16-01-2026

5203CJA101021250018 JA

PART - 1 : PHYSICS

SECTION - I

1) A charge Q is uniformly distributed on circumference of ring. An imaginary sphere is given whose

center is coinciding with a point on ring. If radius of ring and sphere is same then find flux passing
through this sphere.

(A)

(B)

(C)

(D)

2) A capacitor of capacitance C0 is charged to certain potential and energy stored in it U0. Now this
capacitor is connected in parallel to uncharged capacitor of capacitance C. Find the loss of energy.

(A)

(B)

(C)

(D)

3) A beam of equally charged particles after being accelerated through a Voltage V as shown enters
into a magnetic field B as shown It is found that all the particles hit the plate between X and Y. Find
the ratio of the masses of the heaviest and lightest particles of the beam.
(A)

(B)

(C)

(D)

4) A conducting rod of length ฀ is moving as shown with constant velocity. Find the motional emf
induced in rod.
a = distance between wire and mid point of rod.

(A)

(B)

(C)

(D)

5) At 40cm meter bridge galvanometer shows null deflection. The least count of the scale used in the
meter bridge is 1mm. Find the unknown resistance.

(A)
(B)
(C)
(D)

6) Diameter of a plano-convex lens is 8 cm and its thickness at the centre is 4 mm. If the speed of
light in the material of the lens is 1.50×108 m/s, the focal length of the lens is:

(A) 0.16 m
(B) 0.18 m
(C) 0.20 m
(D) 0.22 m

7) In a Young’s double slit experiment, a thin glass plate of thickness t = 12 µm and refractive index
µ = 1.5 is placed in front of one slit. The experiment is performed in air using monochromatic light
of wavelength λ = 600 nm. If β is the fringe width before the insertion of the plate, then the shift of
the central maximum due to the insertion of the plate is:

(A) 5β
(B) 10β
(C) 8β
(D) 12β

8) Electrons are diffracted by a crystal and produce the same diffraction pattern as X-rays of
wavelength 0.165 nm.
h = 6.6×10−34 J·s,
m = 9.0×10−31 kg,
e = 1.6×10−19 C.
The accelerating potential applied to the electrons is (approx.).

(A) 40.5 V
(B) 50.4 V
(C) 65.2 V
(D) 55.6 V

9) A hydrogen atom (initially at rest) in the excited state n = 4 makes a transition to the ground state
n = 1 and emits a photon. The recoil speed of the hydrogen atom after emission of the photon is
approximately:

(A) 4.0 m/s

(B) 3.5 m/s
(C) 3.0 m/s
(D) 4.5 m/s

10) A nucleus A splits into two fragments B and C of mass numbers 105 and 115, respectively. The
binding energy per nucleon of B and C is 6.4 MeV each. If the total energy released per fission (Q-
value) is 220 MeV, then the binding energy per nucleon of the parent nucleus A (mass number 220)
is approximately:

(A) 5.3 MeV

(B) 5.4 MeV
(C) 5.5 MeV
(D) 5.6 MeV

11) A force F = 6x2 +4x−5 N acts on a particle which moves along the x-axis from x = 0 to x = x0.
The work done (in J) by this force is:

(A)
(B)
(C)
(D)

12) Two blocks A (12 kg) and B (8 kg) are placed on a rough horizontal surface and connected by a
light inextensible string, as shown in the figure. A horizontal force F = 50 N is applied on block A at
an angle of 37o above the horizontal. The coefficients of friction between each block and the floor is
and µ = 0.1. The string will break if the tensile stress in it exceeds 17.2 MPa. Find the minimum
cross-sectional area of the string so that it does not break when the system is in motion. (g = 10
m/s2)

(A) 1.0 mm2

(B) 0.1 mm2
(C) 10.0 mm2
(D) 0.01 mm2

13) A solid disc of radius R rolls without slipping on a horizontal surface. The centre moves to the
right with speed V0. A point P on the rim is located at 30o below the horizontal through the centre
(see figure). Find the magnitude of the velocity of P and the angle it makes with the horizontal.

o
(A) vP = V0, 60 below horizontal.
o
(B) vP = V0, 30 below horizontal.

