23-09-2025
2401CJA101001250036 JA
CHEMISTRY
SECTION - I (i)
1) 25 molal an aqueous solution of nonvolatile solute is partially dried
and it is found that 50% by mass of initial water has been removed. % by mass of H2O present in
partially dried solution is :
(A) 33.4
(B) 60
(C) 40
(D) 66.6
2) 1 mole of H2C2O4 is oxidised by X mole of in strong basic medium and 1 mole of NaHC2O4 is
oxidised by y mole of in acidic medium. Ratio of x/y is-
(A) 2 : 1
(B) 5 : 1
(C) 3 : 1
(D) 1 : 3
3) A mixture of oxalic acid (H2C2O4) and NaHC2O4 weighing 2.02 gm was dissolved in water and the
solution was made upto one litre. 10 ml of this solution required 3 ml of 0.1 N NaOH solution for
complete neutralisation. In another experiment, 10 mlof the same solution in hot dilute
H2SO4 medium required 4 ml of 0.1 N KMnO4 solution for complete reaction. Calculate the amount of
H2C2O4 and NaHC2O4 in the mixture :-
(A) 0.9 gm & 1.12 gm
(B) 0.8 gm & 1.22 gm
(C) 1.0 gm & 1.02 gm
(D) 1.1 gm & 0.92 gm
4) Which of the following configuration shows highest ionisation enthalpy?
(A) 2s2, 2p4
(B) 3s2, 3p4
(C) 1s2
(D) 2s2, 2p3
SECTION - I (ii)
1) Which of the following property(ies) of nitrophenol decreases due to intra-molecular H-bonding in
ortho isomer as compared to para isomer.
(A) Boiling Temperature
(B) Volatility
(C) Viscosity
(D) Density
2) A group of students attempted to estimate the concentration of a solution of Fe2+ by pipetting
fixed volumes of the solution into a flask, adding an excess of dilute sulphuric acid, and then titrating
with a standard solution of potassium per manganate (VII) from a burette. The volume of
KMnO4 solution required by one student was 0.2 cm3 higher than that of the other students. Which of
the following are possible explanations for this discrepancy ?
(A) the titration flask was rinsed with the solution of Fe2+ instead of water before titration.
(B) the last drop of Fe2+ solution was blown from the pipette into the flask.
(C) the burette was rinsed with water instead of the solution KMnO4 before titration.
one student rinsed the burette with the solution of Fe2+ and other rinsed with solution of KMnO4
(D)
before titration.
3) In all compounds of IUPAC name P1 - bromo-3-chloro-P3-methyl pent-P4-yne which can be correct
(Pi represent position of side chain & multiple bond according to IUPAC).
(A)
(B)
(C)
(D)
SECTION - I (iii)
Common Content for Question No. 1 to 2
1292.5 gm of aquesous solution of '5m' NaCl is kept in a large bucket. The bucket in placed under a
tap from which a '2m' aqueous solution of NaCl is flowing. Rate of flow of solution from tap is 0.5
gm/sec.
1) The total amount of solution (in gm) finally present in bucket when solution present in bucket
have concentration of NaCl 4m.
(A) 1851.00
(B) 1751.00
(C) 1651.00
(D) 1951.00
2) The time (in seconds) after which the bucket will have '4m' concentration of NaCl.
(A) 1117.00
(B) 1017.00
(C) 1217.00
(D) 1377.00
Common Content for Question No. 3 to 4
Hybridization of
Molecule Properties related to structure
central atom(s)
(P) (HBNH)3 (I) sp2 (i) Cyclic structure
(Q) C3O2 (II) sp3 (ii) linkage
(X = central atom)
(R) (III) sp3d (iii) Planar
(S) N2O4 (IV) sp (iv) Has (X - X) linkage
3) Identify CORRECT match
(A) P, II, iii
(B) P, I, i
(C) P, IV, iii
(D) Q, I, i
4) Identify CORRECT match
(A) Q, IV, iii
(B) Q, IV, i
(C) Q, I, ii
(D) R, I, ii
SECTION - II
1) Find the number of B - O - B linkage(s) in Borax (Na2B4O7.10H2O) :
2) The total number of lone pairs in melamine is................
3) Number of functional groups present in the following compounds is :
4) 1 litre solution containing 0.1 M Na2S2O3 & 0.2 M is titrated with I2 according to following
reaction.
Na2S2O3 + I2 → Na2S4O6 + I-
Calculate moles of I2 consumed ?
5) Iodine (I2) adds to the double bonds in fatty acids (one iodine molecule per double bond). How
many double bonds are in a molecule of arachidonic acid (Molar mass = 304.5 g/mol) if 0.125 g of
the acid require 0.417 g of iodine ? [Mol. mass: I = 127
6) An M2+ ion have total four electron(s) withn = 3, ℓ = 2, ms = +1/2 in its ground state and No
electron in n = 3, ℓ = 2, m = 0 orbital. Find unpaired electron(s) in M+2 ion.
ANSWER KEYS
CHEMISTRY
SECTION - I (i)
Q. 1 2 3 4
A. B B A C
SECTION - I (ii)
Q. 5 6 7
A. A,C,D A,B,C,D A,C
SECTION - I (iii)
Q. 8 9 10 11
A. A A B A
SECTION - II
Q. 12 13 14 15 16 17
A. 5.00 6.00 6.00 0.09 4.00 4.00
SOLUTIONS
CHEMISTRY
1) 1000 gm H2O → 25 ml solutue
mass of H2O present after partially dried solution = 500 gm
=> total mass of solution
% by mass of final H2O
60 %
2) H2C2O4 1 × 2 = X. 1
NaHC2O4 1 × 2 = Y. 5
3)
Let
Now, equivalent of equivalent of NaOH
M × nf × V = N × V
2.02 - x = 1.12 g
4)
(A) O (B) S (C) He (D) N
IE : He> N> O> S
5)
Intramolecular H-bond
6) For exact determination; in titration apparatus has to be rinsed with distilled water so as to
remove any contamination. If rinsing was done with Fe+2 or KMnO4. This will produce different
results of volume required.
In case of Burette: It has to be rinsed with KMnO4 solution before starting : otherwise
concentration of KMnO4 will change, if rinsed with water.
Correct Ans. → A, B, C & D
{If last drop of Fe+2 solution was blown from the pipette into the flask the required amount of
KMnO4 also increases. Hence required volume of KMnO4 also increases}
7)
(A) (C)
8) 5m NaCl: let x : moles of solute(ie NaCl)
so mass of solvent = 1
Kg and solute: 292.5 gm (in original solution)
now let 'y' kg of '2m' NaCl solution is added, moles of solute = 2y
conserving moles of solute in mixing
5 + 2y = (y + 1)4 ; y = 0.5
so, Total solution = 1292.5 + 500 + 58.5 + 1851 gm
9) Amount of '2m' NaCl solution added = 500 + 58.5 = 558.5 gm
time taken = sec
10)
11)
O=C=C=C=O
12)
13)
Melamine : C3H6N3
14)
Functional groups are : Aldehyde, primary amine, ketone, acid anhydride, Acid amide,
carboxylic acid
15)
equivalent of Na2S2O3 = equivalents of I2
M × nf × v = n × nf
0.1 × 1 × 1 = n × 2 ➩ n = 0.05
equivalent Of IO4- = equivalent of I2
M × nf × v = n × 10 ➩ n = 0.04
Total = 0.05 + 0.04
= 0.09
16) nacid × number of double bonds = nI2
or, × number of double bonds =
No. of double bonds = 4
17)
4e- in 3d-subshell :