Target DPP Test Contact Number: 8527521718
1. If the boiling point of water at 750 mm Hg is 99.63°C, 6. Which graph represents the elevation in boiling point?
what quantity of sucrose is needed to be dissolved in 500
g of water to achieve a boiling point of 100°C?
(Molal elevation constant for water is 0.52 K kg mol−1 )
1. 128.17 g
2. 121.67 g
3. 125.57 g 1.
4. 116.27 g
2. 0.2 molal solution of a weak electrolyte AB is 20%
dissociated. The freezing point of the solution would be:
[Kf = 1.86 °C/m]
1. -0.90°C
2. -0.45°C
3. -0.25°C
4. -0.71°C
3. The solution which has the lowest freezing point is
(1) 0.1 M potassium nitrate 2.
(2) 0.1 M aluminium sulphate
(3) 0.1 M potassium chloride
(4) 0.1 M potassium sulphate
4. What is the freezing point of an aqueous solution that
boils at 101°C?
(Given : K f
∘
= 1.86 C/m and K b
∘
= 0.51 C/m )
∘ ∘
1. 3.647 C 2. −3.647 C
∘ ∘
3. −0.364 C 4. −5.647 C
3.
5. Osmotic pressure is 0.0821 atm at a temperature of
300 K. Find concentration in mole/litre [Roorkee 1990]
(1) 0.033
(2) 0.066
(3) 0.33 × 10–2
(4) 3
4. None of the above.
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Target DPP Test Contact Number: 8527521718
7. 12. Assertion(A): Reverse osmosis is used to purify
The observed molar mass of acetic acid seawater.
Assertion (A): in benzene is more than the normal Reason(R): Solvent molecules pass from concentrate
molar mass of acetic acid. solution to pure solvent through a semipermeable
Molecules of acetic acid dimerise in membrane if high pressure is applied on the solution
Reason (R): benzene due to hydrogen bonding. side.
1. Both A and R are correct and R is the correct
explanation of A.
2. Both A and R are correct but R is not the correct
Both (A) and (R) are true and (R) is the correct
1. explanation of A.
explanation of (A).
3. A is true and R is false.
Both (A) and (R) are true but (R) is not the correct 4. A is false and R is true.
2.
explanation of (A).
3. (A) is true but (R) is false. 13. Among the following application/s of osmosis is/are
4. (A) is false but (R) is true. :
(1) In animals, water moves into different parts of the
body.
8. When 12.2 g of benzoic acid is dissolved in 100 g of (2) Stretching of leaves, flower. (3) Opening and closing
water, the freezing point of the solution was found to be of flowers.
–0.93 °C. The number (n) of benzoic acid molecules (4) All of the above.
associated (assuming 100% association) is:
(Kf(H2O) = 1.86K kg mol–1) 14. What is the percent dissociation of SrCl₂ in a 0.01 M
solution if its van’t Hoff factor is 1.8?
1. 3 2. 1 1. 70
3. 2 4. 5 2. 55
3. 40
4. 80
9. If 'A' contains 2 % NaCl and is separated by a semi
permeable membrane from 'B', which contains 10 % 15. 2.56 g of sulphur in 100 g of CS2 has depression in
NaCl, then the event that will occur is a freezing point of 0. 01 °C and Kf = 0.1 K / molal.
1. NaCl will flow from 'A' to 'B' The atomicity of sulphur in the solution will be:
2. NaCl will flow from 'B' to 'A' 1. 2
3. Water will flow from 'A' to 'B' 2. 4
4. Water will flow from 'B' to 'A' 3. 6
4. 8
10. The vapour pressure of 1 molal solution of a non-
volatile solute in water at 300 K would be: 16. Which among the following is mole fraction of the
(The vapour pressure of water at 300 K = 12.3 kPa) solute at 300 K, when vapour pressure of solute over the
1. 21.08 kPa 2. 12.08 kPa mercury reduces from 50 mm to 45 mm upon adding in
3. 33.08 kPa 4. 4.08 kPa a solvent?
1. 0.005 2. 0.010
3. 0.100 4. 0.900
11. Considering the formation, breaking and strength of
hydrogen bond, predict which of the following mixtures
will show a positive deviation from Raoult’s law?
