05-11-2025

6001CJA10102225001RT JA

PHYSICS

SECTION-I

1) N(<100) molecules of a gas have speeds 1,2,3.... N (in km/s). Then:

(A) rms speed and average speed of molecules is same

(B)
Ratio of rms speed to average speed is

(C)
Ratio of rms speed to average speed is

(D)
Ratio of rms speed to average speed of molecules is

2) Two containers of equal volume contain the same gas at pressures P1 and P2 and absolute
temperatures T1 and T2, respectively. On joining the vessels, the gas reaches a common pressure P
and common temperature T. The ratio P / T is equal to:

(A)

(B)

(C)

(D)

3) An air bubble of volume V0 is released by a fish at a depth h in a lake. The bubble rises to the
surface. Assume constant temperature and standard atmospheric pressure (P) above the lake. The
volume of the bubble just before touching the surface will be (density of water is (Neglect surface
tension effect) :

(A)
(B)

(C)

(D)

4) A Carnot’s heat engine works between the temperatures 427°C and 27°C. What amount of heat
should it consume per second to deliver mechanical work at the rate of 1.0 kW?
(A) 0.417 kcal/s
(B) 4.17 kcal/s
(C) 41.7 kcal/s
(D) 0.212kcal/s

5) A cyclic process is shown on the V-T diagram. The same process on a P-T diagram is shown by :

(A)

(B)

(C)

(D)

6) A lead bullet of unknown mass is fired with a speed of into a tree in which it stops.
Assuming that in this process two-third of heat produced goes into the bullet and one-third into
wood. The temperature of the bullet rises by: (Specific heat of lead

(A) 140ºC
(B) 106ºC
(C) 90ºC
(D) 100ºC

7) Two rods of lengths and coefficients of thermal conductivities are kept in

end to end contact with each other. The equivalent thermal conductivity is (Rods have same cross
sectional area) :

(A)
(B)

(C)

(D)

8) When the temperature of a rod increases from t to its moment of inertia increases from

If be the coefficient of linear expansion of the rod, then the value of is :

(A)
(B)

(C)

(D)

9) A bimetallic strip consists of metals X and Y. It is mounted rigidly at the base as shown. The metal
X has a higher coefficient of expansion compared to that for metal Y. When bimetallic strip is placed
in a cold bath:

(A) It will bend towards the right

(B) It will not bend but shrink
(C) It will bend towards the left
(D) It will neither bend nor shrink

10) Two holes of unequal diameters are cut in a metal sheet. If the sheet is
heated:

(A) Both will decrease

(B) Both d1 and d2 will increase
(C) d1 will increase, d2 will decrease
(D) d1 will decrease, d2 will increase

11) Consider the following two statements and choose the correct answer.
I. If heat is added to a system, its temperature must always increase.
II. If positive work is done by a system in thermo-dynamic process, its volume must increase.

(A) Both I and II are correct

(B) I is correct, but II is incorrect
(C) II is correct, but I is incorrect
(D) Both I and II are incorrect

12) A black body has a wavelength of at temperature 2000 K. Its corresponding wavelength at
temperature 3000 K will be:

(A)

(B)

(C)

(D)

13) Pure Si at 300 K has equal electron (ne) and hole (nh) concentrations of Doping
by indium increases nh to Calculate ne in the doped Si-

(A)
(B)
(C)
(D)

14) A wire elongates by when a load w is hanged from it. If the wire goes over a pulley and
two weights w each are hung at the two ends, the elongation of the wire will be (in mm)

(A)
(B)
(C) zero

(D)

15) Radiation coming from transitions of electrons from n = 2 to n = 1 of hydrogen atoms fall on
He+ ions in n = 1 and n = 2 states. The possible transition of electrons helium ions as they absorb
energy from the radiation is

(A)
(B)
(C)
(D)

16) The circuit has two oppositely connected ideal diodes in parallel. What is the current flowing in
the circuit?

