07-12-2025

1015CMD303053250060 MD

CHEMISTRY

1) Given the following reaction and equilibrium constant :

CO(g) + O2(g) ⇌ CO2(g), KC = 1.1 × 1011

So at equilibrium, select the correct response from below :-

The net driving force for the reaction will always be left to right because the equilibrium
(1)
constant is very large.
The rate of forward reaction will always be greater than the rate of the reverse reaction
(2)
because the equilibrium constant is so large
For a reaction mixture containing equilibrium concentrations of the three components, the
(3)
forward and reverse rates will both go to zero
(4) All responses above are incorrect

2) Four vessels of 10 L each A, B, C and D contain 16 g CH4, 18 g of H2O(ℓ), 71 g of Cl2 and 44 g of

CO2 respectively. Which has different active mass ?

(1) A
(2) B
(3) C
(4) D

3) K for a reaction is 300. If the volume of reaction flask is trippled, the equilibrium constant is :

(1) 300
(2) 600
(3) 900
(4) 100

4) For the reaction A + B C + D the initial concentration of A and B were taken as 0.9 mole dm–3.
At equilibrium the concentration of D was found to be 0.6 mol dm–3. The value of equilibrium
constant will be :

(1) 9
(2) 3
(3) 8
(4) 4

5) For a reaction; , the initial concentration of A and B are equal but the equilibrium
concentration of C is twice that of equilibrium concentration of A. The Kc is :

(1) 4
(2) 9
(3) 1/4
(4) 1/9

6) 1.1 mole of A are mixed with 2.2 moles of B and the mixture is kept in a 1 L vessel till the
equilibrium is established in the reaction. If the molar conc. of C at the equilibrium point is 0.2 M
then the value of equilibrium constant for the reaction
A + 2B 2C + D is –

(1) 0.001
(2) 0.002
(3) 0.003
(4) 0.004

7) The equilibrium constant (Kc) for the reaction SO2(g) + NO2(g) SO3(g) + NO(g) is 16. If initially
3
1 mole of each of all the four gases is taken in 1 dm vessel, the equilibrium concentration of NO
would be :-

(1) 0.4 M
(2) 0.6 M
(3) 1.4 M
(4) 1.6 M

8) For the reaction C(s) + CO2(g) ⇋ 2CO (g), at 1123°C, the equilibrium mole percent of CO2(g) is
60%. If the total pressure is 1.00 atm, the value of Kp for the reaction is

(1) 4/15
(2) 1/15
(3) 2/15
(4) 8/15

9) NaHCO3 decomposes as :
2NaHCO3(s) ⇌ Na2CO3(s) + CO2(g) + H2O(g)
The equilibrium pressure is 1.04 atm. The KP for the reaction is :

(1) 0.2704 atm2

(2) 2.704 atm2
(3) 27.04 atm2
(4) 270.4 atm2

10) For which of the following reaction the relationship log – 2 log RT = 0 will be correct

(1) 2A(g) B(g) + 2C(g)

(2) 2A(g) + B(s) C(g) + D(g)
(3) 2A(g) B(g) + 3C(g)
(4) A(g) + 2B(g) 3C(g)

11) For which of the following equilibrium Kc > Kp

(1) 2NO(g) N2(g) + O2(g)

(2) SO2(g) + NO2(g) SO3(g) + NO(g)
(3) A(g) + 3B(g) 4C(g) + 5D(g)
(4) PCl3(g) + Cl2(g) PCl5(g)

12) For the reaction, 2SO2(g) + O2(g) ⇌ 2SO3(g) the value of Kp is 2.5 × 1010 atm–1 at 500 K, Kc value
for the reaction at same temperature is ________ × 1010.

(1) 205
(2) 51.25
(3) 78
(4) 102.5

13)

At 527°C, the reaction given below has KC = 4

NH3(g) ⇌ N2(g) + H2(g)

What is the Kp for the reaction ?

