01-12-2025

1001CJA10TIPS25009 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A large, horizontal disk of radius R, shown below, starts to rotate from rest with an angular
acceleration of α. The rotation is about a vertical axis through the centre of disk. The disk contains a
narrow channel of length 2R and rectangular cross-section. Gravity acts in the vertical direction with
an acceleration of g. There is a small rectangular puck that just fits easily in the aforementioned
channel, as shown. The puck is situated a distance r from the axis of rotation.

If the sides of the channel are frictionless but the bottom of the channel has a static coefficient
(A)
of friction µ, then puck begins to slide at
In case mentioned in option (A),
(B)

Now, instead, the situation is that the bottom of the channel is frictionless but the walls have a
(C)
static coefficient of friction µ. Now puck begins to slide at
In case mentioned in option (C),
(D)

2) A force of constant magnitude F acts on a particle (mass m) moving in a plane such that it is
always perpendicular to the velocity of the body. Select the correct option(s).

(A) The time taken by the particle to cover a distance S is t = S/v

(B)
The angle turned by the velocity vector of the particle during a distance S is .
The magnitude of change in velocity vector during the time t is 2v sin
(C)

The magnitude of change in velocity vector during the time t is 2v sin

(D)
3) A quarter circular tube AB of radius r contains a smooth chain that has a mass per unit length m0.

The chain is released from rest from the position shown.

(A) Mechanical energy of the chain remains constant.

(B) Mechanical energy of the chain + earth system remains constant.

(C)
Speed of chain when last link of chain leaves the tube is .

(D)
Speed of chain when last link of chain leaves the tube is .

4) A cannon, when aimed vertically, is observed to fire a ball to a maximum height of L. Another ball
is then fired with this same speed, but with the cannon aimed up along a plane of length L, inclined

at an angle θ, as shown in figure.

(A) Distance d is maximum at θ = 45°.

(B) Time of flight will be maximum for θ = 90°.
(C) Value of d will be zero if θ is increased to 90° keeping L fixed
Minimum length of plane inclined at an angle θ for which the ball will not leave the plane is
(D)
given by .

5) A particle is projected from a point P with a velocity at an angle θ with horizontal. At a certain
point Q it moves at right angles to its initial direction. Then

(A) Velocity of particle at Q is

(B) Velocity of particle at Q is
(C) Time of flight from P to Q is cosecθ
(D) Time of flight from P to Q is

6) In a situation, a board is moving with a velocity v with respect to earth, while a man A and man B
are running with a velocity 2v with respect to earth and both men are running from the opposite
ends of the board at the same time, as shown. Length of the board is L. If they meet after time T,
then

(A) Value of T is L/4 v

(B) Value of T is L/2 v
(C) Displacement of man B with respect to board in time T is 3L/4
(D) Displacement of man A with respect to board in time T is L/4

SECTION-I (ii)

1) On a rainy day, a man is running on a hilly terrain in such a way that he is always finding the rain
drops hitting him vertically. It is assumed that rainfall is uniform in the whole terrain from O to E.
When the man was at rest on stretch OA, he found the rainfall at an angle of 30º with the vertical.

The ratio of Match the

statements from List I with the values in List II.

List – I List – II

The velocity of rain observed on stretch AB to the

(P) (1)
velocity of man on stretch BC

Velocity of rain observed on stretch BC to the

(Q) (2)
actual velocity of rain

Velocity of rain observed on stretch DE to the

(R) (3)
velocity of rain observed on stretched CD

Velocity of man on stretch DE to the velocity of

(S) (4)
man on stretch CD
(A) P → 2;Q → 1;R → 4;S → 3
(B) P → 1;Q → 2;R → 4;S → 3
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 2;Q → 3;R → 4;S → 1

2) In the List-I below, four different paths of a particle are given as functions of time. In
these functions, α and β are positive constants of appropriate dimensions and α β. In each case,
the force acting on the particle is either zero or conservative. In List-II. Certain statements are given
about speed and angular velocity of the particle about origin. Match each path in List-I with those
quantities in List-II.

List-I List-II

(P) (1) Speed is constant

(Q) (2) Speed is decreasing with time

(R) (3) Speed is increasing with time

(S) (4) Angular velocity is constant

Angular velocity is decreasing with

(5)
time
(A) P → 1,5;Q → 2,5;R → 3,4;S → 5
(B) P → 1,4;Q → 1,4;R → 1,5;S → 3,5
(C) P → 2,4;Q → 3,5;R → 1,4;S → 2,5
(D) P → 3,5;Q → 2,5;R → 2,4;S → 2,5

3) List-II shows some situations. You need to decide direction of force according to coordinate

system and match Fx & Fy with List-I

List-I List-II

(P) Fx = 0 (1)
Resultant force on block of mass m
All the surfaces are smooth

(Q) Fx ≠ 0; Fy ≠ 0 (2)

Force exerted by clamp on pulley

(R) Fx < 0 ; Fy > 0 (3) A cart moving with some initial velocity v
towards right is braked slowly such that string
makes constant angle with vertical
Force exerted by string on pendulum bob
 (S) Fx > 0 ; Fy > 0 (4)

Cart is coming down with constant velocity.

