25-04-2026

1001CJA101029260010 JA

PART-1 : MATHEMATICS

SECTION-I

1) Tangent from to y2 = x3 passes through -

(A) (4, 8)
(B) (1, –1)
(C) (1, 1)
(D) (3, 4)

2) A differentiable function f : R → R, and satisfying the relation

f(x + y) = f(x) + f(y) + 2xy(x + y) – , ∀ x, y ∈ R and . Then

(A) f(x) is an odd function

(B) f(x) is a bijective function
(C) f(x) is a decreasing function
(D) 12f(2) = 100

3) If , given that g(2) = , then the value of 90|g(1) + g(–1)| is

not greater than (where C is the constant of integration)

(A) 30
(B) 50
(C) 70
(D) 90

4) Let y = f(x) be a differentiable function such that f(4 – x) = f(x) and the equation f(x) = 0
has exactly 7 distinct real roots x1, x2, x3, x4, x5, x6 and x7 such that x1 < x2 < x3 < x4 < x5 < x6 < x7 then
which of the following is/are must be correct ?

(A) x1 + x2 + x3 + x4 + x5 + x6 + x7 = 14
(B) y = |f(x)| is not differentiable at x = x2, x4, x6
(C)
(D) f(x) is a periodic function

5) Let and
(where 'c' is constant of integration) and . If h(0) =
(where a ∈ N,b and c are coprime). Then

(A) a + 2b + 3c = 14
(B) 2a + 3b + 5c = 22
(C) 3a + 5b + 4c = 29
(D) 4a + b + 3c = 17

SECTION-II (i)

Common Content for Question No. 1 to 2

If , where f(0) = α and , where

g(0) = α + β and c, k are constant of integration.

1) If β > 0 then the number of solution(s) of the equation , is

2) If β < –1 then the number of solution(s) of the equation , is

Common Content for Question No. 3 to 4

Let P(x) be a polynomial of degree 3 satisfying P(–1) = 10, P(1) = –6 and P(x) has maxima at x = –1
and P ′ (x) has minima at x = 1, then

3) The absolute value of P(2) is -

4) The absolute value of P ′ (1) is

Common Content for Question No. 5 to 6

Let f(x) be a polynomial of degree atmost three such that f(x) + 1 is divisible by (x – 1)2 and f(x) – 1 is
divisible by (x + 1)2, then

5) is equal to

6) If , where g(0) = 0 and C is constant of integration then |3g(3)| is

SECTION-II (ii)

1) Number of solution(s) of the equation cosx = tan–1 2x in the interval [–2π, 2π] is(are)
2) If where
a, b, c and d are real constants and M is the constant of integration then (a + b + c + d) equals

3) Let f(x) be a thrice differentiable function such that it intersects the curve g(x) = 2x3 + 7x2 – 5x +
1 exactly at 7 distinct points, then minimum number of roots of f '''(x) = 12 is

4) If where a, b ∈ N then (a – b) is

SECTION-IV

1)

Column-
Column-I
II

The angle bisector of ∠A in the ΔABC, where A(–8, 5), B(–15, –19) and C(1, –7)
(A) (P) 1
is 11x + by + c = 0, then the value of (b + c) is greater than

Consider two points A(2 , 4) & B(1, 2). Let P(a, a) be a point on the straight
(B) line (Q) 2
L : y = x such that AP + PB is minimum, then 'a' is less than or equal to

If the lines x + ay + a = 0, bx + y + b = 0 and cx + cy + 1 = 0

(a, b, c being distinct ≠ 1) are concurrent, then the value of
(C) (R) 6

If the vertices of a quadrilateral is given by (x2 – 9)2 + (y2 – 4)2 = 0, then the
(D) (S) 24
area of quadrilateral is not less than

(T) 80

2) Column-I contains functions and column-II contains their properties in their domain. One or more
entries of Column-II can be matches with one entry of column-I.