(A) 1.71 A
(B) 2.00 A
(C) 2.31 A
(D) 1.33 A

17) Truth table for system of four NAND gates as shown in figure is

(A)

(B)

(C)
(D)

18) Assume that a neutron breaks into a proton and an electron. The energy released during this
process is (mass of neutron mass of proton mass of
electron )

(A) 0.73 MeV

(B) 7.10 MeV
(C) 6.30 MeV
(D) 5.4 MeV

19) If the kinetic energy of a free electron doubles, its de-Broglie wavelength changes by the factor

(A)

(B) 2

(C)

(D)

20) Suppose an electron is attracted towards the origin by a force k/r, where k is a constant and r is
the distance of the electron from the origin. By applying Bohr model to this system, the radius of the
nth orbital of the electron is found to be rn and the kinetic energy of the electron to be Tn. Then
which of the following is true?

(A)

(B) Tn is independent of n,

(C)

(D)

SECTION-II

1) One mole of an ideal monoatomic gas undergoes a process described by the equation
The heat capacity of the gas during this process is nR. Find n ?

2) In an adiabatic process where pressure is increased by If then the volume decreases

by about Find K.

3) The area of cross-section of a railway track is 0.01 m2. The temperature variation is 10°C.
Coefficient of linear expansion of material of track is 10-5/°C. The energy stored per metre in the
track is ________ J/m.
(Take, Young's modulus of material of track is 1011 Nm-2)

4) The of molybdenum has wavelength 0.071 nm. If the energy of a molybdenum atom
with a K electron knocked out is 27.5 keV, the energy of this atom when an L electron is knocked out
will be _________ keV.
(Round off to the nearest integer) [Take, ]

5) One end of a horizontal thick copper wire of length 2L and radius 2R is welded to an end of
another horizontal thin copper wire of length L and radius R. When the arrangement is stretched by
a applying forces at two ends, the ratio of the elongation in the thin wire to that in the thick wire is:

CHEMISTRY

SECTION-I

1) For combustion of 1 mole of ammonia at 25°C the value of heat change in reaction at constant
volume is ___?

(R = 2 cal K–1 mol–1, ΔH° = –9.06 kcal/mol)

(A) –7140 cal

(B) –4113 cal
(C) –8314.6 cal
(D) –9000 cal

2) The formation of ethane takes place by the following reaction at 25°C

Using following data, predict if reaction is endothermic or exothermic

; ΔH = –94.14 kcal

;
ΔH = –68.47 kcal

;
ΔH = –373.3 kcal

(A) Can’t be predicted

(B) Exothermic
(C) Endothermic
(D) ΔH = 0

3) Bond dissociation energies of H2 and Cl2 are 104 kcal/mol and 58.0 kcal/mol respectively. If
enthalpy of formation of HCl is –44 kcal. The bond dissociation energy of HCl (in kcal/mol) is

‘x’, then is

(A) 125
(B) 52
(C) 25
(D) 29

4) Considering list I and list II, select the correct option containing all the correct combinations, List-
(ll) contains the chemical reactions and List-(l) contains the characteristic enthalpy change
pertaining to these reactions.

List - I (Type of enthalpy List - II (chemical

change) reaction)

A Enthalpy of formation I

Enthalpy change
B II
during phase transformation

C Enthalpy of atomisation III

Standard enthalpy of combustion

D IV
of a compound
(A) A - I, B - III, C - II, D - IV
(B) A - II, B - IV, C - III, D - I
(C) A - II, B - III, C - IV, D - I
(D) A - I, B - III, C - IV, D - II

5) The values of ΔH and ΔS of a certain reaction

are −400 kJ/mol and − 20 kJ/mol/K respectively. The temperature below which the reaction
spontaneous is

(A) 100 K
(B) 20°C
(C) 20 K
(D) 120°C

6) Statement - I : Greater the disorder in an isolated system, the higher is the entropy.
Statement - II : For both reversible and irreversible expansion of an ideal gas, under isothermal
condition,
(A) Statement I and Statement II are true; Statement II is correct explanation for Statement I
Statement I and Statement II are true; Statement II is not the correct explanation
(B)
for Statement I
(C) Statement I is true; Statement II is false
(D) Statement I is false; Statement II is true

7) 5 moles of an ideal monoatomic gas absorbs x Joule of heat when heated from 25° C to 30° C at
constant volume. The amount of heat absorbed when 2 moles of the same gas is heated from 25° C
to 30° C at constant pressure, is:

(A)

(B)

(C)

(D)

8) Two moles of an ideal gas is compressed isothermally and reversibly from a volume 2L to 0.5L at
initial pressure of 1 atm . The work done by gas is (given, 1L atm = 101 J) [magnitude value]

(A) 280 J
(B) 150 J
(C) 184 J
(D) 250 J

9) Some properties of system are given below, out of which ‘x’ is the number of extensive
properties and ‘y’ is the number of intensive properties. Find (x-y).

