16-05-2026

6201JMELITE160526 JM

PHYSICS

SECTION-I

1) Two spheres of mass m and M are situated in air and the gravitational force between them is F.
The space around the masses is now filled with a liquid of specific gravity 3. The gravitational force
will now be :

(A) F

(B)

(C)

(D) 3F

2) A conducting sphere S1 intersects a closed surface S2 as shown in the figure. A positive charge q is
placed at a point P. What is the value of electric flux through the surface S2?

(A) 0

(B)

(C)

(D)

3) Consider the shown uniform solid insulating sphere with a short and light electric dipole of dipole
moment (embedded at its centre) placed at rest on a horizontal surface. An electric field is
suddenly switched on in the region such that the sphere instantly begins rolling without slipping.
Speed of the sphere when the dipole moment becomes horizontal for the first time is : (m = Mass of

the sphere)
(A)

(B)

(C)

(D) Zero

4) A wooden block performs SHM on a frictionless surface with frequency, v0. The block carries a
charge +Q on its surface. If now a uniform electric field is switched-on as shown, then the SHM of

the block will be :

(A) of the same frequency and with shifted mean position.

(B) of the same frequency and with the same mean position.
(C) of changed frequency and with shifted mean position.
(D) of changed frequency and with the same mean position.

5)

A metallic shell has a point charge q kept inside its cavity. Which one of the following diagrams
correctly represents the electric lines of forces?

(A)

(B)
(C)

(D)

6)

Two equal masses (M) revolve around their COM under their mutual gravitational force. If
separation between the masses is 'd', find the angular velocity of rotation.

(A)

(B)

(C)

(D)

7)

Two thin wire rings each having radius R areplaced at a distance d apart with their axescoinciding.
The charges on the two rings are +Q and –Q. The potential difference between thecentres of the two
rings is :

(A) Zero

(B)

(C)

(D)
8)

Which one of the following graphs represents correctly the variation of the gravitational field (F)
with the distance (r) from the centre of a spherical shell of mass M and radius a :

(A)

(B)

(C)

(D)

9)

In the diagram shown, the charge +Q is fixed. Another charge +2q and mass M is projected from a
distance R from the fixed charge. Minimum separation between the two charges if the velocity

becomes times of the projected velocity, at this moment is : (Assume gravity to be absent)
(A)

(B)

(C)

(D) None of these

10)

Potential difference between centre and surface of the sphere of radius R and uniform volume
charge density ρ within it will be :

(A)

(B)

(C)

(D)

11) Initially the spheres A and B are at potentials VA and VB respectively, with some charges on A and
B. Now, sphere B is earthed by closing the switch. The potential of A will now become :

(A) 0
(B) VA
(C) VA – VB
(D) VB

12) Charges Q, 2Q and 4Q are uniformly distributed in three dielectric solid spheres 1, 2 and 3 of
radii R/2, R and 2R respectively, as shown in the figure. If magnitudes of the electric fields at point P
at a distance R from the center of spheres 1, 2 and 3 are E1, E2 and E3 respectively, then :
(A) E1 > E2 > E3
(B) E3 > E1 > E2
(C) E2 > E1 > E3
(D) E3 > E2 > E1

13) As shown in fig. if a charge +q is carried from a point A (r, 135°) to point B (r, 45°). If

dipole moment is p then the work done by the external agent is :-

(A) 0

(B)

(C)

(D)

14) A semicircular wire is uniformly charged with linear charge density dependent on the angle
θ from y-direction as λ = λ0 |sin θ |, where λ0 is a constant. The electric field intensity at the centre of

the arc is:

(A)

(B)

(C)

(D)
15) A thin metallic spherical shell contains a charge Q on it. A point charge +q is placed at the
centre of the shell and another charge q' is placed outside it as shown in figure. All the three

charges are positive. The force on the charge at the centre is :-

(A) zero
(B) toward left
(C) toward right
(D) upward

16) Variation of electrostatic potential along x-direction is shown in the graph. The correct statement

about electric field is :

(A) x component at point B is maximum

(B) x component at point A is towards positive x-axis
(C) x component at point C is along negative x-axis
(D) x component at point C is along positive x-axis

17) There are two bodies of masses 100 kg and 10000 kg separated by a distance 1 m. At what
distance from the smaller body, the intensity of gravitational field will be zero?