Column-I Column-II

(A) f(x) = sin22x – 2sin2x (P) Range contains no natural number

(B) (Q) Range contains atleast one integer

(C) (R) Many one but not even function

(D) (S) Both many one and even function

(T) Periodic but not odd function

 PART-2 : PHYSICS

SECTION-I

1) In the circuit shown, the resistance are given in ohms and the battery is assumed ideal with emf

equal to 3.0 V.

(A) The resistor R5 that dissipates maximum power.

(B) The resistor R1 that disspiates maximum power.
(C) The potential difference across resistor R3 is 0.4 V.
(D) The current passing through 3V battery is 40 mA.

2) In the system of concentric conducting spheres, the :-

(A)
Capacitance of the system is when the outer sphere is earthed

(B) The energy stored in the system if a charge Q is given to the inner sphere is in
(a)
(C) If the inner sphere is earthed, equal and opposite charges will be held by the conductors
If we give a charge Q to the inner conductor, the energy stored in the system of two spheres is
(D)

3) Two capacitors C1 = 4 μF and C2 = 2μF are charged to same potential V = 500 Volt, but with

opposite polarity as shown in the figure. The switches S1 and S2 are closed.

(A) The potential difference across the two capacitors are same and is given by 500/3V
(B) The potential difference across the two capacitors are same and is given by 100/3V
(C) The ratio of final energy to initial energy of the system is 1/9.
(D) The ratio of final energy to initial energy of the system is 4/9.

4) An asteroid orbiting around a planet in circular orbit suddenly explodes into two fragments in
mass ratio 1 : 4. If immediately after the explosion, the smaller fragment starts obriting the planet in
reverse direction in the same orbit, what will happen with the heavier fragment?

(A) Fall on the planet

(B) Start orbiting the planet in a larger orbit
(C) Its angular momentum remains conserved during motion.
(D) Escape from the gravitational interaction with the planet

5) A thin uniform rod of length ℓ and mass m is free to rotate about a smooth axis which passes
through its end A. A point like mass m is shot horizontally with a velocity vo towards the opposite end
of the rod (the point B). When it hits the rod, it sticks to it and the rod just reaches the horizontal

position. Which of the following statements is wrong?

(A) The value of v0 is

The angular acceleration of the rod when it reaches the horizontal position is
(B)

The reaction by the axis on the rod in the horizontal state is

(C)

(D)
The acceleration of center of mass of the system at horizontal position is g

SECTION-II (i)

Common Content for Question No. 1 to 2

All bulbs consume same power. The resistance of bulb 1 is 36Ω. Answer the following questions :

1) What is the resistance (in Ω) of bulb 3?

2) What is the resistance of bulb 4?

Common Content for Question No. 3 to 4

Two planets of equal mass orbit a much more massive star. Planet m1 moves in a circular orbit of
radius 1 × 108 km with a period of 2 years Planet m2 moves in an elliptical orbit with closest distance
r1 = 1 × 108 km and farthest distance r2 = 1.8 × 108 km, as shown.

3) Using the fact that the mean radius of an elliptical orbit is the length of the semimajor axis, find
the period of m2’s orbit in year.

4) Ratio of speeds of planet m2 at P with that at A. (VP/VA) =

Common Content for Question No. 5 to 6

For a glass prism the plot of deviation (δ) vs angle of incidence (i) is as shown. If the refractive index

of the glass is μ and value of angle is i1. Then :

5) Find the refractive index of glass :

6) Find the value of i1 (in degree) :

SECTION-II (ii)

1) A wire of uniform cross-section and resistance 80Ω is bent in the form of a square ABCD. Point A
is connected to a point P on DC by a wire AP of resistance 20Ω. When potential difference is applied
between A and C, the points B and P are seen to be at the same potential. The resistance of part DP
is xΩ.Find the value of x.