Force exerted by string on pendulum bob

(5)

Block is at rest on incline

resultant force on block by incline
(A) P → 4,5;Q → 3,4;R → 3,4;S → 2,5
(B) P → 1,5;Q → 1,2,3;R → 3,4;S → 2
(C) P → 3,5;Q → 3,4;R → 3;S → 2
(D) P → 4,5;Q → 1,2,3;R → 3;S → 2

4) Consider the strings and pulleys system as shown in the figure.

(There is no friction between the strings and pulleys)

List-I List-II

(P) Acceleration of block A (1)

(Q) Acceleration of block B (2)

(R) Acceleration of pulley 2 (3)

(S) Tension in the string between pulleys 1 and 2 (4)

 (5)

The correction option is:

(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 2;Q → 2;R → 1;S → 3
(D) P → 2;Q → 3;R → 1;S → 5

SECTION-II

1) A particle is projected up on incline at t = 0 with speed 14 m/s as shown in the figure. At the same
moment a box starts sliding down, the box has 2 small hole at height of 2m on opposite walls. The

particle enters from 1st window and leaves through the other. The width of the box is . Find the
value of α. Assume friction to be absent everywhere.

2) Spotlight S rotates in a horizontal plane with constant angular velocity of 0.1 rad/s. The spot of
light P moves along the wall at a distance of 3 m. The velocity of the spot P when θ = 45° (see Fig.)

is m/s.

3) A small block of mass 1 kg is moving with constant speed of 10 m/s on a typical path in a x-y

vertical plane whose equation is . The coefficient of friction between the block and path
is 0.01. Find the magnitude of power dissipated by frictional force in watt at x = 2m.
4) The axle of a pulley of mass m = 1 kg is attached to the end of a spring of spring constant k = 200
N/m whose other end is fixed to the ceiling. A rope of negligible mass is placed on the pulley such
that its left end is fixed to the ground and its right end is hanging freely from the pulley which is at
rest in equilibrium. We begin to pull the endpoint A at the right end of the rope by a constant
vertical force of F = 15 N. Friction can be neglected between the rope and the pulley. Find the

maximum displacement of point A after applying F. Express your answer in cm.

5) The 10kg collar A slides with negligible friction on the fixed vertical shaft. When the collar is
released from rest at the bottom position shown, it moves up the shaft under the action of the
constant force F = 200N applied to the cable. The position of the small pulley at B is fixed. The
spring constant k (in kilo-newton/m) which the spring must have if its maximum compression is to be

limited to 0.4 m is :-

6) A rod is arranged at an angle of 30° from the horizontal. Attached to the rod with two strings is
the mass m, as shown in figure. The rod is rotated, maintaining its direction in space, so that m
rotates in a circular path. The strings are of equal length and make angles of 60° with the rod as
shown. Take the length of the strings as 2.4 m. Calculate the minimum value of the tangential speed
(in m/s) of the mass such that the string with tension T2 does not become slack when the mass is

directly above the rod : (g = 10 m/s2)

7) A block of mass 'm' slides on a circular track of radius 'r' whose wall and floor both have
coefficient of kinetic friction 'μ' with the block. The size of block is small compared to the radius of
the track. The floor lies in horizontal plane and the wall is vertical. The block is in contact with
both wall and the floor. The block has initial speed v0. For the block to circle the track exactly once

before coming to rest, ν0 is given by . Find the value of K. [Take π = 3.14]

8) A block of mass 2.5 kg is placed over a fix rough incline (µ = 0.8) plane as shown. A time varying
force F = 5t N acting on block upward along the incline. Time (in sec) after which block will starts

upward slipping, is (g = 10 m/s2)

PART-2 : CHEMISTRY

SECTION-I (i)

1) Sodium azide, NaN3, undergoes the reaction : NaN3(s) → Na(s) + N2(g). Because this reaction is
very fast and produces N2(g), NaN3 is used to inflate car airbags. NaN3(s) in laboratory can be
prepared through following reaction steps.
Step-1 : Na(s) + NH3(g) → NaNH2(s) + ½H2
Step-2 : 2NaNH2(s) + N2O(g) → NaN3(s) + NaOH(s) + NH3(g)
If reaction is started with 23 gm of Na(s) and 33.6 litre of mixture of NH3 and N2O at (0°C and 1
atm). Assume sodium is completely used up and ammonia produced in second reaction is reused for
first reaction. Which of the following option(s) is/are correct. {Both steps have 100% yield}