(A)

(B)

(C)

(D)

18) A uniform electric field exists in x-y plane. The potential of points A(2m, 2m), B(–2m, 2m) and
C(2m, 4m) are 4V, 16V and 12V respectively. The electric field is :

(A)

(B)

(C)

(D)
19) Two large non conducting plates having surface charge densities +σ and –σ, respectively, are
fixed ‘d’ distance apart. A small test charge q of mass m is attached to two non conducting identical
springs of spring constant k as shown in the adjacent figure. The charge q is now released from rest

with springs in natural length. Then q will [neglect gravity] :-

(A)
Perform SHM with angular frequency .

(B)
Perform SHM with amplitude .
Not perform SHM, but will have a periodic motion if charges are removed on plates as well as
(C)
on m.
(D) Remain stationary.

20) A conducting sphere of radius R and a concentric thick spherical shell of inner radius 2R and
outer radius 3R is shown in figure. A charge +10Q is given to the shell and inner sphere is earthed.

Then charge on inner sphere is

(A) –4Q
(B) –10Q
(C) zero
(D) none

SECTION-II

1)
A point charge is placed at the centre of top circular end of a cylinder of length ℓ = 12cm and radius

R = 9cm as shown. Electric flux through the curved surface of the cylinder is , find n :

2) A point charge q is placed at a distance 2r from the centre O of a conducting neutral sphere of
radius r. Due to the induced charge on the sphere, the electric potential at point P on the surface of

sphere is x volt. Then the value of x is ____. (If = 18 volt)

3) The electric field on two sides of a large non-conducting charged plate is shown in figure. The
charge density on the plate in SI unit is given by N∈0. (∈0 is the permittivity of free space in SI units),

then find the value of N.

4) There are four concentric shells A, B, C and D of radii a, 2a, 3a and 4a respectively. Shells B and
D are given charges +q and –q respectively. Shell C is now earthed. The potential difference VA – VC

is Find n.

5) A uniform electric field of 40 V/m is directed at 37° above the x-axis as shown in figure. The

potential difference VA – VB is given by ___. (in mV)

CHEMISTRY

SECTION-I
1) An ideal solution is formed by mixing two liquids ‘A’ and ‘B’. Determine the pressure at which
. (XA and YB are mole fractions of A and B in liquid and vapour
forms, respectively, at equilibrium)

(A) 250 torr

(B) 200 torr
(C) 150 torr
(D) 125 torr

2) According to Henry's law, the partial pressure of gas (Pg) is proportional to mole fraction of gas in
dissolved state i.e. Pgas = [Link] where KH is Henry's constant. Then which of the following
statements is incorrect ?

(A) KH is characteristic constant for a given gas - solvent system at a given temperature.
(B) Higher is the value of KH, more is the solubility of gas for a given partial pressure of gas.
(C) KH has temperature dependence
(D) KH increases with increase in temperature

3) What weight of glucose must be dissolved in 100 g of water to lower the vapour pressure by 0.20
mm Hg?
(Assume dilute solution is being formed)
Given : Vapour pressure of pure water is 54.2 mm Hg at room temperature. Molar mass of glucose is
180 g mol–1.

