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The document contains a series of physics and chemistry problems, primarily focusing on optics, electrostatics, and coordination chemistry. It includes multiple-choice questions regarding lenses, mirrors, electric fields, and properties of complex compounds. The problems are structured in two sections, with Section I covering various concepts and Section II presenting more advanced questions.

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0% found this document useful (0 votes)
4 views35 pages

Solution

The document contains a series of physics and chemistry problems, primarily focusing on optics, electrostatics, and coordination chemistry. It includes multiple-choice questions regarding lenses, mirrors, electric fields, and properties of complex compounds. The problems are structured in two sections, with Section I covering various concepts and Section II presenting more advanced questions.

Uploaded by

ruchirvee
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

02-05-2026

6201JMELITE020526 JM

PHYSICS

SECTION-I

1) An object is at a distance of 20 m from a convex lens of focal length of 0.3 m. The lens forms an
image of the object. If the object moves away from the lens at a speed of 5 m/s, the speed and
direction of the image will be

(A) 3.22 × 10–3 m/s towards the lens


(B) 2.26 × 10–3 m/s away from the lens
(C) 0.92 × 10–3 m/s away from the lens
(D) 1.16 × 10–3m/s towards the lens

2) What is the position and nature of image formed by lens combination shown in figure? (f1, f2 are

focal lengths)

(A) 20/3 cm from point B at right, real.


(B) 70 cm from point B at left; virtual.
(C) 40 cm from point B at right; real.
(D) 70 cm from point B at right; real.

3) A plane mirror is placed at the bottom of a tank containing a liquid of refractive index μ. P is a
small object at a height h above the mirror. An observer O-vertically above P, outside the liquid-sees
P and its image in the mirror. The apparent distance between these two will be

(A) 2μh

(B)

(C)
(D)

4) A point object approaches a plane mirror with a velocity 12 cm/s along a direction making 30° to
the normal of the mirror. The velocity of the image with respect to the object will be :

(A) 12 cm/s
(B) 24 cm/s
(C) 18 cm/s
(D)

5) A concave mirror of curvature radius 40 cm forms the image of an object kept at a distance of 100
cm from the mirror on the horizontal principal axis. The mirror is cut symmetrically along the
principal axis and is separated vertically with the gap between the two parts as 2 cm. The distance
between the two images will be :

(A) 0.5 cm
(B) 2 cm
(C) 2.5 cm
(D) 3 cm

6) A ray is incident on a plane mirror at an angle of incidence i and the angle of deviation of
reflected ray is D. Then choose the most appropriate plot of |D| versus |i|.

(A)

(B)

(C)
(D)

7) Figure shows a parabolic mirror with the equation of a section on the XY plane as y2 = 4ax. A light
ray parallel to the X – axis is incident on the mirror at a point with abscissa 4a . The unit vector

along the reflected ray will be :

(A)

(B)

(C)

(D)

8) Plane surface of a plano-convex lens is silvered. IF μ is the refractive index and ‘R’ is the radius of
curvature of the curved surface then the system behaves like

Convex mirror of focal length


(A)

Concave mirror of focal length


(B)

(C)
Concave mirror of focal length
Convex mirror focal length
(D)

9) A point object is placed at a distance of 20 cm from a thin plano-convex lens of focal length 15cm
and µ = 1.5. The curved surface is silvered. The image will form at
(A) 60 cm left of AB
(B) 30 cm left of AB

(C)
cm left of AB
(D) 60 cm right of AB

10) A prism of apex angle 45° gives angle of emergence 45° for grazing incidence. The refractive
index of prism is

(A)
(B)
(C) 2
(D)

11) A charged ball B hangs from a silk thread S, which makes an angle with a large charged
conducting sheet P, as shown in the figure. The surface charge density of the sheet is proportional
to –

(A)
(B)
(C)
(D)

12) Two point charges are situated at the origin and at the point (a,0, 0), respectively.
The point along the x-axis, where the electric field vanished, is :
(A)

(B)

(C)

(D) None of these

13) Two conducting sphere of radii r1 and r2 are charged to the same surface charge density. The
ratio of electric field near their surface is :

(A)

(B)

(C)

(D) 1 : 1

14) A point charge q is placed at a perpendicular distance from the center of an infinite plate of
width 2a as shown. Find the electric flux through the plate due to charge q.

