Test ID : 836

E- mail : gpccnamakkal@[Link] Website : [Link]

.FIRST YEAR FULL TEST I

Std : Long Term (Batch – A) Marks : 600
Date : 15.03.2024 CHEMISTRY Time : 3 Hrs.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark will be
reduced. For unanswered questions zero mark.
Choose the correct answer: 150 x 4 = 600
1. How much energy is required to ionize one 1) 8 2) 10
mole of H-atoms in eV? 3) 11 4) 13
21 24
1) 9.26 x 10 2) 8.189 x 10 5. What are the average oxidation states of
24 20 carbon atoms in given compounds?
3) 7.16 x 10 4) 5.26 x 10
2. For the hypothetical reactions, the equilibrium i) C6Cl6 ii) C2H4 iii) C2H2
constant (K) values are given as 1) +1, –2, –1 2) –1, +2, +1
A ⇌ B ; K1 = 2 3) +3, +2, +1 4) +1, +2, +3
6. How many of the following are intensive
B ⇌ C ; K2 = 4 properties?
C ⇌ D ; K3 = 3 i) pressure ii) temperature
iii) density iv) surface tension
Then equilibrium constant (K) for the reaction
v) viscosity vi) melting point
A ⇌ D is
vii) heat capacity viii) entropy
1) 48 2) 6 1) 4 2) 5
3) 27 4) 24 3) 6 4) 8
3. What is the pH of aqueous solution of 7. The enthalpy of reaction N2(g) + 3H2(g) →
NH4CN? 2NH3(g) is –92.38 kJ at 298K. What is enthalpy
1 of formation (∆fH) of ammonia
1) pH = (pKw + pKa + log C)
2 1) –92.38 kJ 2) –46.19 kJ
1 3) –23.095 kJ 4) –80 kJ
2) pH = (pKw – pKa – pKb) o
2 8. At 0 C, ice and water are in equilibrium and
1 ∆(fus)H = 6.00 kJ/mole for the process
3) pH = (pKw + pKb + log C)
2 H2O(s) ⇌ H2O(l)
1 Calculate ∆S for conversion of ice to water
4) pH = (pKw + pKa – pKb)
2 1) 2 J mole–1 K–1
4. What is the n-factor of reactant in given
2) 21.98 J mole–1 K–1
equation
+3 3) 11.9 J mole–1 K–1
FeS2 → Fe + SO2
4) 5.6 J mole–1 K–1
 2 Test ID : 836 [Type - I]
9. Which of the following is incorrect? 1) Both Statement-I and II are true
1) ∆Soreaction = ΣSo(Pr oducts ) − ΣSo(Reactants) 2) Both Statement-I and II are false
3) Statement-I is true and Statement-II is false
2) ∆ H reaction = Σ∆ H comb( Reactants) − Σ∆H comb (Pr oducts)
4) Statement-I is false and Statement-II is true
V2 15. Aluminium chloride exist as dimer, Al2Cl6 in
3) WIsothermal = −nRT ln
reversible V1 solid state as well as in solution of non polar
expansion
solvents such as benzene. When dissolved in
4) In adiabatic process, ∆E = q water, it gives
10. Consider PCl5(g) ⇌ PCl3(g) + Cl2(g) reaction is 1) Al
at equilibrium. If volume of reaction medium 2) [Al(H2O)6]3+ + 3Cl–
increases then 3) [Al(OH)6]3– + 3HCl
4) Al2O3 + 6HCl
1) Kc value decreases
16. Statement – I : In C60, the unbounded
2) ‘α’ of PCl5 decreases
electron at each carbon is delocalized in
3) Kp value increases molecular orbtials, which in turn give aromatic
4) Qc < Kc character to molecule.
11. The formula of a binary compound can be Statement – II : Fullerenes are most pure
formed by the element X of atomic number allotropic forms due to absence of dangling
120 and sulphur is bonds.
1) Both Statement-I and II are true
1) XS 2) X2S
2) Both Statement-I and II are false
3) XS2 4) X3S
3) Statement-I is true and Statement-II is false
12. Which of the following is incorrect statement?
4) Statement-I is false and Statement-II is true
1) There are four d-block series
17. Orthoboric acid behaves as weak monobasic
2) Total d-block elements are 40 acid giving H3O+ and
3) Last d-block series start with element 1) [B(OH)4]+ 2) H 2 BO +2
actinium
3) [B(OH)4]– 4) H 2 BO −2
4) All members of d-block series are stable
18. Match the following
elements and found in nature
Column – I Column – II
13. In sixth period the orbitals are filled as (Element) (Density in gcm–3)
1) 6s, 5f, 6d, 6p 2) 6s, 4f, 5d, 6p A) Ga i) 11.85
3) 5s, 5p, 5d, 6p 4) 6s, 6p, 6d, 6f B) In ii) 5.90
14. Statement – I : Covalent radius is half of the C) Al iii) 2.70
internuclear distance between two atoms when D) B iv) 7.31
they are bound together by a single bond in a E) Tl v) 2.35