(A) 4.69 g
(B) 4.33 g
(C) 2.59 g
(D) 3.69 g

4) FeCl3 on reaction with K4[Fe(CN)6] in aqueous solution gives blue colour. These are separated by a

semipermeable membrane AB as shown. Due to osmosis there is

(A) blue colour formation in side X

(B) blue colour formation in side Y
(C) blue colour formation in both of the sides X and Y
(D) no blue colour formation

5) When a liquid that is immiscible with water was steam distilled at 95.2°C at a total pressure of
748 torr, the distillate contained 1.25 g of the liquid per gram of water. The vapour pressure of
water is 648 torr at 95.2°C, what is the molar mass of liquid ?

(A) 7.975 g/mol

(B) 166 g/mol
(C) 145.8 g/mol
(D) 14.58 g/mol

6) Match List-I with List-II

List-I List-II

(A) van't Hoff factor, i (I) Cryoscopic constant

(B) Kf (II) Isotonic solutions

(C) Solutions with same (III) Normal molar mass abnormal molar
osmotic pressure mass

(IV) Solutions with same compositions of

(D) Azeotropes
vapour above it
(A) (A) → (III), (B) → (I), (C) → (IV), (D) → (II)
(B) (A) → (I), (B) → (III), (C) → (II), (D) → (IV)
(C) (A) → (III), (B) → (I), (C) → (II), (D) → (IV)
(D) (A) → (III), (B) → (II), (C) → (I), (D) → (IV)

7) On dissolving 4g of a non volatile hydrocarbon in 200g of benzene, the vapour pressure of

benzene lowers from 74.66 torr to 74.01 torr. What is the molecular formula of hydrocarbon?

(A) C6H10
(B) C14H10
(C) CH4
(D) C2H6

8) Acetic acid (CH3COOH) exists in the dimeric form in a solution. In an actual experiment, the Van't
Hoff factor was found to be 0.52. The degree of association and osmotic pressure of 0.1 M acetic
acid solution at 300K respectively are : (R = 0.0821 litre-atm/K-mole)

(A) 0.96 and 9.6 atm

(B) 0.96 and 1.28 atm
(C) 0.46 and 1.28 atm
(D) 0.96 and 7.86 atm

9) Calculate freezing point of 0.2 molal aq. solution of a mono protic acid HX? (α = 20%) (kf for
water = 1.86 KKg/mol)

(A) 273.4464 K
(B) 272.5536 K
(C) 262.15 K
(D) 270.152 K

10) Consider the following vapour pressure-composition graph, SP is equal to :-

(A) PQ + RS
(B) PQ + QR + RS
(C) SR + SQ
(D) PQ + QR

11) Dry air was drawn through bulbs containing pure water, then through bulbs containing a
solution of 600 grams of a non electrolyte in 360 grams of water at the same temperature and finally
through a tube in which dried CaCl2 was placed. The solution bulb gained 1.5 gram and the dried
CaCl2 gained 2 [Link] Molecular mass of the solute is :

(A) 40
(B) 9
(C) 50
(D) 90

12) Pure water boils at 373 K and nitric acid at 359 K. The azeotropic mixture of water and nitric
acid boils at 393.5 K. On distillation of the azeotropic mixture.

(A) pure nitric acid will distil over first.

(B) pure water will distil over first.
(C) one of them will distil over with small amount of the other.
(D) both of them will distil over in the same composition as they are in the mixture.

13) For which of the following aqueous solutions freezing point is maximum?

(A) 0.1 M urea

(B) 0.1M NaCl
(C) 0.05 M AlCl3
(D) 0.15 M glucose

14) Which of the following aqueous solutions is isotonic with 15 % glucose aqueous solution with
specific gravity of 1.2?

