Ans 2
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Long Term & Regular –YEARWISE FULL TEST (1st Year)- (Answer Key)-04.04.26(AN)
Choose the correct answer : 180 x 4 = 720
PHYSICS Solution :
1. A body starts from rest with uniform AB = 1 cm
acceleration ‘a’ its velocity after ‘n’ seconds is 1
tAB = 15 min = hour
‘v’. The displacement of a body in last 3s 4
(assume total time of journey from 0 to n vb/r = 5 kmph
seconds) Speed of the boat along AB
v(6n 9) 2v(6n 9)
1) 2)
2n n
v2b v2r
2v(n 1) 2v(n 1) r
3) 4)
n n
v(6n 9)
Ans : 1)
2n [Link] ground is v 2b v r2 = vb
r
Solution :
AB = vb tAB
v 1 1v vn
a ; s n an 2 n 2 AB v 2b/r v2r t AB
n 2 2n 2
1 1
s(n-3) = a(n 3)2 1 52 v 2r
2 4
displacement in last 3s will be vr = 3 kmph
1 2 1 3. A particle moves along a straight line such
s = sn – sn-3 = an a(n 3) 2 that its displacement at any time ‘t’ is
2 2
3
s = (t3 – 6t2 + 3t + 4) meter’s the velocity
v (n 3) when the acceleration is zero is
= n
2 n
1) 3 m/s 2) – 9 m/s
6n 9 v 3) – 12 m/s 4) 4 m/s
=
n 2 Ans : 2) – 9 m/s
2. A boat has the speed of 5 kmph in still water Solution :
crosses a river of width 1 km in shortest ds
v = 3t2 – 12t + 3
possible path in 15 minutes. The velocity of dt
river in km/h is dv
a = 6t – 12
1) 3 2) 2 dt
3) 4 4) 41 a=0t=2
Ans : 1) 3 v = 3(2)2 – 12(2) + 3 = -9
2
4. Which of the following pair of three forces 1) 30o 2) 60o
can give resultant as zero? 3) 90o 4) 45o
1) 1 N, 2N, 4 N 2) 5 N, 5 N, 15 N Ans : 4) 45o
3) 10 N, 20 N, 25 N 4) 8 N, 12 N, 24 N Solution :
Ans : 3) 10 N, 20 N, 25 N
R
Solution : 4H = R tan 200, R 400
2
Fmax = 10 + 20 = 30
4(100) = 400 tan
Fmin = 20 – 10 = 10
tan = 1 = 45o
So, resultant of 10 N and 20 N can be
anywhere from 10 N to 30 N. 7. A bomb of mass 2 kg initially at rest explodes
So, resultant of 10 N and 20 N can be 25 N and breaks into three fragments of masses in
also. the ratio 1 : 1 : 3, the two pieces of equal mass
fly off perpendicular to each other with a
Hence resultant will be zero.
speed 15 m/s each the speed of heavier
5. A projectile is thrown in the upward direction
fragment is
make an angle 60o with horizontal direction
with velocity of 147 m/s. The time after which 1) 15 m/s 2) 45 m/s
its inclination with the horizontal is 45o is 3) 5 2 m/s 4) 10 2 m/s
(g = 10 m/s2)
Ans : 3) 5 2 m/s
1) 15 s 2) 10.98 s
Solution :
3) 5.38 s 4) 2.745 s
mv 2
Ans : 3) 5.38 s P1 (15) = 6 kgm/s
5 5
Solution :
m 2
vy P2 v (15) = 6 kg m/s
tan 5 5
vx
Resultant of P1 & P2 = 2P 2 x 6 6 2
u sin gt
tan 45o From conservation of linear momentum
u cos
u sin 60o – gt = u cos 60o P1 P2 P3 0
3
P2
1
147 x - 10 t = 147 P12
2 2
147
2
3 1 = 10 t P1
147 0.732 P3
t = 5.38 sec
2 10 2
P3 m3 v3 3 x v
6. A projectile is thrown up with initial speed ‘u’ 5
at an angle with horizontal. It just crosses a P3 (P1 P2 ) 6 2
tower horizontally at its maximum height. The
6v
tower is 100 m high and the foot of the tower 6 2
is at 200 m from the point of projection. The 5
angle of projection is v 5 2 m/s
3
8. Two cars of unequal masses use similar tyres. mv 2
If they are moving at the same initial speed, For B, N – mg =
R
the minimum stopping distance
1) is smaller for heavier car
2) is smaller for lighter car
3) is same for both cars
4) depens on the volume of car
Ans : 3) is same for both cars
Solution : mv 2
N = mg +
m1g R
Deceleration of car 1, a1 g
m1 mv 2
mg
m 2 g NA R
Deceleration of car 2, a 2 g
m2 NB mv 2
mg
R
Both a1 = a2 so, both car’s have same stopping
distance. gR v2 10 x 20 100 100
=
1 gR v 2 10 x 20 100 300
W = KE mgd = mu 2
2 NA 1
2
u NB 3
d (u is same, is same)
2g 10. A particle of mass 0.5 kg is displaced from
9. Two identical cars A and B are moving at 36 position r1 (2, 3, 1)m to r2 (4, 3, 2)m by
kmph. A goes on a bridge convex upward and applying a force of magnitude 30 N which is
B on concave upward. If the radius of acting along (iˆ ˆj k)
ˆ the work done by the
curvature of bridge is 20 m, the ratio of
force is
normal forces exerted on the car’s when they
are at middle of the bridge (g = 10 m/s2) 1) 10 3 J 2) 30 3 J
1) 1 : 3 2) 1 : 2 3) 30 J 4) 15 J