(C)
below horizontal.

(D)
below horizontal.
14) Two uniform thin rods, each of length L, are joined as shown. The horizontal rod has mass m and
the vertical rod has mass 3m. The distance of the centre of mass of the system from point O is:

(A)

(B)

(C)

(D)

15) A boat can move with a speed of 5 m/s in still water. It has to cross a river flowing with a velocity
of 3 m/s towards east. The boatman wants to reach a point directly north of his starting point.
At what angle (from north towards west) should he steer the boat?

(A) 30°
(B) 37o
(C) 45°
(D) 53°

16) Two SHMs are given by

If the resultant amplitude is 5, then the phase difference ϕ is:

(A) 30°
(B) 37°
(C) 60°
(D) 90°

17) A boat can move at 10 m/s in still water. A river flows east at 6 m/s. The boat is steered 30o west
of north (i.e., 30° from north toward the west). The river bank is 100 m to the north. How far
downstream (east) from the point directly north of the start will the boat land?

(A) 5.77 m
(B) 11.55 m
(C) 20 m
(D) 0 m

18) Two SHMs of equal angular frequency and equal amplitude A = 5 cm are given by
and If the resultant amplitude is 8.66 cm, what is the phase
difference ϕ?

(A) 30o
(B) 60o
(C) 90o
(D) 120o

19) One mole number n=2 of an ideal gas at T=300 K is isothermally compressed from V1= 5.0 L to
V2= 1.0 L. Find the work done by the gas (in joules). Use R=8.314 J/mol K. (Sign matters: work done
by the gas will be negative for compression.)

(A) −4.99×103 J
(B) −8.03×103 J
(C) +8.03×103 J
(D) −1.60×104 J

20) At constant temperature, the mean free path λ of gas molecules is inversely proportional to
pressure P. If λ=150 nm at 1.0 atm, what is λ at 4.0 atm (same temperature)?

(A) 37.5 nm
(B) 75 nm
(C) 300 nm
(D) 600 nm

SECTION - II

1) A step-down transformer has its primary winding of 2600 turns and is connected to a 2.4 kV AC
supply. The primary current is 3 A and the secondary current is 11 A. If the efficiency of the
transformer is 88%, the number of turns in the secondary winding is:

2) An ideal gas expands isothermally from a volume of 2 L to 8 L at a temperature of 300 K. If

n=1 mol, find the work done by the gas.
(Take R=8.314 J/mol K)

3) Two tuning forks sounded together produce 6 beats per second. One fork has frequency 250 Hz,
the other has frequency f. When the frequency of the 250 Hz fork is increased by 4 Hz (so becomes
254 Hz), the beat frequency becomes 2 Hz. What was the original frequency f of the second fork?

4) Monochromatic light of wavelength 300 nm is used in Youngs Double slit experiment. One of the
slit is covered by a transparent sheet of thickness having refractive index 1.6. How
many fringes will shift due to introduction of sheet.

5)

The main scale of a vernier Calliper is calibrated in mm and 19 divisions of main scale are equal in
length of to 20 division of vernier scale. In measuring the diameter of a cylinder by this instrument
the main scale reads 35 division and 4th division of Vernier Scale coincides with a main scale
division. The radius of cylinder will be. x.76cm then the value of x is -

PART - 2 : CHEMISTRY

SECTION - I

1)

The total number of electrons transferred when nitrobenzene is electrically reduced to aniline (NA =
Avogadro's Number)

(A) 2NA
(B) NA
(C) 6NA
(D) 4NA

2)

When water is heated, then select the incorrect option :

(A) Its Kw increases

(B) Its [H+] increases
(C) Its [OH–] increases
(D) Its pH increases

3) During the complete hydrolysis of alkyl nitrile the hybridization of nitrogen has change from sp to
:

(A) sp2
(B) sp3
(C) sp
(D) None of the these

4)
Total number of bonds in compound C are

(A) Four
(B) Two
(C) Three
(D) One
5)

The major product of the following reaction

(A)

(B)

(C)

(D)

6) In a protein molecule various amino acids are linked together by :

(A) α-glycosidic bond

(B) β-glycosidic bond
(C) peptide bond
(D) dative bond

7)

Arrange the following in increasing order of rate of hydrolysis with H2O/Ag+

(A) I<III<IV<II
(B) III<I<IV<II
(C) I<III<II<IV
(D) IV<I<II<III

8)

During an adiabatic compression of an ideal gas from 10L to 5L against a constant external pressure
of 1 bar. The Internal energy increase By :- (1 L bar = 100J )

(A) 5J
(B) 500 J
(C) 50J
(D) 0.5J

9)

The organic compound that can't be used for estimation of nitrogen using Kjeldahl's Method ?

(A) Aniline
(B) Pyrrole
(C) Acetonitrile
(D) Urea

10)

The freezing point of 0.1 molal HX (Ka = 10–5 aqueous solution is: , assume
molality = molarity).

(A) 2.02oc
(B) –0.202oc
(C) –0.2oC
(D) –2oC

11)

Consider the following sequence of reaction:

If electronic configuration of element X is [Ne] 3s' , which of the following result is incorrect?

(A)
(B)
(C)
(D)

12)

Given below are two statements :

Statement (I) : A spectral line will be observed for a 2px → 2py transition.
Statement (II) : 2px and 2py are degenerate orbitals.
In the light of the above statements, choose the correct answer from the options given below :

(A) Both Statement-I and Statement-II are true.

(B) Both Statement-I and Statement-II are false.
(C) Statement-I is true but Statement-II is false.
(D) Statement-I is false but Statement-II is true.

13) Increasing order of reactivity of the following compounds for SN1 substitution is:

(A) (B) < (C) < (D) < (A)

(B) (A) < (B) < (D) < (C)
(C) (B) < (A) < (D) < (C)
(D) (B) < (C) < (A) < (D)

14) Complex compounds which are optically active and does not depend upon the orientation of
ligand around metal cation:

(A) i, ii and iii

(B) ii and iii
(C) only ii
(D) All of the above

15) A sample of PCl5 is allowed to decompose in a container against a constant external pressure till
following equilibrium is achieved:
 The relative vapour density of the sample increases till equilibrium is achieved and after that it
(A)
remain constant.
The degree of dissociation α is dependent on the total pressure under which equilibrium is
(B)
achieved.
The degree of α on attainment of equilibrium is dependent on the total no. of moles of
(C)
PCl5 initially taken.
(D) The molar mass of sample increases and density of sample remains constant

16) For a chemical reaction aA bB

The ratio of ‘a’ and ‘b’ is

(A) 0
(B) 1
(C) 2
(D) 3

17)

Which amine has the lowest boiling point?

(A)

(B)
(C)

(D)

18) Transfer of charge in the cause of colour for permanganate ions

(A) Ligand to metal

(B) Metal to ligand
(C) Anion to metal
(D) Metal to anion

19) Select correct statement :

(A) Sucrose is a trisaccharide & non reducing sugar

(B) Sucrose is a disaccharide & reducing sugar
(C) Sucrose is a disaccharide & non reducing sugar
(D) Sucrose is a trisaccharide & reducing sugar

20)

Which of the following is correctly matched?

Diretion of
Molecule
dipole moment

(A)

(B)

(C)

(D) None of these

(A) A
(B) B
(C) C
(D) D

SECTION - II

1)
"How many of the following can reduce Tollen's reagent to silver mirror & Fehling's reagent to brick
red precipitate?"

* Fructose
* Glucose
* Sucrose
* Galactose
* Formic acid
* Glyoxal
* Acetone
* Benzoin
* Benzaldehyde
* Acetaldehyde

2) Total number of chiral carbons in the tripeptide ASP-THR-VAL.

