Solution

BASED ON CONCENTRATION

1. A solution of naphthalene in benzene is 3% by mass of naphthalene. What is the mass

percent of benzene? [Ans: 97%]
2. If 10 g of glucose present in 80 g of water the calculate W/W %. [Ans: 11.11%]
3. If 15 g nitric acid is present in 80 g solution then calculate W/W%. [Ans: 18.75%]
4. If 20 g sucrose is dissolved in 250 ml of solution then find its W/V %. [Ans: 8%]
5. If 20 g sucrose is dissolved in 250 ml of water then find W/V %. [Ans: 8%]
6. If 10 ml of alcohol is dissolved in 30 ml of water then calculate V/V%. [Ans: 25%]
7. If 20 ml of alcohol is dissolved in 30 ml of water then calculate the W/V % of solution if
it is given that density of alcohol is 0.8 g/ml. [Ans: 32%]
8. If 54 g of glucose is dissolved in 200 ml of water then find molarity of solution?
[Ans: 1.5 M]
9. If 5.3 g of sodium carbonate is present in 1.5 L of solution then calculate its molarity.
[Ans: 0.033 M]
10. If the W/W % of the solution of sulfuric acid is 4.9 %, if the density of solution is 1.2
g/ml then calculate its molarity. [Ans: 0.6 M]
[Link] the W/V % of a solution of ethanol is 20 % then calculate the molarity of the solution.
[Ans: 4.34 M]
12. If molarity of sodium carbonate is 1.2 M and density is 1.10 g/ml then calculate W/W %
of the solution. [Ans: 11.592%]
13. If 53 g of sodium carbonate is dissolved in 100 ml of water them calculate normality of
the solution? [Ans: 10 N]
14. If 5 g CaCO3 is dissolved in 250 ml of solution then calculate normality of the solution.
[Ans: 0.4 N]
15. If molarity of sulphuric acid solution is 0.8 M then calculate normality of the solution.
[Ans: 1.6 N]
[Link] W/V % of nitric acid is 12.6 % then calculate normality of the solution.
[Ans: 2 N]
[Link] 17 g hydrogen peroxide is dissolved in 117 g of solution then find molality and W/W
% of the solution. [Ans: 14.53%]
18. If 0.6 moles of H3PO4 is dissolved in 100 g of water then calculate its molality.
[Ans: 6 m]
19.36 g of glucose is dissolved in 180 g of water then calculate mole fraction of glucose and
water. [Ans: 0.98, 0.02]
[Link] mole fraction of a glucose solution in water whose W/W % is 54%.
[Ans: 0.11. 0.89]
[Link] of sulphuric acid solution is 0.1 N. If density of solution is 1.25 g/ml then
calculate molarity, molality and mole fraction of solution. [Ans: 0.05 M, 0.04, 0.00072]
22.A solution contains 20g sodium chloride in 95 cm³ solution. The density of solution is
1.25 g cm-3. What is the mass percent of NaCl? [Ans: 16.84%]
23.6×10-3g oxygen is dissolved in per kg of sea water. Calculate the ppm of oxygen in sea
water. [Ans: 6 ppm]
[Link] much sodium chloride be dissolved in water to make I litre of 0.1 F solution?
[Ans: 5.85 g]
25.A solution has been prepared by dissolving 60 g of methyl alcohol in 120 g of water.
What are the mole fraction of methyl alcohol and water? [Ans: (i) 0.220 (ii) 0.780]
26. A solution contains 25% water, 25% ethanol and 50% acetic acid by mass. Calculate the
mole fraction of each component. [ Ans: (i) 0.503 (ii) 0.196 (iii) 0.301]
[Link] is the mole fraction of a solute in 2.5 m aqueous solution ? [Ans: 0.043]
[Link] the molality of potassium carbonate solution formed by dissolving 2.5 g of it
one litre of solution (density of solution = 0.85 g ml-¹) [Ans: 0.021m]
29. 100 ml of a solution containing 5 g of NaOH is mixed with 200 ml of M/5 NaOH
solution. Calculate the molarity of the resulting solution. [Ans: 0.55 M]
30. A sugar syrup of weight 183.42 g contains 3.42 g of sugar (C12H22O11). Calculate the
mole fraction of sugar. [Ans: 0.00099]
31. How will you prepare 0.25 m CaCl₂ solution? [ Ans: 27.75 g]
32. A commercially available sample of sulphuric acid is 15% H₂SO₄ by mass
(density = 1.10 g ml). Calculate: (i) Molarity (ii) Normality (iii) Molality of solution.
[Ans: (i) 1.68 M (ii) 3.36N (iii) 1.8 m]
33. Concentrated HNO3 used in the laboratory is usually 69% by mass of HNO3. The
density of HNO3 solution is 1.41 g cm-3. Find the molarity. [Ans: 15.44 M]
34. Commercially available conc. HCI contains 38% HCI by mass and has density of 1.19 g
cm-³. Calculate the molarity of this solution. [Ans: 12.39 M]
35. Calculate the molarity of pure water. Given the density of pure water is 1 g/mol.
[Ans: 55.55 M]
36. Calculate the mass percent of a solution obtained by mixing 100 g of 10% urea solution
with 150 g of 15% urea solution. [Ans: 13%]
37. Calculate the molality of sulphuric acid solution in which mole fraction of water is 0.85.
[Ans: 9.8]
22
38. 200 ml of calcium chloride solution contains 3.01×10 Cl- ions. Calculate the molarity of
the solution. Assume that calcium chloride is completely ionised. [Ans: 0.125M]
 BASED ON HENRY'S LAW

