21-09-2025

2401CJA101001250034 JA

PART-1 : PHYSICS

SECTION - I (i)

1) A completely filled cylindrical tank of height H contains water of mass M. At a height h above the
top of the tank there is another wide container. The entire water from the tank is to be transferred
into the container in time t0 such that level of water in tank decreases at a uniform rate. The power

of external agent will be :

(A)

(B)

(C)

(D)

2) A uniform chain AB of mass m and length is placed with one end A at the highest point of a
hemisphere of radius R. Referring to the top of the hemisphere as the datum (Reference) level, the

potential energy of the chain is :-

(A)

(B)

(C)
(D)

3) In the figure shown the spring constant is K. The mass of the upper disc is m and that of the lower
disc is 3m. The upper block is depressed down from its equilibrium position by a distance = 5mg/K

and released at t = 0. Find the velocity of ‘m’ when normal reaction on 3m is mg.

(A) zero
(B) g[m/K]1/2
(C) 2g[m/K]1/2
(D) 4g[m/K]1/2

4) A uniform rod of length is being rotated in a horizontal plane with a constant angular speed
about an axis passing through one of its ends. If the tension generated in the rod due to rotation is
T(x) at a distance x from the axis, then which of the following graphs depicts it most closely?

(A)

(B)

(C)
(D)

SECTION - I (ii)

1) An ant travels along a long rod with a constant velocity relative to the rod starting from the
origin. The rod is kept initially along the positive x-axis. At t = 0, then rod also starts rotating with
an angular velocity ω (anticlockwise) in x-y plane about origin. Then :

(A) the position of the ant at any time t is

(B) the speed of the ant at any time t is

(C)
the magnitude of the tangential acceleration of the ant at any time t is .
(D) the speed of the ant at any time t is

2) On a train moving along east with a constant speed v, a boy revolves a bob with string of length
ℓ on smooth surface of a train, with equal constant speed v relative to train. Mark the correct

option(s).

(A) Maximum speed of bob is 2 v in ground frame

(B)
Tension in string connecting bob is at an instant

(C)
Tension in string is at all the moment
(D) Minimum speed of bob is zero in ground frame

3) Coefficient of friction between the two blocks Q and R is 0.3 whereas the surface AB is smooth

(A) Acceleration of P is 5.86 m/s2

(B) Tension T1 in the string is 17.7 N
(C) Tension T2 in the string is about 41.4 N
(D) Acceleration of P is 7.55 m/s2

SECTION - I (iii)

Common Content for Question No. 1 to 2

In the shown figure, the spring and string is ideal. The spring has the stiffness of 100 N/m and m = 1
kg. Friction exists between mass 2m and surface with coefficient of friction µ = 0.8. The system is
released with spring from its relaxed position and from rest. Based on above data, answer the

following question : (take g = 10 m/s2)

1) Frictional force acting on the mass 2m when it finally comes to rest is : (in Newton)

(A) 12.00
(B) 8.00
(C) 4.00
(D) None

2) Maximum extension in spring is : (in cm)

(A) 4
(B) 8
(C) 6
(D) 10

Common Content for Question No. 3 to 4

A block of mass 10 kg is put gently on a belt-conveyor system of infinite length at t = 0 sec, which is
moving with constant speed 20 m/sec rightward at all time, irrespectively of any situation by means
of a motor-system as shown in the figure. A constant force of magnitude 15 N is applied on the block

continuously during its motion.

3) The magnitude of acceleration of the block of mass 10 kg at t = 6 sec is (in m/s2)

(A) 4
(B) 2.5
(C) Zero
(D) None of these
4) Work done by the kinetic friction on the block of mass 10 kg is: (in joules)

(A) 1600
(B) 1080
(C) 1260
(D) 1420

SECTION - II

1) In the given figure block is held at rest such that spring is in natural length, now block is
released. Find maximum speed (in m/s) of block during the motion. (Take = 3.16).