N2(g) + 3H2(g) ⇌ 2NH3(g)
(1) 16 × (800 R)2

(2)

(3)

(4) None of these

14) Which is most stable oxide :-

(1) 2NO2 N2 + 2O2 K = 6.7 × 1016

(2) N2O2 N2 + O2 K = 2.2 × 1030
(3) 2N2O3 2N2 + 3O2 K = 1.2 × 1034
(4) 2N2O 2N2 + O2 K = 3.5 × 1033

15) In which of the following reaction reactant is more stable :-

–2
(1) SO2Cl2(g) ⇌ SO2(g) + Cl2(g) ; K = 2.3 × 10
(2) SO2 + NO2(g) ⇌ SO3(g) + NO(g) ; K = 294
2
(3) CH3OH(g) ⇌ CO(g) + 2H2(g) ; K = 2 × 10
(4)
XeO + O2 ⇌ XeO2F2; K = 1.4 × 10–3

16) A schematic plot of ln Keq verses inverse of temperature for a reaction is shown below. The

reaction must be

(1) endothermic
(2) exothermic
(3) highly spontaneous at ordinary temperature
(4) one with negligible enthalpy change

17) Assertion :– The value of equilibrium constant (K) increases when concentration of the
reactants are increased.
Reason :– On increasing concentration of gaseous reactants, the equilibrium shifts in forward
direction.

(1) Both assertion and reason are true and reason is correct explanation of assertion.
(2) Both assertion and reason are true but reason is not a correct explanation of assertion.
(3) Assertion is true but reason is false.
(4) Assertion is false but reason is true.

18) Consider the following equilibria at 300 K and 400K with their equilibria at 300K and 400 K with
their equilibrium constants -

300K 400K

X : A(g) 2B(g) ; Keq = 10 Keq = 5

Y : C(g) D(g); Keq = 2 Keq = 5

Thus,
(1) X is endothermic, Y is exothermic
(2) X is exothermic, Y is endothermic
(3) X and Y both are endothermic
(4) X and Y both are exothermic

19) The equilibrium constant (Kc) for the reaction, N2(g) + O2(g) 2NO(g) at temp T is 4 × 10–4 . The
value of Kc for the reaction,

NO(g) N2(g) + O2(g) at the same temperature is :-

(1) 0.02
(2) 2.5 × 102
(3) 4 × 10–4
(4) 50.0

20)

......(1)

......(2)
above equilibrium are established in a rigid container at constant temp if CO2 is added from out side
at equilibrium then

(1) will increase

(2) will decrease
(3) forward shift in 2nd equilibrium
(4) Backward shift in 1st equilibrium

21) 2 mole N2 are mixed with 6 mole H2 in a closed vessel of 1 L capacity. If 50%. N2 is converted
into NH3 at equillibrium. The value of Kc for the reaction N2(g) + 3H2(g) ⇌ 2NH3(g) is-

(1)

(2)

(3)

(4) 24

22) Calculate the per cent dissociation of H2S(g) if 0.1 mole of H2S is kept in 0.4 litre vessel at 1000K.
For the reaction ⇌ the value of KC is 1.0 × 10–6.

(1) 4 %
(2) 2 %
(3) 1 %
(4) 3.5 %

23) For the gas phase reaction;

ΔH = – 32.7 kcal carried out in a closed vessel, the number of equilibrium moles of C2H4 can be
increased by :

(1) Increasing temperature

(2) Decreasing pressure
(3) Removing some amount of H2
(4) All of these

24) CH4(g) + 2O2(g) CO2(g) + 2H2O(ℓ),

ΔrH = –170.8 kJ mol–1
Which of the following statements is not true?