2) In the shown potentiometer arrangement the wire PQ has a resistance of 5Ω and the driver cell
has an emf of 2V. If a balance point is obtained at 0.6m along PQ, what is the value of resistance R

(in Ω) ? (Length PQ = 1 m)

3) A uniform semicircular disc of mass ‘M’ and radius ‘R’ hinged at point O as shown in figure is
released from rest from a vertical position as shown. If the initial magnitude of angular acceleration

of the disc is then the value of x is :

4) In a uniformly charged fixed nonconducting sphere, a very thin tunnel has been made along the
diameter as shown in figure. A charge particle –q having mass m is released from rest at t = 0 at one
end of the tunnel. Total charge Q of sphere is uniformly distributed in its volume. Charge particle

reaches at the centre of solid sphere first time at . The value of α is ________

SECTION-IV

1) Column-I shows electric circuits and Column-II shows equivalent resistance between A and B.
 Column-I Column-II

(A) (P) R/2

(B) (Q) R/3

(C) (R) 2R/3

(D) (S) 2R

(T) None

2) Answer the following by appropriately matching the lists based on the information given
in the paragraph.
Consider a body rolling on a horizontal surface as shown in figure (Symbols have their usual
meaning)

Column-I Column-II

(A) Velocity is zero (P) Point A

(B) Speed in maximum (Q) Point B

(C) 0 < speed < vcm (R) Point C

(D) 1.3 vcm < speed < 2 vcm (S) Point D

(T) Point E

PART-3 : CHEMISTRY

SECTION-I

1) The correct option(s) regarding the

complex is (are)

(A) It has two geometrical isomers

(B) It will have three geometrical isomers, if bidentate ‘en’ is replaced by two cyanide ligands
(C) It is paramagnetic

(D) It absorbs light at longer wavelength as compared to

2) If (P) and (Q) are major products, then find incorrect statement for given reaction sequence :

(A) Formation of (Q) from (P) is an example of syn addition

(B) Formation of (P) is an example of unimolecular elimination reaction.
(C) Product (P) does not give bromine water test.
(D) Product (Q) is optically inactive due to external compensation.

3) For the reaction sequence given below

If x, y and z are possible alkenes in the reaction and stability order is x > y > z, then correct
statement(s) is/are :

(A) Product x, y and z can be distinguish by test of unsaturation.

(B) Product x gives meso product on reaction with HCl/CCl4
(C) Product y gives Markovnikov product as major product on reaction with H–Br/CCl4
(D) Product Z is major product in given reaction

4) An ionic solid consists of A+2 and B–2 ion, having formula of AB. Identify the correct
statement(s) regarding unit cell and location of ions.

(A) Simple cubic of B–2 ions and A+2 occupying all the body centered voids or cubic voids.
(B) Face centered cubic of B–2 ions and A+2 occupying all tetrahedral voids.
(C) Face centered cubic of B–2 ions and A+2 occupying 50% tetrahedral voids.
(D) Face centered cubic of A+2 ions and B–2 occupying all tetrahedral voids.

5) Which of the following solution(s) is/are isotonic with respect to 0.5 M aqueous NaCl solution in
which NaCl is 80% ionized ? [Atomic mass : Na = 23, S = 32]

(A) 153.9gm of Sucrose dissolved in 500ml of solution.

(B) 0.3 M aqueous Na2SO4 solution undergoing 100 % ionization
(C) 1.8 % (w/v) aqueous NaOH solution undergoing 100 % ionization.
(D) 1.2 M benzoic acid in a solution of benzene where the acid dimerizes to an extent of 50 %.

SECTION-II (i)

Common Content for Question No. 1 to 2

The complex [Cr(NH3)6]+3 is a inner orbital complex with CFSE equal to –1.2Δ0. The Mn+2 and
Fe+2 form outer orbital complex with NH3 ligand then.