covalent molecule. 1) A-ii, B-iv, C-iii, D-v, E-i
Statement – II : Atomic radius of noble gases 2) A-iii, B-v, C-i, D-iv, E-ii
are larger than those halogens because of their 3) A-ii, B-v, C-iv, D-i, E-iii
Vander Waal’s radius. 4) A-i, B-iv, C-iii, D-ii, E-v
 3 Test ID : 836 [Type - I]
19. Boron does not form B +3
(aq) ion easily. It is due 25. Assertion (A) : The charge to mass ratio of
the particles in anode rays depends on the
to
nature of the gas taken in discharge tube.
1) Sum of the first three ionization enthalpies
Reason (R) : The particles in anode rays carry
of boron is very high
positive charge.
2) Boron is non-metal
1) Both (A) and (R) are true and the (R) is a
3) Boron is semi metal correct explanation of the (A)
4) Boron has high electron gain enthalpy 2) Both (A) and (R) are true but (R) is not a
20. Which of the following is incorrect one? correct explanation of the (A)
1) Ionization energy – Li < Be < B 3) (A) is true but the (R) is false
2) Electron affinity – C < N < O 4) Both (A) and (R) are false
3) Atomic size –Mg > Na > Li 26. Statement – I : The radius of second Bohr
4) All of the above orbit of He+ is equal to that of first orbit of
21. Which of the following is wrong triad hydrogen.
according to Doberiner? Statement – II : The radius of an orbit in
1) Li, Na, K 2) Cl, Br, I hydrogen like species is directly proportional
3) C, N, O 4) Ca, Sr, Ba to ‘n2’ and inversely proportional to ‘Z’
22. Diagonal relationship is disappears after 1) Both Statement-I and II are true
1) 2nd group 2) 15th group 2) Both Statement-I and II are false
3) 14th group 4) Noble gases 3) Statement-I is true and Statement-II is false
23. Match the following 4) Statement-I is false and Statement-II is true
Column – I Column – II 27. Particle ‘A’ moving with a certain velocity has
(General electronic (Elements the de-Broglie wavelength of 1 Ao. Calculate
Configuration of which it belongs) de-Broglie wavelength of particle ‘B’ with
block elements) mass 25% of ‘A’ and velocity 75% of ‘A’.
a) ns1–2 i) C 1) 3 Ao 2) 5.33 Ao
2 1–6
b) ns np ii) Na 3) 6.88 Ao 4) 0.48 Ao
c) (n-1)d1–10ns1–2 iii) Nd 28. Consider the following statements
d) (n-2)f1–14 (n-1)d0–1 ns2 iv) Ti
I) Electron density is zero for 3d x 2 − y2 in xy
1) a-ii, b-i, c-iv, d-iii
plane
2) a-i, b-ii, c-iv, d-iii
II) Electron density is zero for 3d z 2 in xy plane
3) a-i, b-ii, c-iii, d-iv
4) a-iii, b-ii, c-iv, d-i III) 2s orbital has only one spherical node
24. What are the values of n, l, m and s for 11th IV) for 2pz orbital yz is the nodal plane
electron of sodium respectively? The correct statements are
1 1) only III 2) I, II, III, IV
1) 3, 0, 1, − 2) 3, 0, 0, 1
2 3) only II 4) I & III only
1 1
3) 3, 1, 1, − 4) 3, 0, 0, +
2 2
 4 Test ID : 836 [Type - I]
29. Assertion (A) : The decomposition of 34. Match the following
hydrogen peroxide to form water and oxygen Column – I Column – II
is an example of disproportionation reaction. (Underline atom) (It’s oxidation state)
Reason (R) : In H2O2 decomposition, oxygen A) Xe[PtF6] p) +3
undergoes both oxidation and reduction. B) [Fe(H2O)5NO]SO4 q) +6
1) Both (A) and (R) are true and the (R) is a C) CrO2Cl2 r) +1
correct explanation of the (A) D) Fe4[Fe(CN)6]3 s) +5
2) Both (A) and (R) are true but (R) is not a 1) A-p, B-q, C-r, D-s
correct explanation of the (A) 2) A-s, B-r, C-q, D-p
3) (A) is true but the (R) is false 3) A-s, B-r, C-p, D-q
4) (A) is false but (R) is true 4) A-p, B-q, C-s, D-r
35. In the reaction
30. Find the average oxidation state of carbon in
2FeCl3 + H2S → 2FeCl2 + 2HCl + S, choose
the following compound CH3CH 2 OH
the correct statement is
1) 0 2) +2 1) FeCl3 acts as an oxidizing agent
3) –2 4) –1 2) Both H2S and FeCl3 are oxidized
31. What products are expected from the 3) FeCl3 is oxidized and H2S is reduced
disproportionation reaction of hypochlorous 4) H2S acts as an oxidizing agent