3) The sum of average oxidation numbers of the d-block metals in chromite ore and pyrolusite ore

4) Total number of carbons in the product of the following reaction :-

5) At 298K, 1 bar pressure 1 g of sulphur was born at constant pressure, the half released heated
1kg H2O (l) by 2oC. The magnitude of is ________kcal/Mol.[given = 1cal/g – oC ].

PART - 3 : MATHEMATICS

SECTION - I

1) A line L is drawn from point P(4, 3) to meet the lines L1: 3x + 4y + 5 = 0 and L2: 3x + 4y + 15 =
0 at points A and B, respectively. From A, a line perpendicular to L is drawn, meeting the line L2 at
A1. Similarly, from point B a line , perpendicular to L is drawn meeting the line L1 at [Link] a
parallelogram AA1BB1 is formed. The slope of line 'L' so that the area of the parallelogram AA1BB1 is
least, is equal to
(A) –7
(B) 7
(C) –5
(D) 5

2) Let A(9, -3), B(4, 2), and C(1, -1) be the vertices of a triangle ABC. A parallelogram AFDE is drawn
with vertices D, E, and F on the line segments BC, CA, and AB, respectively. Find the maximum area
of such a parallelogram is equal to.

(A) 6

(B)

(C) 9
(D) None

3) The ends A, B of a straight line segment of unit length slide upon the fixed rectangular axes OX,
OY respectively. If the rectangle OAPB is completed, then the locus of the foot of the perpendicular
drawn from P to AB is________.

(A) x2+y2=1
(B) x3+y3=1
(C) x2/3+y2/3 = 1
(D) x3/2+y3/2 = 1

4) The line λx+2y+3 = 0 cuts the circle x2 + y2 + 4x + 4y – 1 = 0 at points P and Q and cuts the
coordinate axes at point A and B and the line 2x + 3y +μ= 0 cuts the circle x2+y2+6x+2y–7= 0 at
points R and S and cuts the coordinate axis at point C and D .
If P, Q, R, S are concyclic, and A,B,C,D are concyclic then the value of . (given λ, μ > 0 )

(A) 7
(B) 8
(C) 9
(D) 10

5) Two chords are drawn through the point (4, 4) of the parabola y2 = 4x and are at right angles . If
the join of their other extremities passes through a fixed point (α, β). find the value of (α+β).

(A) 3
(B) 4
(C) 5
(D) 6

6) From a variable point P(t2, 2t), where , on the parabola y2 = 4x, a perpendicular to PM is
drawn to the tangent at the vertex of the parabola. Now from the midpoint Q of PM, a perpendicular
QL is drawn to the focal chord of the parabola through P. Find the maximum length of QL is
(A)

(B)

(C)

(D) None

7) Suppose f is a differentiable real function such that: for all x and f(0) = 0. Then
the largest value of f(1) is equal to _______.

(A)

(B)

(C)

(D)

8)
where a and b are integers. Find the value of (a + b).

(A) –1
(B) 0
(C) 10
(D) 11

9) Let a,b be constant such that . Then the ordered pair (a,b) is

(A) (2,1)
(B) (–2, –1)
(C) (–2,1)
(D) (2,–1)

10)

The area of the region in the xy – plane consisting of all points (a,b) such that the quadratic ax2+2
(a+b–7) x + 2b = 0 has fewer than two real solution of x, is equal to .

(A) 36 π
(B) 25 π
(C) 49 π
(D) 64 π
11) The curve represented by the equation

(A) An ellipse with the foci on the x- axis

(B) A hyperbola with the foci on the x- axis
(C) An ellipse with the foci on the y- axis
(D) A hyperbola with the foci on the y- axis

12) The sum of all the positive integers n satisfying is __________

(A) 10
(B) 21
(C) 33
(D) 47

13) Suppose points F1 and F2 are the left and right foci, of the ellipse respectively , and
point P is on the line . When the angle F1P F2 reaches its maximum, find

the value of the ratio is.

