16-04-2026

7650CJA101021260001 JA

PART - 1 PHYSICS

SECTION-I

1) A small object of mass M and charge Q is connected to an insulating massless string in a

vacuum on Earth. A uniform electric field exists throughout the region of the vacuum as indicated.
The mass remains in static equilibrium at an angle of θ with the vertical as shown in the figure.
When the string is cut, which of the illustrated paths best indicates the trajectory of the mass ?

(A) I
(B) II
(C) III
(D) IV

2) Two small balls each of mass m are held by light strings of length as shown in the figure. The
initial separation between the balls is r. At t = 0, each ball carries a positive charge q0. Now, the
charge of each ball slowly changes; and the variation is given by q(t) = q0(1 + bt)1.5, where b is a
positive constant. The balls are also released at t = 0. Which of the following is correct.

(A) The balls will approach each other at constant speed.

(B) The balls will approach each other at increasing speed.
(C) The balls will approach each other such that the speed will first increase and then decrease.
(D) The balls will approach each other such that the speed will first decrease then increase.

3) A long string with a charge of λ per unit length passes through an imaginary cube of edge a. The
maximum flux of the electric field through the cube will be :-
(A)

(B)

(C)

(D)

4) Consider a uniform electric field . What is the flux of this field through a square
of 10 cm side length and normal to the plane makes α, β, γ from x-axis, y-axis and z-axis and sinα =

, sin β = , sin γ = :-

(A)

(B)

(C)

(D)

5) The charge per unit length of the four quadrant of the ring is 2λ, –2λ, λ and –λ respectively. A
particle of charge –q and mass m is released from center. Its initial acceleration will be

(A)

(B)

(C)

(D)

6) A charge Q is placed at origin in front of a imaginary square plate of side a. The plate is situated

in y-z plane and its centre is at . Total flux passes through plate is
(A)

(B)

(C)

(D)

7) A charged particle q is placed at the centre O of cube of length L (ABCDEFGH). Another same
charge q is placed at a distance L from O. Then the electric flux through ABCD is-

(A) 0

(B)

(C)

(D)

8) Two semi-infinite wires are joined with a quarter circular arc as shown in diagram. The charge
density is same on both the wires and the arc. x component of electric field intensity at point 'C', the

center of arc, is

(A)

(B)

(C)

(D)

9) A charge +Q is located somewhere inside a vertical cone such that the depth of the charge from
the free surface of the cone is H. It is found that the flux associated with the cone with the curved

surface is . If the charge is raised vertically through a height 2H, then the flux through the
curved surface is

(A)

(B)

(C)

(D) Zero

10) A spherical cavity of radius 2R is made in a uniform sphere of radius 4R and charge density +ρ
c/m3 as shown in figure. Choose the correct option for electric field inside cavity.

(A)
Electric field inside cavity is along .

(B)
Electric field at point P is along .

(C)
Electric field at any point inside cavity is along .

(D)
Electric field at any point inside cavity is along x-axis.

11) Two large metal plates each of area A carry charges +q and –q and face each other. The plates
are separated by a small distance d the electric field between the plates would be
(A)

(B)

(C)

(D)

12) A point charge q is placed above center of equilateral triangle of side a at perpendicular height

h. The flux passing through triangle due to charge is then value of is:

(A)
(B)
(C)
(D)

13) Charge 2Q and –Q are placed as shown in figure. The point at which electric field intensity is

zero will be:

(A) Somewhere between –Q and 2Q

(B) Somewhere on the left of –Q
(C) Somewhere on the right of 2Q
(D) Somewhere on the right bisector of line joining –Q and 2Q

14) A cube of side ‘ℓ’ placed as shown in figure . Flux passing through cube will be:-
(A)

(B)

(C)
(D) Zero

15) Two identically charged spheres are suspended by strings of equal length. The strings make an
angle of 30° with each other. When suspended in a liquid of density 0.8 g/cc the angle remains the
same. What is the dielectric constant of liquid? Density of sphere = 1.6 g/cc

(A) 1
(B) 2
(C) 3
(D) 4

16) Fig. shows a large conducting ceiling having uniform charge density s below which a charge
particle of charge q0 and mass m is hung from point O, through small string of length ℓ calculate the
minimum horizontal velocity required for the string to become horizontal : (Neglect gravity)
(A)

(B)

(C)

