 29 30 31 32
A. B,C A,C,D A,B,C,D A,B,C A,C,D A,C

SECTION-I (iii)

Q. 33 34 35 36
A. C C C B

SECTION-III

Q. 37 38 39 40 41 42
A. 3 6 1 3 3 6
 SECTION-IV

Q. 43 44
A. A->S,B->P,C->Q,D->R A->R,B->P,C->S,D->T

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 45 46 47 48
A. C D B A

SECTION-I (ii)

Q. 49 50 51 52 53 54
A. A,C A,B,C A,C A,B,D B,C A,B,C

SECTION-I (iii)

Q. 55 56 57 58
A. A D C D

SECTION-III

Q. 59 60 61 62 63 64
A. 6 3 4 2 3 5

SECTION-IV

Q. 65 66
A. A->PQR,B->PQRS,C->QRST,D->Q A->S,B->P,C->R,D->Q
 SOLUTIONS

PART-1 : PHYSICS

1)

R=

2)

T sin θ =

sin2 θ = ........ (i)

T cos θ = mg

cos2 θ = ........ (ii)

From (A) and (B)

+ =1

or u =

3) & are along tangent

perpendicular to plane of circular motion.

4)

K.E.=kS2

....(i)
Differenciation w.r.t. S
 as
FT = 2KS

FC =
Put value of mV2 from eq. (i)

⇒ Fnet

5)
T1 + T2 = mω2ℓ …(i)
T1 sin 30 – T2 sin 30 = mg
T1 – T2 = 2mg …(ii)
T2 ≥ 0

6)

NH = mg

NV =

7)

8)

x2 + v2 = 1

Radius of circle, R = 1m
Thus, acceleration,
a = –x
Thus, when x positive, a negative
when x negative, a positive
At Q, x = R cos 45°

Magnitude of acceleration ⇒
At S, a = – R
a = – 1 m/s2

9)
Body moves in circle as shown.
At point of slipping
fnet = ma

and

10)
N cos θ = mg ...(1)

...(2)
When friction comes into play there is a maximum and minimum speed at which object can
negotiate a turn on banked road.
vmin ≤ v ≤ vmax

11) vA = 25 m/s vC = 10 m/s

(Rc)at A =

v2 = u2 + 2at × s
100 = 625 + 2 × at × 52.5

at =

50 = aN2 + 25
aN = 5

12)

At dip,
m = mass of car

NA = 10 m + 5 m
NA = 15 m
At hump,
NC = mg – 6 m = 4 m
Thus, NA > NC

13) = =

14) aavg = =

15)

ω = 4 – 2t = 0 t = 2 sec
02 = 42 + 2(–2)θ θ = 4 rad

Total angle rotated = 5 rad.

2π rad → 1 rev

5 rad →

16)
N cos53o + T cos37o = mg ....(i)

Tsin37o – Nsin53o = ....(ii)

From (i) and (ii) N

17) ω = 3π t3 = 24π
t = 2 sec
 rad.

18)

= area under α vs θ graph =

= 6 rad /s

19)

T cos 30 = m(L cos 30)ω2 ...(i)

T sin 30 + N = mg
N = mg–T sin 30 ...(ii)
Putting value of T from equation in (ii) we get N.

20) T cosθ = mg
T sinθ = mω2 (R + R sinθ)

21)

ω = 3t2 – 2t

at = Rα = 6t – 2
Rate of change of angular velocity = α
 22) (P) at = 0, aC ≠ 0
(Q) at ≠ 0, aC ≠ 0
(R) at ≠ 0, aC ≠ 0
(S) at ≠ 0, aC = 0 (v = 0)

PART-2 : CHEMISTRY

23) neq KMnO4 = neq FeC2O4

or, ⇒ V = 24 ml
– 2+
MnO4 → Mn (n-factor = 5)
FeC2O4 → Fe2+ + CO2 (n -factor = 3)

24) –1 +5 +6
–
6I + ClO3 + 6H2SO4
↓
–1 +6 0
– –
Cl + 6HSO4 + 3I2 + 3H2O

25)

The correct answer is option (B)

26) Balancing the equation, we have

K2Cr2O7 + H2SO4 + 3SO2 →
K2SO4 + Cr2(SO4)3 + H2O

27) S undergoes increase in oxidation number from +2 to +2.5, while I undergoes decrease in
oxidation number from 0 to –1.