(A)
(B)
(C)
(D)

14) Find the number of permutations p1, p2, p3, p4, p5 of the numbers 1,2,3,4,5 such that sum of five
products P1P2P3+P2P3P4+P3P4P5+P4P5P1+P5P1P2 is divisible by 3

(A) 40
(B) 80
(C) 81
(D) None

15) Pn denotes the number of persons entered in cinema hall & Cn denotes the number of chairs
alloted to person Pn (Where n= 1,2,3,4,5). The number of ways of alloting all prime numbered
person, prime numbered chair or all composite numbered person composite numbered chair but not
both simulataneously is

(A) 24
(B) 12
(C) 9
(D) 36
16) Three numbers are chosen at random, one after another, with [Link]
If P1 is the probability that the maximum of the chosen numbers is at least 161 and
P2 be the probability that the minimum of choose number is almost 80. Then find value of

(A) 2
(B) 4
(C) 6
(D) 24

17) The value of = α then value

of is

(A) 1
(B) –1
(C)
(D)

18) Number of valves of αε [0,5π] for which the system of linear equations

has no. solution is r than. Find greatest bionomial coefficient in expansion of

13
(A) C7
12
(B) C6
24
(C) C18
8
(D) C6

19) If Mean - and the variance of 10 observation a1,a2,a3...........a10 the 10 & 5 respectively for xεR , if
the mean of (a1+x)2 , (a2+x)2 , .....(a10+x)2 is 160 then sum of all real values of x is

(A) 20
(B) 40
(C) –20
(D) None

20) A relation R is defined on Set . Then find the probability that R is both Symmetric and
transitive is equal to

(A)

(B)
(C)

(D)

SECTION - II

1) The sequence {an} is defined by: Find the greatest integer less than

2) If
May be equal to when n is not multiple of 3.

3) Let
It and

(where p, q, r, s, k are real numbers) has positive real roots and f(2)=1 then the value of sum of
roots of f1 (x) which are greater than 1 is

4) In triangle XYZ let

it

and then value of is

5) If X and Y are two non-singular matrices of order 3 such that and then

value of det equal to 10k then find K (Where det (x) represent determinant
value of matrix X)
 ANSWER KEYS

PART - 1 : PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D B B C C B D A B A A A C B D B B B A

SECTION - II

Q. 21 22 23 24 25
A. 624 3460 256 72 1.00

PART - 2 : CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D B C B C B B C B A D C C B C C C C C

SECTION - II

Q. 46 47 48 49 50
A. 7.00 4.00 9.00 16 64

PART - 3 : MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B C C B C D D C C A C B B A A A B C D

SECTION - II

Q. 71 72 73 74 75
A. 1.00 0.00 12 6.00 6.00
 SOLUTIONS

PART - 1 : PHYSICS

1)
As
hence
so only one third of overall charge enclosed by sphere.

2)

3)

4)
5)

For error calculation

Error formula

As

Hence

6) Given: D = 8 cm = 0.08 m, t = 4 mm = 0.004 m, v = 1.50 × 108 m/s.

Refractive index:
Using the approximation for the radius of curvature of a shallow spherical surface (valid when
the central thickness is small compared to the radius),

For a plano–convex lens the lens-maker relation reduces to

Therefore
Hence the focal length of the lens is 0.20 m.

7) Given: t = 12×10−6 m, µ = 1.5, λ = 600×10−9 m.

When a plate of thickness t and refractive index µ is placed in front of one slit, an additional
optical path difference is introduced:
∆ = (µ −1)t.
The corresponding shift of the central maximum on the screen is:

Substituting the given values:

Therefore, the central maximum shifts by 10β.

8) For an electron accelerated through a potential V,

Substitute the given values:

Hence,

Therefore,

Thus, the accelerating potential required is approximately 56 V.

9) Energy of the emitted photon:

Convert to joules:
E = 12.75×1.6×10−19 = 2.04×10−18 J
Photon momentum:

Momenta of photon and nucleus is equal and opposite by conservation of linear momentum.
Recoil speed of hydrogen atom:

Therefore, the recoil speed of the hydrogen atom is approximately 4.1 m/s.

