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The document discusses various concepts related to solutions, solubility, and the behavior of substances in different states. It includes definitions and examples of saturated and unsaturated solutions, as well as calculations related to molarity and concentration. The text appears to be a mix of instructional content and notes on chemical principles.

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0% found this document useful (0 votes)
5 views16 pages

Print

The document discusses various concepts related to solutions, solubility, and the behavior of substances in different states. It includes definitions and examples of saturated and unsaturated solutions, as well as calculations related to molarity and concentration. The text appears to be a mix of instructional content and notes on chemical principles.

Uploaded by

w5758rvkmz
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

CLASS-il-

HANPWff ITTEN t-lOTf,

Made By Anil Kum!


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· PO((t( :,, MktYt.


cl tohtd- c(o 'f OU mean bV Btt1lh1f &o(<A.h9'1 ')
[Link] -1-y ~e i ,otuh'o~ lOrln:[Link]•~ o~ ~o tuk
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ont 601,el\.t- ccill~d B1nQl1( .Aolu.h'0>1·


eJ Al coho( and WQ tty
whaJ do '/ ou -mean bl/ tti nary,
it:,oluho11? aYld
Sudl pe 1, 6ol [Link].'0¥> co 11 fa-H11 n,t -M O .Aolld t.,
o~e 111\'\/fYJ- caJJcd tet MY'{ ~0\ulro v,
>,.. UNSA1URATtD SOLUTION .
+ SA,oRA,EP Sl>1.,\Jf\D~
~o Jt i\o([Link] ~ ·c,.
ot 6ittd Q'ld t,rt MU ht,
qnoye. av,d cp,ort toluJe
,J,h ose l>ol&.J\1) n ~C M Y\ o
,noye 6D\u.k. CA~ be dissoh1«! ca~ t>e d.J'sso\vtd..
J>iluk ~olu,.ho~ Conct~[Link] Solutt°"1
, tt do lu.h~H
Sue.I\ .f1f pe of Sof'Lh· o~ ~c l, ~t, t
wt\icJ, acid p'ttSt"1- w, u,)\iu, ac id VJ [Link]-
llTMll 'l,~~n'fy Q""
u,a .fty [Link] 'iL(lM~'"f calfecl
to~ ce~ ~ta kd t>oluht>H.
:0 pre se~ Vt' ltn~e q,t0th'n,,
who.I- do vou ~to" by - • 30 1- 41uco~e w
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Pf Y)1 -;. tt,g 1' lo 0
~-r
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,<. lo
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s-oo
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-k> ,tt,e <mom '\ " CO'M'10Ylt~ -

- rA : WA : 1Yl41YJ i"[Link] i~
WA+Wg+We.
- la~ -Wt- - - -
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WA-t~o +t.,J t
f()Qgs t'(Qc!{o vi ::-1
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-ot llY)aro t-cttctio~ 11 a UY1it Ress q. 4itrth'.ly.
w~o.t t1o you mea¥J .by mote frQch·o~ ?.
It ' -ttle '[Link] bf- Y\o. ct cmollD q, 0>1e

[Link],~0Y1t.nt9 i.o -fl \t fb-\,J Y\O• i moltt, 1 ~oluJioYJ.


:Ct de~o~d by l. oi 1- c en! - ~o..i)
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~- Ctdcul(lfe 'Jllo\t ~l' QC .h' o~ 'i 4- 4MoltJ, 'I> n1ef'la~o (

f-h 'JY)o\.t.o 1 ettl Q~ot.


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f:;. IMOLA fllTY I rMOlALtTy ,
dq /n td r,o .
i, d~ i ned ao -no•
It I:t ,.v., QJJ

i cmolu of 6otuk dJ'.uo\lltd ,


'rtlOlt.0 '\ to tu k [Link]\vttl
•~ pe t li h"f ct 1,o\ulro~ t:>et Kd 'b Ao \\l ~
Mel L"' tJt MolQY oY M lJY\if- : me>\ t<j. I OY mot~ Ol' M
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Mo\~ li\-y 'YID•"£

\lol, i ~o\u.,h'QM L MM 1, 61>\"41Mt.;.,


M-;. Wa X (o oo Luhere.
V (mL) wa -= mass 4, oolu.J-c
Ma
Ma-: f't\ol <tr n?Gi? i l>olule
v cn1 t) -=-- 'IoI lfY>l t Y)'J mL.
-m w a x te 0

