01-06-2025

2401CJA101021250010 JA

PART-1 : PHYSICS

SECTION - I (i)

1) A large cubical vessel contains two immiscible liquid of density 2ρ0 and 3ρ0. A solid sphere of

0 0
volume V , radius H/10 and density ρ is tied to one end of a string of length and other end
tied to the bottom of the vessel at centre of the base of the container as shown in the figure. The
sphere is immersed with half of its volume in the liquid of higher density and remaining in the liquid

of lower density. The entire system starts acceleration toward right side with an acceleration .

Then which of the following is/are correct.

(A) The angle made by the string with the horizontal is 37°
(B) The solid sphere moves towards right with respect to the vessel

(C)
The tension in the string in the equilibrium is

(D)
The tension in the string in the equilibrium is

2) A narrow parallel beam of light coming from a distance object is incident on an equilateral
triangular prism of refractive index with its base BC along the x-axis. A concave mirror of
radius of curvature 30 cm is placed at a distance of 50 cm from the point C of the triangular prism.
The principal axis of the mirror is inclined at angle of 15° with x-axis as shown in the diagram. Mark

the correct option(s). Assume paraxial object is valid.

(A) Deviation in the beam of light after emerging from the prism is 30°
(B) Final image formed after reflection from mirror is real, inverted and diminished.

(C)
Y-coordinate of the final image formed after reflection from mirror is
(D) Ray undergoes minimum deviation after passing through the prism
3) Which of the following options is/are CORRECT regarding the below diagram.

(A) I1 = 8 Amp
(B) I2 = Amp
(C) I1 = 0
(D) I3 = 8 Amp

4) If the law of gravity were inverse law instead of inverse square law, considering two satellites of
same mass but in orbits of radii "r" and "2r" around the earth.

(A) The ratio of speeds of two satellites in would be 1 : 1

(B) The ratio of angular speeds of these two satellites would be 2 : 1
(C) The ratio of the potential energy of these two satellites would be 1 : 2
(D) The ratio of kinetic energies of these two satellites would be 2 : 1

5) Volt-ampere (V-I) characteristic of a non-linear device D and corresponding circuit used are
shown in the adjoining figures. Voltage VB of the battery is made to vary from zero to 30 V and
voltage V1 across the device D, voltage V2 across the 10Ω resistor and current I supplied by the
battery are measured by ideal voltmeters V1 and V2 and an ideal ammeter A. Which of the following

graph/graphs represent correct relationship ?

(A)

(B)

(C)

(D)

6) 'A' is huge planet with uniform mass distribution, mass M, radius R. B is a circular tunnel made in

it, concentric with planet. Radius of tunnel is r, cross sectional diameter is d(d << r). C is a
small ball of mass m (m << M) which is moving freely inside the tunnel without friction in a uniform

circular motion, take acceleration due to gravity on surface of A as g :

 If contact force on C is double the gravitational force, its time period =
(A)

If contact force on C is double the gravitational force, its time period =

(B)

(C) If contact force is zero, time period T (radius of tunnel r), then T ∝ r
(D) If contact force is zero, time period T (radius of tunnel r), then T would be independent of r.

SECTION - I(ii)

Common Content for Question No. 1 to 2

A cylinder of mass M and radius R lies on a plank of mass of M as shown. The surface between plank
and ground is smooth, and between cylinder and plank is rough. Assuming no slipping between
cylinder and plank, and velocity amplitude of oscillation of plank V.

1) Time period of oscillation of the set up when displaced from equilibrium is :

(A)

(B)

(C)

(D)

2) Friction between plank and cylinder when acceleration is maximum is :

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

Consider a system of 5 large conducting plates seprated by distance d as shown :
 Each plate is given charge as shown. A uniform electric
field is switched on at t = 0 which has effect through out given region. The charge

distribution on the surface at plate get changed because of this electric field. [Given, ,
where A is surface area of each conducting plate]. Initially switch S1 is opened.

