?

78 , P281 $afety Data $heet

lssue date: 81301202? Version: 1.1

Product form Substance

Trade name P 70 & P281
Product code MODIFIED POLYETHYLENE

Adhesives, binding agents

Recommended use Adhesives, sealants, Manufacture of plastics products, including compounding and conversion,
Other

Manufacturer Manufacturer
A,ddress: Nanjing Tianshi New [4aterial Technology Co., Ltd.
Tianshi Wax
No.29, Caolang Roacl, Lr:he Deveiopmeirl Zone, Nanjirrg. China
Tel.: +86-25-58393220
Fax: +86-25-58393878

Emergency number +8613585'l 59792

eil* riassi{icati{rr
Not classified

No Iabeling applicable

which do not result in dust explosion hazard.

information available
 Polymer
Name Modified Polyethylene
CAS-No. Mixture

Name Product identifiei urr:) ub ctSssillcaltall

MODIFIED POLYETHYLENE/ COPOLYMER CAS-No.: MIXED 91-92 Not classified
(Main constituent)

Carboxylic acid monomer CAS-No.:Trade 8-9 Not classified

Secret
"Chemical name, CAS number and/or exact concentration have been withheld as a trade secret
Full text of hazard classes and H-statements : see section 16

As above

First-aid measures general lf you feel seek medical advice.

First-aid measures after inhalation Remove person to hesh air and keep comfortable for breathing.
First-aid measures after skin contact Wash skin with plenty of water.
First-aid measures after eye contact Rinse eyes with water as a precaution.
First-aid measures after ingestion Call a poison center/doctor/physician if you feel unwell.

Effects on Aside under Description measures and lndication

of immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology lnformation.
Symptoms/effects after inhalation Dust of the product, if present, may cause respiratory initation after an excessive inhalation
exposure. lnhalation may cause irritation (cough, short breathing, difficulty in breathing).
Symptoms/effects aft er skin contact Dust may cause irritation in skin folds or by contact in combination with tight clothing.
Symptoms/effects after eye contact Dust from this product may cause eye irritation.
Symptoms/effects after ingestion May cause irritation to the digestive tract.

Suitable extinguishing Water spray. Dry powder. Foam.

Explosion hazard Warning. May form explosive re if small particles are generated during
processing, handling, or by other means.
Hazardous decomposition products in case offire Toxic fumes may be released. Carbon oxides (CO, CO2).
Precautionary measures fire Minimize generation of dust which may be combustible. Keep cool. Protect from sunlight.
Firefighting instructions Fight fire with normal precautions from a reasonable distance. Do not enter fire area without
proper protective equipment, including respiratory protection.
Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

General measures Stop leak if safe to do so.

*.1.1. f a{ non-en}ergency personnsl

Protective equipment Wear recommended personal protective equipment. ISO 16321-1. EN 407
Emergency procedures Ventilate spillage area.
l\4easures in case of dust release Avoid contact with skin and eyes.

i\.t .?.7*r em*.geilcy lespolrderc

Protective equipment Do not attempt to take action without suitable protective equipment. For further information refer
lo section 8: "Exposure controls/personal protection".
Emergency procedures Stop leak if safe to do so. Evacuate unnecessary personnet. Keep away from combustible
material.

Avoid release to the environment,

For containment Collect spillage.

Methods for cleaning up Mechanically recover the product.
Other information Dispose of materials or solld residues at an authorized site.

For fu rther information to section 13.

Additional hazards when processed may ble and explosive mixture with air. Provide adequate ventilation to
minimize dust and/or vapor concentrations.
Precautions for safe handling Ensure good ventilation of the work station. Do not get in eyes, on skin, or on clothing" Wear
personal protective equipment.
Hygiene measures Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.

Technical measures with applicable regulations. Keep in a cool, well-ventilated place away
locked up. Store in tightly closed, leak-proof contalners.
Storage conditions Store in a well-ventllated place. Keep cool.
lncompatible materials Direct sunlight.
Storage temperature C-JC U
Packaging materials Store always product in container of same material as original container.
 USA . ACGIH - Occupational Exposure Limits
Local name DUST, Not specified

ACGIH OEL TWA '10 mg/m3

Remark (ACGIH) When use in grinding, cutting and processes not limited to specified here which generates
general dust, this applies.

No additional lnformation available

No additional information available

Appropriate engineering controls Ensure good ventilation of the work station.

Environmental exposure controls Avoid release to the environment.

Personal protective equipment:

Wear recommended personal protective equipment. ln case of insufficient ventilation, wear suitable respiratory equipment.

Hand protection:

Protective gloves

Eye protection:

Safety glasses

Type Field of application Characteristics

Safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection
ln case of insufflcient ventilation, wear suitable respiratory equipment

Device Filter type Condition

Dust mask Particle filter, Type P2 Dust protection

Personal protective iquipment symbol(s):

@@,@
Other information:
Do not eat, drink or smoke when using this product.
Physical state Solid
Appearance Pellet.
Color Colorless
Odor Slightly acidic
Odor threshold No data available
pH No data available
iVelting point No data available
Freezing point Not applicable
Boiling point No data available
Flash point Not applicable
Relative evaporation rate (butyl acetate=1) Not applicable
Relative evaporation rate (ether=1 ) Not applicable
Flammability (solid, gas) Non flammable.
Vapor pressure No data available
Relative vapor density at 20'C 3.5 Source: Calculated value based on molecular weight and mean molecular weight of air
Relative density 0.91 - 0.97
Density Not applicable
[,4olecular mass 100.116 g/mol Source: ChemlDplus
Solubility No data available
Partition coeff icient n-octanol/water (Log Pow) No data available
Auto-ignition temperature Not applicable
Decomposition temperature No data available
Viscosity, kinematic Not applicable
Viscosity, dynamic No data available
Explosion limits Not applicable
Explosive properties No data available
Oxidizing properties No data available

available

No additional information available

Stable under normal conditions of use.

