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0% found this document useful (0 votes)
2 views31 pages

Solution

The document contains a series of physics, chemistry, and mathematics questions and answers, organized into sections. It includes multiple-choice questions covering topics such as projectile motion, wave functions, and polynomial equations. The answer keys for each part are provided at the end of the document.

Uploaded by

shashidelhi0212
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

17-05-2026

9610WJA802528260006 JA

PART 1 : PHYSICS

SECTION-I

1)

A particle is projected vertically upwards with velocity u from a point O. When it returns to the point
of projection then for entire journey :- (g = 10 m/s2)

(A) Its average velocity is zero


(B) Its displacement is zero
(C) Its average speed is u/2
(D) Its average speed is u

2) If displacement along x-axis is defind as find value(s) of t for which


velocity is zero :-

(A) t = 1
(B) t = 2
(C) t = 3
(D) t = 4

3)

The path of a projectile thrown vertically upwards is as shown :-

(A) time taken from A to B = time taken from C to D


(B) time taken from A to C = time taken from B to D
(C) velocity at B = velocity at C
(D) speed at A = speed at D

4) Position of a particle is given as


x= – 2t3 + – 6t + 5 Choose the CORRECT option(s) :-

(A) The particle moves on a straight path.


(B) The particle changes its direction of motion at t = 1, 2 & 3 sec.
(C) Minima of acceleration occurs at t = 2s.
Distance travelled by particle from 0 to 2 sec is greater than magnitude of displacement from 0
(D)
to 2s.

5) Acceleration of a particle moving along x axis is given as a = 2t – 1 m/s2. Velocity of particle is


zero at t = 0. Which of the following statements is/are correct :-

(A) At t = 1 sec, particle is at rest.


(B) Particle starts moving in +x direction.
(C) After t = 1 sec particle is moving in +x direction.
(D) Acceleration of particle is increasing with time.

6) Let and denote the velocity and acceleration respectively of a body in one-dimensional motion
:-

(A) must decrease when


(B) Speed must increase when
(C) Speed will increase when both and are < 0

(D) Speed will decrease when and

SECTION-III

1) In a new system of units, mass, acceleration & frequency are taken as fundamental units. If unit of
mass is 100 g, unit of acceleration is 2 m/s2 and unit of frequency is 4 sec–1, in this new system of
units, then the value of 10 J in this new system is K × 100. Fill K in OMR Sheet.

2) A gas bubble formed from an explosion under water oscillates with a time period proportional to
PadbEc, where P is the static pressure, d is the density of water and E is the energy of explosion.
Then, find the value of (–6a + 2b + 3c).

3) The sum of two unit vectors is a unit vector. If the magnitude of their difference is x, then find
value of x2.

4) Two particles are moving with velocity m/s and m/s respectively.
Time at which they are moving perpendicular to each other is ________ (sec.) (Round off to nearest
integer)

5)
If and are two non-collinear unit vectors and if , then the value of .

is . Find the value of x.

6)

A body is thrown up vertically with 100 m/sec. It travels a distance 5 m in last second of its' journey
while going up, (before coming to rest instantaneous). If it is thrown up by 500 m/sec, how much
distance (in meter) it travel in last second of journey while going up.

SECTION-II

1) Force acting on a particle is given by then component of force along displacement

of particle is given by if displacement of particle is then value of is


__________.

2) A person moved from A to B on a circular path as shown in figure. If the distance travelled by him
is 60 m, then the magnitude of displacement would be : (Given cos135° = – 0.7)

3) A particle is moving with 2 m/s velocity at t = 0 and having a constant acceleration 1 m/s2 in
opposite direction to initial velocity. If average speed of particle in first 3 sec is v then fill value of
3v.

4) A car is moving with velocity 90 km/hr. Suddenly driver applies the brakes which produces a
constant retradation of 2.5 m/s2 at t=0. Find out the magnitude of displacement of the car in meters
in 10 sec.

5)

Water drops fall from a tap on the floor 5 m below at regular intervals of time, the first drop striking
the floor when the fifth drop begins to fall. The height (in m) of the third drop from the ground, at
the instant when the first drop strikes the ground, will be (g = 10 ms–2)

6) Velocity of particle depend on x as v = 4x2 – 4 where x is position of the particle then find
acceleration (in m/s2) at x = 1.
PART 2 : CHEMISTRY

SECTION-I

1) The wave functions of 3s and 3pz orbitals are given by

3s =

=
from these we can conclude

(A) Total number of nodal surface for 3pz & 3s orbitals are equal
(B) The angular nodal surface of 3pz orbital has the equation = /2
(C) The radial nodal surfaces of 3s orbital and 3pz orbitals are at equal distance from the nucleus
(D) 3s electron have greater penetrating power into the nucleus in comparison to 3p, electrons

2) The orbital angular momentum of an electron is Which of the following may not be the
permissible value of angular momentum of this electron revolving in unknown Bohr orbit ?

