26-04-2026

1803CJA101029260038 JM

PHYSICS

SECTION-I

1) What is the length of the image of the rod in mirror, according to the observer in air? ( refractive

index of the liquid is μ)

(A) μL + L
L+
(B)

Lμ +
(C)

(D) None of these

2) A concave spherical surface with radius R separates a medium with index of refraction 2 from air.
If an object is moved toward the surface from far away along the central axis, its image :

(A) Changes from virtual to real when it is R/2 from the surface
(B) Changes from virtual to real when it is 2R from the surface
(C) Changes from real to virtual when it is R/2 from the surface
(D) Remains virtual

3) A transparent cylinder is placed coaxially with x-axis. It has variable refractive index from one end

x = 0 to other end x = L as . When a point source of light is kept at origin is seen

from other flat side of cylinder it appears at 0.7 L distance. The value of µ0 is approximately (Take
ln2 = 0.7)
(A) 2.5
(B) 1.5
(C) 1
(D) 3

4) A ray of light is incident normally on the first refracting face of the prism of refracting angle A.
The ray of light comes out at grazing emergence. If one half of the prism (shaded position) is

knocked off, the same ray will :–

(A)
Emerge at an angle of emergence
(B) Not emerge out of the prism

(C)
Emerge at an angle of emergence
(D) None of these

5) The graph shows the variation of v with change in u for a mirror. Points plotted above the point P

on the curve are for values of v

(A) smaller than f

(B) smaller than 2f
(C) larger than 2f
(D) larger than f

6) A small object is placed 50 cm to the left of thin convex lens of focal length 30 cm. A convex
spherical mirror of radius of curvature 100 cm is placed to the right of the lens at a distance of 50
cm. The mirror is tilted such that the axis of the mirror is at an angle θ = 30° to the axis of the lens,
as shown in the figure. If the origin of the coordinate system is taken to be at the centre of the lens,
the coordinates (in cm) of the point (x, y) at which the image is formed are :
(A)

(B)

(C)
(D) (0, 0)

7) A uniform rod of length 2ℓ rocks to and fro on the top of a rough semicircular fixed cylinder of

radius a. The period of small oscillations of rod is

(A)

(B)

(C)

(D)

8) A block of mass m having a charge q is placed on a smooth horizontal table and is connected to
the wall through an unstretched ideal spring of force constant k. A horizontal uniform electric field
as shown in figure is suddenly switched on. Assume that charge is only confined to the block and
induced charges are not produced elsewhere. The motion of the block is

(A) simple harmonic with an amplitude of (qE/k)

(B) simple harmonic with an angular frequency of
(C) not simple harmonic but has an amplitude of

(D) not simple harmonic but has an amplitude of .

9) Three charges +q, –q, +q are placed randomly along a straight line at points P1, P2, P3. The
potential energy of this system of charges is u1 when –q charge is in the middle and is u2 when –q

charge is at one end. Then ratio is equal to :-

(A) 3
(B) –3
(C) 2
(D) –2

10)

Choose the INCORRECT statement for the system.

(A) The net momentum of the system, in the centre of mass frame will be zero.
(B) The kinetic energy of the system in centre of mass frame will be minimum.
In the presence of non-zero impulsive external force for the system, we cannot conserve the
(C)
momentum of the system.
In the presence of non-zero external force for the system, mechanical energy of the system is
(D)
always conserved.

11) Find the angular frequency for small oscillation of block of mass m in the arrangement shown in
the figure. Neglect the mass of the rod (system is in vertical plane).

(A)

(B)

(C)

(D)

12) Find time period of oscillation if each spring has spring constant k.
(A)

(B)

(C)

(D)

13) If we have an irregularly shaped conductor as shown and a charge is given to it, choose the

correct statement.

(A) the electric field and electric potential at P is maximum among all points of conductor.
(B) the electric field at P is maximum and electric potential is same at all points of conductor.
(C) the electric field and electric potential at P is same at all points of conductor.
(D) the electric field and electric potential at P is minimum among all points of conductor.