M 'i Solve Ill" :,_. S,


o;.
~)
WACj)
*
ty\a
Mfl
lb13tt [Link] ·S" fflo lar Na OH o -~ 'rrdo./
H01.4) CQ'll 'lo~ dis O
NaOH ()le ,eMt aiutt>Ud ~olLtJ'l(JI) ,
0-S n,ela-r@)rnea~ 6 -~ rnot~
Ka~H &is.s.o\ved
vi-1 tJe, Qil-fe 'lo \u me i
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<9 whd.1- Yo ¼ t e ffe & of-
OYld 'nlo( [Link] J
1rQk.,re ff* oY\ "1ola1ify

w i~ lYICY'lqse h1 ~ l( Q ~ Y e , Yn
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dtt<[Link]~ b~caJJ.f~ H- ,~vo lV&J \Jol-
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C4'[Link] Mo (ol lly (M ) "1 '-0 1. Of mus NqOH ~- .b >I ~

:_ O"I. N~OH ,ntQ1\D otod ,-JaOH 0YM 100j ~otlAl\·0111


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m~ ~<s'f- L!.if ,;: ~' .: 6-i~ ~o f~ "'
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. f'V1JJ ~ft( ) -
JJ) l'ilol4-.i~ CM) ,. _wa -'
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' 4.1' a pa, ;ii cul4Y k'llll:> , wu1xl m1.1 a,,, 01111t- c!,olu..lC ""1 _11ram.s
disJohlrd ·~ j,q'I't,'c..JQ-. i"°" h ly of .6CJl,lt..t" so ,tt,,sl" .SO 1.,J,'8>1 bt<Offl<f
SQMGJ(d•
,,, Solubi Ii~ of Jol1d .:,, Li~uid

-~e ndott\e-rmic: p.,..octtt e xottit:a°'r>"t'c. P'rfJ ctsr


1'tl>f i~(Mltt( , 4111u1,ilify of 1't,+ ,nctta~, oolub'Jlly
botid k4 Ii\ ~d i~<'h(QSt.t °I, Sol id h~~d deC-tt4s,._.
• Likt ~ ,s~olvt like {NahJrt o~ salu~t and .tolv«t1t t
• Pol4t d., ssalvt t,•la< • No~· polo-, d{tsolve ho.-t .. t,• 14_,
ta
HU + t,IQOH -tj 8 tM ZtJle -,.. To Cut Me
· Pol4t' dDtt'I- d,:tso '"" ~O)I,. ~14't
~J H.t t> + 0 i I
so,~b iHtif of 4QSf.$ li'i,uid
• 'ftr+e,dk.t"t :rT [Link], 6ot&Al,i lr'fy 1,~ dec~t'-'S~
• Ptessu1t
. .
(He~rv Law)
- Alt, to Htllll('S IAc,), 'l'l'IO.U
.
<f. !JOo ~~l«d
•.s drrt city ()10 po, fioMdf tJ;> prtStU'lt '\ 3M•
IIv, k-mtS SoluA,c lifvl
ct ..,p: I<'Xg'X
'I!" 8 molt? !'IS'[Link]°SIM
Hf~i,,~ (. 2ohtbili',)
co"'tG""
Henry's Law
1 bar 2 bar

0 O 0 0 O O O 0
0 0 The Henry's Constant Kh signifies that
Gas 0 0 0 0
0 0 0 0 0 0 0
.. ...

-
.&

- ...

-
...

- 1. It is directly pro portional to Temperature.

2. !t has di~ere nt values for different gases at same temperature. That meai
0 0 O 0
0 Liquid 0 1s a function of nature of gases.
0 0
0 3. Its SI unit is Kbar (kilo bar).
(i) To increase the solubility of CO2 in soft drinks and
soda water, the bottle is sealed under high pressure.

(ii) Scuba divers must cope with high concentrations of


dissolved Nitrogen with breathing air at high pressure
underwater. To avoid this air is diluted with He.

(iii) At high altitudes, the partial pressure of oxygen is


less than that at the ground level. Low blood oxygen
causes anoxia.

Vapour fressurt
r~ t, -ltlt [Link]>ce e~erlfd
va; oqri abo vt ir1tt,act ,t, tJiw·a.
It /IJ de11okd tut (I.
Facto.-. atfeclll19 Vapor Pressure

As temperature Increases, the fraction of molecules with


enough energy to enter the vapor phase Increases, and the
vapa pressure Increases.

higher T _ . higher P

The weaker the intermolecular forces, the more easily


particles enter the vapor phase, and the hlgherthe vapor
pressure.

weaker forces~ higher P


-Pa ~x11
Pa


_~&.. -:: i -X/J. :X,t = t, 8 - r«
Ps . f'a
Lf\, l-r.B Pe -P11 -t \owtl1~ V·P
r ,..

