TOA ENAMEL THINNER No.

21 SAFETY DATA
SHEET ( SDS )
Revised 0 Date 04/2018 Wood Coating Page : 1

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name : TOA ENAMELTHINNER No.21
Product Use : Solvent for Coating.
Company Name : TOA PAINT (THAILAND) PUBLIC COMPANY LIMITED
Address : 31/2 Moo 3, Bangna-Trad Road, Bang Sao Thong Sub-District,
Bang Sao Thong District, Samut Prakarn Province 10570, Thailand
Telephone No. : +662 335 5777
Fax No. : +662 312 8927
Emergency Call : +662 335 5999

2. HAZARDS IDENTIFICATION
[ GHS Classification ]
Hazard Category
Physical Hazard : Flammable liquid Category 3
Health Hazard : Acute toxicity ( Oral / LD50 ) Not Classify
: Acute toxicity ( Dermal / LD50 ) Not Classify
: Acute toxicity ( Inhalation : vapours ) Category 3
: Skin corrosion / Irritation Category 3
: Serious eyes damage / Eyes irritation Category 2B
: Respiratory and skin sensitization Not Classify
: Germ cell mutagenicity Category 2
: Carcinogenicity Category 2
: Reproductive toxicity No data
:Specific target organ systemic toxicity-Single exposure Category 2
( central nervous system )
: Specific target organ systemic toxicity-Repeated exposure Category 2
( kidney )
: Aspiration Hazard (Airways) No data
: Acute aquatic toxicity Category 3
: Chronic aquatic toxicity Not Classify
: Hazard to the ozone layer No data

Pictograms

Signal word Danger

TOA ENAMEL THINNER No.21 SAFETY DATA
SHEET ( SDS )
Revised 0 Date 04/2018 Wood Coating Page : 2

Hazard statements 1. Flammable liquid and vapour.

2. Toxic if inhaled.
3. Causes mild skin and eye irritation.
4. Suspected of causing genetic defects.
5. Suspected of causing cancer.
6. May cause damage to central nervous system depression resulting in headaches,
dizziness and nausea, continued inhalation may result in unconsciousness and/or death.
7. May cause damage to kidney through prolonged or repeated exposure.
8. Harmful to aquatic life.

Precautionary Statements 1. Read label before use. DO NOT handle until all safety precautions have been read and understood.
2. Wear protective gloves / protective clothing / eye protection / face protection. Wear respiratory
protection.
3. Use product only on objects. DO NOT use with human and animal.
4. DO NOT eat this product. Keep this product away from food, drink and animal feeding stuffs.
IF SWALLOWED, DO NOT induce vomiting and seek medical advice immediately.
5. DO NOT eat, drink or smoke when using this product.
6. DO NOT breathing vapors or spray mist. IF INHALATION: Remove to adequate ventilation place and
support breathing
as needed. In case of faint, must recuperate the patient and seek medical advice immediately.
7. Avoid direct contact. Wash the exposed thoroughly after handling. IF ON SKIN: Wash with plenty of
soap and water.
DO NOT use solvent or thinner and seek medical advice immediately.
8. IF IN EYES: Flush with plenty of water for at least 15-20 minutes and seek medical advice
immediately.
9. If you feel unwell: Call a POISON CENTER or doctor/physician.
10. Use and store this product in dry and a well-ventilated place.
11. Product may cause electrostatic force, always use ground connection and antistatic protective
clothes when pouring this product out of container.
12. Keep this product in provided container only.
13. Keep container tightly closed. Keep out of reach of children.
14. Keep away from heat / sparks / open flames / hot surfaces / direct sunlight. In case of fire: Use
foam, dry chemical, water spray for extinction. DO NOT use water in a jet.
15. Keep product away from oxidizing agents, acidic and alkaline substances.
16. Move product with careful, always carry with the top cover stand upright.
17. In case of leakage, use nonflammable absorbent such as dried sand or soil and clean surface with
powdered detergent.
DO NOT use thinner or solvent.
18. Avoid release paint or used container to water drain or natural water resource.
19. Used container dispose as chemical contaminate waste according to local regulation or standard
regulation.