Boiling point, surface tension, heat capacity, Gibbs free energy,

vapour pressure, refractive index, density, temperature, entropy,
enthalpy, mass, length, volume, area, internal energy.
(A) 5
(B) 6
(C) 3
(D) 4

10) If the z-axis is taken as the internuclear axis, then which of the following atomic orbitals is a non-
bonding combination?

(A) s and px
(B) px and pz
(C) px and py
(D) All of these

11)
In the following compounds, which compound has maximum covalent character :-

(A) KCl
(B) LiCl
(C) RbCl
(D) CsCl

12) Assertion (A) : F atom has more electron affinity than Cl atom.
Reason (R) : Among halogens F atom is small in size.

(A) Both A and R are true and R is the correct explanation of A

(B) Both A and R are true but R is not the correct explanation of A
(C) If A is true but R is false
(D) If A is false but R is true

13) Among the following, the incorrect combination is ?

(A) XeF4 – Square planer

–
(B) NO3 – Trigonal planer
(C) PCl5 – Pentagonal bipyramidal
(D) H2O – Angular

14) The boiling point of p-nitrophenol is higher than that of o-nitrophenol because :

(A) NO2 group at p-position behaves in a different way from that at o-position
(B) Intramolecular hydrogen bonding exists in p-nitrophenol
(C) There is intermolecular hydrogen bonding in p-nitrophenol
(D) p-nitrophenol has a higher molecular weight than o-nitrophenol

15) Choose the correct matching option:

List–I List–II

sp3d hybridised
(P) XeF4 (1) with 2 lone pair
on central atom

sp3d2 hybridised
(Q) BrF5 (2) with 2 lone pair
on central atom

sp3 hybridised
(R) ClF3 (3) with 1 lone pair
on central atom

sp3d2 hybridised
(S) (4) with 1 lone pair
on central atom
(A) P → 1, Q → 2, R → 3 , S → 4
(B) P → 2, Q → 4, R → 1 , S → 3
(C) P → 2, Q → 4, R → 3 , S → 1
(D) P → 3, Q → 1, R → 4 , S → 2

16)

Which of the following is CORRECT stability order ?

(A) SiCl2 < GeCl2 < PbCl2 < SnCl2

(B) GeCl2 < PbCl2 < SnCl2 < SiCl2
(C) SiCl2 < GeCl2 < SnCl2 < PbCl2
(D) GeCl2 < SiCl2 < PbCl2 < SnCl2

17) Which of the following acid is monobasic?

(A) Hypophosphorous acid (H3PO2)

(B) Orthophosphoric acid (H3PO4)
(C) Pyrophosphoric acid (H4P2O7)
(D) Hypophosphoric acid (H4P2O6)

18) Which of the following is an amphoteric in nature?

(A) N2O3
(B) P2O3
(C) Sb2O3
(D) Bi2O3

19) Which of the following property is not shown by concentrated

(A) Oxidising
(B) Dehydrating
(C) Reducing
(D) Acidic

20) The decreasing order of number of lone pair of xenon in following compound is.

(A) XeF2 > XeF4 > XeO3 > XeO4

(B) XeF6 > XeOF4 > XeO3F2
(C)
(D) > XeF2 > XeO3 > XeO4

SECTION-II

1) In the reaction 120.4 kJ energy is evolved when 8g of MgO(s) is formed under standard condition.
The of MgO(s) is X kJ/mol. Find the value? [Atomic mass : Mg = 24 ; O = 16]

2) For complete combustion of ethene.

the amount of heat produced as measured in bomb
–1
calorimeter is 1406 kJ mol at 300K. The minimum value of TΔS needed to reach equilibrium is (-)
_____ kJ (Nearest integer) (Given : R = 8.3 JK–1 mol–1)

3) Temperature of one mole of Helium gas is increased by 1°C, find the increase in internal energy
in cal.[ R = 2 cal K–1 mol–1]

4) Find the number of atoms are lying in the same plane of C2(CN)4 . Report your Answer after
dividing after 2.