(A)

(B)

(C)

(D)

3) Which of the following statement(s) is/are incorrect?

(A) An atomic orbital is a 3-dimensional picture of movement of an electron inside an atom


(B) An atomic orbital is the wave function ψ for an electron in an atom.
From the values of ψ at different points within an atom, it is possible to predict the region
(C)
around the nucleus where electron will most probably be found.
The total probability of finding the electron in a given volume can be calculated by the sum of
(D)
all the products of ψ and the corresponding volume elements

4) Which of the following may represent the possible quantum numbers of the last electron of Ga ?
[Given : Ga = 31]

(A)

(B)
(C)

(D)

5) If n + =5, then

(A) Number of possible orbitals are 4


Maximum number of electrons that can be filled with ms = +1/2 is 6 in an atom with above
(B)
condition
(C) for iron (Z = 26) atom, number of electron with above condition must be 1 only
(D) For Germanium (Z = 32), number of electron with above condition can be 5

6) In 2.6 kg of FeSO4 . 6H2O (At. wt. of Fe = 56)

(A) Number of atoms of O are 100 × NA


(B) Moles of H-atoms are 120 × NA
(C) Molecules of water are 60 × NA
– 2–
(D) Moles of e present in SO4 are 500

SECTION-III

1) Wavelength of electron waves in two Bohr orbits is in ratio 3 : 5 the ratio of kinetic energy of
electron is 25 : x, hence x is :

2) The schrodinger wave equation for Hydrogen atom is

where a0 is Bohr's radius. If the radial node in 2s be at r = 4a0 then x would be equal to _____.

3) Among the following, the element with the lowest atomic number that has a ground-state
electronic configuration of (n – 1) d5 ns1 is located in period:

4) Atomic number of Ag is 47. In the same group the atomic numbers of elements placed above and
below Ag in long form of periodic table will be x and y respectively. Give the value of (x + y)/12.

5) If 5g H2 is mixed with 14 gm of N2 for the following reaction N2 + 3H2→2NH3. At the end mass of
H2 (in gram) left unreacted is (At. wt of N = 14, H = 1)

6) Find total number of correct statement for Lothar Meyer's curve :


(I) Curve is plotted between atomic weight and atomic volume
(II) Alkali metals occupy maxima of curve
(III) Halogens occupy descending portions of the curve
(IV) Transition metals occupy bottom portions of the curve

SECTION-II

1) Number of anomalous pairs from Mandeleev periodic table.


(Na, Mg), (Th, Pa), (C, Si), (Co, Ni), (Ar, K), (Si, P), (Te, I)

2) If the value of Azimuthal Quantum Number ℓ for an electron in a particular subshell is 3, then
what will be the minimum value of shell number associated with this electron.

3)

The radius of nucleus (r) is related to its mass number (A) : as

r=
The radius of nucleus of an atom which has 14 neutron and 13 electron will be x × 10–13 cm.
x is: [R0= 1.33 × 10-13 cm] [Answer in nearest integer]

4)

For a 3s-orbital

the maximum distance of radial node from nucleus is

Calculate

5) The vapour density of a mixture containing NO2 and N2O4 is 27.6. The mole fraction of N2O4 in the
mixture is :-
[N = 14, O = 16]

6)

Uub is the symbol of an element then the atomic number of element will be ?

PART 3 : MATHEMATICS

SECTION-I
1) If α and β are the two roots of equation . Then
which of following is/are correct

(A) |α – β| = 16

(B)

(C)

(D) None of these

2) If one of the roots of the equation is the square of the other then the value of a
is/are-

(A)

(B)

(C)

(D)

3) Let a, b ∈ ℚ such that = , then which of the following is NOT true

(A)
is an integer

(B)
is a rational number
(C) is an irrational number
(D) is a rational number

bc 2 4 64
4) If (a) = (2 + 1)(2 + 1)(2 + 1) ... (2 + 1) + 1, then which of the following statement is/are true,
where a is single digit & bc is two digit natural number

(A) b + c = 10
(B) a + b = 10
(C) a + c = 7
(D) a < b < c

5) Consider where x ∈ R. Which of the following are correct :