1) How many following statement(s) is/are correct for complex ammine of Fe(II) and Fe(III)?
(i) Both Fe(II) and Fe(III) form outer orbital complex with NH3
(ii) Both form inner orbital complex with NH3
(iii) Fe(II) form outer while Fe(III) form inner orbital complex with NH3
(iv) Both are diamagnetic
(v) Both are paramagnetic

2) How many following statement(s) is/are correct for the complex [Cr(NH3)6]+3 ? (i) It is diamagnetic

with configuration
(ii) It is paramagnetic with configuration
(iii) It is paramagnetic with magnetic moment of order 4
(iv) It is an outer orbital complex
(v) It has d2sp3 hybridisation

Common Content for Question No. 3 to 4

Dehydrohalogenation of alkyl halide in presence of base gives Saytzeff's product as major product by
E2-elimination reaction which is one step reaction and it is example of anti-elimination.

products
Consider the above reaction and give answer of following questions.

3) Possible number of alkenes is :

4) Number of α-hydrogen in Saytzeff alkene is -

Common Content for Question No. 5 to 6

Initially at t = 0, gas A was present along with some amount of gas C, and initial pressure of gas A is
same as that of gas C. After some time t = t1, total pressure is found to be 22.5 bar and after very
long time total pressure is 40 bar. Assume this decomposition is a first order, at a constant
temperature. (Take ℓn10 = 2.3)

5) If t1 = 1.15 seconds and rate constant is then value of 'X' is _______

6) At t = t1 partial pressure of gas B (in bar) is :

SECTION-II (ii)

1) In which of the following molecule pπ – dπ back bonding present?

CHCl3, B3N3H6, (CH3)3N, SiH3NCO, :CCl2, (CH3)3SiOH, (SiH3)2O, :CF2

2) Find the number of incorrect orders.

(i) Cr > Mn (IE2) (ii) Mn > Fe (IE3) (iii) Cu > Zn (IE2) (iv) Zn > Cu (IE1) (v) Cd ≃ Hg (Atomic size)
3) Calculate mass of CaBr2 (in gram) required to prepare 960 gm of aqueous solution having
depression in freezing point of solution equal to 2K. (Kf of H2O = 2K-kg/mole) (Atomic mass of Ca =
40, Br = 80) ?

4) An electron practically at rest is initially accelerated through a potential difference of 100 volts.
Then it had de-Broglie wave length . When electron is accelerated from rest by potentials of 81
volts and 49 volts its de-Broglie wavelength was found to be respectively. If

then value of X is ______

SECTION-IV

1) Match the following column. Column-I with Column-II

Column-I Column-II

(A) N(SiH3)3 (P) pπ – dπ back bonding

(B) N(CH3)3 (Q) sp3-hybridization for underlined atom

(C) B2H6 (R) pπ – pπ back bonding

(D) BF3 (S) Neither pπ – pπ nor pπ – dπ back bonding

(T) Underlined atom combines with Lewis base

The correct match is

2) Match the column :

Column-I Column-II
(Name of reaction/Test) (Reagent)

(A) Finkelstein reaction (P) SbF3

(B) Swart reaction (Q) HCl + Anhy. ZnCl2

(C) Darzen's halogenation reaction (R) NaI/acetone

(D) Lucas test (S) SOCl2

(T) NaOH/Δ
Match correct reagent/with given reaction/test.
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5
A. C,D B,D B,C,D A,C A,C,D

SECTION-II (i)

Q. 6 7 8 9 10 11
A. 2.00 0.00 17.00 12.00 0.00 0.00

SECTION-II (ii)

Q. 12 13 14 15
A. 1.00 8.00 4.00 1.00

SECTION-IV

Q. 16 17
A. A->PQRS,B->QRST,C->P,D->PQR A->PQST,B->QR,C->PQS,D->PS

PART-2 : PHYSICS

SECTION-I

Q. 18 19 20 21 22
A. B,C,D A,B,D A,C C,D B

SECTION-II (i)

Q. 23 24 25 26 27 28
A. 9.00 4.00 3.31 to 3.35 1.80 1.73 41.00

SECTION-II (ii)