(D)

17) The variation of electric field between the two charges q1 and q2 along the line joining the
charges is plotted against distance from q1 (taking rightward direction of electric field as positive) as

shown in the figure. Then the correct statement is :-

(A) q1 and q2 are positive and q1 < q2

(B) q1 and q2 are positive and q1 > q2
(C) q1 is positive and q2 is negative and q1 < q2
(D) q1 and q2 are negative and q1 < q2

18) As shown in the figure, an insulating rod is set into the shape of a semicircle. The left half of the
rod has a charge of + Q uniformly distributed along its length, and the right half of the rod has a
charge of –Q uniformly distributed along its length. What vector shows the correct direction of the

electric field at point P, the centre of the semicircle ?

(A) A
(B) B
(C) C
(D) D

19) The electric field strength due to a ring of radius R at a distance x from its centre on the axis of

ring carrying charge Q is given by . At what distance from the centre will the
electric field be maximum ?

(A) x = R
(B) x = R/2
(C) x =
(D)

20) A sphere of radius R and charge Q is placed inside an imaginary sphere of radius 2R whose
centre coincides with the given sphere. The flux related to imaginary sphere is :

(A)

(B)

(C)

(D)

SECTION-II

1) Expression for an electric field is given by . The electric flux through the cube of
side 20 cm when placed in electric field (as shown in the figure) is _______ V cm.

2) A uniform electric field E = 500 N/C passes through a hemispherical surface of radius R = 1.2 m
as shown in figure. The net electric flux (in S.I. units) through the hemispherical surface only is Nπ.
Then find the value of N.

3) As shown in figure, a cuboid lies in a region with electric field N/C. The
magnitude of charge within the cuboid is . The value of n is _______

(If dimensions of cuboid is 1 × 2 × 3 m3)

4) An electric field, passes through the surface of 4 m2 area having unit vector

. The electric flux for that surface is _________ V m.

5) A charg q is surrounded by a closed surface consisting of an inverted cone of heigh h and base
radius R, and a hemisphere of radius R as shown in the figure. The electric flux through the conical

surface is (in SI units). The value of n is ______

PART - 2 CHEMISTRY
 SECTION-I

1) Sodium salts are highly soluble in water and hence undergoes complete ionisation in water. If the
freezing point of 0.35 molal aq. NaxA solution is – 3.255°C, the value of 'x' is
(Kf = 1.86 K–kg/mole)

(A) 2
(B) 3
(C) 4
(D) 5

2) Dry air was passed through a solution of 5 gm of a solute in 80 gm of water and then it is passed
through pure water loss in wt. of solution was 2.50 gm and that of pure solvent was 0.04 gm .
Calculate M.W (Approx.) of solution

(A) 16 gmole-1
(B) 87 gmole-1
(C) 40 gmole-1
(D) 70 gmole-1

3) Henry's constant (in kbar) for four gases α, β, γ and d in water at 298 K is given below :

(density of water = 103 kg m–3 at 298 K)

This table implies that :

(A) The pressure of a 55.5 molal solution of γ is 1 bar

(B) The pressure of a 55.5 molal solution of δ is 250 bar
(C) Solubility of γ at 308 K is lower than at 298 K
(D) α has the highest solubility in water at a given pressure

4) The correct relationship between the boiling points of very dilute solutions of AlCl3(t1) and
CaCl2(t2), having the same molar concentration is :

(A) t1 = t2
(B) t1 > t2
(C) t2 > t1
(D) t2 ≥ t1

5) Which of the following aqueous solutions is isotonic with 15 % glucose aqueous solution with
specific gravity of 1.2 ?

(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea

0 0
6) What is the mole ratio of benzene (PB = 150 torr) and toluene (PT = 50 torr) in vapour phase if the
given solution has a vapour pressure of 120 torr ?