(A) Maximum value of f(x) is 5


(B) Minimum value of f(x) is –1
(C) Total number of integral values of k for which equation f(x) = k has exactly 2 real solutions is 3
Total number of integral values of k for which equation f(x) = k has exactly one real solution is
(D)
1

6) If a polynomial ax3 + bx2 + cx + d vanishes at x = 1 and at x = –2 and leaves the remainder 4 & 28
when divided by x + 1 and x – 2 respectively, then d is not equal to

(A) 14
(B) 7
(C) –7
(D) –2

SECTION-III

1) The roots of a quadratic equation ax2 – 45x + 100 = 0 are two consecutive natural numbers,
where a ∈ N. The greater root is

2) If , then find the value of

3) If , then the sum of real values of all possible elements of


the set A is λ, then the value of 3λ is equal to

4)

Let P(x) = x3 + ax2 + bx + c be a polynomial such that P(1) = 2, P(2) = 3, P(3) = 4, then the value of

is

5)

Let
and x is prime number greater than 2}
and then number of elements in is

6) If x, y ∈ R & , such that 8x3 – 27x6 + y3 + 18x3y = 0, then the value of is equal
to

SECTION-II

1) If N = 2 3 4 P 5 Q where P = 3 then number of values of single digit number Q such that N is


completely divisible by 6 is
2) If 2n(A\B) = n(B\A) and 5n(A ∩ B) = n(A) + 3n(B), where P\Q=P∩Qc. If n(A ∪ B) = 10, then the

value of is
(where n(X) denotes the cardinal number of set X)

3) In a class of 55 students, the number of students studying different subjects are 23 in


mathematics, 24 in physics, 19 in chemistry, 12 in mathematics and physics, 9 in mathematics and
chemistry, 7 in physics and chemistry and 4 in all the three subjects. The number of students who
have taken exactly mathematics is

4) The number of possible ordered pairs (x,y) (where x and y are integers) which satisfy xy – 2x – y –
4 = 0 is (are)

5) If x,y,z are distinct non zero real numbers for which , then absolute value of
xyz is equal to

6) Let α,β are roots of x2 – 3x + 5 = 0. If the value of is k, then the value of (100 – |k|) is
ANSWER KEYS

PART 1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6
A. A,B,C B,C A,B,D A,B,C,D A,C,D C,D

SECTION-III

Q. 7 8 9 10 11 12
A. 4 7 3 3 2 5

SECTION-II

Q. 13 14 15 16 17 18
A. 1.40 46.90 to 47.05 2.50 125.00 3.75 0.00

PART 2 : CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24
A. A,B,D A,B A,C,D B,D A,D A,C,D

SECTION-III

Q. 25 26 27 28 29 30
A. 9 2 4 9 2 3

SECTION-II

Q. 31 32 33 34 35 36
A. 4.00 4.00 4.00 4.00 0.20 112.00

PART 3 : MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42
A. A,B A,B A,B,D A,B A,B,C A,B,C

SECTION-III

Q. 43 44 45 46 47 48
A. 5 0 5 6 3 3
SECTION-II

Q. 49 50 51 52 53 54
A. 1.00 63.00 6.00 8.00 8.00 5.00
SOLUTIONS

PART 1 : PHYSICS

1)

Explain the question:


A particle is projected vertically upward and returns to the starting point; identify correct
statements for the whole motion.
Concept:
Average velocity, average speed
Solution:
Initial velocity = u
Acceleration = −g
Time to reach highest point = u / g
Total time of journey = 2u / g
Displacement over the entire journey = 0
Average velocity = displacement / total time = 0
Distance covered upward = u² / (2g)
Distance covered downward = u² / (2g)
Total distance = u² / g
Average speed = total distance / total time
Average speed = (u² / g) / (2u / g) = u / 2
Thus:
Average velocity is zero ✔
Displacement is zero ✔
Average speed is u / 2 ✔
Average speed is u ✘

Final Answer: Correct options: 1, 2, and 3

2) Question Explanation:
We need to find the values of t when its velocity is zero, given the displacement equation

Concept:
This question is based on kinematics, velocity.