3) The charge on surface b when system reaches the steady state, is :

(A)

(B)

(C)

(D)

4) Now switch S1 is closed. is still present. The system again achieves steady state. The potential
difference between plate 1 and plate 5 is :

(A)

(B)

(C)

(D)

SECTION - II

1) A frustum is cut from a right circular cone. The two circular faces have radii R and 2R and their
centers are at O1 and O2 respectively. Height of the frustum is h = 3R. When a point charge Q is
placed at O1, the flux of electric field through the circular face of radius 2R is ϕ1 and when the

charge Q is placed at O2, the flux through the other circular face is ϕ2. The ratio of is found to
be . The value of (a + b) is : (a and b are minimum possible natural integer)

2) A soap bubble of radius r and surface tension T is formed in vacuum. It is slowly sprayed with
some amount of charge, as a result of which it slowly expands and finally stops expanding when

radius becomes 2r. If the amount of charge given to the bubble is , then find N.
(assume temperature of the gas to be constant during expansion)

3) Consider two spheres of the same radius R having uniformly distributed volume charge density of
same magnitude but opposite sign (+ρ and –ρ). The spheres overlap such that the vector joining the
centre of the negative sphere to that of the positive sphere is . The magnitude of electric
field at a point outside the spheres at a distance r in a direction making on angle θ with is found to

be . The value of (a + b) is (Distance r is measured with respect to the

mid point of the line joining the centers of the two spheres).

4) A rocket is launched from a pole of the Earth with velocity V0, where V0 is the orbital velocity of
rotation near the surface of the Earth, in such a way that it lands at the equator. The rocket's time of

flight is . Where R→ Radius of earth, g→ acc. due to gravity at the surface. Find
value of K.

5) Two identical small elastic conducting balls each of mass m and radius r have charges of opposite
signs 3Q and –Q. Initially they are held in free space with their centres at separation 8r and then
released. Ignore non-uniformity in charge distribution when ball come close to each other, magnetic
field produced by motion of charges and the gravitational interaction between them. Their speeds v

long after collision is . Find 'α'.

6) Four ammeters with identical internal resistances r and a resistor of resistance R are connected
to a current source as shown in figure. It is known that the reading of the ammeter A1 is I1 = 3A and
the reading of the ammeter A2 is I2 = 5A. Determine the ratio of the resistances R/r.
7) In the circuit shown find the value of current I (in A).

8) All the wires on the front and the back hexagonal face (of the skelton hexagonal prism) have
resistance R. All the wires along the lines joining the vertices of two hexagons have resistance R.

Take . The equivalent resistance between P and Q as shown in the figure is .....Ω.

PART-2 : CHEMISTRY

SECTION - I (i)

1) Suppose that the volume of a certain ideal gas is to be doubled by one of the following processes :
(A) isothermal expansion
(B) adiabatic expansion
(C) free expansion in insulated condition
(D) expansion at constant pressure
If E1,E2,E3 and E4 respectively are the changes in average kinetic energy of the molecules for the
above four processes, then-

(A) E2 = E3
(B) E1 = E3
(C) E1 > E4
(D) E4 > E3

2) At 27°C, the osmotic pressure of a non-volatile non-electrolyte solute is 47.7 mm Hg. The solution
is diluted and heated upto 127°C, when the osmotic pressure becomes 19 mm Hg. Then

(A) Molality of solution becomes half

(B) Number of milli moles of solute remains same
(C) Extent of dilution of solution is 3.35 times
(D) Relative lowering in vapour pressure reduces

3) 1 mole of an ideal monoatomic gas undergoes given thermodynamic processes as shown :

Which of the following options is/are correct ?

(A) Heat released by the gas is –P0V0

(B) Net work done by the gas is P0V0
(C) |ΔUBC| = |ΔUCA| + |ΔUAB|
Maximum temperature obtained in whole process is
(D)

4) What is/are the product of reaction?

Product / s

(A)

(B)
(C)

(D)

5) Identify reactions correctly matched with their major products ?

(A)

(B)
Me—C≡CH

(C)
Me—C≡CH

(D)

6) In which of the following reactions, diastereomers will be formed ?

(A)

(B)

(C)
(D)

SECTION - I(ii)

Common Content for Question No. 1 to 2

A cylindrical container of volume 44.8 litres is containing equal no. of moles (in integer no.) of an
ideal monoatomic gas in two sections A and B separated by an adiabatic frictionless piston as shown
in figure. The initial temperature and pressure of gas in both section is 27.3K and 1 atm. Now gas in
section ‘A’ is slowly heated till the volume of section B becomes (1/8)th of initial volume.

