Solution
Solution
9610WJA802544260006 JA
PHYSICS
SECTION-I (i)
1)
2)
3) A charge –q of mass m is rotating in circle of radius r, around an infinite large uniformly charged
(A)
(B)
(C)
(D)
4) A point charge q moves from point P to point S along the path PQRS in a uniform electric field
pointing parallel to the positive direction of the x-axis. The coordinates of the points P, Q, R and S
are (a, b, 0), (2a, 0, 0), (a, – b, 0) and (0, 0, 0) respectively. The work done by the field in the above
(A) qaE
(B) –qaE
(C)
(D)
5) A point charge Q is located on the axis of a disc of radius R at a distance 'a' from the plane of the
disc. If one fourth (1/4th) of the flux from the charge passes through the disc, then value of a is :-
(A)
(B)
(C)
(D)
6) Point charge Q is placed at point P in the plane of circular face of sphere. The electric flux passing
(A)
(B)
(C)
SECTION-I (ii)
1) The four pairs of force vectors are given, which pairs of force vectors cannot be added to give a
resultant vector of magnitude 10 N?
(A) 2N, 13 N
(B) 5N, 16 N
(C) 7N, 8N
(D) 100N, 105 N
2) A semicircular ring having charge density +λ on first half and –2λ on second half is kept as shown
in figure. Direction of electric field at O can be given by
(A)
(B)
(C)
(D)
3) Two point charges 4µC and –1µC are kept at a distance of 3 m from each other. What is the
electric potential at the point where the electric field is zero ?
(A) 0 V
(B) 1500 V
(C) 3000 V
(D) 500 V
4) Two point charges q1 = +2Q and q2 = –Q are placed as shown in figure. The charges divide the
line joining them in three regions I, II and III then which of the following statement(s) is/are
CORRECT :
5) There is a uniform electric field in X-direction. If the work done by external agent in moving a
charge of 0.2 C through a distance of 2 metre slowly along the line making an angle of 60° with x-
direction is 4 joule, then the magnitude of E is :
(A)
(B) 4 N/C
(C) 5 N/C
(D) 20 N/C
6) A point charge 25 µC is located in the XY plane at the point of position vector . What
is the magnitude of electric field at the point of position vector ?
(A)
(B)
(C)
SECTION-II
1) If the resultant of two forces of magnitudes P and Q acting at a point at an angle of 60o is ,
then P/Q is ___
3) Two point charges q1 = 2µC and q2 = 1µC are placed at distances b = 1 cm and a = 2 cm from the
origin of the y and x axes as shown in figure. The electric field vector at point P(a,b) will subtend an
4) A uniform electric field E = 500 N/C passes through a hemispherical surface of radius R = 2m as
shown is figure. The net electric flux (in SI units) through the hemispherical surface only is
5) A line charge of linear charge density is fixed in space then magnitude of electric
field (in N/C) at point P is:-
6) The work done in carrying a charge of 5μC from a point to a point in an electric field is 10 mJ.
The potential difference (VB – VA) is K volts. Find the value of K.
CHEMISTRY
SECTION-I (i)
(A) Activation energy of backward reaction is E1 and product is more stable than reactant.
(B) Activation energy of forward reaction is E1 + E2 and product is more stable than reactant.
(C) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable
(D)
than product.
(A) 2
(B) 1
(C)
(D)
3) For the first order reaction A → B + C, carried out at 27oC. If 3.8 × 10–16% of the reactant
molecules exists in the activated state, the Ea (activation energy) of the reaction is :-
(A) 12 kJ/mol
(B) 831.4 kJ/mol
(C) 100 kJ/mol
(D) 88.57 kJ/mol
4) For and ideal solution of A and B, YA is the mole fraction of A in vapour phase at equilibrium.
Which of the following plot should be linear?
(A) PT vs YA
(B) PT vs YB
(C)
(D)
5) Calculate the boiling point of a one molar aqueous solution (density = 1.04 g/ml) of potassium
chloride, Kb of water = 0.52 kg/mol. Atomic mass of K = 39, Cl = 35.5.