Solution:

v = t2 – 5t + 6
v=0
(t – 2)(t – 3) = 0
t = 2, 3
Final Answer:
The correct option are (2) and (3).
3) Explain Question: Choose correct option
Concept: Kinematic 1-D
Solution:
tascent = descent
Speed at same level is same
Final Answer: (A,B,D)

4) Explain Question: Choose correct option


Concept: Variable acceleration
Solution:

⇒ Particle move on straight line

For turning point v = 0


⇒ t3 – 6t2 + 11t – 6 = 0 ⇒ t = 1, 2 & 3.
Since between 0-2 sec, particle changes its velocity direction
⇒ distance > |displacement|

For
6t – 12 = 0
t = 2 sec

= +ive
Then minima of acceleration occurs at t = 2 sec
Final Answer: (ABCD)

5) Explain Question: Choose correct option


Concept: Variable acceleration
Solution:
a = 2t – 1

= 2t – 1

v = t2 – t
Final Answer: (ABD)

6) Explain Question: Choose correct option


Concept: Kinematics 1-D
Solution:
speed up
speed down
Final Answer: (CD)
7)

Question Explanation: In a new system mass, acceleration and frequency are taken on
fundamental units. then it is asked to calculate value of 10 joules.
Concept : This question is based on this question is based on Unit and dimension.
Solution :
Joule = N. M.

=
Energy × (mass . acceleration2 / frequency2)

n1 u1 = n2 u2

n2 = 400
K=4
Final Answer : 4

8) Explain Question: Find dimensional formula for time


Concept: Dimensional analysis
Solution:

Final Answer: (7)

9) Explanation : sum of two unit vectors is a unit vector we have to find magnitude of there
difference -
Concept : addition - subtraction
Solution : sum of two unit vectors is also a unit vector hence angel b/w them must be 120°
proof :
12 + 12 + 2 × 1 × 1 cos θ = 12
nS2 = n12 + n22 + 2n1n2cos θ
⇒ θ = 120°
so nd2 = n12 + n22 – 2n1n2 cos 120°

final answer :- x2 = 3
Final Answer : (3)

10)

Explanation :- Two points moving with variable velocities.


we have to find time when they moves perpendicular to each other.
Concept :- Application of dot product
Solution :-
When particle moving perpendicular to each other then

4t – 2t – 6 = 0
2t – 6 = 0
t = 3 sec
Final answer :- t = 3 sec

11) Explain Question: Find value of x


Concept: Scalar product
Solution:
a1 = a2 = 1
and
Now

Final Answer: (2)

12)

Question Explanation :
A body thrown vertically upward covers a certain distance in its last second before stopping;
find it for a higher speed.

Concept: Uniform acceleration, kinematics under gravity

Solution:
For vertical motion under gravity, speed becomes zero at the highest point.

Distance covered in the last second before stopping:


slast = distance covered between times (T − 1) and T

Using equation:
s = ut − (1/2) g t²
Let total time of ascent = T = u / g

Distance in last second:


slast = [uT − (1/2) g T²] − [u(T − 1) − (1/2) g (T − 1)²]

Simplifying:
slast = u − g(T − 1/2)

Substitute T = u / g:
slast = u − g(u/g − 1/2)
slast = g/2

Thus, distance covered in the last second is independent of initial speed.

Given in first case:


slast = 5 m ⇒ g/2 = 5 ⇒ g = 10 m/s²

For u = 500 m/s:


slast = g/2 = 5 m

Final Answer: 5

13) Explain Question: Find value of α, β & γ


Concept: Scalar product
Solution:

Component of force along

Final Answer: (1.40)

14) Explain Question: Find displacement


Concept: Distance & displacement
Solution:
d = Rθ

Displacement
≈ 47 m
Final Answer: (46.90-47.05)

15) Question Explanation: Find 3v, where v is the average speed of a decelerating particle
over 3 seconds, given its initial velocity and constant acceleration.
Concept : Average Speed = Total Distance / Total Time.
Solution :
Given: u = 2 m/s, a = -1 m/s², time = 3 s.
1. Time to Stop (v_f = 0):

A. v_f = u + at
B. 0 = 2 - 1(t) ⟹ t = 2 s

2. Total Distance Calculation: The particle turns at t = 2 s, so we calculate the distance in two
parts.

A. Distance in first 2 s (s₁): s₁ = ut + ½at² = 2(2) + ½(-1)(2)² = 2 m.


B. Position at 3 s (s_pos): s_pos = 2(3) + ½(-1)(3)² = 1.5 m.
C. Distance from 2s to 3s (s₂): s₂ = |Position at 2s - Position at 3s| = |2 - 1.5| = 0.5 m.
D. Total Distance = s₁ + s₂ = 2 + 0.5 = 2.5 m.

3. Final Value:

A. Average Speed (v) = Total Distance / Time = 2.5 / 3 m/s.


B. Final Value = 3v = 3 * (2.5 / 3) = 2.5.

Final Answer : The value of 3v is 2.5.