(A)

(B)

(C)

(D)

15) A uniformly charged rod of length , having linear charge density is lying along the axis of
a uniformly charged ring of radius R. Total charge on the ring is Q. One end of the rod is at the
center of the ring. Find the electrostatic force on the rod due to ring.
(A)

(B)

(C)

(D)

16) Two point charges q1 and q2 are kept as shown.

One of the electric field line coming out from q1 makes an angle 30° with the line joining q1q2,

terminates at q2 making an angle 60°. The ratio is

(A)

(B)

(C)

(D) 2

17) A semicircular ring is welded to semi infinite rod as shown and uniform charge density is
given to this non conducting material configuration. Now a charge q is kept at the centre of the
semicircular charged ring. Calculate the net electrostatic force on the particle.
(A)

(B)

(C)

(D)

18) A charged particle (mass m and charge q) moves along x-axis with velocity v0. When it passes
through the origin, it enters a region having uniform electric field which extends upto x = d.

Equation of path of electron in the region (x > d) is :

(A)

(B)

(C)

(D)

19) Figure shows a particle of mass m and charge –q at the centre of a fixed uniformly charged ring
in a gravity free zone. The angular frequency of small oscillations of the particle along the axis of the
ring is
(A)

(B)

(C)

(D)

20) Two charged thin infinite plane sheets of uniform surface charge densities σ+ and σ–, where |σ+|
> |σ–|, intersect at right angle. Which of the following best represents the electric field lines for
this system?

(A)

(B)
(C)

(D)

SECTION-II

1) An object in a lift is dropped freely and the lift, having a plane mirror at its floor, is operated
simultaneously. The lift starts descending with an acceleration 'a'. If the velocity of the image
relative to the object be 32 m/s , after 2 second. The value of a in m/s2 will be : (Take: g = 10 m/s2)

2) A prism of refractive index has an angle of 30°. One of the refracting surfaces of prism is
silvered. The angle of incidence i for which the ray retraces its path is ___. (in degrees)

3) A uniform surface charge density exists over the entire x-y plane except for a circular hole of

radius a centred at the origin. The electric field at a point on the z-axis is found to be

. Find the value of x.

4) In a region of space, the electric field is given by The electric field flux through a
surface of area of 100 units XY-plane is 'n' units. Then the value of n is ____.
5) Charge is uniformly distributed with volume charge density ρ inside a very long cylinder of radius
R. Find ratio of field at distance r = R/2 from centre to field at distance r = 2R.

CHEMISTRY

SECTION-I

1) The following ligand is

(A) Bidentate
(B) Hexadentate
(C) Tetradentate
(D) Tridentate

2) Which one of the following complex compound is most stable?

(A) [Co(en)(NH3)4]Cl2
(B) [Co(en)3]Cl2
(C) [Co(en)2(NH3)4]Cl2
(D) [Co(NH3)6]Cl2

3) 100 mL of 0.1 M solution of a complex CoCℓ3​⋅5NH3​ is treated with excess AgNO3​ and yields 2.87 g
of AgCl precipitate. (Molar mass AgCl = 143.5 g mol–1) The number of ionisable chloride ions per
formula unit is:

(A) 0
(B) 1
(C) 2
(D) 3

4) The INCORRECT statement is :

2+ 2+
(A) The spin-only magnetic moments of [Fe(H2O)6] and and [Cr(H2O)6] are nearly similar.
2+
(B) The spin-only magnetic moment of [Ni(NH3)4(H2O)2] is 2.83BM.
(C) The gemstone, ruby, has Cr3+ ions occupying the octahedral sites of beryl.
2+
(D) The color of [CoCl(NH3)5] is violet as it absorbs the yellow light.

5) Which of the following statement is correct?