14) A point charge Q mass m is projected with same initial velocity v0 from a very far off point as
shown. The sphere shown has a charge –Q, radius R and is uniformly distributed over its entire
volume. Through out the process, this sphere stays stationary. Find v0 so that the point charge
strikes the sphere at 45°. (given that , g = 0)

(A)

(B)

(C)

(D)

15) In given two cases two concentric conducting spherical shells are arranged as shown. In case-1
when switch S1 is closed energy loss is Q1. In case-2 when switch S2 is closed energy loss is Q2 then

the value of is :

(A) 5
(B) 0.5
(C) 1
(D) 0

16) Figure shows an electric line of force which curves along a circular arc. The magnitude of
electric field intensity is same at all points on this curve and is equal to E. If the potential at A is V

then the potential at B is :-

(A)

(B) V – ERθ
(C) V + ERθ

(D)

17) The figure represents an elliptical orbit of a planet around the sun. The planet takes time T1 to
travel from A to B and it takes time T2 to travel from C to D. If the area CSD is double that of area

ASB, then

(A) T1 = T2
(B) T1 = 2T2
(C) T1 = 0.5T2
(D) Data insufficient

18) A uniform rod of mass m and length R/2 is put into a tunnel of the same length inside the Earth's
surface as shown. Distance of the centre of gravity of the rod from the centre of the earth will be :

(A)

(B)

(C)

(D)

19)

One face of a prism with a refracting angle 30° is coated with silver. A ray is incident on another
face at an angle of 45° is refracted and reflected from the silver coated face & retraces its path. The
refractive index of prism is

(A)
(B) 2
(C)
(D) 1.5

20) A point source S is placed at the bottom of a transparent block of height 10 mm and refractive
index 2.72. It is immersed in a lower refractive index liquid as shown in the figure. It is found that
the light emerging from the block to the liquid forms a circular bright spot of diameter 11.54 mm on
the top of the block. The refractive index of the liquid is :-

(A) 1.21
(B) 1.30
(C) 1.36
(D) 1.42

SECTION-II

1) In the figure as shown, a triangular portion is cut from a circular disc of radius R. The distance of

centre of mass of the remaining portion from the centre of disc is . Calculate

2) A sphere A of mass 2kg moving with velocity v0 collide with bob of mass 1kg as shown in the
figure. value of tension at which string of pendulum break is 40N. If length of pendulum is 30 cm,

0
then find the maximum value of v in m/s so that string does not break. Coefficient of restitution is

3) A small ball of mass m = 10 gm hangs from a light rod of length 10 cm. An identical ball projected
from ground strikes the hanging ball and sticks to it. Collision takes place at height of 5m while
projected ball is travelling horizontally. After collision the combined mass just rotates to vertical
position. Assume that plane of projectile motion and circular motion is same. If velocity of projection
of ball is expressed as . Give the value of .

4) An observer can see through a small hole on the side of a jar (radius 15 cm) at a point at height
of 15 cm from the bottom (see figure). The hole is at a height of 45 cm. When the jar is filled with a
liquid up to a height of 30 cm the same observer can see the edge at the bottom of the jar. If the
refractive index of the liquid N/100, where N is an integer, the value of N is___________.

5)

A thin rod of length 10 cm is placed along the principal axis of a concave mirror of focal length = 30
cm such that its image, which is real and elongated, just touches the rod. Find the length (in cm) of
the image?

CHEMISTRY

SECTION-I

1) Which property is not caused by hydrogen bonding?

(A) High boiling point of water

(B) Solubility of NH3 in H2O
(C) Polar nature of halogen acid
(D) High viscosity of H3PO4

2) Density of ice is less than that of water because of

(A) presence hydrogen bonding

(B) crystal modification of ice
(C) open porous structure of ice due to hydrogen bonding
(D) different physical states of these
3) Which of the following oxyacids of sulphur contain S-S bonds?

(A) H2S2O8
(B) H2S2O6
(C) H2SO5
(D) None of these

4)

Which of the following is false order of –I effect ?