16) Question Explanation: A car traveling at a high speed applies its brakes, causing a
constant deceleration. We need to find the car's total displacement in meters during the first
10 seconds of braking.
Concept : This problem is solved using the equations of motion for an object under constant
acceleration.
Solution :
Given:

A. Initial Velocity (u) = 90 km/hr


B. Retardation (a) = -2.5 m/s²
C. Time (t) = 10 s

1. Convert Initial Velocity to m/s:

A. u = 90 km/hr * (5/18)
B. u = 25 m/s

2. Check the Time to Stop: First, we must check if the car stops before the 10-second mark. Let's
find the time (t_stop) it takes for the final velocity (v_f) to become 0.

A. v_f = u + at
B. 0 = 25 + (-2.5) * t_stop
C. 2.5 * t_stop = 25
D. t_stop = 10 s The car comes to a complete stop exactly at the 10-second mark.

3. Calculate Displacement (s): Since the car moves in one direction and stops at t = 10 s, we can
directly calculate the displacement.

A. s = ut + ½at²
B. s = (25)(10) + ½(-2.5)(10)²
C. s = 250 + ½(-2.5)(100)
D. s = 250 - 125
E. s = 125 m

Final Answer :
The magnitude of the displacement of the car in 10 seconds is 125 m.

17) Explain Question: Find height of 3rd drop


Concept: Motion under gravity
Solution:

time taken by first drop to strike the ground.


Let the time interval b/w two drops be T
4T = 1
T = 0.25 sec.
Therefore third drop falls from the tap after 0.5 sec. of the first are
When 1st drop is about to strike the ground third drop has travelled for 0.5 seconds

= 1.25 m
Height from the ground = 5 – 1.25
= 3.75 m
Final Answer: (3.75)

18) Explain Question: Find position of particle


Concept: Variable acceleration
Solution:
v = 4x2 – 4

at x = 1

at x = 1
v=0

a= =0×4=0
Final Answer: (0.00)

PART 2 : CHEMISTRY
19) Explain Question: Observe wave function and find correct option.
Concept: This question is based on Quantum mechanical model.
Solution:
3s orbital has two radial node at the values of radius given by solutions of

3pz orbital has one radial nodal surface at = 0 & one angular node at = /2
for 3 pz , at r = 0 = 0 while for
3s at r = 0 = maximum so, 3s has greater penetrating power than 3pz orbital
Final Answer: Options (A, B, D)

20) Question Explanation: Question is asking about may not be the permissible value of
angular momentum.
Concept: This question is based on Orbit angular momentum.
Solution:

∴l=3 ∴n≥4

Orbit angular momentum =

∴ Orbit angular momentum can be


Final Answer: (AB)

21) Question Explanation: Select incorrect statement.


Concept: This question is based on Schrodinger's statement
Solution:
(1) Picture of an electron cannot be captured. Orbital is a 3-dimensional graph (or function
called “wave function”)
(3) From the values of | ψ |2 (probability density) at different points within an atom, it is
possible to predict the region around the nucleus where electron will most probably be found.
(4) The total probability of finding the electron in a given volume can be calculated by the sum
of all the products of | ψ |2 (probability density) and the corresponding volume elements.
Final Answer: (ACD)

22) Question Explain : Find the set of possible quantum numbers of the last electron of Ga
Concept : Quantum number
Solution :
Ga = 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1.
Final Answer: (BD)

23)

Explain Question: Find the correct options with given conditions


Concept: Quantum number
Solution:
If n + =5,
m = +1 or -1

n=4 l=1 4p

n = 3 l = 2 3d
no. of posible orbitals = 4
Final Answer: (AD)

24) Explain Question : Find the correct answer


Concept : Mole calculation
Solution :

n(FeSO4.6H2O) =
number of O-atom = 10 × 10 × NA
moles of H-atom = 10 × 12
molecules of H2O = 10 × 6 × NA
moles of electron in SO42– = 10 × 1 × 50
Final Answer: (ACD)

25)

Question explanation: Determine the value of x given the ratios of electron wavelengths and
kinetic energies in two Bohr orbits.

Concept: de Broglie Wavelength & Kinetic Energy


Solution:

The de Broglie wavelength is related to kinetic energy by . This implies an

inverse square root relationship:

Substitute the given values :

Squaring both sides gives , which simplifies to x = 9.


Final Answer : (9)

26)

Explain Question : If the distance r =4a0 then find the value of x


Concept : Schrodinger wave equation
Solution :
for a radial node
Ψ2s = 0
x2 – =0

x=2
Final answer: (2)

27)

Question Explanation:
• Find period of first element with configuration (n–1)d5 ns1.

Concept:
Half-filled d-subshells follow (n–1)d5 ns1 for stability in d-block elements.