2) One end of a spring of natural length ℓ and spring constant k is fixed at the ground and the other
is fitted with a smooth ring of mass m which is allowed to slide on a horizontal rod fixed at a height ℓ
(figure). Initially, the spring makes an angle of θ with the vertical when the system is released from

rest. If the speed of the ring when the spring becomes vertical is (2ℓ / 3) m/s then the value of

angle θ (in degree) is :

3) A particle of mass 5 kg is free to slide on a smooth ring of radius r = 20 cm fixed in a vertical

plane. The particle is attached to one end of a spring whose other end is fixed to the top point O of
the ring. Initially the particle is at rest at a point A of the ring such that OCA = 60°, C being the
centre of the ring. The natural length of the spring is also equal to r = 20 cm. After the particle is
released and slides down the ring the contact force between the particle and the ring becomes zero
when it reaches the lowest position B. Determine the force (in N/m) constant of the spring.
4) An old record player of 10 cm radius turns at 10 rad/s while mounted on a 30° incline as shown in
the figure. A particle of mass m can be placed any where on the rotating record. If the least possible
coefficient of friction that must exist for no slipping to occur any where is , find the value of

5) A block of mass 1 kg is released from rest from the top of an inclined plane of inclination 45°. The
coefficient of friction between block and the inclined plane varies with distance x from top position

as where x is meter. Then block will have maximum speed after travelling a distance

6) A block A of mass 4 kg is placed on another block B of mass 5 kg and block B rests on smooth
horizontal table. For sliding the block A and B, a horizontal force 12 N is required to be applied on it.
How much maximum horizontal force can be applied on B so that both A and B move together ?

PART-2 : CHEMISTRY

SECTION - I (i)

1) Which of the following set contains specie that have interaction energy proportional to ? (r →
internuclear distance)
(A)

(B)

(C)

(D) KCl(aq.) + NaCl(aq.)

2) The correct order of bond angle in the above molecule is

(A) y = z > x
(B) z > y > x
(C) y > x > z
(D) x > y > z

3)

Choose the correct IUPAC name of following compound ?

(A) 2,4-diethyl-6-methyl heptane

(B) 3,7-dimethyl-5-ethyl octane
(C) 5-ethyl-3,7-dimethyl octane
(D) 4-ethyl-2,6-dimethyl octane

4) Insulin contains 3.4% sulphur. The minimum mol. wt. of insulin is:

(A) 941.176
(B) 944
(C) 945.27
(D) None

SECTION - I (ii)

1)

Which among the following is CORRECT ?

(A) is linear species because I and C atoms are sp hybridised

(B) Each bond length is identical present in SF2, and
(C) and SOF4 both have atleast one bond angle less than 90°
(D) The number of angles less than 120° present in PH2F3 is 8

2)
What is the correct IUPAC name of the given structure?

(A) Compound I is But – 3 – en – 1 – yne

(B) Compound I is But – 1 – en – 3 – yne
(C) Compound II is 2 – ethyl – 3 – chlorobuta – 1, 3 – diene
(D) Compound II is 2 – chloro – 3 – methylbuta –1,3 – diene

3) A mixture of 100 ml of CO, CO2 and O2 was sparked. When the resulting gaseous mixture
was passed through KOH solution, contraction in volume was found to be 80 ml, the composition of
initial mixture may be (in the same order)

(A) 30 ml, 60 ml, 10 ml

(B) 30 ml, 50 ml, 20 ml
(C) 50 ml, 30 ml, 20 ml
(D) 30 ml, 40 ml, 30 ml

SECTION - I (iii)

Common Content for Question No. 1 to 2

Consider following homogenous aqueous solution (Take π = 3)
1) If content of cube and sphere are mixed then molarity of final H+ in mixture

(A) 1.68
(B) 0.84
(C) 0.42
(D) 0.68

2) If content of sphere and cylinder are mixed then molarity of SO42– in final solution is (ions of BaSO4
are not present in solution because it is a precipitate)

(A) 0.25
(B) 0.5
(C) 2.5
(D) 0.005

Common Content for Question No. 3 to 4

The VSEPR model considers double and triple bonds to have slightly greater repulsive effect
than single bonds because of the repulsive effect of π-electrons. However the lone pair creats the
maximum repulsive effect.

3) Total number of planes where maximum number of atoms lying in one plane in IF5 molecule :

(A) 1
(B) 2
(C) 3
(D) 4

4) Number of molecules 'ion' in which, -orbital is not involved in bonding (with respect to
central atom)?