Not established

Direct sunlight. Extremely high or low temperatures

agent.

Thermal generates
Acute toxicity (oral) Not classified (Based on available data, the class criteria are not met)
Acute toxicity (dermal) Not classified (Based on available data, the classification criteria are not met)
Acute toxicity (inhalation) Not classified (Based on available data, the classification criteria are not met. Lack of data)

LD50 oral rat > 5000 mg/kg

LD50 dermal rabbit > 2000 mg/kg

LD50 oral rat > 5000 mg/kg Source: lnternational Uniform ChemicaL lnformation Database

Skin corrosion/irritation Not classified (Based on available data, the classification criteria are not met. Lack of data)
Serious eye damage/irritation Not classified (Based on available data, the classification criteria are not met. Lack of data)
Respiratory or skin sensitization Not classifled (Based on available data, the classification criteria are not met. Lack of data)
Germ cell mutagenicity Not classified (Based on available data, the classification criteria are not met. Lack of data)
Carcinogenicity Not classified (Based on available data, the classification criteria are not met. Lack of data)
Reproductive toxicity Not classified (Based on available data, the classification criteria are not met. Lack of data)
STOT-single exposure Not classified (Based on available data, the classification criteria are not met. Lack of data)
STOT-repeated exposure Not classified (Based on available data, the classification criteria are not met. Lack of data)
Aspiration hazard Not classified
(Based on available data, the classification criteria are not met. Lack of data)
Viscosity, kinematic Not applicable

Viscosity, kinematic Not applicable

Effects on humans Aside from the information found under Description of first aid measures (above) and lndication
of immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology lnformation.
Symptoms/effects after inhalation Dust of the product, if present, may cause respiratory irritatlon after an excessive inhalation
exposure. lnhalation may cause irritation (cough, short breathing, difficulty in breathing).
Symptoms/effects after skin contact Dust may cause irritation in skin folds or by contact in combination with tight clothing.
Symptoms/effects after eye contact Dust from this product may cause eye irritation.
Symptoms/effects aft er ingestion May cause irritation to the digestive tract.

Ecology - general The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.

LC50 - Fish [1] > 10000 mg/l Source: IUCLID

Persistence and degradability Not established.

Not rapidly degradable

 Not rapidly degradable

Bioaccumulative potential The product is not biodegradable.

Partition coefficient n-octanol/water (Log Pow) 5.18 Source: Quantitative Structure Activity Relation

Mobility in soil Material is expected to remain in the soil and to float in aquatic environment

Other information No other effects known

Regional legislation (waste) Disposal must be done according to official regulations.

Waste treatment methods Dispose of contents/container in accordance with licensed collector's sorting instructions.
Sewage disposal recommendations Disposal must be done according to official regulatlons.
Additional information Industrial waste. Do not re-use empty containers.
Ecology - waste materials Avoid release to the environment.

ln accordance with DOT / TDG / IMDG / lAT,

1,{.1. il$ nurnhsr

Not regulated for transport

'lr4.L Pr*;:rer $hippir:g Name

Not applicable Not applicable Not applicable Not applicable

1 ;i."t. Tr;l**p*lt hazard elass{es}

Not applicable Not applicable Not applicable Not applicable
.?4.4.
Far;ki*g group
Not applicable Not applicable Not applicable Not applicable
'l
4"5- [l:l ir*r:*:*nti]l hazards
Not applicable Not applicable Not applicable Not applicable

No supplementary information available

DO,T
No data available

tuu
No data available

IMDG
No data available

IATA
No data available

Not applicable

All components of this product are present and listed as Active on the United States Environmental Protection Agency Toxic Substances Control Act
(TSCA) inventory, except for:

Carboxylic Acid monomer CAS-No. secret 8-9

CANADA

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations
No additional informalion available

National regulations

Listed introduction on Australian lndustrial Chemicals lntroduction Scheme (AlClS lnventory)

Listed on IECSC (lnventory of Existing Chemical Substances Produced or lmported in China)
Listed on KECL/KECI (Korean Existing Chemicals lnventory)
Listed on NZIoC (New Zealand lnventory of Chemicals)
Listed on PICCS (Philippines lnventory of Chemicals and Chemical Substances)
Listed on TECI (Thailand Existing Chemicals lnventory)
Listed on the Japanese ENCS (Existing New Chemical Substances) inventory
Listed on the NCI (Vietnam - National Chemical lnventory)
Listed on the TCSI (Taiwan Chemical Substance lnventory)

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm
 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 1D412023
Data sources : REGULATToN (Ec) No 1z72tzoo} oF THE EURoPEAN PARLTAMENT AND oF THE
couNClL of '16 December 2008 on classiflcation, labeling and packaging of substances and
mixtures, amending and repealing Directives 6Tls{gt!-Ec and 1999/45/EC, and amending
Regulation (Ec) No 190712006. This MSDS is prepared based on KosHA, NtrE, ESts, NLM,
slDS, IPCS, NCls, etc. This MSDS is prepared based on Article 41 of the occupational safety
and Health Act and Notice No.2016-19 of the Ministry of Employment and Labor (based on the
availability of material safety and health data), taking into account the status of regulations
related to Korea. This safety data sheet was compiled with data and information from the
following sources : RTECS, ECOSAR, HSDB, SIDS StAp, ChemWATCH, CESAR, Chemicat
DB.
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