3) 2 : 3 4) 1 : 5
Ans : 2) 30 3 J
Ans : 1) 1 : 3
Solution : Solution :
Unit vector corresponding to
mv 2
For A, mg – N = ˆi ˆj kˆ
R ˆi ˆj kˆ is
N 3
30 ˆ ˆ ˆ
So, (i j k) 10 3 (iˆ ˆj k)
ˆ
A 3
W = F.r = F.(r2 r1 )
mg W = 10 3(iˆ ˆj k).(2i
ˆ ˆ k)
ˆ
W = 10 3 (2 1) 30 3 J
mv 2
N = mg -
R
4
11. A 2 kg block slides on horizontal floor with 13. A ball is dropped onto a fixed horizontal
speed of 5 m/s. If strikes an uncompressed surface from a height ‘h’. The coefficient of
spring and compresses it till the block is restitution is ‘e’. The average speed of the ball
motionless. The kinetic frictional force is 15 N is
and spring constant is 20 N/m. The spring 1 e gh 1 e2 gh
1) 2) 2
compressed by 1 e 2 1 e 2
1) 0.5 m 2) 1 m (1 e) 2
1 e2 gh gh
3) 3 m 4) 2 m 3) 4)
(1 e) 2 2 1 e2 2
Ans : 2) 1 m
1 e2 gh
Solution : Ans : 3)
(1 e) 2 2
(KE)ini = (PE)SP + (W)f
Solution :
1 1
(2)52 (20)x 2 15x Average speed =
total dis tan ce
2 2 total time
10x2 + 15x – 25 = 0
(1 e 2 )
2x2 + 3x – 5 = 0 H 2
= (1 e )
3 9 40 3 7 2H 1 e
2x2 4
g 1 e
3 7 3 7
= , = 1 (or) – 2.5 1 e2 gh
4 4 v
(1 e)2 2
12. A car starts from rest along straight level
R
frictionless road by an engine delivering 14. A uniform disc of diameter is put over
2
constant power, then velocity is directly
another uniform disc of diameter R of same
proportional to thickness and density, the peripheries of the
1 two discs touch each other. The centre of mass
1) t 2)
t of the system from centre of big disc is
3) t 4) t3/2 R R
1) 2)
10 20
Ans : 3) t 9R 11R
3) 4)
Solution : 10 10
P = Fv R
Ans : 2)
P = mav 20
dv p Solution :
P= m .v vdv dt
dt m Mass Area
v t
p R2 R2
m1 , m2
0 vdv 0 m dt 4 16
R2 R
v2 p m2d
x
R
t v t
2 m x cm = 16
2
4 ; xcm =
m1 m 2 R R2 20
4 16
5
15. Identify the increasing order of radius of 2 2
1) 2)
gyration of following bodies of same radius 3 5
I) About natural axis of circular ring 2 2
3) 4)
II) About diameter of circular ring 8 7
III) About diameter of circular plate 2
Ans : 4)
IV) About diameter of solid sphere 7
1) II, III, IV, I 2) III, II, IV, I Solution :
3) III, IV, II, I 4) II, IV, III, I tan
Ans : 3) III, IV, II, I
R2
Solution : 1 2
k
Conceptual
1 2
16. A particle of mass 5 g is moving with uniform
5 7
speed of 3 2 cm/s in the xy plane along the 1
2
line y = x + 4. Magnitude of its angular
18. Gravitational potential energy of mass ‘m’
momentum about origin is g cm2s-1 is
placed at centre of earth is (If mass of the
1) zero 2) 30
earth is M and radius is R)
3) 30 2 4) 60
GMm
Ans : 4) 60 1) 2) 0
R
Solution :
GMm 3 GMm
L = mvr 3) 4)
2R 2 R
4 3 GMm
x+ Ans : 4)
= 2 R
y
Solution :
(0, 4)
3 GM
v(C) =
2 R
(0, 0) u=vxm
(-4, 0)
3 GMm
4 u=
r 4 cos 45 2 R
2
19. An object is taken to a height 3R above the
|004| 4 surface of earth. The increase in potential
r
2 2 energy is (R is radius of earth)
4 mgR 5
L 5(3 2) 1) 2) mgR
2 3 4
L = 60 CGS unit 2 3
3) mgR 4) mgR
17. A solid sphere rolls down without slipping on 3 4
an inclined plane of inclination 45o. The 3
minimum coefficient of static friction to Ans : 4) mgR
4
support pure rolling is
6
Solution :
mgh mg(3R)
u
h 3R
1 1
R R
3
u = mgR A A
4 sin = A'
A' sin
20. There are four point masses ‘m’ each on the
corners of a square side length l. What is the Fcos
Shearing stress =
moment of inertia of the system about one of A'
its diagonals? F cos .sin
Shearing stress =
1) 2 ml2 2) ml2 A
22. A steel wire is stretched by 1 [Link]. If the
3) 4 ml2 4) 6 ml2
radius of the wire is double, its Young’s
Ans : 2) ml2
modulus will
Solution :
1) remain unchanged
I = m(AO)2 + m(OC)2
2) becomes half
3) become double
4) become four times
Ans : 1) remain unchanged
2 2 Solution :
l l
I = m m Conceptual
2 2
23. The cylindrical tube of spray pump has radius
I = ml2
R, one end of which has ‘n’ fine holes, each of
21. Two equal and opposite forces F and F act on radius ‘r’ of the speed of liquid in a tube is ‘v’,
a rod of uniform cross sectional area A, as the speed of the ejection of the liquid through
shown in the figure. Find the shearing stress the hole is
on the section AB.