(A) 3
(B) 4
(C) 5
(D) 6

SECTION - II

1) How many compounds are polar and central atom is sp3d hybridised
(a) PCl3F2 (b) PF3Cl2 (c) XeF2 (d) ClF3
(e) BrF5 (f) S3O9

2) What is ratio of P – O (sigma) and P = O (pi) bonds in H4P2O7 ?

3) D.B.E. of the above compound is :

4) Total number of functional group in the following given compound.

5) 50 ml of ‘20V’ H2O2 is mixed with 200 ml, ‘10 V’ H2O2 . The volume strength of resulting solution is

6) On heating 1.763 g of hydrated barium chloride [BaCl2.x H2O] to dryness, 1.505 g of anhydrous
salt remained. Find the value of x (Mol. wt. of BaCl2 = 208) -

PART-3 : MATHEMATICS

SECTION - I (i)

1) The expression x2 + (2λ + 1)y2 + 2λx – 2y + 4 for real x & y can be resolved as a product of two
real & linear factors for

(A) exactly one integral value of λ

(B) exactly two integral values of λ
(C) exactly three integral values of λ
(D) no integral value of λ
2) If f(x) = x9 – 6x8 – 2x7 + 12x6 + x4 – 7x3 + 6x2 + x – 3, then f(6) is equal to :

(A) 0
(B) 2
(C) 3
(D) –6

3)

If aα2 + bα + c = 3α2 – 4α + 1, aβ2 + bβ + c = 3β2 – 4β + 1 and aγ2 + bγ + c = 3γ2 – 4γ + 1

(where α, β, γ ∈ R and distinct) these sum of root of the equation 3ax2 + 9bx + 7c = 0.

(A) 1
(B) 2
(C) 3
(D) 4

4) and x + y + z = π,
then the value of tan x + tan2y + tan2z
2

(A)

(B) 38
(C) 114

(D)

SECTION - I (ii)

1) If α,β,γ be distrinct real number such that aα2 + bα + c = (cosθ)α2 + (sinθ)α,

aβ2 + bβ + c = (cosθ)β2 + (sinθ)β,
aγ2 + bγ + c = (cosθ)γ2 + (sinθ)γ,
where a,b,c ∈ R. Then

(A) Maximum value of 3a – 4b + 5c is 12.

(B) Maximum value of 3a + 4b + 5c is 5.
(C) Maximum value of 3a – 4b – c is –1.
(D) Minimum value of 3a – 4b – c is –5

2) For real numbers a, b, c and d, if a2 + b2 = 4 and c2 + d2 = 1, then possible value of ac + bd is/are

-

(A) 2
(B) 3
(C) 1
(D)

3) If x2 + y2 = 9 and E = x2 + 2xy – y2, then (x, y ∈ R)

(A) maximum value of E is

(B) minimum value of E is –
(C) x ∈ [–3, 3]
(D) y ∈ [–3, 3]

SECTION - I (iii)

Common Content for Question No. 1 to 2

If ;x∈R& ; where , n ∈ I.

1) The maximum value of P is _________

(A) 15
(B) 16
(C) 17
(D) 18

2) The least positive odd integral value of y is _______.

(A) 5
(B) 4
(C) 3
(D) 8

Common Content for Question No. 3 to 4

If ƒ(x) = |x – 3| + 2|x – 1| and g(x) = –2x2 + 3x – 1.

3) Minimum value of ƒ(x) is -

(A) 0.67
(B) 2
(C) 4
(D) 5

4) Number of solution(s) of the equation ƒ(x) = g(x) is -

(A) 2
(B) 3
(C) 4
(D) 0
 SECTION - II

1)

If the roots of cubic equation x3 – 6x2 + kx – 8 = 0 are positive real numbers, then find the value of
(k – 7).