28)

The correct answer is option (A), (C) & (D)

29) (A) 8 Zn + 20 HNO3 → 8 Zn(NO3)2 + 2 N2O + 10 H2O

4 Zn + 10 HNO3 → 4 Zn(NO3)2 + N2O + 5 H2O

nf(HNO3) =
(B) –3 +6 0 +3
(NH4)2Cr2O7 → N2 + Cr2O3 + 4H2O

nf(NH4)2Cr2O7 =
(D) 0 0 +1 –1
Na + H2 → NaH
Hydrogen get reduced, therefore it is an oxidizing agent.

30)

The correct answer is option (A), (B) & (C)

31)

The correct answer is option (A), (C) & (D)

32) KHC2O4.H2C2O4.2H2O has

(i) three ionisable H+. If it is 0.3 N then it is

as an acid.
(ii) two C2O4–2 oxidised to CO2

Thus, 0.1 M = 0.1 × 4 = 0.4 N as a reducing agent.

Thus, (A) and (C) are true.

33)

The correct answer is option (C)

34)

The correct answer is option (C)

35) (A)
Oxidation number of Mn is +7. hence incorrect
(B) KMnO4 + I2 Mn+2 +
Oxidation number of Mn is +7, hence incorrect.

(C)
eq. of KMnO4 = eq. of FeSO4
1 × 3 = 1 × moles of FeSO4; moles of = 3
FeSO4 correct
(D) KMnO4 + K2C2O4 = Mn+4 + CO2

eq. of KMnO4 = eq. of K2C2O4 moles of K2C2O4 =

1 × 3 = 2 × moles of K2C2O4; incorrect.

36) (A) KMnO4 + K2C2O4 Mn+2 + CO2

eq. of KMnO4 = eq. of K2C2O4
1 × 5 = 2 × moles of K2C2O4; moles of K2C2O4 = incorrect
(B)
1 × 2 = 2 × moles of K2C2O4 ; moles of K2C2O4 = 1 correct

(C)
1 × 2 = 2 × moles of K2SO3; moles of K2SO3 = 1 incorrect
(D) MnO2 has Mn in +4 oxidation state, hence C does not matches with Q. incorrect

37) Necessary equations : KBrO3 + KI —→ I2 + Br⊝

I2 + Na2S2O3 —→ Na2S4O6 + NaI
equivalent of I2 = equivalent of KBrO3 = 12 × 10–2
equivalent of Na2S2O3 = equivalent of I2

M×1× = 12 × 10–2
so, molarity = 3 M.

38) In neutral/faintly alkaline medium converts to MnO2.

Since is strong oxidizing agent it will oxiding sulphur to its highest oxidation state +6.

nf = 3 nf = +4
equivalents of = equivalents of S6+
8 × 3 = x(+4)
n = 6 moles

39)

H2PO2–1
2 + x – 4 = –1
x=+1

40)

Ce+4 + Sn+2 → Sn+4 + Ce+2

40.05 + 20 ml
1M 1M
Meq. of Ce = Meq. Sn+2
+4

40.05 × 1 × (4 – n) = 20 × 1 × 2

(4 – n) =
n=3

41)

(n-factor of KMnO4 in faintly alkaline medium = 3)

 (here, n – factor of S2O32– = 8)

42)

The correct answer is '6'

43) (Q) gm eq. of IO3– = gm eq. of HSO3– = gm eq. of I–

× 6 = moles of HSO3– × 2 = moles of I– × 6

(R) gm eq. of I2 = gm. eq. of I–

moles × = 2 × 1
moles of I2 = 1.2

44) The correct sequence is A-R ; B-P ; C-S ; D-T

PART-3 : MATHEMATICS

45) |cosx| = 1 & |siny| = 1

⇒ cosx = ±1 or siny = ±1

⇒ x = 0, π, 2π
∴ total 6 ordered pairs.