[Link] fraction of helium in a saturated solution at 20°C is 1.2 × 10 -6. Find out the
pressure of helium above the solution. Given that at 20°C, Henry's law constant (K H) =
144.97 k bar. [Ans: 0.174 bar]
-
[Link] what partial pressure, nitrogen will have a solubility of 0.05 g L ¹ in water at 293 K?
Given that KH for N₂ at 293 K is 76.48 k bar. Assume that the density of the solution is
the same as that of the pure solvent. [Ans: 246.26 bar]
[Link] O₂ gas is bubbled through water at 293 K, how many milli moles of O₂ gas would
dissolve in 1 litre of water? Assume that O₂ exerts a partial pressure of 0.987 bar and
KH for O₂ = 34.86 k bar. [Ans: 1.57 milli moles]

BASED ON RAOULT'S LAW

[Link] the partial vapor pressure of C₂H₄Br₂ at 85°C for an ideal solution with mole
fraction of 0.25. Vapor pressure of pure C₂H₄Br₂ at 85°C is 170 mm Hg.
[Ans: 42.5 mm Hg]
[Link] 40°C, the vapor pressure of water is 55.3 mm Hg. Calculate the vapor pressure at
the same temperature over 10% aqueous solution of urea [NH₂CONH₂].
[Ans: 53.48 mm Hg]
[Link] and toluene form nearly ideal solution. At a certain temperature, the vapour
pressure of pure benzene is 150 mm Hg and that of pure toluene is 50 mm Hg.
Calculate the vapour pressure of the solution containing equal weights of benzene and
toluene. [Ans: 104.1 mm Hg]
[Link] that Raoult's law is followed, what would be the vapour pressure of a
solution formed when 40 g of sugar (molecular mass 342) is dissolved in 360 ml of
water at 25°C ? At 25°C, the vapor pressure of water is 20 mm and the density is
1g/ml. [Ans: 19.884 mm]
[Link] 25°C the vapour pressure of pure water is 23.76 mm of Hg and that of an aqueous
dilute solution of urea is 22.98 mm of Hg. What is the molality of the solution?
[Ans: 1.896 m]
[Link] the vapour pressure of a 0.1 M urea solution at 298 K. The vapour pressure
of pure water at 298 K is 200 mm Hg. Assume density of solution to be 1g ml.
[Ans: 199.6 mm Hg]
[Link] liquids A and B have vapour pressure of 500 mm Hg and 200 mm Hg
respectively. Calculate the mole faction of A at which two liquids have equal partial
pressures. [Ans: 0.286]