(A) –F > –Cl > –Br > –I

(B) –F > –OH > –NH2

(C)
–F > –NO2 >
(D)

5) Which resonating structure of vinyl chloride is least stable :-

(A)

(B)

(C)

(D) All have equal stability

6) The correct time independent Schrodinger's wave equation for an electron with E as total energy
and V as potential energy is:

(A)

(B)

(C)

(D)

7) λ absorbed for d—d transition is increased when [M(H2O)6]2+ is converted to :

3+
(A) [M(H2O)6]
2+
(B) [M(en)3]
4–
(C) [MF6]
 4–
(D) [M(NO2)6]

8) Select the correct one about complex [Ni(NH3)6]+2

(A) Hybridization is d2sp3

(B) It form inner orbital complex
(C) It is paramagnetic in nature
(D) NH3 is a weak ligand

9) Which of the following is most reactive towards SN2 mechanism ?

(A) CH3–Cl
(B) CH2=CH–CH2–Cl

(C)

(D)

10)
Choose correct option for mechanism x and y, product A and B :-

x y A B

(1) SN2 SN2

(2) SN1 SN2

(3) SN 1 E2

(4) SN 1 E1

(A) 1
(B) 2
(C) 3
(D) 4
11) In which of the following reaction saytzeff alkene is major product ?

(A)

(B)

(C)

(D)

12) , (B) is

(A)

(B)

(C)

(D)

13) The Henry’s law constant for the solubility of N2 gas in water at 298 K is 1.0 × 105 atm. The mole
fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles of water at 298
K and 5 atm pressure is :

(A) 4.0 × 10-4

(B) 4.0 × 10-5
(C) 5.0 × 10-4
(D) 4.0 × 10-6

14) The rate of a certain biochemical reaction physiological temperature (T) occurs 106 times faster
with enzyme than without. The change in the activation energy upon adding enzyme at is :
(A) -6RT
(B) +6RT
(C) +6(2.303)RT
(D) -6(2.303)RT

15) A reaction : A2 + B → Products, involves the following mechanism:

(A being the intermediate)

Products (slow).
The rate law consistent to this mechanism is :

(A) Rate = k[A2] [B]

2
(B) Rate = k[A2] [B]
1/2
(C) Rate = k[A2] [B]
2
(D) Rate = k[A2] [B]

16) Assuming complete ionisation, the solution having maximum freezing point will be

(A) 1 M CaF2
(B) 1.5 M Al2(SO4)3
(C) 2 M NaCl
(D) 1 M AgNO3

17) Match Column - I with Column - II

Column - I Column - II

P van't Hoff factor, i I Cryoscopic constant

Q kf II Isotonic solutions

Solution with same Normal colligative property

R III
osmotic pressure / Abnormal colligative property

Solutions with same composition of

S Azeotropes IV
vapour above it
Choose the correct answer from the options given below :
(A) P - I, Q - III, R - II, S- IV
(B) P - III, Q - II, R - I, S - IV
(C) P - III, Q - I, R - IV, S - II
(D) P - III, Q - I, R - II, S - IV

18) Which of the crystal systems contains the maximum number of Bravais lattices ?

(A) Cubic
(B) Hexagonal
(C) Triclinic
(D) Orthorhombic
19) F-centres are :-

(A) the electrons trapped in anionic vacancies

(B) the electrons trapped in cation vacancies
(C) non-equivalent sites of stoichiometric compounds
(D) all of the above

20) The face centered cubic cell of platinum has edge length of 0.392 nm. Calculate the density of
platinum (g/cm3) : (Atomic weight : Pt = 195)

(A) 2.09
(B) 30.6
(C) 7.9
(D) 21.5

SECTION-II

1) Number of statements is (are) true about resonance?

(i) Resonance is an intramolecular phenomenon.
(ii) Resonance involves delocalization of both σ and π electrons.
(iii) Resonance involves delocalization of pi electrons only.
(iv) Resonance decreases potential energy of an acyclic molecule.
(v) Resonance has no effect on the potential energy of a molecule.
(vi) Resonance is the only way to increase molecular stability.
(vii) Resonance is not the only way to increase molecular stability.
(viii) Any resonating molecule is always more stable than any non resonating molecule.
(ix) The canonical structure explains all features of a molecule.
(x) The resonance hybrid explains all features of a molecule.
(xi) Resonating structures are real and resonance hybrid is imaginary.
(xii) Resonance hybrid is real and resonating structures are imaginary.
(xiii) Resonance hybrid is always more stable than all canonical structures.