1. Methanol and acetone
2. Chloroform and acetone
3. Nitric acid and water
4. Phenol and aniline
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Target DPP Test Contact Number: 8527521718
17. Consider the given two statements: 22. The amount of CaCl (i = 2.47) that must be
2
The value of Van't Hoff factor (i) for dissolved in 3 litre of water such that its osmotic
Assertion (A):
ethanoic acid in benzene is less than pressure is 4.94 atm at 27 °C is:
unity. 1. 2.405 × 10 mol −3
Molecules of ethanoic acid dimerizes 2. 0.243 mol
Reason (R): 3. 0.0267 mol
in benzene due to hydrogen bonding.
4. 1.486 mol
1. Both (A) and (R) are True and (R) is the correct
explanation of (A). 23. 20 gm of a non-volatile and non-electrolyte solute
(molecular weight = 62) is dissolved in 200 gm of water
Both (A) and (R) are True but (R) is not the correct
2. at −10 C . How much ice will be separated?
∘
explanation of (A).
(kf f or H2 O = 1.86 K/m)
3. (A) is True but (R) is False. 1. 60 gm
4. Both (A) and (R) are False. 2. 120 gm
3. 140 gm
4. 180 gm
18. The values of van’t Hoff factors for KCl, NaCl and
K2SO4 respectively are: 24. Preservation of fruits against bacterial action by
1. 2, 2 and 2 2. 2, 2 and 3 adding sugar is an example of-
3. 1, 1 and 2 4. 1, 1 and 1 1. Exosmosis
2. Reverse-osmosis
3. Diffusion
4. Capillary action
19. The Vapour pressure of CCl4 at 25°C is 143 mm Hg.
0.5 g of a non-volatile solute (mol. wt. 65) is dissolved 25.
in 100 ml of CCl4. The vapor pressure of the solution is: The boiling point of 1M Urea solution is 101oC. At
the same temperature, the boiling point of 1M KCl
(Density of CCl4 = 1 .58 g/cm3) solution will be:
1. 141.93 mm Hg 1. 101oC
2. 94.39 mm Hg
2. 102oC
3. 199.34 mm Hg
4. 143.99 mm Hg 3. 202oC
4. Cannot be predicted (Insufficient Data)
20. A 5% (w/v) solution of cane sugar (molar mass 342)
is isotonic with 1% (w/v) of a solution of an unknown 26. Which of the following pairs of solutions shows a
solute. The molar mass of an unknown solute in g/mol positive deviation from Raoult's law?
is: 1. CH OH + H O
3 2
1. 171.2 2. CH Cl + CH COCH3 3 3
2. 68.4 3. H O + H N O
2 3
3. 34.2 4. C H + C H CH
6 6 6 5 3
4. 136.2
27. A solution of x moles of sucrose in 100 grams of
21. 200 cm3 of an aqueous solution of a protein contains water freezes at −0.2°C. As ice separated the freezing
point goes down to 0.25°C. How many grams of ice
1.26 g of the protein. The osmotic pressure of such a
would have separated?
solution at 300 K is found to be 2.57 × 10–3 bar. The 1. 10 grams
molar mass of the protein is: 2. 20 grams
1. 61,022 g mol–1 2. 65,042 g mol–1 3. 25 grams
3. 68,012 g mol–1 4. 57,012 g mol–1 4. 23 grams
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Target DPP Test Contact Number: 8527521718
28. What is the freezing point (in °C) of a solution
containing 0.1 g of K [F e(CN ) ] [Mol. wt. 329] in 100
3 6
g of water?
−1
(U se : Kf = 1.86 K kg mol )
−2
1. −2.3 × 10
−2
2. −5.7 × 10
3. −8.7 × 10 −3
−2
4. −1.2 × 10
29. A solution that has the highest osmotic pressure
among the following is:
1. 0.1 M NaCl solution 2. 0.5 M Glucose solution
3. 0.1 M MgCl2 solution 4. 0.2 M KCl solution
30. Which solution has the highest osmotic pressure?
1. 0.1 M NaCl 2. 0.5 M Urea
3. 0.1 M MgCl2 4. 0.2 M NaCl
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