Solution:
• General configuration:(n–1)d5 ns1 → Group 6 (Cr, Mo, W).
• Look for lowest atomic number → Chromium (Cr, Z = 24)
• Cr is in 4th period of periodic table.

Final answer: (4)

28)

Question Explanation:
Finding atomic numbers of elements in the same group using magic numbers.

Concept:
Group-wise Atomic Number Trends (Magic Numbers).

Solution:
Silver (Ag) has an atomic number of 47 and belongs to Group 11 (Coinage metals). To
find the atomic numbers of elements in the same group, we use the "magic numbers" rule,
which accounts for the addition of electrons in different shells. For transition metals in the 5th
period like Ag, we subtract 18 to find the element above (Cu) and add 32 to find the element
below (Au).
• Element above (x): 47 – 18 = 29 (Copper, Cu)
• Element below (y): 47 + 32 = 79 (Gold, Au)

• Value required: = =9
Final Answer: 9

29) Question Explanation:


Calculating mass of unreacted H₂ after reaction with N.

Concept:
Limiting Reagent and Stoichiometry.

Solution:
N2 + 3H2 → 2NH3
28g 6g 34g
28 g N2 combine with 6g H2.

∴ 14g H2 combine with = = 3g


H2 left = 5 – 3 = 2 g
Final answer: 2

30) Explain Question: Find total number of correct options


Concept: Lothar Mayer curve
Solution:

Final Answer: (3)

31)

Question Explanation: Count pairs where an element with higher atomic mass is placed first.
Concept: Anomalous Pairs in Mendeleev Table.
Solution: Mendeleev's periodic table was organized by increasing atomic weight, but to group
similar properties, he occasionally placed a heavier element before a lighter one. These are
called anomalous pairs. The identified anomalous pairs are:

A. (Ar, K): Argon (39.9) before Potassium (39.1)


B. (Co, Ni): Cobalt (58.9) before Nickel (58.7)
C. (Te, I): Tellurium (127.6) before Iodine (126.9)
D. (Th, Pa): Thorium (232) before Protactinium (231)

Total pairs identified = 4 (Pairs like Na-Mg, C-Si, and Si-P follow the correct mass order)
Final Answer: 4.00

32)

Explain Question: If the value of Azimuthal Quantum Number ℓ for an electron in a


particular subshell is 3, then what will be the minimum value of shell number associated with
this electron.
Concept: Angular quantum number
Solution:
The principal quantum number n (shell number) determines the size and energy of the orbital,
while the azimuthal quantum number ℓ (subshell) determines the shape. For a given shell n,
the allowed values of ℓ are integers ranging from 0 to n-1. This relationship is defined by the
following inequality:
ℓ≤n-1
To find the minimum value of n for a specific subshell, we can rearrange the inequality to solve
for n :
n ≥ℓ+1
Given that the azimuthal quantum number ℓ = 3 (which corresponds to an f subshell), we
substitute the value into the expression:
nmin = 3 + 1
nmin = 4
Final answer: 4.00

33) Question Explanation: Calculate radius of nucleus (r)

Concept:
Solution:

= 1.33 × 10–13 × 3
= 3.99 × 10–13 cm
4 × 10–13 cm
Final Answer: (4.00)

34)

Explanation of Question: Question is asking about calculation of A, B & C, for maximum


distance of radial node from nucleus.

Concept: “This question is based on Schrodinger wave equation”

Solution:

For radial Node

Max distance of Radial Node from Nucleus


∴ A = 3, B = 2, C = 3
Final Answer: (4.00)

35)

Explain Question:
Asked mole fraction of N2O4

Concept:
Based on Mole fraction

Solution:
Mmix = 2 × 27.6
= 55.2 gm/mole

Let x be the mole fraction of N2O4


55.2 = x(92) + (1 – x)46
9.2 = 46x
x = 0.2

Final Answer: 0.20

36) Question Explanation: Uub is the symbol for the element with atomic number
Concept: This question is based on IUPAC nomenclature
Solution:
Uub = ununbium = 112
Final Answer: (112.00)

PART 3 : MATHEMATICS

37) Question Explanation: Finding roots of an algebraic equation using substitution.


Concept: Method of substitution in algebraic equations.
Solution:
y = x2 – 10x – 45

⇒ y = –6
2
x – 10x – 39 = 0
α + β = 10, αβ = –39
Final Answer : (A,B)

38) Explain Question: You are asked to find the possible values of the constant a in a
quadratic equation where one root is the square of the other root.
Concept: Relationship between roots and coefficients ( , ) and solving
quadratic equations by factoring.
Solution:

Let equation has two roots α, α2.