(A) 7 : 1
(B) 7 : 3
(C) 8 : 1
(D) 7 : 8

7) 30.11 × 1022 unit cell of K2S is dissolved in 10 litre water. K2S has antifluorite structure. The
freezing point of the solution becomes [Kf of water is 1.86 ºC kg/mole, = 273K]

(A) 272.78K
(B) 271.884 K
(C) 272.87K
(D) 272.9K

8) Dry air was drawn through bulbs containing pure water ,then through bulbs containing a solution
of 600 grams of a non electrolyte in 360 grams of water at the same temperature and finally
through a tube in which dried CaCl2 was placed. The solution bulb gained 1.5 gram and the dried
CaCl2 gained 2 [Link] Molecular mass of the solute is :-

(A) 40
(B) 9
(C) 90
(D) 50

9) A solution of x moles of sucrose in 100 grams of water freezes at –0.2ºC. The amount of ice that
will separate out when it is cooled upto –0.25°C is :-

(A) 18 grams
(B) 20 grams
(C) 25 grams
(D) 23 grams

10) We have three aqueous solutions of NaCl labelled as 'A', 'B' and 'C' with concentrations 0.1M,
0.01M and 0.001M, respectively. The value of van't Hoff factor for these solutions will be in the
order ____.

(A) iA < iB < iC

(B) iA > iB > iC
(C) iA = iB = iC
(D) iA < iB > iC

11)
State T(true)/F(false) for following statements regarding given liquid solutions :

(a) Final volume of solutions if equal volume of compounds are mixed, is in the order:
VI=VII < VIII
(b) ΔSmix for solution I and solution II is positive but for solution III it is zero.
(c) Enthalpy change of mixing is negative for solution II and solution III but positive for solution I.

(A) TFF
(B) FFF
(C) TTF
(D) FTT

12) Which of the following plots represents an ideal binary mixture ?

(A) Plot of Ptotal v/s 1/XB is linear (XB = mole fraction of 'B' in liquid phase).
(B) Plot of Ptotal v/s YA is linear (YA = mole fraction of 'A' in vapour phase)

(C)

(D)

13) The phase diagrams for a pure solvent (represented by the solid line) and a corresponding
solution (containing a nonvolatile solute and represented by the dashed lines) are shown below.

If Tf, Tb and m stand for freezing point temperature, boiling point temperature and molality.
Choose the correct option.

(A) A = ΔTb m and B = ΔTfm

(B) A = ΔTf m and B = ΔTbm
(C) A = ΔTf and B = ΔTb
(D) A = ΔTb and B = ΔTf
14) For an ideal binary liquid solution with , which relation between XA (mole fraction of A
in liquid phase) and YA (mole fraction of A in vapour phase) is correct?

(A) YA < YB
(B) XA > XB

(C)

(D)

15) Arrange the following aqueous solutions in order of increasing freezing points (that is lowest
first) :-

I. 0.10 m Ba3(PO4)2 II. 0.10 m Na2SO4

III. 0.10 m C2H5OH IV. 0.10 m KCl

V. 0.10 m Li3PO4
(A) I < V < II < IV < III
(B) III IV < II < V < I
(C) IV < II < V < I < III
(D) I < V < II < IV = III

16) The Henry's law constant for the solubility of N2 gas in water at 298K is 1.0 × 105 atm. The mole
fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles of water at 298 K
and 5 atm pressure is

(A) 4 × 10-4
(B) 4 × 10-5
(C) 5 × 10-4
(D) 4 × 10-6

17) Which of the following curves represents Henry's law ?

(A)

(B)
(C)

(D)

18) Molar solubililty of helium, nitrogen and oxygen are plotted against partial pressure of the gas at
constant temperature
Henry's law constant for these gases will lie in following sequence?

(A) O2 > N2 > H2

(B) O2 < N2 < He
(C) O2 = N2 = He
(D) O2 > N2 < He

19) Five percent solution of a solute (X) is isotonic with 0.855% solution of sucrose (Moleculor
weight = 342) what is the molecular mass of solute (X)

(A) 200
(B) 58.482
(C) 400
(D) 2000

20) Vapour pressure of a solution containing nonvolatile solute is -

(A) More than the vapour pressure of a solvent

(B) Less than the vapour pressure of solvent
(C) Equal to the vapour pressure of solvent
(D) None of these

SECTION-II

1) Container A in figure holds an ideal gas at a pressure of 1.0 × 105 Pa and a temperature of 300K.
It is connected by thin tube (and a closed valve) to container B, with four times the volume of A.
Container B holds the same ideal gas at a pressure of 9.0 × 105 Pa and a temperature of 400K. The
valve is opened to allow the pressures to equalize, but the temperature of each container is
maintained as before. What then is the common pressure in 105 Pa ? (Nearest Integer)

2) For an aqueous solution of 0.1M Ba(NO3)2, osmotic pressure at 300K is found to be 6.0 atm.