TOA ENAMEL THINNER No.21 SAFETY DATA
SHEET ( SDS )
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3. COMPOSITION / INFORMATION ON INGREDIENTS
No. Component / Chemical Name CAS Number EC Number %
1 White Spirit 64742-82-1 265-185-4 98

4. FIRST AID MEASURES

General : In all cases of doubt or when symptoms persist, get medical attention immediately.
DO NOT give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Give nothing by mouth. If unconscious place in recovery position and seek medical advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or
use recognised skin cleanser. Do NOT use solvents or thinners.
Eye Contact : Check for and remove any contact lenses. Immediately flush eyes with running water
at least 15 minutes, keeping eyelids open.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.
5. FIRE - FIGHTING MEASURES
Extinguishing Media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used : waterjet.
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to
fire with water. Do not release runoff from fire control methods to sewers or waterways.

6. ACCIDENTAL RELEASE MEASURES
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8.
Spill : Contain and collect spillage with non-combustible absorbent materials e.g. diatomaceous earth,
sand, vermiculite and place in container for disposal according to local regulations (see section 13)
Do not allow to enter drains or watercourses. Clean preferably with a detergent, avoid use of
solvents. If the product contaminates lakes, rivers or sewage, inform appropriateauthorities in ac
cordance with local regulations.
TOA ENAMEL THINNER No.21 SAFETY DATA
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7. HANDLING AND STORAGE

Handling : Keep container tightly closed. Keep away from heat, sparks and flame.
No sparking tools should be used. Avoid contact with skin and eyes. Avoid the inhalation
of dust, particulates and spray mist arising from the application of this preparation.
Avoid inhalation of dust from sanding. Eating, drinking and smoking should be prohibited
in area where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking and smoking.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty the container because the container can not resist the pressure.
Always keep this products in containers that made with same material as the original one.
Comply with the health and safety at work laws.
Vapors of this product are heavier than air and may spread along floors.
Prevent flame by control the vapor concentration under Occupational Exposure Limits.
In addition, the product should only be used in areas from which all naked lights and other
sources of ignition have been excluded.
Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving container
with bonding strap. Operators should wear anti-static footwear and clothing.
The floors should be the conducting type.
When operators, whether spraying or not, have to work inside the spray booth, ventilation is
unlikely to be sufficient to control particulates and solvent vapor in all cases.
In such circumstances they should wear a compressed air-fed respirator during the spraying
process and until such time as the particulates and solvent vapor concentration has fallen below the
exposure limits.
Storage : Store in accordance with local regulations. Observe label precautions.
Store in a cool, well-ventilated area where away from incompatible materials and
ignition sources. Keep away from oxidizing agents, strong alkali, strong acids.
Ideal storage temperature range is 25 – 30 ํC. DO NOT freeze this products.
No smoking and prevent unauthorized access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
DO NOT allow to enter drains or watercourses.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Engineering controls : Provide adequate ventilation. Where reasonably practicable this should be achieved by
the use of local exhaust ventilation and good general extraction. If these are not sufficient
to maintain concentrations of particulates below the Occupational Exposure Limit (OEL),
suitable respiratory protection must be worn.
TOA ENAMEL THINNER No.21 SAFETY DATA
SHEET ( SDS )
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Personal protective equipment

Respiratory system : If workers are exposed to concentrations above the exposure limit they must use appropriate,
certified respirators. Use respiratory mask with charcoal and dust filter when spraying
this product (as filter combination A2-P2). In confined spaces use compressed air or fresh air
respiratory equipment. When use of roller or brush, consider use of charcoal filter (A2).
Skin and body : Wear anti-static clothing made of natural fibre or high temperature resistant synthetic fibre.
Before rewearing, wash the contaminated suit separately from other laundry.
Hands : For prolonged or repeated handling, use gloves: neoprene or nitrile gloves.
Use barrier cream together with the gloves to protect the exposed areas of the skin.
However, prohibit to use the barrier cream after exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
Eyes : Use safety eyewear designed to protect against splash of liquids.