(1) At equilibrium the moles of CO2(g) and H2O(ℓ) are not equal
The equilibrium constant for the reaction is given by Kp =
(2)

(3) Addition of CH4(g) or O2(g) at equilibrium will cause a shift to the right
(4) The reaction is exothermic

25)

Which of the following gaseous reaction will be favoured forward at low pressure :-

(1) N2 + O2 2NO
(2) H2 + I2 2HI
(3) PCl5 PCl3 + Cl2
(4) N2 + 3H2 2NH3

26)

Column-I Column-II

Pressure increased in Equilibrium shifted in

(A) (P)
2NO(g) ⇌ X2(g) + O2(g) forward direction

Pressure increased in Equilibrium shifted in

(B) (Q)
CH4(g) + H2O ⇌ CO(g) + 3H2(g) backward direction

Temp. increased and pressure

Equilibrium remains
(C) increased (R)
unaffected
3O2(g) ⇌ 2O3 (g) ΔH = 285 kJ

Pressure decreased and moles of N2(g)

Theoritically we can not
(D) increased (S)
predict
N2(g) + 2O2(g) ⇌ 2NO2(g) ; ΔH = 66 kJ
(1) A→R, B→Q, C→P, D→S
(2) A→S, B→R, C→Q, D→P
(3) A→R, B→P, C→Q, D→S
(4) A→P, B→Q, C→R, D→S

27) Statement-1 : Melting of Ice is favoured by High pressure.

Statement-2 : Intermolecular hydrogen bond is present between water molecules.

(1) Statement-1 & Statement-2 both are correct.

(2) Statement-1 & statement-2 are incorrect.
(3) Statement-1 is true but statement-2 is false.
(4) Statement-1 is false but statement-2 is true.

28) For a reversible reaction aA + bB cC + dD ; the variation of K with temperature is given by

log then,

(1) K2 > K1 if T2 > T1 for an endothermic change

(2) K2 < K1 if T2 > T1 for an endothermic change
(3) K2 > K1 if T2 > T1 for an exothermic change
(4) All are correct

29)

Calculate Kp if equilibrium pressure is 8 atm and ,

(1) 1/4
(2) 1
(3) 4
(4) 1/8

30) A(g) ⇌ B(g) + D(g) if initial pressure is 4 atm and total pressure at equilibrium is 5 atm, then
what is percent dissociation of A.

(1) 30%
(2) 40%
(3) 50%
(4) 80%

31) In the following reaction : 2NO(g) + Cl2(g) ⇌ 2NOCl(g) It is observed that equilibrium is not
attained and the rate of forward reaction is greater than rate of backward reaction. Which of the
following is true for the reaction ?

(1) Kp = Qp
(2) Qp > Kp
(3) Qp < Kp
(4)

32) Match the column :

Column-I Column-II

(a) QC < KC (i) net reaction goes from left to right

(b) QC > KC (ii) Net reaction goes from right to left

(c) QC = KC (iii) Reaction is at equilibrium

ΔH =
(d) (iv) Endothermic reaction
+ve
Correct answer is :-
(1) a-i, b-ii, c-iii, d-iv
(2) a-ii, b-i, c-iii, d-iv
(3) a-i, b-ii, c-iv, d-iii
(4) a-iv, b-iii, c-ii, d-i

33) For a reaction 2NO2 + , if equilibrium constant is kp, then kp for this reaction 2N2O5
4NO2 + O2 will be:-

2
(1) kp

(2)

(3)

(4)

34) Equal moles of H2 and I2 are heated in a closed vessel till equilibrium is obtained. If 80% of the
hydrogen is converted to HI, the Kc at this temperature is (H2 + I2 ⇌ 2HI)

(1) 64
(2) 16
(3) 0.25
(4) 14

35) For gaseous homogeneous equilibrium

A(g) + 2B(g) 3C(g) + D(g)

When 4 moles of A and 7 moles of B was taken in a container of volume 2L. At equilibrium = 2,
then concentration of C at equilibrium will be:-

(1) 2 M
(2) 3 M
(3) 6 M
(4) 14 M

36) For the reaction N2O3 ⇌ NO + NO2, at constant temperature and at 5 atm pressure, Kp is found to
be 4. Calculate degree of dissociation of N2O3.