Degree of dissociation of Ba(NO3)2 in solution is . Then find the value of 'p'. (R = 0.08 atm-L/mole-
K).

3) In the saturated aqueous solution of PbCl2 the freezing point decreases by °C then ‘D’ is
(Given Ksp of PbCl2 = 4 × 10–6, Kf, water = 2K-kg/mole.

4)

Liquids A and B form ideal solution over the entire range of composition. At temperature T,
equimolar binary solution of liquids A and B has vapour pressure 45 Torr. At the same temperature,
a new solution of A and B having mole fractions xA and xB respectively, has vapour pressure of 22.5

Torr. If the value of in the new solution is Y. Then the value ‘Y-10’ is :
(Given that the vapour pressure of pure liquid A is 20 Torr at temperature T)

5) How many of the following solutions show negative deviation from Raoult's Law ?

Liquid A + Liquid B
(I) (CH3)2CO + CS2

(II) CCl4 + C6H6

(III) CCl4 + CHCl3

(IV) H2O + C2H5OH

(V) (C2H5)2O + (CH3)2CO

(VI) CH3COOH + C5H5N (pyridine)

(VII) C6H5NH2 + (CH3)2CO

(VIII) C6H5Cl + C6H5Br

(IX) Cyclohexane + Ethanol

PART - 3 MATHEMATICS
 SECTION-I

1)

Which one of the following relations on R is an equivalence relation :

(A) a R1b ⇔ |a| = |b|

(B) aR2b ⇔ a ≥ b
(C) a R3b ⇔ a divides b
(D) a R4b ⇔ a < b

2) Let R = {(3, 3), (5, 5), (9, 9), (12, 12), (5, 12), (3, 9), (3, 12), (3, 5)} be a relation on the set A = {3,
5, 9, 12}. Then, R is :-

(A) reflexive, transitive but not symmetric.

(B) symmetric, transitive but not reflexive.
(C) an equivalence relation
(D) reflexive, symmetric but not transitive.

3) The total no. of binary relations on a set with 4 elements is

(A) 216
(B) 44
(C) 162
(D) 28

4) Let A be a set of first 10 natural number and R be a relation on A, defined by

then domain of R is

(A) {1, 2, 3, 4…….10}

(B) {2, 4, 6, 8}
(C) {1, 2, 3, 4}
(D) {2, 4, 6, 8, 10}

5) Let set X = {1, 2, 3} and a relation R is defined in X as : R = {(1, 3), (2, 2), (3, 2)}, then minimum
ordered pairs which should be added in relation R to make it reflexive and symmetric are:

(A) {(1, 1), (2, 3), (1, 2)}

(B) {(3, 3), (3, 1), (1, 2)}
(C) {(1, 1), (3, 3), (3, 1), (2, 3)}
(D) {(1, 1), (3, 3), (3, 1), (1, 2)}

6) Let a relation R on the interval is defined as x R y if and only if sec2 x - tan2 y = 1. Then R is
:
(A) an equivalence relation
(B) both reflexive and transitive but not symmetric
(C) both reflexive and symmetric but not transitive
(D) reflexive but neither symmetric not transitive

7)

The number of all onto functions from the set (1, 2, 3, 4, 5} to itself is

(A) 52
(B) 5!
(C) 25
(D) 225

8) If R = {(x, y) : x, y ∈ Z, x2 + 3y2 ≤ 8} is a relation on the set of integers Z, then the domain of R–1
is:

(A) {–2, –1, 1, 2}

(B) {–1, 0, 1}
(C) {–2, –1, 0, 1, 2}
(D) {0, 1}

9) Given , then sum of all real numbers which are not in the range of ƒ(x) is equal
to -

(A)

(B) 1
(C) –1

(D)

10) The range of the function f(x) = loge (3x2 – 4x + 5) is:

(A)

(B)

(C)

(D) None of these

11) Let ƒ : [2, ∞) → R be the function defined by ƒ(x) = x2 – 4x + 5, then the range of ƒ is

(A) R
(B) [1, ∞)
(C) [4, ∞)
(D) [5, ∞)

12) The number of solutions of the equation log4(x – 1) = log2(x – 3) is

(A) 0
(B) 2
(C) 1
(D) 3

13) The number of real solutions of the equation, x2 – | x | – 12 = 0 is :