(A) Complex compounds give test of all its constituent ions.
(B) Mohr's salt and Potash alum are example of double salt
2+
(C) K4[Fe(CN)6] gives test of Fe ion in aqueous solution
(D) Fe2(SO4)3 is an example of co-ordination compound.

6) The coordination number and the oxidation state of the element ‘E’ in the complex
[E(en)2(C2O4)]NO2 (where (en) is ethylene diamine) are, respectively,

(A) 6 and 2
(B) 4 and 2
(C) 4 and 3
(D) 6 and 3

7) Which of the following is not considered as an organometallic compound?

(A) Ferrocene
(B) cis-platin
(C) Ziese's salt
(D) Grignard reagent

8) A complex cation is formed by Pt(in some oxidation state) with ligands (in proper number so that
coordination number of Pt becomes six). Which of the following can be its correct IUPAC name?

(A) Diammineethylenediaminedithiocyanato-S-platinum (II)


(B) Diammineethylenediaminedithiocyanato-S-platinate (IV) ion
(C) Diammineethylenediaminedithiocyanato-S-platinum (IV) ion
(D) Diamminebis (ethylenediamine) dithiocyanato-S-platinum (IV) ion

9) Which of the following Werner’s complex has least electrical conductivity?

(A)
(B)

(C)

(D)

10) Which of the following does not obey Sidgwick effective atomic number rule?

(A) Co2(CO)8
(B) Fe(CO)5

(C) [V(CO)6]
(D) [Mn(CO)6]

11) Nickel (Z = 28) combines with a uninegative monodentate ligand to form a diamagnetic complex
[NiL4]2⊝. The hybridisation involved and the number of unpaired electrons present in the complex are
respectively :

(A) sp3, zero


(B) sp3, two
(C) dsp2, one
(D) dsp2, zero
12) According to crystal field theory, which of the following orbital has maximum energy among
given orbitals for a square planar complex?

(A)
(B) dyz
(C)
(D) dxz

13) Ferri ferrocyanide is a blue coloured complex. Average oxidation state of 'Fe' in complex is 'a',
oxidation state of central iron atom is 'b' and oxidation state of counter iron atom is 'c'. a, b and c are
respectively :-

(A)
, +3, +2

(B)
, +2, +3

(C)
, +2, +3

(D)
, +3, +2

14) Which of the following is correctly matched?

(A) [Co(NH3)6]Cl3 : diamagnetic, Δ0 < pairing energy


(B) K4[Fe(CN)6] : Low spin complex, colourless
(C) [Co(H2O)6]SO4 : Paramagnetic, high spin complex
–2
(D) [NiF6] : diamagnetic, Δ0 < pairing energy

15) The Crystal Field Stabilisation Energy (CFSE) for is 18000 cm–1. The CFSE for
will be :

(A) 6000 cm–1


(B) 16000 cm–1
(C) 18000 cm–1
(D) 8000 cm–1

16) Which of the followg isomerism(s) is/are shown by the following complex?

(A) Optical isomerism


(B) Geometrical isomerism
(C) Co-ordination position isomerism
(D) Ionization isomerism

17) Select the CORRECT statements?


(i) [Zn(gly)2] is optically active compound
(ii) [PdClBr(gly)] exhibits geometrical isomerism
(iii) [IrBr4(en)] exhibits cis trans isomerism
(iv) [RhCl2(NH3)4]+ number of stereo isomers is equal to number of geometrical isomers

(A) (i), (ii), (iv)


(B) (ii), (iii), (iv)
(C) (ii), (iii)
(D) (i), (iii), (iv)

18) Compare C–O & M–C bond length in the following complexes.
(a) [M(CO)x]2+
(b) [M(CO)x]+
0
(c) [M(CO)x]
(d) [M(CO)x]–
(e) [M(CO)x]2–

for C–O a < b < c < d < e ;


(A)
for M–C a > b > c > d > e
for C–O a > b > c > d > e ;
(B)
for M–C a > b > c > d > e
for C–O a > b > c < d < e ;
(C)
for M–C a < b < c > d > e
for C–O a > b > c > d > e ;
(D)
for M–C a < b < c < d < e

19) The colour of the co-ordination compounds depends on the crystal field splitting. What will be
the correct order of absorption of wavelength of light in the visible region.