acid? 36. Which of the following is a redox reaction?
1) HClO3and Cl2O 1) NaCl + KNO3 → NaNO3 + KCl
2) HClO2 and HClO4 2) CaC2O4 + 2HCl → CaCl2 + H2C2O4
3) Cl2O7 and Cl2O 3) Ca(OH)2 + 2NH4Cl → CaCl2 + 2NH3 + 2H2O
4) HCl and HClO3 4) 2K[Ag(CN)2] + Zn → 2Ag + K2[Zn(CN)4]
32. Statement – I : The hybrid orbitals are less 37. In the reaction
effective in forming stable bonds than the pure 8Al + 3Fe3O4 → 4Al2O3 + 9Fe, total number
atomic orbitals. of electrons transferred from the reductant to
Statement – II : According to MOT, atomic the oxidant is
orbitals having same or nearly the same 1) 8 2) 4
energy will not combine, if they do not have 3) 16 4) 24
the proper symmetry. 38. Ionization enthalpy (I.E1) for the elements of
group 13 follows the order
1) Both Statement-I and II are true
1) B > Al > Ga > In > Tl
2) Both Statement-I and II are false
2) B < Al < Ga < In < Tl
3) Statement-I is true and Statement-II is false
3) B < Al > Ga < In > Tl
4) Statement-I is false and Statement-II is true
4) B > Al < Ga > In < Tl
33. Which of the following acts as an oxidizing as
39. Which of the following does not exist in free
well as reducing agent? form?
1) Na2O 2) Na2S 1) BF3 2) BCl3
3) NaNO3 4) NaNO2 3) BBr3 4) BH3
 5 Test ID : 836 [Type - I]
40. Which one of the following is correct 1) Both (A) and (R) are true and the (R) is a
statement? correct explanation of the (A)
1) The hydroxide of aluminium is more acidic 2) Both (A) and (R) are true but (R) is not a
than that of boron correct explanation of the (A)
2) The hydroxide of boron is basic, while that 3) (A) is true but the (R) is false
of aluminium is amphoteric 4) (A) is false but (R) is true
3) The hydroxide of boron is acidic, while that 44. Assertion (A) : The gaseous reaction 2A + B
of aluminium is amphoteric
⇌ 2C + 100 kJ is favoured in the forward
4) The hydroxide of boron and aluminium are
amphoteric direction with increase of pressure.
Reason (R) : The above forward reaction is an
41. Assertion (A) : Si-Si bonds are weaker than
Si–O bonds. exothermic.
Reason (R) : Silicon electronegativity is 1) Both (A) and (R) are true and the (R) is a
greater than that of oxygen. correct explanation of the (A)
1) Both (A) and (R) are true and the (R) is a 2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A) correct explanation of the (A)
2) Both (A) and (R) are true but (R) is not a 3) (A) is true but the (R) is false
correct explanation of the (A) 4) (A) is false but (R) is true
3) (A) is true but the (R) is false 45. A sample of HI(g) is placed in a flask at
4) (A) is false but (R) is true pressure of 0.2atm. At equilibrium, the partial
42. Assertion (A) : Ionization energy (I.E1) of pressure of HI(g) is 0.04atm. What is Kp for the
nitrogen (Z = 7) is more than that of oxygen given equilibrium, 2HI(g) ⇌ H2(g) + I2(g)
(Z = 8).
1) 3 2) 4
Reason (R) : Half filled p-orbitals in nitrogen
is more stable than partially filled p-orbitals in 3) 6 4) 8
oxygen. 46. Which of the following species acts as both
1) Both (A) and (R) are true and the (R) is a bronsted acid and base?
correct explanation of the (A) 1) H 2 PO −2 2) HPO 3−2
2) Both (A) and (R) are true but (R) is not a 3) HPO −4 2 4) All of these
correct explanation of the (A)
47. The solubility product of a salt having general
3) (A) is true but the (R) is false
formula MX2 in water is 4 x 10–12, then
4) (A) is false but (R) is true
concentration of M+2 ions in the aqueous
43. Assertion (A) : Buffer solution of carbonic solution of the salt is
acid and sodium bicarbonate is used for the
1) 4 x 10–10 M 2) 1.6 x 10–4 M
precipitation of hydroxides of third group
3) 1.0 x 10–4 M 4) 2.0 x 10–6 M
basic radicals.
Reason (R) : Buffer solution of carbonic acid 48. 10g of a gas occupies 5.6L volume at STP.
and sodium bicarbonate is found in our blood The molecular formula of the gas is
and it maintains the pH of blood to a constant 1) HF 2) H3F3