(A) 1
(B) 2
(C) 3
(D) 4

14) Let ƒ : R → R be a function defined by , then ƒ is:

(A) one-one but not onto

(B) one-one and onto
(C) onto but not one-one
(D) neither one-one nor onto

15) ƒ : R → R, ƒ(x) = ex+sinx is

(A) one-one and into function

(B) one-one and onto function
(C) many-one and into function
(D) many-one and onto function

16) The function defined by f(x) = x3 - 5x2 + 7x + 1, is

(A) one-one onto

(B) onto but not one-one
(C) one-one but not onto
(D) neither one-one nor onto

17) If f : [–4, 4] → R, where

f(x)= sinx+ cosx +

(where [.] is greatest integer function) is an even function then

(A) a ∈ (0, 257]

(B) a ∈ [257,∞)
(C) a ∈ (257, ∞)
(D) a ∈ (0, 257)

18) The function is

(A) even
(B) odd
(C) neither even nor odd
(D) both even and odd

19) Which one of the following is an odd function :-

(A)

(B)

(C)

(D)

20) Let ƒ : → R be given by

ƒ(x) = (log(sec x + tan x))3, then f(x) is :-

(A) even function

(B) odd function
(C) neither an even nor an odd function
(D) none of these

SECTION-II
1) The range of the function is [a, b] then a2 + b2 = .....

2) If range of ƒ(x) = x2 + 8x + 20 is [a, b) ∀ x ∈ [–4, 0), then value of is

3) Given f(x) = 3 + sinx number of integers in the range of f(x) is/are

4)

Let and be a relation on A.

Then the minimum number of elements, that must be added to the relation R so that it becomes
reflexive and symmetric, is_____.

5) Let A = {1, 2, 3, ………100}. Let R be a relation on A defined by (x, y) R if and only if 2x = 3y.
Let R1 be a symmetric relation on A such that and the number of elements in R1 is n. Then,
the minimum value of n is ___________.
 ANSWER KEYS

PART - 1 PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C D B B C A B B C C D B B B C A C C A

SECTION-II

Q. 21 22 23 24 25
A. 640.00 576.00 12.00 12.00 3.00

PART - 2 CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D B B C A B A B C B C D C A A A B D B

SECTION-II

Q. 46 47 48 49 50
A. 7.00 3.00 6.00 9.00 2.00

PART - 3 MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A A B C A B B A B B C B D A B C B D B

SECTION-II

Q. 71 72 73 74 75
A. 15.00 5.00 3.00 7.00 66.00
 SOLUTIONS

PART - 1 PHYSICS

1) Explaining the Question :- Electrostatic force

Concept:-Electrostatic field and force.
Solution :-
After cutting string particle will move in direction of resultant force. Path will be straight line

Final Answer :- Option 2

2) Initially it is at rest
∴ speed will increase. But since charge is increasing
∴ it will come to rest again

3) diagonal length =

∴ flux =

4)
sinα =
cosα = 1/2

= 3 × 103 × 100 × 10–4

5) Electric field due to an arc at centre is given by

Force on –q,

6)

ϕ through one surface =

7) Through ABCD,
ϕin = ϕout
ϕnet = ϕout – ϕin = 0
8)

9) If we place another similar cone on this one, net flux =

⇒ Flux with the upper cone

=
This must also be the flux associated with the lower cone when the charge is raised through a
height 2H because of symmetry.

10) along line joining

Here r = 2R

11)

12) Charge can be covered making a tetrahedron so height of center from any triangle face. =

13) Explaining the Question :- Electric field due to a point charge is given byE = KQ/r2The
field due to positive charge is away from it, and due to negative charge is towards [Link] net
electric field to be zero, the magnitudes of both fields must cancel each other and the
directions must be opposite.
Concept:-
· Between –Q and +2Q, the fields add up (they are in same direction), so cancellation not
possible there.
· So, check left of –Q or right of +2Q.
· Net zero field is possible on the left of –Q, where both fields can oppose and magnitudes may
match.
Solution :- Let the distance between –Q and +2Q be [Link] electric field be zero at a point at
distance x left to –[Link]:Electric field due to –Q at that point:

Electric field due to +2Q at distance (d + x)

For fields to cancel, E1 = E2:

Cancel Q:

Cross-multiply:(d + x)2 = 2x2

Final Answer :- somewhere on left of –Q

14)

and

Using the Gauss theorem, we get

or

15)
16)

By conservation of energy ΔKE = ΔPE

17) E = o at a point near q1

and E = o b/w both the charge so the are like charges

18)

19) =

x=

20) By gauss law

21) Flux =

= 4000 (0·2)2 · (0·2)2m2

= 640 Vcm

22) ϕ = (E sin 53° × πR2)

23)
 |q| = 12∈0

24)

= × (4 + 6 + 8) = 12 Vm

25)

PART - 2 CHEMISTRY

26) NaxA → xNa+ + Ax–

ΔTf = ikf.m
3.255 = (x + 1) × 1.86 × 0.35
x=4

27)

Hence,
M.W. = 70.31

28)

Solution : The pressure of a 55.5 molal solution of δ is 250 bar

29)

The correct answer : t1 > t2

30) Explain Question :

Which is isotonic with 15% glucose solution.

Concept :
Isotonic solution
Solution :
for glucose i = 1
π = iCRT

πglucose =

isotonic solution i.e same osmotic pressure

0.5M ⇒ πNaCl = iCRT = 2 × 0.5 RT = RT

1N ⇒ = iCRT =
1M ⇒ = iCRT = 3 × 1 × RT = 3RT
0.5 ⇒ πurea = iCRT = 1 × 0.5 RT = 0.5RT
Final Answer option (3)

31) P = PB°XB + PT° XT

120 = 150(XB) + 50 (1 – XB)
100XB = 70
XB = 0.7

YB = = = 0.875
YT = 1 – 0.875 = 0.125
Final Answer: Option (1)

32)

Antifluorite structure = Anion + Cation

FCC lattice point Tetrahedral voids
S2– K⊕
No. of molecules in an unit cell = 4
No. of unit cell = 30.11 × 1022 unit cell
Total number of molecules = 30.11 × 4 × 1022 molecules

Moles of molecules =
Van’t Hoff factor = i = 3 as it is strong electrolyte.
K2S → 2K+ + S2–
ΔTf = Kf.m.i
ΔTf = 1.86 × 0.2 × 3 10 litre of water = 10 kg of water
ΔTf = 1.116 Density = 1 g/mL = 1 kg/litre

273 – Tf = 1.116 Molality = = 0.2

Tf = 271.884

33) Explanation: Find Molecular mass of the solute

Concept: Relative lowering of vapour pressure

Solution:

In the given Ostwald-Walker experiment setup:

Gain in weight of solution bulbs (Δw1 ) ∝ P0 – Ps= 1.5 g
Gain in weight of CaCl2 tube (Δw2 ) ∝ Ps = 2 g
According to Raoult's law:

Therefore, the molecular mass of the solute is 40.

Final Answer:
The correct option is (1).

34)

Ans : → Given : → moles of sucrose = x moles

mass of water (solvent) = 100 g

malality = = 10 x mol/kg
Freezing point = –0.2°C
Depression in freezing point. = ΔTf = 0.2°C
ΔTf = Kf m

Kf = = =
⇒ New temperature = –0.25°C
= 0.25°C

KF = , mass of solvent left = Wg

moles of sucrose = x moles
= 0.25 = Kf × m

0.25 =

W= = 80 g
Mass of ice separated = initial mass of solvent – mass of solvent left
= 100 – 80 = 20g – .

35) Question Explanation: Find value of van't Hoff factor for these solutions

Concept: Van't Hoff factor

Solution:
For a strong electrolyte like NaCl, it is assumed to undergo 100% dissociation into its ions
(Na+ and Cl–) regardless of the concentration in dilute aqueous solutions.
The dissociation reaction is: NaCl → Na+ + Cl–.
Since the number of particles produced per formula unit is constant (n = 2), the Van't Hoff
factor (i) remains the same for all three solutions: iA = iB = iC = 2.

Final Answer: Option (3)

36)

I. Ethyl ether + acetone : + ve deviation from Raoult’s law

II. Chloroform + acetone : –ve deviation from Raoult’s law
III. n–Hexane + h–heptane: ideal solution

37)

The correct answer : Plot of is linear

38)
Explanation: Find correct [Link]: Depression in freezing point Solution:In the
phase diagram:
The horizontal difference ' A ' at higher temperature (near 1 atm) represents the boiling point
elevation: A=ΔTb.
The horizontal difference ' B ' at lower temperature represents the freezing point depression:
B = ΔTf.
Therefore, A=ΔTb and B = ΔTf.
Correct option is (4).