10) Given: A has mass number 220, and after fission produces fragments B(105) and C(115)
with binding energy per nucleon 6.4 MeV. The total energy released is Q = 220 MeV.
Total binding energy after fission:
Eafter = 220×6.4 = 1408 MeV
Let the binding energy per nucleon of A be x. Then the total binding energy before fission is
Ebefore = 220x.
Since Q = Eafter −Ebefore,
220 = 1408−220x.
Solving,
220x = 1408−220 = 1188 MeV/nucleon.
Therefore, the binding energy per nucleon of nucleus A is 5.4 MeV.

11) The work done by a variable force is given by

On integrating,

Substituting the limits,

Therefore, the work done by the force is

12) For block A,

NA = mAg−F sin37 = 12×10−50×0.6 = 120−30 = 90 N
For block B,
NB = mBg = 8×10 = 80 N.
The maximum static friction for the system (using the same µ) is
fs,max = µ(NA +NB) = 0.10(90+80) = 17.0 N
F cos37 = 50×0.8 = 40 N.
Since 40 > 17.0, motion occurs and friction is kinetic.
The kinetic friction forces are
fkA = µNA = 0.10×90 = 9 N, fkB = µNB = 0.10×80 = 8 N.
The acceleration of the system is

For block B,
T − fkB = mBa ⇒T = mBa+ fkB = 8(1.15)+8 = 9.2+8 = 17.2 N
The minimum cross-sectional area of the string is

Therefore, the minimum area required so that the string does not break is 1.0 mm2.

13) For pure rolling without slipping, the tangential speed of any rim point relative to the
centre equals the speed of the centre:
ωR = V0
Thus the rotational (tangential) velocity of P has magnitude V0.

Add the two equal vectors and by the parallelogram law. The angle between them is
o
120 and their magnitudes are equal (V0 and V0). The resultant of two equal vectors separated
by 120o bisects the angle between them and has magnitude
The bisector of the 120o angle between 0o (right) and 120o points at 60o below the +x axis.
Hence the resultant velocity has magnitude V0 and is directed 60o below the horizontal.
Therefore option (A) is correct.

14) Take downward direction as positive y-axis with origin at O.

The centres of mass of the rods are:

yh = 0 (horizontal rod), (vertical rod).

Using the definition of the combined centre of mass:

Thus, the centre of mass lies a distance below point O.

15) To reach directly north, the boat’s resultant velocity must be directed north.
Let river velocity vr=3 m/s (east), boat’s speed vb=5 m/s.
The westward component of boat’s velocity must cancel river flow:

16) Resultant amplitude:

17) Northward component of boat speed:

Time to cross 100m :

Westward component of boat speed:

River pushes east at 6 m/s.

Net eastward velocity
Downstream drift =vnet, east​ × t = 1 × 11.547005 = 11.547005 m ≈ 11.55 m

18) For two equal amplitudes A and phase difference ϕ, resultant amplitude
Given and :

corresponds to ϕ/2=30o. Thus ϕ=60o

19) Formula for isothermal work done by the gas:

Convert liters to m3 (not strictly necessary if ratio used, but we keep units consistent):
V1​=5.0 L=5.0×10−3 m3, V2​= 1.0 × 10−3 m3
Compute constants: nRT=2 × 8.314 × 300 = 2 × 2494.2 = 4988.4 J

Volume ratio:
ln(0.2) = ln(1/5) = −ln 5. ln ⁡ 5 ≈ 1.6094379. So ln(0.2) ≈−1.6094379.
Now W = 4988.4 × (−1.6094379) ≈−8028.52 J.
Rounded: −8.03 ×103 J

20) So

21) Given: Np = 2600, Vp = 2400 V, Ip = 3 A, Is = 11 A, η = 88% = 0.88.

Input power: Pin = VpIp = 2400×3 = 7200 W.
Output power: Pout = ηPin = 0.88×7200 = 6336 W.

Secondary voltage:

Transformer relation:

Therefore, the number of turns in the secondary winding is 624.