value of about 7.4. 3) H2F2 4) H4F4
 6 Test ID : 836 [Type - I]
49. Statement – I : The empirical formula 54. Assertion (A) : Absolute values of internal
represents the simplest whole number ratio of energy of a substance can’t be determined.
various atoms present in a compound. Reason (R) : It is impossible to determine the
Statement – II : The empirical formula exact values of constituent energies of the
weight of ethane is half of its molecular mass. substances.
1) Both Statement-I and II are true 1) Both (A) and (R) are true and the (R) is a
2) Both Statement-I and II are false correct explanation of the (A)
3) Statement-I is true and Statement-II is false 2) Both (A) and (R) are true but (R) is not a
4) Statement-I is false and Statement-II is true correct explanation of the (A)
50. Statement – I : In some elements, the 3) (A) is true but the (R) is false
constituent particles are molecules.
4) Both (A) and (R) are false
Statement – II : ‘amu’ has been replaced by
unified mass ‘u’. 55. A sample of 1.0 mole of a mono atomic ideal
1) Both Statement-I and II are true gas is taken through a process as shown in the
2) Both Statement-I and II are false figure. What will be the value of ∆H for the
process as a whole?
3) Statement-I is true and Statement-II is false
4) Statement-I is false and Statement-II is true
51. 1.020g of metallic oxide contains 0.540g of
the metal. If the atomic mass of metal is 3
times of its equivalent mass, the molecular
formula of its oxide is
1) MO 2) M2O3 1) –3.150 2) –2.303
3) M2O4 4) M2O 3) +2.303 4) 0
52. For an electron in a hydrogen atom, the wave 56. Statement – I : Combustion of all organic
function ‘Ψ’ is proportional to e–r/ao where ao compounds is exothermic process.
is the Bohr’s radius. What is the ratio of the Statement – II : The enthalpy of formation
probability of finding the electron in the for all elements in their standard state is taken
nucleus to the probability of finding it at ao? as zero.
1) e 2) e2 1) Both Statement-I and II are true
1 2) Both Statement-I and II are false
3) 2 4) zero
e 3) Statement-I is true and Statement-II is false
53. Which of the following will violate aufbau 4) Statement-I is false and Statement-II is true
principle as well as Paulis exclusion principle? 57. Mark the correct statement
1s 2s 2p 1) For a chemical reaction to be feasible, ∆G
1) should be zero
2) Entropy is a measure of orderness in a
2) system
3) For a chemical reaction to be feasible, ∆G
3) should be positive
4) The total energy of an isolated system is
4) constant
 7 Test ID : 836 [Type - I]
58. The solubility of Pb(OH)2 in water is 2 x 10–6 M. 64. Which one of the following ion has the highest
Calculate the solubility of Pb(OH)2 at pH = 12. value of ionic radius?
1) 1.20 x 10–5 M 2) 3.2 x 10–5 M 1) Li+ 2) B+3
3) 2.4 x 10–4 M 4) 3.2 x 10–13 M 3) O2– 4) F–1
59. What is the Kp & Kc relation for 65. Which one of the following series contains
electrophiles only?
1 3
N 2(g ) + H 2(g ) → NH 3(g ) 1) H2O, SO3, H3O+ 2) NH3, H2O, AlCl3
2 2
3) AlCl3, SO3, NO +2 4) H2O, Cl+, NH3
1) Kp = Kc 2) Kp > Kc
66. In which of the following cannot show +M
3) Kp < Kc 4) Kp = 2Kc
effect?
1
60. For the reaction N2O5(g) ⇌ 2NO2 + O2(g)
2 1) 2)
at a constant volume and temperature, if the
initial pressure is 600mm Hg and pressure at
3) 4) Both (2) and (3)
equilibrium is 960 mm Hg. Find the degree of
dissociation of N2O5. 67. Consider the following three halides
1) 0.1 2) 0.2 A) CH3 – CH2 – Cl
3) 0.6 4) 0.4 B) CH2 = CH – Cl
61. The ionization energy of Li is 520 kJ/mole.
C)
The amount of energy required to convert
140mg of Li atoms into gaseous Li+ ions is Arrange C – Cl bond length of these
1) 10.4 kJ 2) 520 kJ compounds in decreasing order
3) 72.8 kJ 4) 3.71 kJ 1) A > B > C 2) A > C > B
62. The electronic configuration of four elements 3) C > B > A 4) B > C > A
are 68. Arrange the given groups in decreasing order