v2R vR 2
1) 2)
nr n 2r 2
vR 2 vR 2
3) 4)
nr 2 n3r 2
Fsin cos F
1) 2) vR 2
A A cos Ans : 3)
nr 2
F cos Fsin Solution :
3) 4)
A A Equation of continuity, A1v1 = A2v2
Fsin cos
Ans : 1) R2v = nr2v2
A
vR 2
Solution : v2 =
nr 2
7
24. A small sphere of radius ‘r’ falls from rest in a 26. A soap bubble in vacuum has a radius of 3 cm
viscous liquid. As a result heat is produced and another soap bubble in vacuum has a
due to viscous force. The rate of production of radius of 4 cm. If the two bubbles coalesce
heat when the sphere attains its terminal under isothermal condition, then the radius of
velocity is proportional to new bubble is
1) r3 2) r2 1) 2.3 cm 2) 4.5 cm
3) r5 4) r4 3) 5 cm 4) 7 cm
5
Ans : 3) r Ans : 3) 5 cm
Solution : Solution :
dQ 2r 2 r r12 r22 = 9 16 = 5 cm
Fv v T vT ( )g
dt 9 27. A glass is full of water at 4oC when it is
= 6rvT x vT ( vT r2) a) cooled b) heated then, which one of the
dQ following is correct?
r v T2
dt 1) water level decreases, increases
dQ 2) water level increases, decreases
r r 4 r5
dt 3) water level decreases, decreases
25. A large number of water drops each of radius 4) water overflow in both cases
‘r’ combine to have a drop of radius R. If the Ans : 4) water overflow in both cases
surface tension is T and mechanical equivalent
Solution :
of heat is J, then the rise in temperature will be
Due to Anamalous expansion of water at 4oC
2T 3T
1) 2) water occupies minimum volume.
rJds RJds
28. If 10 g of ice at 0oC is mixed with 10 g of
3T 1 1 2T 1 1 water at 10oC. The final temperature is (Lice =
3) 4)
Jds r R Jds r R 80 cal/g)
3T 1 1 1) 2.5oC 2) 0oC
Ans : 3)
Jds r R 3) 5oC 4) 7.5oC
Solution : Ans : 2) 0oC
1 1 Solution :
T4R 3 (ms)J
r R Q1 = mL = 800 cal
1 1 4 Q2 = ms t = 10 x 1 x 10 cal
T4R 3 R 3 (s) J
r R 3 Q1 > Q2 So t = 0oC
1 1 29. Six identical conducting rods are joined as
3T (s)J
r R shown in figure. Points A and D are
maintained at temperatures 200oC and 20oC
Rise in temperature
respectively. The temperature of junction B
3T 1 1
will be
Jsd r R
8
32. The molar heat capacity in a process of a
Q
diatomic gas if it does a work of when a
4
1) 120oC 2) 100oC heat of Q is supplied to it is
3) 140oC 4) 80oC 2 5
1) R 2) R
Ans : 3) 140oC 5 2
Solution : 10 6
3) R 4) R
Let R is thermal resistance 3 7
RAB = R 10
Ans : 3) R
RBD = 2R 3
If temperature of junction B is T Solution :
200 T T 20
Then, 5
R 2R dU = nCVdT = R(dT)
o
2
T = 140 C
2 dU
30. Choose the correct graph which represents dT
Wein’s displacement law (symbols have their 5 R
usual meaning) From 1st law, dU = dQ – dW
Q 3Q
= Q
4 4
1) 2)
dQ Q
So, C
dT 2dU
5R
5 QR 10
3) 4) Both (1) & (3) C R
2 3Q 3
4
Ans : 4) Both (1) & (3)
33. Heat is supplied to a diatomic gas at constant
Solution :
pressure. The ratio of Q : U : W is
mT = constant (hyperbola)
1) 5 : 3 : 2 2) 5 : 2 : 3
So both (1) & (3)
3) 7 : 5 : 2 4) 7 : 5 : 3
31. Newton’s law of cooling is applied in
laboratory for the determination of Ans : 3) 7 : 5 : 2
1) specific heat of gases Solution :
2) latent heat of gases Q : U : W
3) specific heat of liquids = nCPT : nCVT : n(CP – CV)T
4) latent heat of liquids CP C CV
= :1: P
Ans : 3) specific heat of liquids CV CV
Solution :
= : 1 : ( - 1)
Using Newton’s law of cooling specific heat
capacities of different liquids can be 7 2
= :1: 7 : 5 : 2
calculated. 5 5
9
34. A container is filled with 20 moles of an ideal 36. The average kinetic energy of a gas molecule
diatomic gas at absolute temperature T. When can be determined by knowing
heat is supplied to gas, temperature remains 1) the number of molecules in the gas
constant but 8 moles dissociates into atoms. 2) the pressure of the gas only
Heat energy given to gas is 3) the temperature of the gas only
1) 3 RT 2) 4 RT 4) volume of the gas
3) 6 RT 4) 5 RT Ans : 3) the temperature of the gas only
Ans : 2) 4 RT
Solution :
Solution :
KE Temperature
Heat supplied U = Ufinal - Uinitial
37. The mean free path of molecules of gas
f (radius ‘r’) is inversely proportional to
U nRT
2 1) r3 2) r2
5 3) r 4) r
Uinitial = 20 (RT) = 50 RT
2 2
Ans : 2) r
5 3
Ufinal = (20 – 8) RT + (2) (8) RT Solution :
2 2
1
= 54 RT m ( d = 2r)
2 nd 2
U = 54 RT – 50 RT
1
= 4 RT m
r2
35. A given quantity of an ideal gas is at pressure
38. A particle is executing SHM along a straight
P and absolute temperature T obeys P T3
line. Its velocity at x1 and x2 displacements
during adiabatic process, the adiabatic bulk
from the mean positions are v1 and v2
modulus of the gas is
respectively. Its time period is
2
1) P 2) P x12 x 22 x 22 x12
3 1) 2 2 2) 2 2
v1 v 22 v1 v 22
3
3) P 4) 2P
2 v12 v 22 v12 v 22
3) 2 2 4) 2 2
3 x1 x 22 x1 x 22
Ans : 3) P
2
x 22 x12
Solution : Ans : 2) 2
v12 v 22
P1- T = constant
Solution :
1
PT = constant v A 2 x 2 v2 = 2(A2 – x2)
3
Given, 3 v12 = 2 (A2 – x12)
1 2
v22 = 2 A 2 x 22
3
Adiabatic bulk modulus k = P = P
2 v 22 v12 2 x12 x 22
10
v 22 v12 x12 x 22 n1l1 n 2 l2
T 2 Ans : 1)
x12 x 22 v 22 v12 2(n 2 n1 )
Solution :