Pg PS-l'B ..., Relak've Iowtli~


-1-18 WI V·P
<9· "·' of ~Urt do(" i [Link] v., j rtakY \(. (J 'A brr Jl\f
~ - lnt I/·P ot 'f,4i-t ~d.!tt reakt beca.c.u e i I- ~-I''?
covnpl~tdr v*o\.lll&ed eqs,•! f On +he o-fhet -hand \,<\1 b-r,~
.b"[Link]~ Nae[ is t1on.- 'lO(t:t,wl~ . h-1 n~re . So \/[Link]'
tJ}'[Link]'r! i rN.s t>alu..h~~ JI) Re~ -

lhnor1lt>VI'! la."6 Accov-di'}? h Hiis [Link] / ~ - <'(, .fhL <1o/uli_'o1,1

'
t'.' dJrtc~ pn,po'l'n·on~ J:J.J_ t:So luh'o~
«l w~ pttss lO"e coo~,1 ' .
red4u coo k1',. 1?,+t~,
~· u>itti lY1Chta1e w, p-rt1JtOre , YJA1d<l coo~tr-
- Y> er ea sto . ~o bo i n
'vtJ b/ [Link] (s4okt:
.:[Link] i'otc.,ko>, No" .. 1dtal g.h.L-ho.-.
:tt ob~1 Raout+1c QQ&-0 • It' [Link] v,ot obty ~[Link]-.s
t), IA' • J..4w
A = ,,A. XA • pA-=F pA l A -"· ._, X
t'& Pe•lg ~8 -r- "S B
Ththl Aho&Aid be no • 1Jler-t 6hoult.l be th4Vlje
chot13t '" er.~;vft.~ t., e~~'f
b~-:o Art *o
1Jltl'e bhouOd be no ~hOMj~ • 'fhe,u Ahoufd be chortj t:
WI 'I oil(~ e A\/ -:-o \lo1uw,t. AV::/ o
• · Inkt~ch·o~ b/u., A.-8 c.o , .r~Ik-tQchbM u:> A .. g
h tlmilQ,r -l;o Ari+ g .. a * co~~e~ t,
<!.; ~10-. Jo
>1~
A,. 1r ' S-- B
e.-l Hexttt\e + H~f1'Yle
CH3 0H ~~Hl"OK r~ Attl'o-,,t ,t C~lo)O~,~

[Link] i>t"1ohoM tj0'1vt peviok·o.-.


• Parh'd 'l·f 1, ot1t co~r1t""'1- 1hd..Q ;. "b one cont,oYlt"'1-
'io :1,eflk.,, .f-hQvi 'l·I tt .f+ial-- " 2el 1 ~'V\ p-rodt1 d--
c«!>~ont~ ~4-re ~t«Je f> lUffl ~yessu~e QVld mol£
'YY)LIAh' t,1,(d [Link] yno\t i.-odi'ovt 6Ytt.t..fiot1 '1) ~YJt~·
'f, #IQf- co~ont~ ) It'' '1. 1'A .('°AXA <)-/a 'X~
,," ? i,A. 1.. A 1Pa a
Pa
• C~QV\jt t,, \lo\Ltwtt. co +vc
q
.. cntt~e ~o\~Wl't t, -ve.
0 \J-:. -'le.
t,v: -t~
ttl K,iJt,y 4, &ol l VJCY't!QJU
I
. Evwtfr~ 1
&0 \ll dtfrt4!~
Art ) D C-flttlt oJoJO,f,tol) .AH< o (~eat evotvrd)

• Fof<'- inkl'Q the~ 'of"" • Fot<L inkt'Q th9~ bl '-"


lD n&t, on eJ\h we [Link]-< #14tl lO*t>[Link] £, S~M1tt' ,HIQ~
)-)qf t C.D Y\4,or1tN? )'[Link] c.o ~oritN?

ej H.,. SD'< + H.t O


,,
D
CH3 - c .. c.~ + ewe~
HND3 -t H.1. 0
• t. -~-- ~- p:
l
~ ~~9~~
Y..;.-•- - - . . . . ~
P · ...Pr •P,-•
P,
j ,,
jI . ,. .
I
I
....,.
! .1/

x.. = 1 . . . PNictiaa x.. • O
x.•o x. • 1
P .Z . . . . . . . . . - . . . . . . P aol_ _ _ _ _ .._
Colljak'vt Vrope1ftt.s: :-
,, 'fhost properh"fb ~cJ\ dependo upon YJll • lfi mole..o
tb So\u~ btd- no~ dePtrtttJ Uf)OYl [Link] 1, Jotuk.
Osmott'c. uhe
_.. &le'Jaf18t, 01 Boil1·n~ fo1>1t-
0 0 r
P¤c:,resJ10Y1 vn r-<eeu "J ,o,n
. , r<l (}