i) [Xe]5s1 ii) [Xe]4f145d16s2 of their +I power?
iii) [Ar]3d104s24p5 iv) [Ar]3d74s2 A) CH 3 − B) CH3 – CH2 –
Select the incorrect statement about these CH3
elements CH 3 − CH − |
C) | D) CH3 − C −
1) (i) is a strong reducing agent CH 3 |
CH3
2) (ii) is a d-block element
3) (iii) belongs to halogens 1) A > B > C > D 2) B > C > A > D
3) D > C > B > A 4) D > C > A > B
4) (iv) exhibits variable oxidation states
69. In the following compound, at which carbon
63. An element which occurs in the first short
the abstraction of proton will be fastest?
period has an outer electronic configuration
s2p1. What are the formula and acid-base
character of its oxide
1) XO3, basic 2) X2O3, basic
3) X2O3, acidic 4) XO2, acidic 1) p 2) q
3) r 4) s
 8 Test ID : 836 [Type - I]
70. Statement – I : Benzene forms only one type
of mono substituted product.
Statement – II : In benzene there are three 3) 4) All of these
C – H single bonds and three C – C double
bonds.
75. Correct statement about inductive effect?
1) Both Statement-I and II are true
2) Both Statement-I and II are false 1) It is a temporary effect
3) Statement-I is true and Statement-II is false 2) Distance dependent
4) Statement-I is false and Statement-II is true 3) It operates through π-bond only
71. sp3 hybridized negatively charged carbon atom 4) All of these
is present in 76. Choose the correct stability order
⊕ ⊕
1) CH 2 = CH − CH 2− 2) CH 3 − C − CH 3 CD3 − C − CD3
P) | Q) |
CH 3 CD3
3) 4) All the above
1) P > Q
72. Assertion (A) : is more stable 2) Q > P
3) P = Q
than but-1-ene.
4) Stability cannot be predicted
Reason (R) : has more hyper 77. Assertion (A) : Hydrazine gives Prussian blue
colour in the Lassaignes test.
conjugated structures.
Reason (R) : Hydrazine does not contain ‘C’
1) Both (A) and (R) are true and the (R) is a
so with ‘Na’ metal CN– is not formed
correct explanation of the (A)
1) Both (A) and (R) are true and the (R) is a
2) Both (A) and (R) are true but (R) is not a
correct explanation of the (A) correct explanation of the (A)
3) (A) is true but the (R) is false 2) Both (A) and (R) are true but (R) is not a
4) Both (A) and (R) are false correct explanation of the (A)
73. Energies of three resonating structures of a 3) (A) is true but the (R) is false
compound are E1, E2 and E3 respectively and 4) (A) is false but (R) is true
energy of real molecule is Eo. If E1 > E2 > E3 78. Which of the following shows enantiomorphism?
then magnitude of the resonance energy will
1) CH 3 − CH − COOH
be |
1) (E1 + E2 + E3) – Eo 2) E1 – Eo CH 3
E + E 2 + E3 2) CH2 = CH – CH2 – CH2 – CH3
3) E3 – Eo 4) 1
3 3) CH 3 − CH − CH 3
74. Which of the following compound is |
aromatic? NH 2
4) CH 3 − CH 2 − CH − CH 3
1) 2) |
NH 2
 9 Test ID : 836 [Type - I]
79. Correct IPUAC name of following compound
is 3)
O NH 2
|| |
HC − CH − CH − COOH
| 4)
COOH
1) 2-amino-3-formylbutane-1,4-dioic acid 85. Match the following
2) 2-formyl-3-aminobutane-1,4-dioic acid Column – I
3) 3-amino-2-formylbutane-1,4-dioic acid A) Pyrrole
4) 2-amino-3-carboxy-4-oxobutanoic acid B) Cyclopentadienyl anion
80. Number of 1o, 2o and 3o hydrogens in iso C) Cyclohexene
pentane is D) Cyclopentadienyl cation
1) 6, 2, 4 2) 6, 6, 0 Column – II
3) 9, 2, 1 4) 6, 4, 2 p) non-benzenoid aromatic
81. Which compound is not smallest member of
q) non-aromatic
their corresponding homologous series?
r) Heterocyclic aromatic
1) Acetone 2) Acetylene
3) Acetic acid 4) Ethylene s) Antiaromatic
82. In Duma’s estimation 0.3 g of organic 1) A-p, B-r, C-s, D-q
compound gave 42 ml of nitrogen gas at STP. 2) A-r, B-p, C-q, D-s
Then the percentage composition of nitrogen 3) A-q, B-s, C-r, D-p
in the compound is
4) A-s, B-q, C-p, D-r
1) 56% 2) 17.5%
86. Conformational changes in ethane molecule
3) 14% 4) 70%
leads to change in
1) Torsional angle 2) Bond angle
83. IUPAC name of
3) Bond length 4) All of these