Given : R = 2

cal/mol-K, Cv,m of monoatomic gas = R,

At 1 atm & 0°C ideal gas occupy 22.4 litre.

1) Final temperature in container A will be

(A) 1638 K
(B) 6988 K
(C) 3274 K
(D) 51 K

2) Change in enthalpy for section A in Kcal

(A) 48.3
(B) 80.53
(C) 4.83
(D) 8.05

Common Content for Question No. 3 to 4

The four alkenes a, b, c and d are the open chain isomers of each other having molecular formula
C4H8. The order of heat of combustion (HOC) of the four isomeric alkenes is : b > c > a > d.
Based on above facts answer the following.

3) Which of the alkene gives meso product on reaction with Br2/CCl4 :

(A) a
(B) b
(C) c
(D) d

4) Which of the following is most reactive towards HBr addition :

(A) a
(B) b
(C) c
(D) d

SECTION - II

1) One mole of an ideal gas at 500 K follows path A → B (Reversible isothermal) and
then B → C (Reversible adiabatic) as shown in graph. What will be the volume of gas (in litre) at
point C?

[Given R = 0.08 L atm mol–1 K–1, 23/5 = 1.52]

2) A gaseous mixture of H2 and He in the mass ratio 1 : 4 is successively effused through a series of
containers connected through narrow tubes of negligible volume and fitted with valves. The valves
are successively opened for a very small time interval, dt. Find the minimum number of total
containers required to obtain a molar ratio 8 : 1 for H2 and He after the effusion process.

3) In He+, electron is initially present in an orbital having no radial nodes but in which the sign of
wave function changes once across a plane. On absorbing photon having energy which is 75% of
ground state energy of hydrogen, the electron moves to higher orbital. Find the sum of principal
quantum numbers of initial and final orbital of electron.

4) A real gas obeys the equation P(Vm – b) = RT, where (b = 0.1 L/mol), if 2 moles of gas is slowly
compressed from 1.2 litre to 0.6 litre at constant temperature of 300 K. Find work done in the

process. (in kJ) (given : )

5) The number of substrates which neither show SN1 nor SN2.

6) How many ring expansion does the given carbocation undergo to form most stable final

carbocation (containing no π bond)

7)

Which of the following compound decolorise Br2/H2O ?

(i) (ii)

(iii) (iv)

(v) (vi) But -2-ene

(vii) (viii)
(ix) But-2-yne (x) CH2= CH–CH = CH2

8) (i) (ii) (iii) (iv) CH3–F

(v) (vi) (vii)

X = Number of compound can give Racemic product on SN1 hydrolysis reaction.

Y = Number of compound(s) can not give SN1 reaction.
Find X + Y = ?

PART-3 : MATHEMATICS

SECTION - I (i)

1) If the tangent drawn to the curve f(x) = –e–x(x2 + 2x + 2) + x at (α, f(α)) meets the curve again at
two distinct points and the range of α is (a, b) then the value of (a + b) is :

(A) 1
(B) 2
(C) 4
(D) 5

2) Let f : R→R be a continuous function and let . If g(x) < 0, x belongs to R

and g(0) = 0, then the value of f{g(ln 5)} + g{f(ln 5)} is equal to :

(A) 0
(B) 1
(C) 5
(D) 10

3) Let f be derivable function such that ; . If f′(0) = –1 and f(0)

= 1, then :

(A) 2f–1(x) = f(x)

(B) f–1(x) = 2f(x)
(C) f–1(x) = –f(x)
(D) f–1(x) = f(x)

4) Let . If the line y = x is tangent at infinity to the curve y = f(x)

then which of the following is/are true ?
(A) m = 6n
(B) m2 + n2 = 148
(C) m + n = 14
(D) |m – n| = 10

5) In triangle ABC, if 2b = a + c and A – C = 90°, then sin B equals :

(A)

(B)

(C)

(D)

6) The value(s) of x satisfying the equation is/are :

(A)
(B)
(C)
(D)

SECTION - I(ii)

Common Content for Question No. 1 to 2

A differentiable function satisfy the relation ℓn(f(x + y)) = ℓn(f(x)) . ℓn(f(y)) , f(0) ≠ 1, f′(0)
= e and g be the inverse of f.