(1) 1/3
(2) 2/3
(3) 7/9
(4) 1/2

37)
Select correct matching of column-I with column-II.
(Initial mole of all the reactant is taken as one)

Column-II
Column-I (If α is
(Reaction) negligiable w.r.t.
1, V = 1 litre)

(P) 2X(g) Y(g) + Z(g) (1) α=2×

(Q) X(g) Y(g) + Z(g) (2) α=3×

(R) 3X(g) Y(g) + Z(g) (3) α = (2Kc)1/3

(S) 2X(g) Y(g) + 2Z(g) (4) α=

P Q R S

(1) 4 1 3 2

(2) 1 4 3 2

(3) 1 4 2 3

(4) 2 3 1 4
(1) 1
(2) 2
(3) 3
(4) 4

38) A equimolar mixture of PCl3(g) and Cl2(g) at 10 atm pressure undergoes 20% change into
product till equilibrium. Calculate the total pressure of equilibrium mixture.

(1) 90 atm
(2) 9 atm
(3) 80 atm
(4) 20 atm

39) For the reaction

H2(g) + CO2(g) ⇌ CO(g) + H2O(g),
if the initial concentration of [H2] = [CO2] and x moles litre–1 of hydrogen is consumed at equilibrium,
the correct expression of KP is :-

(1)

(2)

(3)
(4)

40) For the reaction, 2X(g) ⇌ Y(g) + 3Z(g), KC = 16 what must be the volume of the flask, if a mixture
of 2 mole each of X, Y and Z exist in equilibrium ?

(1) 1 L

(2)

(3)

(4) 2L

41) For the reaction 2CO2 ⇌ 2CO + O2, the dissociation of 2 moles of CO2 is carried out in container
with volume 5L, if at equilibrium 60% CO2 is dissociated, then total number of moles at equilibrium
will be :-

(1) 2.3
(2) 2.6
(3) 0.52
(4) 3.2

42) The reaction for which Kc = 2.3 × 103 moles/litre is -

(1) 2SO2(g) + O2(g) ⇌ 2SO3(g)

(2) N2(g) + 3H2(g) ⇌ 2NH3(g)
(3) N2(g) + O2(g) ⇌ 2NO(g)
(4) PCl5(g) ⇌ PCl3(g) + Cl2(g)

43) For an elementary reaction, the rate constants for forward and reverse reactions are 0.50 and 5
× 104 respectively. The equilibrium constant for the reaction would be :-

(1) 2.5 × 103

(2) 2.5 × 104
(3) 1 × 10–5
(4) 1 × 105

44) PCl5 PCl3 + Cl2

In above reaction if volume increase by 16 time, degree of dissociation change will be-

(1) 4 time

(2)
time
(3) 2 time

(4)
time
45) In a reaction, PCl5(g) PCl3(g) + Cl2(g), degree of dissociation is 30%. If initial moles of PCl5(g) is 1,
then total moles at equilibrium is :-

(1) 1.3
(2) 0.7
(3) 1.6
(4) 1.0
 ANSWER KEYS

CHEMISTRY

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 4 2 1 4 1 1 4 1 1 3 4 4 3 1 4 2 4 2 4 4
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. 1 2 4 2 3 1 1 1 2 3 3 1 3 1 2 2 3 2 1 3
Q. 41 42 43 44 45
A. 2 4 3 1 1
 SOLUTIONS

CHEMISTRY

1)

Since KC is very large.

So reaction goes for competition.

2) [CH4] = = 0.1 M
[H2O] = 1 (Liquid)

[Cl2] = = 0.1 M

[CO2] = = 0.1 M

3)

Explanation

A. The equilibrium constant (K) for a reaction depends only on temperature. It is independent
of changes in concentration, pressure, volume, or the presence of a catalyst.

Answer option 1,(300).