(A) 107.28°C
(B) 103.68°C
(C) 101.079°C
(D) 110.09°C
6) A solution of 36g of glucose in 1000 gm of water is cooled to –0.5ºC. How many gram of ice would
have separated from the solution Kf = 1.86 deg/molal (Mol. wt. of Glucose = 180)
(A) 744 g
(B) 300 g
(C) 256 g
(D) 180 g
SECTION-I (ii)
1) 3 moles of N2 mixed with 8 mole H2 and 4 moles of NH3 obtained according to reaction N2 + 3H2
—→ 2NH3 then incorrect statement(s) is/are
2) A sample of a mixture of CaCl2 and NaCl weighing 4.44 gm was treated to precipitate all the Ca as
CaCO3, which was then heated and quantitatively converted to 1.12g of CaO. Select the correct
option(s) regarding the mixture (At . wt. : Ca = 40, Na = 23, Cl = 35.5)
4) For a zero order reaction which of the following statements are true?
6)
1.22 gm C6H5COOH is added into 100 gm of acetone, elevation in B.P. is found to be 0.17. If Kb
(acetone) = 1.7 K - Kg mol–1 then select the incorrect options
SECTION-II
1) The ‘roasting’ of 100.0 g of a copper ore yielded 71.8 g pure copper. If the ore is composed of
Cu2S and CuS with 4.5% inert impurity, calculate the percent of Cu2S in the ore.
The reactions are :
Cu2S + O2 → 2Cu + SO2 and CuS + O2 → Cu + SO2
[Atomic masses Cu = 63.5, S = 32]
4) A(g) → 2B(g) initially 2 moles of A are taken in 5 litre vessel. After 20 min, [A]t = . Find half
life time of A (in minutes) in the first order reaction
5) A compound H2X with molar weight of 80 g is dissolved in a solvent having density of 0.4 g /ml,
assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is.
6) H2S (5 moles) reacts completely with acidified aqueous potassium permanganate solution. In this
reaction, the number of moles of water produced is x, and the number of moles of electrons involved
is y. The value of (x + y) is ____.
MATHEMATICS
SECTION-I (i)
(A) 49
(B) 50
(C) 51
(D) 98
(A) a + b – c = 9
(B) a + b – c = 1
(C) ab < c
(D) ab ≤ c
4) In a class of 175 students. The following data shows the number of students obtaining one or
more subjects. Mathematics 100 ; Physics 70; Chemistry 40; Mathematics and Physics 30;
Mathematics and Chemistry 28; Physics and Chemistry 23 ; Mathematics ,Physics and Chemistry 18.
How many students have offered Mathematics alone ?
(A) 35
(B) 48
(C) 60
(D) 22
5) Let X and Y be two non empty sets such that and for some non
empty set A. Then
SECTION-I (ii)
1) If (a)bc = (2 + 1)(22 + 1)(24 + 1) ... (264 + 1) + 1, then which of the following statement is/are true,
where a is single digit & bc is two digit natural number
(A) b + c = 10
(B) a + b = 10
(C) a + c = 7
(D) a < b < c
(A) (3, 4)
(B) (3, π) ∪ (π, 4)
(C) [3, 4]
(D) [3, π) ∪ (π, 4]
5) In a study about pandemic, data about the health issues of 900 persons was collected. It was
found that,
190 persons had fever
220 persons had cough
220 persons had breathing problem
330 persons had fever or cough or both
350 persons had cough or breathing problem or both
340 persons had fever or breathing problem or both
30 persons had all three : fever and cough and breathing problem
Based on above information tick the correct alternative(s) :
6) Let A be the finite set and n(A) = 5 then which of the following is/are correct ?
SECTION-II
1)
3) Find the number of equivalance relation on the set with elements {1, 2, 3, 4}
4) If S1 = {1, 2, 3 .....12}, S2 = {a, b, c, d}, S3 = {b, d, e, f}. Then find number of elements in (S1 ×
S2) ∪ (S1 × S3)
5) If y = 2[x] + 3 and y = 3[x – 2] + 5, then find the value of [x + y] ? (whare [.] is greatest integer
function.)
6) Two finite sets have m and n elements. The number of subsets of the first set is 112 more than
PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5 6
A. C D C B B B
SECTION-I (ii)
Q. 7 8 9 10 11 12
A. A,B C C A,D D B
SECTION-II
Q. 13 14 15 16 17 18
A. 2.00 2.00 2.00 12.00 3.00 2000.00
CHEMISTRY
SECTION-I (i)
Q. 19 20 21 22 23 24
A. C C C C C C
SECTION-I (ii)
Q. 25 26 27 28 29 30
A. B,D A,C A,C,D B,C,D D A,D
SECTION-II
Q. 31 32 33 34 35 36
A. 62.5 3.00 40.00 20.00 8.00 18.00
MATHEMATICS
SECTION-I (i)
Q. 37 38 39 40 41 42
A. B A D C C A
SECTION-I (ii)
Q. 43 44 45 46 47 48
A. A,B A,C,D A,B,C A,C A,C A,C
SECTION-II
Q. 49 50 51 52 53 54
A. 5.00 3.00 15.00 72.00 15.00 1.75
SOLUTIONS
PHYSICS
= J/molK
Final Answer: (C)
2)
[b] = ⇒ acceleration
–1
[c] = LT T = L ⇒ Distance
[d] = T ⇒ Time
[a] = ⇒ Distance
Final Answer (D)
Electric field =
= (independent of r.)