9. PHYSICAL & CHEMICAL PROPERTIES

Appearance : Liquid
Color : Clear
Flash Point : 32 ํC
Odor : Solvent smell
Specific Gravity : 0.75-0.78 g/cm3
Water Solubility : Insoluble

10. STABILITY AND REACTIVITY

Chemical Stability : Stable under normal temperatures and pressures.
Conditions to Avoid : Heat, flame and freezing or temperatures below 0 ํC
Incompatible Materials : Oxidizing agents, Strong acids and alkalis.
Hazardous Decomposition Products : Carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

11. TOXICOLOGICAL INFORMATION

Cassification according the GHS
Oral : Rat (LD50) (mg/kg) or ATE : ATE = 5000 mg/kg
Dermal : Rabbit (LD50) (mg/kg) or ATE : ATE = 3160 mg/kg
Inhalation : Rat (LC50) (mg/L) or ATE : ATE = 5 mg/L
Skin corrosion/irritation : Causes mild skin irritation.
Serious eye damage/eye irritation : Causes mild eye irritation.
Respiratory or skin sensitization : No data available.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Suspected of causing cancer. : No data available
Reproductive toxicity : No data available.
Specific target organ toxicity : May cause damage to central nervous system depression resulting in headaches, dizziness and nausea,
- single exposure continued inhalation may result in unconsciousness and/or death.
Specific target organ toxicity : May cause damage to kidney through prolonged or repeated exposure.
- repeated exposure : May be harmful if swallowed and enters airways
Aspiration hazard : No data available.

TOA ENAMEL THINNER No.21 SAFETY DATA
SHEET ( SDS )
Revised 0 Date 04/2018 Wood Coating Page : 6

12. ECOLOGICAL INFORMATION

Hazardous to
Acute the aquatic environment Harmful to aquatic life
Chronicthe aquatic environment No data available.
the ozone layer Not Classified.

13. DISPOSAL CONSIDERATIONS

Method of disposal The generation of waste should be avoided or minimized wherever possible. Empty containers or liners
may retain some product residues. This material and its container must be disposed of in a safe way.
Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal
of this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements.
Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.

Material and/or container must be 08 01 11 Waste paint and varnish containing organic solvents or other dangerous substances
disposed of as hazardous waste 08 01 17 Wastes from paint or varnish removal containing organic solvents or other dangerous
European waste catalogue (EWC) substances

14. TRANSPORT INFORMATION
Proper Shipping Name Turpentine substitute
Class 3
UN. Number 1300
Packing Group III

Label

Transport in accordance with ADR/ ADR/RID : Viscous substance. Not restricted, ref. chapter [Link].5
(applicable to receptacles < 450 litre capacity)
RID, IMDG/IMO and ICAO/IATA and
: Viscous substance. Transport in accordance with paragraph [Link]
national regulation. IMDG
(applicable to receptacles <30 litre capacity)


TOA ENAMEL THINNER No.21 SAFETY DATA
SHEET ( SDS )
Revised 0 Date 04/2018 Wood Coating Page : 7
15. REGULATORY INFORMATION

Thai regulation : HAZARDOUS SUBSTANCE ACT, B.E. 2535 (1992)

: Notification of Ministry of Industry Subject: Hazard Classification and 2555 (2012)
Communication System of Hazardous Substances B.E.

16. OTHER INFORMATION The information in this SDS is based on the present state of our knowledge and on current laws. The
product is not to be used for purposes other than those specified under section 1 without first
obtaining written handling instructions.
It is always the responsibility of the user to take all necessary steps to fulfill the demands set out in the
local rules and legislation.
The information in this SDS is meant to be a description of the safety requirements for our product.
It is not to be considered a guarantee of the product's properties.