[Link] 20°C the vapour pressure of pure liquids A is 22 mm of Hg and that of pure liquid
B is 75 mm of Hg. What is the composition of these components that has the vapour
pressure of 48.5 mm of Hg at this temperature? (Assuming ideal solution behavior).
[Ans: Same no. of moles]
50.A 95 mass percent solution of ethanol is further diluted with water. If the mole fraction
of ethanol in diluted solution is 0.25, what is the mole fraction of water in the diluted
solution? Is it still an ideal solution? [Ans. 0.75, Solution is not ideal]
[Link] aqueous solution contains 3g of urea dissolved in 50g of water. Calculate the
vapour pressure of the solution. The vapour pressure of water at the same temperature
is 2267.7 Nm² [Ans: 2227.6Nm²]
[Link] vapour pressure of pure liquid A and pure liquid B at 20°C are 22 and 75 mm of
Hg respectively. A solution is repaired by mixing equal moles of A and B. Assuming
the solution to be ideal, calculate the vapour pressure of the solution. [Ans: 48.5mm]
[Link] pressure of pure components A and B are 120 mm ad 96mm of Hg
respectively. What will be total pressure when solution contains 1 mole of component
A and 4 moles of comment B if the solution is ideal? [Ans: 100.8 mm]
[Link] vapour pressure of pure liquid A is 40 mm Hg at 310 K. The vapour pressure of
this liquid in solution with liquid B is 32 mm Hg. Calculate the mole fraction if the
mixture obeys Raoult's Law. [Ans. 0.8]
[Link] forms an ideal solution with water. Determine the vapour presser of the aqueous
solution containing 10% by mass of urea at 40°C (V.P. of water at 40°C = 55.3 mm
Hg) [Ans: 53.52 mm]

BASED ON RELATIVE LOWERING IN VAPOUR PRESSURE

56. The vapour pressure of a solution containing 108.24 g of a non-volatile solute

dissolved in 1000g of water at 293 K is 17.354 mm Hg. The vapour pressure of water
at 293K is 17.54 mm Hg. Assuming the solution to be ideal, calculate the molar mass
of the solute. [Ans: 181.78 g mol']
57. The vapour pressure of 2.1% of an aqueous solution of a non-volatile solute at 373 K
is 755 mm Hg. Calculate the molar mass of the solute. [Ans: 58.3 g mol-1]
58.A solution containing 6g of benzoic acid (C6H5COOH) in 50g of diethyl ether,
(C₂H5OC₂H5), has a vapour pressure of 410 mm Hg at 293K. Calculate the molar mass
of the benzoic acid. Vapour pressure of diethyl ether at 293K is 442 mm Hg.
[Ans: 113.8 g mol-1]
59. The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-
volatile solute weighing 2.175 g is added to 39.0 g of benzene. The vapour pressure of
solution is 600 mm Hg. What is the molar mass of the solute? [Ans: 65.25 g mol-1]
[Link] vapour pressure of pure benzene at a certain temperature is 200 mm Hg. At the
same temperature the vapour pressure of a solution containing 2g of a non-volatile,
non-electrolytic solid in 78g of benzene is 195 mm Hg. What is the molecular mass of
the solid? [Ans: 78 g mol-1]
[Link] vapour pressure of pure water at 30°C is 31.80 mm of Hg. How many grams of
urea molecular mass = 60) should be dissolved in 1000g of water to lower the vapour
pressure by 0.25 mm of Hg? [Ans: 26.2 g]
62. Calculate the mass of non volatile solute (Molecular Mass = 40 u) which should be
dissolved in 114 g octane to reduce its vapour pressure to 80%. [Ans: 10 g]
 BASED ON ELEVATION IN BOILING POINT