Final Answer: (C)
4) Explanation: A charge q moves from P→Q→R→S in a uniform electric field; find total work
done by the field using coordinates of initial and final points.
Concept: This question is based on the work–energy relation in a uniform electric field
Solution :
The work done is independent of the path followed, and is equal to where =
displacement from P to S.
Here, , while .
∴ work =
Final Answer : (B)
An element is taken in the form of a ring of radius "r" and thickness "dr"
electric field at ring = E
E=
area of element (dA) = 2πrdr
flux through ring (dϕ) = EdA cosθ
dϕ =
tanθ = ⇒ r = a tan θ
dr = a sec2 θ .dθ
dϕ = =
dϕ =
ϕ= =
θ=
0
cos θ =
ϕ= =
,
2a = , 4a2 = a2 + R2, 3a2 = R2, a =
Final Answer: (B)
6) Question Explanation:
Calculating the electric flux through a spherical segment when a point charge is placed on the
plane of its circular base.
Concept:
Gauss's Law and Solid Angle.
Solution:
According to Gauss's Law, the total flux through a closed surface is . For an open surface,
the flux depends on the solid angle subtended by that surface at the position of the charge.
The charge Q is placed at point P, which lies exactly on the plane of the circular face of the
spherical part.
For a point charge on the flat face of a hemisphere, the flux is shared equally between the two
sides of the plane.
However, in this specific geometry, point P is inside the sphere's boundary. If we consider the
symmetry, any field line emanating from Q that goes "left" into the large spherical volume will
eventually pass through the spherical surface.
Since the charge is placed on the plane of the circular opening, exactly half of the total field
lines (representing half of the total flux) will enter the spherical region and pass through the
curved part.
Therefore, the flux through the spherical part is:
Final Answer:
Option (2)
7) Explain Question: Pairs of force vectors which cannot produce resultant of magnitude 10
N are asked.
Concept: Vector Addition
Solution:
≤ Resultant vector ≤
(1) 11 ≤ ≤ 15
(2) 11 ≤ ≤ 21
(3) 1 ≤ ≤ 15
(4) 5 ≤ ≤ 205
Final Answer: (A, B)
Two point charge 4μC and -1μC are kept at distance of 3m. We have to find electric potential
at the point where electric field is zero.
Key Concept:
Electric field and electric potential.
Formula:
x=
V=
Visual Aid:
Solution/Explanation/Calculation:
vat this point
vnet = v1 + v2
vnet =
vnet =
vnet =
=
vnet = 300 V
angle =
∴x=2
Final Answer: (2.00)
so, N = 12
Final Answer: (12.00)
17) Explain Question: Find the field
Concept: Field of time wire
Solution:
CHEMISTRY
19)
20)
Explanation
• The slow step determines the overall reaction rate.
• Rate law from slow step, equilibrium for intermediate.
Given Data
• Reaction mechanism with slow step.
...(fast)
A + B2 → AB + B ...(slow)
A + B → AB ...(fast)
Concept
• From the slow step: rate = k[A][B2]
• A is an intermediate. From the fast equilibrium step: Keq = [A]2/[A2] => [A] = Keq1/2 [A2]1/2
• Substituting [A] into the rate law: rate = kKeq1/2 [A2]1/2 [B2]
Overall order = 1/2 + 1 = 1.5
Calculation
• rate = k[A][B2] = k’[A2]1/2[B2] (k’ = kKeq1/2)
• order=1.5
Final Answer: (C)
Ea = 100 kJ/mol
Final Answer: (C)
22) Question Explanation: Find which of the following plot should be linear
Concept: Ideal solution
Solution:
Y = mx + C
23) Question Explanation: Find the boiling point of a one molar aqueous solution (density =
1.04 g/ml) of potassium chloride
Concept: Elevation in boiling point
Solution:
TS – 100 = i × m × Kb
Mass of solution V × d = 1000×1.04 = 1040
Mass of solvent = 1040 – 74.5 = 965.5 g
24) Question Explanation: Find how many gram of ice would have separated from the
solution
Concept: Depression in freezing point
Solution:
t=0 3 8 0
moles of CaO =
∴ moles of CaCl2 = 0.02
weight of CaCl2 = 0.02 × 111 = 2.22 g
Final Answer: (AC)
Solution:
A redox reaction involves a change in the oxidation states of elements.