2)

Total number of possible product after monochlorination of butane?

3) is a first order reaction. The initial pressure of the system was found to be
800 mm Hg which increased to 1600 mm Hg after 10 min. The total pressure of the system after 30
min will be_____ mm Hg. (Nearest integer)

4) The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it
has to be isotonic with blood. The concentration of glucose solution in gL–1 is _____
(Molar mass of glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer)
5)
Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major
product P is 80% whereas Q is 100%.
Mass of product Q obtained is ________g.
(Given molar mass in g mol–1 H: 1, C : 12, O : 16, Br : 80)

MATHEMATICS

SECTION-I

1) Consider ΔABC as shown in the figure,

if AB, BC, CA are distinct integers then minimum possible value of (AD + EC+ BF) is :-

(A)

(B)

(C)

(D)

2) Let ℓ1 and ℓ2 be two arcs of equal length of two circles with radius r1 and r2 respectively.

If ℓ1 and ℓ2 subtend angle and at their corresponding centres such that (m, n are
coprime) then

(A) m + n = 9
(B) m + n = 1
(C) m + n = 18
(D) m + n = 2

3) If in a ΔABC, and b : c = 2 : then =

(A) 30°
(B) 45°
(C) 90°
(D) 60°

4) Let A0A1A2A3A4A5A6A7 be a regular octagon inscribed in a circle of unit radius, then the product of
the segments A0A2 and A0A6 is -

(A)

(B)
(C)
(D) 2

5)

In ΔABC, with usual notations r1, r2, r3 are in harmonic progression. If area of ΔABC is 24 and
perimeter is 24 then length of its longest side is

(A) 12
(B) 10
(C) 9
(D) 6

6) If is expanded in the power of tanx, the constant is-

(A) 1
(B) 2

(C)

(D) –1

7) If where n ∈ N, then which of the following is true ?

(A)

(B)

(C)

(D) T100.T101 = 48

8)
If and , then

(A) D1 = 2
(B) D2 = 9
(C) D1 = 4
(D) D2 = 5

9)

If an invertible function ƒ(x) satisfies x + |ƒ(x)| = 2ƒ(x), then ƒ–1(x) satisfies

(A) 3x + |ƒ–1(x)| = 2ƒ–1(x)

(B) x + |ƒ–1(x)| = 2ƒ–1(x)
(C) ƒ–1(x) – |x| = 2x
(D) 3x – |ƒ–1(x)| = 2ƒ–1(x)

10) If then complete set of values of x (where represents greatest integer

function)

(A) [1, 3)
(B) (1, 3)
(C) [1, 2]
(D) [0, 3)

11) If . If ab < 0, then which of the following is incorrect ?

(A)

(B)

(C)
ay = , bx =
(D) None of these

12) Let . Then

(A) f is continuous at x = 1
(B)

(C)

(D) does not exist

13) The value of limit

is value of ___________.

(A) 1
(B) 2
(C) -1
(D) 3

14) is :-

(A) non-differentiable at two points.

(B) discontinuous at two points.
(C) continuous but non-differentiable at three points.
(D) non-differentiable at more than three points.

15) If then the complete set of points where is non-differentiable are

(A)
(B)
(C)
(D) None of these

16) Let , where [.] denotes the greatest

integer function. Which of the following statement is true ?

(A) g(x) is discontinuous at seven points.

(B) g(x) is discontinuous at six points.
(C) g(1.7) = + 1
(D) None of these

17)

Let ƒ(x,y) = ax2 + 2hxy + by2 + 2gx + 2ƒy + c such that abc + 2ƒgh – aƒ2 – bg2 – ch2 = 0 and h2 > ab.