x2 x2
(or) T 2 22 12
v1 v 2 v
l1 + 2e =
n1
39. The time period of a particle in SHM is 8 sec.
At t = 0 it is at the mean position the ratio of v
l2 + 2e =
the distances travelled by it in the first and in n2
the second second is
n1(l1 + 2e) = n2(l2 + 2e)
1 1
1) 2) n1l1 – n2l2 = 2e(n2 – n1)
2 2
1 n1l1 n 2 l2
3) 2 4) e
2(n 2 n1 )
2 1
1 41. Assertion : The change in air pressure effect
Ans : 4)
2 1 the speed of sound.
Solution : Reason : The speed of sound in a gas is
y = A sin t, T = 8 proportional to square root of absolute
2 A temperature.
t = 1, y = A sin x1 , y
8 2 1) Both assertion and reason are correct and
2 reason is the correct explanation of the
t = 2, y = A sin x 2, y = A
8 assertion
Distance in 2nd second, 2) Both assertion and reason are correct but
2 1 reason is not the correct explanation of the
A
A A assertion
2 2
3) Assertion is correct, but reason is incorrect
A 4) Assertion is incorrect, but reason is correct
y1 2 1
Ans : 4) Assertion is incorrect, but reason is
y 2 A( 2 1) 2 1
correct
2
Solution :
40. In a pipe open at the both ends n1 and n2 be the
frequencies corresponding to vibrating air Speed of sound is independent of pressure
column lengths l1 and l2 respectively. The end P
because v . At constant temperature, if
correction is
n1l1 n 2 l2 n 2 l2 n1l1 P
1) 2) P changes then also changes. So, ratio
2(n 2 n1 ) 2(n 2 n1 )
n 2 l2 n1l1 n1l1 n 2 l2 constant so, no effect of pressure as speed of
3) 4)
2(n1 n 2 ) (n1 n 2 ) sound. Speed of sound is proportional to
square root of absolute temperature.
11
42. Match Column- I and Column – II. 9
1VSD = MSD
Column – I Column - II 10
LC = 1 MSD – 1 VSD
A) Velocity gradient P) M0L0T-1
9
B) Linear mass Q) ML-1T-1 1 MSD MSD
10
density
1
0 -1 0 LC = MSD
C) Rydberg constant R) ML T 10
D) Coefficient of S) ML-1T0 1mm
LC = = 0.1 mm = 0.01 cm
viscosity 10
l = MSR + VC x LC
1) A – P, B – Q, C – R, D - S
= 6.4 + 8(0.01) = 6.48 cm
2) A – S, B – R, C – Q, D - P
44. Which of the following groups has different
3) A – Q, B – R, C – P, D - S
dimensions?
4) A – P, B – S, C – R, D - Q 1) potential difference, emf, voltage
Ans : 4) A – P, B – S, C – R, D - Q 2) pressure, stress, young’s modulus
Solution : 3) heat, energy, work done
dv 4) dipole moment electric flux, electric fields
Velocity gradient = M0L0T-1
dx Ans : 4) dipole moment electric flux, electric
Mass fields
Linear mass density = = ML-1T0
length Solution :
Rydberg constant = M0L-1T0 A) V = M1L2T-3 = Voltage = emf
F B) Pressure stress, Young’s modulus
Coefficient of viscosity A = ML-1T-1 =M1L2T-2
dV
dx C) Heat, energy, work done = M1L2T-2
43. Length of 9 MSD of vernier calipers are equal D) Dipole moment = L1T1A1
to 10 VSD and 1 MSD = 1mm. For measuring Electric flux = M1L3T-3A-1
the length of rod, reading on main scale is 6.4 Electric field = M1L3T-3A-1
cm and 8th division on Vernier scale is 45. Four persons A, B, C and D initially at corners
coinciding with marking on main scale of square of side length ‘d’, if each person
division. There is no zero error then find out starts moving with same speed ‘v’ such that A
length of rod. towards B, B towards C, C towards D the
1) 6.23 cm 2) 6.58 cm persons will meet after a time
3) 6.48 cm 4) 6.83 cm d 2d
1) 2)
Ans : 3) 6.48 cm v v
d d
Solution : 3) 4)
2v 2v
10 VSD = 9 MSD
12
d 1) 2035 kJ mol–1 2) 1017.5 kJ mol–1
Ans : 1)
v 3) –2035 kJ mol–1 4) –1017.5 kJ mol–1
Solution : Ans : 3) –2035 kJ mol–1
Solution :
3
2M (s) O(g) M 2 O3(s) 1273 kJ --- (i)
2
1
H 2(g) O(g) H 2 O( l ) 286 kJ --- (ii)
v 2
v1 = v cos 45o =
2 44 kJ H 2O ( l ) H 2O (g) --- (iii)
d 36 kJ 2M (s) 3H 2(g) M 2 H 6(g) --- (iv)
t
OA
2 td
H = i + 3 (ii) + 3 (iii) – (iv)
v1 v v
H = –1273 – 858 + 132 – 36
2
= –2035 kJ mol–1
CHEMISTRY
46. How many significant figures should be 48.
present in the mass of CaCO3 is required to
react completely with 25 mL of 0.75M HCl?