4) Initial concentration:

A. [A]0 = 0.9 mol dm–3

B. [B]0 = 0.9 mol dm–3

A. At equilibrium:
A. [D] = 0.6 mol dm–3
B. Since the reaction is 1 : 1 : 1 : 1, the concentration of C at equilibrium is also 0.6 mol
dm–3.
C. So. equilibrium concentration:
A. [A] = 0.9 – 0.6 = 0.3 mol dm–3
B. [B] = 0.9 – 0.6 = 0.3 mol dm–3

Concept:
The equilibrium constant expression for the reaction:

Final Answer = 4
Hence, option (4) is correct.

5) A + B C+D
t=0 1 1 – –
teq 1–x 1–x x x
At equilibrium : [C] = 2[A]
x = 2 (1 – x) = 2 – 2x
3x = 2

x=

1–x=1– =

KC = 4
Final answer : 1

6)

A B C D

Initial (I) 1.1M 2.2M 0M 0M

Equilibrium(E) 1.1–x 2.2–2x 0+2x 0+x

A. From
B. Then:
C. [A] = 1.1 - 0.1 = 1.0 M
D. [B] = 2.2 - 0.2 = 2.0 M
E. [D] = x = 0.1 M

Solution of Kc:

Kc =

Kc =

Kc =
Kc = 0.001
Final Answer: (1)

7)

SO2 + NO2 ⇌ SO3 + NO

Initial 1mol 1 mol 1 mol 1 mol
At 1–x 1–x 1+x 1+x
equilibrium
[NO] at equilibrium =

8) = 0.6 atm, pCO = 0.4 atm

∴ Kp =

9) 2NaHCO3(s) ⇌ Na2CO3(s) + CO2(g) + H2O (g)

t=0 0 atm
t = eq 0 0

2p = 1.04 P = 0.52 atm

Kp = .
KP = 0.52 × 0.52 = 0.2704

10) Solution:
Kp = Kc (RT) Δn
Taking log, log(Kp / Kc) = Δn log RT.
Given: log(Kp / Kc) – 2 log RT = 0 → Δn = 2.
For each reaction, find Δn —
(1) 2A(g) ⇌ B(g) + 2C(g) → Δn = (1 + 2) – 2 = 1
(2) 2A(g) + B(s) ⇌ C(g) + D(g) → Δn = (1 + 1) – 2 = 0
(3) 2A(g) ⇌ B(g) + 3C(g) → Δn = (1 + 3) – 2 = 2
(4) A(g) + 2B(g) ⇌ 3C(g) → Δn = 3 – 3 = 0
Final Answer: Option (3)

11)

1. Determine When Kc > Kp

(From Kp = Kc (RT)Δn)

A. For Kc to be greater than Kp, the term (RT)(Δn) must be less than 1.

B. This occurs when Δn is negative (i.e., there are fewer moles of gaseous products than
gaseous reactants).

2. Analyze the Given Reactions:

A. (1) 2NO(g) ⇌ N2(g) + O2(g)

A. Δn = (1 + 1) - 2 = 0
 B. Kp = Kc

B. (2) SO2(g) + NO2(g) ⇌ SO3(g) + NO(g)

A. Δn = (1 + 1) - (1 + 1) = 0

B. Kp = Kc

C. (3) A(g) + 3B(g) ⇌ 4C(g) + 5D(g)

A. Δn = (4 + 5) - (1 + 3) = 5

B. Kp > Kc

D. (4) PCl3(g) + Cl2(g) ⇌ PCl5(g)

A. Δn = 1 - (1 + 1) = -1

B. Kc > Kp

12) Reaction:

= 1.026 × 1012
= 102.6 × 1010
102.5 × 1010
Final Answer : option (4)

13) Explanation:

Reaction: NH3(g) ⇌ N2(g) + H2(g) KC = 4

Reverse reaction: N2(g) + 3H2(g) ⇌ 2 NH3(g) KC'
Solution:
The relation between Kp and Kc is given by:

KC' =
∴

KP =
Answer is option (3).