+3 –3 +3
(A) [Co(NH3)6] > [Co(CN)6] > [Co(H2O)6]
+3 +3 –3
(B) [Co(NH3)6] > [Co(H2O)6] > [Co(CN)6]
+3 +3 –3
(C) [Co(H2O)6] > [Co(NH3)6] > [Co(CN)6]
–3 +3 +3
(D) [Co(CN)6] > [Co(NH3)6] > [Co(H2O)6]

20) Which one of the following coordination compound is used to inhibit the growth of tumours?

(A) Trans-[Pd(NH3)2Cl2]
(B) EDTA complex of calcium
(C) [(Ph3P)3RhCl]
(D) Cis-platin

SECTION-II
1) Among the following, total number of specie(s) is/are exist as optically inactive form : [Rh, Z=45]

[Fe(en)3]Cl3 ; [RhCl(PPh3)(CO)(H2O)] ; [Pd(en)Cl2] ;

2) Considering that Δ0 > P, the magnetic moment (in BM) of [Ru(H2O)6]2+ would be___. [Ru, Z = 44]

3) How many of the following statement(s) is/are correct for the complex [Cr(NH3)6]+3?

(i) It is diamagnetic with configuration .


(ii) It is paramagnetic with configuration .
(iii) It is paramagnetic having magnetic moment of 1.73 BM.
(iv) It is an outer orbital complex.
(v) It has d2sp3 hybridisation.

4) EDTA4– is ethylenediaminetetraacetate ion. The total number of N–Co–O bond angles


in [Co(EDTA)]–1 complex ion is ___ ligatures (direct connections)

5) [Fe(CN)6]3– should be an inner orbital complex. Ignoring the pairing energy, the value of crystal
field stabilization energy for this complex is (–) ____ Δo. (Nearest integer)

MATHEMATICS

SECTION-I

1) Let f : R ➝ R be a function defined by , for some m, such


that the range of f is [0,2]. Then the value of m is ___

(A) 3
(B) 5
(C) 2
(D) 4

2) Let the function f : [0, 1] → R be defined by Then the value of

is :

(A) 19
(B) 20
(C) 21
(D) 22
3) If E = {1, 2, 3, 4,5} and F = {1, 2,3}, then number of onto functions defined from E to F is

(A) 200
(B) 120
(C) 140
(D) 150

4) The domain of is

(A)
(B)
(C)
(D) None of these

5) Which of the following function is identical to

(A)
(B)

(C)

(D)

6) If then the domain of ƒ(x) is, where [.] denotes GIF.

(A) [-3, -2) ∪ [3, 4]


(B) [-3, -2) ∪ [3, 4)
(C) [-3, -2)
(D) [3, 4)

7) Which of the following pairs of functions are not identical?

(A)
f(x) = logxe, g(x) =
(B) f (x) = sgn(x2 + 1) ; g(x) = sin2x + cos2x
(C) f(x) = sec2x – tan2x ; g(x) = cosec2x – cot2x

(D) f(x) = ; g(x) =

8) For real x, let f (x) = x3 + 5x + 1, then:


(A) f is one-one but not onto R.
(B) f is onto R but not one-one.
(C) f is one-one and onto R.
(D) f is neither one-one nor onto R.

9) If are two functions defined by then

(A)

(B)

(C)

(D)

10) R is an equivalence relation defined on the set A = {2, 3, 4}. R contains (2, 3) and (3, 4). The
number of such relations R is

(A) 1
(B) 2
(C) 4
(D) 8

11) If is an odd function, where n is an even natural number, then n can


be

(A) 6
(B) 8
(C) 10
(D) 50

12)
.
If T1 and T2 are fundamental periods of f(x) and g(x) respectively, T2 – T1 =

(A) 0
(B)

(C)

(D)

13) The function f(x) satisfies f(x + 1) + f(x – 3) = 7 for all The period of f(x) is
(A) 2
(B) 4
(C) 8
(D) 12

14) Which of the following is odd function ?