Correct statement is
1) one 2) four
1) W, Y are homomers
3) three 4) five
2) X, Z are positional isomers
Ans : 2) four
3) W, Y are functional isomers
Solution :
4) X, Z are homomers
CaCO3(s)+2HCl(aq)CaCl2(aq)+ H2O(l) + CO2(g)
Ans : 4) X, Z are homomers
W N Vml
= Solution :
GEW CaCO3 1000
W is
W 0.75 1 25
50 1000
W = 0.9375g
47. A compound M2H6 undergoes combustion 49. Correct match among the following is
according to the reaction ; IUPAC Symbol Element belongs to
M2H6(g) + 3O2(g) M2O3(s) + 3H2O(g), from the A) Unu i) s-block
following data, calculate the enthalpy change
B) Une ii) p-block
for the combustion of M2H6.
C) Uus iii) d-block
3
2M (s) O(g) M 2 O3(s) 1273 kJ D) Ubn iv) f-block
2
1 1) A-i, B-iii, C-ii, D-iv
H 2(g) O(g) H 2 O( l ) 286 kJ
2 2) A-i, B-ii, C-iii, D-iv
44 kJ H 2O ( l ) H 2O (g) 3) A-iv, B-iii, C-ii, D-i
36 kJ 2M (s) 3H 2(g) M 2 H 6(g) 4) A-iv, B-ii, C-iii, D-i
Ans : 3) A-iv, B-iii, C-ii, D-i
13
Solution : Solution :
Unu (101) f-block
Une (109) d-block
Uus (117) p-block
Ubn (120) s-block
50. Dipole moment of NH3 is X than NF3,
52. Statement I : H+ ion concentration in H2SO4
o-nitrophenol boiling point is Y than
[PH = 3] is 103N.
p-nitro phenol and n+l value of 4d subshell is
Statement II : The normality of the resulting
Z to 5p subshell.
solution which is formed by mixing of 0.1N,
1) X = lesser, Y = greater, Z = equal
200 mL H2SO4 and 0.1N, 100 mL of Ba(OH)2
2) X = lesser, Y = lesser, Z = equal
1
3) X = greater, Y = lesser, Z = equal is .
3
4) X = greater, Y = greater, Z = equal
1) Both statements I and II are correct
Ans : 3) X = greater, Y = lesser, Z = equal 2) Both statements I and II are incorrect
Solution : 3) Statement I is correct, II is incorrect
NH3 NF3 4) Statement I is incorrect, II is correct
OH OH Ans : 2) Both statements I and II are incorrect
NO2 Solution :
Boiling point of pH = log [H+] [H+]
N = 10pH = 103
N V N 2 V2 20 10 1
NO2 Ne = 1 1 = =
V1 V2 300 30
Subshell energy n + l 4d and 5p
53. Match the column I with column II
= 4 + 2, 5+1
=6 =6 Column I Column II
51. Which of the following molecule can exhibit
Geometrical isomerism? Subshell with
I A
one radial node
1)
Subshell with
2) 2-Methyl -2-butene
II B two angular
nodes
3)
A subshell
4) III C which has three
orientation
Ans : 4)
14
Solution :
Subshell with
3Mg + N2 Mg3N2 - Combination
IV D energy (n + l)
Cl2 + 2KI 2KCl + I2 - Non metal
value = 1
displacement
I II III IV PCl5 PCl3 + Cl2 - Decomposition
1) D A C B 3HNO2 HNO3 + 2NO + H2O –
2) D A B C Disproportination reaction
3) D C B A 55. In the reaction A2(g) + 3B2(g) 2AB3(g), the
entropies in (J k–1 mol–1) of A2(g), B2(g) and
4) A B D C
AB3(g) are 190, 130 and 195 respectively and
Ans : 2) D A B C enthalpy change for the reaction is –95 kJ/mol.
Solution : The temperature at which the reaction
spontaneous is
1) 500 K 2) 400 K
3) 1300 K 4) 600 K
Ans : 2) 400 K
Solution :
A2(g) + 3B2(g) 2AB3(g)
S = 2 x SAB3 – SA 2 3SB2
= 2 x 195 – [190 + 3 x 130]
dxy pz = –190 J K–1 mol–1
54. Choose the correct matching H = –95 kJ/mol
Column – I (Reaction) G = H - TS
i) 3Mg + N2 Mg3N2 H 95 x103
Teq =
ii) Cl2 + 2KI 2KCl + I2 S 190
iii) PCl5 PCl3 + Cl2 Teq = 500 K
If S is –ve, H is –ve then the reaction is
iv) 3HNO2 HNO3 + 2NO + H2O
spontaneous at below equilibrium temperature.