(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea

15) The osmotic pressure of a dilute solution of an ionic compound XY in water is four times that of a
solution of 0.01 M BaCl2 in water. Assuming complete dissociation of the given ionic compounds in
water, the concentration of XY (in mol/L) in solution is :

(A) 4 × 10–2
(B) 16 × 10–4
(C) 4 × 10–4
(D) 6 × 10–2

16) A binary solution of liquid A and B will show positive deviation from Raoult's law if it fulfils the
following condition :-
(1) PA > PAoXA and PB > PBoXB
(2) The inter molecular force of A–B < A–A as well as A–B < B–B
(3) ΔHmix is positive
(4) ΔVmix is negative

(A) 1, 2 and 4 are True

(B) 1, 2 are wrong
(C) 1, 2, 3 are true
(D) 1, 3, 4 are true

0 0
17) What is the mole ratio of benzene (PB = 150 torr) and toluene (PT = 50 torr) in vapour phase if
the given solution has a vapour pressure of 120 torr?

(A) 7 : 1
(B) 7 : 3
(C) 8 : 1
(D) 7 : 8

18) The unit of ebullioscopic molal elevation constant is :

(A) K kg mol–1 or K (molality)–1

(B) mol kg K–1 or K–1 (molality)
(C) kg mol–1 K–1 or K–1 (molality)–1
(D) K mol kg–1 or K (molality)

19) Which of the following is an example of positive deviation solution?

(A) Benzene + Toluene

(B) H2O + HNO3
(C) Acetone + CS2
(D) Acetone + CHCl3

20) The degree of dissociation (α) of a weak electrolyte, AxBy is related to van't Hoff factor (i) by the
expression

(A)

(B)

(C)

(D)

SECTION-II

1) When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was
found to be –0.93°C (Kf (H2O) = 1.86K kg mol–1). The number (n) of benzoic acid molecules
associated (assuming 100% association) is ____.

2) 1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to –4°C before freezing. The
amount of ice (in g) that will be separated out is ________ .
(Nearest integer) [Given : Kf(H2O) = 1.86 K kg mol–1]

3) How many of the following solutions show negative deviation from Raoult's Law?

Liquid A + Liquid B
(I) (CH3)2CO + CS2

(II) CCl4 + C6H6

(III) CCl4 + CHCl3

(IV) H2 O + C2H5OH

(V) (C2H5)2O + (CH3)2CO

(VI) CH3COOH + C5H5N (pyridine)

(VII) C6H5NH2 + (CH3)2CO

(VIII) C6H5Cl + C6H5Br

(IX) Cyclohexane + Ethanol
4) Number of correct statements are ___.
(i) Azeotrope obey Raoult's law.
(ii) Minimum boiling point azeotrope is formed if ΔHmix < 0
(iii) ΔHvap for ideal aqueous solution containing non-volatile solute is same as ΔHvap for pure water
(iv) When azeotrope is vapourised, composition of vapour formed is same as solution.

5) Elevation in boiling point of 0.25M aq. solution of weak acid HX is 0.14. What is molarity of H+ ion
in solution.
HXaq.
Given : Kb(H2O) = 0.5
Molality = Molarity
[Give answers as [H+] × 100].

MATHEMATICS

SECTION-I

1) If the range of the function is then α2 + β2 is equal to

:

(A) 190
(B) 192
(C) 188
(D) 194

2) If the domain of the function log5(18x – x2 – 77) is (α, β) and the domain of the function

is (λ, δ), then α2 + β2 + λ2 is equal to :

(A) 195
(B) 179
(C) 186
(D) 174

3) Let [x] denote the greatest integer less than or equal to x. Then the domain of f(x) = sec–1(2[x] +
1) is :

(A)
(B)
(C) (–∞, ∞)
(D) (–∞, ∞) – {0}

4) Consider the sets A = {(x, y) ∈ R × R : x2 + y2 = 25}, B = {(x, y) ∈ R × R : x2 + 9y2 = 144}, C =

{(x, y) ∈ Z × Z : x2 + y2 ≤ 4} and The total number of one-one functions from the set D to
the set C is :

(A) 15120
(B) 19320
(C) 18290
(D) 17160

5) Number of solutions of the equation, 3|x| = |2 – |x|| is :