(A) f(x) = x2 + 7
(B) f(x) = sin2x

(C)

(D)

15) Which of the following functions, is not periodic ({ . } denotes fractional function) ?

(A)

(B)
(C)
(D)

16) If f(x) and are odd functions then f(5) =

(A) 5
(B) 9
(C) 2
(D) 0

17) If for all , then the product of values of a satisfying f(a) = f(–a) is

(A) 2
(B) –2
(C) –1
(D) 4

18) The function defined as is

(A) Injective and surjective


(B) Injective but not surjective
(C) Surjective but not injective
(D) Neither injective nor surjective
19) The domain of is

(A)
(B)
(C)
(D)

20) The relation R is given by


R = {(a, b) : is irrational, }
then R is

(A) Reflexive only


(B) Reflexive and symmetric
(C) Reflexive and transitive
(D) Symmetric and transitive

SECTION-II

1) Let y = f(x) be a polynomial such that f(x) + f(1/x) = f(x).f(1/x), ∀ x ≠ 0. If f(2) = 17 then f(–3) is

2) The number of solutions of the equation [x + 1]2 = 2x + 3{x} where [.] and {.} denotes the
greatest integer function and fractional part function, respectively, is

3) If , then

4) The range of is R – [a, b), then b – a =

5) The number of functions 'f' from {1, 2, 3, 4} to itself satisfying the condition f(1) =
1, and is ____.
ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D D B D C A C C C D D A D C C B B C B A

SECTION-II

Q. 21 22 23 24 25
A. 2 45 3 300 1

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B C C B D B C C D D C C C D D A A C D

SECTION-II

Q. 46 47 48 49 50
A. 2 0 2 8 2

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A D C A B C C B A C C C C D D B B A A

SECTION-II

Q. 71 72 73 74 75
A. 82 3 0 1 36
SOLUTIONS

PHYSICS

1)

2)

3) Conceptual

4) Velocity of object normal to the mirror is

Therefore, The required relative velocity

5)
6) The deviation is given by formula D = 180–2i.

7)

8)

9)
∴ R = 7.5 cm
With polished surface,

=
F = – 2.5 cm
Now, using mirror formula,

Solving, we get

v= cm

10) For first refraction


sin90° = μsinr
For second refraction μ sin (45 – r) = sin 45°.

11)

12)

13) As,

or
14)

15)

16)

17)
18)

Equuation of line

19)

for, y << R

Now,

20) Field due to large sheet is uniform and normal to it.

21) Referring to the above figure, velocity of freely falling object after two seconds

Velocity of the mirror (and hence the floor of the lift) after two seconds.
22) According to Snell’s law,

23)

24)

(direction of area is perpendicular to XY-plane)

25)

CHEMISTRY
26) Donating atoms are both nitrogen & oxygen.
Correct option : (3)

27) [Co(en)3]Cl2 is most stable complex among the given complex compounds because more
number of chelate rings are present in this complex as compare to others.
(A) [Co(en)(NH3)4]Cl2 ; 1 chelate ring
(B) [Co(en)3]Cl2 ; 3 chelate ring
(C) [Co(en)2(NH3)4]Cl2 ; 2 chelate ring
(D) [Co(NH3)6]Cl2 ; 0 chelate ring

28) Moles of complex = 0.01;

Moles
⇒ two free Cl⁻ ions

29) (1) [Fe(H2O)6]2+, Fe2+ → 3d6 → 4 unpaired electron


[Cr(H2O)6]2+, Cr2+ → 3d4 → 4 unpaired electron
(2) [Ni(NH3)4(H2O)2]2+ = Ni2+ → 3d8
→ 2 unpaired electron µm = 2.83 B.M
(3) In gemstone, ruby has Cr3+ ion occupying the octahedral sites of aluminium oxide (Al2O3)
normally occupied by Al3+ ion.
(4) Complimenry color of violet is yellow