Q. 29 30 31 32
A. 8.28 995.00 8.00 1.00

SECTION-IV

Q. 33 34
A. A->R,B->P,C->S,D->P A->R,B->P,C->T,D->QS

PART-3 : CHEMISTRY
 SECTION-I

Q. 35 36 37 38 39
A. A,B,D A,C,D C,D A,C A,B,C,D

SECTION-II (i)

Q. 40 41 42 43 44 45
A. 2.00 2.00 3.00 9.00 49.00 2.50

SECTION-II (ii)

Q. 46 47 48 49
A. 3.00 0.00 60.00 20.00

SECTION-IV

Q. 50 51
A. A->P,B->QS,C->QST,D->RT A->R,B->P,C->S,D->Q
 SOLUTIONS

PART-1 : MATHEMATICS

1) Let tangent at (t2, t3) passes through

⇒ 2t3 + 1 = 3t3 ⇒ t = 1

⇒ Equation of tangent is
⇒ 2y – 2 = 3x – 3 ⇒ 3x = 2y + 1

2) ∵

∴ f(2) =

3)

Since

⇒ 90|g(1) + g(–1)| = 40

4) The graph of f(x) is symmetric about x = 2 Obviously from given figure.

x1 + x2 + x3 + x4 + x5 + x6 + x7 = 14 and
Option (a), (c) are correct.
5)
Let ex = t

Hence, h(x) =

h(0) =
∴ a = 2, b = 3, c = 2

6)

Now,

7)

Now,
8) P ″ (x) = a(x – 1)

P ′ (x) =

P ′ (1) = 0 ⇒ b =

∴ P ′ (x) =

P(x) =
P(–1) = 10 ⇒ 5a + 6c = 60
Given P(1) = –6
⇒ –11a + 6c = –36
∴ a = 6, c = 5
P(x) = x3 – 3x2 – 9x + 5 ⇒ P(2) = –17
P ′ (x) = 3x2 – 6x – 9 ⇒ P ′ (1) = –12

9) P ″ (x) = a(x – 1)

P ′ (x) =

P ′ (1) = 0 ⇒ b =

∴ P ′ (x) =

P(x) =
P(–1) = 10 ⇒ 5a + 6c = 60
Given P(1) = –6
⇒ –11a + 6c = –36
∴ a = 6, c = 5
P(x) = x3 – 3x2 – 9x + 5 ⇒ P(2) = –17
P ′ (x) = 3x2 – 6x – 9 ⇒ P ′ (1) = –12

10) f ′ (x) = k.(x – 1) (x + 1) = k(x2 – 1)

on integrating
f(x) = k +M
Now using f(1) = –1, f(–1) = 1

we get M = 0 , k =

∴ f(x) = (x3 – 3x)

11)

Let – 3x = t3 ⇒ (x2 – 3) dx = 3t2 dt

12) Consider f(x) = cosx – tan–1(2x) (Apply IVT)

The equation f(x) = 0 has a root in .

13)
Put tanx = t2 ⇒ sec2xdx = 2t dt
∴ Hence, a + b + c + d = 15 – 11 + 7 – 3 = 8

14) Let h(x) = f(x) – g(x)

⇒ h(x) = 0 has exactly 7 distinct roots
⇒ h'(x) = has at least 6 roots
⇒ h"(x) = has at least 5 roots
⇒ h"'(x) = has at least 4 roots
⇒ h"'(x) = f "'(x) – 12

15) I =

16) (A) AB = 25 and AC = 15

Let M is the point of intersection of angle bisector and BC. Then M will divide the BC in the

ration of 5 : 3, hence coordinates of M will be

∴ Equation of AM is

⇒ 11x + 2y + 78 = 0
(B) As shown in figure, Let A' be the image of point A in line L
∴ AP + PB = A'P + PB
For any point P on line L,
A'P + PB ≥ A'B
∴ Minimum value of A'P + PB is A' B
when A', P, B are collinear
Now, coordinates of A' will be reflection of A(2, 4) in the line L : y = x
⇒ A' ≡ (4, 2)
Equation of A'B : y = 2
∴ Point P(a, a) will be (2, 2)
∴ a=2
(C) For concurrency
C2 → C2 – C1, C3 → C3 – C1