1. : Nitrogen changes from +5 to +3 (reduction) and Oxygen
changes from -2 to 0 (oxidation). It is a redox reaction.
2. : All elements (K, Cl, Na, N, O) maintain the same oxidation
states. It is a double displacement reaction, not redox.
3. : Iron changes from 0 to +2 (oxidation) and Hydrogen changes
from +1 to 0 (reduction). It is a redox reaction.
4. : Silver changes from 0 to +1 (oxidation)
and Oxygen changes from 0 to –2 (reduction). It is a redox reaction.
Reactions 1, 3, and 4 are redox reactions.
28)
Question Explanation: Find which of the following statements are true.
Solution:
A. Step 1: By definition, the rate law for a zero-order reaction is Rate = k[A]0 = k. This confirms
that the rate is independent of reactant concentration, making statement 2 true.
B. Step 2: The rate constant k is temperature-dependent according to the Arrhenius equation (k
= Ae–E /RT), so the reaction rate also depends on temperature. Thus, statement 1 is false.
a
C. Step 3: The half-life for a zero-order reaction is given by . This shows a direct
dependence on the initial reactant concentration, making statement 3 true.
D. Step 4: The units of the rate constant k for a zero-order reaction are concentration ⋅ time–1,
which is mol L–1s–1. Therefore, statement 4 is true.
29)
Concept:
This question is based on elevation in B.P.
Solution:
ΔTb = [Link].m
0.17 = i × 1.7 ×
i = 1, so no association or dissociation take place.
n-factor = 6, 1
M=3
Final Answer: (3.00)
33)
moles of solute =
molality =
⇒ (101.36 – 100) k =
⇒ ⇒ formula = C40H80O40
Final Answer: (40.00)
34) Explain Question: Find half life time of A (in minutes) in the first order reaction
Concept: First order reaction
Solution:
According to question,
0.4 – x =
0.4 = 2x
x = 0.2
[A]t = 0.4 – 0.2
= 0.2 mol/ltr
concentration of A becomes half in 20 min. So t1/2 = 20 min.
Final Answer: (20.00)
35)
molality =
Final Answer: (8.00)
36)
MATHEMATICS
37)
Explain Question : Calculate the sum of a series of Greatest Integer Function (floor function)
values ranging from to .
Concept : Greatest Integer Function [x]; properties of floor functions and summation of
series.
Solution :
= 50
Final Answer : (B)
38) Question Explain: In this question, we have to find values of parameters a, b and c of
given polynomial.
39)
Explain Question : Determine if two specific relations, (sum of squares is rational) and
R2 (sum of squares is irrational), satisfy the transitive property for all real numbers.
Concept : Relation theory; properties of relations (Transitivity); Rational and Irrational
number properties.
Solution :
is not transitive
is not transitive.
Final Answer : (D)
40)
Explain Question : Given data on students taking Mathematics, Physics, and Chemistry, find
the specific number of students who are enrolled in Mathematics only, excluding those taking
other subjects.
Concept : Set Theory; Venn Diagrams; Principle of Inclusion-Exclusion for three sets.
Solution :
n(M) = 100, n(P) = 70, n(C) = 40,
n(M ∩ P) = 30, n(M ∩ C) = 28, n(P ∩ C) = 23, n(M ∩ P ∩ C) = 18
n(M ∪ P ∪ C) = 100 + 70 + 40 - (30 + 28 + 23) + 18
n(M ∪ P ∪ C) = 147
41)
Explain Question : Given two sets X and Y that have identical unions and identical empty
intersections with a third set A, prove the relationship between X and Y.
Concept : Set operations (Union, Intersection); properties of disjoint sets; proof by
contradiction.
Solution :
is non empty
This contradicts that
so X = Y
Final Answer : (C)
42)
Explain Question : Determine the set of all real values of x for which the function
Given that :
f(x) is defined if
4 – x ≥ 0 or x2 – 1 > 0 ⇒ –x ≥ – 4 or (x – 1)(x + 1) > 0
⇒ x ≤ 4 or x < –1 and x > 1
∴ Domain of f(x) is (–∞, –1) ∪ (1, 4]
Final Answer : (A)
43)
Explanation Question: Solving a product and simplifying its value to get a, b and c.