For complete consumption of Na, volume of N2O taken may be greater than 11.2 litre (0°C and
(A)
1 atm).
(B) Produced NaN3(s) can provide 16.8 litre of N2(g) at (0°C and 1 atm).
If volume of NH3 is greater than 22.4 litre (0°C and 1 atm) then only, sodium gets completely
(C)
consumed.
(D) At the completion of reaction, half of volume of NH3 used in step-I is reproduced.

2) Bornite (Cu3FeS3) is a copper ore used in the production of copper. When heated with oxygen the
following reaction occurs :
2Cu3FeS3(s) + 7O2(g) → 6Cu(s) + 2FeO(s) + 6SO2(g)
Yield of this reaction depend on the amount of O2 supplied w.r.t. moles of Bornite. {Mwt (Cu3FeS3) =
344 gm/mol}

Assuming the curve has constant slope between O to A.

Which of the following option(s) is/are correct regarding above process.

(A) If 2 moles of Cu3FeS3 are used, then 11 moles of O2 tends to maximised yield.
(B) When 2 mole Cu3FeS3 and 7 moles of O2 is used, then yield of reaction is 63%.
(C) At 50% yield of reaction, O2 gas is present in limiting amount.

(D)
If nBronite , even at this condition yield may not be exactly 100% for above reaction.

3) Concentrated H2SO4 can show dehydrating action as follows :

HCOOH(ℓ) CO(g) + H2O(ℓ)
CH3COOH(ℓ) CO(g) + CO2(g) + 2H2O(ℓ)
Assuming no other reaction takes place, mass of H2SO4 required to obtain maximum yield of the
processes is 200 gm and 300 gm per mole of HCOOH and CH3COOH, respectively. A mixture of
formic acid and acetic acid is dehydrated using excess of H2SO4 at 25°C and gaseous products are
passed through red hot charcoal to convert mixture completely into CO. During this process volume
of gases increases by 25% at same temperature and pressure. In another experiment, the same
amount of original gaseous products are passed through KOH where volume of gaseous mixture is
decreased by 30 ml. Which of the following option(s) is/are correct ?

(A)
Molar ratio of HCOOH and CH3COOH is 2.

(B)
Molar ratio of CO and CO2 in dehydrated mixture is 3.
Mass ratio of H2SO4 used, if HCOOH and CH3COOH are dehydrated completely and separately
(C)
is
Mass ratio of H2SO4 used, if HCOOH and CH3COOH are dehydrated completely and separately
(D)
is .

4)
If an electron can have four values of spin magnetic quantum numbers and rest of
the quantum numbers are same.
Which of the following statements are correct.

(A) Boron would have been the first element of second period in periodic table
(B) The total number of elements in the second period would have been 12
(C) There would have been 64 elements in the sixth period of periodic table
Number of period would have been less than the number of periods present in the modern
(D)
periodic table, for the elements discovered so far. (upto Z = 118)

5)
Above graph shows first ionisation enthalpies (ΔHi) of elements of second period as a function of
atomic number (Z). Select the INCORRECT statements :

(A) IE2 of U is lower as compared to V

(B) In the given graph, Q is 2nd group element while T is 14th group element.
(C) I.E2 of P will be highest second ionisation energy as compared to other elements shown above.
(D) The value of screening constant for outermost electron increases from P to W

6) Select the correct option(s).

Energies of the orbitals of the same subshell decreases with increase in the effective nuclear
(A)
charge (Zeff).
(B) The ionic radii of Al3+ , Ga3+ and Tℓ+3 can be 53.5 pm , 47.3 pm and 88.5 pm respectively
Total number of enthalpy(s) (out of given eight) of A(g) which is/are not associated with
(C) conversion of
IE1 , IE2 , IE3 , IE4 , IE5 , IE6 , EGE1 , EGE2 is equal to 2.
If value of Azimuthal quantum number (ℓ) ranges from 0 to (n + 1), then the maximum number
(D)
of electrons in second shell will be 32.

SECTION-I (ii)

1) Match the list :

List-I List-II

Zn(s) + 2HCl(aq) → ZnCl2(s) + H2(g) above reaction is

(P) (1) 50% of excess reagent left.
carried out by taking 2 moles each of Zn and HCl
 AgNO3(aq) + HCl(aq) → AgCl(s) + HNO3(aq)
22.7 L of gas at STP is
(Q) above reaction is carried out by taking 170 g AgNO3 and (2)
liberated.
18.25 g HCl (Ag = 108)

CaCO3(s) → CaO(s) + CO2(g) 1 mole of solid (product)

(R) (3)
100 g CaCO3 is decomposed completely obtained.