22) For isothermal process:

=2494.2×ln(4)
ln(4) = 1.386 ⇒ W = 2494.2 × 1.386 = 3456.6 J

23) Initial beat frequency: So f = 244 or 256.

After increasing the 250 Hz fork to 254 Hz, new beat frequency:
Check
Check

24) Number of fringes shifted

= 72

25)
 1 MSD = 1 mm
19 M = 20V

Reading = 35 mm + 4 (0.05)
= 35 + 0.2
= 35.2mm = 3.52cm

PART - 2 : CHEMISTRY

26)

The total number of electrons transferred when nitrobenzene is reduced to

aniline
This is because the nitrogen atom's oxidation state changes from +4 in nitrobenzene to -2 in
aniline, requiring the transfer of 6 electrons per molecule.
{Change in Oxidation State} = (+4) - (-2) = 6
For one mole, the total number of electrons is .

27)

Question Explanation: Effect of temperature on auto-ionization of water.

Concept: H₂O ⇌ H⁺ + OH⁻

Auto-ionization of water is endothermic.

Solution:
On heating, equilibrium shifts forward → K₍w₎ increases
Hence [H⁺] increases and [OH⁻] increases equally
Since pH = −log[H⁺], increase in [H⁺] ⇒ pH decreases, not increases

Final Answer: Option 4

28)

On hydrolysis the by product is ammonium while main product is carboxylic acid.

29)

The end product is an aldol condensation product which will have a conjugated system of 3
sp2 carbons and one oxygen resulting in three sp2 - sp2 sigma bonds.

30)

1,2-Shift (Ring Expansion):

The net result is the ring expansion of the six-membered ring alcohol/amine precursor to a
seven-membered ring ketone.
Major Product = Cycloheptanone

31)

Correct Answer is (C)

32)

The rate of hydrolysis with follows an SN1 mechanism, where the rate-determining
step is the formation of a carbocation. Therefore, the rate is directly proportional to the
stability of the carbocation intermediate.

33)

The internal energy (ΔU) increases by the amount of work done on the gas, as the process is
adiabatic (q=0).
Given:
V1 = 16L
V2 = 5L
Pext = 1bar
1L. bar = 100J
Work Done ω

Change in Internal Energy ΔU

Final Answer (Based on Calculation): 1100J (Not listed in options).

Selecting the Option Based on Likely Typo: Assuming V1 and V2 were intended to yield 5L
bar of work: (B) 500J.

34)

Kjeldahl's method fails for compounds where the nitrogen atom is part of a structural group
that does not quantitatively convert into ammonium sulfate under the method's conditions.
These groups include:

Azo groups (–N= N–)

Nitrogen in rings (Heterocyclic compounds like Pyridine)

35)

Degree of Dissociation (α)

van't Hoff Factor (i):

Freezing Point Depression

 = 0.202oC
Freezing Point (Tf): = 0oC–ΔTf = – 0.202o C

36) A is correct.
Successive I.E. increases ' C', 'D' are correct.
On reversing the magnitude of enthaly reaction same.

37)

No spectral line will be observed for a 2px → 2py transition because 2px and 2py orbitals are
degenerate orbitals.

38)

Explain Question: 0
Concept: 0
Solution:
SN1 Reactivity order

Order C > D > A > B

Final Answer: (3)

39) Correct Answer only ii

40) The degree of dissociation α is dependent on the total pressure under which equilibrium is
achieved.

41)

Correct Answer is (C)

42) (3o amine) cannot form intermolecular H-bonds.

 43) permanganate ions have zero electrons in 3d subshell but are coloured purpole due charge
transfer from oxide to metal.

44) Sucrose is a disaccharide & non reducing sugar

45)

46) The compounds that can reduce both Tollen's reagent and Fehling's reagent are:

A. Fructose
B. Glucose
C. Galactose
D. Formic acid
E. Glyoxal
F. Benzoin

7. Acetaldehyde

The total number of compounds that satisfy the condition is 7.