1) The value of g′′(e) is equal to :

(A)

(B)

(C) –2e2

(D)

2) The number of solution(s) of the equation is(are):

(A) 0
(B) 1
(C) 2
(D) Infinite
Common Content for Question No. 3 to 4

are the roots of the equation 8x3 – 4x2 – 4x + 1 = 0 :

3) The value of is :

(A) 2
(B) 4
(C) 8
(D) None of these

4) The value of is :

(A)

(B)

(C)

(D)

SECTION - II

1) If equation of tangent drawn to the curve y = f(x) at its point P(3, 5) is 5x – 4y + 5 = 0 and

where a and c are prime numbers and b ∈

N, then find the value of (a + b + c).

2) Let P(x) be a polynomial of degree 3 such that P(x) + 2 is divisible by (x – 2)2 and P(x) – 2 is

divisible by (x + 2)2. if the value of P(–3) is equal to . (where a, b ∈ N) then find the minimum value
of (a – b).

3) Let x(t) = cos3t and y(t) = sin2t defines a curve where t is a parameter. This curve passes through

the point at some . If the absolute value of the slope of the curve at that point

is (where p and q are in their lowest form). Find (p + q).

4) A polynomial function P(x) of degree 5 with leading coefficient one, increases in the interval (–∞,
1) and (3, ∞) and decreases in the interval (1, 3). Given that P(0) = 4 and P′(2) = 0. If the value of
P′(6) = abcd, find the value of a + b + c + d.
5) The value of tan1°.tan2° + tan2°.tan3° + ______ + tan88° is equal to cot21° – n, then the value of
n is ______ :

6) The number of values of θ in the range [0, 2π] satisfying the equation cos42θ + 2 sin2 2θ = 17(sinθ
+ cosθ)8 is ______.

7) For a ΔABC if then sin 2A + sin 2B + sin 2C is equal to _____.

8) If x, y, z are real variables such that 3 tan x + 4 tan y + 5 tan x = 20, then the minimum value of
tan2x + tan2y + tan2z is :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION - I (i)

Q. 1 2 3 4 5 6
A. A,B,D A,B,C,D A,B,D A,B A,B,C,D A,D

SECTION - I(ii)

Q. 7 8 9 10
A. C A C B

SECTION - II

Q. 11 12 13 14 15 16 17 18
A. 23.00 08.00 6.00 2.00 2.46 9.00 2.00 7.00

PART-2 : CHEMISTRY

SECTION - I (i)

Q. 19 20 21 22 23 24
A. B,D B,C,D B,D A,B,C,D A,C,D A,B,D

SECTION - I(ii)

Q. 25 26 27 28
A. A B A D

SECTION - II

Q. 29 30 31 32 33 34 35 36
A. 15.20 9.00 6.00 4.50 3.00 5.00 6.00 7.00

PART-3 : MATHEMATICS

SECTION - I (i)

Q. 37 38 39 40 41 42
A. B A D A,B,C,D C C,D

SECTION - I(ii)

Q. 43 44 45 46
A. A C B B
 SECTION - II

Q. 47 48 49 50 51 52 53 54
A. 28.00 1.00 7.00 3.00 89.00 4.00 0.00 8.00
 SOLUTIONS

PART-1 : PHYSICS

1)

When the vessel starts accelerating then the sphere gets completely immersed in the liquid of
density 2r0.

So,

3)
Req = 2Ω
[All 3 resistance are in parallel]

So, total current = 12 Amp.

PART-2 : CHEMISTRY

19) For ideal gas, volume doubled from P, V, T. Let : KE = E

(A) Isothermal expansion Tf = T = constant

Kinetic energy (as K.E. = f(T))

(B) Adiabatic expansion Tf decreases from T [Tf < T, adiabatic expansion]

So kinetic energy
(C) Insulated (q = 0); free expansion (w = 0)
So ΔU = q + w ⇒ ΔU = 0 ⇒ nCVmΔT = 0
⇒ ΔT = 0 So Tf = T

(D) Isobaric expansion So kinetic energy

Pconstant ⇒ V ∝ T; During expansion T increases.
 ⇒

20)

Given : π = 47.7 mmHg Solution is diluted and is heated upto 127°C, π = 19 mmHg
Hence, on dilution, no. of millimoles remains same and relative lowering in vapour pressure
decreases.