2KClO3(s) → 2KCl(s) + 3O2(g)

(S) (4) HCl is the limiting reagent.
2/3 moles of KClO3 decomposed completely
The correct match is :
(A) P → 4;Q → 3;R → 2;S → 2
(B) P → 1;Q → 4;R → 1;S → 3
(C) P → 1;Q → 4;R → 3;S → 2
(D) P → 4;Q → 1;R → 1;S → 3

2) Matching list :

List-I List-II

(P) PCl5 → PCl3 + Cl2 (1)

tan θ =

(Q) 3C2H2 → C6H6 (2)

tan θ =

(R) 2O2 → 3O2 (3)

tan θ = –

(S) 3A → 2B + 5C (4)

tan θ = 1
(Where α = degree of dissociation, Mreactant = Molar mass of reactant, Mavg = Average molar mass of
reaction mixture.)
The correct match is :
(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 2;Q → 4;R → 3;S → 1
(D) P → 4;Q → 3;R → 1;S → 2

3)

List-I List-II

Addition of first electron is exothermic process where as

(P) F(g) (1)
addition of 2nd electron is endothermic process

(Q) Cl(g) (2) Minimum value of EA in its respective group

(R) N(g) (3) H-bond formation take place in its respective hydride

(S) O(g) (4) Formation of M from is endothermic process

(g)

(5) Can show ⊕ve oxidation state

(A) P → 1,3;Q → 3,4;R → 3;S → 1,2,3,4
(B) P → 1,4;Q → 1,2,5;R → 1,5;S → 1,2,3,5
(C) P → 1,3,4;Q → 1,4,5;R → 2,3,5;S → 1,2,3,4,5
(D) P → 1,3,4;Q → 1,4;R → 2,3,4;S → 1,2,4,5

4)

List-I List-II

Set of quantum number for the last electron can be n =

(P) Fe2+ (1)
3, ℓ = 2, m = 1, s =

(Q) Mn+2 (2) Highest energy subshell is partially filled

(R) Zn2+ (3) Spin multiplicity = 5

(S) Al+3 (4) Diamagnetic

(5) Oxide will be amphoteric in this oxidation state

The correct option is :
(A) P → 1,2,3;Q → 1,2;R → 1,2;S → 1,2,5
(B) P → 1,2;Q → 1,2;R → 1,3,4;S → 4,5
(C) P → 1,2,3;Q → 1,2;R → 1,4,5;S → 4,5
(D) P → 1,2,3;Q → 1,5;R → 1,4,5;S → 3,4

SECTION-II

1) Uranium found in nature consists largely of two isotopes U-235 and U-238. The production of
energy in nuclear reactions is from the "fission" or splitting of U-235 atoms, a process which
releases energy in the form of heat. Natural uranium oxide contains 1% of 'U' atoms as the U-235
isotope. Rest is U-238. Isotope separation is a physical process to concentrate ('enrich') one isotope
relative to other and this enriched uranium is used for nuclear weapons.
UO2(g) + 4HF(g) → UF4(g) + 2H2O(ℓ)
UF4(g) + F2(g) → UF6(g)

104 UF6(g)
Calculate minimum mass (kg) of UO2 required to obtain 4.7 kg of enriched U(s) with capacity of
producing a nuclear weapon. Assuming yield of first and second reactions are 30% and 90%
respectively. Assume chemical reactivity of U235 and U238 is identical.
{Mwt (UO2) ore = 270 gm/mol, Mwt of enriched uranium = 235 gm/mol}.

(If your answer is x then report your answer as )

2) The space shuffle, environmental control system handles excess CO2 and water vapours (which
astronauts breathe out) by reacting with Li2O(s) and LiOH(s) (Pellets).
Li2O(s) + H2O → 2LiOH(s)
2LiOH(s) + CO2 → Li2CO3(s) + H2O
If there are 8 astronauts on board of shuffle and each exhales 20 litre of air per minute. If clean air
inside space station contain negligible CO2 and H2O by mass and exhaled air by average human
contain 13.75% mass CO2, 4.5% mass H2O. Calculate minimum mass of Li2O and LiOH required per
minute so that air can be cleaned inside space shuttle. H2O formed in second reaction should be
used completely for the first reaction.
{Density of exhald air is 1 kg/m3 Mwt (Li2O) = 30 gm/mol, Mwt (LiOH) = 24 gm/mol}

3) Devarda's alloy is an alloy of Al, Cu and Zn used as an reducing agent in analytical chemistry. If
alloy mixture is made by combining equal masses of Al and Zn and reacted with HCl to produce
H2 gas at STP.