47) Total Count :- The total number of chiral carbons in the tripeptide is the sum of the
chiral carbons in each constituent amino acid residue:
Total Chiral Carbons = (Chirality of ASP) + ( Chirality of THR) + ( Chirality of VAL)
Total Chiral Carbons = 1 + 2 + 1 = 4
The total number of chiral carbons in the tripeptide ASP-THR-VAL is 4.

48) Factual
Correct Answer is 9.00

49) The second reaction involves aldol condensation which doubles number carbons.

50)
Convert to Molar Enthalpy of Formation.

The molar enthalpy of formation

 Convert cal/mol to kcal/mol

The standard enthalpy of formation of is -64 kcal / mol .

PART - 3 : MATHEMATICS

51)

Area is minimum when θ = 45o

Let slope of line 'L' is m

52)
AC= b
BC = a
are similer

Area of AFDE = xysinA

are the midpoint.

Area of

Area of parallelogram AFDE =

53)
AB= 1
a2+b2 = 1
MPQ. MAB = –1

Point Q(h,k) lies an AB line

Solving (i) and (ii)

54) Intersects the coordinate axis in concyclic point.

λ(2) = 2(3)
λ=3
3(2μ–18)–2 (–2μ–12)+3(–6–4)= 0
6μ–54+4μ+ 24 – 30 = 0
10μ – 30 – 30 = 0
μ=6
λ+μ=9

55)
MPQ MPR = –1
.

The equation of chord QR

y(t1+t2)= 2x+2t1t2
y (t1+t2)= 2x+2[–2(t1+t2) –8]
(y+4)(t1+t2) –(2x–16) = 0

For fixed point (α,β)

α+β = 4
56)
The equation of focal chord PR is
(t–1/t)y = 2 X –2

57)

58)

= a=5
b = 6 (Both are integers, as required).
a+b = 11.
59) 1+a+b = 0
Using L' Hopital rule,

a = –2
b= 1

60)

Circle with centre (7,7) and r = 7

Area = πr2 = 49π

61)

Curve is an ellipse with the foci on the y – axis

62) in

n = 10 ,11, 12, satisfes

Answer 33

63)
AF1 = 8 , AF2 =

64) Let any one of the no.

So P3 = 3
3(P2P4+P4P5+P1P2)+P1P5(P2+P4)
So remaining number are 1,2,4,5
P1 . P5 can not be divisible by 3 hence P2+P4 can be divisible by 3. If pair (P2,P4) is
(1,2) (2,1) (1,5) (5,1) (4,2) (2,4) (4,5) (5,4)
For each pair of (P2P4) & P3 = 3
P1 & P5 can be selected from remaining 2 number in 2 ways so total ways are & we
can put any of P1, P2, P3, P4, P5 equal to 3 so.
Total ways

65) (I) If prime no chair alloted to prime number person

(P2, P3, P5) can be alloted (C1, C3, C5) in 3! ways & P1 alloted C4, P4 alloted C1
Since C4 Cannot be alloted P4 both are composite
(II) If composite number person alloted composite no. chair i.e. P4 alloted C4 & P2, P3 P5 can be
,

alloted C1 in 3C1 ways.

Now remaining three persons can be alloted remaining three chairs in 3! ways.
So total ways

66) P1 = 1 – (Probability that 3 Chosen number are less than 161)

P2 = 1 – (Probability that 3 Chosen number are greater than 80)

67)

68)
 total 6 solution.
Total 12 solution so r = 12
, middle term in

coefficient is 12C6

69)

70)

Total Relation is
Favourable relation are

Total 5 favourable relation

So Probability

71)

.
.
.
.
.
.
.
The intermediate terms cancel out:

will all be less than 1.

72)

If n is not multiple of 3.

73) f2(x) has 5 positive real

By rulles theorem
f2'(x) = 0 has 4 positive real roots .
f1(x) = 0 has 4 positive roots
pr – 16s = 0

Hence
74)

75) X–1Y2+XY = 0
X–1YYY–1 +XYY–1=0.Y–1

K= 6