1) 2-Methoxy-4-nitrobenzaldehyde
2) 4-Nitroanisaldehyde
87. is a tautomer of
3) 3-Methoxy-4-formylnitrobenzene
4) 2-Formyl-4-nitroanisole
84. In which of the following molecules, all atoms
are coplanar?
1) 2)
1)

3) 4) Both (1) and (2)

2)
 10 Test ID : 836 [Type - I]
88. The number of 1o, 2o and 3o amines possible 93. Racemic mixture is formed by mixing two
with the molecular formula C3H9N 1) Isomeric compounds
respectively (Excluding stereo isomers) 2) Meso compounds
1) 1, 2, 2 2) 1, 2, 1 3) Equimolar mixture of enantiomers
3) 2, 1, 1 4) 3, 0, 1
4) Both (1) and (2)
89. Total number of benzenoid aromatic isomers
94. For which of the following molecules dipole
having formula C7H7Cl
moment is zero.
1) 4 2) 3
3) 5 4) 6
CHO

90. Relative configuration of HO H is

CH2OH
1) R 2) S
3) D 4) L 1) only III 2) III & IV only
91. Assign R, S configuration to the given 3) only I 4) I & II only
compound

95. shows

1) Geometrical isomerism
1) 2R, 3S 2) 2S, 3S 2) Optical isomerism
3) 2S, 3R 4) 2R, 3R 3) Both (1) and (2)
92. Which of the following will show optical 4) Tautomerism
activity? 96. Statement – I : Me – C ≡ N and Me – N C
1) are not functional isomers.
Statement – II : In HCN, cyanide and
isocyanide groups are inter convertible into
each other and remains in equilibrium
2) 1) Both Statement-I and II are true
2) Both Statement-I and II are false
3) Statement-I is true and Statement-II is false
3) 4) Statement-I is false and Statement-II is true
97. Statement – I : Diastereomers are mirror
images of each other.
Statement – II : Diastereomers may be
4)
optically active.
 11 Test ID : 836 [Type - I]
1) Both Statement-I and II are true 101. The
IUPAC name of the compound
2) Both Statement-I and II are false CH3 − CH 2 − CH − CH 2 − CH − CH3
| |
3) Statement-I is true and Statement-II is false CH3 − CH CH 3
4) Statement-I is false and Statement-II is true |
CH3
98. Assertion (A) : In CH2 = CH2 molecule the
rotation about C – C double bond is restricted. 1) 3-Ethyl-2,5-dimethylhexane
Reason (R) : Rotation of one CH2 fragment 2) 2-Ethyl-2,5-dimethylhexane
with respect to other interferes with maximum 3) 2, 5-dimethyl-3-ethylhexane
overlap of p-orbitals. 4) 2, 5-dimethyl-3-ethylpentane
1) Both (A) and (R) are true and the (R) is a 102. In wurtz reaction, if we take ethyl chloride and
correct explanation of the (A) methyl chloride, the number of possible
2) Both (A) and (R) are true but (R) is not a alkanes obtained
correct explanation of the (A) 1) 1 2) 2
3) (A) is true but the (R) is false 3) 3 4) 4
4) Both (A) and (R) are false 103. Which of the following method cannot be used