63. A solution of 7g of a non-volatile solute in 250g of water boils at 100.26°C. Find the
molecular mass of the solute Kb for what is 0.52 K kg mol-1 . [Ans: 56g mol-1]
64. A solution containing 0.45g of urea in 22.50 g of water gave a boiling point elevation
of 0.17 K. Calculate the molal boiling point elevation constant for water. Molar mass
of urea is 60 g mol-1. [Ans: 0.51 K kg mol']
o
65. The boiling point of ethanol is 78 C and its molal boiling point elevation constant per
1000 g is 1.15K. A solution of 1.12g of camphor in 32g of ethanol has a boiling point
of 78.28oC Calculate the molecular mass of camphor. [Ans: 143.75 g mol-1]
66. A solution containing 0.90g of a non-volatile solute in 100 ml of benzene has density
0.88 g ml-1 at 298 K, and it boils at a temperature 0.25o higher than benzene. Calculate
the molecular mass of solute. Molal boiling point elevation constant for benzene is
2.52 K kg mol-1. [Ans: 103.1 g mol-1]
67. A solution of 12.5 g of an unknown solute in 170 g water gave a boiling point
elevation of 0.63K. Calculate the molar mass of the solute. (K b = 0.53 K kg mol-1)
[Ans:61.85 g mol-1]
68. Calculate the boiling point of a solution containing 1.8 g of a non-volatile solute
dissolved in 90 g of benzene. The boiling point of pure benzene is 53.23K, Kb = 2.53
K kg mol-1 [molecular mass of solute = 58 g mol-1]. [Ans: 54.102 K]
o o
[Link] boiling point of water is 100 C and it becomes 100.52 C if 3g of a non-volatile
solute is dissolved in 20 ml of it, calculate the molecular weight of the solute. (Kb for
water is 0.52 K kg mol-1 density of water = 1g mol-1). [Ans: 150g mol-1]
70. Calculate the molecular mass of a substance, 1.0 gram of which when dissolved in
100 gram of solvent gave an elevation of 0.307 K in the boiling point. (Molal elevation
constant Kb = 1.84 k kg mol-1) [Ans: 59.93 g mol-1]
[Link] boiling point of water becomes 100.52o C if 1.5g of a non-volatile solute is
dissolved in 100 ml of it. Calculate the molecular weight of the solute. (Kb for water =
0.6 K kg mol-1), (Density of water = 1g ml-1). [Ans: 17.31 g mol-1]
[Link] boiling point 5% solution (w/w) of non-volatile solute in water is 100.45o C. The
boiling point of pure water is 100o C. Calculate the molar mass of the solute (Kb for
water = 0.52 K kg mol-¹) [Ans: 60.8 g mol-1]
73. Molal elevation constant for benzene is 2.52 K/m. A solution of some organic
substance in benzene boils at 0.126o C higher than benzene. What is the molality of
solution.
74. The boiling point of benzene is 353.23 K. When 1.80 g of non volatile solute was
dissolve in 90 g of benzene, the boiling point raised to 354.11 K. Calculate the molar
mass of solute (Kb for benzene = 2.53 K Kg / mol). [Ans: 57.5 g]
75. A solution containing 0.730 g of camphor (molar mass = 152 u) in 36.8 g of Acetone
(B.P. = 56.30o C) boils at 56.55o C, a solution of 0.564 g unknown compound in the
same weight of solvent boils at 56.46o C. Calculate the molar mass of unknown
compound. [Ans: 183.5 g/ml]
 BASED ON DEPRESSION IN FREEZING POINT

[Link] freezing point of a solution containing 18g of a non-volatile solute dissolved in

200 g of water decreases by 0.93. Find the molecular mass of solute. Kf for water is
1.86 K/m. [Ans: 180 g mol-l]
77.A solution of 1.25 g of a certain non-electrolyte in 20.0 g of water freezes at 271.94 K.
Calculate the molecular mass of the solute. Kf for water is 1.86 K/m.
[Ans: 109.67 g mol-1]
78. A solution containing 62.5 g of non-volatile solute per 1000 g of water has a freezing
point 1.06oC less than that of water. Calculate the molecular mass of the solute. (Kf =
1.86 K kg mol-l). [Ans: 109.67 g mol-1]
79.A solution of sucrose (molar mass = 342g/mol) is prepared by dissolving 68.4g in
1000 g of water. What is the (i) freezing point and (ii) boiling point of the solution? Kf
for water is 1.86 K/m and Kb = 0.52 K/m. [Ans: f.p. = 272.63K, b.p. = 373.1K]
80. On dissolving 0.25 g of a non-volatile substance in 30 ml of benzene (density 0.8 g
mL-1) , its freezing point decreases by 0.40oC. Calculate the molecular mass of the
non-volatile substance. Kf for benzene is 5.12 Km-1. [Ans: 133.33 g/mol]
81. A solution containing 25.6g of sulphur dissolved in 1000 g of naphthalene whose
melting point is 80.1o C. gave a freezing point lowering of 0.68o C. Calculate the
formula of sulphur. Kf for naphthalene is 6.8 K/m. [Ans: S8]
82. A solution containing 18 g of a non-volatile solute in 200 g of water freezes at 272.07
K. Calculate the molecular mass of the solute. (Given Kf = 1.86 K/m)
[Ans: 180 g/mol]
o
83. Normal freezing point of a solvent is 150 C. A 0.5 molal solution of urea in this
solvent causes a freezing point depression of two degrees. Calculate the molal
depression constant. [Ans: 4 K/m]
84. The freezing point of cyclohexane is 279.65 K. A solution of 14.75g of a solute in 500
g of cyclohexane has a freezing point of 277.33 K. Calculate the molar mass of the
solute. (Given Kf = 20.2 K kg/mol) [Ans: 256.8 g/mol]
[Link] of 0.643 g of a compound to 50 mL of benzene (density 0.879 g/mL) lowers
the freezing point from 5.51o C to 5.03o C. If Kf = 5.12 k/m. Calculate the molecular
mass of the compound. [Ans: 156 g/mol]
86. Calculate the amount of KCl in grams which must be added to 100 g of water so that
its freezing point is depressed by 2 K. Given Kf for water is 1.86 K/m. [Ans: 8 g]
[Link] the freezing point of a solution containing 0.52 g of glucose (C6H12O6) in 80
g of water. Kf for water is 1.86 K/m. [Ans: 272.93 K]
[Link] the temperature at which a solution containing 54 g glucose (C6H12O6) in
250 g of water will freeze (Kf for water is 1.86 K Kg/mol). [Ans: 270.77 k]
89. Addition of 0.643 g of a compound to 50 ml of benzene (density = 0.879 g/ml) lowers
the freezing point from 5.51o C to 5.03o C. If Kf for benzene is 5.12KKg/mol.
Calculate the molar mass of compound. [Ans: 156.06 g]
 BASED ON OSMOTIC PRESSURE