If ƒ(2,3) = ƒ(–1,4) = ƒ(7,–12) = ƒ(0,0) = 0 and , then is equal to :-

(A) 2

(B)

(C) –4
(D) 4

18) If y = 1 + x + + ... ∞, then =

(A) y
(B) y – 1
(C) y + 1
(D) None of these

19) If tan–1(a2+3|a|–4)+cot–1(4π + sin–1(sin14)) = , then the value of sin–1 sin (2|a|) is equal to

(A) 6 – 2π
(B) 2π – 6
(C) π – 3
(D) 3 – π

20) Let is continuous for all x ∈ R, then which of the following is

true-

(A) Range of ƒ(x) is (0,∞)

(B) ƒ(x) = 1 has two solution
(C) ƒ(x) = |ƒ(x)| only for x > 0
(D) ƒ(x) = 1 has no solutions

SECTION-II

1) A circle of area 20 is centered at the point indicated by a solid dot in the accompanying figure.
Suppose that ΔABC is inscribed in that circle and has area 8. The central angles α, β and γ are as

shown. then the value of is

2) Let f(x) be a continuous and differentiable function satisfying the given functional rule (x – y) f(x +

y) – (x + y) f(x – y) = 4xy(x2 – y2) ∀ x, y ∈ R and f(1) = 1 then is equal to :

3) Let a quadratic polynomial ƒ(x) satisfy ƒ(–1 + x) = ƒ(–1 – x) ∀ x ∈ R and (ƒ(1) – 5)2 + (ƒ(–1) – 1)2 =

ƒ'(–1). Value of is, where [.] represents greatest integer function.

4) If , then the value of is

(where [.] is greatest integer function)

5) Let ℝ be such that . Then equals

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D C A C A A A A D A C B A C B C C A C

SECTION-II

Q. 21 22 23 24 25
A. 6 3 2 158 15

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C B D C C C C C C D A A D C D D D A D

SECTION-II

Q. 46 47 48 49 50
A. 7 3 2200 54 184

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A C D B A B C D A C C C C C A C A A A

SECTION-II

Q. 71 72 73 74 75
A. 1 100 3 2 7
 SOLUTIONS

PHYSICS

1) Since Apparent depth =

Length of Image = L +

2) Explain question
To determine the nature of image formed by refracting curved surface

Concept
Refraction at curved surface

Solution

V is always negative.
∴ Image remains virtual

Final Answer. Option (4)

3)

⇒ µ0 = 1

4)
 r2 = A

µ sin A = 1 sin 90°

dividing the two equations.

5) Question explanation :
The graph shows how image distance v varies with object distance u; what points above P
represents ?

Concept :
Mirror formula

Solution:

where u = v

so u = 2f = v

Final Answer: The correct option is (3).

6)

Ans.-1

7)
Iα = t = mgasinθ
 8) For mean position : qE = kx

x= = Amplitude A

⇒
Net force on block at any instant Fnet = qE – kx

Fnet = –k
= – k(x – x0)
Fnet = –kX
ma = –kX

a=–

9)

Question Explanation: We need to find the ratio u1/u2 of the system's electrostatic potential
energies.

Concept: Electrostatic Potential Energy of a Point Charge System

Solution:

For a system of three charges, potential energy is Let

Case 1: at P2 (middle)

A. Pairs: at a, at a , and (+q,+q) at 2a.

B.

Case 2: at P1 (end)

A. Pairs: at a,(+q,+q) at a, and at 2a

B.

Ratio Calculation:
 Final Answer: Option (1)

10)

(A) The net momentum of the system, in the centre of mass frame will be O :
Suppose n particle of mass
m1, m2, m3 ........ mn
and their velocity ...... respectively

.... (i)

In C.O.M frame momentum of system :-

=0

Question Explanation : The problem asks to identify the incorrect statement(s) regarding a
system, particularly in the context of the centre of mass frame.

Concept: “This question is based on centre of mass frame”

Solution:

(B) The K.E. of the system in C.O.M frame will be minimum.

If we take same assumption as in option A

(K.E. of particle 1 w.r.t C.O.M)

(K.E. of particle 2 w.r.t C.O.M)

(K.E.)n,cm = mn (vn–vcm)2

(Total K.E.)cm = m1 (v1–vcm)2 + m2 (v2 – vcm)2 + ...... + mn (vn–vcm)2 .... (i)

(v1 –vcm) < v1
(v2 –vcm) < v2

(vn – vcm) < vn

(K.E)ground = ... (ii)
(K.E.)system w.r.t ground > (K.E)system w.r.t C.O.M
So, Option (B) is correct
(C) Non-zero impulsive external force for the system

for momentum conservation force must be 0. on the system

(D)

Above Both example is show. In presence of Non-zero external force for the system (m). Mechanical
energy conserve.
System is 'm' normal is external force. work done by
Normal on 'm' is :-
So, Mechanical energy Conserved.