30) 1. In a complex compound (coordination compound), the ions inside the coordination
sphere do not give their characteristic tests in aqueous solution.
2. Mohr’s salt is FeSO4·(NH4)2SO4·6H2O and potash alum is K2SO4·Al2(SO4)3·24H2O. Both
contain two different salts crystallized together and are true “double salts.”
3. K4[Fe(CN)6] does not give the test for free Fe2+ in solution because the iron is tightly bound
in the [Fe(CN)6]4– complex.
4. Fe2(SO4)3 is simply an ionic salt, not a coordination compound.

31) In the given complex we have two bidentate ligands (i.e. en and C2O4), so coordination
number of E is 6.
(2 × 2 + 1 × 2 = 6)
Let the oxidation state of E in complex be x, then
[x + (–2) = 1] or x – 2 =1
Or x = +3, so its oxidation state s + 3
Thus option (d) is correct.

32) Conceptual

0
33) (A) [Pt(en)(SCN)2(NH3)2] ; it is not ion
(B) [Pt(en)(SCN)2(NH3)2]2+ ; not platinate (ate used for anionic complex)
(C) [Pt(en)(SCN)2(NH3)2]
Diammineethylenediaminedithiocyanato-S-platinum (IV) ion
(D) [Pt(en)2(SCN)2(NH3)2]2+ ;
its co-ordination number = 8

34) Conductivity µ no. of ion [Co(NH3)3Cl3] → 0 ion

35) E.A.N = Z– (oridn no) + 2 × [Link]


Co2(CO)8 EAN of Co = 36
EAN of Fe = 36
EAN of V = 36
[Mn(CO)6] EAN of Mn = 37

36)

37) Energy order is square planar complex

38) a = avg. oxidation state of Fe


b = oxidation state of central metal ion.
c = oxidation state of counter ion.
Fe3+ : Ferri ion
Fe2+ : Ferro ion
So, Formula is

So, O.S. of counter 'Fe' i.e. c = +3


O.S. of central 'Fe' i.e. b = +2

Avg O.S. =

39) (1) [Co(NH3)6]Cl3

NH3 → S.F.L., diamagnetic, Δ0 > P.E.


(2) K4[Fe(CN)6]

CN → S.F.L., low spin, colored

(3) [Co(H2O)6]SO4

H2O → W.F.L., Paramagnetic, high spin complex(4) [NiF6]–2

F-act as S.F., due to high charge on N


Diamagnetic, Δ0 > P.E

40)

41)
Optical isomerism is observed at left side central atom

Where (en) is ligand


Geometrical isomerism is observed at right side central atom. Position of NH3 can be changed
to obtain an other geometrical isomer.
Coordination position isomerism is observed when two H2O ligand and one en ligand exchange
positions.

42) (1) [Zn(gly)2]


Zn+2 → 3d10
Hybridization = sp3
tetrahedral unsymmetrical bidentate ligand optically active
(ii) [PdClBr (gly)]– has square planar geometry

It can show G.l.

(IV)

S.I = G.I + O.I


=2+0
S.I = 2
S.I = G.I = 2

43) As the negative charge on the metal increases, back-donation from metal d-orbitals to CO
π orbitals increases. This weakens and lengthens the C–O bond, while strengthening and
shortening the M–C bond. Hence, with increasing negative charge: C–O bond length increases
and M–C bond length decreases.

44) Stronger field ligands cause greater crystal field splitting (Δ), leading to absorption of
lower wavelength (higher energy) light.
According to the spectrochemical series:
CN– > NH3 > H2O (field strength: strong > moderate > weak)
So, crystal field splitting:
[Co(CN)6]3– > [Co(NH3)6]3+ > [Co(H2O)6]3+
Hence, wavelength absorbed is in reverse order:
[Co(H2O)6]3+ > [Co(NH3)6]3+ > [Co(CN)6]3–

45) Cis form of platin [Pt(NH3)2Cl2] in used for therapy


(Anticancerous)

46)
1.
2-optically active.