Al + 3HCl → AlCl3 + H2
Zn + 2HCl → ZnCl2 + H2
Cu does not react with HCl. If alloy is reacted with excess HCl, then 94.08 litre of H2 gas is produced
at STP. {Vm at STP = 22.4 litre/mol, Mwt (Zn) = 66; Mwt(Al) = 27 gm/mol}. Calculate mass of Zn in
alloy.

4) An alloy (homogenous mixture) of iron (75.7%) cobalt (7.2%) and molybdenum (17.1%) by mass,
has density of 8.10 gm/cm3. If number of cobalt atoms present on surface of cube, with edge length
of 30 cm, are x × 10y (written in scientific notation)
{Atomic masses : Fe = 56, Co = 60, Mo = 96, NA = 6 × 1023 atoms/mol}
The value of 'y' is.

5) An experiment was performed in which an empty 100 mL graduated cylinder was weighed. It was
weighed once again after it had been filled to the 10.0 mL mark with dry sand. A 10 mL pipet was
used to transfer 10.00 mL of methanol to the cylinder. The sand methanol mixture was stirred until
bubbles no longer emerged from the mixture and the sand looked uniformly wet. The cylinder was
then weighed again. Use the data obtained from this experiment (and displayed at the end of this
problem) to find the density of the dry sand (X), the density of methanol (Y), and the density of sand-
methanol mixture (Z), all densities in gm/ml.

Mass of cylinder plus wet sand 45.2613 g

Mass of cylinder plus dry sand 37.3488 g

Mass of empty cylinder 22.8317 g

Volume of dry sand 10.0 mL

Volume of sand plus methanol 18.0 ml

Volume of methanol 10.00 mL

Calculate value of (X + Y + Z).

6) How many of the following statement(s) correct?

(i) Pairing of electrons in degenerate orbitals decreases the energy of the system.
(ii) 2px and 3px orbitals are called degenerate orbitals
(iii) Cu+ is repelled by external magnetic field
(iv) In writing the electronic configuration of an atom the 5d orbital will be filled before 6s orbital
(v) Maximum value of (n + ℓ) for an electron in chlorine atom in its first excited state is 4
+4 +2
(vi) Mn and Co having same spin only magnetic moment value.
(vii) All metallic oxide are basic in nature.

7) The sum of oxidation state of Al in Al2O3 and Cr in CrO5 is "X". Monopositive ion of an element "Y"
has exactly "2X" number of electrons in ultimate shell. If the element belongs to 4th period then
number of correct orders among the following is _______.
(i) Zn > Y (Atomic size)
(ii) Y > Zn (IE1)
(iii) Y > Zn (IE2)
(iv) Y > Na (number of unpaired electrons)
(v) Y2O > ZnO (basic nature)
(vi) Y > Mn (Spin multiplicity)
(vii) Y+ > Y+2 (Stability order in aqueous medium)
(viii) Y > Pd (Magnetic moment)

8) Calculate the sum of "Code numbers" of all the cases in which correct order of the mentioned
parameter is represented.

S. Code
Order Parameter
NO. Number

1. Na < Br < Cl Electronegativity 28

2. Mg < Ca < K Metallic character 53

3. Be2+ > Al+3 Ionic radius 14

4. Cl2O7 > Al2O3 > Na2O Basic Nature of oxide 59

5. Mn > Co > Fe IE3 6

For example if Sr. No. (3) & (5) are correct your answer should be 14 + 59 = 73 therefore fill 73.00.
 PART-3 : MATHEMATICS

SECTION-I (i)

1) Let 9 + 99 + 999 + ...........upto n terms = a, then the correct option(s) is/are-

(A)
The value of 7 + 77 + 777 +.....upto n terms
The value of 7 + 77 + 777 + ......upto n terms
(B)

The value of 22 + 222 + 2222 + ........upto n terms

(C)

The value 22 + 222 + 2222 + ........upto n terms

(D)

2) If the equation x3 + 5x2 + p1x + q1 = 0 and x3 + 7x2 + p1x + r1 = 0 have two roots in common, then
-

(A) product of uncommon roots is 35

(B) product of uncommon roots is –35
(C) sum of uncommon roots is –12
(D) sum of uncommon roots is 12

3) If a,b,c are positive numbers where 2a + b = 4 and 2b + c = 6, then

(A)
maximum value of a3b is
(B) maximum value of b2c is 8
(C) maximum value of b2c is 2