2) If α, β are roots of the equation x2 – 6x + 4 = 0, then value of is

3) If a + b + c = 8, ab + bc + ca = 12 (where a, b, c ∈ R), then number of possible integral values of

a is

4) If 0 < θ < π, then minimum value of 3 sin θ + cosec3 θ is :-

5) If sin x + sin2x = 1; then

cos8x + 2 cos6x + cos4x =

6) Let and then the value of is :

 ANSWER KEYS

PART-1 : PHYSICS

SECTION - I (i)

Q. 1 2 3 4
A. A D D D

SECTION - I (ii)

Q. 5 6 7
A. A,B,C A,C,D A,B,C

SECTION - I (iii)

Q. 8 9 10 11
A. A B C C

SECTION - II

Q. 12 13 14 15 16 17
A. 1.58 53.00 500.00 6.00 3.00 27.00

PART-2 : CHEMISTRY

SECTION - I (i)

Q. 18 19 20 21
A. A B D A

SECTION - I (ii)

Q. 22 23 24
A. C,D B,D A,B

SECTION - I (iii)

Q. 25 26 27 28
A. B A C C

SECTION - II

Q. 29 30 31 32 33 34
A. 2.00 3.00 12.00 5.00 12.00 2.00

PART-3 : MATHEMATICS
 SECTION - I (i)

Q. 35 36 37 38
A. D C D A

SECTION - I (ii)

Q. 39 40 41
A. B,D A,C,D A,B,C,D

SECTION - I (iii)

Q. 42 43 44 45
A. B C B D

SECTION - II

Q. 46 47 48 49 50 51
A. 5.00 257.00 7.00 4.00 1.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1) If this dx length of water is transferred to the wide container in time dt then

dW =

The water level decrease at constant rate

2)

Ans. (D)
D is the correct answer

3)

Ans. (D)
D is the correct answer

4)

=
5)

Ans. (A,B,C)
(A,B,C) is the correct answer

6)

Explaining the Question :-

Bob is rotating in circle on train which is moving with constant speed.
Concept:- This question is based on
Dynamics of circular motion.
Solution :-

Option (1) is correct

F=

Option (3) is correct

Option (4) is correct

Final Answer :- (1, 3, 4)

7) 10 a = 10 g –T2
2 a = T1 – fK
3a = T2 – T1 – fK
⇒ a = 5.86;
T1 = 17.7 N and T2 = 41.4 N

8)

2mg – kx = f;
and h = 2x

4mg = kx + 2fK
2mg – (4mg – 2fx) = f
2fx – 2mg = f
2(µ 2mg) – 2mg = f
4µmg – 2mg = f
(1.2) mg = f
12 = f

9)

Ans. (B)
(B) is the correct answer.

10) Ans. (C)

(C) is the correct answer.

11) In the time interval t = 0 sec to t = t0 sec, till the time. The relative velocity is not zero the
nature of friction will be kinetic.

12)

Maximum speed is at equilibrium let displacement of block is x in equilibrium

4kx = mg

x=
Apply W.E.T.
13)

14)

Explanation Question: We are given that a particle can move or slide on a smooth ring
Initially particle is released from point 'A' as shown . we have to find the force constant of the
spring and it is given that the contact force becomes zero at point 'B'
Concept: Vertical circular motion
Solution:

Initial length of spring = r (relaxed)

kr – mg = …(i)
COE at A and B

mgr (1 + cos 60°) –

⇒ mv2 = 3 mgr
From equation (i)
 kr – mg = 3mg
kr = 4 mg

k=
∴ final answer = 500

15)

Ans. (6.00)
(6.00) is the correct answer

16) Speed is maximum when a = 0

i.e.g (sin θ - μ cos θ) = 0
tan θ = μ

x = 3m

17)

Ans. (27.00)
(27.00) is the correct answer

PART-2 : CHEMISTRY

18)

Ans. (A)
A is the correct answer

19)

Ans. (B)
B is the correct answer

20) Explain question : The question asks for the correct IUPAC name of the given structure?
Concept : This question is based on IUPAC nomenclature (selection and numering of PCC)
Solution :

PCC ⇒ 6C with single bond ⇒ Octane.

Thre substituent are present ⇒ 2-Methyl, 6-Methyl, 4-Ethyl, written in alphabetical order.
The IUPAC name is 4-Ethyl-2, 6-dimethylcoctane
Final answer : option 4

21)

Ans. (A)
A is the correct answer

22)

Ans. (C,D)
(C,D) is the correct answer

23) Question Explanation:

To write IUPAC name of the given compounds.