14)

Explain Question : Compare given equilibrium constants for oxide → elements reaction to
determine most stable oxide.

Concept : This question is based on Stability of reactant ∝ 1/K(c)

Solution :
Given K values:
Option 1: K = 6.7 × 1016
Option 2: K = 2.2 × 1030
Option 3: K = 1.2 × 1034
Option 4: K = 3.5 × 1033
Smallest K = 6.7 × 1016 → highest stability.

Final Answer : option (1)

15) Stability of reactants increases when value of K decreases.

16)
⇒ ΔH = –ve ⇒ Exothermic reaction

17) Solution :
Assertion :- False, because Keq does not depend on concentration.
Reason :- True
∵ At equilibrium ⇒ [reactant] ↑ ⇒ reaction shifts in forward direction.
Final Answer : 4

18) For endothermic, Temperature Keq

For exothermic, Temperature Keq ↓

19) Given:
Original reaction:
N2 +O2 2NO with Kc = 4 ×10-4
Target reaction:
NO 1/2 N2 + 1/2 O2
This is the reverse of the original reaction, and also the stoichiometry is halved
Explanation :
Rules for modifying equilibrium constants:
• Reversing a reaction take reciprocal of Kc
• Multiplying the reaction by a factor (e.g.. %) raise Kc to the power of that factor
So:
• Reverse: Kc becomes 1 / (4 × 10– 4) = 2.5 × 103
• Then take square root (because of 1/2):

Answer
4. 50.0
The value of Kc for the given reaction is 50.0

20)

on addition of CO2 2nd equilibrium shift in forward direction and equilibrium 1st will shift in
backward direction.

21) Solution : N2 (g) + 3H2 (g) ⇋ 2 NH3 (g)

t=0 2 6 –
teq 2 – x 6 – 3x 2x

(%α)N2 = 50 ⇒

KC =
Final answer = 1

22) Solution :
The correct option is A 2%
2H2S(g) = 2H2(g) + S2(g)
(Initially) 0.1 0 0

(At equilibrium) 0.1-x x

Since x is small because KC = 10–6

So
0.1 – 2x = 0.1
Since, 'x' is small because KC =

∴ or,
This is degree of dissociation for 0.1 mol
∴ Degree of dissociation for 1 mol = 10 x (2x )=2x
Hence, % dissociation = 2 x x 100 = 2
Final Answer: option (2)

23)

Solution
Reaction: (exothermic)
• Increasing temperature → shifts equilibrium backward (more )
• Decreasing pressure → increases total moles (shifts backward)
• Removing shifts backward to form more reactants

All these actions shift equilibrium backward, increasing moles.

Final Answer
Option (4)

24)

Question Explanation:
We are given a combustion equilibrium of methane and asked which statement is not true.
Concept:

A. For equilibrium expressions, pure liquids (like H₂O(ℓ)) are excluded from Kp or Kc.

B. The reaction is exothermic (ΔH < 0).

C. Adding reactants (CH₄ or O₂) shifts equilibrium to the right (Le Chatelier’s principle).

D. Concentrations of CO₂ and H₂O need not be equal.

Solution:
Let’s write equilibrium constant expression correctly:

Final Answer: option (2)

25)

Solution:
(1) N2 + O2 2NO → 2 moles → 2 moles → no change
(2) H2 + I2 2HI → 2 → 2 no change
(3) PCl5 PCl3 + Cl2 → 1 → 2 moles → forward favored at low P
(4) N2 + 3H2 2NH3 → 4 → 2 → backward favored at low P
Final answer: option (3)

When pressure decreases reaction moves towards more number of moles.

26) On increasing P, Eq shifts towards lesser No. of moles & for Endothermic reaction, T↑,
Keq ↑ forward shift.

27) It is due to intermolecular H-bonding.