⇒ and


Hence,
Final Answer: (A, B)

39) Explain Question: After rationalizing a given expression to find rational numbers a and b,
identify which of the provided statements regarding their ratios and square roots is false.
Concept: Rationalization of denominators, equality of rational and irrational parts, and
properties of rational/irrational numbers.
Solution:

× =

= a= ,b=

(A) ∉I

(B) ∉Q

(C) ∉Q

(D) ∉Q
Hence (A), (B), (D) are not true
Final Answer: (A, B, D)

40) Explanation Question: Solving a product and simplifying its value to get a, b and c.
Concept: This question is based on manipulating the expression to find its value.
Solution:

N= (2 + 1)(22 + 1) ... (264 + 1) + 1


N = (2 – 1)(22 + 1) ... (264 + 1) + 1
2

N = 2128 – 1 + 1

⇒ ⇒ N = (4)64

∴ Now check options


Final Answer : (A,B)

41) Explain Question: Analyze the function f(x) involving multiple absolute value terms to
find its maximum and minimum values and the number of solutions for f(x) = k.
Concept: Piecewise functions, absolute value properties, and graphical analysis of functions to
determine range and number of intersections.
Solution:

maximum value of f(x) is 5


minimum value of f(x) is –1
for , f(x) = k has exactly one solution
for , has exactly 2 solution
Final Answer: (A, B, C)

42) Explain Question: Given a cubic polynomial's behavior at specific points and its
remainders when divided by linear factors, determine which value the constant d cannot be.
Concept: Remainder Theorem, Factor Theorem, and solving systems of linear equations to
find polynomial coefficients.
Solution:
Let ƒ(x) = ax3 + bx2 + cx + d
ƒ(1) = 0 and ƒ(–2) = 0
∴ x – 1 and x + 2 are factors
∴ ƒ(x) = (x – 1)(x + 2)(px + q)
Now ƒ(–1) = (–1 – 1) (–1 + 2)(–p + q)
4 = –2(–p + q) ⇒ p – q = 2 ...(1)
Now ƒ(2) = (2 – 1) (2 + 2)(2p + q)
28 = 4(2p + q) ⇒ 2p + q = 7 ...(2)
Add eq. (1) & (2)
3p = 9 ⇒ p = 3 and q = 1
∴ ƒ(x) = ax3 + bx2 + cx + d
= (x – 1)(x + 2)(3x + 1)
ƒ(0) = d = (0 – 1)(0 + 2)(0 + 1) = –2
Final Answer: (A, B, C)

43) Explain Question: Find the larger root of a quadratic equation given that the roots are
two consecutive natural numbers and the coefficient a is a natural number.
Concept: Properties of consecutive integers, sum and product of roots, and prime
factorization.
Solution:
Let root be n & n + 1


⇒ 9n2 + 9n = 40n + 20
⇒ (9n + 5) (n – 4) = 0
Hence n = 4 (as n ≠ –5/9)
Hence greater root is n + 1 i.e. 5
Alternate :

Product of roots = (where a ∈ N)


Breaking 100 as a product of prime factors,
we get 100 = 4 × 5 × 5, of which two consecutive numbers are 4 & 5
Hence a = 5 and roots are 4 & 5.
Final Answer: (5)

44) Explain Question: Given the value of , calculate the numerical value of a specific
expression involving and .
Concept: Algebraic identities for squares (a-b)2 and cubes (a-b)3, and manipulation of
reciprocal terms.
Solution:

..... (i)

Put in required expression ⇒ 2(36) – 3(11) – 39 = 0


Final Answer: (0)

45) Explain Question: Solve an exponential equation where the bases are reciprocals to find
the sum of all possible real values of x, denoted as λ, then find 3λ.
Concept: Exponential equations (af = ag or a=1, -1, 0), base comparison, and identifying valid
solutions for the domain.
Solution:

* * x – 2 = 3 – 2x

⇒x–4=x ⇒
no solution.