46) but there exist no x for which both sides are simultaneously 1.
Hence no solution

47) 2cos3x = sinx ⇒ 2 = tanx sec2x

⇒ 2 = tanx(1 + tan2x)
⇒ tan3x + tanx – 2 = 0
⇒ (tanx – 1)(tan2x + tanx + 2) = 0

⇒ tanx = 1 ⇒ x = nπ +

48) sinx + 1 = 2cos2x

⇒ 2sin2x + sinx – 1 = 0
⇒ (sinx + 1)(2sinx – 1) = 0

⇒ sinx = or sinx = –1 (rejected)

(∵ cosx ≠ 0)
49) 3 cosθ + sinθ = 1

number of solutions = 2.

50)

(1 – sinθ1)2 + (1 – sinθ2)2 = 2
Possible when sinθ1 = 0 & sinθ2 = 0
θ1 = 0, π & θ2 = 0, π

51) The given equation can be written as

(4cos2x + 1)(cosx – 1) = 0
⇒ 4cos2x + 1 ≠ 0, cosx = 1
⇒ x = 2π, 4π, ....., 100π
so the no. of solution = 50
and sum of solution = 2π(1 + 2 + 3 + ..... + 50)

and

52) Range of is

So or or

53)

cos2x = sinx(sinx + cosx)

⇒ tan2x + tanx – 1 = 0

⇒ ( tanx > 0)

and
54) cos4x cos8x – cos5x cos9x = 0 ⇒ 2 cos4x cos8x = 2 cos5x cos9x
⇒ cos12x + cos4x = cos14x + cos4x ⇒ 14x = 2nπ ± (12x)

⇒ 2x = 2nπ or 26x = 2nπ ⇒ x = nπ or ∴ sinx = 0 or sin13x = 0.

55)

56)

57) &x–y=

58) sin2πx – sin2πy = 1

⇒ possible when sinπy = 0

x–y=

⇒ y = 0, 1, 2, 3, 4, 5, 6 & x =
sin2πx = 1

59)

⇒ (θ ≠ nπ)

θ = nπ + (–1)n.

∴ number of solutions = 6

60)

61)

∴ for solution

62)

sinx = 1 ⇒

63) Given a + b + c = 0
⇒ a3 + b3 + c3 = 3abc

⇒
⇒ sinx = 0 or sin2x = sin2x – 1
⇒ sinx = 0

64)

65) (A) y = cos2(45 + x) + (sinx – cosx)2

y = cos2(45 + x) +
y = 3cos2(45 + x)
⇒ y ∈ [0, 3]

(B)

0 ≤ sin2(2θ) ≤ 1

So, y ∈ [1, 4]
y can be 1, 2, 3, 4
(B) → P, Q, R, S
(C) x2 + y2 = 1
Let x = cosθ, y = sinθ
P = (3x – 4x3)2 + (3y – 4y3)2 = cos2(3θ) + sin2(3θ) = 1
(D) tan50° – tan40°
cot40° – tan40°
2cot80°
2tan10° = k tan10°
So, k = 2
(D) → Q

66)

(A) cos7x + sin4x = 1 ; x ∈ (–π, π)

⇒ cos7x = 1 – sin4x
⇒ cos7x = (1 – sin4x)(1 + sin4x)
⇒ cos7x cos2x(1 + sin4x) = 0
⇒ cos2x(cos5x – (1 + sin2x)) = 0

⇒ cos2x = 0 or

⇒ ⇒ cos5x = 1 & 1 + sin2x = 1

⇒ cosx = 1 & sinx = 1
⇒ x = {0}

Three roots

(B) ;0<x<π

when 0 < x < ; cotx = cotx +

⇒ No solution

When ≤ x < π ; –cotx = cotx +

⇒
⇒ ; {as sinx ≠ 0}

⇒
(C) LHS → +ve
RHS → –ve
No Solution
(D) cosec x = 1 + cotx

⇒
⇒ sinx + cosx = 1 ; (sinx ≠ 0)

⇒ ;n∈I

⇒ or ;n∈I

⇒ or x = 2nπ (reject) as sinx ≠ 0

In x ∈ [–2π, 2π] two solutions