(A) 0
(B) 2
(C) 4
(D) 5

6) Let the domains of the functions f(x) = log4log3log7(8 – log2(x2 + 4x + 5)) and

be (α, β) and [γ, δ], respectively. Then α + β + γ + δ is equal to :

2 2 2 2

(A) 15
(B) 13
(C) 16
(D) 14

7) Let A = {1, 2, 3, 4} and B = {1, 4, 9, 16}. Then the number of many-one functions f : A → B such
that 1 ∈ f(A) is equal to :

(A) 151
(B) 139
(C) 127
(D) 163

8) is equal to :

(A) 1
(B) 2

(C)

(D)

9) Using the principal values of the inverse trigonometric functions, the sum of the maximum and

the minimum values of is :

(A) 24π2
(B) 22π2
(C) 31π2
(D) 18π2

10) Let f : R → R and g : R → R be defined as

Then gof : R → R is :

(A) one-one but not onto

(B) neither one-one nor onto
(C) onto but not one-one
(D) both one-one and onto

11) If and (fof)(x) = g(x), where then (gogog)(4) is

equal to :

(A)

(B)

(C) –4
(D) 4

12) Let A = {1, 3, 7, 9, 11} and B = {2, 4, 5, 7, 8, 10, 12}. Then the total number of one-one maps f :
A → B such that f(1) + f(3) = 14 is :

(A) 480
(B) 240
(C) 120
(D) 180

13) The equation x2 – 4x + [x] + 3 = x[x], where [x] denotes the greatest integer function, has :

(A) exactly two solutions in (–∞, ∞)

(B) no solution
(C) a unique solution in (–∞, 1)
(D) a unique solution in (–∞, ∞)

14) Let f : R → {0, 1} → R be a function such that then f(2) is equal to :

(A)
(B)

(C)

(D)

15) The range of the function

is :

(A)

(B)

(C)

(D)

16)
is equal to :

(A)

(B)

(C)

(D)

17) The range of is :

(A) [0, 2π]

(B) [0, π]
(C) [0, 2π)
(D) [0, π)

18) For x ∈ (–1, 1], the number of solutions of the equation sin–1x = 2tan–1x is equal to :

(A) 0
(B) 1
(C) 2
(D) 3

19) Let R = {a, b, c, d, e} and S = {1, 2, 3, 4}. Total number of onto functions f : R → S such that
 is equal to :

(A) 180
(B) 240
(C) 60
(D) 100

20) The domain of the function is : (where [x] denotes greatest integer less
than or equal to x)

(A)
(B)
(C)
(D)

SECTION-II

1)

Let [.] denote the greatest integer function. If the domain of the function is [α,
β), then α2 + β2 is equal to :

2)

Let x*y = x2 + y3 and (x*1)*1 = x*(1*1), a value of is K then [K] is equal to ____.
(where [.] denotes GIF)

3)

If for some α, β ; α ≤ β, α + β = 8 and sec2(tan–1α) + cosec2(cot–1β) = 36, then α2 + β is ____.

4)

Consider the function f : R → R defined by If the composition of

then the value is equal to ____.

5)

Let A = {1, 2, 3, ...., 7} and let P(A) denote the power set of A. If the number of functions f : A → P(A)
such that a ∈ f(a), for all a ∈ A is mn, m, n ∈ N and m is least, then m + n is equal to ____.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C B A C B C D A A C C C B A D C D B A

SECTION-II

Q. 21 22 23 24 25
A. 5 3 4 6 480

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B D D C D B B B C A D A C D C A A C C

SECTION-II

Q. 46 47 48 49 50
A. 2 518 2 2 3

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C C D B A A B B B D B D B A C C C A B

SECTION-II

Q. 71 72 73 74 75
A. 5 1 14 1024 44
 SOLUTIONS

PHYSICS

1) Gravitational force does not depend on the medium.

2)

Charge induced < q.

3)

4)

Conceptual

5)

Properties of conductors.

6)

7)

8)

Intensity will be zero inside the spherical shell.