90. How much glucose, (C6H12O6) must be dissolved per litre of the solution that yields
osmotic pressure of 2.72 atmospheres at 298K? R =0.082I~L atm / K mol.
[Ans:20.0116g]
91. 3.0 g of non-volatile solute when dissolved in 1 litre water shows as osmotic pressure
of 2 atmospheres at 300K. Calculate the molecular mass of the solute. (R = 0.082 litre
atm / K mol. [Ans: 36.9 g / mol]
92. The osmotic pressure of a solution containing 1.0 g protein in 200 mL of aqueous
solution at 27o C has been found to be 2.0 × 10-1 atm. Calculate the molecular mass of
protein. (R = 0.082 L atm / mol K). [Ans: 615.7g / mol]
[Link] pressure of a solution containing 2 g dissolved protein per 300 cm3 of
solution is 20 mm of Hg at 27o C. Calculate the molecular mass of protein. (R =
0.0821 L atm / K mol). [Ans: 6238.6g / mol]
[Link] pressure of a solution containing 7g of a protein per 100 mL of solution is 25
mm Hg at 310 K. Calculate the molecular mass of the protein. (R = 0.0821 L atm / K
mol)? [Ans: 54159.3]
95. 10g of an organic compound is dissolved per litre of the solution and gave and osmotic
pressure of 1.18 atmospheres at 273 K. Calculate the molecular mass of the compound.
[Ans: 189.94 g / mol]
96. A 5% solution of sucrose (C12H22O11) is isotonic with 0.877% solution of urea.
Calculate the molecular mass of urea. (Atomic mass C = 12, H = 1, O = 16) .
[Ans: 59.99 g / mol]
97. What is the volume of a solution containing 1 g mole of sugar that will give rise to
osmotic pressure of 1 atmosphere at 0o C [Ans: 22.4 L]
o
[Link] the osmotic pressure of M/20 solution of urea at 27 C (R = 0.0821 L atm / K
mol). [Ans: 1.2315 atm]
[Link] the osmotic pressure of a solution obtained by mixing 100 cm3 of 0.25 M
solution of urea and 100 cm3 of 0.1 M solution of cane sugar at 298 K.[Ans: 4.28 atm]
100. At 300 K, 36 g of glucose present per litre of the solution has an osmotic pressure of
4.98 bar. If the osmotic pressure of the solution is 1.52 bar at the same temperature,
what would be its concentration? [Ans: 0.061 M]
3
101. 200 cm of an aq. Solution of a protein contains 1.26 g of a protein. The osmotic
pressure of such a solution at 300 K is found to be 2.57×10-3. Calculate molar mass of
protein. (R = 0.083 Lbar mol-1 K-1). [Ans: 61000 g/ml]
102. If 1.71 g of sugar (molar mass = 342 g) are dissolved in 500 cm3 of a solution at
300 K. What will be its osmotic pressure? (R = 0.083 L bar mol-1 K-1). [Ans: 0.249 bar]
103. The osmotic pressure of blood is 8.21 atm at 37o C, how much glucose should be
used per litre for an intravenous injection i.e. isotonic with blood. [Ans: 57.43 g]
104. 36 g of glucose dissolved per litre of the solution as an osmotic pressure of 4.98 bar
at 300 K. If the osmotic pressure of the solution is 1.76 bar at the same temperature.
What is the concentration? [Ans: 0.2M, 0.071M]
105. A 5 % solution of cane sugar (342 u) is isotonic with 0.872 % solution of urea.
Calculate the molar mas of Urea. [Ans: 60 g]
 BASED ON VAN'T HOFF FACTOR