⇒ (1– b)(1– c) – (a –1)b(1– c) – (a –1)c(1– b) = 0 ⇒ (b –1)(c –1) + b(a –1)(c –1) +c(a – 1)(b
–1) = 0

(D) x2 = 9 ⇒ x = ±3
y2 = 4 ⇒ y = ±2
hence vertices of quadrilateral are
(3, 2), (–3, 2), (–3, –2) & (3, –2) respectively
hence area of quadrilateral = 24

17) (A) We have f(x) = sin2 2x – 2sin2x, x ∈ R

= 4sin2x cos2x – 2sin2x = 4sin2x(1 – sin2x) – 2sin2x = 2sin2x – 4sin4x

Clearly range of 'f' =

Also f(–x) = f(x)
So f is even function
Also f is periodic with period π.

(B) We have f(x) = sin–1 (sin πx), x ∈ R

Clearly 'f is periodic function with period '2' and also f is an odd function.
Clearly Rf = [–2, 2]
(C) We have, f(x) =
For domain,
ℓn(cos(sinx)) ≥ 0 ; (cos(sinx)) ≥ 1 ⇒ cos(sinx) = 1 ;
sinx = 0 ⇒ x = nπ, n ∈ I
Rr = {0}
since f(x) = 0
∴ f is both odd and even.
Also, f is periodic with period π.

(D) We have

Let
 ⇒ yx2 + y = x2 + 1 ⇒

So,

∴ Range of f(x) =
Also f(–x) = f(x) ∀ x ∈ R
∴ f is even function.

PART-2 : PHYSICS

18)
The equivalent circuit can be redrawn as shown in figure. From the figure it is obvious that

power dissipated by R1 is maximum. Potential difference across R2 is .

Therefore, potential difference across R3 or R4 is

The equivalent resistance of circuit across the cell is 50 + 25 = 75Ω.
Therefore, current drawn through cell is

19) For A : C = = For B : U =

For C : If inner sphere is earthed, potential of inner sphere becomes zero.

For D : If Q is given to the inner sphere,

U=
20)

21)
pi = pf
5mv = –mv + 4mv'

v ' is greater than escape velocity

so the heavier fragment will escape from the gravitational interaction with the planet

22) Applying conservation of angular momentum about A,

After impact, kinetic energy will be converted into potential energy.

∴
Now in horizontal position,

2mg – N = (2m)acm ⇒ N =

23)
24)

25) Mean radius of planet,

Now, T ∞ r3/2

Time period of
or T2 = 2(1.4)3/2 = 3.31 year

26)

Correct answer is (1.80)

27) δ = 1 + e – A
δmin = 2i – A
60° = 120° – A ⇒ A = 60°
63 = i1 + 2i1 – 60°

28) δ = 1 + e – A
δmin = 2i – A
60° = 120° – A ⇒ A = 60°
63 = i1 + 2i1 – 60°
29)
Since B and P are at same potential
RAP = RPC

30)

Using basics concept of potentiometer.

31) Question Explanation:

We need to find the value of x, the initial angular acceleration of the uniform semicircular disc
needs to be calculated and compared to the given expression.

Concept:
This question is based on moment of inertia, angular acceleration.

Solution:

T = Iα ; T = mg ; ,

Final Answer:
The correct answer is 8.

32)

⇒ SHM with MP at the centre of sphere

 33) (Q) Equivalent diagram

(S)
Assigning potential to each corner & solving

34) C is ICOR & speed of point at a distance r from C is

PART-3 : CHEMISTRY

35) Explain Question:

Isomerism, magnetism, and color (CFSE) in Co(III) complexes.