(यह अतरआिवक H-बधन के कारण हे ।)

28)

For endothermic reaction as T ↑ K ↑

29)

30)

pi 4 0 0
peq 4–x x x

⇒x=2

% dissociation = 0.5 × 100 = 50%

31) When Qp < Kp, the rate of forward reaction is more than rate of backward reaction.

32) NCERT Pg. # 206

33)

2NO2 + O2 N2O5 ; kp
So 4NO2 + O2 2N2O5 ;

So 2N2O5 4NO2 + O2;

34)

H2 + I2 2 HI
ni 1 1 0
neq 0.2 0.2 1.6

Kc =

35) Explain the question : We need to find equilibrium concentration of C if initial moles of A

and B and volume, at equilibrium are given.

Concept : This question is based on equilibrium concentration.
Solution :
A(g) + 2B(g) ⇌ 3C(g) + D(g)
t=0 4 7
(mole)
t=teq 4–x 7–2x 3x x
(mole)

⇒x=2

Final answer : option (2)

36)

N2O3 ⇌ NO + NO2
initially 1 0 0
At eqn 1–x x x
total moles at equilibrium = 1 + x

or

∴
⇒ 4 – 4x2 = 5x2
⇒ 9x2 = 4
⇒ x = 2/3

37) (P) 2X Y + Z

1–α

KC = ⇒ 1 – α ....(1)
(Q) X Y + Z
1–α α α

KC =
(R) 3X Y + Z

1–α

KC =

(S) 2X Y + 2Z

1–α α

KC =

KC = (2KC)1/3 = α

38)

A: Question Explanation
Find total pressure at equilibrium for PCl₃(g) + Cl₂(g) ⇌ PCl₅(g) when an equimolar mixture at
10 atm undergoes 20% conversion to product.

B: Concept
Partial-pressure change using percent conversion (degree of dissociation).

C: SOLUTION

Given: total initial P = 10 atm, equimolar of each so initial pressure is same i-e P₀(PCl₃) = P₀(Cl₂) =
5.0 atm
20% conversion ⇒ each reactant decreases by 20% of 5 atm = 1.0 atm.
PCl3(g) + Cl2(g) ⇌ PCl5(g)

t=0 5 atm 5atm 0atm

t=Eq 4atm 4atm 1atm

P total = 4 + 4 + 1 = 9 atm

D: Final Answer → Option 2

39) Explain the Question : We need to find value of KP for given reaction if initial
concentration and consumed concentration of reactants are given.
Concept : This question is based on relation between KP and KC.
Solution :
H2(g) + CO2(g) ⇌ CO(g) + H2O(g)
Δng = 0, KP = KC
H2(g) + CO2(g) ⇌ CO(g) + H2(g)
t=0 1 1 – –
teq 1–x 1–x x x

Final Answer : 1

40) 2X(g) ⇌ Y(g) + 3Z(g)

At eq. 2 2 2

16 =

41)

2CO2 ⇌ 2CO + O2
2 0 0
2–2x 2x x
2 – (2 × 0.6) 2 × 0.6 0.6
0.8 1.2 0.6

∝= ⇒∝=x=
x = 0.6
Moles at equilibrium = 0.8 + 1.2 + 0.6 = 2.6

42) The unit of kc is mol L–1 which is only

possible for the reaction
PCl5(g) ⇌ PCl3(g) + Cl2(g)

Unit → mol L–1

43)
44)

45) Explain the question : We need to find number of total moles at equilibrium for given
reaction if %α and initial moles of PCl5 is given.
Concept : This question is based on degree of dissociation.
Solution :
PCl5 PCl3 + Cl2
t=0 1 – –
teq 1–x x x

%∝ = 30% ⇒ ⇒ x = 0.3
Total moles at equilibrium = 1 – x + x + x
= 1 + x = 1 + 0.3
Total moles at equilibrium = 1.3
Final answer : option (1)