---> f([Link]\re towerinJ WI vapt>tllS' Pressu.9re


Freezing
Point
Depression J.• • * Bolling
Point
Elevation

Vapor
Osmostic
Pressure
Pressure
()()(0 - L
.
_J
Lowering

Osmotic. Pressure : CPo1r tr')


Applied semipermeable
p reuu,e membrane " l:~ -1-+tt par-h·lu.£>41' ()Y(~ U'ze.
---• rC_ ~[Link] al- Ndt CDh tlnkra 11'ot7 sidt.
t.o preve~t- ~e osmosis -ttn1>'-'jh
fresh
6em1, ~e1 meohlt mel71b-ran-L
water
/ ffla ~tlloliea1 ET- pr e1:s iDM /
<O .... Solullanl

Hi~ /1'-it tow Po< c_ C tnn(Ql' conc •1 ---{i 1


lBMl• t9M~ tJ \ C fe~ ia-itlJtt) -t"1i)
kiot.
0..,
Revtrlt ) low FMm (1, 6- ·d
'1o<C ,c_, -:::,>

p -=- (_"' ~"' T


\__-/f //_NJ LO'n~ tq.-, f--
\.f

~-= kl f R~, { C= 01D(Qr l9t'Jt.}


V
IP\/ = n~TI .idellR .3an [Link]., i (~~•1- Ho~ 1Qtt-c>-i)
L> far noY> e\ech-1\yle
P~ £i_!L ~~XT [: 1-: "O,,•~ Hoff Ij,.j. I (,~ GNCO!t
V c.h>, )
L?~\rtbolylt

eJ NqCR .-,.Na-t-+u-
t L~i\
i #iat- otmotic. pye~ture it a con13aHve Pn>~t14Y.
P-iove
Hou> ea" ~ou dtleY mine molot [Link] us,~ coll!jt1.1r"e
Ot I -L•

We know #la.I- tt': C'f.. R)( r &t,tt+,?


rr~n~R1r
$i~re,
't
osmo -b'c. ()re.ss111i: &e()entll!J
60 I..de 60 '-" e Cll V1 .hfJJf -#,ol- \ r 11
YID ·
a C
~\;~;~te
O

e tr+y.
ff'-;. ( t 1, \ f(1ol4Y 'f, _!./~
't1': wa_ t,. loo~ "f....R.1-T/
- ~8 \[(ML) w,s ~l 0
••XtlX,
::::) tll B -= TI')( v l ~\)
-=t> 1h h ~· cia.D f- p. M CQ
be made. b'I -1 cdDtt lo~e Ni tt"a.1-e
tA:>htil- lo -1+,1: dl ffet"e)1tt bt-lwtt~ rumoti-1 aVld ,;>1ffu1iot1?
Osmosis Diffusion
Water molecules Air molecules
HIQh conc~tnitlan LOw concM!rallOft HIQll conctn1r.M10n [Link] concentrMIOn

Cc( _ C
1t .,e -~
till I: tl - SMiipe~
C (] t C «n~
mem~ne
(' C C - Cw

-, l Y\ -l+uo phtfln ~t.110 VI .fflt. -, :&, t,htn omen° n ..ff,L


fflove 111btt- i ffl Ole [Link] ~(I) mo\[Link] movet, ~DtM
pltut . tow c8Y\ c. s,1-e "-'f' cet1t, tn low ctMc.
to fur' cont- sik rl~
_, No g.l'-M ,t, used
-, S·P-M VJ tt~cl
{)~ ~lvtnl- cmotecuf(L) ClUf [Link] as wel.D oo l>o 1Vf~
mov'e .,.,~ }.ou)IJ.1 do ead, t,fflet
--t c~ be 1eve1£[Link] -, CQV1t4- be 1r evetJed •

ISO TONIC SDLUTlON s~c11 i Ool tt '1avi~ c10~


osmoh't f)[Link]'-t [Link] ,·.tott,V\lc ,r.l~
A i'. to\u..tlo H 1, Wit OLlf QI t tS ott>nlc. I.>) i-th o· gg:, 'f.
~" 1 [Link] "111owri 00 llt.(e . {<w/ .ff/t. [Link] 'Y)IQSS 't
U~K'f\OUln ~l [Link]
i IJ~~f; M
1
? /. Sol b '{ cane l,'11t isoft>)U( w·1-tfl O·&&n Sci
11' P-=
i CRT==- ic.'RT
:J.. [ 1.J· - \ 1 (
M.a \l(L) J M.a
X _!_
'/(L))
°'
-;=_ 5:. )\ J_ -::: O·&g':f- X J.
'J4.t I M I