5)
The number of bonds at central atom in missing product is ______ ?

MATHEMATICS

SECTION-I

1) The equation of the circle which passes through the point (2a,0) and whose radical axis with

respect to the circle is the line , is

(A)
(B)
(C)
(D) None of these

2) The length of the common chord of the two circles and

(A)

(B)

(C)

(D)

3) The equation of the circle through the point of intersection of and

and touches the line is
(A)
(B)
(C)

(D)

4) The number of common tangents to circles and

(A) 1
(B) 2
(C) 3
(D) 4

5) The point from which the lengths of the tangents to the following circles
, & are equal, is

(A)
(B)
(C)
(D)

6) The bisector of acute angle formed between the lines and has the
equation

(A)
(B)
(C)
(D)

7) The equation of two equal sides of an isosceles triangle are and and its
third side passes through the point , then the equation of third side is

(A)
(B)
(C)
(D)

8) If be the midpoints of the sides of the triangle, its centroid is at

(A)
(B)
(C)
(D) None of these

9) If the points (1, 2) and (3,4) be on the same side of the line 3x 5y + a = 0, then
(A) 7 < a < 11
(B) a = 7
(C) a = 11
(D) a < 7 or a > 11

10) If z is a complex number of unit modulus and argument , then equals

(A)

(B)

(C)
(D)

11) If and Z2 be two complex numbers such that is a purely imaginary number, then

is equal to:

(A) 1
(B) 5
(C) 3
(D) 2

12) If a complex number z satisfies the equation , then is equal to:

(A)
(B)
(C) 1
(D) 2

13) Let , where z is any non-zero complex number. The set

is equal to:

(A)
(B)
(C)
(D)

14) If then is equal to

(A) 0
(B) 1
(C) 2
(D) 3

15) If p, q, r are real and distinct numbers, then the value of is

(A) 1
(B) pqr
(C) 2
(D) 3

16) The perpendicular bisector of the line segment joining P (1, 4) and Q (k, 3) has y intercept 4.
Then a possible value of k is-

(A) 1
(B) 2
(C)
(D)

17) Let A & B are two non singular matrices of order 3 such that A + B = I & A + B–1 = 2I, then
–1

|adj(4AB)|, is (where adj(A) is adjoint of matrix A) :

(A) 4
(B) 16
(C) 64
(D) 128

18) How many 3 × 3 matrices M with entries from {0, 1, 2} are there, for which the sum of the
diagonal entries of MTM is 5 ?

(A) 198
(B) 126
(C) 135
(D) 162

19) Let A and B be two non singular matrices of order 2 such that

.
If

B= and trace(A)= , then is equals to: ( denote determinant of matrix A)

(A) 2
(B) 1
(C)

(D)

20) If then is equal to-

(A) a, b, c
(B) 1
(C) – 1
(D) 0

SECTION-II

1) A rectangle is inscribed in a circle with a diameter lying along the line 3y = x + 7. If the two
adjacent vertices of the rectangle are ( 8, 5) and (6, 5), then the area of the rectangle (in sq. units)
is:

2) If are the distinct roots, of the equation , then is equal to:

3) If
Then a+b is equal to

4) Let A = and suppose that det.(A) = 2 then the det.(B) equals,

5)

Let then the value of , is

(Where tr(A) denotes trace of matrix A)
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D D D A A C D A C B C A A A D B A A C B

SECTION-II

Q. 21 22 23 24 25
A. 1 18 5 10 2

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B C B C C C A C D B D C C B C A C C A

SECTION-II

Q. 46 47 48 49 50
A. 10 1411 3 5 1

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D C C C C A A D C A A D C D D C A C D

SECTION-II

Q. 71 72 73 74 75
A. 84 1 0 -16 100
 SOLUTIONS

PHYSICS

1)

2) Number of moles in first vessel

Number of moles in second vessel

If both a are joined together, then quantity of gas remains same, i.e.,

3) As the bubble rises the pressure gets reduced for constant temperature, if P is the
standard atmospheric pressure, then

or

4) The efficiency of the heat engine is

But

Thus, the engine would require 417 cal of heat per second, to deliver the requisite amount of
work.
5)

For AB and DC process

Pressure = constant.
Satisfy by only option A.