(D)
maximum value of a2b is

4) If logxa, ax/2 and logbx are in G.P., then x is equal to (wherever is defined)

(A) loga(logba)
(B) loga(logea) – loga(logeb)
(C) –loga(logab)
(D) loga(logeb) – loga(logea)

5) If , then x can be equal to (x, n ∈ N, n ≥

2)

(A) 2
(B) 4
(C) 16
(D) 256

6) Let a1,a2,a3,....a100 be an arithmetic progression with a1 = 5 and . If is independent

of n where m = 5n then possible value of a2 is/are (m, n ∈ N) -

(A) 3
(B) 9
(C) 5
(D) 15

SECTION-I (ii)

1) Let , such that p(n) f(n + 2) = p(n) f(n) + q(n), n ∈ N where p(n), q(n)
are polynomials of least possible degree and p(n) has leading coefficient unity.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) (1)

(Q) (2)

(R) (3)

(S) (4)

(5)

(6)

(A) P → 4;Q → 1;R → 2;S → 3

(B) P → 2;Q → 3;R → 1;S → 5
(C) P → 4;Q → 3;R → 2;S → 6
(D) P → 2;Q → 1;R → 4;S → 3

2) Let ƒ(x) = 2x2 – 5x + 1, then

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) If x ∈ [–1, 0], then (1)

range of ƒ(x) is

(Q) If x ∈ [0, 2], then (2)

range of ƒ(x) is

(R) If x ∈ [2, 4], then (3)

range of ƒ(x) is

(S) (4) range of ƒ(x) is [1, 8]

If x ∈ , then

(5) range of ƒ(x) is [–1, 13]

(6)
range of ƒ(x) is
(A) P → 4;Q → 3;R → 5;S → 1
(B) P → 5;Q → 2;R → 4;S → 3
(C) P → 4;Q → 2;R → 5;S → 1
(D) P → 5;Q → 3;R → 2;S → 1

3) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) (1) 2
The value of x for which is

(Q) The sum of the real roots of the equation is (2) 4

(R) (3) 3
If and βα = 9, then value is equal to

(S) (4) 5
is equal to

(5)

(A) P → 1;Q → 2;R → 2;S → 5

(B) P → 3;Q → 4;R → 2;S → 5
(C) P → 1;Q → 2;R → 4;S → 1
(D) P → 3;Q → 4;R → 4;S → 1

4) (i) Let harmonic mean, arithmetic mean and geometric mean of two positive numbers a and b
respectively be 4, A and G. If 2A + G2 = 27 then a2 + b2 = α1
(ii) If the value of x + y + z = 15 where a, x, y, z, b are in arithmetic progression while the value of
 is where a, x, y, z, b are in harmonic progression, then the value of a2 + b2 is α2

(iii) The value of is α3

(iv) If the geometric mean and harmonic mean of two positive numbers x1 and x2 are 18 and
respectively then the value of |x1 – x2| is α4.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) The value of α1 is (1) 52

(Q) The value of α2 is (2) 45

(R) The value of α3 is (3) 446

(S) The value of α4 is (4) 15

(A) P → 2;Q → 1;R → 2;S → 3
(B) P → 2;Q → 2;R → 1;S → 4
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 1;Q → 1;R → 4;S → 2

SECTION-II

1) A polynomial in x of degree greater than 3 leaves remainder 2,1,–1 when divided by (x –1), (x + 2),
(x + 1) respectively. If value of remainder when polynomial is divided by (x2 – 1) (x + 2) is ax2 + bx +

c, then the value of is

2) Let α,β are roots of x2 – 3x + 5 = 0. If the value of is k, then the value of (100 – |k|) is

3) If a = and b =
log2 Then the value of a – b is -

4) If logba + logab = 5, then the value of is

5) If sum of solutions of equation ; if a > 1 is λ, then value of λ + 3 is

6) The value of , x > 1, y

> 1; is
7) If , then number of possible real triplet (x, y, z) is

8) If the sum of the infinite series is λ, then equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. B,D A,B,D B,C B,C,D B,C A,C,D

SECTION-I (ii)

Q. 7 8 9 10
A. A B D C

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 5.00 0.60 3.00 60.00 5.00 6.00 12.56 6.20

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,B,D A,B,C,D A,B,D A,C,D A,B A,C,D

SECTION-I (ii)

Q. 25 26 27 28
A. C B C C

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 20.00 15.00 59.40 18.00 3.48 or 3.49 2.00 4.00 87.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,C A,C A,C A,B,C A,B,C C,D

SECTION-I (ii)

Q. 43 44 45 46
A. A C D C
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 0.50 5.00 0.00 1.10 3.10 -4.00 1.00 5.75
 SOLUTIONS