2. [RhCl (PPh3) (CO) (H2O)] ; [Pd(en)Cl2]


have square planar (high CF splitting energy) from 4d transition series metals) shape where
plane of symmetry present,
thus optically inactive

3.
3
because of sp hybridization of boron & due to asymmetrical didentate (AB) nature of the
salicylato ligand it is optically active.

47) Magnetic moment (in B.M.) of [Ru(H2O)6]2+ would be; while considering that Δ0 > P,
Ru(44) ; [Kr]4d75s1 (in ground state)
0
⇒ In Ru2+ ⇒ 4d6 ⇒ (t2g)6(eg)

⇒ Here number of unpaired electrons in


0
Ru2+ = (t2g)6 (eg) = 0 and Hence
µm =

48)

• Electronic State: Cr3+ is a 3d3 ion.


• Configuration: In an octahedral field, it is always .
• Magnetism: It has 3 unpaired electrons (n =3), making it paramagnetic.
• Moment : .
• Hybridization: It uses two inner 3d orbitals for d2sp3 (inner orbital) hybridization.
(ii) & (v) are correct

49)

EDT A4– is a hexadentate ligand that coordinates to the Co3+ central metal ion through two
nitrogen atoms and four oxygen atoms (from acetate groups), forming an octahedral geometry.
Total 8 N–Co–O bond angles (a)N–Co–O1 (b) N–Co–O1
(a)N–Co–O2 (b)N–Co–O2
(a)N–Co–O3 (b)N–Co–O3

(a)N–Co–O4 (b)N–Co–O4

50)

[Fe(CN)6]3–
CN– is strong field ligand
Fe+3 3d5 ( )

CFSE = 5 (–0.4 Δ0) = –2.0 Δ0

MATHEMATICS

51)

Conceptual

52)

53)

Correct answer is (4).

54)

55)
56) Conceptual

57)

Question Explanation: Identify pairs of functions with different domains or expressions.

Concept: Conditions for Identical Functions

Solution:

A. Pair 1: . Both require . Identical.

B. Pair 2: . Both defined


for all . Identical.

C. Pair 3: (Domain: and


(Domain: . Not Identical due to different domains.

D. Pair 4: and . Both defined for . Identical.

Final Answer: Option (3)

58) f (x) = x3 + 5x + 1

59)

Conceptual

60) For equivalence, elements to be included


{(2, 4), (4, 3), (3, 2), (4, 2), (2, 2), (3, 3), (4, 4)}
is A × A
Only one R. [Exercise-1, Q.2]

61)

[Exercise-1, Q.15]
62) [Exercise-1, Q.24]

63) f(x + 1) + f(x – 3) = 7


f(x + 4) + f(x) = 7
f(x + 8) + f(x + 4) = 7
f(x + 8) = f(x)
T=8
[Exercise-1, Q.28]

64)

Correct answer is (3).

65) has period , but {x} has period 1 (rational)


[Exercise-2, Q.7]

66) f(x) = 0
[Exercise-3, Q.2]

67)

Solving

[JEE-MAINS 2016]

68)

[JEE-MAINS 2019]

69)

[JEE-MAINS 2019]

70)

, but
[JEE-MAINS 2023]

71) f(x) = 1 ± xn
f(2) = 1 ± 2n = 17 ; n = 4
= 1 + x4 f(–3) = 82

72) [x + 1]2 = 2x + 3{x}


⇒ [x]2 + 1 + 2[x] = 2x + 3{x}
⇒ [x]2 + 2[x] + 1 = 2({x} + [x]) + 3{x}
⇒ [x]2 + 1 = 5{x}

⇒ {x} = ...(1)
Since, 0 ≤ {x} < 1



⇒ [x]2 < 4
⇒ –2 < [x] < 2
∴ [x] = –1, 0, 1

⇒ {x} = , where [x] = –1 from (1)

= , when [x] = 0

= , when [x] = 1

73)
= 2f(x)

74)

75) No. of functions = 1 × 3 × 4 × 3


= 36

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