Column – II (Type of redox reaction) 56. IUPAC name of
A) Non metal displacement
B) Decomposition
should be
C) Combination
D) Disproportination reaction
1) i-A, ii-C, iii-B, iv-D
1) 5-Bromo-3-carbamoyl-2-chlorocarbonyl-4-
2) i-C, ii-D, iii-B, iv-A
formylhexanoic acid
3) i-C, ii-A, iii-B, iv-D
2) 2-Bromo-4-carbamoyl-5- chlorocarbonyl-3-
4) i-A, ii-C, iii-D, iv-B formylhexanoic acid
Ans : 3) i-C, ii-A, iii-B, iv-D
15
3) 2- chlorocarbonyl-3-carbamoyl-4-formyl-5- 59. An ideal gas undergoes isothermal expansion
bromohexanoic acid from (10 atm, 1L) to (1atm, 10L) either by
4) 4-Formyl-2- chlorocarbonyl-3-carbamoyl- path –I [infinite stage expansion] or by path –
II [first against 5 atm and then against 1atm)
5-bromohexanoic acid
q path I
Ans : the value of is
1) 5-Bromo-3-carbamoyl-2-chlorocarbonyl-4- q path II
formylhexanoic acid 1) 1.77 2) 0.56
Solution : 3) 0.177 4) 5.6
Ans : 1) 1.77
Solution :
V2
2.303PV log
q path I (rev) w rev V1
q path II (irri) w irri (PV)1 (PV) 2
5-Bromo-3-carbamoyl-2-chlorocarbonyl-4-
10
formylhexanoic acid 10 x1 x 2.303 x log
= 1 10 x 2.303 = 1.77
57. The standard hydrolysis constant of anilinium
5(2 1) 1(10 2) 13
acetate Ka (CH3COOH) = 1.8 x 10-5 M, Kb
60. A mixture of XHC2O4 and YHC2O4.H2C2O4
(Aniline) = 4.6 x 10-10 M at 25oC is
required equal volumes of 0.2N KMnO4 and
1) 1 2) 1.21 0.12N NaOH separately. The molar ratio of
3) 1.35 4) 2.6 x 10-2 YHC2O4.H2C2O4 and XHC2O4 in the mixture
Ans : 2) 1.21 is? [X, Y are having outermost electronic
Solution : configuration of ns1]
1) 3 : 1 2) 1 : 6
Kw
Kh = 3) 6 : 1 4) 1 : 3
Ka x Kb
Ans : 4) 1 : 3
1.0 x 1014 Solution :
=
1.8 x105 4.6 x1010 Let the number of moles of XHC2O4 and
= 1.21 YHC2O4.H2C2O4 are a, b
58. Which of the following is incorrect order? N1V1(L) n2 x nf2
1) Al < Al+ < Al2+ (Ionisation energy) KMnO4 (vs) XHC2O4 + YHC2O4.H2C2O4
2) Cl– < S2– < P3– (Ionic radii) 0.2 x V = a x 2 + b x 4 2a + 4b ----(1)
NaOH (vs) XHC2O4 + YHC2O4.H2C2O4
3) B < C < S < I (Electronegativity)
0.12 x V = 1 x a + 3 x b a + 3b ----(2)
4) Ne > Kr > Xe > He (Magnitude of egH)
From (1) / (2)
Ans : 3) B < C < S < I (Electronegativity)
2a 4b 0.2V 5
Solution :
a 3b 0.12V 3
Order of electronegativity: 6a + 12b = 5a + 15b
B<C=S=I b
2 2.5 2.5 2.5
a = 3b 1: 3
a
16
61. The molecular formula of the compound,
which contains 6 x 1023 atoms of carbon,
22.4L of H2 gas at STP and 16g of oxygen
atom can be
Ans : 4)
1) CH3CHO 2) CH3OCH3
3) CH3COOH 4) CH3CH2OH
Ans : 3) CH3COOH
Solution : Solution :
MF can be CH3COOH
62. Identify the incorrect combination in the
following
64.
1) Hypo-valent molecules AlCl3, BeCl2
2) Odd electron molecule NO, NO2
3) Super octet molecules PF5, SF6 Identify incorrect statement about electrophilic
4) Octet molecules SF4, XeF2 substitution and Benzene?
Ans : 4) Octet molecules SF4, XeF2 1) P has meta directing group
Solution : 2) Q has o & p-directing group
SF4, XeF2 are does not obey’s octet rule. 3) -electron density : P > Q > R
63. Which among the following is less stable 4) Reactivity towards ESR : Q > R > P
resonating structure of p-nitro phenol?
Ans : 3) -electron density : P > Q > R
Solution :
COOH
P is and Q is
1) 2)
65. What is the oxidation state of ‘A’ in the
molecule ABO3, in which oxidation state of
‘B’ is equal to the lowest oxidation state of
individual ‘Br’ in Br3O8? [Group valency of
‘A’ is 7]
3) 4) 1) 4 2) 2
3) 2.5 4) 7
Ans : 2) 2
17
Solution : 3
AB3(g) A(g) + B2(g)
2
Br3O8 : 300 0 0
3
300-p p p
Lowest oxidation state of individual 2
Br is 4 3 3
PT = 300 – p + p + p = 300 + p = 650
Then, ABO3 2 2
x+4–6=0 700
p= = 233 (approx.)
x=2 3
66. Which is the incorrect reaction? 233
= 100
300
1) α = 77.7%
68. ‘X’ mole of photons would contain sufficient
energy to raise the temperature of 100gr of
water from 75oC to 100oC. The value of ‘X’ is
[Specific heat of water is 4.18 J g–1 k–1 and
2)
frequency of light used is 1.0 x 1010 Hz]
1) 3.8 x 10–4 2) 2618
Br
3) 1577 x 1024 4) 15.77 x 1020
3) Br2/H2O
Ans : 2) 2618
OH Solution :
E = mC T
4) E = 100 x 4.18 x 25 = 10,450 Joule
E = nh
E 10450
n=
Ans : 4) h 6.625 x1034 x1010
= 1577 x 1024
Solution :
n 1577 x1024
Addition of Br2 / CCl4 is anti-addition X = moles of photon =
No 6.023 x1023
3
67. AB3(g) dissociates as AB3(g) A(g) + B2(g). If = 2618
2
the initial pressure of AB3 is 300 torr and the 69. The IE1 of 2nd period elements plotted against
total pressure developed at equilibrium is 650 atomic numbers shown below
torr, what fraction of AB3(g) is dissociated?