PART-1 : PHYSICS

1) (A) µmg = mω2r = α2rt2

(C) N = mrα
µN = mω2r
µmrα = mω2r = α2t2

2) Since ⇒ circular motion

3)
dU = (m0)Rdθ . (R – R sinθ)
dU = m0R2 (1 – sinθ)dθ

U = m R2

0
= m R2

U = m0R2

0
m R2

v2 =

4)

Correct answer are (B,C,D)

5) Horizontal component of velocity remains unchanged

or
In vertical (y) direction,

6)

At the plane VAB = 4V

7) Correct answer is (A)

8)

Correct answer is (B)

9) (P) For mass m

It moves downward as well as towards right.
So resultant force on mass m must be
Fx > 0 & Fy < 0 (B)

(Q)
So force applied by clamp on pulley must be upward & towards right to keep it balanced.
Fx > 0 & Fy > 0 (B,D)
(R) Acceleration of cart is towards left. Tention on bob must be at an angle with its component
towards left & upward direction
Fx < 0, Fy > 0 (B,C)
(S) Cart as well as bob is coming down with constant velocity, acceleration of bob = 0 ⇒ T =
mg & tension is in vertically upward direction
Fx = 0, Fy > 0 (A)
Resultant force on block must be in upward direction.
R–mg = ma0
Fx = 0 & Fy > 0 (A)

10)
11)

width

12) v cos 45° = v⊥

v = 0.6 m/s
13)

and at

and at
Hence the particle is at it's lowest (minimum) position, in it's path at x = 2 m

14) Initially pulley is at equilibrium

at t = 0

0 0
+ mg (x – x) + 2F (x – x) = 0

0
k(x + x) + mg + 2F = 0

x0 = 35 cm
Disp. of point A is 2(x0 – x) = 60 cm

15) WS + WG + WF = ΔK = 0

(0.4)2 – mg(12) + F (13 – 5) = 0

(0.16) – 100 × 12 + 200 × 8 = 0

k(0.08) = 1600 – 1200
k(0.08) = 400

= 5 × 103 N/m
 16)

When particle is at top

T2cos 30° + T1 cos 30° + mg cos 30° = ... (i)

T2 sin 30° + mg sin 30° = T1 sin 30° ... (ii)
Just slack ⇒ T2 = 0 ⇒ T1 = mg putting in equation (i)
2 mg cos 30° × L cos 30° = mv2

⇒ v = 6 m/s

17)

Correct answer is 12.56

18)
[5t = mgsinθ + µmgcosθ]

PART-2 : CHEMISTRY

19) Na(s) + NH3(g) → NaNH2(s) + ½H2

t=0 1 x
t = t1 0 1
2NaNH2(s) + N2O(g) → NaN3(s) + NaOH(s) + NH3(g)

t = t1 1 y

t = t2 –

x+y=

For NaNH2 to act as limiting reagent y > ; that means litre.

20) Yield factor may also depends variety of products formed different than desired products.
If 100% of reactant is not converted into our desired products then yield will not be 100%.

21) HCOOH CO + H2O

x x
CH3COOH CO + CO2 + 2H2O
y y y
CO2 + C(s) → 2CO
t=0 y 2y
Vi ∝ x + 2y
Vf ∝ x + 3y

Vf = Vi {25% more}

x + 3y = x + y

y = 30 ml ; x = 60 ml

22)

The correct answer is option (A), (C), (D)

23)

I.E order in second Period

Li < B < Be < C < O < N < F < Ne
Option (1)
T → Nitrogen V → Oxygen
Option (2)
Q → Be R → Boron
Option (3)
Successive I.E is always greater irrespective of electronic configuration.

24)

The correct answer is option (A), (C), (D)

25) Correct answer is option (C)

26) (P)
(Q)

(R)

(S)

27) The correct answer is option (C)

28) The correct answer is option (C)

29)

4
= 200 × 10 gm = 2000 kg.

30) Mass of CO2 in exhaled air per minute

= 8 × 20 × 1 × 10–3 × × 103 gm = 22 gm
On adding the reactions :
Li2O(s) + CO2 → Li2CO3(s)
0.5 mole 0.5 mole
= 15 gm

31) Al + 3HCl → AlCl3 + H2

Zn + 2HCl → ZnCl2 + H2

Volume of H2 at STP = × 22.4 = 94.08 litre.

m = 59.4

32) Mass of cube = 8.10 × 30 × 30 × 30

mass of cobalt in cube = × 8.1 × 30 × 30 × 30

Number of cobalt atoms in cube

=
Since mixture is homogeneous and cube contain x number of particles then number of
particles present on one of its surfaces will be x2/3.
∴ Total number of cobalt atoms on surface
 = = 1.7496 × 1018

33) Density of dry sand = = 1.45 gm/ml

Density of methanol = = 0.7912 gm/ml

Density of mixture = = 1.25 gm/ml.