Final Answer: The correct option is (4)

11) k3 can be replaced by k'3 at centre of rod, such that

also k2 , k3' are in series and their net in parallel with k1

12)
15) Question Explanation: The question asks to find the ratio of heat energy loss
during the redistribution of charge when grounding spherical shells.
Concept: Electrostatic Potential Energy and Earthing.
Solution:

After earthing

⇒ Q = – q Uf =

Ui =

Energy loss (Q1) = Ui – Uf =

After connecting charge will move to outer sphere

Uf =

Ui =

Energy lost (Q2) =

Final Answer: Options (3)

17) Question Explanation:

Relating time taken by a planet to the area swept in its orbit.

Concept:
Kepler's Second Law of Planetary Motion.

Solution:
Kepler's second law states that the line joining a planet and the Sun sweeps out equal areas in
equal intervals of time. This means the rate at which area is swept (areal velocity) is constant.
Therefore, the time taken to travel a segment of the orbit is directly proportional to the area
swept during that time.

Areal velocity: constant.

This implies .
We are given that Area CSD = 2 × Area ASB.

Substituting this into the equation: .

This simplifies to , which means or .

Final Answer:
Correct option is (3).

18)

20)

1.36

21)
Here α = 3
β=4

22)
 v0 = 3 m/s

23)

Velocity after collision to complete circular motion

= 2m/s
Velocity before collision = 2 × 2 = 4m/s
Initial velocity along y direction = = 10 m/s
Hence

So require value =

24)

1sin45° = µsin r

N = 100 µ
N = 158.11
So integer value of N = 15800

25)

Explanation: To determine length of image placed along the axis of concave mirror

Concept: Reflection at curved surface.

Solution:

One end of image is touching rod, this point will be at centre of curvature. (C), image is elongated,
so, it will be away from centre C and object will be between C and F.
For point B of rod,

f = –d, (d = 30 cm)

v= is position of B’

So, length of image is

Final Answer: 15

CHEMISTRY

26)

Ans.-3

27)

Ans.-3

28)

Ans.-2

29)

Ans.-4

30)

Ans.-3

31)

Ans.-3
32)

Ans.-3

33)

Ans.-3

34) Explanation Question: Question is asking about the most reactive substrate towards SN2
reaction.
Concept: This question is based on mechanism of SN2.
Solution: Rate of SN2 ∝ Electrophilic nature of α-carbon atom of R–X

∝
∝ stability of transition state

–I and –M groups increase electrophilicity of α-Carbon atom of R–X.

Over all reactivity towards SN2 reaction is :

O = CH —CH2 —Cl > CH3—Cl > CH2 = CH – CH2 – Cl >

(–I) (least hindered)

Final Answer : Option 3

35)

Explanation Question:
Question is asking about mechanism and product of given reaction.

Concept:
This question is based on multiple concept SN1 & E2 reaction.

Solution:
(1) SN1 reaction are favored by conditions stabilize carbocations, involve good leaving groups,
weak nucleophilic and utilize polar protic solvents.
(2) E2 reactions, or bimolecular elimination reactions, require a strong base, a good leaving
group and a specific stereochemical orientation (anti-periplanar) for the leaving group and the
hydrogen being eliminated. The reaction proceeds in a single step with a transition state
where the base is abstracting proton while the leaving group is departing.
The correct option is (3)

36) Question Explanation: Determining which reaction conditions favor the more substituted
(Saytzeff) alkene.

Concept: Saytzeff (Zaitsev) Rule in elimination reactions.

Solution: Saytzeff's rule states that the major product is the more substituted (more stable)
alkene.

A. Saytzeff products are favored with small bases (like CH3OK) and good leaving groups
(like Br−).
B. Hofmann products (less substituted) are favored with bulky bases (t−BuOK), poor leaving
groups (F−), or quaternary ammonium salts.

A. Option 1: Quaternary ammonium salt → Hofmann.

B. Option 2: Alkyl fluoride (poor leaving group) → Hofmann.
C. Option 3: Bulky base (t−BuOK) → Hofmann.
D. Option 4: Normal base (CH3OK) + Good leaving group (Br) → Saytzeff.