106. Decinormal solution of NaCl developed an osmotic pressure of 4.6 atmospheres at

300 K. Calculate the degree of dissociation. [Ans: 87%]
107. How many grams of KCI should be added to 1.0 kg of water to lower its freezing
point to -8o C (Kf for water = 1.86 K kg / mol). [Ans: 162.2g]
108. The freezing point of a solution containing 0.2 g of acetic acid in 20.0 g of benzene
is lowered by 0.45o C Calculate the degree of association of acetic acid in benzene. (Kf
for benzene = 5.12 K kg / mol). [Ans: 94.6%]
109. A solution containing 3.1 g of BaCl2 in 250 g of water boils at 100.083o C.
Calculate the ratio of the Van't Hoff factor and molality of BaCl₂ in this solution. (Kb
for water = 0.52K/m. Molar mass of BaCl2 = 208.3g / mol). [Ans: 45:1]
110. A solution containing 7.45g of KCl per litre of solution has an osmotic pressure of
4.68 atm at 300 K. Calculate the degree of dissociation of KCl in solution.[Ans: 90%]
111. Calculate the osmotic pressure of potassium ferrocyanide solution whose
0.1 M aqueous solution dissociates at 45% at 298 K. [Ans: 6.85 atm]
112. Osmotic pressure of a 0.0103 molar solution of an electrolyte was found to be 0.70
atm at 27o C Calculate Van't Hoff factor. [Ans: 3]
o
113. The freezing point depression of 0.1 m NaCl solution is 0.372 C. What conclusion
would you draw about the state in aqueous solution? (K f for water = 1.86 K kg / mol).
[Ans: alpha=1 , % dissociation = 100]
114. The freezing point depression of 0.1 molal solution of benzoic acid in benzene is
0.256 K. For benzene Kf is 5.12 K kg / mol. Calculate the value of Van't Hoff actor of
benzoic acid in benzene. What conclusion can you draw about the molecular state of
benzoic acid in benzene? [Ans: Benzoic acid is a dimer in benzene]
115. An aqueous solution containing 4.9 g of a solute dissolved in 500 mL of solution
shows an osmotic pressure of 2.1 atmosphere at 27o C. What is the nature of the solute
(associated or dissociated) if the molar mass of the solute is 57.4 amu?
[Ans: associated]
116. How many grams of KCl should be added to 1 Kg of water to lower its freezing
point to -8o C? (Kf for water = 1.86 KKg/mol). [Ans: 160.2 g]
117. A solution containing 0.5 g of KCl dissolved in 100 g of water freezes at -0.24o C.
Calculate the percentage ionisation of salt. (Kf for water = 1.86 Kmolal-1). [Ans: 92 %]
118. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 L of such that its osmotic
pressure is 0.75 atm at 27o C. [Ans: 5.75 g]
119. Determine the osmotic pressure of a solution prepared by dissolving 25 milligram of
K2SO4 in 2 L of water at 25o C, Assuming that its completely dissociated.
[Ans: 0.00525 atm]
120. If 20 g MgBr2 is dissolved in 100 g of water then calculate elevation in boiling
point, it is given that MgBr dissociate 20% and Kb for water = 0.52.
[Ans: 1.4, 0.79o C]
121. 2 g of benzoic acid (C6H5COOH) dissolved in 25 g benzene shows a depression in
freezing point equal to 1.62 K. Molar depression constant for benzene is 4.9 K
Kg/mol. What is % association of acid if it forms dimer (Double molecule in solution).
[Ans: 0.502, 99.6%]
o
122. At 25 C, 3 g of a solute A in 100 ml of an aq. Solution gave an osmotic pressure of
2.5 atm. What is the nature of solute if its normal molar mass is 246 u.
[Ans: associate]

Ques.
Ethylene Glycol ( 62 g/ml) is a common automobile antifreeze. Calculate the freezing
point of a solution containing 12.4 g of this solution in 100 g of water. Would it be
advisable to keep this substance in car radiator during summer? (Kf for water = 1.86
K/m & Kb for water = 0.512 K/m).