Elt ...QN Otl Boi li'1J Poi~t ( AT~)


~)1
" It- ic [Link] rd 40 -Hie a.t wki ti\ [Link] u:t ()rttJ1tre
of ~of~kotJ btCOmtc t~~aJ .d-lt a} rno£pho 1< {)'r-tJJ'P(>
u to denokd t2.y ATt, .
or
ATbo< m (morJ.i¾y)
Botl1ng point

l.013 b8r
Solvenl Solution
A Tb-: t<b n,
or l Atm,1-- - .- ----.1'.-
't mold elt\14.h'o""
f (Oy\f t'Q~

li I
I I
I
4'1J
-i:, Ir , ,
oy
e [Link].t'o .s,o ~•·e,
(D 11,C f'o,t f ·
-$
Temperature/ K ____,.
T.
Iu~+ 'l k'bl ~Tb: k~ r\11
Ka.-: LlTb : o,s ~J wtol' '
m -m,t t,·1
~. llilt b.,,t- o l- pq rt bet12tt1e k.> ~s-1 . ., .7 K . whe~ I· eo j 1-
a Y\c!>~ vot4liJt ao(u.1-e l.Jl1~ cli Uo \ved .9 0;1 'f,-
bet11tne. . 1\ie B-t'~ becoW\~ 1$4. tl K. [Link].k
Y)1ol4"t
Tmtr ti, ~" tuk. l kb tt,is ber12t'le -: ~.Sj K K3 rnol"')
~- -· T k,, : J{1-J:l K
Tk, : ~r+. n K .6 T~-= Kb h1
W~ -:. l·~3"- --= \<bX Wll 'f.(oo~
WA • 3D(! Ma WAC '.f)
" } o·&t-:- &I.·~"- 't(t,go X tooo
l-lTt:>-= T-- 'r~::- o , ggk - .....
Mg jo
Ma-:: c:l , ~,1)(\ •toxtoOO

• Elev 4 h'o111 1111 8ot111~ ~oi t1~ ( A T.f) : o·U X S 0


\' ffie. .J.e~ • af ~-d\ "4',ott1" ()Yt s1l!'te °I> lt'[Link] becom"'
[Link] to V·P i i)o\id Ato..k ,, . I.t detiokd b'f [Link] .
ilTf o<M
/j T'- -= k~
I
11,1

1' . ._
ff
cc
'' .. ...
. motai deprts.t\OH ([Link]
::,
1--111
,-1:
I .....
: ...
.
o-c- C'r\fOSCo(J{c co~1tarit-
T: :r•
,• • f

TEMPERATUREIK
6 Tf e k4-- X ,c t•o 0

Ma '-llA(g)

6. T~ : i K~
• ~etgt-ivt
to ~t

Pure Solllmt l molal


l mol oCIGlutc

(a)

II• Val1'~ Hoff f-actn,r Ci)


'' l:t v.> +ht lrQ/1a t>f- e1()t¥1 Y11th trJ.0
• ft

iht -6,eoreh·c~ co\[Link] pnftrfy.


ot
''It itJ .file ,co.h·o of- -lflto't'eh·ca1
'lolut o f- 11>[Link]~ YVI~ tD ¾he
---
I• 1
--
----- --
---...
I• 2 e)( eY ,meMl.f 'la!ue. of molecu..lct1 WJQfl'
r C 'l)Jeorrh"tJ molel'ul4¥ mass
(_~ ob~tr\ftd niolteuhw tM•.t !.
Fo.- no~ -efec ~lyle c. "S~ fur e \et bt>ly fc
i=:i qJ For [Link](14'to~. •f-' t,) f:o't Q.tSOC1a.h_, of-
ej ~yeq CNf1.iCON1) elecn-o1y,k Ci>!) et rrtn,y ft t .(,1)

:J.-1..
0

q ll(cose CC, H,1 o,) o<. ::. A. - i o(


M-j_ y,, -,
II• Abnotmd Mola-r Mass :
- - - - - - - - w hoi tl1(: -molo't m~ caJJcc,fali
bl( collijl!live [Link] L, towe-.- 0¥ Nr'eY -tho" .file
ey ~ec\td \/[Link] , tt,o, ,f+\e [Link] rv,a.u M ccdkd t.14
AbllormaJ ,maw.

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