Final Answer: Option (4)

37)

Ans.-1

38) As the mole fraction of N2 gas is 0.8 and total pressure is 5 atm. Therefore the partial
pressure of N2 will be 4 atm.
Now, Pa = KH Xa

n = 4×10—4 moles
39)

40) From the slow step : rate = k2[A][B] ... (i)

From fast step:

... (ii)
From (i) and (ii)

41)

Ans.-4

42) Theoretical.

43)

Ans.-4

44)

Ans.-1

45) d =

d=
d = 21.5 gm/cm3

46) (i), (iii), (iv), (vii), (x), (xii), (xiii) are correct statement about resonance.
 47)

Ans.-3

48) Answer is (2200)

49)

π = C.R.T
7.47= C × 0.083 × 300
C = 0.3 M
= 0.3 ×180 gL–1
= 54 gL–1

50)
Molecular mass of Q = 230g mol–1
Mass of Q = 0.8 × 230
= 184 g

MATHEMATICS

51)
1, 2, 3 is not possible because it is not a triangle next is 2, 3, 4.

52)

53)

cosB = 0 ∠B=90°.
54) Question Explain: We have to find product of segment of regular octagon inscribed in a
circle.
Concept: This question is based on Properties of triangle
Solution:

A0A2 = 2A0D = 2cos45°=

Similarly A0A6 =
⇒ (A0A2)(A0A6) = 2

Final Answer: Option (4)

55)

a,b,c AP ; 2s = a + b + c = 24
2b = a + c 3b = 24 b=8
a + c = 16 ...(1)

576 = 48(144 – 12(a + c) + ac)

12 = 144 – 12(16) + ac
ac = 60 ...(2)
from (1) and (2)

56) Explain Question: In this question we have given a 3 × 3 determinant with trigonometric
functions and we have to find the constant term expanding this in terms of tan x.

Concept: The constant term of any polynomial P(t) is the value of the polynomial when the
variable t is set to 0.

Solution: Given (1 + tan2 x = sec2 x)

put tan x = 0

=1

Final answer: Therefore correct option is (1).

57)
C2 → C2–C1, C3 → C3–C2

Tn = –1(–6) = 6

58) where x = 28
D1 = D2 = 4 i.e., independent of 'x'.

59)

Given x + |ƒ(x)| = 2ƒ(x) ...(1)

If ƒ(x) ≥ 0, then (1) ⇒ ƒ(x) = x
⇒ ƒ–1(x) = x is x ≥ 0 ...(3)

if ƒ(x) < 0, then (1) ⇒

⇒ ƒ–1(x) = 3x is x < 0 ...(4)
∴ Now option (4) satisfies both (3), (4)

60)

Final answer : Option(1)

61)
⇒ a2x2 + b2y2 = 1 and |ax + by| = 0
⇒ –2abxy = 1

62)

63)

64)

Non-differentiable at x = –1, 0, 1

65) Given that

Clearly the domain of is

⇒ It is non differentiable at the points
66)

Also

So
Now, options can be checked directly without further simplification.

67) ƒ(x, y) = 0 represents pair of straight lines passing through (2, 3), (–1, 4), (7, –12) and (0,
0).

∴
( i.e. slope of other line passing through (–1, 4) and (0, 0)

68)

69) a2 + 3|a| – 4 = 4π + (14 – 4π) ∴ |a| = 3

70)
ƒ(0 + h) = λ
ƒ(x) is a continuous function and λ = 1
Range of ƒ(x) is (0,∞)
ƒ(x) = 1 has one solution
ƒ(x) = |ƒ(x)| is always possible
because ƒ(x) > 0 for all x ∈ R

71) r2(sin α + sin β + sin γ) = 8 and πr2 = 20

72) f(x) = x3

73) ƒ(x) = a(x + 1)2 + b ; ƒ(1) = 5; ƒ(–1) = 1

⇒ ƒ(x) = (x + 1)2 + 1; i.e. ƒ(x) ≥ 1

74)

75) =1

α – 1 = 0 & β × 3! =1

α=1 & β=
6(α + β) = 7

Final answer: 7