99. Which of the following not having neo alkyl for preparation of CH3 – CH3?
group? Zn
A) C2H5 – Cl +
→
H
LiAlH4
1) B) CH 3 − CH 2 →
|
Cl
H O
2
C) Al4C3 
HCl→
2) HO
2
D) CaC2 +
→
H
1) only C 2) only D
3) 3) Both (C) and (D) 4) Both (A) and (B)
NaOH NaOH +CaO
104. CH3COOH  → A  → B;
B is
4) 1) CH3 – CH3 2) CH3 – H
3) C3H8 4) CH3 – D
105. Number of moles of O2 required for complete
100. Statement – I : IUPAC name of combustion of one mole of propane.
CH2 = CH – CH2 – C ≡ CH is pent-4-en-1-yne 1) 7 2) 5
Statement – II : Double bond should get
3) 16 4) 10
lowest numbering, while naming at equivalent
106. Nitration of propane at elevated temperature
position to the triple bond.
follows which mechanism
1) Both Statement-I and II are true
1) Electrophilic substitution
2) Both Statement-I and II are false
2) Free radical substitution
3) Statement-I is true and Statement-II is false 3) Nucleophilic substitution
4) Statement-I is false and Statement-II is true 4) Free radical addition
 12 Test ID : 836 [Type - I]
107. When n-butane is heated in the presence of 112. Assertion (A) : All the carbon atoms in
AlCl3/HCl it will be converted into CH2 = C = CH2 are sp2 hybridized.
1) Ethane 2) Propane Reason (R) : In the above molecule, two pi-
3) Butene 4) Isobutane bonds are in different plane.
108. One molecule of alkene ‘X’ an ozonlysis gave
1) Both (A) and (R) are true and the (R) is a
one of the product is acetone. The IUPAC of
‘X’ is correct explanation of the (A)
1) 2-methyl-1-butene 2) Both (A) and (R) are true but (R) is not a
2) 2-methyl-2-butene correct explanation of the (A)
3) 2-butene 3) (A) is true but the (R) is false
4) 1-butene 4) (A) is false but (R) is true
109. Statement – I : 1-Butene on reaction with
HBr in the presence of peroxide, produces 1-
bromo butane as major product.
113.
Statement – II : It involves the formation of a
primary radical only.
1) Both Statement-I and II are true
2) Both Statement-I and II are false
3) Statement-I is true and Statement-II is false
4) Statement-I is false and Statement-II is true
110. Match the following
Column – I Column – II
B and Q are
(Reagents) (Reactions)
A) O3, Zn + H2O p) Test for unsaturation 1) Diastereomers 2) Enantiomers
B) Na, Dry ether q) reductive ozonolysis 3) Geometrical isomers 4) Both (1) and (3)
C) Cold alkaline KMnO4 r) Wurtz reaction 114. What would be the product when ethene is
D) Br2/CCl4 s) Bayer’s reagent oxidized with Bayers reagent?
1) A-p, B-q, C-r, D-s
CH 2 − CH 2
2) A-s, B-r, C-s, D-p 1) | | 2) H − C − H
OH OH ||
3) A-q, B-r, C-s, D-p O
4) A-r, B-q, C-s, D-p
H − C − OH
Conc.H SO
111. (Ph) 2 CH − CH − CH 3 
∆
2 4
→ (A) 3) || 4) CO2 + H2O
| O
OH
115. Match the following
(A) is
Column – I
1) (Ph)2C = CH – CH3
A) –Cl, –Br, –I
2) Ph − CH = CH − CH 2 − Ph
B) –NHCOR, –OCOCH3
3) (Ph)2CH – CH = CH2
C) –COOH, –CHO
4) (Ph) 2 C = C − CH3
| D) –NH2, –OH
OH
Column – II
 13 Test ID : 836 [Type - I]
p) Ring deactivating and meta directing groups Statement – II : In the nitration of benzene
q) Strong ring activating and ortho, para both HNO3 and H2SO4 act as Bronsted acids.
directing groups 1) Both Statement-I and II are true
2) Both Statement-I and II are false
r) Ring deactivating groups but ortho, para
3) Statement-I is true and Statement-II is false
directing groups
4) Statement-I is false and Statement-II is true
s) Moderate activating and ortho, para directing
119. Which of the following compound(s) is/are
groups
not suitable to prepare by wurtz reaction?
1) A-r, B-s, C-p, D-q
1) CH3 – CH3 2) CH 3 − CH − CH 3
2) A-s, B-r, C-p, D-q |
CH 3
3) A-q, B-r, C-p, D-s
CH 3
4) A-r, B-s, C-q, D-p |
116. When sodium or potassium salt of maleic acid 3) CH 3 − C − CH 3 4) Both (2) and (3)
|
or fumeric acid is electrolysed, which alkyne CH 3
is formed at anode? 120. When HCl gas is passed through propene in
1) Propyne 2) Butyne the presence of benzoyl peroxide, it gives
3) Ethyne 4) All the above 1) n-propyl chloride 2) 2-chloro propane
117. Assertion(A) : The reactivity order of given 3) Allyl chloride 4) No reaction
compounds towards aromatic electrophilic 121. Statement – I : Equilibrium constant of a
substitution reaction is reaction is temperature dependent.
Statement – II : When NaCl is dissolved in
water, the electrostatic interactions are
reduced.
1) Both Statement-I and II are true
2) Both Statement-I and II are false
3) Statement-I is true and Statement-II is false
Reason (R) : Electron donating group 4) Statement-I is false and Statement-II is true
increases electron density on benzene ring, 122. The compound which contains both covalent

hence aromatic electrophilic substitution and coordinate covalent bond is

reactivity increases. 1) C2H5NC 2) C2H5CN
1) Both (A) and (R) are true and the (R) is a 3) HCN 4) KMnO4
123. The hybridization and geometry of BrF3
correct explanation of the (A)
molecule are
2) Both (A) and (R) are true but (R) is not a
1) sp3d and trigonal bipyramidal
correct explanation of the (A)
2) sp3d2 and octahedral
3) (A) is true but the (R) is false
3) sp3d and see-saw
4) (A) is false but (R) is true 4) sp3, tetrahedral
118. Statement– I : The rate of nitration of chloro 124. In the following which central atom has
benzene is greater than benzene. different hybridization from others
 14 Test ID : 836 [Type - I]
1) Cl2O 2) OF2 4) Intra molecular hydrogen bond in p-nitro
3) H2O 4) SO2 phenol
125. Assertion (A) : Though the central atom of 130. Order of bond angles in NH3, PH3 and AsH3 is
both NH3 and H2O molecule are sp3 1) NH3 > PH3 > AsH3
hybridized, H – N – H bond angle is greater 2) AsH3 > PH3 > NH3
than that of H – O – H. 3) NH3 = PH3 > AsH3
Reason (R) : Magnitude of lone pair – lone 4) NH3 = PH3 < AsH3
pair repulsions are greater than lone pair – 131. The ionization energies of C, Si, Ge and Sn
bond pair repulsions. are in the order of
1) Both (A) and (R) are true and the (R) is a 1) C > Si > Sn > Ge 2) C > Si > Ge > Sn
correct explanation of the (A) 3) C < Si < Sn < Ge 4) C < Si < Ge < Sn
2) Both (A) and (R) are true but (R) is not a 132. Which of the following molecule violates
correct explanation of the (A) octet rule?
3) (A) is true but the (R) is false 1) SF6 2) BeCl2
4) Both (A) and (R) are false 3) XeO3 4) All the above
126. Which of the following statement is incorrect? 133. Polarisibility of halide ions decreases in the
1) Non-bonding pairs occupy more space than order of
bonding pairs around the central atom 1) F– > Cl– > Br– > I–
2) The bonding orbitals in a trigonal bipyramidal 2) I– > Br– > Cl– > F–
molecules are described as sp3d hybridized 3) I– > Br– > F– > Cl–
3) SnCl2 has linear shape 4) F– > Cl– > I– > Br–
4) PCl +4 and AlCl −4 are isoelectronic species 134. The correct decreasing order of stability of
carbocations is
127. Which of the following has maximum bond
1) (C6H5)2CH+ > C 6 H 5 CH 2+ > (C6H5)3C+
strength?
1) O2 2) O +2 2) (C6H5)2CH+ > (C6H5)3C+ > C 6 H 5 CH 2+