1) 22.3% 2) 77.7%
3) 25% 4) 50%
Ans : 2) 77.7%
Solution :
18
Select the correct option about X, Y, Z and A
1) X, Y are Be, N respectively 71.
2) Z, A are N, F respectively
3) X, Y, Z are Be, N, C respectively
4) Y, A are N, F respectively
A, B and C are in the given equation
Ans :
respectively
2) Z, A are N, F respectively
1) 2-bromo-2, 3-dimethyl butane, 2, 2-
Solution : dimethyl propanoic acid, isobutane
IE1 order of second period elements is
2) 2-bromo-3, 3-dimethylbutane and 2, 2-
Li < B < Be < C < O < N < F < Ne dimethyl propanoic acid, ethane
3) 2, 3-dimethyl-1-bromo butane and ethanoic
acid, isobutane
4) 2-bromo-2, 3-dimethyl butane and 2, 2-
dimethyl propanoic acid, ethane
Ans : 4) 2-bromo-2, 3-dimethyl butane and 2,
2-dimethyl propanoic acid, ethane
Solution :
Solution :
Eka – aluminium Gallium
1)
Eka – Silicon Germanium
Z 105 Dubnium
19
Solution :
NaOH CaO
CH3CH2CH2COONa
2)
CH3CH2CH3 + Na2CO3
8
C3 H8(g) 3 O 2(g) 3CO 2 4H 2 O( l )
propane 4
74. Given that,
Ksp of AB2 = 4 109 M3
3)
Ksp of AB3 = 2.7 1011 M4
Ksp of AB4 = 2.56 1018 M5
Calculate the solubility of the salt [which has
lowest solubility from given above] in 0.2M
XB2 salt solution?
4)
[Assume that ‘B’ in all given compounds is
uninegative ion]
1) 108M 2) 1014M
3) 1016M 4) 1015M
Ans : 3) 1016M
Ans : 4)
Solution :
1
K sp AB2 3
Ksp AB2 sS
4
Solution :
1
4 109 3 3
= 10 M
4
1
K sp AB3 4
Ksp AB3 sS
27
1
NaOH CaO
73. X
Y Na 2 CO3 . 2.7 1011 4 3
(Alkane) = 10 M
27
One mole of ‘Y’ in the given reaction on
1
complete combustion required 5 moles of 2.56 1018 5
oxygen. Then compound ‘X’ is Ksp AB4 sS
256
1) Sodium ethanoate = (1020)1/5 = 104M
2) Sodium propanoate So ‘S’ of AB4 is less
3) Sodium butanoate Hence
4) Sodium farmate Ksp AB4 = [A+4][B]4 = S(S + 0.4)4 = S(0.4)4
K sp AB4 2.56 1018
Ans : 3) Sodium butanoate S= 4 4 = 1016 M
4
4 10 256 10
20
75. According to photo electric effect concept, Ans : 1) (A) is false (R) is true
which of the following is incorrect? Solution :
1) Number of electrons ejected increases with In the equilibrium process H2O(s) H2O(l), If
increase in brightness of incident light
pressure of the system increases, more
quantity of water is present and boiling point
of water increase.
2) Density of ice less than density of water,
hence increase in pressure, equilibrium shifted
towards forward direction.
electrons are ejected from both metal A and B 77. N2 and O2 are converted into mono cations,
3) There is no time lag between the striking of N 2 and O 2 respectively. Which of the
light beam [with suitable frequency] and the following is wrong statement?
ejection of electrons from the metal 1) In N 2 formation, N – N bond length
4) Both (1) and (3) increases
Ans : 2)In O 2 formation, O – O bond order
increases
3)In O 2 formation, para-magnetism decreases
2)
4) N 2 becomes diamagnetic
Ans :4) N 2 becomes diamagnetic
electrons are ejected from both metal A and B Solution :
Solution :
N2 N 2
Condition for the ejection of electrons is >
B.O = 3 B.O = 2.5
o and λo > λ
Diamagnetic Paramagnetic
76. Assertion (A) : In the equilibrium process
78. The equilibrium constant for the following
H2O(s) H2O(l), If pressure of the system reactions are given at 25oC.
increases, more quantity of water is present 2A B + C K1 = 1.0
and boiling point of water decrease.
Reason (R) : Density of ice less than density 2B C + D K2 = 16
of water, hence increase in pressure 2C + D 2P K3 = 25
equilibrium shifted towards lesser volume
The equilibrium constant for the endothermic
side.