Concept:
This question is based on nomenclature of alkenes and alkynes and their halogen derivatives.

Solution:

Final Answer:
The correct options are (2 & 4).

24) Let the volume of CO, CO2 and O2 are a, b and c respectively

a (100 – a – b)
If CO is L.R. then

After passing KOH

Vcont. = 80 ml = a + b ....(i)
a + b + c = 100 ....(ii)
On solving (i) & (ii)
C = 20 ml
If a 30 ml and b = 50 ml then CO will L.R.
If O2 is L.R. then

a (100–a–b)
a–2 (100 –a–b) 0 2(100–a–b)
 80 = 200 – 2a – 2b + b
2a + b = 120 ....(iii)
from options a = 30 ml, b = 60 ml,
(A) & (B)

25)

Ans. (B)
B is the correct answer

26)

Ans. (A)
A is the correct answer

27)

Ans. (C)
C is the correct answer

28)

Ans. (C)
C is the correct answer

29)

Ans. (2.00)
(2.00) is the correct answer

30)

Ans. (3.00)
(3.00) is the correct answer

31)

Ans. (12.00)
(12.00) is the correct answer

32)

Ans. (5.00)
(5.00) is the correct answer
 33)

Final molarity

Volume strength

34)

Ans. (2.00)
(2.00) is the correct answer

PART-3 : MATHEMATICS

35)

⇒ 4(2λ + 1) – 1 – λ2(2λ + 1) = 0
...(1)
If λ ∈ I
(1) has no solution.

36) f(6) = 69 – 6.68 – 2.67 + 12.66 + 64 – 7.63 + 6.62

= (69 – 69 – 2.67 + 2.67) + 64 – 64 – 63 + 63 + 6 – 3)
=3

37)

a = 3, b = –4, c = 1

38) tanx + tany + tanz = tanx tany tanz

2k + 3k + 5k = 2k.3k.5k

tan2x + tan2y + tan2z = 38k2 = \(\frac{{38}}{3}\)

39) a = cosθ; b = sinθ & c = 0 Now verify options

40) a = 2cosθ, b = 2 sinθ
and c = cosϕ, d = sinϕ
ac + bd = 2cos(θ – ϕ)

41) x2 + y2 = 9
x = 3cosθ, y = 3sinθ \(x,y \in [ - 3,3]\)
2 2
E = x + 2xy – y
E = 9 cos2θ + 18 cosθ sinθ – 9 sin2θ
E = 9 cos2θ + 9 sin2θ
Emax =
Emin =

42)

43)

44)
ƒ(x) =|x – 3|+ 2|x – 1|

ƒ(x)|min = 2

45) g(x) = –2x2 + 3x – 1

ƒ(x) & g(x) do not intersect at any point
∴ Equation ƒ(x) = g(x) does not have any solution.

46)

47) α2 – 6α + 4 = 0 ⇒ (α – 2)2 = 2α

& β2 – 6β + 4 = 0 ⇒ (β – 6) =

Now

48) a + b + c = 8
ab + bc + ca = 12
c = 8 – (a + b)
ab + b(8 – (a + b)) + a(8 – (a + b)) = 12
ab + 8b – ab – b2 + 8a – a2 – ab – 12 = 0
b2 + b(a – 8)+ a2 – 8a + 12 = 0
D≥0
(a – 8)2 – 4(a2 – 8a + 12) ≥ 0
a2 – 16a + 64 – 4a2 + 32a – 48 ≥ 0
3a2 – 16a – 16 ≤ 0
number of integral values of a is 0, 1, 2, 3, 4, 5, 6

49) Using A.M. ≥ G.M.

Hence, minimum value of 3 sinθ + cosec3θ is 4.

50) sinx = 1 – sin2x ⇒ sin2x = cos4x

⇒ 1 – cos2x = cos4x ⇒ cos4x + cos2x = 1
squaring both sides; cos8x + cos4x + 2cos6x = 1

51) f(θ) = 1 + tanθ, g(θ) = 1 – cotθ so if A + B = then f(A) . f(B) = (1 + tanA) (1+tanB) = 2
and g(A) . g(B) = (1 – cotA) (1–cotB) = 2