3) O −2 4) O 22 − 3) (C6H5)3C+ > (C6H5)2CH+ > C 6 H 5 CH 2+

128. Bond length of HCl is 1.275 Ao (q = 4.8 x 10–10 4) C 6 H 5 CH 2+ = (C6H5)3C+ > C 6 H 5 CH 2+

esu) if µ = 1.02 D then HCl is (approximately) 135. Method used to find the percentage composition
1) 100% ionic 2) 83% covalent of halogens is
3) 50% covalent 4) 40% ionic 1) Carius method 2) Beilstein test
129. p-Nitro phenol has high boiling point than 3) Dumas method 4) Lassaigne’s test
o-Nitro phenol. This is due to the presence of 136. The element that does not show catenation is
1) Ionic bond 1) Ge 2) Si
2) Covalent bond 3) Sn 4) Pb
137. What is the end point in permanganate
3) Inter molecular hydrogen bond in p-nitro
titration?
phenol
1) Appearance of blue colour
 15 Test ID : 836 [Type - I]
2) Appearance of black colour 3) Decreases by 14kJ
3) Disappearance of blue colour 4) Increases by 14 kJ
4) Appearance of light pink colour 145. What are the favourable conditions for
138. Which of the following order is correct? spontaneous process at all temperature?
1) Bond energy of O – O : O2 < O3 1) ∆H = -ve, ∆S = +ve
2) Bond length of C – C : C2H6 < C2H4
2) ∆H = +ve, ∆S = -ve
3) Bond angle – NH3 > PH3
3) ∆H = +ve, ∆S = +ve
4) Bond order of C – C : C2H4 > C2H2
4) ∆H = -ve, ∆S = -ve
139. Which of the following is more acidic oxide?
146. For the reaction
1) CO 2) H2O
3) NO 4) Cl2O7 C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(l) at room
140. Which orbital has maximum number of total temperature, then ∆H – ∆E is
nodes? (radial and angular nodes) 1) +RT 2) –3RT
1) 4s 3) +3RT 4) –RT
2) 4p 147. Forwhich of the following reaction at 298K,
3) 4d the value of Kp/Kc is maximum and minimum
4) all have same number of total nodes respectively
141. MnO 4
−
oxidizes Xn+ ion to XO 3− , MnO −4 a) N2O4(g) ⇌ 2NO2(g)
+2 -3
changes to Mn in acidic solution. 2.68 x 10
mole of Xn+ requires 1.61 x 10-3 mole of b) 2SO2(g) + O2(g) ⇌ 2SO3(g)
MnO −4 . Then the value of n is
c) X(g) + Y(g) ⇌ 4C(g)
1) 1 2) 2
3) 3 4) 4 d) A(g) + 3B(g) ⇌ 7C(g)
142. Which of the following cannot act as an 1) d and c 2) d and b
oxidizing agent is
3) c and b 4) d and a
1) SO −4 2 2) NO 3−
148. Calculate the equilibrium constant for the
3) Cl– 4) All of the above given reversible reaction
143. In
the reactions
A(g) + 2B(g) ⇌ C(g)
HCl + NaOH → NaCl + H2O + Xk. cal mol–1
Equilibrium concentrations of A, B and C are
H2SO4 + 2NaOH → Na2SO4 + 2H2O + Yk. cal mol–1
0.06 mol/L, 0.12 mol/L and 0.216 mol/L.
1) X = Y 2) X = 2Y
1) 250 2) 416
Y
3) X = 4) X = Y 3) 0.004 4) 125
2
144. Asystem absorbs 10kJ of heat and does 4kJ of 149. Calculate the amount of C formed in the
work. The internal energy of the system reaction 2A + 4B → 3C + 4D when 5 moles of
A react with 6 moles of B
1) Decreases by 6kJ
1) 2.5 moles 2) 3.5 moles
2) Increases by 6kJ
 16 Test ID : 836 [Type - I]
3) 4.5 moles 4) 7.5 moles 1) 4 x 1020 2) 1.5 x 1020
150. Thenumber of photons emitted per second by 3) 3 x 1020 4) 2 x 1020
a 60W source of monochromatic light of wave
length 663 nm is (Given h = 6.63 x 10–34 Js)

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