Concept: This question is based on manipulating the expression to find its value.
Solution:
⇒ ⇒ N = (4)64
44)
Explain Question : Identify which of the given intervals do not represent the domain of the
complex logarithmic function involving |sin x| and a quadratic expression.
Concept : Domain of Logarithmic functions; Trigonometric inequalities; Logarithmic base
properties .
Solution :
log|sinx|(x2 – 7x + 21) – 2log|sinx|(3) > 0
and |sin x| ≠ 0, 1
2
⇒ x – 7x + 12 < 0 and sinx ≠ 0, 1, –1
45)
46)
47)
Explain Question : Using pandemic health data for 900 people, verify the count of individuals
having exactly two health issues and those having no health issues at all.
Concept : Set Theory; Venn Diagram application; calculating regions for "exactly n" elements
and "neither".
Solution :
n(F∪C) = 330
n(F) + n(C) – n(F∩C) = 330
190 + 220 – n(F∩C) = 330
⇒ n(F∩C) = 80
111log1 n(C∩B) = 90
111log1 n(B∩F) = 70
Hence,
Exactly 2 health issues :
= 40 + 50 + 60 = 150
None health issue :
= 900 – (70 + 50 + 80 + 40 + 30 + 60 + 90)
= 900 – 420
= 480
Final Answer : (A,C)
48)
Explain Question : For a set A with 5 elements, evaluate the total number of reflexive
relations and those that are also symmetric or specifically not symmetric.
Concept : Combinatorics of relations; formulas for Reflexive and Symmetric
relations.
Solution :
1. Reflexive Relations For a relation to be reflexive, every element must relate to itself. In our
5 × 5 matrix, the diagonal elements (a, a) are mandatory (they have only 1 choice: to be
included). The remaining n2 – n elements (25 – 5 = 20) can either be in the relation or not ( 2
choices each).
• Formula: .
2. Reflexive and Symmetric Relations
• Reflexive: Diagonal elements are fixed (included).
• Symmetric: If (a, b) is included, (b, a) must also be included. This means we only have a
choice for the elements above the diagonal. The elements below the diagonal are automatically
determined by the ones above.
49)
Explain Question : Determine the smallest positive integer that falls within the domain of the
function .
Concept : Domain of Logarithmic functions; Wavy curve method for solving rational
inequalities.
Solution :
least positive integer belonging to the domain of the function is 5.
Final Answer : (5.00)
50)
Explain Question : Solve the equation to find the number of solutions (N),
and then compute the value of N+2.
Concept : Relation between x, [x], and (i.e., x = [x] + ; solving equations with
fractional parts.
Solution :
6{x} – 3[x] = 2x
⇒ 6{x} – 3[x] = 2[x] + 2{x}
⇒ 4{x} = 5[x]
⇒ ....(1)
⇒ 0 ≤ {x} < 1
⇒ [x] = 0
From equation (1)
{x} = 0
⇒x=0
Number of solution = 1 = N
⇒N+2=3
Final Answer : (3.00)
52)
Explain Question : Find the number of elements in the union of two Cartesian products
given three specific sets.
Concept : Cartesian Product of sets; Cardinality of union of sets; .
Solution :
S1 ∈ {1, 2, 3, 4.....12}
S2 ∈ {a, b, c, d}
S3 ∈ {b, d, e, f}
n(S1 × S2) = 48
n(S1 × S3) = 48
S2 ∩ S3 = {b, d}
n(S1 × S2) ∩ (S1 × S3) = 24
n{(S1 × S2) ∪ (S1 × S3)}
= n(S1 × S2) + n (S1 × S3)
–n{(S1 × S2) ∩ (S1 × S3)}
= 48 + 48 – 24 = 72
Final Answer : (72.00)
53)
Explain Question : Solve the system of two equations involving greatest integer functions to
find the value of [x+y].
Concept : Properties of Greatest Integer Function; [x+n] = [x]+n for integer n; solving linear
equations with [x].
Solution :
y = 3[x – 2] + 5 = 3[x] – 1
so 3 [x] – 1 = 2 [x] + 3
[x] = 4 ⇒ 4 ≤ x < 5
then y = 11
so x + y will lie in the interval [15, 16)
so [x + y] = 15
Final Answer : (15.00)
54)
Explain Question : Given two sets with m and n elements where one has 112 more subsets