I = 0 upto r = a and where r > a.

9)
Conserving angular momentum

10)

11) The field between spheres remains unchanged. So, P.D is same.

12)

13)

14)
15)

Conceptual

16)

Conceptual

17)

18)

x=3

y=4

19)

A = deformation in equilibrium state.

Springs are connected in parallel Keq = 2k

Angular frequency =

20)
3Q1 + 20Q + 2Q1 =0 ⇒ Q1 = – 4Q

21)

Flux through bottom circular end

Flux through curved surface is

22)
Vnet at P = Vnet at C .... (i)

.... (ii)

.... (iii)
(ii) in (iii)

23) Eext + E = 12
Eext – E = 8
E=2

=2
6 = 4∈0
 24)

25)

= 48 × 10–2 = 480 mV

CHEMISTRY

26)
... (i)
Also, XA + XB = 1 ∴ XB = 1 – XA
∵ PT = PA + PB
PT = 400 XA + 100 (1 – XA) .... (ii)
Also from (i)

(∵ YB = XA)

Now, Putting this value in equation (ii)

27) Facts about KH

28) (for dilute solution)

; w = 3.69g

29) Conceptual

30) For two immiscible liquid

⇒ 145.8

31)

(A) → (III), (B) → (II), (C) → (I), (D) → (IV)

32)
0
P = 74.66 torr ; PS = 74.01 torr
Hydrocarbon Solute (Wsolute = 4g)
Benzene Solvent (Wsolvent = 200 g)

(B) C14H10
Molar mass = (14 × 12) + 10 = 178 g

33)
π = iCRT
= 0.52 × 0.1 × 0.0821 × 300
= 1.28 atm

34)

= 1 + 0.2 (2 –1)
i = 1.2
ΔTf = ikf m

273 – Tf = 0.4464
Tf = 273 – 0.4464
= 272.5536K

35) SP = Ptotal
Ptotal = PA + PB
PA = SR PB = SQ
SP = SR + SQ

36) In the given Ostwald-Walker experiment setup:

Gain in weight of solution bulbs (Δw1 ) ∝ P0 – Ps= 1.5 g
Gain in weight of CaCl2 tube (Δw2 ) ∝ Ps = 2 g
According to Raoult's law:

37) An azeotrope is a special type of solution that boils at a constant temperature and distills
without any change in its composition. The given mixture of water and nitric acid is a
maximum boiling azeotrope, meaning its boiling point (393.5 K) is higher than that of its
individual components (373 K and 359 K). When distilled, the liquid and vapor phases have the
same composition, so the mixture distills over as a whole.

38) Freezing point depression:

For comparison (same solvent), compare . Smaller im gives smaller and hence higher
freezing point.
Compute i for each:
Urea: non-electrolyte, i = 1
Glucose: non-electrolyte, i = 1
NaCl: strong electrolyte,
AlCl3 : strong electrolyte,
Now compare im:
1. 0.1 M urea:
2.
3. :
4. 0.15 M glucose:
Smallest im is for 0.1 M urea, so it has the smallest and hence maximum freezing point.

39) For glucose i = 1

π = iCRT

πglucose =

isotonic solution i.e same osmotic pressure

0.5M ⇒ πNaCl = iCRT = 2 × 0.5 RT = RT

1N ⇒ = iCRT =
1M ⇒ = iCRT = 3 × 1 × RT = 3RT
0.5 ⇒ πurea = iCRT = 1 × 0.5 RT = 0.5RT

40)

41) For non-ideal solution showing positive deviation

ΔHmix = positive; ΔVmix = positive
A–B < A–A, B–B
PA > PAoXA and PB > PBoXB

42) P = PB°XB + PT° XT

120 = 150(XB) + 50 (1 – XB)
100XB = 70
XB = 0.7

YB = = = 0.875
43) [Link]: The elevation in boiling point is given by where Kb is the
ebullioscopic constant and m is molality.