21)

Cyclic process
ΔU = 0⇒ q = – w
ΔUBC = –3/2 P0V0, ΔUCA = –3/2 P0V0 , ΔUAB = 3 P0V0
B to C

0
(P – P ) =

At maxima

Maximum

22)

25) At final stage pressure in both chambers is same

Pf(A) = Pf(B)

⇒
⇒ TA = 15 × 4 × 22.7
⇒ = 60 × 22.7

26) Change in enthalpy in chamber A

(ΔH)A = nACPmΔTA

= × 2 × 10–3 kcal (1638 – 27.3)

= 80.717 kcal

27) C4H8 alkene isomers :

, , ,

HOC : order

29)
∴ VB = 125 R
Now B → C is adiabatic

VC = 1.52 × 125 R
VC = 15.2 litre

30) Initial mass ratio of H2 & He = 1 : 4

⇒ Initial molar ratio of H2 & He = 1 : 2
Final molar ratio of H2 and He = 8 : 1
we have,

⇒ minimum number of containers required

=n+1=9

31)

Initially, electron is in an orbital with no radial nodes,

So n – – 1 = 0; and wave function changes sign once across a plane i.e. there is one angular
node so = 1
 n=2
Hence initially electron is in 2p.

Now this electron absorbs

energy to move to higher orbit (shell)
In He+, E1 = –4 × 13.6 eV

Hence we can see that E4 – E2 = .

Hence electron goes in 4th shell.
So, nintial + nfinal = 2 + 4 = 6

32)

For n mol gas, P(V – nb) = nRT

w=

35)

II, IV, VI, VII, IX, X

PART-3 : MATHEMATICS

37)

f(x) = –e–x(x2 + 2x + 2) + x
f′(x) = e–x(x2 + 2x + 2) – e–x(2x + 2) + 1
f′(x) = x2e–x + 1
f′′(x) = –x2e–x + 2x, e–x
f′′(x) = e–x(2x – x2) = xe–x(2 – x)
x = 0, 2 are point of inflection
so,
α ∈ (0, 2)

38)

Let

g(x) < g(0)

⇒ g(x) < 0
⇒ G′(x) < 0
So, G(x) < 0
⇒ G(x) = 0

So,
⇒ f(x) = 0
So, g(x) = 0

39)
f(x) = 1 – x
f–1(x) = 1 – x

40)

Slope of tangent at infinity is

So,
M = 12
n=2
|m – n| = 10

41) 2b = a + c ⇒ 2sin B = sin A + sin C

42) Given equation can be written as

43)

Putting x = 0;

⇒ ℓn(ℓnf(y)) = y + c

Now g(x) = ℓn(ℓn(x)) and

44)

ℓn(ℓnf(x)) = g2(f(x) – 3g(f(x))) – 5

⇒ x = x2 – 3x – 5
x2 – 4x – 5 = 0
⇒ (x – 5) (x + 1) = 0
⇒ x = –1, 5

45) are the roots of the equation

x3 – 4x2 – 4x + 8 = 0

and

We can write

8x3 – 4x2 – 4x + 1
Put x = 1

47)

f(x) = 5

f′(3) =

= 34f(x) (log 3) (4f′(x)) = 5(320)log 3

a=5
b = 20
c=3

48)

P(x) + 2 = (x – 2)2g1 (x)

P(x) – 2 = (x + 2)2g2 (x)
So,
P(–3) =
a–b=1

49)

t = n/3

see t

50)

P′(x) = 5(x – 1) (x – 3) (x – 2)2

P′(6) = 1200 = abcd
a = 1, b = 2, c = 0, d = 0

51)
Then
tan1°.tan2° + tan2°.tan3° + ______ = cot21° – n

52) Put sin 2θ = x given equation become

x4 + 1 = 17(1 + 2x + x)2
Divide by x2, we have

Now put

Now have no solution and

we have , –2
So, there are (4) solution in [0, 2π]

53)

Use C and D rule will get sin 2A + sin 2B + sin 2C = 0

54) Let
⇒ tan2x + tan2y + tan2z > 8