Concept:
Crystal Field Theory & Stereoisomerism

Solution:
Analyze the geometry for isomers, oxidation state for magnetism, and ligand field strength for
absorption wavelength
Calculation:
• Isomerism: It has 2 GIs (H2O trans to 'en' or cis
to 'en'). (Option 1 Correct).
• Ligand Replacement: Replacing 'en' with 2 CN– gives (type
[Ma3b2c]). This typically forms 3 GIs (1 facial + 2 meridional). (Option 2 Correct).
Explanation
(A) Two G.I. of [Co (NH3)3 (H2O) (en)]3+
(B) Two G.I. of [Co (NH3)3 (H2O) (en)]3+

• Magnetism: Co(III) (3d6) with Strong Field Ligands (en, NH3) pairs all electrons It is
Diamagnetic. (Option 3 Incorrect).
• Absorption: H2O is a weaker ligand than NH3. The given complex has weaker field splitting
than Since Energy lower energy means longer wavelength.
(Option 4 Correct).

Final Answer: Option (1, 2, 4)

36) The correct answer is option (A, C, D)

37)

38) Required formula of AB only exist in option (A) and (C).

(A) B–2 → simple cubic → 1
A+2 → cubic voids → 1
(C) B–2 → FCC → 4
A+2 → 50% of tetrahedral voids → 4

39) For NaCl :-

ic = 0.5 × [l + (2 – l) 0.8] = 0.9 M
For Sucrose solution :–

For Na2SO4 solution :–

ic = 0.3 × 3 = 0.9 M
For NaOH :-

For Benzoic acid :-

40)

Explain Question:
Analyzing the nature of ammine complexes of Fe(II) and Fe(III).

Concept:
Crystal Field Theory (CFT).

Solution:
NH3 is a weak field ligand for Fe2+ but acts as a strong field ligand for Fe3+.
Fe2+ (d6) with NH3 forms a high-spin, outer orbital complex (sp3d2) and is paramagnetic (4
unpaired electrons).
Fe3+ (d5) with NH3 forms a low-spin, inner orbital complex (d2sp3) and is paramagnetic (1
unpaired electron).
Correct statements are: (iii) and (v).
Calculation:

Fe(II) : [Ar]3d6; NH3 (WFL) → (Paramagnetic, Outer orbital).

Fe(III) : [Ar]3d5; NH3 (SFL) → (Paramagnetic, Inner orbital).

Final Answer: 2.00

0 0 0 0

41) [Cr(NH3)6]+3 Cr+3 ⇒ [Ar]3d3 4s 4p 4d 4f ⇒

inner orbital complex with d2sp3 hybridisation
⇒ 3 unpaired e– = paramagnetic
⇒μ= = B.M.

42) The correct answer is (3)

43)

44) A —→ 2B + C
P0 P0
P0 – p 2p p + P0
– 2P0 P 0 + P0
2P0 + P0 + P0 = 40
P0 = 10 bar
P0 – p + 2p + p + P0 = 22.5
p = 1.25 bar

45)

46)

SiH3NCO, (CH3)3SiOH and (SiH3)2O have pπ–dπ back bonding

47) IE1 : Cr < Mn < Fe

IE2 : Mn < Fe < Cr
IE3 : Fe < Cr < Mn
Among 3d elements
IE1 is maximum Zn
IE2 is maximum for Cu
IE3 is maximum for Zn
size : Zn < Cd ≃ Hg

48)

ΔTf = i Kpm

2=

960 – w = 3 × (500)
960 = 16w
w = 60 gm

49)
By retardation through 19 volts the original accelerating voltage is reduced to 81 volts.

By further retardation through 32 volts.

50)

Question is Asking About :-

Match the column (List-I with List-II)

Concept :-

(A)

(C)
→ sp3
→ No Back Bonding
→ e⊝ deficient i.e. combines with lewis base

(D)
→B←F
2Pπ–2Pπ Back Bonding
→ B has vacant orbital (sp2 - hybridised). Therefore, combines with lewis base.

51) The correct match :

Finkelstein reaction → NaI/acetone
Swart reaction → SbF3
Darzen's halogenation reaction → SOCl2
Lucas test → HCl + Anhy. ZnCl2