34)

The correct answer is 2.00

35)

The correct answer is 4.00

36)

The correct answer is 87.00

PART-3 : MATHEMATICS

37) (10 – 1) + (102 – 1) + (103– 1) + ......(10n –1) = a

⇒
Now (A) option

Now (C) option

[92 + 992 + 9992+....upto n terms]

⇒ [(10 – 1)2 + (102 – 1)2+......(10n – 1)2]

(102 + 104 + 106+...102n + n – 2(10 + 102 + 103 +......10n))

38) Subtract the equation
2x2 + (r1 – q1) = 0
α+β=0
α + β + γ = –5 & α + β + δ = –7
γ = –5 & δ = –7

39) 2a + b = 4

(A)
AM ≥ GM

(B) b, b, c
AM ≥ GM

(b2c)1/3 ≤ 2
b2c ≤ 8
a, a, b
AM ≥ GM

40) b2 = ac
⇒ (ax/2)2 = (logxa)(logbx)
⇒ ax = logba ⇒ x = loga(logba)
or x = loga(logea) – loga(logeb)
or x = –loga(logab)

41) log2x + log2x + ... + n times = 8

log2(xn) = 8
xn = 28
xn = 256

42) d = common difference

 is independent of n
⇒ d = 0, 10
a2 = 5,15

43)
p(n) f(n + 2) = p(n) f(n) + q(n)

p(n)(2n + 3) = q(n)((n+1)(n+2))
∴ p(n) = (n + 1)(n + 2), q(n) = 2n + 3

(P)

(Q)

(R)

(S)

44) ƒ(x) = 2x2 – 5x + 1

Vertex :
(P) If x ∈ [–1, 0], then ƒ(x) ∈ [1, 8]

(Q) If x ∈ [0, 2], then ƒ(x) ∈

(R) If x ∈ [2, 4], then ƒ(x) ∈ [–1, 13]

(S) If x ∈ , then ƒ(x) ∈

45) (P)
Let 2x = t
t2 – 12t + 32 = 0 ⇒ t = 4 or t = 8
∴ x = 2 (rejected) or x = 3
(Q) Take log both sides to base '10'

x = 1 or x = 4
Hence, sum = 5
(R)

(S)

46) (P) H.M. = 4 ⇒

⇒ ab = 2(a + b) ...(1)

, G2 = ab, 2A + G2 = 27
⇒ a + b + ab = 27
(1), (2) ⇒ a + b = 9, ab = 18
⇒ a = 3, b = 6 ⇒ a2 + b2 = 45

(Q) a, x, y, z, b are in A.P. ⇒

x + z = a + d + b – d = a + b, where d is the common difference.

∴ x + y + z = 15 ⇒
⇒ a + b = 10 ...(1)
a, x, y, z, b are in H.P.
 , given

∴ [using (1)] ...(2)

Using (1) and (2) ⇒ (a, b) = (4, 6)
⇒ a2 + b2 = 52

(R)

(S) G2 = A4

x1 and x2 are roots of x2 – 2Ax + G2 = 0

47) ƒ(x) = (x – 1)(x + 1)(x + 2)Q(x) + ax2 + bx + c

ƒ(1) = 2 ⇒ a + b + c = 2
ƒ(–2) = 1 ⇒ 4a – 2b + c = 1
ƒ(–1) = –1 ⇒ a – b + c = –1
add 6a – 2b + 3c = 2

48) α + β = 3, αβ = 5
(α + β)5 = (α5 + β5) + 5αβ(α3 + β3) + 10α2β2(α + β)
⇒ 243 = α5 + β5 + 25(–18) + 10.(25)(3)
⇒ α5 + β5 = –57

49) a =
= ( +1+ – 1) = 1
and b = log2( +1–( – 1)) = log22 = 1
50) logba + logab = 5
(logba + logab)3 = 125

51) take log base 'a' both sides

loga(2x) loga2 = loga(5x)loga5
(loga2)2 + [Link] = (loga5)2 + logax.loga5
(loga2)2 – (loga5)2 = logax(loga5 – loga2)
logax = –(loga2 + loga5)

i.e.

52) Let logxy = t

= (t2 + 6t + 4) – (t2 + 6t + 8)
= –4

53)
Apply A.M ≥ G.M

x = –1, y = –1, z = –1
(–1, –1, –1)

54)

_________________________
________________________

⇒ P = 10