39)

Explain Question:
The objective is to determine the relationship between liquid phase mole fractions and vapor
phase mole fractions for a binary solution.

Concept:
Raoult’s Law and Dalton’s Law of Partial Pressures.

Solution:
For a binary solution, the more volatile component (the one with a higher P°) will always
maintain a higher relative concentration in the vapor phase compared to the liquid phase.
Since P°A > P°B, component A is more volatile.

Calculation:
According to Raoult's Law and Dalton's Law: PA = XA P°A and PA = YA Ptotal.
This implies →
Taking the ratio:

Since

Final Answer: Option (3)

40)
if

41)

The correct answer is : 4 × 10-4

42)

The correct answer :

43)

Explain Question:
Comparing Henry’s law constants based on solubility-pressure graphs.

Concept:
Henry’s Law and Solubility

Solution:
According to Henry’s Law, P = KH • x (where x is solubility/mole fraction). For a given partial
pressure, solubility is inversely proportional to the Henry’s law constant (KH). A steeper slope
on a Solubility vs. Pressure graph indicates higher solubility and therefore a lower KH value.
Calculation:
Observe Slopes: Solubility slope order is O2 > N2 > He.

Relate to KH: Solubility

Determine KH Order: Since O2 is most soluble, it has the lowest KH. Since He is least soluble, it
has the highest KH.
Sequence: KH(O2) < KH(N2) < KH(He).

Final Answer: Option (2)

44)

The correct answer : 2000

45)

The correct answer is : Less than the vapour pressure of solvent

46) Explain question : We are given two containers in which ideal gases are filled at different
pressure and temperature. Both are connected by thin tube. It is asked to find the common
pressure in both container.
Concept : This question is based on kinetic theory of ideal gas.
Solution : The number of moles remains constant

∴ P = 7 × 105 Pa

Final answer : 7

47) π = iCRT
6 = [1 + α(3 – 1)] × 0.1 × 0.08 × 300

α = 0.75
p=3

48)

PbCl2 ⇌ Pb2+ + 2Cl–

Ksp = 4s3 = 4 × 10–6
s = 10–2 M
ΔTf = ikf.m
i = 3, kf = 2 K. kg/mol

ΔTf = 3 × 2 × 10–2 = 6 × 10–2 =

D=6

49)

Given : →
1. → A and B are in equimolar solution.
= 0.5
 = 45 Torr, = 20 Torr

45 = 0.5 × 20 + 0.5
45 – 10 = 0.5
= 70 Torr
2. PT = 22.5 Torr
PT = XA + XB , XA + XB = 1 XA = 1– XB
PT = (1–XB)
22.5 = 20 – 20XB + 70 XB
2.5 = 50 XB
XB = 0.05
XA= 1–0.05 = 0.95

y – 10 = 19 – 10 =

50) Negtive Deviation from Raoult's law

CH3COOH + C5H5N (pyridine)
C6H5NH2 + (CH3)2CO.

PART - 3 MATHEMATICS

51)

a R1b ⇔ |a| = |b| is reflexive, symmetric and transitive so this relation is equivalence relation.

52) Solution :
R = {(3, 3), (5, 5), (9, 9), (12, 12), (5, 12), (3, 9), (3, 12), (3, 5)} be a relation on the set A = {3,
5, 9, 12}
(a, a) ∈ R ∀ at {3, 5, 9, 12} so reflexive
For (5, 12), (12, 5) ∉ R. so not symmetric
for transitive (a, b) ∈ R and (b, c) ∈ R then (a, c) ∈ R
so transitive as for (3, 5) (5, 12) ∈ R ⇒ (3, 12) ∈ R
Final Answer : Option (1)

53) Conceptual

54) Conceptual

55)

The correct answer is : {(1, 1), (3, 3), (3, 1), (2, 3)}
 56) sec2 x - tan2 x = 1 (on replacing y with x)
Reflexive
Sec2 x - tan2 y = 1
1 + tan2x + 1 - sec2 y = 1
sec2y - tan2 x = 1
symmetric
sec2x - tan2y = 1,
sec2y - tan2 z = 1
Adding both
sec2x - tan2y + sec2y - tan2 z = 1 + 1
sec2x + 1 - tan2 z = 2
sec2 x - tan2 z = 1
Transitive
hence equivalence relation

57)

The number of all onto functions from the set = 120

the correct answer is : 5!