* *
⇒ x = 2 (reject) x = 4 reject

sum
⇒ 3λ = 5
Final Answer: (5)

46) Explain Question: Determine the value of P(5)/5 for a cubic polynomial P(x) given its
values at x=1, 2, and 3.
Concept: Polynomial construction using roots, specifically creating an auxiliary function g(x)
= P(x) - (x+1) that vanishes at given points.
Solution:
p(x) = x3 + ax2 + bx + c
P (1) – 2 = 0
P (2) – 3 = 0
P (3) – 4 = 0
Let p(x) – (x+1) = k (x–1) (x–2) (x–3)
k = 1 {∵ coeff. of x3 is 1 in p(x)}
⇒ p(x) = (x–1) (x–2) (x–3) + (x+1)
⇒ p(5) = (4) (3) (2) + 6
⇒ p(5) = 30

⇒ =6
Final Answer: (6)

47) Explain Question: Find the number of elements in the intersection of the complements of
three sets (A, B, C) within a defined universal set of natural numbers.
Concept: Set theory, De Morgan's Laws, cardinal number of sets, and identifying prime
numbers and multiples.
Solution:
A = {1, 2, 3, 4, 5}
B = {3, 5, 7} U = {1, 2, 3, 4, 5, 6, 7, 8, 9, 10}
C = {5, 10}

= 10 – 7 = 3
Final Answer: (3)

48) Explain Question: Given an algebraic equation relating x and y, find the value of the
expression (2/x) + (y/x2).
Concept: Algebraic identity a3 + b3 + c3 - 3abc = 0, which implies a+b+c=0 or a=b=c.
Solution:
∵ 8x3 + (–27x6) + y3 = –18x3y
⇒ (2x)3 + (–3x2)3 + (y)3 = 3(2x) (–3x2)(y)
{ ∵ We know that, If a3 + b3 + c3 = 3abc
then a + b + c = 0 or a = b = c}
⇒ 2x+ (–3x2) + y = 0 or 2x = –3x2 = y
(reject)
2
⇒ 2x + y = 3x
Final Answer: (3)

49) Explain Question: Determine the number of possible values for a digit Q such that the
six-digit number 23435Q is divisible by 6.
Concept: Divisibility rules for 2 (even last digit) and 3 (sum of digits divisible by 3).
Solution:
Given N = 2 3 4 P 5 Q, P=3
⇒N=23435Q
N is divisible by 6 if it is divisible by 3 and 2
(i) Q must be even (i.e., 0, 2, 4, 6, 8)
(ii) Sum of digit 17 + Q must be divisible by 3 here valid Q = 4
So number of values of Q is one
Final Answer: (1.00)

50) Explain Question: Given relationships between the sizes of set differences and
intersections, find the value of a specific product involving the cardinalities of sets A and B.
Concept: Set cardinality formulas ( ) and solving systems of
linear equations.
Solution:
2(n (A) - n(A ∩ B)) = n(B) - n(A ∩ B)
2n(A) - n(B) = n(A ∩ B)
n(A) + 3n(B) = 5n(A ∩ B)
⇒ n(A) + 3n(B) = 10n(A) - 5n(B)
8n(B) = 9n(A)

n(A) = 8k ; n(B) = 9k
⇒ n(A ∩ B) = 7k
n(A ∪ B) = 10k = 10
k=1

Final Answer: (63.00)

51) Explain Question: In a group of 55 students with overlapping subject enrollments,


calculate how many students are studying only Mathematics.
Concept: Principle of Inclusion-Exclusion for three sets and Venn diagram logic for "exactly
one" category.
Solution:
n(M) = 23, n(P) = 24, n(C) = 19
n(m∩P) = 12, n(M∩C) = 9, n(P∩C) = 7,
n(M∩P∩C) = 4
We have to find n(M∩P'∩C')
n(m ∩ p′ ∩ c′)
= n(m) − n(m ∩ p) − n(m ∩ c) + n(p ∩ m ∩ c)
= 23 – 12 – 9 + 4 = 6
Final Answer: (6.00)

52) Question Explanation:


We have to find number of ordered pairs (x, y) for the given equation.
Concept:
This question is based on Number system.
Solution:
xy – 2x – y – 4 = 0

∴ x – 1 = –1,1,–2,2,–3,3,–6,6
Thus number of possible ordered pairs is 8.

Final Answer : (8.00)

53) Explain Question: Given a cyclic system of three equations involving x, y and z, find the
absolute value of their product xyz.
Concept: System of equations, manipulation of differences, and solving by multiplying
equations.
Solution:


Final Answer: (8.00)
54) Explain Question: For roots α,β of x2 - 3x + 5 = 0, find k from a specific expression and
then calculate (100 - |k|).
Concept: Symmetric functions of roots, Newton's sums or higher power expansions ,
and Vieta's formulas.
Solution:
α + β = 3, αβ = 5
(α + β)5 = (α5 + β5) + 5αβ(α3 + β3) + 10α2β2(α + β)
⇒ 243 = α5 + β5 + 25(–18) + 10.(25)(3)
⇒ α5 + β5 = –57

Final Answer: (5.00)

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