6) Since, specific heat of lead is given in joule. Specific heat of lead

The two-third of head produced goes into the bullet.

So,

7) For end to end (series combination)

Equivalent thermal conductivity,

8) Moment of inertia of a rod,

On differentiating w.r.t.l, we get

9) The metal X has a higher coefficient of expansion compared to that for metal Y so, on
placing bimetallic strip in a cold bath, X will shrink more than Y. Hence, the strip will bend
towards the left.

10) If the sheet is heated then both will increase since the thermal expansion of
isotropic solid is similar to true photographic enlargement.

11) In cyclic and isothermal processes, energy supplied to a system does not change
temperature of the system.
If gas expands then volume of gas system increases.

12) According to Wien’s displacement law,

or
 or

14) Let us consider the length of wire as L and cross-sectional area A, the material of wire has
Young's modulus as Y.

15)

16) In the given, circuit diode D1 is reverse biased while D2 is forward biased, so the circuit can
be redrawn as

[ for ideal diodes, reverse biased means open and forward biased means short]
Apply AVL to get current following through the circuit

or
17)

18)
19)

20)

21) For polytropic process of index

Specific heat Capacity

Process,

For monoatomic gas, f = 3

So,

22) For an adiabatic process,

For small change

Thus, volume decreases by

 23)

24)

CHEMISTRY

26) ΔH = –9.06 kcal = –9.06 × 103 = –9060 cal

= –9060 + 745.37
= –8314.62 cal

27) ΔH = –ve for exothermic reaction

28)
29 + 52 - x = - 44
x = 81+ 44
x = 125 k cal

29) Enthalpy of formation

Enthalpy of atomisation
Enthalpy of combustion

30) ΔG= ΔH - TΔS

ΔH = -ve, ΔS = -ve
Condition for spontaneous reaction is
TΔS < ΔH

31) Entropy is a property representing the state of disorder of a system

For reversible process;

32)
... (1)

... (2)

33)

T = 12.18 K
for isothermal reversible process

W = 281.2 J

34) x = 9, y = 6
= (x - y) = 3
35)

36)

37)

Cl > F : electron affinity

Atomic size : F < Cl < Br < I

38)

PCl5 – Pentagonal bipyramidal

39)

There is intermolecular hydrogen bonding in p-nitrophenol

40)

41) SiX2 < GeX2 < SnX2 < PbX2

Stability of +2 oxidation state.

43) Question Explanation:

Amphoteric oxide among following.

Concept:
This question is based on going down the group metallic and basic nature of oxide increases.

Solution:
∴ Sb2O3 is amphoteric.

Final Answer:
The correct option is (3).

46)
40g → ?
X = 602 kJ/mol

47)

48)

= 3 Cal

49)

50)
 tetrahedral

MATHEMATICS

51) Let circle be

Given circle is
Passes through (2a,0)

Required circle is

52)

53) Equation of family of circle

use length of from centre to x+2y=0 is equal to radius to get value.

54)

55) Radicle centre

56)

57) Equation of third side will be to angle bisector

Using point slope form of straight line.

58) Centroid of triangle will be same as centroid of triangle joining mid points.

59) for same side of line

60)

As, if

61)

62)

Comparing Real and Imaginary Part

63)
at

64)

65) If a+b+c = 0
Then

66) Equation of bisector

as it passes through

67) A–1 + B–1 = 2I

⇒ I + AB–1 = 2A
⇒ B + A = 2AB or 2AB = I

68) 9C5 + 9C1 8C1 = 126 + 72 = 198

69) Post Multiply by B–1

9A2 – 6A + I =

|3A – I| = ± 9 ......(i) Let

3A – I =
|3A – I| = 9ad – 3(a + d) + 1 – 9 bc = ±9

a+d= (given)
9 |A| = 0 or 18
|A| = 2

70)
71)

Let vertex c is (6, K) then center of circle

it lies on diameter

So AB = 14 and BC = 6
Area

72)

where is imaginary cube root of unity.

Let

If we consider
we get the same results.

73)
74) det(B) =

= (4)(2)(–1)

=–8 =–8

75)

A2 = ⇒