[Link] for constant:

[Link] analysis: The unit of temperature change (ΔTb) is Kelvin(K) and the unit of molality
(m) is mol/kg or simply "molality".

4. Substitution: Unit of
[Link] expression: In terms of the term molality itself, the unit is K/molality =
K(molality)–1.

44) A solution that shows positive deviation from Raoult's Law has weaker intermolecular
forces between its components (A-B) than the pure components (A-A and B-B).
This leads to a higher-than-expected vapour pressure. In the mixture of Acetone and CS2​, the
new forces are weaker, causing the solution to exhibit positive deviation.

45) AxBy → xA+y + yB–x

n=x+y
i = 1 + α (n – 1)

46)

47) Let mass of water initially present = x gm

⇒ Mass of sucrose = (1000 - x) gm

⇒ moles of sucrose =

⇒ 0.75 =
⇒ 256.5 x = 106 – 1000x
⇒ x = 795.86 gm
⇒ moles of sucrose = 0.5969
 ⇒ New mass of H2O = a kg

⇒
⇒ a = 0.2775 kg
⇒ ice separated = (795.86 – 277.5) = 518.3 gm

48) Negtive Deviation from Raoult's law

CH3COOH + C5H5N (pyridine)
C6H5NH2 + (CH3)2CO.

49) (i) Incorrect : → Azeotropes are non-ideal solutions so do not obey Rault’s law.
(ii) Incorrect : → for minimum boiling azeotropes ΔHmix > 0.
(iii) Correct : → addition of non-volatile solute decreases vapour pressure However ΔHvap
remains unaffected.
(iv) Correct : → In case of azeotropes, composition of vapours formed is same as solution after
vapourisation.

50)
∵ ΔTb = i Kb m
= [1 + α(n–1)] × Kb m
= [1 + α(2 – 1)] Kb m
= (1 + α)Kbm
0.14 = (1 + α)(0.5)(0.25)
α = 0.12
[H+] = Cα
= 0.25 × 0.12
= 0.03 M
[H+] × 100 = 0.03 × 100 = 3

MATHEMATICS
51)

52)

53)
54)

55)
Number of solution is 2.

56)

57) A = {1, 2, 3, 4}
B = {1, 4, 9, 16}
Total number of functions = 44
Total number of one-one functions = 4!
Total number of many one functions = 44 – 4! = 232
Total number of many-one functions in which
∴ Total number of many one functions
= 232 – 81 = 151

58)
59)

60)
Clearly the function is many-one and into.

61)
g(4) = 4
g(g(g(4))) = 4

62) f(1) + f(3) = 14

(i) 2 + 12
(ii) 4 + 10
Total number of one-one maps = 2 × 2 × 5 × 4 × 3 = 240

63) x2 – 4x + [x] + 3 = x[x]

x2 – 4x + 3 = x[x] – [x]
(x – 1) (x – 3) = [x] (x – 1)
x = 1 or x – 3 = [x]
x – [x] = 3
{x} = 3 not possible

64)

65)
66)

67)

68) By graph or

x + x3 = 2x
x = 0, 1, –1

69) If f(a) = 1
Total cases = 34 – (3C1 × 24) + 3C2 × 1
Number of onto functions when f(a) = 1 is 24 + 36 = 60
Total number of onto functions
= 45 – (4C1 × 35) + 4C2 × 25 – 4C3 = 240
Number of functions when will be 240 – 60 = 180

70) [x]2 – 3[x] – 10 > 0

([x] – 5) ([x] + 2) > 0
[x] > 5 or [x] < –2
71)

72)

73)
α+β=8
α = 3, β = 5

74)

75)

f : A → P(A)
a ∈ f(a)
Total options for 1 will be 26.
Similarly for every other element also 26.
26 × 26 × ....× 26 × = 242 = mn
m + n = 2 + 42 = 44