58) Question Explanation: Find the domain of the inverse of a relation on integers.
Concept: Domain and Range of Inverse Relation
Solution: The domain of the inverse relation R−1 is the range of the relation R.
The relation R on Z is defined by R={(x,y):x,y∈Z,x2+3y2≤8}.
We need to find the possible integer values for y (the range of R).

A. If y=0: x2+3(0)2≤8⟹x2≤8. Integer x values: {−2,−1,0,1,2}. (Possible, so y=0 is in the range).

B. If y=1: x2+3(1)2≤8⟹x2≤5. Integer x values: {−2,−1,0,1,2}. (Possible, so y=1 is in the range).
C. If y=−1: x2+3(−1)2≤8⟹x2≤5. Integer x values: {−2,−1,0,1,2}. (Possible, so y=−1 is in the
range).
D. If y=2: x2+3(2)2≤8⟹x2≤8−12=−4. (Not possible).
E. If y≥2 or y≤−2, 3y2≥12, so x2+3y2>8. (Not possible).

The integer values of y (the range of R) are {−1,0,1}. The domain of R−1 is {−1,0,1}.
Final Answer: option (2)

59)
∴ Range of ƒ(x) = R–{1} but if x = 6

then (1) ⇒

∴ Range =

∴ sum

60)
 f (x) = loge (3x2 – 4x + 5)
For domain

3x2 – 4x + 5 > 0 ∀ x ∈ R

Range =

62)

x2 + 9 – 6x = x – 1
x2 – 7x + 10 = 0 x = 5 & x = 2 (rejected)

63) | x |2 – | x | – 12 = 0
( | x | + 3) ( | x | – 4) = 0
|x|=4⇒x=±2

64)

Question Explanation: Determine if the given function is one-one, many-one, onto, or into.

Concept: Types of Functions (Injectivity and Surjectivity)

Solution:
Let f(x1) = f(x2)

⇒
⇒
⇒
⇒ 10(x1 – x2)(x1 + x2) = 0
⇒ x1 – x2 = 0 or x1 + x2 = 0
∴ f is not one one
OR

f(1) = f(–1)
(Q f(x) is even function \ many one)
Range :

yx2 + 2y = x2 – 8
(y – 1)x2 + 2y + 8 = 0
 Range = [–4, 1)
∴ Not onto

Final Answer: neither one-one nor onto

65) x + sinx is strictly increasing function

if x + sinx then ex+sinx also ⇒ ƒ(x) is one-one
ex+sinx ∈ (0,∞) ⇒ ƒ(x) is into function

66) f'(x) = (3x - 7) (x - 1)

Many one but onto

67) f(x) = f(–x)

⇒ a > x4 + 1
⇒ a > 257
∴ a ∈ (257, ∞ )

69) Only in option (4), the graph has a symmetry w.r.t. origin.

70) ƒ(–x) = (log(sec(–x) + tan(–x)))3

= (log(sec x –tan x)))3

= –(log(sec x + tan x))3 = –ƒ(x)

ƒ(x) is odd function.

71) 8x – 7 – x2 > 0 or x2 – 8x + 7 < 0 ⇒ x ∈ (1, 7)

⇒ x = 2, 3, 4, 5, 6
satisfy the given inequality.

72) ƒ(x) = (x + 4)2 + 4 ∀ x ∈ [–4, 0)

ƒ(x) ∈ [4, 20), a = 4, b = 20
73)

The correct answer is : 3.00

74)

The correct answer is : 7.00

75)

Question Explanation: Determining the minimum size of a symmetric relation containing a

given relation.

Concept: Symmetric Closure of a Relation.

Solution:

Condition for
For y to be an integer, x must be a multiple of 3.

∴ R = {(3, 2), (6, 4), (9, 6)......(99, 66)} Total elements = 33

Now, R1 be a symmetric relation on A such that R ⊂ R1
For a relation R1 to be symmetric if a pair (a, b) is in R1 then the pair (b, a) must also be in R1.
∴ Minimum element in symmetric .

Final Answer: 66