1
1) (A) is false (R) is true reaction : P A + B at 35oC is
2
2) Both (A) and (R) are true but (R) is not a
1
correct explanation of the (A) 1) 2) > 0.05
20
3) (A) is true but the (R) is false
1
4) Both (A) and (R) are false 3) 4) 0.01
42
21
Ans : 2) > 0.05 80. The de-Broglie wavelength associated with a
Solution : ball of mass 1 kg having kinetic energy 0.5J is
2A B + C K1 = 1.0 1) 6.626 1010 ym 2) 6.626 1010 Ym
carbocation substitution
22
KMnO4
C6H5CH3 C6H5COOH -Oxidation Ans : 4) (a – b) kJ mol–1
H 2SO4
ZnHg,HCl
Solution :
C6H5COCH3 C6H5CH2CH3 -
solH = H(Lattice) + H(Hyd)
Reduction
= (a) + (–b)
HBr
C6H5CH = CH2
Peroxide
C6H5CH2CH2Br - = (a – b) kJ mol–1
Free radical addition
HBr
CH3 – CH = CH2 CH 3 CH CH3 -
|
Br
Electrophilic addition
82. The sum of the number of dative bonds
85. Which of the following reaction will lead to
present in all the given species are
the creation of two chiral centres in the
Al2Cl6, [Al(H2O)6]+3, CO, NH 4 product?
1) 5 2) 9 CCl
4
1) CH3CH = CHCH3 + Br2
3) 8 4) 10
CCl
4
Ans :4) 10 2) CH3CH2CH = CH2 + Br2
Solution : H
3) CH2 = CH2 + HBr
Number of dative bonds in the given species
H
4) CH3CH = CHCH3 + HBr
Al2Cl6 = 2, CO = 1, [Al(H2O)6]+3 = 6, NH = 1 4
CCl
4
Ans : 1) CH3CH = CHCH3 + Br2
83. Given
xNa2HAsO3 + yNaBrO3 + zHCl NaBr + Solution :
Br2 / CCl4
H3AsO4 + NaCl CH3CH = CHCH3
The values of x, y and z in the above redox * *
reaction are respectively CH3 CH CH CH3
1) 2, 1, 3 2) 3, 1, 6 | |
Br Br
3) 2, 1, 2 4) 3, 1, 4
(2 chiral carbons)
Ans :2) 3, 1, 6
86. Which of the following mixture gives a buffer
Solution :
solution with pH = 4.75 [Given that pKb of
3Na2HAsO3 + 1NaBrO3 + 6HCl
CH3COOH is 9.25]
NaBr + 3H3AsO4 + 6NaCl
1) 0.2M, 0.4ml CH3COOH and [Link], 0.1ml
84. Consider the dissolution of MX(s). Calculate
NaOH
the enthalpy of solution of MX(s) from the
2) 0.2M, 0.5ml CH3COOH and [Link], 0.5ml
following
NaOH
M (g) X (g) MX (s) + a kJ mol–1
3) 0.5M, 0.2ml CH3COOH and 0.2M, 0.5ml
M (g) X (g) M (aq)
X (aq) + b kJ mol–1 NaOH
3) (b – a) kJ mol–1 4) (a – b) kJ mol–1
23
Ans : 2) 0.2M, 0.5ml CH3COOH and [Link], Ans : 3) Statement I is true, II is false
0.5ml NaOH Solution :
Solution : 2H2 + O2 2H2O
CH3COOH + NaOH CH3COONa + H2O 2 : 1
0.2M, 0.5ml 0.1 x 0.5 30 ml : 15 ml 30 ml H2O + 5ml of O2
0.1 millimole 0.05 milli 0.05 milli Limiting reagent completely consumed
[CH 3COONa] 89. The heat of formation of ethane is -19.5
pH = pKa + log
[CH 3COOH] kcal/mol. Bond energies of H-H, C-H and C-C
0.05 bonds are 104.2, 99 and 80 kcal/mol
4.75 log respectively. Calculate the heat of atomization
0.05
of graphite
pH = 4.75
1) 171 kcal 2) 271 kcal
87. Choose the incorrect from the following
3) 100 kcal 4) can’t be predicted
a) Pb3O4 proceeds differently with HCl and
HNO3 Ans : 1) 171 kcal
b) PbO2 reaction with HCl is a redox reaction Solution :
where as PbO2 with HNO3 is an acid-base 2C(s) + 3H2(g) C2H6(g)
reaction fH = HB.E (Reactants) - HB.E (Products)
c) Hydrolysis of XeF6 is an example for fH = (2Hatomization(c) + 3BEH-H)-(BEC-C + 6BEC-H)
disproportination reaction -19.5 = 2x + 3(104.2) – 80 – (6 x 99)
d) In a reaction 2Cu2O(s) + Cu2S(s) 6Cu(s) + -19.5 = 2x – 361.4
SO2(g) ; Cu2O is act as reductant and Cu2S is 2x = 361.4 – 19.5 = 341.9
act as an oxidant
x = 171 kcal
1) a, c, d 2) b, c
90. A, B, C, D are represents excited states at
3) c, d 4) a, d which the molecules CH4, PCl5, XeF2 and SF4
Ans : 3) c, d are formed. The values of A, B, C, D
Solution : respectively are
XeF6 + 3H2O XeO3 + 6HF [Neither 1) 1, 1, 1, 1 2) 1, 2, 1, 1
oxidation nor reduction] 3) 1, 1, 2, 1 4) 2, 1, 1, 2
Cu2O is oxidant, Cu2S is reductant Ans : 1) 1, 1, 1, 1
88. Statement I : At STP if 30 ml of H2 gas and Solution :
20 ml of O2 gas react to form water, 5 ml of Molecule At which it formed
O2 is left at the end of reaction. CH4 st
1 excited state (A)
Statement II : Limiting reagent will remains
PCl5 1st excited state (B)
at the end of reaction.
XeF2 1st excited state (C)
1) Both statements are true
2) Both statements are false SF4 1st excited state (D)